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MX2016010639A - Procedimiento para el mejoramiento de procesos de lixiviacion de cobre utilizando cloruro de sodio. - Google Patents

Procedimiento para el mejoramiento de procesos de lixiviacion de cobre utilizando cloruro de sodio.

Info

Publication number
MX2016010639A
MX2016010639A MX2016010639A MX2016010639A MX2016010639A MX 2016010639 A MX2016010639 A MX 2016010639A MX 2016010639 A MX2016010639 A MX 2016010639A MX 2016010639 A MX2016010639 A MX 2016010639A MX 2016010639 A MX2016010639 A MX 2016010639A
Authority
MX
Mexico
Prior art keywords
copper
leaching
calcium chloride
improvement
mineral
Prior art date
Application number
MX2016010639A
Other languages
English (en)
Inventor
Backit Gutiérrez Abraham
TAPIA CORTÉS Gustavo
Original Assignee
Antofagasta Minerals S A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Antofagasta Minerals S A filed Critical Antofagasta Minerals S A
Publication of MX2016010639A publication Critical patent/MX2016010639A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0065—Leaching or slurrying
    • C22B15/0067—Leaching or slurrying with acids or salts thereof
    • C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B1/00—Preliminary treatment of ores or scrap
    • C22B1/14—Agglomerating; Briquetting; Binding; Granulating
    • C22B1/16—Sintering; Agglomerating
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0002—Preliminary treatment
    • C22B15/0004—Preliminary treatment without modification of the copper constituent
    • C22B15/0008—Preliminary treatment without modification of the copper constituent by wet processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0084—Treating solutions
    • C22B15/0086—Treating solutions by physical methods
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0084—Treating solutions
    • C22B15/0089—Treating solutions by chemical methods
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/10—Hydrochloric acid, other halogenated acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B23/00—Obtaining nickel or cobalt
    • C22B23/04—Obtaining nickel or cobalt by wet processes
    • C22B23/0407—Leaching processes
    • C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

La invención divulga un procedimiento que permite disminuir significativamente los tiempos de lixiviación de minerales primarios y secundarios de cobre chancados con una granulometría entre 80% bajo 12mm a 80% bajo 3mm en que se utiliza para lixiviar minerales sulfurados de cobre conteniendo mineralización primaria y/o secundaria de cobre como Calcopirita, Bornita y Covelina, donde el procedimiento comprende: un primer proceso de aglomeración en que la solución de aglomeración es una mezcla de agua de mar, salina u otro tipo de agua con solución recirculada; un segundo proceso de curado en pila a continuación del proceso anterior de aglomeración en que la mezcla agua de mar, salina u otro tipo de agua, cloruro de calcio, ácido sulfúrico y solución recirculada es alimentada a temperaturas mayores 30oC y menores que 60oC; un tercer proceso de lixiviación en pilas que contiene solución recirculada a continuación del proceso anterior de curado en que la solución recirculada de riego de la pila entra a una temperatura mayor a 30°C y menor que 60oC; un cuarto proceso de lavado en pilas con solución de refino a continuación del proceso anterior de lixiviación en pilas en que la solución de refino de riego de la pila anteriormente tratada con solución recirculada y anteriormente calentada a temperaturas mayores que 30oC, después de pasar por el proceso de extracción por solvente también entra a la pila como solución de refino a una temperatura mayor a 30oC y menor que 60°C.
MX2016010639A 2016-05-18 2016-08-16 Procedimiento para el mejoramiento de procesos de lixiviacion de cobre utilizando cloruro de sodio. MX2016010639A (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CL2016001188A CL2016001188A1 (es) 2016-05-18 2016-05-18 Procedimiento para el mejoramiento de procesos de lixiviación de cobre utilizando cloruro de calcio

Publications (1)

Publication Number Publication Date
MX2016010639A true MX2016010639A (es) 2017-11-17

Family

ID=59776730

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016010639A MX2016010639A (es) 2016-05-18 2016-08-16 Procedimiento para el mejoramiento de procesos de lixiviacion de cobre utilizando cloruro de sodio.

