MX2018009318A - Proceso para preparar etilenaminas superiores y derivados de etilenamina. - Google Patents
Proceso para preparar etilenaminas superiores y derivados de etilenamina.Info
- Publication number
- MX2018009318A MX2018009318A MX2018009318A MX2018009318A MX2018009318A MX 2018009318 A MX2018009318 A MX 2018009318A MX 2018009318 A MX2018009318 A MX 2018009318A MX 2018009318 A MX2018009318 A MX 2018009318A MX 2018009318 A MX2018009318 A MX 2018009318A
- Authority
- MX
- Mexico
- Prior art keywords
- ethylene
- derivatives
- present
- units
- functional
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
- C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
- C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/14—Amines containing amino groups bound to at least two aminoalkyl groups, e.g. diethylenetriamines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C269/06—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups by reactions not involving the formation of carbamate groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
- C07C273/1809—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
- C07C273/1809—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
- C07C273/1836—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety from derivatives of carbamic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
- C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
- C07C273/1854—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety
- C07C273/1863—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas by reactions not involving the formation of the N-C(O)-N- moiety from urea
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C275/00—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
- C07C275/04—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms
- C07C275/06—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton
- C07C275/14—Derivatives of urea, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups having nitrogen atoms of urea groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton being further substituted by nitrogen atoms not being part of nitro or nitroso groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/30—Oxygen or sulfur atoms
- C07D233/32—One oxygen atom
- C07D233/36—One oxygen atom with hydrocarbon radicals, substituted by nitrogen atoms, attached to ring nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G71/00—Macromolecular compounds obtained by reactions forming a ureide or urethane link, otherwise, than from isocyanate radicals in the main chain of the macromolecule
- C08G71/02—Polyureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0273—Polyamines containing heterocyclic moieties in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/0605—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
- C08G73/0616—Polycondensates containing five-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with only two nitrogen atoms in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente invención se refiere a un proceso para preparar etilenaminas de la fórmula NH2-(C2H4-NH-)pH, en donde p es por lo menos 3, o derivados de las mismas, en donde pueden estar presentes una o más unidades -NH-C2H4-NH- como una unidad de etilenurea cíclica, o entre dos unidades -NH-C2H4-NH- está presente una porción carbonilo, haciendo reaccionar un compuesto etanolamina funcional, un compuesto amina funcional, en presencia de un agente de liberación de óxido de carbono, en donde la proporción molar de agente de liberación de óxido de carbono a compuesto amina funcional es de por lo menos 0.6 a 1.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16155545 | 2016-02-12 | ||
| PCT/EP2017/052946 WO2017137531A1 (en) | 2016-02-12 | 2017-02-10 | Process to prepare higher ethylene amines and ethylene amine derivatives |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2018009318A true MX2018009318A (es) | 2018-11-09 |
| MX390660B MX390660B (es) | 2025-03-21 |
Family
