MX2018000413A - Metodo para la hidroformilacion de butadienos 2-sustituidos y la produccion de productos secundarios de estos, especialmente ambrox. - Google Patents
Metodo para la hidroformilacion de butadienos 2-sustituidos y la produccion de productos secundarios de estos, especialmente ambrox.Info
- Publication number
- MX2018000413A MX2018000413A MX2018000413A MX2018000413A MX2018000413A MX 2018000413 A MX2018000413 A MX 2018000413A MX 2018000413 A MX2018000413 A MX 2018000413A MX 2018000413 A MX2018000413 A MX 2018000413A MX 2018000413 A MX2018000413 A MX 2018000413A
- Authority
- MX
- Mexico
- Prior art keywords
- hydroformylation
- ambrox
- production
- secondary products
- substituted butadienes
- Prior art date
Links
- 238000007037 hydroformylation reaction Methods 0.000 title abstract 3
- -1 2-substituted butadienes Chemical class 0.000 title abstract 2
- YPZUZOLGGMJZJO-UHFFFAOYSA-N ambrofix Natural products C1CC2C(C)(C)CCCC2(C)C2C1(C)OCC2 YPZUZOLGGMJZJO-UHFFFAOYSA-N 0.000 title abstract 2
- YPZUZOLGGMJZJO-LQKXBSAESA-N ambroxan Chemical compound CC([C@@H]1CC2)(C)CCC[C@]1(C)[C@@H]1[C@]2(C)OCC1 YPZUZOLGGMJZJO-LQKXBSAESA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical class C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
- B01J31/186—Mono- or diamide derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
- B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/56—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by isomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C33/00—Unsaturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C33/02—Acyclic alcohols with carbon-to-carbon double bonds
- C07C33/025—Acyclic alcohols with carbon-to-carbon double bonds with only one double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
- C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/92—Naphthofurans; Hydrogenated naphthofurans
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
- Catalysts (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
La presente invención se refiere a un método para la hidroformilación regioselectiva de hidrocarburos acíclicos poliinsaturados, que son 1,3 butadienos, que, en la posición 2, tienen un radical hidrocarburo acíclico saturado o monoinsaturado o poliinsaturado. La presente invención también se refiere a la producción de productos secundarios de estos productos de hidroformilación, especialmente, de ambrox.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15176280 | 2015-07-10 | ||
| PCT/EP2016/066225 WO2017009205A1 (de) | 2015-07-10 | 2016-07-08 | Verfahren zur hydroformylierung von 2-substituierten butadienen und zur herstellung von folgeprodukten davon, speziell von ambrox |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2018000413A true MX2018000413A (es) | 2018-09-06 |
Family
ID=53773218
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2018000413A MX2018000413A (es) | 2015-07-10 | 2016-07-08 | Metodo para la hidroformilacion de butadienos 2-sustituidos y la produccion de productos secundarios de estos, especialmente ambrox. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10315975B2 (es) |
| EP (1) | EP3319951B1 (es) |
| JP (1) | JP6852046B2 (es) |
| CN (1) | CN108026062B (es) |
