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WO2025205032A1 - Method for producing cylindrical battery, device for producing cylindrical battery, and cylindrical battery - Google Patents

Method for producing cylindrical battery, device for producing cylindrical battery, and cylindrical battery

Info

Publication number
WO2025205032A1
WO2025205032A1 PCT/JP2025/009732 JP2025009732W WO2025205032A1 WO 2025205032 A1 WO2025205032 A1 WO 2025205032A1 JP 2025009732 W JP2025009732 W JP 2025009732W WO 2025205032 A1 WO2025205032 A1 WO 2025205032A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrode
negative electrode
cylindrical battery
face
electrode body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/JP2025/009732
Other languages
French (fr)
Japanese (ja)
Inventor
貴士 川口
友彰 忍
克哉 近藤
悠佑 森山
佑太 辻
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Intellectual Property Management Co Ltd
Original Assignee
Panasonic Intellectual Property Management Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Panasonic Intellectual Property Management Co Ltd filed Critical Panasonic Intellectual Property Management Co Ltd
Publication of WO2025205032A1 publication Critical patent/WO2025205032A1/en
Pending legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/04Construction or manufacture in general
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • H01M10/0587Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/536Electrode connections inside a battery casing characterised by the method of fixing the leads to the electrodes, e.g. by welding
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • H01M50/538Connection of several leads or tabs of wound or folded electrode stacks
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Definitions

