MX2017015723A - Procedimiento para la preparacion de una composicion purificada de acido. - Google Patents
Procedimiento para la preparacion de una composicion purificada de acido.Info
- Publication number
- MX2017015723A MX2017015723A MX2017015723A MX2017015723A MX2017015723A MX 2017015723 A MX2017015723 A MX 2017015723A MX 2017015723 A MX2017015723 A MX 2017015723A MX 2017015723 A MX2017015723 A MX 2017015723A MX 2017015723 A MX2017015723 A MX 2017015723A
- Authority
- MX
- Mexico
- Prior art keywords
- fdca
- ffca
- esters
- solution
- oxidation product
- Prior art date
Links
- 239000002253 acid Substances 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 2
- CHTHALBTIRVDBM-UHFFFAOYSA-N furan-2,5-dicarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)O1 CHTHALBTIRVDBM-UHFFFAOYSA-N 0.000 abstract 22
- 150000002148 esters Chemical class 0.000 abstract 8
- 230000003647 oxidation Effects 0.000 abstract 5
- 238000007254 oxidation reaction Methods 0.000 abstract 5
- 239000000243 solution Substances 0.000 abstract 5
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- 230000003301 hydrolyzing effect Effects 0.000 abstract 2
- SHNRXUWGUKDPMA-UHFFFAOYSA-N 5-formyl-2-furoic acid Chemical compound OC(=O)C1=CC=C(C=O)O1 SHNRXUWGUKDPMA-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000002425 crystallisation Methods 0.000 abstract 1
- 230000008025 crystallization Effects 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 239000002798 polar solvent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/75—Cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B31/00—Reduction in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B33/00—Oxidation in general
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B41/00—Formation or introduction of functional groups containing oxygen
- C07B41/02—Formation or introduction of functional groups containing oxygen of hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B63/00—Purification; Separation; Stabilisation; Use of additives
- C07B63/02—Purification; Separation; Stabilisation; Use of additives by treatment giving rise to a chemical modification
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00033—Continuous processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Furan Compounds (AREA)
Abstract
Se prepara una composición ácida purificada que comprende ácido 2,5-furanodicarboxílico en un procedimiento, que comprende (i) oxidar una materia prima que contiene 5-alcoximetilfurfural a un producto de oxidación que comprende ácido 2,5-furanodicarboxílico (FDCA) y ácido 2-formil-furan-5-carboxílico (FFCA), y ésteres de FDCA y, opcionalmente, ésteres de FFCA; (ii) opcionalmente, disolver al menos parte del producto de oxidación en un solvente polar para obtener una solución del producto de oxidación, que comprende FDCA, FFCA y ésteres de FDCA y, opcionalmente, ésteres de FFCA; (iii) hidrolizar la al menos parte del producto de oxidación en presencia de agua, hidrolizando de este modo al menos ésteres de FDCA y, opcionalmente, ésteres de FFCA para obtener una solución acuosa de una composición ácida que comprende FDCA, FFCA y éster de FDCA en una cantidad por debajo de la cantidad de éster de FDCA en la solución del producto de oxidación; (iv) poner en contacto al menos parte de la solución de la composición ácida obtenida en la etapa (iii) con hidrógeno en presencia de un catalizador de hidrogenación para hidrogenar FFCA a productos de hidrogenación, produciendo una solución hidrogenada; y (v) separar al menos una porción del FDCA de al menos parte de la solución hidrogenada mediante cristalización.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL2014923 | 2015-06-05 | ||
| PCT/NL2016/050405 WO2016195500A1 (en) | 2015-06-05 | 2016-06-06 | Process for the preparation of a purified acid composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2017015723A true MX2017015723A (es) | 2018-04-24 |
Family
ID=53502805
