MX2014002263A - Proceso para la carbonilacion de alquenos opcionalmente funcionalizados. - Google Patents
Proceso para la carbonilacion de alquenos opcionalmente funcionalizados.Info
- Publication number
- MX2014002263A MX2014002263A MX2014002263A MX2014002263A MX2014002263A MX 2014002263 A MX2014002263 A MX 2014002263A MX 2014002263 A MX2014002263 A MX 2014002263A MX 2014002263 A MX2014002263 A MX 2014002263A MX 2014002263 A MX2014002263 A MX 2014002263A
- Authority
- MX
- Mexico
- Prior art keywords
- ester
- alkoxycarbonylation
- carbonylation product
- source
- carboxylic acid
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 150000001336 alkenes Chemical class 0.000 title abstract 3
- 238000007083 alkoxycarbonylation reaction Methods 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 abstract 5
- 230000006315 carbonylation Effects 0.000 abstract 3
- 238000005810 carbonylation reaction Methods 0.000 abstract 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/62—Use of additives, e.g. for stabilisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/003—Esters of saturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/34—Esters of acyclic saturated polycarboxylic acids having an esterified carboxyl group bound to an acyclic carbon atom
- C07C69/40—Succinic acid esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Esta invención se refiere a un proceso para la alcoxicarbonilación de alquenos funcionalizados con ácido carboxílico o sus ésteres, dicho proceso que comprende: (a) la reacción (i) de un alqueno funcionalizado con ácido carboxílico o uno de sus ésteres; (ii) de un sistema catalizador que comprende una fuente de Pd y un ligando, (iii) de una fuente de aniones derivada de un ácido con un pKa < 3, (iv) de monóxido de carbono, y (v) de un compuesto que comprende un grupo hidroxilo, en condiciones en las que se produce un producto de carbonilación de un éster, por lo que el proceso se lleva a cabo en presencia de un producto de carbonilación de ésteres. La presencia de los productos de carbonilación de ésteres produce la estabilización del sistema catalizador y previene la formación de negro de Pd.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161530141P | 2011-09-01 | 2011-09-01 | |
| EP11179766 | 2011-09-01 | ||
| PCT/EP2012/066970 WO2013030344A1 (en) | 2011-09-01 | 2012-08-31 | Process for the alkoxycarbonylation of functionalized alkenes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2014002263A true MX2014002263A (es) | 2014-04-25 |
Family
ID=47755372
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2014002263A MX2014002263A (es) | 2011-09-01 | 2012-08-31 | Proceso para la carbonilacion de alquenos opcionalmente funcionalizados. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US9056829B2 (es) |
| EP (1) | EP2750799B1 (es) |
| JP (1) | JP5895292B2 (es) |
| KR (1) | KR20140057287A (es) |
| CN (1) | CN103764284B (es) |
| BR (1) | BR112014004595A2 (es) |
| CA (1) | CA2845500A1 (es) |
| EA (1) | EA024174B1 (es) |
| ES (1) | ES2565814T3 (es) |
| MX (1) | MX2014002263A (es) |
| PL (1) | PL2750799T3 (es) |
| WO (1) | WO2013030344A1 (es) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018175332A1 (en) * | 2017-03-18 | 2018-09-27 | Qatar Foundation For Education, Science And Community Development | Metal-catalyzed alkoxycarbonylation of a lactone |