  • Patent Document 1 A conventional cylindrical battery is described in Patent Document 1.
  • the bottom end of the outer can in the axial direction of the electrode assembly is made up of a negative electrode, and this bottom end is pressed against the negative electrode current collector plate.
  • a wide longitudinal area of the strip-shaped negative electrode is electrically connected to the negative electrode current collector plate, shortening the current path on the negative electrode side and reducing the electrical resistance of the cylindrical battery.
  • an axial load is applied to the second axial end of the electrode body to press the exposed portion of the negative electrode substrate against the negative electrode current collector plate, bringing the exposed portion of the negative electrode substrate into contact with the negative electrode current collector plate.
  • Laser light is then irradiated from the outside of the negative electrode current collector plate to weld the negative electrode current collector plate and the exposed portion of the negative electrode substrate.
  • the object of the present disclosure is therefore to provide a cylindrical battery manufacturing method and cylindrical battery manufacturing apparatus that can reliably and stably weld the exposed portion of the electrode core located at the first axial end of the electrode body to the current collector plate, and that can suppress unnecessary load on the electrode at the second end of the electrode body.
  • the object of the present disclosure is also to provide a cylindrical battery that is likely to have the exposed portion of the electrode core located at the first axial end of the electrode body reliably and stably welded to the current collector plate, and that is unlikely to have unnecessary load on the electrode at the second end of the electrode body.
  • the cylindrical battery manufacturing method and manufacturing apparatus disclosed herein enable the exposed portion of the electrode core located at the first axial end of the electrode body to be reliably and stably welded to the current collector plate, preventing unnecessary load from being applied to the electrode at the second end of the electrode body.
  • cylindrical battery manufacturing method and manufacturing apparatus according to the present disclosure, and a cylindrical battery that can be manufactured using the manufacturing method and manufacturing apparatus will be described in detail.
  • a cylindrical lithium-ion battery equipped with a non-aqueous electrolyte will first be described as an example of a cylindrical battery that can be manufactured using the manufacturing method and manufacturing apparatus.
  • cylindrical batteries that can be manufactured using the manufacturing method and manufacturing apparatus are not limited to this.
  • Cylindrical batteries that can be manufactured using the manufacturing method and manufacturing apparatus may be primary batteries or secondary batteries.
  • cylindrical batteries that can be manufactured using the manufacturing method and manufacturing apparatus may be batteries that use either an aqueous electrolyte or a non-aqueous electrolyte.
  • the solid electrolyte for example, a solid or gel-like polymer electrolyte, an inorganic solid electrolyte, etc. is used.
  • the polymer electrolyte includes, for example, a lithium salt and a matrix polymer, or a non-aqueous solvent, a lithium salt, and a matrix polymer.
  • the matrix polymer for example, a polymer material that absorbs the non-aqueous solvent and gels is used.
  • the polymer material for example, fluororesin, acrylic resin, polyether resin, etc. is used.
  • the negative electrode 12 is formed with dimensions slightly larger than the positive electrode 11 to prevent lithium precipitation.
  • the negative electrode 12 is formed to be longer than the positive electrode 11 in the winding direction and axial direction.
  • the two separators 13 are formed with dimensions slightly larger than the positive electrode 11 and are arranged to sandwich the positive electrode 11. The separator 13 protrudes upward beyond the positive electrode 11 and negative electrode 12, and the negative electrode 12 protrudes downward beyond the positive electrode 11 and separator 13.
  • the positive electrode 11 has a positive electrode core and positive electrode mixture layers formed on both sides of the positive electrode core.
  • the positive electrode core can be made of a metal foil, such as aluminum or an aluminum alloy, that is stable within the potential range of the positive electrode 11, or a film with such a metal disposed on the surface.
  • the positive electrode mixture layer contains a positive electrode active material, a conductive agent, and a binder.
  • the positive electrode 11 can be produced, for example, by applying a positive electrode mixture slurry containing a positive electrode active material, a conductive agent, and a binder onto the positive electrode core, drying the coating, and then compressing it to form positive electrode mixture layers on both sides of the positive electrode core.
  • the positive electrode 11 has one or more positive electrode core exposed portions where the positive electrode core is exposed, and in this embodiment, it has eight positive electrode core exposed portions arranged at intervals in the longitudinal direction of the positive electrode.
  • Positive electrode leads 20 are joined one by one to the positive electrode core exposed portions by ultrasonic welding or the like. Effectively shortening the positive electrode side current path greatly reduces the electrical resistance, so it is preferable that the center positions of the eight positive electrode leads 20 in the longitudinal direction of the positive electrode be arranged at approximately equal intervals in the longitudinal direction of the positive electrode.
  • the negative electrode 12 has a negative electrode core 40 and a negative electrode mixture layer 42 formed on both sides of the negative electrode core 40.
  • the negative electrode core 40 can be made of a metal foil, such as copper or a copper alloy, that is stable within the potential range of the negative electrode 12, or a film with such a metal disposed on the surface.
  • the negative electrode mixture layer 42 contains a negative electrode active material and a binder.
  • the negative electrode 12 can be produced, for example, by applying a negative electrode mixture slurry containing a negative electrode active material and a binder to the negative electrode core 40, drying the coating, and then compressing it to form the negative electrode mixture layer 42 on both sides of the negative electrode core 40.
  • Anode active materials generally use carbon materials that reversibly absorb and release lithium ions.
  • Preferred carbon materials are graphites such as natural graphites such as flake graphite, lump graphite, and amorphous graphite, and artificial graphites such as lump artificial graphite and graphitized mesophase carbon microbeads.
  • the anode active material of the anode mixture layer 42 preferably contains a Si material containing silicon (Si) particles, and the mass ratio of Si element in the anode mixture layer 42 is preferably 5.0 mass% or more. It is also preferable that 3.0 mass% or more of the anode mixture layer be composed of silicon oxide.
  • Metals other than Si that alloy with lithium, alloys containing such metals, compounds containing such metals, etc. may also be used as anode active materials.
  • the binder contained in the negative electrode mixture layer 42 may be fluororesin, PAN, polyimide resin, acrylic resin, polyolefin resin, etc., but styrene-butadiene rubber (SBR) or a modified version thereof is preferred.
  • SBR styrene-butadiene rubber
  • the negative electrode mixture layer 42 may also contain, for example, CMC or a salt thereof, polyacrylic acid (PAA) or a salt thereof, polyvinyl alcohol, etc.
  • Separator 13 is made of a porous sheet that is ion permeable and insulating. Specific examples of porous sheets include microporous thin films, woven fabrics, and nonwoven fabrics. Preferred materials for separator 13 include polyolefin resins such as polyethylene and polypropylene, and cellulose. Separator 13 may have either a single-layer structure or a laminated structure. A heat-resistant layer or the like may be formed on the surface of separator 13.
  • the battery 10 has a circular insulating plate 18 on the upper side of the electrode body 14.
  • the positive electrode lead 20 attached to the positive electrode 11 passes through a through-hole in the insulating plate 18 and extends toward the sealing body 17.
  • the sealing body 17 has a positive electrode current collector 26 and a terminal cap 27.
  • the positive electrode current collector 26 is a circular metal plate member with a through-hole 26a in its radial center.
  • the terminal cap 27 is a metal plate-shaped member with no through holes and is located axially above the sealing body 17.
  • the axially upper end face of the terminal cap 27 is exposed to the outside except for the outer edge, and this exposed portion forms the positive electrode terminal.
  • the sealing body 17 further has a metal plate 25.
  • the metal plate 25 is a metal annular member with a through hole.
  • Each positive electrode lead 20 passes from the positive electrode 11 through the through hole 26a of the positive electrode collector plate 26 and is bent along the upper surface of the positive electrode collector plate 26.
  • the tip of each positive electrode lead 20 is sandwiched between the upper surface of the positive electrode collector plate 26 and the lower surface of the metal plate 25.
  • Each positive electrode lead 20 is bonded to the upper surface of the positive electrode collector plate 26.
  • the positive electrode collector plate 26 and the metal plate 25 are also bonded, and each positive electrode lead 20 and the metal plate 25 are also bonded. These bonds can be achieved, for example, by laser welding the tip of each positive electrode lead 20 sandwiched between the positive electrode collector plate 26 and the metal plate 25 by irradiating the metal plate 25 with a laser beam in the axial direction from above. By laser welding the tip of the positive electrode lead 20 sandwiched between the positive electrode collector plate 26 and the metal plate 25, the positive electrode lead 20 can be reliably and easily welded and bonded to the positive electrode collector plate 26.
  • the radially extending portion 53 is connected to the flat portion 51 via a step portion 54, and the bottom surface of the flat portion 51 is located lower than the bottom surface of the radially extending portion 53.
  • the bottom surface of the flat portion 51 can be tightly adhered to the inner surface of the bottom 68 of the outer can 16 without any gaps, making it easier to achieve good joining of the flat portion 51.
  • the radially extending portion 53 has a protrusion portion 56 on its upper side.
  • the protrusion portion 56 is provided in the widthwise center of the radially extending portion 53 and protrudes in the thickness direction.
  • the protrusion portion 56 extends in the radial direction.
  • a groove portion 57 extending in the radial direction is provided at a location on the underside of the radially extending portion 53 that overlaps the protrusion portion 56 in the thickness direction.
  • the widthwise center portion of the underside of the radially extending portion 53 is pressed upward in the thickness direction by a predetermined radial distance. This press forming process forms the protrusions 56 and grooves 57.
  • the negative electrode core exposed portion 41 (see Figure 2) is joined to the protrusion portion 56. More specifically, while the negative electrode core exposed portion 41, which constitutes the lower end of the electrode body 14, is pressed against the protrusion portion 56, laser light is irradiated from below toward the bottom of the groove portion 57. This laser light irradiation joins the negative electrode core exposed portion 41 of the electrode body 14 to the protrusion portion 56 by laser welding over a wide radial area.