| BR (1) | BR112018000481B1 (es) |
| ES (1) | ES2899823T3 (es) |
| MX (1) | MX2018000413A (es) |
| PL (1) | PL3319951T3 (es) |
| WO (1) | WO2017009205A1 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10202323B2 (en) | 2015-07-15 | 2019-02-12 | Basf Se | Process for preparing an arylpropene |
| EP3170828A1 (de) * | 2015-11-23 | 2017-05-24 | Basf Se | Verfahren zur herstellung von verbindungen mit 16-oxabicyclo[10.3.1]pentadecengerüst und deren folgeprodukten |
| EP3816297A1 (de) | 2016-02-19 | 2021-05-05 | Basf Se | Biokatalytische zyklisierung von mehrfach ungesättigten carbonsäuren-verbindungen |
| US10981885B2 (en) | 2016-05-31 | 2021-04-20 | Basf Se | Tetrahydropyranyl lower alkyl esters and the production of same using a ketene compound |
| JP7039551B2 (ja) | 2016-07-15 | 2022-03-22 | ビーエーエスエフ ソシエタス・ヨーロピア | 3-メチル-1,5-シクロペンタデカンジオンからの14-メチル-16-オキサビシクロ[10.3.1]ペンタデセンの調製 |
| CN110800150B (zh) | 2017-03-31 | 2022-11-29 | 株式会社村田制作所 | 包含电解质稳定材料的非水电解质和电解液、包含它们的二次电池及其用途 |
| EP3619189B1 (en) | 2017-05-06 | 2022-08-17 | Basf Se | 2,3,7-trimethyloct-6-enyl acetate and 3,7-dimethyl-2-methylene-oct-6-enyl acetate and derivatives thereof and their use as aroma chemicals |
| KR20200018442A (ko) | 2017-06-13 | 2020-02-19 | 바스프 에스이 | 1,6-헥산디올 유도체를 제조하기 위한 히드로포르밀화 방법 |
| EP4195154A4 (en) | 2020-12-09 | 2024-01-17 | Samsung Electronics Co., Ltd. | ARTIFICIAL INTELLIGENCE CODING APPARATUS AND OPERATION METHOD THEREFOR, AND ARTIFICIAL INTELLIGENCE DECODING APPARATUS AND OPERATION METHOD THEREFOR |
| ES2989800T3 (es) * | 2021-12-17 | 2024-11-27 | Evonik Oxeno Gmbh & Co Kg | Procedimiento para la hidroformilación de olefinas con empleo de Pt y yodo |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3625261A1 (de) | 1986-07-25 | 1988-02-04 | Basf Ag | Verfahren zur kontinuierlichen hydroformylierung olefinisch ungesaettigter verbindungen |
| JP2893902B2 (ja) | 1989-10-19 | 1999-05-24 | 三菱化学株式会社 | オレフィンのヒドロホルミル化法 |
| US5326888A (en) | 1990-10-09 | 1994-07-05 | Henkel Research Corporation | Carbonylation of allylic alcohols and synthesis of an ambergris fragance compound |
| US5744650A (en) | 1995-12-06 | 1998-04-28 | Union Carbide Chemicals & Plastics Technology Corporation | Metal-Ligand complex catalyzed processes |
| US5962744A (en) * | 1998-03-27 | 1999-10-05 | The Research Foundation Of State University Of New York | Process for hydrocarbonylations in supercritical carbon dioxide |
| DE19836807A1 (de) | 1998-08-14 | 2000-02-17 | Basf Ag | Verfahren zur Herstellung von Aldehyden und/oder Alkoholen oder Aminen |
| DE10005794A1 (de) | 2000-02-10 | 2001-08-16 | Basf Ag | Verbindungen des Phosphors, Arsens und des Antimons |
| EP1156055A1 (en) | 2000-05-16 | 2001-11-21 | Firmenich Sa | Process for the preparation of ruthenium compounds |
| DE10046026A1 (de) | 2000-09-18 | 2002-03-28 | Basf Ag | Verfahren zur Hydroformylierung, Xanthen-verbrückte Liganden und Katalysator, umfassend einen Komplex dieser Liganden |
| DE10106482A1 (de) | 2001-02-13 | 2002-08-14 | Basf Ag | Hydroformylierung |
| EP1383777B1 (de) | 2001-03-29 | 2005-11-16 | Basf Aktiengesellschaft | Liganden für pnicogenchelatkomplexe mit einem metall der viii. nebengruppe und verwendung der komplexe als katalysatoren für hydroformylierung, carbonylierung, hydrocyanierung oder hydrierung |
