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MX2010002085A - Activaciones de catalizador de aluminoxano derivados de agentes precursores de cation dialquilaluminio, procesos para su elaboracion, y su uso en catalizadores y polimerizacion de olefinas. - Google Patents

Activaciones de catalizador de aluminoxano derivados de agentes precursores de cation dialquilaluminio, procesos para su elaboracion, y su uso en catalizadores y polimerizacion de olefinas.

Info

Publication number
MX2010002085A
MX2010002085A MX2010002085A MX2010002085A MX2010002085A MX 2010002085 A MX2010002085 A MX 2010002085A MX 2010002085 A MX2010002085 A MX 2010002085A MX 2010002085 A MX2010002085 A MX 2010002085A MX 2010002085 A MX2010002085 A MX 2010002085A
Authority
MX
Mexico
Prior art keywords
radical
making same
catalysts
polymerization
olefins
Prior art date
Application number
MX2010002085A
Other languages
English (en)
Inventor
Lubin Luo
Samuel A Sangokoya
Xiao Wu
Steven P Diefenbach
Brian Kneale
Original Assignee
Albemarle Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=40097470&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX2010002085(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Albemarle Corp filed Critical Albemarle Corp
Publication of MX2010002085A publication Critical patent/MX2010002085A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1608—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes the ligands containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

Composiciones útiles para activar catalizadores para la polimerización de olefina, y métodos para su elaboración, se proveen; las composiciones se pueden derivar de al menos: a) una composición intermedia derivada de al menos un compuesto organoaluminio, un portador, y una fuente de oxígeno; y b) R22AlY, en donde cada R2 comprende independientemente un grupo hidrocarbilo que tiene de 1 a 20 carbonos, e Y comprende un radical haluro, un radical pseudo haluro, un radical alcóxido, un radical arilóxido, un radical amida sustituido con alquilo, un radical amida sustituido arilo, un radical siloxi, un radical boronoxi, un radical boronoxi diarilo, o un radical boronoxi diarilo halogenado.
MX2010002085A 2007-08-29 2008-08-29 Activaciones de catalizador de aluminoxano derivados de agentes precursores de cation dialquilaluminio, procesos para su elaboracion, y su uso en catalizadores y polimerizacion de olefinas. MX2010002085A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US96881007P 2007-08-29 2007-08-29
PCT/US2008/074880 WO2009029857A1 (en) 2007-08-29 2008-08-29 Aluminoxane catalyst activators derived from dialkylaluminum cation precursor agents, processes for making same, and use thereof in catalysts and polymerization of olefins

Publications (1)

Publication Number Publication Date
MX2010002085A true MX2010002085A (es) 2010-03-26

Family

ID=40097470

Family Applications (2)

Application Number Title Priority Date Filing Date
MX2010002085A MX2010002085A (es) 2007-08-29 2008-08-29 Activaciones de catalizador de aluminoxano derivados de agentes precursores de cation dialquilaluminio, procesos para su elaboracion, y su uso en catalizadores y polimerizacion de olefinas.
MX2013009779A MX347382B (es) 2007-08-29 2010-02-23 Activadores de catalizador de aluminoxano derivados de agentes precursores de cation dialquilaluminio, procesos para su elaboracion, y su uso en catalizadores y polimerizacion de olefinas.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2013009779A MX347382B (es) 2007-08-29 2010-02-23 Activadores de catalizador de aluminoxano derivados de agentes precursores de cation dialquilaluminio, procesos para su elaboracion, y su uso en catalizadores y polimerizacion de olefinas.

Country Status (10)

Country Link
US (2) US8354485B2 (es)
EP (1) EP2195112B1 (es)
JP (2) JP5695419B2 (es)
KR (1) KR101529340B1 (es)
CN (2) CN101821004A (es)
BR (1) BRPI0815807B1 (es)
CA (1) CA2696926C (es)
ES (1) ES2627289T3 (es)
MX (2) MX2010002085A (es)
WO (1) WO2009029857A1 (es)