  • a presser rod (not shown) inserted from above into the hollow portion 14a of the electrode body 14 (see Figure 1) presses the upper surface of the flat portion 51 against the inner surface of the bottom portion 68 of the outer can 16. With this in place, laser light is irradiated from below the outer can 16 to laser-weld the bottom portion 68 to the negative electrode current collector plate 19. This electrically connects the negative electrode 12 of the electrode body 14 to the outer can 16 via the negative electrode current collector plate 19. By joining the negative electrode core exposed portion 41 over a wide area to the upper surface of the negative electrode current collector plate 19, it is possible to prevent current from flowing long distances along the longitudinal direction of the elongated negative electrode 12, thereby reducing the electrical resistance of the battery 10.
  • the outer can 16 has a cylindrical portion 39 and a bottom portion 68, and the cylindrical portion 39 includes an annular grooved portion 22 and an annular shoulder portion 29.
  • the grooved portion 22 is formed by spinning a portion of the cylindrical portion 39 to recess it radially inward around the entire circumferential direction.
  • the sealing body 17 is placed on the grooved portion 22 and is crimped and fixed to the opening of the outer can 16 via a resin gasket 28.
  • the shoulder portion 29 is formed when the upper end of the cylindrical portion 39 is bent radially inward and crimped to the outer edge of the sealing body 17, and extends radially inward at the upper end of the cylindrical portion 39.
  • the battery 10 has a thin, easily breakable portion 68a on the bottom 68 of the outer can 16.
  • the easily breakable portion 68a is formed, for example, by stamping a circle or C-shape on the underside of the bottom 68.
  • the sealing body 17 does not have a rupture plate, and an easily breakable portion 68a is provided on the bottom 68 of the outer can.
  • the bottom of the outer can does not have to have an easily breakable portion.
  • the sealing body may also have two rupture plates (a lower valve body and an upper valve body) and a convex terminal cap that covers the rupture plates.
  • the sealing body may be composed of only a rupture plate, or may have a structure in which an internal terminal plate, an insulating plate, and a rupture plate are stacked in this order from the electrode body side.
  • FIG. 5 is a schematic diagram illustrating the pre-processing performed on the negative electrode core exposed portion 41 that constitutes the lower end of the electrode body 14 before welding the electrode body 14 and the negative electrode current collector plate 19 together (before the welding process). Note that below, when simply referring to welding or during welding, welding refers to the welding of the electrode body 14 and the negative electrode current collector plate 19, and during welding refers to the welding of the electrode body 14 and the negative electrode current collector plate 19.
  • a bending process (bending step) is performed to bend the negative electrode substrate exposed portion 41 radially inward.
  • Figure 5(a) is a plan view illustrating the bending process, showing the electrode body 14 as it is being bent, viewed from below in the height direction (below in the axial direction).
  • the bending of the negative electrode substrate exposed portion 41 radially inward during the bending process is performed as follows. First, the electrode body 14 is fixed at a predetermined position in three-dimensional space by a holding device (not shown). Next, multiple flat bending plates 80, 81 (not shown) are moved from the radially outer side to the radially inner side of the electrode body 14 on a plane approximately perpendicular to the height direction of the electrode body using multiple linear actuators (not shown). At this time, the bending plates 80, 81 are moved at a height position where they come into contact with the negative electrode substrate exposed portion 41. In this way, the negative electrode substrate exposed portion 41 is tilted radially inward, bent radially inward, and flexed radially inward.
  • first bending plates 80 and four second bending plates 81 are used to bend the negative electrode core exposed portion 41 radially inward.
  • the four first bending plates 80 have a long, narrow rectangular planar shape.
  • the four first bending plates 80 are arranged at equal intervals in the circumferential direction, and in Figure 5(a), with the central axis 80a of the first bending plate 80 approximately aligned with the radial direction of the electrode body 14, the first bending plate 80 moves from the radially outer side to the radially inner side of the electrode body 14.
  • the tip 81a of the second folded plate 81 has the shape of a right-angled isosceles triangle with an apex angle of 90 degrees.
  • the second folded plate 81 moves from the radially outer side to the radially inner side of the electrode body 14.
  • a portion of the negative electrode core exposed portion 41 in the circumferential region sandwiched between the movement regions of the circumferentially adjacent first folded plates 80 is bent and tilted radially inward, and is formed radially inward.
  • Such partial load application can be performed, for example, using the manufacturing apparatus 60 shown in Figure 8.
  • Figure 6 omits part of the manufacturing apparatus 60 and shows the positional relationship between the electrode body 14, pressure plate 62, and plate mounting portion 63.
  • the manufacturing apparatus 60 includes the pressure surface 61 shown in Figure 6 and a pressure mechanism (reference numeral 65 in Figure 8) that moves the electrode body 14 relative to the pressure surface 61 to press only a portion of the first end surface 85 against the pressure surface 61.
  • the pressure surface 61 is formed by one side of the pressure plate 62 provided at a predetermined position in three-dimensional space, and the pressure plate 62 is fixed to the plate mounting portion 63 provided at a predetermined position in three-dimensional space.
  • the pressing mechanism 65 includes a base stage 65a, a movable stage 65b that is movable relative to the base stage 65a in a first direction indicated by arrow A in FIG. 8, and a holding device 65c installed on the movable stage 65b.
  • the movable stage 65b is slidable in the first direction relative to the base stage 65a.
  • the electrode body 14 is held by the holding device 65c and fixed to the movable stage 65b.
  • the first direction roughly coincides with the thickness direction of the plate mounting portion 63 (thickness direction of the pressing plate 62).
  • the pressing mechanism 65 is equipped with a pressing device (not shown) including a linear actuator.
  • the pressing device has an extendable rod, and the tip surface of the rod presses with a predetermined force in the first direction against a second end face of the electrode body 14 held by the holding device 65c on the side opposite the negative electrode core exposed portion 41 in the axial direction.
  • the pressure plates 62 have a planar shape corresponding to the above-mentioned regions 85a, 85b, 85c, and 85d.
  • the moving stage 65b in FIG. 8 is moved relative to the base stage 65a in the first direction as shown in (a) to (c) of FIG. 8, pressing the first end surface 85 of the electrode body 14 against the two pressure plates 62 fixed in the cylindrical hole 63a. In this way, a load can be applied only to the first region 85a and third region 85c of the first end surface 85 of the electrode body 14.
  • the metal plate 91 is, for example, rectangular and has one or more slits in the thickness direction.
  • the negative electrode current collector 19 (see Figure 3) is fixed to one side of the metal plate 91 with a magnet so that the four grooves 57 overlap the slits in the thickness direction of the metal plate 91.
  • the second end face 86 on the axial side of the electrode body 14 opposite the exposed negative electrode core portion is pressed, and the first end face 85 is pressed with a predetermined force against the end face of the negative electrode current collector 19 on the side where the protrusion portion 56 is formed.
  • the load applied to the second end surface 86 of the electrode body 14 is received by the metal plate 91 and transferred to the first end surface 85 of the electrode body 14 according to the law of action and reaction. During this pressure, the bent portions of the negative electrode substrate exposed portion 41 that have been bent radially inward by the four first bent plates 80 (see Figure 5(a)) are pressed against the protrusion portions 56.
  • a laser beam is emitted toward the slit from the side of the metal plate 91 opposite the fixed side of the negative current collector plate 19, irradiating the groove 57 of the negative current collector plate 19.
  • This laser beam welds the formed portion to the protrusion 56, thereby joining the electrode body 14 to the negative current collector plate 19 and integrating them.
  • spatter occurs at the point irradiated with the laser beam.
  • the metal plate 91 prevents this spatter from scattering toward the electrode body 14.
  • an axial load is applied to the second axial end of the electrode body to press the exposed portion of the negative electrode substrate against the negative electrode current collector plate, bringing the exposed portion of the negative electrode substrate into contact with the negative electrode current collector plate.
  • Laser light is then irradiated from the outside of the negative electrode current collector plate to weld the negative electrode current collector plate and the exposed portion of the negative electrode substrate.
  • a load is applied in advance to a portion of the negative electrode substrate exposed portion 41 that constitutes the lower end of the electrode body 14 by the partial load application process described above, before welding, and the portion of the negative electrode substrate exposed portion 41 is crushed toward the center in the height direction of the electrode body 14 in advance before welding. Furthermore, because the portion of the negative electrode substrate exposed portion that is crushed by the partial load application process is only a portion of the negative electrode substrate exposed portion 41, the load applied to the electrode body 14 by the partial load application process is smaller than the load that would be required to crush the entire negative electrode substrate exposed portion 41.
  • the load applied to the electrode body 14 need only be the load necessary to crush the portion of the negative electrode substrate exposed portion 41 to which no load was applied during the partial load application process toward the center of the height of the electrode body 14, and this load can be used to preferentially crush this portion toward the center of the height of the electrode body 14.
  • the load applied to the electrode assembly 14 when welding the negative electrode substrate exposed portion 41 to the negative electrode current collector plate 19 is also smaller than the load required to crush the entire negative electrode substrate exposed portion 41. Therefore, the technology disclosed herein can simultaneously achieve the exceptional and significant effect of reliably and stably welding the negative electrode substrate exposed portion 41 to the negative electrode current collector plate 19, which are in a trade-off relationship, and suppressing the application of unnecessary load to the electrode ends (positive electrode 11 end, negative electrode 12 end) on the axial side of the electrode assembly 14 opposite the negative electrode substrate exposed portion 41.
  • a load is applied before welding to only approximately half of the negative electrode substrate exposed portion 41 that constitutes the first end surface 85 of the electrode body 14. Therefore, if the load required to crush the entire negative electrode substrate exposed portion 41 is defined as load N, the load required in the partial load application process and the load required in the welding process can both be approximately load N/2. In other words, according to this embodiment, the load applied to the electrode end portion on the opposite side of the electrode body 14 from the negative electrode substrate exposed portion 41 can be rapidly reduced to approximately half the load.
