MX2018011567A - Formulacion acrilica mejorada de resistencia a la fundicion. - Google Patents
Formulacion acrilica mejorada de resistencia a la fundicion.Info
- Publication number
- MX2018011567A MX2018011567A MX2018011567A MX2018011567A MX2018011567A MX 2018011567 A MX2018011567 A MX 2018011567A MX 2018011567 A MX2018011567 A MX 2018011567A MX 2018011567 A MX2018011567 A MX 2018011567A MX 2018011567 A MX2018011567 A MX 2018011567A
- Authority
- MX
- Mexico
- Prior art keywords
- acrylic
- formulation
- foundry
- resistance
- useful
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/003—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/0005—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor characterised by the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/02—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising combinations of reinforcements, e.g. non-specified reinforcements, fibrous reinforcing inserts and fillers, e.g. particulate fillers, incorporated in matrix material, forming one or more layers and with or without non-reinforced or non-filled layers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/142—Compounds containing oxygen but no halogen atom
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2033/00—Use of polymers of unsaturated acids or derivatives thereof as moulding material
- B29K2033/04—Polymers of esters
- B29K2033/08—Polymers of acrylic acid esters, e.g. PMA, i.e. polymethylacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/024—Preparation or use of a blowing agent concentrate, i.e. masterbatch in a foamable composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2333/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
La invención se refiere a una formulación acrílica que tiene una matriz acrílica y de 1 a 20% en peso de un aditivo de procesamiento acrílico de peso molecular muy alto, con un peso molecular medio superior a 5,000,000 de Daltons. La formulación tiene una alta resistencia a la fundición, pero se puede implementar en condiciones típicas de procesamiento por fundición. La formulación es útil para los productos tratados en fundido, incluidos los productos extruidos tales como láminas extruidas, espumas, perfiles coextruidos, películas obtenidas por moldeo por soplado, y otros objetos típicamente formados por una operación de procesamiento térmica. Las matrices acrílicas útiles incluyen resinas Plexiglas(r) y Solarkote(r) de Arkema Inc.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662313276P | 2016-03-25 | 2016-03-25 | |
| PCT/US2017/023982 WO2017165743A1 (en) | 2016-03-25 | 2017-03-24 | Enhanced melt strength acrylic formulation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2018011567A true MX2018011567A (es) | 2019-05-27 |
Family
ID=59900749
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2018011567A MX2018011567A (es) | 2016-03-25 | 2017-03-24 | Formulacion acrilica mejorada de resistencia a la fundicion. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20200291154A1 (es) |
| EP (1) | EP3432893B1 (es) |
| JP (1) | JP2019509389A (es) |
| KR (1) | KR20180128033A (es) |
| MX (1) | MX2018011567A (es) |
| WO (1) | WO2017165743A1 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109836532A (zh) * | 2019-03-04 | 2019-06-04 | 浙江华慧塑业有限公司 | 一种超高分子量的pvc熔体增强剂及其制备方法 |
| CN116194530A (zh) * | 2020-09-30 | 2023-05-30 | 罗门哈斯公司 | 用于热塑性加工的高分子量丙烯酸加工助剂浓缩物 |
| CN116891616A (zh) * | 2023-07-19 | 2023-10-17 | 漳平市国联玩具礼品有限公司 | 一种改性塑胶材料玩具生产工艺 |
