[go: up one dir, main page]

MX2019000598A - Metodo de oligomerizacion de olefinas. - Google Patents

Metodo de oligomerizacion de olefinas.

Info

Publication number
MX2019000598A
MX2019000598A MX2019000598A MX2019000598A MX2019000598A MX 2019000598 A MX2019000598 A MX 2019000598A MX 2019000598 A MX2019000598 A MX 2019000598A MX 2019000598 A MX2019000598 A MX 2019000598A MX 2019000598 A MX2019000598 A MX 2019000598A
Authority
MX
Mexico
Prior art keywords
oligomerization
olefins
unsubstituted
substituted
aryl
Prior art date
Application number
MX2019000598A
Other languages
English (en)
Inventor
Alekseevich Lenev Denis
Alexandrovich Kardash Vladislav
Vladimirovich Lipskikh Maxim
Acevedo Forero Rafael
Original Assignee
Sibur Holding Public Joint Stock Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sibur Holding Public Joint Stock Co filed Critical Sibur Holding Public Joint Stock Co
Publication of MX2019000598A publication Critical patent/MX2019000598A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122—Metal aryl or alkyl compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/128—Mixtures of organometallic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04—Mixing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/34—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation
    • B01J37/341—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation
    • B01J37/343—Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves ; Ionic sputtering; Flame or plasma spraying; Particle radiation making use of electric or magnetic fields, wave energy or particle radiation of ultrasonic wave energy
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/107—Alkenes with six carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/24—Catalytic processes with metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24
    • C07C2531/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups C07C2531/02 - C07C2531/24 of chromium, molybdenum or tungsten
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se relaciona con un método para preparar a-olefinas mediante oligomerización de ?2-?4 olefinas; el método se lleva a cabo mediante oligomerización de C2-C4 olefinas en la presencia de un sistema de catalizador comprendiendo una fuente de metal de transición, un activador, el cual es un alquilaluminoxano y un compuesto de fórmula (I), Ar1Ar2P-N(R)-PAr3Ar4 [fórmula I], en donde Ar1-4 son los mismos o diferentes y se seleccionan de C6-C10 arilo no sustituido y sustituido, R se selecciona de C1-C4 alquilo lineal o ramificado, C6-C10 arilo sustituido o no sustituido, y C3-C10 cicloalquilo sustituido o no sustituido, en donde la oligomerización se lleva a cabo en un solvente, el cual es un compuesto bicíclico o una mezcla de compuestos bicíclicos, preferiblemente decalina; el método reclamado provee un incremento significativo en la actividad del catalizador durante el proceso de oligomerización y como una consecuencia, una reducción en el consumo de unidad de catalizador, así como una reducción en la formación del subproducto de polímero.
MX2019000598A 2016-07-15 2016-07-15 Metodo de oligomerizacion de olefinas. MX2019000598A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/RU2016/000443 WO2018012997A1 (en) 2016-07-15 2016-07-15 Method of oligomerization of olefins

Publications (1)

Publication Number Publication Date
MX2019000598A true MX2019000598A (es) 2019-06-13

Family

ID=60953255

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019000598A MX2019000598A (es) 2016-07-15 2016-07-15 Metodo de oligomerizacion de olefinas.

Country Status (13)