| EP3441383B1 (de) | 2017-08-08 | 2019-12-25 | Evonik Operations GmbH | Methoxycarbonylierung mit ameisensäure als co-quelle |
| US10710956B2 (en) | 2018-02-08 | 2020-07-14 | Regents Of The University Of Minnesota | Process for the preparation of acrylate esters from alkyl lactates |
| CN117142953A (zh) * | 2022-05-24 | 2023-12-01 | 上海浦景化工技术股份有限公司 | 一种丁二酸酯的制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5346913A (en) * | 1976-10-06 | 1978-04-27 | Ube Ind Ltd | Preparation of dicarboxylic acid diesters |
| KR880007426A (ko) * | 1986-12-24 | 1988-08-27 | 오노 알버어스 | 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법 |
| US5026901A (en) * | 1990-03-29 | 1991-06-25 | E. I. Du Pont De Nemours And Company | Palladium catalyzed carboalkoxylation of butadiene |
| US5618819A (en) * | 1994-07-07 | 1997-04-08 | Adir Et Compagnie | 1,3-dihydro-2H-pyrrolo[2,3-b]pyridin-2-one and oxazolo[4,5-b]pyridin-2-(3H)-one compounds |
| TW272949B (es) * | 1994-07-22 | 1996-03-21 | Taishal Kagaku Kogyo Kk | |
| JPH08299803A (ja) * | 1995-03-07 | 1996-11-19 | Daicel Chem Ind Ltd | カルボニル化触媒系およびそれを用いたカルボニル化方法 |
| GB9705699D0 (en) * | 1997-03-19 | 1997-05-07 | Ici Plc | Process for the carbonylation of ethylene |
| GB9918229D0 (en) * | 1999-08-04 | 1999-10-06 | Ici Plc | Improvements relating to metal-compound catalysed processes |
| US6706912B2 (en) * | 2000-03-14 | 2004-03-16 | Shell Oil Company | Process for the carbonylation of ethylenically unsaturated compounds |
| DE10060313A1 (de) * | 2000-12-04 | 2002-06-13 | Basf Ag | Verfahren zur Carbonylierung von Pentensäure und deren Derivate |
| WO2002048094A1 (en) * | 2000-12-11 | 2002-06-20 | E. I. Du Pont De Nemours And Company | tROCESS FOR MAKING 5-CYANOVALERIC ACID, ADIPIC ACID OR DIMETHYL ADIDPATE |
-
2012
- 2012-08-31 EP EP12756429.2A patent/EP2750799B1/en not_active Not-in-force
- 2012-08-31 CA CA 2845500 patent/CA2845500A1/en not_active Abandoned
- 2012-08-31 WO PCT/EP2012/066970 patent/WO2013030344A1/en not_active Ceased
- 2012-08-31 CN CN201280042667.7A patent/CN103764284B/zh not_active Expired - Fee Related
- 2012-08-31 US US14/240,816 patent/US9056829B2/en not_active Expired - Fee Related
- 2012-08-31 JP JP2014527675A patent/JP5895292B2/ja not_active Expired - Fee Related
- 2012-08-31 MX MX2014002263A patent/MX2014002263A/es not_active Application Discontinuation
- 2012-08-31 BR BR112014004595A patent/BR112014004595A2/pt not_active IP Right Cessation
- 2012-08-31 EA EA201400288A patent/EA024174B1/ru not_active IP Right Cessation
- 2012-08-31 KR KR20147004944A patent/KR20140057287A/ko not_active Withdrawn
- 2012-08-31 PL PL12756429T patent/PL2750799T3/pl unknown
- 2012-08-31 ES ES12756429.2T patent/ES2565814T3/es active Active
Also Published As
| Publication number | Publication date |
|---|---|
| BR112014004595A2 (pt) | 2017-03-21 |
| EA024174B1 (ru) | 2016-08-31 |
| US9056829B2 (en) | 2015-06-16 |
| ES2565814T3 (es) | 2016-04-07 |
| CA2845500A1 (en) | 2013-03-07 |
| EP2750799B1 (en) | 2016-01-06 |
| JP5895292B2 (ja) | 2016-03-30 |
| KR20140057287A (ko) | 2014-05-12 |
| US20140206893A1 (en) | 2014-07-24 |
| PL2750799T3 (pl) | 2016-06-30 |
| WO2013030344A1 (en) | 2013-03-07 |
| EA201400288A1 (ru) | 2014-06-30 |
| CN103764284A (zh) | 2014-04-30 |
| EP2750799A1 (en) | 2014-07-09 |
| CN103764284B (zh) | 2016-08-17 |
| JP2014527541A (ja) | 2014-10-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |