MX2009011054A - Proceso para la preparacion de una carga mineral tratada, la carga mineral obtenida y sus usos. - Google Patents
Proceso para la preparacion de una carga mineral tratada, la carga mineral obtenida y sus usos.Info
- Publication number
- MX2009011054A MX2009011054A MX2009011054A MX2009011054A MX2009011054A MX 2009011054 A MX2009011054 A MX 2009011054A MX 2009011054 A MX2009011054 A MX 2009011054A MX 2009011054 A MX2009011054 A MX 2009011054A MX 2009011054 A MX2009011054 A MX 2009011054A
- Authority
- MX
- Mexico
- Prior art keywords
- mineral filler
- filler product
- preparation
- treated
- product
- Prior art date
Links
- 239000012764 mineral filler Substances 0.000 title abstract 9
- 238000000034 method Methods 0.000 title abstract 3
- 238000002360 preparation method Methods 0.000 title abstract 2
- -1 C24 aliphatic monocarboxylic acid Chemical class 0.000 abstract 4
- 239000004698 Polyethylene Substances 0.000 abstract 2
- 239000004743 Polypropylene Substances 0.000 abstract 2
- 229920000573 polyethylene Polymers 0.000 abstract 2
- 229920001155 polypropylene Polymers 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 238000007765 extrusion coating Methods 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
- C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/22—Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Materials For Medical Uses (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
La presente invención se refiere al ámbito de los procesos de tratamiento de cargas minerales. El proceso para preparar la carga mineral tratada consta de los siguientes pasos: (a) tratar al menos una carga mineral seca con al menos una sal del Grupo II o del Grupo II de un ácido monocarboxílico alifático C8 a C24 para producir una carga mineral intermedia; y, a continuación, (b) tratar la carga mineral intermedia del paso (a) con al menos un ácido monocarboxílico alifático 08 a 024 para producir una carga mineral tratada. Aplicaciones en particular para preparar cargas minerales tratadas (como carbonato cálcico) para su uso en aplicaciones plásticas como aplicaciones de películas protectoras extrusionadas o transpirables a base de polipropileno (PP) o de polietileno (PE).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07007599A EP1980588B1 (en) | 2007-04-13 | 2007-04-13 | Process for the preparation of a treated mineral filler product, the obtained mineral filler product and its uses |
| PCT/IB2008/000889 WO2008125955A1 (en) | 2007-04-13 | 2008-04-11 | Process for the preparation of a treated mineral filler product, the obtained mineral filler product and its uses |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2009011054A true MX2009011054A (es) | 2009-10-30 |
Family
ID=38457956
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2009011054A MX2009011054A (es) | 2007-04-13 | 2008-04-11 | Proceso para la preparacion de una carga mineral tratada, la carga mineral obtenida y sus usos. |
Country Status (25)
| Country | Link |
|---|---|
| US (2) | US10131791B2 (es) |
| EP (3) | EP1980588B1 (es) |
| JP (1) | JP5200268B2 (es) |
| KR (1) | KR101353179B1 (es) |
| CN (2) | CN102336927B (es) |
| AR (2) | AR066017A1 (es) |
| AT (2) | ATE514745T1 (es) |
| AU (1) | AU2008237670B2 (es) |
| BR (1) | BRPI0810188B1 (es) |
| CA (1) | CA2683700C (es) |
| CL (1) | CL2008001031A1 (es) |
| DK (2) | DK1980588T3 (es) |
| EG (1) | EG25740A (es) |
| ES (2) | ES2369000T3 (es) |
| HR (2) | HRP20120625T1 (es) |
| IL (1) | IL201396A (es) |
| JO (1) | JO2745B1 (es) |
| MX (1) | MX2009011054A (es) |
| PL (2) | PL1980588T3 (es) |
| PT (2) | PT1980588E (es) |
| RU (1) | RU2463325C2 (es) |
| SI (2) | SI1980588T1 (es) |
| TW (1) | TWI438247B (es) |
| WO (1) | WO2008125955A1 (es) |
| ZA (2) | ZA200907024B (es) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2370453T3 (es) * | 2008-08-26 | 2011-12-16 | Omya Development Ag | Productos de carga mineral tratada, proceso de preparación de los mismos y usos de los mismos. |
