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MX2015014592A - Materiales de moldeo termoplastico a base de acrilonitrilo, butadieno y estireno. - Google Patents

Materiales de moldeo termoplastico a base de acrilonitrilo, butadieno y estireno.

Info

Publication number
MX2015014592A
MX2015014592A MX2015014592A MX2015014592A MX2015014592A MX 2015014592 A MX2015014592 A MX 2015014592A MX 2015014592 A MX2015014592 A MX 2015014592A MX 2015014592 A MX2015014592 A MX 2015014592A MX 2015014592 A MX2015014592 A MX 2015014592A
Authority
MX
Mexico
Prior art keywords
graft
molding materials
thermoplastic molding
butadiene
styrene
Prior art date
Application number
MX2015014592A
Other languages
English (en)
Other versions
MX382688B (es
Inventor
Norbert Niessner
Sangjun Ahn
Brian J Banaszak
Roland Walker
Michel Pepers
Johannes Barth
Gisbert Michels
Florian Patcas
Younghwa Hwang
Rudy Verstraeten
Original Assignee
Styrolution Group Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Styrolution Group Gmbh filed Critical Styrolution Group Gmbh
Publication of MX2015014592A publication Critical patent/MX2015014592A/es
Publication of MX382688B publication Critical patent/MX382688B/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • C08F2/24Emulsion polymerisation with the aid of emulsifying agents
    • C08F2/26Emulsion polymerisation with the aid of emulsifying agents anionic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/08Copolymers of styrene
    • C08L25/12Copolymers of styrene with unsaturated nitriles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18Homopolymers or copolymers of nitriles
    • C08L33/20Homopolymers or copolymers of acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La invención se refiere a materiales de moldeo termoplásticos a base de acrilonitrilo-butadieno-estireno, que comprende una matriz de polímero-SAN y un copolímero de injerto, estructurado a partir de una base de hule de injerto-aglomerada y una cubierta de injerto SAN. La base del sustrato de injerto es un hule diénico que tiene una proporción de vinilo aromático de 10.5 a 24.5% en peso. El sustrato de injerto aglomerado tiene una distribución de tamaño de partícula bimodal de una fracción x) de partículas no aglomeradas que tienen valor de d50 en el intervalo de 80 a 120 nm y una fracción y) de partículas aglomeradas que tienen un valor d50 en el intervalo de 350-550 nm y una polidispersidad U de menos de 0.28. La invención se refiere además a un proceso para producir el copolímero de injerto, en el que un copolímero de acrilato que tiene una polidispersidad U de menos de 0.27 y un valor de d50 de 100 a 150 nm se utiliza para la aglomeración. La invención se refiere además al uso de materiales de moldeo termoplásticos para la producción de partes moldeadas.
MX2015014592A 2013-04-18 2014-04-16 Materiales de moldeo termoplástico a base de acrilonitrilo, butadieno y estireno. MX382688B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13164275 2013-04-18
PCT/EP2014/057823 WO2014170406A1 (de) 2013-04-18 2014-04-16 Thermoplastische formmassen auf basis von acrylnitril, styrol und butadien

Publications (2)

Publication Number Publication Date
MX2015014592A true MX2015014592A (es) 2016-04-28
MX382688B MX382688B (es) 2025-03-13

Family

ID=48128185

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015014592A MX382688B (es) 2013-04-18 2014-04-16 Materiales de moldeo termoplástico a base de acrilonitrilo, butadieno y estireno.

Country Status (7)

Country Link
US (1) US9624333B2 (es)
EP (1) EP2986650B1 (es)
KR (1) KR102179358B1 (es)
CN (1) CN105164166B (es)
ES (1) ES2685809T3 (es)
MX (1) MX382688B (es)
WO (1) WO2014170406A1 (es)

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KR102511537B1 (ko) * 2018-12-17 2023-03-17 주식회사 엘지화학 비닐시안 화합물-공액디엔 화합물-방향족 비닐 화합물 그라프트 공중합체의 제조방법
KR102465134B1 (ko) * 2018-12-19 2022-11-10 주식회사 엘지화학 그라프트 공중합체의 제조방법
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KR102674487B1 (ko) * 2019-03-19 2024-06-13 주식회사 엘지화학 그라프트 공중합체의 제조방법
KR20220051210A (ko) 2019-08-21 2022-04-26 이네오스 스티롤루션 그룹 게엠베하 높은 escr, 높은 색상 및 열 안정성 및 낮은 박리 경향을 갖는 시트 압출 및 열성형을 위한 abs 성형 조성물
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CN115043995B (zh) * 2021-03-08 2023-06-30 中国石油天然气股份有限公司 一种乳液聚合法制备热塑性树脂的方法及制得的热塑性树脂
CN115043997B (zh) * 2021-03-08 2023-07-25 中国石油天然气股份有限公司 一种乳液聚合法制备含羧基热塑性弹性体的方法及制得的热塑性弹性体
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Also Published As

Publication number Publication date
ES2685809T3 (es) 2018-10-11
EP2986650B1 (de) 2018-08-08
KR20150144795A (ko) 2015-12-28
MX382688B (es) 2025-03-13
EP2986650A1 (de) 2016-02-24
CN105164166A (zh) 2015-12-16
US9624333B2 (en) 2017-04-18
WO2014170406A1 (de) 2014-10-23
CN105164166B (zh) 2017-12-22
US20160075813A1 (en) 2016-03-17
KR102179358B1 (ko) 2020-11-18

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