[go: up one dir, main page]

MX2013010134A - Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo. - Google Patents

Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo.

Info

Publication number
MX2013010134A
MX2013010134A MX2013010134A MX2013010134A MX2013010134A MX 2013010134 A MX2013010134 A MX 2013010134A MX 2013010134 A MX2013010134 A MX 2013010134A MX 2013010134 A MX2013010134 A MX 2013010134A MX 2013010134 A MX2013010134 A MX 2013010134A
Authority
MX
Mexico
Prior art keywords
styrene
preparation
methods
polymer
butadiene rubber
Prior art date
Application number
MX2013010134A
Other languages
English (en)
Other versions
MX341179B (es
Inventor
Silvia Valenti
Evemarie Hamann
Karin Schmiedel
Original Assignee
Styron Europe Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Styron Europe Gmbh filed Critical Styron Europe Gmbh
Publication of MX2013010134A publication Critical patent/MX2013010134A/es
Publication of MX341179B publication Critical patent/MX341179B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
    • C08F4/48—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from lithium, rubidium, caesium or francium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K11/00—Use of ingredients of unknown constitution, e.g. undefined reaction products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Un polímero tiene al menos las siguientes características: (a) un contenido de estireno en bloque que contiene 4 a 6 unidades de estireno de aproximadamente 27 a aproximadamente 50 por ciento en peso basado en el contenido de estireno total en el polímero; (b) un contenido de vinilo de aproximadamente 30 a aproximadamente 80 por ciento en peso basado en la cantidad total de 1,3-butadieno polimerizado; y (c) un contenido de estireno de aproximadamente 40 a aproximadamente 70 por ciento en peso basado en el peso total del polímero. Se describen procesos para la polimerización de un polímero de este tipo, composiciones que contienen dicho polímero, y artículos que contienen al menos un componente formado a partir de dicha composición.
MX2013010134A 2011-03-04 2012-03-01 Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo. MX341179B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11156987A EP2495266A1 (en) 2011-03-04 2011-03-04 High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof
PCT/EP2012/053524 WO2012119918A1 (en) 2011-03-04 2012-03-01 High styrene high vinyl styrene-butadiene rubber and methods for preparation thereof

Publications (2)

Publication Number Publication Date
MX2013010134A true MX2013010134A (es) 2014-03-26
MX341179B MX341179B (es) 2016-08-10

Family

ID=44147899

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013010134A MX341179B (es) 2011-03-04 2012-03-01 Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo.

Country Status (10)

Country Link
US (1) US8981000B2 (es)
EP (1) EP2495266A1 (es)
JP (1) JP6077470B2 (es)
KR (1) KR20140003584A (es)
CN (1) CN103443152B (es)
BR (1) BR112013022511A2 (es)
MX (1) MX341179B (es)
RU (1) RU2606129C2 (es)
SG (1) SG192912A1 (es)
WO (1) WO2012119918A1 (es)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PL2537872T3 (pl) * 2011-06-22 2015-11-30 Trinseo Europe Gmbh Kauczuk styrenowo-butadienowy wysokostyrenowy wysokowinylowy o wąskim rozkładzie masy cząsteczkowej oraz metody jego przygotowania
ES2653868T3 (es) 2012-12-21 2018-02-09 Borealis Ag Procatalizador de Ziegler Natta soportado para la polimerización de etileno
ES2615499T3 (es) 2012-12-21 2017-06-07 Borealis Ag Procedimiento para la producción de un procatalizador de Ziegler-Natta para la polimerización de etileno
ES2709631T3 (es) 2013-04-30 2019-04-17 Borealis Ag Catalizadores de Ziegler-Natta soportados modificados con donador
CN103672218A (zh) * 2013-12-23 2014-03-26 苏州市依星橡塑有限公司 一种新型橡胶管
TWI531605B (zh) * 2014-12-30 2016-05-01 奇美實業股份有限公司 共軛二烯－乙烯基芳香烴共聚物及橡膠組成物
RU2706012C1 (ru) * 2016-07-19 2019-11-13 Публичное Акционерное Общество "Сибур Холдинг" (Пао "Сибур Холдинг") Статистические сополимеры винилароматических соединений и сопряженных диенов и способ их получения
WO2018016986A1 (en) * 2016-07-22 2018-01-25 Public Joint Stock Company "Sibur Holding" A method of producing a rubber, a rubber composition comprising the rubber obtained by said method, and also use of the rubber composition
US11525049B2 (en) 2017-03-29 2022-12-13 Synthos S.A. Polar additive for the synthesis of copolymers of vinylaromatic monomer and conjugated diene monomer having high vinylaromatic and low vinyl contents
CN109485791B (zh) * 2017-09-13 2021-10-19 中国石油化工股份有限公司 线形丁苯共聚物及其制备方法和组合物以及芳族乙烯基树脂及其制备方法
CN109627382B (zh) * 2017-10-06 2022-03-18 台橡股份有限公司 共轭二烯聚合物及其组合物及制造方法
KR102154046B1 (ko) * 2017-10-26 2020-09-09 주식회사 엘지화학 연속식 중합에 의한 공액디엔계 중합체의 제조방법
US11591428B2 (en) * 2017-12-26 2023-02-28 Bridgestone Corporation Synthesis of low molecular weight tapered styrene-butadiene copolymer and its use in tires
CN120569418A (zh) 2023-03-20 2025-08-29 日本弹性体株式会社 共轭二烯系聚合物和共轭二烯系聚合物组合物