| EP2390285A1 (en) * | 2010-05-28 | 2011-11-30 | Omya Development AG | Process for the preparation of surface treated mineral filler products and uses of same |
| PL2390280T3 (pl) * | 2010-05-28 | 2015-08-31 | Omya Int Ag | Poddane obróbce produkty stanowiące wypełniacze mineralne, sposób ich wytwarzania i ich zastosowania |
| PL2410023T3 (pl) | 2010-07-20 | 2013-03-29 | Omya Int Ag | Sposób wytwarzania traktowanego powierzchniowo węglanu wapnia i stosowanie tego materiału w kontroli materiału organicznego w środowisku wodnym |
| US8987363B2 (en) * | 2011-04-12 | 2015-03-24 | J.M. Huber Corporation | Narrow particle size distribution calcium carbonate and methods of making same |
| DK2770017T3 (en) | 2013-02-22 | 2015-12-14 | Omya Int Ag | New coating of white mineral materials for use in plastic |
| EP2843005A1 (en) * | 2013-08-26 | 2015-03-04 | Omya International AG | Earth alkali carbonate, surface modified by at least one polyhydrogensiloxane |
| RU2543209C1 (ru) * | 2013-09-10 | 2015-02-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Воронежский государственный университет инженерных технологий" (ФГБОУ ВПО "ВГУИТ") | Способ получения гидрофобного наполнителя для полимеров путем модифицирования химически осажденного карбоната кальция стеариновой кислотой |
| EP2975078A1 (en) | 2014-08-14 | 2016-01-20 | Omya International AG | Surface-treated fillers for breathable films |
| GB201514458D0 (en) * | 2015-08-14 | 2015-09-30 | Imerys Minerals Ltd | Coated calcium carbonates and their uses |
| EP3133127B1 (en) * | 2015-08-21 | 2018-08-08 | Omya International AG | Process for the preparation of a mineral filler product |
| EP3176204A1 (en) | 2015-12-02 | 2017-06-07 | Omya International AG | Surface-treated fillers for ultrathin breathable films |
| EP3192850B1 (en) | 2016-01-14 | 2018-10-03 | Omya International AG | Use of surface-treated calcium carbonate as oxygen scavenger |
| EP3192838A1 (en) * | 2016-01-14 | 2017-07-19 | Omya International AG | Treatment of surface-reacted calcium carbonate |
| EP3272524A1 (en) * | 2016-07-21 | 2018-01-24 | Omya International AG | Calcium carbonate as cavitation agent for biaxially oriented polypropylene films |
| EP3415570A1 (en) | 2017-06-14 | 2018-12-19 | Omya International AG | Process for preparing a surface treated filler material product with mono-substituted succinic anhydride(s) and a mixture of aliphatic linear or branched carboxylic acids comprising stearic acid |
| EP3628705A1 (en) | 2018-09-28 | 2020-04-01 | Omya International AG | Process for preparing a coarse surface treated filler material product |
| CN111019332B (zh) * | 2019-12-10 | 2021-09-03 | 浙江华峰合成树脂有限公司 | 一种聚氨酯防水透湿膜及其制备方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5423648A (en) * | 1977-07-25 | 1979-02-22 | Shiraishi Kogyo Kaisha Ltd | Calcium carbonate filler for wire and its making method |
| JPS54162746A (en) | 1978-06-14 | 1979-12-24 | Matsushita Electric Works Ltd | Vinyl chloride resin composition |
| JPS56120742A (en) | 1980-02-29 | 1981-09-22 | Idemitsu Petrochem Co Ltd | Polypropylene composition |
| SU1198001A1 (ru) * | 1983-12-15 | 1985-12-15 | Предприятие П/Я А-7815 | Способ получени гидрофобного карбоната кальци дл наполнени поливинилхлоридных композиций |
| US4520073A (en) * | 1983-12-23 | 1985-05-28 | Usg Corporation | Pressure coating of mineral fillers |
| SU1326590A1 (ru) | 1985-04-25 | 1987-07-30 | Белгородский технологический институт строительных материалов им.И.А.Гришманова | Способ получени модифицированного карбоната кальци |
| US5135967A (en) | 1988-01-21 | 1992-08-04 | Deutsche Solvay-Werke Gmbh | Underseal composition, and process for the production thereof |
| JPH0431318A (ja) * | 1990-05-23 | 1992-02-03 | Mitsubishi Materials Corp | 炭酸カルシウムの二層表面処理方法 |
| WO1992002587A1 (en) | 1990-08-06 | 1992-02-20 | Pfizer Inc. | Calcium carbonate treated with fatty acids, manufacture and use |