Families Citing this family (72)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101821004A (zh) * 2007-08-29 2010-09-01 雅宝公司 由二烷基铝阳离子前体试剂得到的铝氧烷催化剂活化剂、用于制备其的方法以及其在催化剂和烯烃聚合中的用途
US8507103B2 (en) 2007-12-18 2013-08-13 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8436114B2 (en) 2010-10-21 2013-05-07 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
US8431661B2 (en) 2010-10-21 2013-04-30 Exxonmobil Chemical Patents Inc. Polyethylene and process for production thereof
EP2623522B1 (en) * 2010-09-29 2018-08-29 LG Chem, Ltd. Preparation method of hybrid supported metallocene catalyst
KR101972725B1 (ko) 2010-11-22 2019-04-25 더블유.알. 그레이스 앤드 캄파니-콘. 활성화제 조성물, 그의 제법 및 촉매 작용에서의 그의 용도
TWI555574B (zh) 2011-03-09 2016-11-01 亞比馬利股份有限公司 含有碳陽離子劑之鋁氧烷催化活性劑及其於聚烯烴催化劑中之用途
ES2805782T3 (es) 2012-04-27 2021-02-15 Grace W R & Co Composiciones de activador, su preparación y su uso en catalizadores
FR3015400B1 (fr) * 2013-12-20 2016-01-22 Valeo Systemes Dessuyage Connecteurs pour un balai d'essuie-glace de vehicule
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
EP3274380B1 (en) 2015-04-20 2020-08-19 ExxonMobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
CN114685703A (zh) 2015-04-20 2022-07-01 埃克森美孚化学专利公司 包含氟化物化的载体的催化剂组合物及其使用方法
WO2016172099A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Polyethylene composition
US10280233B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst systems and methods of making and using the same
US9920176B2 (en) 2015-06-05 2018-03-20 Exxonmobil Chemical Patents Inc. Single site catalyst supportation
US9809664B2 (en) 2015-06-05 2017-11-07 Exxonmobil Chemical Patents Inc. Bimodal propylene polymers and sequential polymerization
US10077325B2 (en) 2015-06-05 2018-09-18 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
WO2016197037A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
US10294316B2 (en) 2015-06-05 2019-05-21 Exxonmobil Chemical Patents Inc. Silica supports with high aluminoxane loading capability
US10329360B2 (en) 2015-06-05 2019-06-25 Exxonmobil Chemical Patents Inc. Catalyst system comprising supported alumoxane and unsupported alumoxane particles
EP3303423A1 (en) 2015-06-05 2018-04-11 ExxonMobil Chemical Patents Inc. Single reactor production of polymers in gas or slurry phase
US9738779B2 (en) 2015-06-05 2017-08-22 Exxonmobil Chemical Patents Inc. Heterophasic copolymers and sequential polymerization
US9725569B2 (en) 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. Porous propylene polymers
US10280235B2 (en) 2015-06-05 2019-05-07 Exxonmobil Chemical Patents Inc. Catalyst system containing high surface area supports and sequential polymerization to produce heterophasic polymers
US9725537B2 (en) 2015-06-05 2017-08-08 Exxonmobil Chemical Patents Inc. High activity catalyst supportation
WO2016196331A1 (en) 2015-06-05 2016-12-08 Exxonmobil Chemical Patents Inc. Supported metallocene catalyst systems for polymerization
CN107922537B (zh) 2015-06-05 2021-07-27 埃克森美孚化学专利公司 气相或淤浆相中多相聚合物的制备
EP3344665A4 (en) 2015-08-31 2019-08-14 ExxonMobil Chemical Patents Inc. ALUMINUM ALKYLE WITH HANGING OLEFINS FOR POLYOLEFINREACTIONS
US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
WO2017039994A1 (en) 2015-08-31 2017-03-09 Exxonmobil Chemical Patents Inc. Aluminum alkyls with pendant olefins on clays
US9982067B2 (en) 2015-09-24 2018-05-29 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
US9994657B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US10414887B2 (en) 2015-10-02 2019-09-17 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
US10000593B2 (en) 2015-10-02 2018-06-19 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
US9994658B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
US9975973B2 (en) 2015-10-02 2018-05-22 Exxonmobil Chemical Patents Inc. Asymmetric fluorenyl-substituted salan catalysts
US9982076B2 (en) 2015-10-02 2018-05-29 Exxonmobil Chemical Patents Inc. Supported bis phenolate transition metals complexes, production and use thereof
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
EP3452521B1 (en) 2016-05-03 2023-07-12 ExxonMobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
WO2017204830A1 (en) 2016-05-27 2017-11-30 Exxonmobil Chemical Patents, Inc. Metallocene catalyst compositions and polymerization process therewith
US10562987B2 (en) 2016-06-30 2020-02-18 Exxonmobil Chemical Patents Inc. Polymers produced via use of quinolinyldiamido transition metal complexes and vinyl transfer agents
US10723819B2 (en) 2017-02-20 2020-07-28 Exxonmobil Chemical Patents, Inc. Supported catalyst systems and processes for use thereof
EP3583140B1 (en) 2017-02-20 2023-03-08 ExxonMobil Chemical Patents Inc. Supported catalyst systems and processes for use thereof
US10626200B2 (en) 2017-02-28 2020-04-21 Exxonmobil Chemical Patents Inc. Branched EPDM polymers produced via use of vinyl transfer agents and processes for production thereof
US10676551B2 (en) 2017-03-01 2020-06-09 Exxonmobil Chemical Patents Inc. Branched ethylene copolymers produced via use of vinyl transfer agents and processes for production thereof
SG11202000942TA (en) 2017-08-04 2020-02-27 Exxonmobil Chemical Patents Inc Mixed catalysts with unbridged hafnocenes with -ch2-sime3 moieties
US10844150B2 (en) 2017-08-04 2020-11-24 Exxonmobil Chemical Patents Inc. Mixed catalysts with 2,6-bis(imino)pyridyl iron complexes and bridged hafnocenes
SG11202001743RA (en) * 2017-10-31 2020-05-28 Exxonmobil Chemical Patents Inc Toluene free silica supported single-site metallocene catalysts from in-situ supported alumoxane formation in aliphatic solvents
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
KR102405495B1 (ko) 2017-12-01 2022-06-08 엑손모빌 케미칼 패턴츠 인코포레이티드 촉매계 및 이를 사용하기 위한 중합 방법
US10926250B2 (en) 2017-12-01 2021-02-23 Exxonmobil Chemical Patents Inc. Catalyst systems and polymerization processes for using the same
US10865258B2 (en) 2018-01-31 2020-12-15 Exxonmobil Chemical Patents Inc. Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same
US10851187B2 (en) 2018-01-31 2020-12-01 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US10894841B2 (en) 2018-03-19 2021-01-19 Exxonmobil Chemical Patents Inc. Processes for producing high propylene content PEDM having low glass transition temperatures using tetrahydroindacenyl catalyst systems
CN112135863A (zh) 2018-04-06 2020-12-25 埃克森美孚化学专利公司 热塑性硫化橡胶组合物
US11291861B2 (en) 2019-03-08 2022-04-05 Mevion Medical Systems, Inc. Delivery of radiation by column and generating a treatment plan therefor
CN114286840B (zh) 2019-07-17 2025-04-08 埃克森美孚化学专利公司 用于层状制品的基于乙烯的共聚物和丙烯-α-烯烃-二烯组合物
US11472828B2 (en) 2019-10-11 2022-10-18 Exxonmobil Chemical Patents Inc. Indacene based metallocene catalysts useful in the production of propylene polymers
WO2021247244A2 (en) 2020-06-03 2021-12-09 Exxonmobil Chemical Patents Inc. Process for production of thermoplastic vulcanizates using supported catalyst systems and compositions made therefrom
BR112023000804A2 (pt) 2020-07-17 2023-02-07 Dow Global Technologies Llc Processos para polimerizar monômeros de olefina e de polimerização
KR20230039687A (ko) 2020-07-17 2023-03-21 다우 글로벌 테크놀로지스 엘엘씨 비스-페닐페녹시 금속-리간드 착물을 위한 히드로카르빌-개질된 메틸알루미녹산 공촉매
JP7726977B2 (ja) 2020-07-17 2025-08-20 ダウ グローバル テクノロジーズ エルエルシー 拘束幾何プロ触媒のためのヒドロカルビル変性メチルアルミノキサン助触媒
BR112023000737A2 (pt) 2020-07-17 2023-02-07 Dow Global Technologies Llc Processo de polimerização de monômeros de olefina
CN116438212A (zh) 2020-11-23 2023-07-14 埃克森美孚化学专利公司 不含甲苯的负载型甲基铝氧烷前体
EP4247820A1 (en) 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. <smallcaps/>? ? ?in-situ? ? ? ? ?improved process to prepare catalyst fromformed alumoxane
WO2022108974A1 (en) 2020-11-23 2022-05-27 Exxonmobil Chemical Patents Inc. Improved in-situ mao derived silica supported single-site metallocene catalysts
WO2022155026A1 (en) 2021-01-12 2022-07-21 Exxonmobil Chemical Patents Inc. Asymmetric constrained geometry catalysts
WO2023250240A1 (en) 2022-06-24 2023-12-28 Exxonmobil Chemical Patents Inc. Low cost processes of in-situ mao supportation and the derived finished polyolefin catalysts
WO2024253831A1 (en) 2023-06-06 2024-12-12 ExxonMobil Technology and Engineering Company Non-coordinated alkylaluminum free anion modified alumoxanes and methods thereof
WO2024253830A1 (en) 2023-06-06 2024-12-12 ExxonMobil Technology and Engineering Company Non-coordinated alkylaluminum free cation modified alumoxanes and methods thereof
WO2024253829A1 (en) 2023-06-06 2024-12-12 ExxonMobil Technology and Engineering Company Solution catalyst systems and uses thereof

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US491207A (en) * 1893-02-07 Car-coupling
DE3424697C2 (de) * 1984-07-05 1999-07-08 Targor Gmbh Verfahren zur Polymerisation von Ethylen oder von Mischungen von Ethylen mit anderen 1-Olefinen
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
KR920001353B1 (ko) 1986-08-26 1992-02-11 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 α-올레핀의 중합용 촉매 및 중합법
US4937217A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US4912075A (en) * 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
JP2613618B2 (ja) * 1988-04-11 1997-05-28 三井石油化学工業株式会社 エチレン系重合体の製法およびエチレン系重合体製造用触媒
US4904631A (en) 1988-11-08 1990-02-27 Exxon Chemical Patents, Inc. Supported vanadium catalyst for polymerization of olefins and a process of preparing and using the same
ES2087145T3 (es) 1989-10-10 1996-07-16 Fina Technology Catalizadores metalocenos con acidos de lewis y alkilo-aluminios.
US5369196A (en) 1990-11-30 1994-11-29 Idemitsu Kosan Co., Ltd. Production process of olefin based polymers
TW304963B (es) 1992-01-27 1997-05-11 Hoechst Ag
US5329032A (en) 1992-03-18 1994-07-12 Akzo Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
DE69403928T2 (de) 1993-04-09 1997-12-18 Tosoh Corp Katalysator und Verfahren zur Olefin-Polymerisation
JPH07173214A (ja) * 1993-10-27 1995-07-11 Nippon Oil Co Ltd オレフィン類重合用触媒成分
TW454020B (en) * 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
KR970015606A (ko) 1995-09-01 1997-04-28 윤덕용 폴리올레핀 중합용 메탈로센 담지촉매의 제조방법
EP1019415A1 (en) * 1997-09-19 2000-07-19 The Dow Chemical Company Modified alumoxane catalyst activator
US5990035A (en) 1997-10-21 1999-11-23 Koeppl; Alexander Polymerization catalyst systems, their preparation, and use
WO2003082879A1 (en) * 2002-03-28 2003-10-09 Albemarle Corporation Ionic aluminoxanate compositions and their use in catalysis
JP3914502B2 (ja) * 2002-04-08 2007-05-16 東ソー・ファインケム株式会社 オレフィン重合用助触媒およびオレフィン重合触媒用修飾メチルアルミノキサンの製造方法
EP1352913B1 (en) * 2002-04-08 2016-06-01 Tosoh Finechem Corporation Preparation of modified methylaluminoxane olefin polymerisation catalyst component
US20030207757A1 (en) * 2002-04-30 2003-11-06 Daelim Industries Co., Ltd. Catalyst composition comprising metallocene compound having bulky cycloalkyl-substituted cyclopentadienyl ligand, and process for olefin polymerization using the same
US7193100B2 (en) * 2003-12-31 2007-03-20 Albemarle Corporation Haloaluminoxane compositions, their preparation, and their use in catalysis
US7385015B2 (en) * 2004-10-12 2008-06-10 Exxonmobil Chemical Patents Inc. Trialkylaluminum treated supports
WO2007005364A2 (en) * 2005-07-01 2007-01-11 Albemarle Corporation Haloaluminoxane compositions
WO2007005676A2 (en) * 2005-07-01 2007-01-11 Albemarle Corporation Activator compositions and their use in catalysts and olefin polymerization
EP1749841A1 (en) * 2005-08-03 2007-02-07 Total Petrochemicals Research Feluy Activating fluorinated supports with iron-based post-metallocene complexes
WO2007076398A2 (en) 2005-12-21 2007-07-05 Albemarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
CA2663445A1 (en) * 2006-09-20 2008-03-27 Albemarle Corporation Catalyst activators, processes for making same, and use thereof in catalysts and polymerization of olefins
CN101821004A (zh) * 2007-08-29 2010-09-01 雅宝公司 由二烷基铝阳离子前体试剂得到的铝氧烷催化剂活化剂、用于制备其的方法以及其在催化剂和烯烃聚合中的用途

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