  • the partial load application process is preferably performed by pressing only a portion of the first end surface 85 with the pressing surface 61, and a protrusion 62a is preferably provided on the pressing surface 61 at a location corresponding to the welding location of the negative electrode substrate exposed portion 41 to be welded in the welding process.
  • the protrusion 62a is formed as a ridge portion, and extends on a bisector that bisects the fan-shaped pressing surface 61 of the pressing plate 62.
  • the protrusion 62a is provided to press the negative electrode substrate exposed portion that is joined to the ridge portion 56 of the negative electrode current collector plate 19 (see FIG. 3).
  • the pressing surface 61 does not overlap the electrode located at the innermost periphery on the first end face 85 in the height direction of the electrode body, and in the partial load application process, it is preferable that a load in the height direction is applied only to a portion of the area located radially outward from the electrode located at the innermost periphery on the first end face 85.
  • the electrode plate at the start of winding tends to meander. By doing so, it is possible to effectively prevent unnecessary load from being applied to the electrode plate at the start of winding.
  • FIG. 10 is a schematic diagram of the negative electrode 312 of the first reference example unfolded into a long strip
  • FIG. 11 is a schematic diagram of the negative electrode 412 of the second reference example unfolded into a long strip
  • FIG. 12 is a schematic diagram of the negative electrode 512 of the second reference example unfolded into a long strip.
  • the shaded areas in FIGS. 10 and 11 are the areas where the negative electrode mixture layers 342, 442, and 542 are arranged.
  • the rigidity of the negative electrode substrate exposed portions 341, 441, 541 is reduced, making the negative electrode substrate exposed portions 341, 441, 541 more likely to be crushed in the axial direction of the electrode body, and reducing the load applied to the electrode body when welding the negative electrode substrate exposed portions 341, 441, 541 to the negative electrode current collector plate 19.
  • the negative electrode substrate exposed portion 41 has a band shape that extends from the inner end of the winding to the outer end of the winding in the longitudinal direction of the negative electrode 12, and the negative electrode substrate exposed portion 41 does not have any notches. Therefore, the rigidity of the negative electrode substrate exposed portion 41 is high, the negative electrode substrate exposed portion 41 is less likely to be crushed in the axial direction, and the load required to press the negative electrode substrate exposed portion 41 in the axial direction is large. Therefore, the effects achieved by the technology disclosed herein are remarkable.
  • a second partial load application process may be performed with two additional pressure plates 62 fixed in positions corresponding to the second region 85b and the fourth region 85d within the cylindrical hole 63a, as shown in FIG. 13 .
  • the negative electrode substrate exposed portion 41 can be crushed toward the center in the height direction of the electrode body 14 along the entire circumferential direction before welding the negative electrode substrate exposed portion 41 to the negative electrode current collector plate 19. This further reduces the load applied to the electrode body 14 when welding the negative electrode substrate exposed portion 41 to the negative electrode current collector plate 19, significantly reducing the possibility of unnecessary load being applied to the electrode end of the electrode body 14 on the side opposite the negative electrode substrate exposed portion 41.
  • partial load applying processing may be performed three or more times.
  • partial load applying processing may be performed four times with one more pressing plate 62 than in the previous partial load applying processing.
  • four different plate mounting portions 63 may be spaced apart in a second direction indicated by arrow C, which is perpendicular to the first direction, to provide four stations for performing partial load applying processing.
  • the base stage 65a may be moved in the second direction using a ball screw, linear slider, conveyor, or the like to the processing position (station) for the next partial load applying processing, and the next partial load applying processing may be performed.
  • the load applied to the electrode body 14 in each partial load application process can be further rapidly reduced to approximately one-quarter of the load required to crush the entire negative electrode substrate exposed portion 41, and it is possible to almost reliably prevent unnecessary load from being applied to the electrode end portion of the electrode body 14 on the side opposite the negative electrode substrate exposed portion 41.
  • only one pressing plate 62 may be attached to four different plate attachment portions 63 at mutually different positions.
  • the electrode body 14 is moved toward the stationary pressing surface 61, and the first end surface 85 of the electrode body 14 is pressed by the pressing surface 61.
  • the pressing surface may be moved toward the stationary first end surface of the electrode body and the first end surface may be pressed by the pressing surface, or both the electrode body and the pressing surface may move during partial load application processing, and the first end surface may be pressed by the pressing surface.
  • Figure 15 is a schematic diagram illustrating the structure of a modified battery manufacturing apparatus 160. More specifically, Figure 15(a) is a side view showing the rod 162 of the manufacturing apparatus 160 and the electrode body 14 before it comes into contact with the rod 162, and Figure 15(b) is a plan view of the rod 162 and electrode body 14 in the state shown in Figure 15(a) when viewed from the axial outside of the first end surface 85 of the electrode body 14.
  • the manufacturing apparatus 160 has four identical rods 162 arranged in two rows and two columns in a matrix.
  • Each rod 162 is a rod of a linear actuator and is extendable in one direction relative to the linear actuator case (not shown).
  • the tip surface 161 of the rod 162 has the same structure as the pressing surface 61 of the above-mentioned pressing plate 62, and has a convex portion 162a having the same structure as the convex portion 62a.
  • the second axial end surface of the electrode body 14 is in contact with a stationary plane.
  • the linear actuator case is fixed immovably at a predetermined position in three-dimensional space.
  • the electrode body 14 is held movably in its height direction by a holding device (not shown).
  • the tip surface 161 of the rod 162 presses a partial area of the first end surface 85 of the electrode body 14. In this way, as the tip surface 161 presses against the first end surface 85 of the electrode body 14, the second end surface of the electrode body 14 is pressed against the stationary plane.
  • the manufacturing apparatus 160 of the modified example can be constructed more compactly and can easily perform processing in a shorter time. Therefore, if the manufacturing apparatus 160 is used to perform partial load application processing, it is easy to shorten the cycle time and improve the mass productivity of the battery 10.
  • the manufacturing device may have only one rod 162.
  • the case of the linear actuator may then be fixed to a rotary stage, and the rotary stage may be rotated to move the processing position of the rod 162 in the circumferential direction of the electrode body.
  • the partial region of the first end face 85 of the electrode body 14 to which a load is applied by the partial load application process has been described as being a partial region in the circumferential direction of the first end face 85.
  • the region to which a load is applied by the partial load application process may be any partial region on the end face on the electrode core exposed portion side of the electrode body.
  • the partial region to which a load is applied by the partial load application process may be an outer peripheral region located radially outward over the entire circumferential direction on the end face on the electrode core exposed portion side of the electrode body, or an inner peripheral region located radially inward over the entire circumferential direction on the end face on the electrode core exposed portion side of the electrode body.
  • the electrode core exposed portion is the negative electrode core exposed portion 41 that constitutes the end portion in the height direction of the electrode body 14, and the technology disclosed herein is used to prevent unnecessary loads from being applied to the electrodes (positive electrode 11 and negative electrode 12) when welding the negative electrode core exposed portion 41 to the negative electrode current collector plate 19.
  • the electrode core exposed portion may also be a positive electrode core exposed portion that constitutes the end portion in the height direction of the electrode body, and the technology disclosed herein may also be used to prevent unnecessary loads from being applied to the electrodes (positive electrode and negative electrode) when welding the positive electrode core exposed portion to the positive electrode current collector plate.
  • the cylindrical battery manufacturing method, cylindrical battery manufacturing apparatus, and cylindrical battery of the present disclosure may also have the following configurations.
  • Configuration 1 A method for manufacturing a cylindrical battery, which includes a welding step of welding an exposed portion of an electrode core that constitutes an end portion in the height direction of an electrode body to a current collector plate, and which includes a partial load application step of applying a height direction load to only a portion of the end face on the end side in the height direction of the electrode body before the welding step.
  • Configuration 2 The method for manufacturing a cylindrical battery according to Configuration 1, wherein in the partial load application step, a height direction load is applied only to a portion of a region located radially outward from an electrode located radially innermost on the end face.
  • Configuration 3 The method for manufacturing a cylindrical battery according to Configuration 1 or 2, wherein the partial load application step is performed multiple times by changing the region of the end face to which the height direction load is applied.
  • Configuration 4 The method for manufacturing a cylindrical battery according to any one of Configurations 1 to 3, wherein the partial load application step is performed by pressing only a portion of the end face against a pressing surface, and a convex portion is provided on the pressing surface at a corresponding location that corresponds to a welding location of the electrode core exposed portion that is to be welded in the welding step.
  • Configuration 5 The method for manufacturing a cylindrical battery according to any one of Configurations 1 to 4, wherein the portion of the end face is included in a partial region of the end face in the circumferential direction.
  • Configuration 6 The method for manufacturing a cylindrical battery according to any one of Configurations 1 to 5, wherein the electrode substrate exposed portion has a band shape that extends from the inner end of the electrode to the outer end of the electrode in the longitudinal direction of the electrode, and the electrode substrate exposed portion does not have a notch.
  • Configuration 7 A cylindrical battery manufacturing device comprising: a pressing surface; and a pressing mechanism that moves the electrode body relative to the pressing surface to press only a portion of the height-wise end surface of the electrode body against the pressing surface.
  • Configuration 8 The cylindrical battery manufacturing apparatus according to Configuration 7, wherein, when a portion of the end face is pressed against the pressing surface, the pressing surface is positioned radially spaced apart from the radially inner side of the end face.

