[go: up one dir, main page]

MX2009009258A - Conversion de acido tereftalico a di-n-butil tereftalato. - Google Patents

Conversion de acido tereftalico a di-n-butil tereftalato.

Info

Publication number
MX2009009258A
MX2009009258A MX2009009258A MX2009009258A MX2009009258A MX 2009009258 A MX2009009258 A MX 2009009258A MX 2009009258 A MX2009009258 A MX 2009009258A MX 2009009258 A MX2009009258 A MX 2009009258A MX 2009009258 A MX2009009258 A MX 2009009258A
Authority
MX
Mexico
Prior art keywords
terephthalic acid
conversion
butyl terephthalate
terephthalate
butyl
Prior art date
Application number
MX2009009258A
Other languages
English (en)
Inventor
Vickie Haygood Osborne
Steven Leroy Cook
Phillip Wayne Turner
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Publication of MX2009009258A publication Critical patent/MX2009009258A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0225—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts
    • B01J31/0227—Sulfur-containing compounds comprising sulfonic acid groups or the corresponding salts being perfluorinated, i.e. comprising at least one perfluorinated moiety as substructure in case of polyfunctional compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
    • C07C69/80—Phthalic acid esters
    • C07C69/82—Terephthalic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se divulga un proceso para la preparación de di-n-butil tereftalato por medio de la esterificación de ácido tereftálico con n-butanol en la presencia de un ácido fuerte mientras que se emplea una columna de fraccionamiento.
MX2009009258A 2007-04-03 2008-03-24 Conversion de acido tereftalico a di-n-butil tereftalato. MX2009009258A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/732,236 US7741509B2 (en) 2007-01-30 2007-04-03 Conversion of terephthalic acid to Di-n-butyl terephthalate
PCT/US2008/003855 WO2008123928A1 (en) 2007-04-03 2008-03-24 CONVERSION OF TEREPHTHALIC ACID TO DI-n-BUTYL TEREPHTHALATE

Publications (1)

Publication Number Publication Date
MX2009009258A true MX2009009258A (es) 2010-01-28

Family

ID=39495189

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2009009258A MX2009009258A (es) 2007-04-03 2008-03-24 Conversion de acido tereftalico a di-n-butil tereftalato.

Country Status (9)

Country Link
US (1) US7741509B2 (es)
EP (1) EP2139844B1 (es)
JP (1) JP2010523560A (es)
KR (1) KR101543810B1 (es)
CN (1) CN101652343A (es)
BR (1) BRPI0808031A2 (es)
MX (1) MX2009009258A (es)
TW (1) TWI415835B (es)
WO (1) WO2008123928A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9481628B2 (en) 2012-03-30 2016-11-01 Exxonmobil Chemical Patents Inc. Esterification process
US20150307435A1 (en) 2012-03-30 2015-10-29 Exxonmobil Chemical Patents Inc. Esterification Process
US9587087B2 (en) * 2013-05-08 2017-03-07 Lg Chem, Ltd. Method for preparing ester composition and resin composition
WO2014185872A1 (en) * 2013-05-13 2014-11-20 Cey Kimya Geri Dönüşüm Makine Ve Ticaret Limited Şirketi Dotp (di-octly terephthalate)production method
TWI654177B (zh) * 2013-10-31 2019-03-21 德商巴斯夫歐洲公司 製備羧酸酯的方法及其作爲塑化劑的用途
BR112016024512A2 (pt) 2014-04-22 2017-08-15 Basf Se ?processo para produção de ésteres carboxílicos?
KR102325729B1 (ko) * 2018-11-28 2021-11-15 주식회사 엘지화학 가압 구간을 포함하는 테레프탈레이트계 조성물의 제조방법
KR102692500B1 (ko) 2021-01-29 2024-08-07 주식회사 엘지화학 가소제 조성물 및 이를 포함하는 수지 조성물
CN119258937A (zh) * 2023-07-07 2025-01-07 中国石油化工股份有限公司 微反应制备对苯二甲酸二丁酯的方法及装置

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3250801A (en) * 1966-05-10 Process for preparation of bis-allyl esters from a dicarboxylic acid an- hydride and an allyl halide
US1944887A (en) * 1931-07-03 1934-01-30 Du Pont Esters and method of preparing same
US2124605A (en) * 1934-06-12 1938-07-26 Du Pont Alkyl chlorides
US2459014A (en) * 1946-09-27 1949-01-11 Du Pont Process for making dimethyl terephthalate
US2479066A (en) * 1947-01-15 1949-08-16 Du Pont Preparation of mono-alkyl esters of terephthalic acid
US2491660A (en) * 1947-01-15 1949-12-20 Du Pont Preparation of esters of terephthalic acid
US2579329A (en) * 1949-10-18 1951-12-18 Gen Electric Trimethylol phenol compound and derivatives thereof
GB733322A (en) 1952-05-16 1955-07-06 Henkel & Cie Gmbh Process for the manufacture of polybasic aromatic carboxylic acids
BE539716A (es) * 1954-07-13
US2975209A (en) * 1956-01-31 1961-03-14 Stamicarbon Preparation of dialkyl esters of terephthalic acid
NL246758A (es) 1959-09-12
US3155715A (en) * 1959-09-30 1964-11-03 Socony Mobil Oil Co Inc Preparation of dialkyl esters of terephthalic acid
US4380677A (en) * 1981-05-11 1983-04-19 Uop Inc. Preparation of 2,6-di-tert-butyl-4-alkylphenols
JPS604151A (ja) 1983-06-20 1985-01-10 Mitsubishi Monsanto Chem Co テレフタル酸ジエステルの製造方法
KR850000300B1 (ko) * 1983-11-30 1985-03-18 한국과학기술원 프탈산 에스테르류의 제조방법
US4654436A (en) * 1985-09-05 1987-03-31 Eastman Kodak Company Carbonylation process for the production of aromatic acids or esters
FR2648136B1 (fr) * 1989-06-12 1994-06-17 Rhone Poulenc Sante Procede de preparation de l'acide ascorbique
NL9001027A (nl) * 1990-04-27 1991-11-18 Tno Werkwijze voor de bereiding van calciumbindende polycarboxyverbindingen op basis van polysacchariden, alsmede fosfaat-vervangers voor wasmiddelen op basis van deze polycarboxyverbindingen.
US5101050A (en) * 1989-11-29 1992-03-31 Amoco Corporation Process for the production of aromatic anhydrides and aromatic esters with superior color properties
US5138025A (en) * 1990-08-30 1992-08-11 Amoco Corporation Stabilized naphthalenedicarboxylic acid diesters
US5532495A (en) * 1993-11-16 1996-07-02 Sandia Corporation Methods and apparatus for altering material using ion beams
US5571387A (en) * 1994-09-13 1996-11-05 Uop Continuous single vessel distillation and adsorption process
US5585527A (en) * 1994-10-31 1996-12-17 Uop Continuous distillation and membrane process
RU2114100C1 (ru) 1996-01-23 1998-06-27 Открытое акционерное общество "Химпласт" Способ получения сложных эфиров
JP2001031794A (ja) 1999-07-21 2001-02-06 Hokoku Seiyu Kk テレフタル酸エステル
DE10043545A1 (de) * 2000-09-05 2002-03-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Carbonsäureestern
DE10056179A1 (de) * 2000-11-13 2002-05-29 Basf Ag Verfahren zur Herstellung von Estern mehrbasiger Säuren
JP2003238479A (ja) 2002-02-13 2003-08-27 Mitsubishi Chemicals Corp 高級アルコールのテレフタル酸エステルの製造方法
US6841505B2 (en) * 2002-07-26 2005-01-11 E..I. Du Pont De Nemours And Company Titanium-zirconium catalyst compositions and use thereof
JP4333317B2 (ja) 2003-10-16 2009-09-16 三菱化学株式会社 テレフタル酸ジエステルの製造方法
JP4396373B2 (ja) 2004-04-20 2010-01-13 三菱化学株式会社 テレフタル酸ジエステルの製造方法
US7799942B2 (en) * 2005-08-12 2010-09-21 Eastman Chemical Company Production of terephthalic acid di-esters
US7276621B2 (en) * 2005-08-12 2007-10-02 Eastman Chemical Company Production of di-(2-ethylhexyl) terephthalate

Also Published As

Publication number Publication date
EP2139844B1 (en) 2017-03-08
CN101652343A (zh) 2010-02-17
EP2139844A1 (en) 2010-01-06
KR20100014672A (ko) 2010-02-10
WO2008123928A1 (en) 2008-10-16
US20080183012A1 (en) 2008-07-31
WO2008123928A8 (en) 2009-06-25
TW200904795A (en) 2009-02-01
TWI415835B (zh) 2013-11-21
JP2010523560A (ja) 2010-07-15
BRPI0808031A2 (pt) 2014-06-17
US7741509B2 (en) 2010-06-22
KR101543810B1 (ko) 2015-08-11

Similar Documents

Publication Publication Date Title
MX2009009258A (es) Conversion de acido tereftalico a di-n-butil tereftalato.
MY179320A (en) Hdrodeoxygenation process
PL2044003T3 (pl) Sposób przekształcania pierwszorzędnych amidoalkoholi w kwasy amidokarboksylowe z wysoką wydajnością z użyciem wody jako rozpuszczalnika
EP3792352A3 (en) Microorganisms and methods for enhancing the availability of reducing equivalents in the presence of methanol, and for producing 1,4-butanediol related thereto
WO2013006730A3 (en) Biological methods for preparing a fatty dicarboxylic acid
MY157837A (en) Production of carboxylic acid esters by stripping with alcohol vapor
WO2014100504A3 (en) Biological methods for preparing a fatty dicarboxylic acid
BR112012001105A2 (pt) produção de ácido acético por meio de carbonilação com uma reação e vaporização instantânea melhoradas
MY159303A (en) Process for producing acetic acid and dimethyl ether using a zeolite catalyst
WO2010128518A3 (en) Novel process for the preparation of cisatracurium besylate
WO2011097208A3 (en) Process for heat integration for ethanol production and purification process
AU2012329618A8 (en) Process for the conversion of lignocellulose material into an organic acid
WO2012031045A3 (en) Phosphonate ester derivatives and methods of synthesis thereof
HK1207397A1 (en) Purification of succinic acid
WO2012065115A3 (en) Ketocarboxylic acids, ketocarboxylic esters, methods of manufacture and uses thereof
WO2012006217A3 (en) Esterification of vapor crude product in the production of alcohols
PL2089152T3 (pl) Układ do wytwarzania poliestru wykorzystujący recyrkulację gorącego alkoholu do strefy estryfikacji
BR112015014163A2 (pt) processo para a produção de um produto de hidrogenação
FR2974116B1 (fr) Procede de production d'ethanol et de solvants a partir de biomasse lignocellulosique avec recyclage d'un vin butylique obtenu par fermentation des pentoses
WO2009091866A3 (en) Process and system for preparation of bio-fuels
WO2009028371A1 (ja) アクロレインの製造方法およびアクリル酸の製造方法
EP2571842A4 (en) PREPARATION OF AROMATIC CARBOXYLIC ACIDS
MY165746A (en) Method for the production of 2-octyl acrylate by means of transesterification
FR2978157B1 (fr) Procede flexible de transformation de biomasse lignocellulosique en hydrocarbures en presence d'un acide
WO2017204913A3 (en) Purified plasticizers, production and use

Legal Events

Date Code Title Description
FG Grant or registration