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3496154A (en) * 1965-10-15 1970-02-17 Phillips Petroleum Co Random copolymerization
JPS58142901A (ja) 1982-02-19 1983-08-25 Nippon Zeon Co Ltd ゴムの変性方法
JPS5936144A (ja) 1982-08-23 1984-02-28 Sumitomo Rubber Ind Ltd ジエン系ゴム組成物及び該組成物をトレツドに用いたタイヤ
US4616069A (en) 1984-10-26 1986-10-07 Nippon Zeon Co., Ltd. Process for making diene polymer rubbers
EP0299074B1 (en) 1987-01-14 1992-01-29 Bridgestone Corporation Tire
DE3724870A1 (de) * 1987-07-28 1989-02-09 Huels Chemische Werke Ag Verfahren zur herstellung von polymerisaten auf basis von konjugierten dienen und ggf. monovinylaromatischen verbindungen
CA1338317C (en) 1988-02-25 1996-05-07 Akio Imai Modified diene polymer rubbers
DE69119125T3 (de) 1990-03-02 2001-01-11 Bridgestone Corp., Tokio/Tokyo Luftreifen
US5066729A (en) 1990-04-09 1991-11-19 Bridgestone/Firestone, Inc. Diene polymers and copolymers terminated by reaction with n-alkyl and n-aryl imines
US5070150A (en) 1990-07-02 1991-12-03 The Goodyear Tire & Rubber Company Process for the solid state (solventless) hydroxylation of vinyl-containing rubbers using a hydroxymercaptan
US5227431A (en) 1991-04-12 1993-07-13 Bridgestone/Firestone, Inc. Diene polymers and copolymers jumped by partial crosslinking and terminated with a substituted imine
US5210145A (en) 1991-12-20 1993-05-11 Bridgestone/Firestone, Inc. Diene polymers and copolymers terminated by reaction with fused-ring polynuclear aromatic compounds
US5532327A (en) 1991-12-30 1996-07-02 Xerox Corporation Random copolymers made by anionic polymerization, toners incorporating these copolymers and method for the manufacture thereof
JP3319639B2 (ja) * 1992-12-24 2002-09-03 株式会社ブリヂストン 共役ジエン系重合体の製造方法、スチレン−ブタジエン系重合体及びそのゴム組成物
ES2119008T3 (es) 1993-04-30 1998-10-01 Bridgestone Corp Iniciadores de polimerizacion anionica y productos de histeresis reducida de los mismos.
FR2722503A1 (fr) 1994-07-15 1996-01-19 Michelin & Cie Polymeres dieniques fonctionnels, leur procede de preparation et leur utilisation dans des compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques
EP0798339B1 (en) * 1996-03-29 2002-06-05 Bridgestone Corporation Styrene-butadiene copolymer and rubber composition comprising the copolymer
US6274680B1 (en) 1998-12-31 2001-08-14 Bridgestone/Firestone Research, Inc. Sulfenyl halide polymerization terminators
ES2400176T3 (es) 2001-12-03 2013-04-08 Bridgestone Corporation Proceso para producir polímero modificado, polímero modificado obtenido mediante el proceso y composición de caucho
RU2377258C2 (ru) * 2008-01-09 2009-12-27 Открытое акционерное общество "Воронежский синтетический каучук" Способ получения полимеров бутадиена и сополимеров бутадиена со стиролом
HUE027362T2 (en) 2008-04-30 2016-09-28 Trinseo Europe Gmbh Styrene-grade styrene-butadiene polymers and their preparation method
CN102459447B (zh) * 2009-04-16 2014-07-02 株式会社普利司通 含硫醇的液态橡胶组合物
WO2011087841A1 (en) * 2009-12-22 2011-07-21 Bridgestone Corporation Improved vinyl modifier composition and processes for utilizing such composition
TW201211083A (en) * 2010-06-15 2012-03-16 Styron Europe Gmbh Low vinyl styrene-butadiene polymers and methods of making the same
PL2537872T3 (pl) * 2011-06-22 2015-11-30 Trinseo Europe Gmbh Kauczuk styrenowo-butadienowy wysokostyrenowy wysokowinylowy o wąskim rozkładzie masy cząsteczkowej oraz metody jego przygotowania