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Abstract

This method for producing a cylindrical battery (10) comprises a welding step for welding, to a collector plate (19), an electrode core body exposed part (41) that constitutes a height direction end of an electrode body (14). The method for producing the cylindrical battery (10) comprises a partial load application step for, before the welding step, applying a height direction load to only part of an end face on the height direction end side of the electrode body (14). The partial load application step may be performed a plurality of times in which the region of the end face to which the height direction load is applied is changed. The method for producing a cylindrical battery according to the present disclosure makes it possible to reliably and stably weld, to the collector plate (19), the electrode core body exposed part (41) of the electrode body (14) positioned at said end, and makes it possible to suppress application of an unnecessary load to an electrode (11, 12) at an end on the opposite side from said end of the electrode body (14).

Description

円筒形電池の製造方法、円筒形電池の製造装置、及び円筒形電池Cylindrical battery manufacturing method, cylindrical battery manufacturing device, and cylindrical battery

 本開示は、円筒形電池の製造方法、円筒形電池の製造装置、及び円筒形電池に関する。 This disclosure relates to a method for manufacturing a cylindrical battery, an apparatus for manufacturing a cylindrical battery, and a cylindrical battery.

 従来、円筒形電池としては、特許文献1に記載されているものがある。この円筒形電池は、電極体における軸方向の外装缶の底側の端部を負極で構成して、その底側の端部を負極集電板に押し付けている。このようにして、帯状の負極における長手方向の広範な領域を負極集電板に電気的に接続することで負極側の電流経路を短縮して、円筒形電池の電気抵抗を抑制している。 A conventional cylindrical battery is described in Patent Document 1. In this cylindrical battery, the bottom end of the outer can in the axial direction of the electrode assembly is made up of a negative electrode, and this bottom end is pressed against the negative electrode current collector plate. In this way, a wide longitudinal area of the strip-shaped negative electrode is electrically connected to the negative electrode current collector plate, shortening the current path on the negative electrode side and reducing the electrical resistance of the cylindrical battery.

特開2014-186912号公報JP 2014-186912 A

 電極体の軸方向の第1端部を負極芯体露出部で構成して、その負極芯体露出部を負極集電板に溶接した後、負極集電板を外装缶の底部に溶接すると、負極における長手方向の広範な領域を負極集電板に確実かつ安定的に電気的に接続することができる。 By configuring the first axial end of the electrode body as an exposed negative electrode core portion, welding this exposed negative electrode core portion to the negative electrode current collector plate, and then welding the negative electrode current collector plate to the bottom of the outer can, a wide longitudinal area of the negative electrode can be reliably and stably electrically connected to the negative electrode current collector plate.

 また、負極芯体露出部を負極集電板に溶接する際には、電極体の軸方向の第2端部に軸方向に荷重を印加することで負極芯体露出部を負極集電板に押圧して負極芯体露出部を負極集電板に当接させた状態で、負極集電板の外側からレーザ光を照射することによって、負極集電板と負極芯体露出部を溶接する。 Furthermore, when welding the exposed portion of the negative electrode substrate to the negative electrode current collector plate, an axial load is applied to the second axial end of the electrode body to press the exposed portion of the negative electrode substrate against the negative electrode current collector plate, bringing the exposed portion of the negative electrode substrate into contact with the negative electrode current collector plate. Laser light is then irradiated from the outside of the negative electrode current collector plate to weld the negative electrode current collector plate and the exposed portion of the negative electrode substrate.

 係る背景において、負極芯体露出部を負極集電板に確実かつ安定に溶接するために負極芯体露出部を負極集電板に確実に当接させる必要があり、電極体の第2端部に良好な当接性確保に必要な荷重を付与する必要がある。しかし、電極体の第2端部にそのような荷重を付与すると電極体の第2端部に位置する極板に不必要な荷重が加わる虞がある。 In light of this background, in order to reliably and stably weld the exposed portion of the negative electrode substrate to the negative electrode current collector plate, it is necessary to ensure that the exposed portion of the negative electrode substrate is in secure contact with the negative electrode current collector plate, and it is necessary to apply the load necessary to ensure good contact to the second end of the electrode body. However, applying such a load to the second end of the electrode body may result in unnecessary load being applied to the electrode plate located at the second end of the electrode body.

 そこで、本開示の目的は、電極体の軸方向の第1端部に位置する電極芯体露出部を確実かつ安定に集電板に溶接でき、電極体の第2端部の電極への不必要な荷重を抑制できる円筒形電池の製造方法、及び円筒形電池の製造装置を提供することにある。また、本開示の目的は、電極体の軸方向の第1端部に位置する電極芯体露出部が確実かつ安定に集電板に溶接されている可能性が高く、電極体の第2端部の電極に不必要な荷重がかかる虞が低い円筒形電池を提供することにある。 The object of the present disclosure is therefore to provide a cylindrical battery manufacturing method and cylindrical battery manufacturing apparatus that can reliably and stably weld the exposed portion of the electrode core located at the first axial end of the electrode body to the current collector plate, and that can suppress unnecessary load on the electrode at the second end of the electrode body. The object of the present disclosure is also to provide a cylindrical battery that is likely to have the exposed portion of the electrode core located at the first axial end of the electrode body reliably and stably welded to the current collector plate, and that is unlikely to have unnecessary load on the electrode at the second end of the electrode body.

 上記課題を解決するため、本開示に係る円筒形電池の製造方法は、電極体の高さ方向の端部を構成する電極芯体露出部を集電板に溶接する溶接工程を含む円筒形電池の製造方法であって、前記溶接工程の前に、前記電極体の高さ方向の前記端部側の端面の一部のみに高さ方向の荷重を付与する一部荷重付与工程を含む。 In order to solve the above problems, the manufacturing method for a cylindrical battery according to the present disclosure is a manufacturing method for a cylindrical battery that includes a welding step of welding the exposed portion of the electrode core that constitutes the end portion in the height direction of the electrode body to a current collector plate, and includes a partial load application step, prior to the welding step, of applying a height direction load to only a portion of the end face of the electrode body on the end side in the height direction.

 また、本開示に係る円筒形電池の製造装置は、押圧面と、前記電極体を前記押圧面に相対移動させて前記電極体の高さ方向の端面の一部のみを前記押圧面に押圧させる押圧機構と、を備える。 In addition, the cylindrical battery manufacturing apparatus according to the present disclosure includes a pressing surface and a pressing mechanism that moves the electrode body relative to the pressing surface to press only a portion of the end surface in the height direction of the electrode body against the pressing surface.

 本開示に係る円筒形電池の製造方法及び製造装置によれば、電極体の軸方向の第1端部に位置する電極芯体露出部を確実かつ安定に集電板に溶接でき、電極体の第2端部の電極に不必要な荷重がかかるのを抑制できる。 The cylindrical battery manufacturing method and manufacturing apparatus disclosed herein enable the exposed portion of the electrode core located at the first axial end of the electrode body to be reliably and stably welded to the current collector plate, preventing unnecessary load from being applied to the electrode at the second end of the electrode body.

