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I saw this film when it came out on British TV in the 1990s and it's remained embedded in my memory ever since. All young Hollywood directors should be contractually obliged to see "Captives" to see what real on-screen chemistry is like: the heat and intensity generated between leads Tim Roth and Julia Ormond just isn't something you see in every modern film, so much so that there were moments when I almost wanted to look away, embarrassed for their intimacy and urgency, shout "get a room!" – ah, but there's the rub – they can't. He's in prison; she's the visiting prison dentist, and they're caught in an impossible position that there's no easy escape from.

Others here have described the story well, so I won't cover that ground again. But it's exactly the kind of "little" British film I love to watch: when they're good, you're rewarded with an unusually good cast, a decent script and a neat premise that draws you in and grips you. The slightly unconvincing conclusion doesn't detract from how very enjoyable and stirring this film is.

"Captives" illustrates why Tim Roth deserved his reputation as an actor; but I'm sorry not to have seen more of Julia Ormond on screen since the 90s. Is it that she's in that twilight zone of female actresses, who suffer from the lack of good parts for women who don't look twenty years younger than their age?

Rachel Clifford is a teacher in a dentistry school who starts doing a few days a week in a local prison while breaking up with her husband. It is in this delicate state that she meets prisoner Philip Chaney in the chair. When she meets him again it is in a supermarket – she is doing a shop while he is on day release to attend college. From this informal meeting they gain a natural, chatty air and, with neither really understanding why, they start to become close and meet up each time he gets out. However, in the vicious world of prison there are no real secrets and it is only a matter of time before other cons will see this as a chance to manipulate the situation to their advantage.

Although this sounds like it has a terrible plot, it actually works pretty well for the majority of the film. The core relationship that drives the film is convincingly developed and it is only really in the later stages of the film that the need for a dramatic narrative sees things turning away from the small scale and become slightly less convincing. Of course by then I was into the characters and could forgive it but it still didn't sit that easily with me. Of course for some viewers even the relationship side won't work and I can understand why; some will see it as clunky and obvious but for me it worked and it did so for two reasons.

The first reason is the acting. Ormond may have seemed to have dropped off the A-list that she was in during the mid-1990's but here she is great. Her character is just damaged and frail enough to be needy enough to fall in love in such a situation but not to the point where her love seems like a failing. It sounds simple but it isn't and yet Ormond manages to pull it off. Roth is always interesting and he is just as good here. He is dark, hurt, filled with regret and entirely unsure of how to exist in the two worlds (prison and love) at the same time. They go well together and make things a lot more natural than the plot summary would suggest. The second reason is Pope. Her direction is very good and makes the most out of what must have been a modest budget – only occasionally does it show that it was a BBC film. She never overdoes stuff to draw emotion from the audience and she lets the actors work well.

Overall this was a good film but one that requires you to accept that you are watching a slow BBC drama rather than a Hollywood tearjerker. The story may not be totally convincing but it is not for the want of trying – Pope, Ormond and Roth combine to make this much better than it could have been. Worth seeing for slow development and engaging performances although I wonder how well it sells outside of a UK market more suited to this sort of slow burn stuff.

Even if you're not a fan of the great Tim Roth, "Captives" is a must see film. The story draws you in, along with the strong believable performances by Roth and Julia Ormond. The strong chemistry between those two is electric - you can literally feel the sparks. Bittersweet and touching, but also suspenseful. Be sure to check out this drama.

This is a movie I watch over and over. You care about Rachel (Ormond) and Philip (Roth) from the beginning. You see the struggle they both go through when weighing what they have to lose by beginning a relationship. Then it's a romantic/suspenseful joyride to the end. If you like Roth or Ormond, you will love this movie, the rest of you, give it a try, you won't be sorry.

I probably wouldn't have rented it if I realized it was a woman having an affair with a prisoner, so I'm glad I didn't know that or I would have missed out on this very good movie. As it was, it turned out to be more of what I expected - two people who had been drawn together by sexual chemistry being bonded together from a shared adversity. And the sexual chemistry and tension between Roth and Ormond (or, technically, their characters as portrayed by the two excellent actors) is very strong. This is one hot movie, and it manages to be so with no nudity (although, it does have a sex scene). The movie also keeps tension throughout by showing various people noticing them. That way, you really can't be sure who their future threat will be.