| AU2002324067A1 (en) | 2001-08-24 | 2003-03-10 | Basf Aktiengesellschaft | Method for the production of 2-propylheptanol and hydroformylating catalysts and the further use thereof for carbonylation, hydrocyanation and hydrogenation |
| DE10242636A1 (de) | 2002-09-13 | 2004-03-18 | Basf Ag | Verfahren zur Herstellung von Dialdehyden und/oder ethylenisch ungesättigten Monoaldehyden durch Hydroformylierung ethylenisch ungesättigter Verbindungen |
| DE10342760A1 (de) | 2002-09-17 | 2004-03-25 | Basf Ag | Pnicogenverbindungen |
| DE10333519A1 (de) | 2003-07-23 | 2005-02-17 | Basf Ag | Zweistufiges Hydroformylierungsverfahren |
| WO2005042458A2 (de) * | 2003-10-21 | 2005-05-12 | Basf Aktiengesellschaft | Verfahren zur kontinuierlichen herstellung von aldehyden |
| DE10349343A1 (de) * | 2003-10-23 | 2005-06-02 | Basf Ag | Stabilisierung von Hydroformylierungskatalysatoren auf Basis von Phosphoramiditliganden |
| WO2005063730A1 (de) | 2003-12-23 | 2005-07-14 | Basf Aktiengesellschaft | Verfahren zur herstellung von in 2,7-position substituierten xanthen-4,5-diolen |
| FR2887253A1 (fr) | 2005-06-20 | 2006-12-22 | Phosphoenix Sarl | Nouvelles arylphosphines p chirales ortho-fonctionnalisees et derives: leur preparation et utilisation en catalyse asymetrique |
| CN101332437A (zh) * | 2008-05-29 | 2008-12-31 | 上海焦化有限公司 | 一种丁烯氢甲酰化催化剂组合物及其应用 |
| BRPI0919349A2 (pt) * | 2008-09-22 | 2015-12-29 | Procter & Gamble | aldeídos ramificados específicos alcoóis, tensoativos e produtos á base dos mesmos destinados ao consumidor. |
| MX2011012757A (es) | 2009-06-05 | 2011-12-16 | Basf Se | Produccion biocatalitica de ambroxan. |
| WO2013156398A1 (de) | 2012-04-16 | 2013-10-24 | Basf Se | Verbessertes verfahren zur herstellung von (3e, 7e)-homofarnesol |
| US20130273619A1 (en) * | 2012-04-16 | 2013-10-17 | Basf Se | Process for the Preparation of (3E, 7E)-Homofarnesol |
| MX2015008354A (es) | 2013-01-23 | 2015-11-09 | Firmenich & Cie | Proceso para la preparacion de derivados de 4-metilpent-3-en-1-ol. |
| WO2015014644A1 (en) | 2013-07-31 | 2015-02-05 | Basf Se | Process for the bioconversion of c3-c13 alkanes to c3-c 13 primary alcohols |
| EP3027759A1 (en) | 2013-07-31 | 2016-06-08 | Basf Se | Process for the bioconversion of butane to 1-butanol |
| JP2017502944A (ja) | 2013-12-11 | 2017-01-26 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | シクロドデカトリエンおよび活性触媒系を含有する反応混合物(rg)の後処理法 |
| EP3094614B1 (de) | 2014-01-17 | 2018-05-02 | Basf Se | Verfahren zur herstellung von arylpropenen |
| EP2915797A1 (de) | 2014-03-07 | 2015-09-09 | Basf Se | Verfahren zur Herstellung von Menthonen aus Isopulegol in der Gasphase |
| ES2925686T3 (es) | 2014-04-14 | 2022-10-19 | Basf Se | Preparación de 4-hidroxi-4-metil-tetrahidropiranos sustituidos en la posición 2 a partir de materiales de partida que contienen 2-alquil-4,4-dimetil-1,3-dioxano |
| EP2865676A1 (de) | 2014-04-14 | 2015-04-29 | Basf Se | Herstellung von 2-substituierten 4-Methyl-tetrahydropyranen aus 2-Alkyl-4,4-dimethyl-1,3-dioxan-haltigen Ausgangsstoffen |
| EP3137445B1 (de) | 2014-04-30 | 2019-10-02 | Basf Se | Verfahren zur herstellung von farnesylaceton |