ID=55353139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2018009318A MX390660B (es) | 2016-02-12 | 2017-02-10 | Proceso para preparar etilenaminas superiores y derivados de etilenamina. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US10844001B2 (es) |
| EP (1) | EP3414221B1 (es) |
| JP (1) | JP6836596B2 (es) |
| KR (1) | KR102139560B1 (es) |
| CN (1) | CN108713012B (es) |
| BR (1) | BR112018014267B1 (es) |
| MX (1) | MX390660B (es) |
| WO (1) | WO2017137531A1 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017137532A1 (en) | 2016-02-12 | 2017-08-17 | Akzo Nobel Chemicals International B.V. | Process to prepare higher ethylene amines and ethylene amine derivatives |
| CN108602788B (zh) | 2016-02-12 | 2022-06-07 | 阿克苏诺贝尔化学品国际有限公司 | 制备高级亚乙基胺和亚乙基胺衍生物的方法 |
| WO2018108888A1 (en) | 2016-12-15 | 2018-06-21 | Akzo Nobel Chemicals International B.V. | Process for manufacturing hydroxyethyl ethylene amines |
| US10975017B2 (en) * | 2016-12-15 | 2021-04-13 | Nouryon Chemicals International B.V. | Process for manufacturing ethylene amines |
| TWI761545B (zh) * | 2017-07-10 | 2022-04-21 | 荷蘭商安科智諾貝爾化學國際公司 | 製備伸乙基胺及伸乙基胺衍生物之方法 |
| WO2019030191A1 (en) | 2017-08-11 | 2019-02-14 | Akzo Nobel Chemicals International B.V. | METHOD FOR PRODUCING CYCLIC UREA PRODUCT OF ETHYLENEAMINE COMPOUND |
| TWI834620B (zh) * | 2017-08-11 | 2024-03-11 | 荷蘭商安科智諾貝爾化學國際公司 | 製備環狀伸烷基脲之方法 |
| BR112020002390A2 (pt) * | 2017-08-11 | 2020-09-08 | Nouryon Chemicals International B.V. | processo de conversão da monoureia cíclica de compostos de etileno amina em composto de etileno amina |
| CN110997621A (zh) * | 2017-08-11 | 2020-04-10 | 诺力昂化学品国际有限公司 | 将环状亚烷基脲转化成其相应亚烷基胺的方法 |
| CN113061249B (zh) * | 2021-04-29 | 2022-06-07 | 中山大学 | 聚乙烯亚胺的制备方法 |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US2613212A (en) * | 1950-10-26 | 1952-10-07 | Rohm & Haas | Imidazolidone derivatives |
| US2812333A (en) | 1954-09-27 | 1957-11-05 | Union Carbide Corp | Process for the preparation of 1-(2-hydroxyethyl) imidazolidine-2 |
| CH478180A (de) | 1966-11-07 | 1969-09-15 | Francis Dr Pascoe Peter | Verfahren zur Herstellung von Polyäthylenaminen |
| GB1510538A (en) | 1974-06-22 | 1978-05-10 | Bayer Ag | Colourless triethylene tetramine and tetraethylene pentamine |
| US4123462A (en) | 1976-01-07 | 1978-10-31 | Union Carbide Corporation | Amination process using nickel-rhenium catalysts |
| JPS5538329A (en) * | 1978-09-13 | 1980-03-17 | Toyo Soda Mfg Co Ltd | Preparation of polyethylenepolyamine |
| US4503250A (en) * | 1981-09-30 | 1985-03-05 | Union Carbide Corporation | Preparation of polyalkylene polyamines |
| CA1202328A (en) * | 1981-09-30 | 1986-03-25 | William B. Herdle | Preparation of polyalkylene polyamines |
| US4387249A (en) * | 1981-12-18 | 1983-06-07 | The Dow Chemical Company | Process for the manufacture of diethylenetriamine |
| IT1159074B (it) | 1982-06-24 | 1987-02-25 | Stoppani Luigi Spa | Composto di addizione fra menadione e tiamina a reciproca stabilizzazione |
| NL8204546A (nl) | 1982-11-23 | 1984-06-18 | Akzo Nv | Werkwijze voor het winnen van ethyleenamines uit waterige oplossing. |
| JPS59161338A (ja) | 1983-03-04 | 1984-09-12 | Toyo Soda Mfg Co Ltd | エチレンアミン類炭酸塩水溶液からエチレンアミン類を得る方法 |
| US4684729A (en) | 1983-07-15 | 1987-08-04 | The Dow Chemical Company | Polyethylene polypiperazine compositions |
| JPS60120842A (ja) | 1983-12-03 | 1985-06-28 | Toyo Soda Mfg Co Ltd | エチレンアミン類炭酸塩からエチレンアミン類を得る方法 |
| JPS60126248A (ja) | 1983-12-09 | 1985-07-05 | Toyo Soda Mfg Co Ltd | エチレンアミン類炭酸塩水溶液の脱炭酸方法 |
| EP0222934A1 (en) | 1985-09-11 | 1987-05-27 | The Dow Chemical Company | Process for preparation of polyalkylenepolyamines |
| US4758354A (en) | 1985-12-12 | 1988-07-19 | General Technology Applications, Inc. | Separation process |
| DE3744120A1 (de) | 1987-12-24 | 1989-07-06 | Basf Ag | Verfahren zur herstellung von 1,3-dialkyl-2-imidazolidinonen |
| US5011999A (en) * | 1989-02-23 | 1991-04-30 | The Dow Chemical Company | Process of preparing non-cyclic polyalkylenepolyamines employing group VB metal catalysts |
| US5112984A (en) | 1990-09-20 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Processes for the preparation of cyclic nitrogen-containing compounds |