Country Link
US (1) US10807922B2 (es)
EP (1) EP3484839B1 (es)
JP (1) JP6871358B2 (es)
KR (1) KR102218261B1 (es)
CN (1) CN109563009A (es)
BR (1) BR112019000550A2 (es)
CA (1) CA3030567C (es)
CO (1) CO2019000907A2 (es)
EA (1) EA039177B1 (es)
MX (1) MX2019000598A (es)
SG (1) SG11201900267YA (es)
WO (1) WO2018012997A1 (es)
ZA (1) ZA201900364B (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20210162373A1 (en) * 2019-12-03 2021-06-03 Purdue Research Foundation Zinc(II) and Gallium(III) Catalysts for Olefin Reactions
WO2022060108A1 (ko) * 2020-09-15 2022-03-24 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물 및 이를 포함하는 촉매 시스템
CN112473741B (zh) * 2020-10-22 2023-09-01 杭州小菱科技有限公司 一种乙烯齐聚催化剂体系及其制备方法与用途
CN115703850B (zh) * 2021-08-11 2024-04-30 中国石油天然气股份有限公司 非茂金属催化剂及其制备方法与应用
CN113731505B (zh) * 2021-09-13 2024-05-03 万华化学集团股份有限公司 一种乙烯齐聚催化剂体系与应用
CN116023548B (zh) * 2021-10-27 2024-10-15 中国石油化工股份有限公司 外给电子体组合物及应用、催化剂体系和烯烃聚合的方法
CN114163475B (zh) * 2021-12-01 2023-07-28 浙江智英石化技术有限公司 含吡咯基刚性结构多位点配体的催化剂体系、制备方法及应用
KR20240124384A (ko) * 2021-12-23 2024-08-16 사빅 글로벌 테크놀러지스 비.브이. 올리고머화 반응을 위한 촉매 조성물
CN115555053A (zh) * 2022-09-22 2023-01-03 中化泉州石化有限公司 一种配体化合物及其应用

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1164882A (en) * 1967-04-20 1969-09-24 Nii Monomerov Dyla Sint Kauchu Method of Olefin Dimerisation
TW354300B (en) * 1993-02-17 1999-03-11 Mitsubishi Chem Corp Process for producing <alpha>-olefin oligomers
FR2710280B1 (fr) * 1993-09-22 1995-11-17 Inst Francais Du Petrole Composition catalytique et procédé pour la dimérisation des oléfines.
GB0016895D0 (en) * 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
DE10211386A1 (de) * 2002-03-14 2003-09-25 Basf Ag Verfahren zur Oligomerisierung von Olefinen unter Verwendung eines Cycloalkylalkyl-substituierten Triazacyclohexans
DE10215754A1 (de) * 2002-04-10 2003-10-30 Basf Ag Verfahren zur Oligomerisierung von Olefinen
KR20060002742A (ko) * 2002-12-20 2006-01-09 사솔 테크날러지 (프로프라이어터리) 리미티드 올레핀의 사량체화
EP1710013A1 (en) * 2005-04-08 2006-10-11 Saudi Basic Industries Corporation A process for the preparation of linear alpha-olefin oligomers
ES2390858T5 (es) 2005-07-12 2016-09-20 Sasol Technology (Pty) Ltd Oligomerización de compuestos olefínicos en presencia de un activador diluido con contenido en metal
US7550639B2 (en) 2005-07-27 2009-06-23 Sumitomo Chemical Company, Limited Process for producing olefin oligomer
US20070156003A1 (en) 2005-12-09 2007-07-05 Taiichi Furukawa Method for producing saturated hydrocarbon compound
KR101074202B1 (ko) * 2007-01-18 2011-10-14 에스케이종합화학 주식회사 에틸렌 사량체화 촉매계 및 이를 이용한 1-옥텐의 제조방법
CA2639882C (en) 2008-09-29 2016-07-12 Nova Chemicals Corporation Tetramerization
IN2012DN03367A (es) * 2009-10-19 2015-10-23 Sasol Technolgoy Pty Ltd
KR102102347B1 (ko) 2012-05-09 2020-04-21 사솔 테크날러지 (프로프라이어터리) 리미티드 에틸렌의 사량체화
CN110452318A (zh) * 2013-01-14 2019-11-15 尤尼威蒂恩技术有限责任公司 制备高产率催化剂系统的方法
CN105228974B (zh) * 2013-05-09 2021-01-19 沙索技术有限公司 乙烯低聚成1-己烯和1-辛烯的混合物的低聚方法
WO2014181250A1 (en) 2013-05-09 2014-11-13 Sasol Technology (Proprietary) Limited Tetramerisation of ethylene
EP2832445A1 (en) 2013-07-29 2015-02-04 Linde AG Catalyst composition and process for oligomerization of ethylene
GB201408615D0 (en) * 2014-05-15 2014-06-25 Scg Chemicals Co Ltd Oligomerisation of ethylene
CN107074679B (zh) * 2014-09-22 2020-11-17 三菱化学株式会社 α-烯烃低聚物的制造方法和制造装置
BR112017019457A2 (pt) * 2015-03-13 2018-05-15 Dow Global Technologies Llc processo de oligomerização de olefina com um catalisador compreendendo um complexo de cromo com um ligante contendo fosfaciclo
US10464862B2 (en) * 2017-09-28 2019-11-05 Chevron Phillips Chemical Company Lp Oligomerization reactions using aluminoxanes
US20190352439A1 (en) * 2018-05-17 2019-11-21 Formosa Plastics Corporation, Usa Ethylene/Alpha-Olefin Copolymers for Better Optical and Mechanical Properties and Processability of Film Made Therefrom