Also Published As

Publication number Publication date
CN103443152A (zh) 2013-12-11
JP2014506951A (ja) 2014-03-20
WO2012119918A1 (en) 2012-09-13
MX341179B (es) 2016-08-10
SG192912A1 (en) 2013-09-30
KR20140003584A (ko) 2014-01-09
RU2606129C2 (ru) 2017-01-10
EP2495266A1 (en) 2012-09-05
RU2013144577A (ru) 2015-04-10
US20140024767A1 (en) 2014-01-23
BR112013022511A2 (pt) 2016-12-06
JP6077470B2 (ja) 2017-02-08
CN103443152B (zh) 2016-01-13
US8981000B2 (en) 2015-03-17

Similar Documents

Publication Publication Date Title
MX2013010134A (es) Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para preparar el mismo.
MY165740A (en) A latex comprising water and a styrenic block copolymer and a process for preparing articles therefrom
RU2014138498A (ru) Резиновая композиция и шина
MY178756A (en) Block copolymer composition and adhesive composition
MY176208A (en) Block copolymer and adhesive composition
RU2014112226A (ru) Каучуковая композиция и шина
MY162805A (en) Polymer microparticle-dispersed resin composition and method for producing same
MY172470A (en) Rubber composition
MY182810A (en) Asphalt composition
JP2013241609A5 (es)
MY174182A (en) Polymer and asphalt composition
IN2015DN00696A (es)
MX2016003817A (es) Copolimeros elastomericos modificados por enlaces de bajo vinilo.
MX345632B (es) Caucho de estireno-butadieno de alto contenido de estireno y alto contenido de vinilo con distribucion estrecha del peso molecular y metodos para la preparacion de los mismos.
IN2014CN04040A (es)
MY169167A (en) Concentrated polymeric compositions of vinyl aromatic polymers and/or vinyl aromatic copolymers
CA2862782A1 (en) Toughness modifier for curable resin, and curable resin composition
PH12015500120A1 (en) Composition for foam tire
MY164463A (en) Process for the preparation of 1,3-butadiene and styrene copolymers and use thereof in vulcanizable elastomeric compositions
WO2012115846A3 (en) Methods of improving the physical properties of polyolefin films
MX344267B (es) Caucho de estireno-butadieno de alto contenido de estireno alto contenido de vinilo y metodos para la preparacion del mismo.
MX2017010238A (es) Composicion de copolimero de bloques, material moldeado, composicion de resina y producto moldeado.
MX345472B (es) Caucho estireno-butadieno de alto contenido de estireno y alto contenido de vinilo con distribucion estrecha del peso molecular y metodos para la preparacion de los mismos.
MY170891A (en) Process for the preparation of branched polybutadiene having a high content of 1, 4-cis units
MY180377A (en) Rubber composition and styrene resin composition using the same

Legal Events

Date Code Title Description
FG Grant or registration