MX2017004000A - Proceso de deshidrogenacion oxidativa (odh) de alta conversion y selectividad. - Google Patents
Proceso de deshidrogenacion oxidativa (odh) de alta conversion y selectividad.Info
- Publication number
- MX2017004000A MX2017004000A MX2017004000A MX2017004000A MX2017004000A MX 2017004000 A MX2017004000 A MX 2017004000A MX 2017004000 A MX2017004000 A MX 2017004000A MX 2017004000 A MX2017004000 A MX 2017004000A MX 2017004000 A MX2017004000 A MX 2017004000A
- Authority
- MX
- Mexico
- Prior art keywords
- selectivity
- high conversion
- odh process
- reactor
- cfb
- Prior art date
Links
- 238000006243 chemical reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/28—Regeneration or reactivation
- B01J27/30—Regeneration or reactivation of catalysts comprising compounds of sulfur, selenium or tellurium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
- B01J38/12—Treating with free oxygen-containing gas
- B01J38/30—Treating with free oxygen-containing gas in gaseous suspension, e.g. fluidised bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1818—Feeding of the fluidising gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
- B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
- B01J8/224—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement
- B01J8/228—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid the particles being subject to a circulatory movement externally, i.e. the particles leaving the vessel and subsequently re-entering it
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
- B01J8/38—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it
- B01J8/384—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only
- B01J8/388—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique with fluidised bed containing a rotatable device or being subject to rotation or to a circulatory movement, i.e. leaving a vessel and subsequently re-entering it being subject to a circulatory movement only externally, i.e. the particles leaving the vessel and subsequently re-entering it
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/04—Ethylene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
- C07C11/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/42—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor
- C07C5/48—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with a hydrogen acceptor with oxygen as an acceptor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/20—Vanadium, niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/20—Vanadium, niobium or tantalum
- C07C2523/22—Vanadium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
El etano puede ser catalíticamente oxidativamente deshidrogenado a etileno con altas conversiones y alta selectividad en un reactor de lecho fluidizado en circulación (CFB) en presencia de oxígeno en la alimentación en una cantidad por arriba de límite de flamabilidad. El reactor tiene un reactor de regeneración acoplado para regenerar el catalizador y reciclarlo nuevamente hacia el CFB.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2867731A CA2867731C (en) | 2014-10-15 | 2014-10-15 | High conversion and selectivity odh process |
| PCT/IB2015/057711 WO2016059518A1 (en) | 2014-10-15 | 2015-10-08 | High conversion and selectivity odh process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MX2017004000A true MX2017004000A (es) | 2017-07-07 |
| MX383730B MX383730B (es) | 2025-03-14 |
Family
ID=54364404
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2017004000A MX383730B (es) | 2014-10-15 | 2015-10-08 | Proceso de deshidrogenación oxidativa (odh) de alta conversión y selectividad. |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US10626066B2 (es) |
| EP (1) | EP3206783B1 (es) |
| JP (1) | JP6721580B2 (es) |
| KR (1) | KR102467896B1 (es) |
| CN (1) | CN107108404A (es) |
| BR (1) | BR112017006648B1 (es) |
| CA (1) | CA2867731C (es) |
| ES (1) | ES2843691T3 (es) |
| MX (1) | MX383730B (es) |
| TW (1) | TW201628713A (es) |
| WO (1) | WO2016059518A1 (es) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018085614A1 (en) * | 2016-11-03 | 2018-05-11 | Battelle Energy Alliance, Llc | Oxidative dehydrogenation of alkanes to alkenes, and related system |
| US10450242B2 (en) * | 2016-12-20 | 2019-10-22 | Exxonmobil Research And Engineering Company | Upgrading ethane-containing light paraffins streams |
| CN109499486B (zh) * | 2017-09-14 | 2022-05-17 | 中国石油大学(华东) | 一种烷烃催化脱氢或催化裂解制烯烃循环流化床反应装置 |
| CA2965062A1 (en) * | 2017-04-25 | 2018-10-25 | Nova Chemicals Corporation | Complex comprising odh unit with integrated oxygen separation module |
| US10662130B2 (en) * | 2017-08-15 | 2020-05-26 | Exxonmobil Research And Engineering Company | Process for generation of olefins |
| CA3019803A1 (en) * | 2017-11-06 | 2019-05-06 | Nova Chemicals Corporation | Controlling carbon dioxide output from an odh process |
| KR102312033B1 (ko) * | 2017-11-30 | 2021-10-13 | 롯데케미칼 주식회사 | 에탄의 산화탈수소화 반응용 촉매 시스템, 이의 제조방법 및 이를 이용한 에탄으로부터 에틸렌의 제조방법 |
| CN110511109A (zh) * | 2018-05-22 | 2019-11-29 | 中国科学院大连化学物理研究所 | 一种乙烷连续生产乙烯的方法和装置 |
| CA3008612A1 (en) * | 2018-06-18 | 2019-12-18 | Nova Chemicals Corporation | Removing and cleaning dehydrogenation catalysts |
| WO2020075086A1 (en) * | 2018-10-11 | 2020-04-16 | Nova Chemicals (International) S.A. | Oxygenate separation following dehydrogenation of a lower alkane |
| CA3036625C (en) | 2019-03-13 | 2025-12-30 | Nova Chemicals Corporation | Thermal decomposition in chemical looping combustion |
| ES2955289T3 (es) | 2019-03-18 | 2023-11-29 | Shanghai Supezet Eng Tech Co Ltd | Dispositivo de reacción de deshidrogenación catalítica de alcanos que comprende un distribuidor catalítico anular |
| CN113710633A (zh) * | 2019-03-21 | 2021-11-26 | 凯洛格·布朗及鲁特有限公司 | 用于催化链烷烃脱氢和催化剂回收的方法 |
| WO2020194228A1 (en) | 2019-03-26 | 2020-10-01 | Sabic Global Technologies B.V. | Method of reactivating catalyst |
| CN110124647B (zh) * | 2019-06-27 | 2022-05-17 | 大连理工大学 | 负载型非金属催化剂、制备方法及其应用 |
| CN110465245A (zh) * | 2019-09-11 | 2019-11-19 | 上海电气电站环保工程有限公司 | 沸腾床联合固定床反应器及其用途 |
| US12479811B2 (en) | 2020-03-09 | 2025-11-25 | Sabic Global Technologies, B.V. | Process for producing ethylene oxide from ethane by oxidative dehydrogenation and epoxidation with low ethane concentration in oxidative dehydrogenation effluent |
| WO2023009031A1 (ru) * | 2021-07-26 | 2023-02-02 | Акционерное общество "Специальное конструкторско-технологическое бюро "Катализатор" | Регенератор системы дегидирования парафиновых углеводородов с3-с5 (варианты) |
| CN113477191B (zh) * | 2021-08-09 | 2022-03-08 | 中国石油大学(北京) | 一种甲烷氧化偶联制乙烯的反应装置和方法 |
| CN116272306B (zh) * | 2021-12-20 | 2024-08-16 | 中国石油化工股份有限公司 | 脱除环氧氯丙烷尾气中氧气的方法 |
| CN115745918B (zh) * | 2022-09-19 | 2023-12-22 | 中国科学院大连化学物理研究所 | 一种利用液固循环流化床反应-再生系统的hppo法生产环氧丙烷工艺 |
| CN119951422B (zh) * | 2025-04-09 | 2025-06-20 | 苏州大学 | 一种多级流化循环反应系统的加热控制方法 |
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-
2014
- 2014-10-15 CA CA2867731A patent/CA2867731C/en active Active
-
2015
- 2015-10-01 TW TW104132433A patent/TW201628713A/zh unknown
- 2015-10-08 BR BR112017006648-3A patent/BR112017006648B1/pt active IP Right Grant
- 2015-10-08 CN CN201580055681.4A patent/CN107108404A/zh active Pending
- 2015-10-08 WO PCT/IB2015/057711 patent/WO2016059518A1/en not_active Ceased
- 2015-10-08 JP JP2017519829A patent/JP6721580B2/ja active Active
- 2015-10-08 EP EP15787679.8A patent/EP3206783B1/en active Active
- 2015-10-08 ES ES15787679T patent/ES2843691T3/es active Active
- 2015-10-08 US US15/514,841 patent/US10626066B2/en active Active
- 2015-10-08 MX MX2017004000A patent/MX383730B/es unknown
- 2015-10-08 KR KR1020177010280A patent/KR102467896B1/ko active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN107108404A (zh) | 2017-08-29 |
| BR112017006648B1 (pt) | 2021-06-08 |
| BR112017006648A2 (pt) | 2017-12-26 |
| KR20170070056A (ko) | 2017-06-21 |
| US20170210685A1 (en) | 2017-07-27 |
| CA2867731A1 (en) | 2016-04-15 |
| MX383730B (es) | 2025-03-14 |
| EP3206783A1 (en) | 2017-08-23 |
| EP3206783B1 (en) | 2020-12-02 |
| JP2017532335A (ja) | 2017-11-02 |
| TW201628713A (zh) | 2016-08-16 |
| JP6721580B2 (ja) | 2020-07-15 |
| WO2016059518A1 (en) | 2016-04-21 |
| US10626066B2 (en) | 2020-04-21 |
| ES2843691T3 (es) | 2021-07-20 |
| KR102467896B1 (ko) | 2022-11-16 |
| CA2867731C (en) | 2022-08-30 |
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