| ATE416226T1 (de) | 1998-05-22 | 2008-12-15 | Imerys Minerals Ltd | Verwendung von teilchenförmigen carbonaten in thermoplastischen filmzusammensetzungen |
| FR2784371B1 (fr) * | 1998-10-07 | 2000-12-15 | Pluss Stauffer Ag | Nouveaux carbonates de calcium naturels broyes, eventuellement traites avec un acide gras ou son sel, leur application comme regulateur de rheologie dans des compositions polymeriques |
| JP2000345068A (ja) * | 1999-06-04 | 2000-12-12 | Shiraishi Kogyo Kaisha Ltd | 充填用炭酸カルシウム |
| GB9925927D0 (en) | 1999-11-03 | 1999-12-29 | Ecc Int Ltd | Treating particulate alkaline earth metal carbonates |
| US6686044B2 (en) | 2000-12-04 | 2004-02-03 | Shiraishi Kogyo Kaisha, Ltd. | Surface-coated calcium carbonate particles, method for manufacturing same, and adhesive |
| FR2819518B1 (fr) * | 2001-01-12 | 2005-03-11 | Omya Ag | Procede de traitement d'une charge minerale par un polydialkylsiloxane et un acide gras, charges hydrophobes ainsi obtenues, et leurs applications dans des polymeres pour films "respirables" |
| AUPS146402A0 (en) | 2002-03-28 | 2002-05-09 | Compco Pty Ltd | Nanofiller compositions |
| KR101009601B1 (ko) * | 2002-10-03 | 2011-01-20 | 마루오 칼슘 가부시키가이샤 | 표면처리 탄산칼슘 및 그것을 함유해서 이루어지는수지조성물 |
| US20070167531A1 (en) | 2004-02-05 | 2007-07-19 | Preston David J | Natural particulate carbonate |
-
2007
- 2007-04-13 ES ES07007599T patent/ES2369000T3/es active Active
- 2007-04-13 PL PL07007599T patent/PL1980588T3/pl unknown
- 2007-04-13 EP EP07007599A patent/EP1980588B1/en not_active Not-in-force
- 2007-04-13 SI SI200730734T patent/SI1980588T1/sl unknown
- 2007-04-13 AT AT07007599T patent/ATE514745T1/de active
- 2007-04-13 DK DK07007599.9T patent/DK1980588T3/da active
- 2007-04-13 PT PT07007599T patent/PT1980588E/pt unknown
-
2008
- 2008-04-10 AR ARP080101490A patent/AR066017A1/es not_active Application Discontinuation
- 2008-04-11 CN CN201110189975XA patent/CN102336927B/zh not_active Expired - Fee Related
- 2008-04-11 CA CA2683700A patent/CA2683700C/en not_active Expired - Fee Related
- 2008-04-11 CL CL2008001031A patent/CL2008001031A1/es unknown
- 2008-04-11 EP EP11005154.7A patent/EP2380929B1/en not_active Revoked
- 2008-04-11 DK DK11005154.7T patent/DK2380929T3/da active
- 2008-04-11 KR KR1020097023758A patent/KR101353179B1/ko not_active Expired - Fee Related
- 2008-04-11 PT PT110051547T patent/PT2380929E/pt unknown
- 2008-04-11 HR HRP20120625AT patent/HRP20120625T1/hr unknown
- 2008-04-11 RU RU2009141838/05A patent/RU2463325C2/ru not_active IP Right Cessation
- 2008-04-11 MX MX2009011054A patent/MX2009011054A/es active IP Right Grant
- 2008-04-11 CN CN2008800185689A patent/CN101679680B/zh not_active Expired - Fee Related
- 2008-04-11 ES ES11005154T patent/ES2427291T3/es active Active
- 2008-04-11 US US12/450,719 patent/US10131791B2/en not_active Expired - Fee Related
- 2008-04-11 SI SI200831016T patent/SI2380929T1/sl unknown
- 2008-04-11 AU AU2008237670A patent/AU2008237670B2/en not_active Ceased
- 2008-04-11 JP JP2010502604A patent/JP5200268B2/ja not_active Expired - Fee Related
- 2008-04-11 BR BRPI0810188A patent/BRPI0810188B1/pt not_active IP Right Cessation
- 2008-04-11 TW TW097113171A patent/TWI438247B/zh not_active IP Right Cessation
- 2008-04-11 WO PCT/IB2008/000889 patent/WO2008125955A1/en not_active Ceased
- 2008-04-11 PL PL11005154T patent/PL2380929T3/pl unknown
- 2008-04-11 AT AT08737426T patent/ATE556112T1/de active
- 2008-04-11 EP EP08737426A patent/EP2193165B1/en active Active
- 2008-04-13 JO JO2008170A patent/JO2745B1/en active
-
2009
- 2009-10-08 ZA ZA2009/07024A patent/ZA200907024B/en unknown
- 2009-10-11 IL IL201396A patent/IL201396A/en active IP Right Grant
- 2009-10-12 EG EG2009101501A patent/EG25740A/xx active
-
2011
- 2011-03-18 ZA ZA2011/02073A patent/ZA201102073B/en unknown
-
2013
- 2013-09-04 HR HRP20130826AT patent/HRP20130826T1/hr unknown
-
2016
- 2016-01-14 AR ARP160100089A patent/AR103417A2/es unknown
- 2016-09-29 US US15/280,191 patent/US20170051153A1/en not_active Abandoned
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