Country Status (16)

Country Link
US (1) US10400308B2 (es)
EP (1) EP3246420B1 (es)
AR (1) AR105704A1 (es)
AU (1) AU2016213865B2 (es)
BR (1) BR102016019114B1 (es)
CA (1) CA2938682C (es)
CL (1) CL2016001188A1 (es)
CY (1) CY1121644T1 (es)
DK (1) DK3246420T3 (es)
ES (1) ES2728154T3 (es)
MX (1) MX2016010639A (es)
PE (1) PE20171074A1 (es)
PL (1) PL3246420T3 (es)
PT (1) PT3246420T (es)
TR (1) TR201908101T4 (es)
ZA (1) ZA201605740B (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10961604B2 (en) 2015-04-17 2021-03-30 The University Of British Columbia Process for leaching metal sulfides with reagents having thiocarbonyl functional groups
JP2020522606A (ja) 2016-10-19 2020-07-30 ザ ユニバーシティ オブ ブリティッシュ コロンビアＴｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｂｒｉｔｉｓｈ Ｃｏｌｕｍｂｉａ チオカルボニル官能基を有する試薬による金属硫化物の浸出方法
MX2020006537A (es) 2017-12-21 2020-12-03 Bhp Chile Inc Equilibrio acido en una lixiviacion en pilas de cloruro.
US12116650B2 (en) * 2018-04-06 2024-10-15 Nova Mineralis S.A. Method for dissolving metallogenically primary copper metals obtained from ores and/or chalcopyrite concentrates that contain same
US12291761B2 (en) * 2018-11-14 2025-05-06 Nova Mineralis S.A. Solid-liquid-solid method for the solubilisation of copper minerals and concentrates, independent of the redox potential and with low consumption of water and acid
WO2022056621A1 (en) 2020-09-18 2022-03-24 The University Of British Columbia Extraction of base metals using carbonaceous matter and a thiocarbonyl functional group reagent
MX2023003207A (es) 2020-09-18 2023-04-27 Jetti Resources Llc Extracto de metales base con un agente humectante y un reactivo de grupo funcional de tiocarbonilo.
CL2021001250A1 (es) * 2021-05-12 2021-12-17 Corporacion Nac Del Cobre Chile Proceso de tratamiento secuencial para la lixiviación en pilas de sulfuros primarios y secundarios de cobre, tales como calcopirita, bornita, calcosina, covelina u otros minerales sulfuros y mixtos de cobre, en donde el proceso de lixiviación en todas sus etapas se realiza bajo concentraciones de ion cloro elevadas, [cl-] > 40 g/l, mejorando el rendimiento metalúrgico de este tratamiento secuencial.
CL2023002049A1 (es) * 2022-07-15 2024-02-23 Corporacion Nac Del Cobre De Chile Proceso de lixiviación de minerales en pila con calentamiento semi-autógeno

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6802888B2 (en) * 1998-12-14 2004-10-12 Geobiotics, Llc High temperature heap bioleaching process
CA2432743C (en) * 2002-11-26 2010-12-14 Minera Michilla S.A. Non-biochemical method to heap leach copper concentrates
CA2475833C (en) * 2004-01-29 2011-02-01 Minera Michilla S.A. Procedure to leach copper concentrates, under pressure and at ambient temperature, by forming a colloidal mass in a sulfate - chloride medium
EA014569B1 (ru) * 2006-05-12 2010-12-30 Би Эйч Пи Биллитон Са Лимитед Кучное выщелачивание с применением хлоридов
JP5319718B2 (ja) 2011-03-04 2013-10-16 Ｊｘ日鉱日石金属株式会社 硫化鉱からの銅及び金の浸出方法
EA026211B1 (ru) * 2012-08-22 2017-03-31 БиЭйчПи ЧИЛИ ИНК. Способ кучного выщелачивания
CN107208176B (zh) * 2014-12-17 2020-04-03 Bhp比利顿奥林匹克坝有限公司 堆浸方法

Also Published As

Publication number Publication date
TR201908101T4 (tr) 2019-06-21
AR105704A1 (es) 2017-11-01
AU2016213865B2 (en) 2022-12-01
ES2728154T3 (es) 2019-10-22
CA2938682C (en) 2021-06-08
DK3246420T3 (da) 2019-05-20
EP3246420B1 (en) 2019-03-06
BR102016019114A2 (pt) 2017-12-05
PL3246420T3 (pl) 2019-09-30
ZA201605740B (en) 2017-09-27
PT3246420T (pt) 2019-06-12
EP3246420A1 (en) 2017-11-22
AU2016213865A1 (en) 2017-12-07
CY1121644T1 (el) 2020-07-31
CA2938682A1 (en) 2017-11-19
CL2016001188A1 (es) 2017-02-24
US20170335428A1 (en) 2017-11-23
BR102016019114B1 (pt) 2021-09-28
PE20171074A1 (es) 2017-08-03
US10400308B2 (en) 2019-09-03

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