| WO2025029795A1 (en) * | 2023-08-01 | 2025-02-06 | Rohm And Haas Company | High molecular weight acrylic processing aid concentrate for thermoplastic processing |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2887478B2 (ja) * | 1988-03-29 | 1999-04-26 | 三菱レイヨン株式会社 | 熱可塑性樹脂用加工助剤及びそれを用いた熱可塑性樹脂組成物 |
| JP2705812B2 (ja) | 1988-10-31 | 1998-01-28 | 三菱レイヨン株式会社 | 熱可塑性樹脂用滑剤およびこれを用いた熱可塑性樹脂組成物 |
| CA2042452A1 (en) * | 1990-05-25 | 1991-11-26 | Loren D. Trabert | Modified acrylic capstock |
| DE19927769A1 (de) * | 1999-06-17 | 2000-12-21 | Roehm Gmbh | Schlagzähmodifizierte Polymethacrylat-Formmasse mit verbesserter Fließfähigkeit |
| US6784230B1 (en) * | 1999-09-23 | 2004-08-31 | Rohm And Haas Company | Chlorinated vinyl resin/cellulosic blends: compositions, processes, composites, and articles therefrom |
| EP1152033B1 (en) * | 2000-05-03 | 2017-05-24 | Rohm And Haas Company | Polymeric compositions and processes for providing weatherable film and sheet |
| EP1153936B1 (en) * | 2000-05-12 | 2004-08-04 | Rohm And Haas Company | Plastics additives, improved process, products, and articles containing same |
| MY131000A (en) * | 2001-03-16 | 2007-07-31 | Dow Global Technologies Inc | High melt strength polymers and method of making same |
| GB0508255D0 (en) * | 2005-04-25 | 2005-06-01 | Lucite Int Uk Ltd | Acrylic blends |
| FR2912412B1 (fr) * | 2007-02-12 | 2012-09-28 | Arkema France | Composition thermoplastique comprenant une matrice thermoplastique et un copolymere particulier. |
| JP5346192B2 (ja) | 2007-10-05 | 2013-11-20 | ローム アンド ハース カンパニー | 改善されたポリマー組成物 |
| US9309397B2 (en) * | 2007-10-05 | 2016-04-12 | Rohm And Haas Company | Processing aids and polymer formulations containing the same and method for producing the same |
| BRPI0907893B1 (pt) * | 2008-02-25 | 2019-01-15 | Arkema France | composição de liga acrílica transparente. |
| US8299139B1 (en) * | 2009-09-08 | 2012-10-30 | Ovation Polymer Technology And Engineered Materials, Inc. | Process and reactor for synthesis of ultra-high molecular weight acrylic polymers |
| JP5652401B2 (ja) * | 2009-10-13 | 2015-01-14 | コニカミノルタ株式会社 | 光学フィルム |
| US8288494B2 (en) * | 2009-12-31 | 2012-10-16 | Cheil Industries Inc. | Transparent thermoplastic resin composition with improved impact strength and melt flow index |
| JP5527252B2 (ja) * | 2010-02-25 | 2014-06-18 | 日立金属株式会社 | ノンハロゲン難燃樹脂組成物及びそれを用いたケーブル |
| JP2011246655A (ja) * | 2010-05-28 | 2011-12-08 | Kaneka Corp | 熱可塑性樹脂組成物、その成形体、及び成型方法 |
| JP5619638B2 (ja) * | 2011-01-27 | 2014-11-05 | ユニチカ株式会社 | ポリ乳酸系樹脂組成物およびそれから得られる成形体と発泡体 |
| JP2013213087A (ja) * | 2012-03-30 | 2013-10-17 | Kaneka Corp | 熱可塑性樹脂組成物 |
| JP2013221039A (ja) * | 2012-04-13 | 2013-10-28 | Unitika Ltd | ポリ乳酸系樹脂組成物及び射出成形品 |
| JP2015063583A (ja) * | 2013-09-24 | 2015-04-09 | ユニチカ株式会社 | ポリ乳酸系樹脂組成物および成形体 |
| JP6219130B2 (ja) * | 2013-11-05 | 2017-10-25 | リケンテクノス株式会社 | 医療用塩化ビニル樹脂組成物およびそれからなる医療用器具 |
-
2017
- 2017-03-24 MX MX2018011567A patent/MX2018011567A/es unknown
- 2017-03-24 WO PCT/US2017/023982 patent/WO2017165743A1/en not_active Ceased
- 2017-03-24 JP JP2018550355A patent/JP2019509389A/ja active Pending
- 2017-03-24 EP EP17771220.5A patent/EP3432893B1/en active Active
- 2017-03-24 KR KR1020187031005A patent/KR20180128033A/ko not_active Ceased
- 2017-03-24 US US16/086,020 patent/US20200291154A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US20200291154A1 (en) | 2020-09-17 |
| EP3432893A4 (en) | 2019-10-30 |
| WO2017165743A1 (en) | 2017-09-28 |
| EP3432893A1 (en) | 2019-01-30 |
| KR20180128033A (ko) | 2018-11-30 |
| EP3432893B1 (en) | 2022-10-26 |
| JP2019509389A (ja) | 2019-04-04 |
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