Also Published As

Publication number Publication date
SG11201900267YA (en) 2019-02-27
BR112019000550A2 (pt) 2019-05-21
CO2019000907A2 (es) 2019-02-08
EA039177B1 (ru) 2021-12-14
KR20190029663A (ko) 2019-03-20
JP6871358B2 (ja) 2021-05-12
US20190144357A1 (en) 2019-05-16
CA3030567C (en) 2021-03-02
EP3484839A4 (en) 2020-03-18
EA201990186A1 (ru) 2020-02-11
EP3484839A1 (en) 2019-05-22
CN109563009A (zh) 2019-04-02
ZA201900364B (en) 2021-01-27
KR102218261B1 (ko) 2021-02-23
US10807922B2 (en) 2020-10-20
CA3030567A1 (en) 2018-01-18
JP2019522667A (ja) 2019-08-15
EP3484839B1 (en) 2020-12-30
WO2018012997A1 (en) 2018-01-18

Similar Documents

Publication Publication Date Title
MX2019000598A (es) Metodo de oligomerizacion de olefinas.
EA201692489A1 (ru) Прокатализатор полимеризации олефинов, содержащий сложный моноэфир и амидобензоатный внутренний донор
MX2023011282A (es) Analogos de rapamicina ligados a c40, c28 y c-32 como inhibidores de mtor.
MX2023000410A (es) Analogos de rapamicina como inhibidores de mtor.
EA201692461A1 (ru) Прокатализатор для полимеризации олефинов
EA201500779A1 (ru) Каталитическая композиция для полимеризации олефинов
MX362715B (es) Procedimiento para oligomerización de etileno.
MY205585A (en) Dual inhibitors of vista and pd-1 pathways
MY152879A (en) Transition metal complex compounds, olefin oligomerization catalysts including the compounds, and processes for producing olefin oligomers using the catalysts
IN2014DN05639A (es)
WO2011106480A3 (en) Internal and external donor compounds for olefin polymerization catalysts ii
MY178722A (en) Catalyst component for olefin polymerization, preparation method thereof, and catalyst comprising same
CL2012001681A1 (es) Compuestos n2-fosfinil amidina; complejos metalicos; sistemas catalizadores; metodos de preparacion; y su uso para oligomerizar o polimerizar olefinas.
WO2016149025A3 (en) Phosphacycle-containing ligand for chromium complex and olefin oligomerization catalyst therefrom
MX2016015210A (es) Proceso para la dimerizacion de olefinas activadas.
MY176619A (en) Catalyst component for olefin polymerization, and catalyst containing the same
EA201691281A1 (ru) Композиция катализатора полимеризации олефинов
EP4122924A3 (en) Compounds and the use thereof in metathesis reactions
BR112017022154A2 (pt) método para síntese de complexos de monociclopentadienil de zircônio e háfnio
BR112019025028A2 (pt) Método para preparar um composto.
EA033164B1 (ru) Каталитическая система для полимеризации олефина
PE20210159A1 (es) Metodo para la preparacion de una 1,2,4-triazolona 2,4,5-trisustituida
EA201990805A1 (ru) Прокатализатор для полимеризации олефинов
EA201691038A1 (ru) Модифицированные углеводородные смолы в качестве снижающих фильтрацию добавок
MX2020003162A (es) Proceso para la produccion de alquilaromaticos.