本開示の製造方法で製造可能な円筒形電池の軸方向の断面図である。1 is an axial cross-sectional view of a cylindrical battery that can be manufactured by the manufacturing method of the present disclosure. FIG. 電極体及び正極リードの一部を示す斜視図である。FIG. 2 is a perspective view showing a portion of the electrode body and the positive electrode lead. 負極集電板の斜視図である。FIG. 負極集電板を下側から見たときの平面図である。FIG. 2 is a plan view of the negative electrode current collector plate as viewed from below. 電極体と負極集電板の溶接前に電極体の下側端部を構成する負極芯体露出部に対して施す前加工について説明する模式図である。10 is a schematic diagram illustrating pre-processing performed on the negative electrode substrate exposed portion that constitutes the lower end portion of the electrode body before welding the electrode body and the negative electrode current collector plate. FIG. 一部荷重付与工程の一例を説明する図である。FIG. 10 is a diagram illustrating an example of a partial load applying step. 負極芯体露出部を負極集電板に溶接する際に使用する溶接装置の構造と、溶接方法について説明するための図である。10A and 10B are diagrams for explaining the structure of a welding device used when welding a negative electrode substrate exposed portion to a negative electrode current collector plate, and a welding method. 一部荷重付与工程で使用できる製造装置の構造と、一部荷重付与工程の一例を説明するための図である。10A and 10B are diagrams for explaining the structure of a manufacturing device that can be used in a partial load applying step and an example of the partial load applying step. 本件発明者が見出した課題について説明する図である。FIG. 1 is a diagram illustrating a problem found by the present inventors. 第1参考例の負極を長尺状に展開した模式図である。FIG. 2 is a schematic diagram showing the negative electrode of the first reference example developed into a long strip. 第2参考例の負極を長尺状に展開した模式図である。FIG. 10 is a schematic diagram showing the negative electrode of the second reference example developed into a long strip. 第3参考例の負極を長尺状に展開した模式図である。FIG. 10 is a schematic diagram showing the negative electrode of the third reference example developed into a long strip. 2回目の一部荷重付与工程の一例について説明する図である。10A and 10B are diagrams illustrating an example of a second partial load applying step. 一部荷重付与加工を4回行う工程の一例について説明する図である。10A and 10B are diagrams illustrating an example of a process in which partial load application processing is performed four times. 変形例の電池の製造装置の構造を説明する模式図である。FIG. 10 is a schematic diagram illustrating the structure of a modified battery manufacturing apparatus.

 以下、図面を参照しながら、本開示に係る円筒形電池の製造方法及び製造装置、及び当該製造方法及び製造装置で製造できる円筒形電池について詳細に説明する。以下では、一先ず、当該製造方法及び製造装置で製造できる円筒形電池の一例として、非水電解質を備える円筒形リチウムイオン電池について説明する。なお、当該製造方法及び製造装置で製造できる円筒形電池は、これに限定されない。当該製造方法及び製造装置で製造できる円筒形電池は、一次電池でもよく、二次電池でもよい。また、当該製造方法及び製造装置で製造できる円筒形電池は、水系電解質を用いた電池でもよく、非水系電解質を用いた電池でもよい。 Below, with reference to the drawings, a cylindrical battery manufacturing method and manufacturing apparatus according to the present disclosure, and a cylindrical battery that can be manufactured using the manufacturing method and manufacturing apparatus will be described in detail. Below, a cylindrical lithium-ion battery equipped with a non-aqueous electrolyte will first be described as an example of a cylindrical battery that can be manufactured using the manufacturing method and manufacturing apparatus. Note that cylindrical batteries that can be manufactured using the manufacturing method and manufacturing apparatus are not limited to this. Cylindrical batteries that can be manufactured using the manufacturing method and manufacturing apparatus may be primary batteries or secondary batteries. Furthermore, cylindrical batteries that can be manufactured using the manufacturing method and manufacturing apparatus may be batteries that use either an aqueous electrolyte or a non-aqueous electrolyte.

 以下において複数の実施形態や変形例などが含まれる場合、それらの特徴部分を適宜に組み合わせて新たな実施形態を構築することは当初から想定されている。以下の実施形態では、図面において同一構成に同一符号を付し、重複する説明を省略する。また、複数の図面には、模式図が含まれ、異なる図間において、各部材における、縦、横、高さ等の寸法比は、必ずしも一致しない。本明細書では、軸方向(高さ方向)の封口体17側を上側と言及し、軸方向の外装缶16の底部68側を下側と言及する。また、以下の説明で、径方向とは、外装缶16の径方向であり、円筒形電池10の径方向に一致する。また、周方向とは、外装缶16の周方向であり、円筒形電池10の周方向に一致する。また、以下で説明される構成要素のうち、最上位概念を示す独立請求項に記載されていない構成要素については、任意の構成要素であり、必須の構成要素ではない。 When the following includes multiple embodiments and variations, it is anticipated from the beginning that new embodiments can be constructed by appropriately combining their characteristic features. In the following embodiments, the same components are designated by the same reference numerals in the drawings, and redundant explanations will be omitted. Furthermore, the multiple drawings include schematic diagrams, and the dimensional ratios of the length, width, height, etc. of each component do not necessarily match between different drawings. In this specification, the side of the sealing body 17 in the axial direction (height direction) is referred to as the upper side, and the side of the bottom 68 of the outer can 16 in the axial direction is referred to as the lower side. Furthermore, in the following description, the radial direction refers to the radial direction of the outer can 16, which coincides with the radial direction of the cylindrical battery 10. Furthermore, the circumferential direction refers to the circumferential direction of the outer can 16, which coincides with the circumferential direction of the cylindrical battery 10. Furthermore, among the components described below, components not recited in the independent claims representing the highest concepts are optional components and are not required components.

 図1は、本開示の一実施形態に係る円筒形電池10の軸方向の断面図である。図1に示すように、円筒形電池(以下、単に電池という)10は、巻回形の電極体14と、非水電解質(図示せず)と、電極体14及び非水電解質を収容する有底筒状の外装缶16と、外装缶16をガスケット28を介して封口する封口体17とを備える。 FIG. 1 is an axial cross-sectional view of a cylindrical battery 10 according to one embodiment of the present disclosure. As shown in FIG. 1, the cylindrical battery (hereinafter simply referred to as battery) 10 comprises a wound electrode assembly 14, a non-aqueous electrolyte (not shown), a bottomed cylindrical outer can 16 that houses the electrode assembly 14 and the non-aqueous electrolyte, and a sealing body 17 that seals the outer can 16 via a gasket 28.

 電極体14は、長尺状の正極11と、長尺状の負極12と、正極11と負極12の間に介在するセパレータ13を含み、正極11と負極12がセパレータ13を介して巻回された巻回構造を有する。 The electrode assembly 14 includes a long positive electrode 11, a long negative electrode 12, and a separator 13 interposed between the positive electrode 11 and the negative electrode 12, and has a wound structure in which the positive electrode 11 and the negative electrode 12 are wound with the separator 13 interposed therebetween.

 非水電解質は、イオン伝導性(例えば、リチウムイオン伝導性)を有する。非水電解質は、液状の電解質(電解液)であってもよく、固体電解質であってもよい。液状の電解質(電解液)は、非水溶媒と、非水溶媒に溶解した電解質塩とを含む。非水溶媒には、例えば、エステル類、エーテル類、ニトリル類、アミド類、及びこれらの2種以上の混合溶媒等が用いられる。非水溶媒の一例としては、エチレンカーボネート(EC)、エチルメチルカーボネート(EMC)、ジメチルカーボネート(DMC)、ジエチルカーボネート(DEC)、及びこれらの混合溶媒等が挙げられる。非水溶媒は、これら溶媒の水素の少なくとも一部をフッ素等のハロゲン原子で置換したハロゲン置換体(例えば、フルオロエチレンカーボネート等)を含有していてもよい。電解質塩には、例えば、LiPF等のリチウム塩が使用される。 The non-aqueous electrolyte has ion conductivity (e.g., lithium ion conductivity). The non-aqueous electrolyte may be a liquid electrolyte (electrolytic solution) or a solid electrolyte. The liquid electrolyte (electrolytic solution) includes a non-aqueous solvent and an electrolyte salt dissolved in the non-aqueous solvent. Examples of non-aqueous solvents include esters, ethers, nitriles, amides, and mixed solvents of two or more of these. Examples of non-aqueous solvents include ethylene carbonate (EC), ethyl methyl carbonate (EMC), dimethyl carbonate (DMC), diethyl carbonate (DEC), and mixed solvents of these. The non-aqueous solvent may contain a halogen-substituted solvent (e.g., fluoroethylene carbonate) in which at least a portion of the hydrogen atoms of these solvents are substituted with halogen atoms such as fluorine. The electrolyte salt may be, for example, a lithium salt such as LiPF6 .