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017015720A MX2017015720A (es) | 2015-06-05 | 2016-06-06 | Procedimiento para la preparacion de una composicion purificada de acido. |
| MX2017015723A MX2017015723A (es) | 2015-06-05 | 2016-06-06 | Procedimiento para la preparacion de una composicion purificada de acido. |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017015720A MX2017015720A (es) | 2015-06-05 | 2016-06-06 | Procedimiento para la preparacion de una composicion purificada de acido. |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US10464913B2 (es) |
| EP (2) | EP3303311B1 (es) |
| JP (2) | JP6615230B2 (es) |
| KR (2) | KR102072002B1 (es) |
| CN (2) | CN107848999B (es) |
| AU (2) | AU2016271835B2 (es) |
| BR (2) | BR112017025910B1 (es) |
| CA (2) | CA2988392C (es) |
| ES (2) | ES2833165T3 (es) |
| MX (2) | MX2017015720A (es) |
| WO (2) | WO2016195499A1 (es) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112018014278B1 (pt) | 2016-01-13 | 2022-07-12 | Stora Enso Oyj | Processos para a preparação de ácido 2,5-furandicarboxílico e intermediários e derivados dos mesmos |
| JP2017190316A (ja) * | 2016-04-15 | 2017-10-19 | 三菱ケミカル株式会社 | ２，５−フランジカルボン酸の精製方法 |
| BR112020000611B1 (pt) * | 2017-07-12 | 2024-03-05 | Stora Enso Oyj | Produtos purificados de via de ácido 2,5-furanoodicarboxílico |
| EP3444354A1 (en) * | 2017-08-16 | 2019-02-20 | Basf Se | Process of separating 2,5-diformylfuran from an aqueous mixture by cooling |
| TWI650318B (zh) | 2017-10-30 | 2019-02-11 | 財團法人工業技術研究院 | 以結晶法純化２，５－呋喃二甲酸的粗產物之方法與聚酯之形成方法 |
| US11440895B2 (en) | 2018-06-25 | 2022-09-13 | Eastman Chemical Company | Oxidation process to produce 5-(alkoxycarbonyl)furan-2-carboxylic acids (ACFC) |
| US10941245B2 (en) | 2018-06-25 | 2021-03-09 | Eastman Chemical Company | Oxidation process to produce 5-(alkoxycarbonyl)furan-2-carboxylic acids (ACFC) |
| CN109293608B (zh) * | 2018-09-21 | 2023-06-16 | 中国科学技术大学 | 一种5-甲酰基糠酸的制备方法 |
| TWI697487B (zh) * | 2019-07-02 | 2020-07-01 | 遠東新世紀股份有限公司 | 粗製2,5-呋喃二甲酸的純化方法 |
| TWI697488B (zh) * | 2019-07-02 | 2020-07-01 | 遠東新世紀股份有限公司 | 粗製2,5-呋喃二甲酸的純化方法 |
| BR112022002858A2 (pt) | 2019-09-05 | 2022-05-17 | Eastman Chem Co | Processo para preparar um composto |
| MX2022007653A (es) | 2019-12-20 | 2022-07-19 | Furanix Technologies Bv | Tratamiento termico y con agua de acido 2,5-furandicarboxilico purificado. |
| ES2985772T3 (es) | 2019-12-20 | 2024-11-07 | Furanix Technologies Bv | Tratamiento térmico de ácido 2,5-furandicarboxílico purificado y composición de ácido carboxílico resultante |
| JP7675081B2 (ja) * | 2019-12-20 | 2025-05-12 | フラニックス・テクノロジーズ・ベーフェー | ５－ヒドロキシメチルフルフラールのエーテルから２，５－フランジカルボン酸を製造するプロセス |
| BR112023024159A2 (pt) * | 2021-05-20 | 2024-01-30 | Eastman Chem Co | Processo de purga para ácido 5-(alcoxicarbonil)furan-2-carboxílico (acfc) |
| US20240360093A1 (en) * | 2021-05-20 | 2024-10-31 | Eastman Chemical Company | Purge process for 5-(methoxycarbonyl)furan-2-carboxylic acid (mcfc) |
| US20240317698A1 (en) * | 2021-05-20 | 2024-09-26 | Eastman Chemical Company | Mother liquor composition generated in mcfc process |
| CN115028610B (zh) * | 2022-05-07 | 2024-03-05 | 浙江恒逸石化研究院有限公司 | 一种2,5-呋喃二甲酸的纯化方法 |
| WO2023242152A1 (en) | 2022-06-14 | 2023-12-21 | Furanix Technologies B.V. | Producing 2,5-furandicarboxylic acid from mixed feed |
| EP4540233A1 (en) | 2022-06-14 | 2025-04-23 | Furanix Technologies B.V. | Producing 2,5-furandicarboxylic acid with recovery of acid |
| EP4540235A1 (en) | 2022-06-14 | 2025-04-23 | Furanix Technologies B.V. | Producing 2,5-furandicarboxylic acid in the presence of modifying acid |
| CN119948018A (zh) | 2022-09-23 | 2025-05-06 | 福兰尼克斯科技公司 | 呋喃衍生物的氧化 |
| CN115894411A (zh) * | 2022-12-29 | 2023-04-04 | 厦门大学 | 低沸点溶液在2,5-呋喃二甲酸纯化中的应用及其纯化方法 |
| CN118772090A (zh) * | 2023-03-31 | 2024-10-15 | 中国石油化工股份有限公司 | 2,5-呋喃二甲酸的提纯方法 |
| CN119552139A (zh) * | 2023-08-28 | 2025-03-04 | 中国石油化工股份有限公司 | 2,5-呋喃二甲酸的提纯方法 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2893860B2 (ja) * | 1990-05-17 | 1999-05-24 | 三菱瓦斯化学株式会社 | 高純度イソフタル酸の製造法 |