| US5262534A (en) | 1990-09-20 | 1993-11-16 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the preparation of nonaromatic cyclic nitrogen-containing compounds |
| US5399706A (en) * | 1993-03-02 | 1995-03-21 | H. B. Fuller Licensing & Financing, Inc. | Imidazolidinone diamine and derivatives thereof |
| US5364971A (en) | 1993-08-25 | 1994-11-15 | Texaco Chemical Inc. | Decolorization of polyethylene polyamines using ruthenium |
| US5491263A (en) * | 1993-12-21 | 1996-02-13 | The Dow Chemical Company | Aminoethylation process for production of substituted ethylene diamines |
| JPH1045682A (ja) | 1996-08-05 | 1998-02-17 | Tosoh Corp | 高品位ポリエチレンポリアミン類の製造方法 |
| DE10335991A1 (de) | 2003-08-01 | 2005-02-24 | Basf Ag | Verfahren zur Herstellung von Ethylenaminen |
| FR2912148B1 (fr) | 2007-02-07 | 2009-04-10 | Arkema France | Materiau polymere de type styrene / anhydride, greffe ayant des proprietes ameliorees |
| RU2472772C2 (ru) * | 2007-03-01 | 2013-01-20 | Басф Се | Способ получения триэтилентетрамина (тэта) через этилендиаминдиацетонитрил (эддн) |
| CN101675025B (zh) | 2007-03-01 | 2015-04-08 | 巴斯夫欧洲公司 | 制备四亚乙基五胺的方法 |
| BRPI0914054A2 (pt) | 2008-10-06 | 2015-11-03 | Union Carbide Chem Plastic | método para produzir etilenoaminas |
| WO2010042159A1 (en) * | 2008-10-06 | 2010-04-15 | Union Carbide Chemicals & Plastics Technology Llc | Methods of making cyclic, n-amino functional triamines |
| WO2010042160A1 (en) | 2008-10-06 | 2010-04-15 | Union Carbide Chemicals & Plastics Technology Llc | A process to selectively manufacture diethylenetriamine (deta) or other desirable ethylenamines via continuous transamination of ethylenediamine (eda), and other ethyleneamines over a heterogeneous catalyst system |
| US8459941B2 (en) | 2009-06-15 | 2013-06-11 | General Electric Company | Mechanical joint for a gas turbine engine |
| CA2785028C (en) | 2009-12-21 | 2018-01-16 | Schlumberger Canada Limited | Hydrogen bonding material for oilfield application |
| FR2955105B1 (fr) * | 2010-01-11 | 2012-04-20 | Arkema France | Procede de preparation d'aminoethyl imidazolidone ou de son thiocarbonyle |
| CN101870679A (zh) * | 2010-06-03 | 2010-10-27 | 华东理工大学 | N-(2-氨乙基)-2-咪唑烷酮的制备方法 |
| WO2013110092A1 (en) | 2012-01-20 | 2013-07-25 | Board Of Regents, The University Of Texas System | Blends of amines with piperazine for co2 capture |
| CN103333323B (zh) * | 2013-06-13 | 2015-09-02 | 武汉市科达云石护理材料有限公司 | 高韧性高活性环氧树脂固化剂及其制备方法 |
| MX384400B (es) | 2016-02-12 | 2025-03-14 | Akzo Nobel Chemicals Int Bv | Proceso para convertir alquilenureas cíclicas en sus correspondientes alquilenaminas. |
| CN108602788B (zh) | 2016-02-12 | 2022-06-07 | 阿克苏诺贝尔化学品国际有限公司 | 制备高级亚乙基胺和亚乙基胺衍生物的方法 |
| WO2017137532A1 (en) | 2016-02-12 | 2017-08-17 | Akzo Nobel Chemicals International B.V. | Process to prepare higher ethylene amines and ethylene amine derivatives |
-
2017
- 2017-02-10 WO PCT/EP2017/052946 patent/WO2017137531A1/en not_active Ceased
- 2017-02-10 CN CN201780009826.6A patent/CN108713012B/zh active Active
- 2017-02-10 US US16/074,485 patent/US10844001B2/en active Active
- 2017-02-10 BR BR112018014267-0A patent/BR112018014267B1/pt not_active IP Right Cessation
- 2017-02-10 JP JP2018539990A patent/JP6836596B2/ja active Active
- 2017-02-10 KR KR1020187024313A patent/KR102139560B1/ko active Active
- 2017-02-10 MX MX2018009318A patent/MX390660B/es unknown
- 2017-02-10 EP EP17703438.6A patent/EP3414221B1/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017137531A1 (en) | 2017-08-17 |
| US10844001B2 (en) | 2020-11-24 |
| BR112018014267B1 (pt) | 2021-12-28 |
| MX390660B (es) | 2025-03-21 |
| EP3414221B1 (en) | 2021-09-01 |
| US20190039993A1 (en) | 2019-02-07 |
| BR112018014267A2 (pt) | 2018-12-18 |
| KR102139560B1 (ko) | 2020-07-31 |
| CN108713012A (zh) | 2018-10-26 |
| CN108713012B (zh) | 2021-07-02 |
| KR20180103154A (ko) | 2018-09-18 |
| JP2019504845A (ja) | 2019-02-21 |
| JP6836596B2 (ja) | 2021-03-03 |
| EP3414221A1 (en) | 2018-12-19 |
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