 固体電解質としては、例えば、固体状またはゲル状のポリマー電解質、無機固体電解質等が使用される。ポリマー電解質は、例えば、リチウム塩とマトリックスポリマー、あるいは、非水溶媒とリチウム塩とマトリックスポリマーとを含む。マトリックスポリマーとしては、例えば、非水溶媒を吸収してゲル化するポリマー材料が使用される。ポリマー材料としては、例えば、フッ素樹脂、アクリル樹脂、ポリエーテル樹脂等が使用される。無機固体電解質としては、例えば、全固体リチウムイオン二次電池等で公知の材料(例えば、酸化物系固体電解質、硫化物系固体電解質、ハロゲン化物系固体電解質等)が使用される。 As the solid electrolyte, for example, a solid or gel-like polymer electrolyte, an inorganic solid electrolyte, etc. is used. The polymer electrolyte includes, for example, a lithium salt and a matrix polymer, or a non-aqueous solvent, a lithium salt, and a matrix polymer. As the matrix polymer, for example, a polymer material that absorbs the non-aqueous solvent and gels is used. As the polymer material, for example, fluororesin, acrylic resin, polyether resin, etc. is used. As the inorganic solid electrolyte, for example, a material known in all-solid-state lithium-ion secondary batteries (for example, oxide-based solid electrolytes, sulfide-based solid electrolytes, halide-based solid electrolytes, etc.) is used.

 図2は、電極体14及び正極リード20の一部を示す斜視図である。図2に示すように、電極体14は、長尺状の正極11と、長尺状の負極12と、長尺状の2枚のセパレータ13とを有し、正極11と負極12がセパレータ13を介して巻回された巻回構造を有する。正極11には、1以上の正極リード20が接合され、好ましくは、6つ以上の正極リード20が接合され、本実施形態では、8つの正極リード20が、正極長手方向に互いに間隔をおいた状態で正極11に接合される。 Figure 2 is a perspective view showing a portion of the electrode body 14 and positive electrode lead 20. As shown in Figure 2, the electrode body 14 has a long positive electrode 11, a long negative electrode 12, and two long separators 13, and has a wound structure in which the positive electrode 11 and negative electrode 12 are wound with the separator 13 interposed therebetween. One or more positive electrode leads 20 are joined to the positive electrode 11, and preferably six or more positive electrode leads 20 are joined; in this embodiment, eight positive electrode leads 20 are joined to the positive electrode 11 at intervals from one another in the longitudinal direction of the positive electrode.

 負極12は、リチウムの析出を防止するために、正極11よりも一回り大きな寸法で形成される。負極12は、正極11より巻方向及び軸方向に長く形成される。2枚のセパレータ13は、正極11よりも一回り大きな寸法で形成され、正極11を挟むように配置される。セパレータ13は正極11及び負極12よりも上方に突出し、負極12は正極11及びセパレータ13よりも下方に突出する。 The negative electrode 12 is formed with dimensions slightly larger than the positive electrode 11 to prevent lithium precipitation. The negative electrode 12 is formed to be longer than the positive electrode 11 in the winding direction and axial direction. The two separators 13 are formed with dimensions slightly larger than the positive electrode 11 and are arranged to sandwich the positive electrode 11. The separator 13 protrudes upward beyond the positive electrode 11 and negative electrode 12, and the negative electrode 12 protrudes downward beyond the positive electrode 11 and separator 13.

 負極12は、負極芯体40において負極合剤層42が設けられていない負極芯体露出部41を負極12の負極長手方向の巻内端から巻外端まで軸方向の下側端部に有する。負極芯体露出部41は、電極芯体露出部の一例である。電極体14の軸方向(高さ方向)の下側端部は、負極芯体露出部41で構成される。負極12は、電極体14の巻内端を構成してもよい。しかし、一般的には、セパレータ13が負極12の巻内端を超えて延出し、セパレータ13の巻内端が電極体14の巻内端となる。 The negative electrode 12 has a negative electrode core exposed portion 41, where the negative electrode mixture layer 42 is not provided on the negative electrode core 40, at the lower axial end from the inner end to the outer end in the negative electrode longitudinal direction of the negative electrode 12. The negative electrode core exposed portion 41 is an example of an electrode core exposed portion. The lower axial end (height direction) of the electrode body 14 is formed by the negative electrode core exposed portion 41. The negative electrode 12 may form the inner end of the electrode body 14. However, typically, the separator 13 extends beyond the inner end of the negative electrode 12, and the inner end of the separator 13 becomes the inner end of the electrode body 14.

 正極11は、正極芯体と、正極芯体の両面に形成された正極合剤層を有する。正極芯体には、アルミニウム、アルミニウム合金など、正極11の電位範囲で安定な金属箔、当該金属を表層に配置したフィルム等を用いることができる。正極合剤層は、正極活物質、導電剤、及び結着剤を含む。正極11は、例えば正極芯体上に正極活物質、導電剤、及び結着剤等を含む正極合剤スラリーを塗布し、塗膜を乾燥させた後、圧縮して正極合剤層を正極芯体の両面に形成することにより作製できる。 The positive electrode 11 has a positive electrode core and positive electrode mixture layers formed on both sides of the positive electrode core. The positive electrode core can be made of a metal foil, such as aluminum or an aluminum alloy, that is stable within the potential range of the positive electrode 11, or a film with such a metal disposed on the surface. The positive electrode mixture layer contains a positive electrode active material, a conductive agent, and a binder. The positive electrode 11 can be produced, for example, by applying a positive electrode mixture slurry containing a positive electrode active material, a conductive agent, and a binder onto the positive electrode core, drying the coating, and then compressing it to form positive electrode mixture layers on both sides of the positive electrode core.

 正極活物質は、リチウム含有金属複合酸化物を主成分として構成される。リチウム含有金属複合酸化物に含有される金属元素としては、Ni、Co、Mn、Al、B、Mg、Ti、V、Cr、Fe、Cu、Zn、Ga、Sr、Zr、Nb、In、Sn、Ta、W等が挙げられる。好ましいリチウム含有金属複合酸化物の一例は、Ni、Co、Mn、Alの少なくとも1種を含有する複合酸化物である。 The positive electrode active material is composed primarily of a lithium-containing metal composite oxide. Metal elements contained in the lithium-containing metal composite oxide include Ni, Co, Mn, Al, B, Mg, Ti, V, Cr, Fe, Cu, Zn, Ga, Sr, Zr, Nb, In, Sn, Ta, and W. An example of a preferred lithium-containing metal composite oxide is a composite oxide containing at least one of Ni, Co, Mn, and Al.