| JPH05190908A (ja) | 1992-01-13 | 1993-07-30 | Nec Corp | 光電変換装置 |
| DE4334100C2 (de) | 1992-10-13 | 2003-02-13 | Mitsubishi Chem Corp | Verfahren zur Herstellung hochreiner Terephthalsäure |
| JPH09151162A (ja) | 1995-11-30 | 1997-06-10 | Sekiyu Sangyo Kasseika Center | ナフタレンジカルボン酸の精製法 |
| US6265608B1 (en) | 1998-06-30 | 2001-07-24 | Eastman Chemical Company | Method of purifying aromatic dicarboxylic acids |
| US6455742B1 (en) | 1999-09-02 | 2002-09-24 | Wisconsin Alumni Research Foundation | Method for catalytically reducing carboxylic acid groups to hydroxyl groups in hydroxycarboxylic acids |
| DE602004003722T2 (de) | 2004-12-15 | 2007-10-04 | Saudi Basic Industries Corp. | Verfahren zur Herstellung gereinigter Terephtalsäure |
| CN104744414B (zh) | 2009-05-14 | 2017-04-12 | 阿彻丹尼尔斯米德兰德公司 | 糠醛化合物的氧化 |
| WO2011043661A1 (en) | 2009-10-07 | 2011-04-14 | Furanix Technologies B.V. | Method for the preparation of 2,5-furandicarboxylic acid and for the preparation of the dialkyl ester of 2,5-furandicarboxylic acid |
| CA2773640C (en) | 2009-10-07 | 2019-09-10 | Furanix Technologies B.V. | Method for the preparation of 2,5-furandicarboxylic acid and esters thereof |
| US20120302773A1 (en) * | 2011-05-24 | 2012-11-29 | Eastman Chemical Company | Oxidation process to produce a crude and/or purified carboxylic acid product |
| US8969404B2 (en) * | 2012-06-22 | 2015-03-03 | Eastman Chemical Company | Purifying crude furan 2,5-dicarboxylic acid by hydrogenation |
| US8748479B2 (en) | 2012-06-22 | 2014-06-10 | Eastman Chemical Company | Process for purifying crude furan 2,5-dicarboxylic acid using hydrogenation |
| US9006470B2 (en) | 2012-11-08 | 2015-04-14 | Eastman Chemical Company | Method of synthesizing low color furan diesters |
| US9156805B2 (en) * | 2012-11-20 | 2015-10-13 | Eastman Chemical Company | Oxidative purification method for producing purified dry furan-2,5-dicarboxylic acid |
| NL2010572C2 (en) | 2013-04-05 | 2014-10-07 | Furanix Technologies Bv | Process for the preaparation of 2,5-furan-dicarboxylic acid. |
| WO2015030590A1 (en) * | 2013-08-30 | 2015-03-05 | Furanix Technologies B.V. | Process for purifying an acid composition comprising 2-formyl-furan-5-carboxylic acid and 2,5-furandicarboxylic acid |
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2016
- 2016-06-06 US US15/579,256 patent/US10464913B2/en active Active
- 2016-06-06 JP JP2017563081A patent/JP6615230B2/ja active Active
- 2016-06-06 MX MX2017015720A patent/MX2017015720A/es unknown
- 2016-06-06 JP JP2017563100A patent/JP6615231B2/ja active Active
- 2016-06-06 WO PCT/NL2016/050404 patent/WO2016195499A1/en not_active Ceased
- 2016-06-06 MX MX2017015723A patent/MX2017015723A/es unknown
- 2016-06-06 WO PCT/NL2016/050405 patent/WO2016195500A1/en not_active Ceased
- 2016-06-06 CN CN201680045984.2A patent/CN107848999B/zh active Active
- 2016-06-06 CA CA2988392A patent/CA2988392C/en active Active
- 2016-06-06 ES ES16742030T patent/ES2833165T3/es active Active
- 2016-06-06 AU AU2016271835A patent/AU2016271835B2/en not_active Ceased
- 2016-06-06 CN CN201680045976.8A patent/CN107848998B/zh active Active
- 2016-06-06 BR BR112017025910-9A patent/BR112017025910B1/pt active IP Right Grant
- 2016-06-06 CA CA2988307A patent/CA2988307C/en active Active
- 2016-06-06 KR KR1020187000145A patent/KR102072002B1/ko active Active
- 2016-06-06 US US15/579,257 patent/US10351544B2/en active Active
- 2016-06-06 AU AU2016271834A patent/AU2016271834B2/en not_active Ceased
- 2016-06-06 ES ES16742029T patent/ES2833164T3/es active Active
- 2016-06-06 KR KR1020187000228A patent/KR102067718B1/ko active Active
- 2016-06-06 EP EP16742030.6A patent/EP3303311B1/en active Active
- 2016-06-06 EP EP16742029.8A patent/EP3303310B1/en active Active
- 2016-06-06 BR BR112017025913-3A patent/BR112017025913B1/pt active IP Right Grant
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