| EP2963121A1 (en) | 2014-07-03 | 2016-01-06 | Basf Se | Redox self-sufficient biocatalytic amination of alcohols |
| KR102507217B1 (ko) | 2014-07-24 | 2023-03-07 | 바스프 에스이 | 무기 박막의 제조 방법 |
| KR102429077B1 (ko) | 2014-08-04 | 2022-08-04 | 바스프 에스이 | 무기 박막의 제조 방법 |
| US10017464B2 (en) | 2014-08-12 | 2018-07-10 | Basf Se | Process for preparing cyclic alpha-keto alcohols from cyclic alpha-keto enols |
| JP6776224B2 (ja) | 2014-08-12 | 2020-10-28 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | アスタシンからアスタキサンチンを製造する方法 |
| MX2017003131A (es) | 2014-09-09 | 2017-06-14 | Basf Se | Metodo para la preparacion de 2-alcoxi ciclohexanol. |
| JP2017532306A (ja) | 2014-09-09 | 2017-11-02 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 香気物質の生成方法 |
| RU2017112051A (ru) | 2014-09-11 | 2018-10-11 | Басф Се | Способ получения сложных эфиров астаксантина |
| PL3197987T3 (pl) | 2014-09-26 | 2019-07-31 | Basf Se | Zastosowanie izomerycznie czystego lub izomerycznie wysoce wzbogaconego octanu cis- lub trans- 2-izobutylo-4-metylotetrahydropiran-4-ylu |
| US10179923B2 (en) | 2014-09-29 | 2019-01-15 | Basf Se | Method for biocatalytically cyclizing geranyllinalool and cyclization products thereby obtained |
| JP6689831B2 (ja) | 2014-10-02 | 2020-04-28 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | アスタキサンチン及びカンタキサンチンの精製方法 |
| CN107001201A (zh) | 2014-11-18 | 2017-08-01 | 巴斯夫欧洲公司 | 制备1‑(2,6,6‑三甲基环己基)‑链烷‑3‑醇的方法 |
| US20160194272A1 (en) | 2014-12-12 | 2016-07-07 | Basf Se | Process for the etherification of amino alcohols |
| US20160176803A1 (en) | 2014-12-18 | 2016-06-23 | Basf Se | Process for the etherification of amino alcohols at low temperatures |
| EP3233780B1 (en) | 2014-12-19 | 2018-08-01 | Basf Se | 1-(7,10,10-trimethyl-4-bicyclo(6.2.0)decanyl)ethanone as novel aroma chemical |
| US20160194273A1 (en) | 2015-01-06 | 2016-07-07 | Basf Se | Process for the etherification of amino alcohols with metal alcoholates |
| EP3251120A1 (de) | 2015-01-26 | 2017-12-06 | Basf Se | Entfernung von radionukliden aus mischungen |
-
2016
- 2016-07-08 PL PL16736463T patent/PL3319951T3/pl unknown
- 2016-07-08 WO PCT/EP2016/066225 patent/WO2017009205A1/de not_active Ceased
- 2016-07-08 MX MX2018000413A patent/MX2018000413A/es unknown
- 2016-07-08 US US15/743,153 patent/US10315975B2/en active Active
- 2016-07-08 EP EP16736463.7A patent/EP3319951B1/de active Active
- 2016-07-08 BR BR112018000481-2A patent/BR112018000481B1/pt active IP Right Grant
- 2016-07-08 JP JP2018500639A patent/JP6852046B2/ja active Active
- 2016-07-08 CN CN201680040498.1A patent/CN108026062B/zh active Active
- 2016-07-08 ES ES16736463T patent/ES2899823T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| BR112018000481A2 (pt) | 2018-09-18 |
| CN108026062B (zh) | 2022-04-12 |
| CN108026062A (zh) | 2018-05-11 |
| WO2017009205A1 (de) | 2017-01-19 |
| PL3319951T3 (pl) | 2022-02-28 |
| JP2018528930A (ja) | 2018-10-04 |
| EP3319951A1 (de) | 2018-05-16 |
| BR112018000481B1 (pt) | 2022-01-11 |
| US10315975B2 (en) | 2019-06-11 |
| US20180273458A1 (en) | 2018-09-27 |
| ES2899823T3 (es) | 2022-03-14 |
| JP6852046B2 (ja) | 2021-03-31 |
| EP3319951B1 (de) | 2021-09-08 |
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