 正極合剤層に含まれる導電剤としては、アセチレンブラック、ケッチェンブラック等のカーボンブラック、黒鉛等の炭素材料が例示できる。正極合剤層に含まれる結着剤としては、ポリテトラフルオロエチレン(PTFE)、ポリフッ化ビニリデン(PVdF)等のフッ素樹脂、ポリアクリロニトリル(PAN)、ポリイミド樹脂、アクリル樹脂、ポリオレフィン樹脂などが例示できる。これらの樹脂と、カルボキシメチルセルロース(CMC)又はその塩等のセルロース誘導体、ポリエチレンオキシド(PEO)などが併用されてもよい。 Examples of conductive agents contained in the positive electrode mixture layer include carbon black such as acetylene black and ketjen black, and carbon materials such as graphite. Examples of binders contained in the positive electrode mixture layer include fluororesins such as polytetrafluoroethylene (PTFE) and polyvinylidene fluoride (PVdF), polyacrylonitrile (PAN), polyimide resin, acrylic resin, and polyolefin resin. These resins may be used in combination with cellulose derivatives such as carboxymethyl cellulose (CMC) or its salts, and polyethylene oxide (PEO).

 正極11は、正極芯体が露出した1以上の正極芯体露出部を有し、本実施形態では、正極長手方向に間隔をおいて配置される8つの正極芯体露出部を有する。正極芯体露出部には、正極リード20が超音波溶着等で1つずつ接合されている。正極側電流経路が効果的に短縮されることによって、電気抵抗の低減値が大きくなるので、8つの正極リード20の正極長手方向の中心位置は、正極長手方向に略等間隔に配置されることが好ましい。 The positive electrode 11 has one or more positive electrode core exposed portions where the positive electrode core is exposed, and in this embodiment, it has eight positive electrode core exposed portions arranged at intervals in the longitudinal direction of the positive electrode. Positive electrode leads 20 are joined one by one to the positive electrode core exposed portions by ultrasonic welding or the like. Effectively shortening the positive electrode side current path greatly reduces the electrical resistance, so it is preferable that the center positions of the eight positive electrode leads 20 in the longitudinal direction of the positive electrode be arranged at approximately equal intervals in the longitudinal direction of the positive electrode.

 図2に示すように、負極12は、負極芯体40と、負極芯体40の両面に形成された負極合剤層42を有する。負極芯体40には、銅、銅合金など、負極12の電位範囲で安定な金属箔、当該金属を表層に配置したフィルム等を用いることができる。負極合剤層42は、負極活物質、及び結着剤を含む。負極12は、例えば負極芯体40上に負極活物質、及び結着剤等を含む負極合剤スラリーを塗布し、塗膜を乾燥させた後、圧縮して負極合剤層42を負極芯体40の両面に形成することにより作製できる。 As shown in FIG. 2, the negative electrode 12 has a negative electrode core 40 and a negative electrode mixture layer 42 formed on both sides of the negative electrode core 40. The negative electrode core 40 can be made of a metal foil, such as copper or a copper alloy, that is stable within the potential range of the negative electrode 12, or a film with such a metal disposed on the surface. The negative electrode mixture layer 42 contains a negative electrode active material and a binder. The negative electrode 12 can be produced, for example, by applying a negative electrode mixture slurry containing a negative electrode active material and a binder to the negative electrode core 40, drying the coating, and then compressing it to form the negative electrode mixture layer 42 on both sides of the negative electrode core 40.

 負極活物質には、一般的に、リチウムイオンを可逆的に吸蔵、放出する炭素材料が用いられる。好ましい炭素材料は、鱗片状黒鉛、塊状黒鉛、土状黒鉛等の天然黒鉛、塊状人造黒鉛、黒鉛化メソフェーズカーボンマイクロビーズ等の人造黒鉛などの黒鉛である。容量を大きくし易いので、負極合剤層42の負極活物質に、ケイ素(Si)粒子を含有するSi材料が含まれることが好ましく、負極合剤層42におけるSi元素の質量比率が、5.0質量%以上であることが好ましい。また、負極合剤層の3.0質量%以上が、酸化ケイ素で構成されることが好ましい。負極活物質には、Si以外のリチウムと合金化する金属、当該金属を含有する合金、当該金属を含有する化合物等が用いられてもよい。 Anode active materials generally use carbon materials that reversibly absorb and release lithium ions. Preferred carbon materials are graphites such as natural graphites such as flake graphite, lump graphite, and amorphous graphite, and artificial graphites such as lump artificial graphite and graphitized mesophase carbon microbeads. To facilitate increased capacity, the anode active material of the anode mixture layer 42 preferably contains a Si material containing silicon (Si) particles, and the mass ratio of Si element in the anode mixture layer 42 is preferably 5.0 mass% or more. It is also preferable that 3.0 mass% or more of the anode mixture layer be composed of silicon oxide. Metals other than Si that alloy with lithium, alloys containing such metals, compounds containing such metals, etc. may also be used as anode active materials.

 負極合剤層42に含まれる結着剤には、正極11の場合と同様に、フッ素樹脂、PAN、ポリイミド樹脂、アクリル樹脂、ポリオレフィン樹脂等を用いてもよいが、好ましくはスチレン-ブタジエンゴム(SBR)又はその変性体を用いる。負極合剤層42には、例えばSBR等に加えて、CMC又はその塩、ポリアクリル酸(PAA)又はその塩、ポリビニルアルコールなどが含まれていてもよい。 As with the positive electrode 11, the binder contained in the negative electrode mixture layer 42 may be fluororesin, PAN, polyimide resin, acrylic resin, polyolefin resin, etc., but styrene-butadiene rubber (SBR) or a modified version thereof is preferred. In addition to SBR, the negative electrode mixture layer 42 may also contain, for example, CMC or a salt thereof, polyacrylic acid (PAA) or a salt thereof, polyvinyl alcohol, etc.

 セパレータ13には、イオン透過性及び絶縁性を有する多孔性シートが用いられる。多孔性シートの具体例としては、微多孔薄膜、織布、不織布等が挙げられる。セパレータ13の材質としては、ポリエチレン、ポリプロピレン等のポリオレフィン樹脂、セルロースなどが好ましい。セパレータ13は、単層構造、積層構造のいずれでもよい。セパレータ13の表面には、耐熱層などが形成されてもよい。 Separator 13 is made of a porous sheet that is ion permeable and insulating. Specific examples of porous sheets include microporous thin films, woven fabrics, and nonwoven fabrics. Preferred materials for separator 13 include polyolefin resins such as polyethylene and polypropylene, and cellulose. Separator 13 may have either a single-layer structure or a laminated structure. A heat-resistant layer or the like may be formed on the surface of separator 13.

 図1に示すように、電池10は、円環状の絶縁板18を電極体14の上側に備える。正極11に取り付けられた正極リード20は、絶縁板18の貫通孔を通って封口体17側に伸びる。封口体17は、正極集電板26と、端子キャップ27を有する。正極集電板26は、金属製で円環状の板部材であり、径方向の中央部に貫通孔26aを有する。 As shown in FIG. 1, the battery 10 has a circular insulating plate 18 on the upper side of the electrode body 14. The positive electrode lead 20 attached to the positive electrode 11 passes through a through-hole in the insulating plate 18 and extends toward the sealing body 17. The sealing body 17 has a positive electrode current collector 26 and a terminal cap 27. The positive electrode current collector 26 is a circular metal plate member with a through-hole 26a in its radial center.

 端子キャップ27は貫通孔を有さない金属製の板状部材であり、封口体17の軸方向上側に位置する。端子キャップ27の軸方向上側の端面は、外縁部を除いて外部に露出し、当該露出部分が正極端子を構成する。封口体17は、更に金属板25を有する。金属板25は、金属製の円環状部材であり、貫通孔を有する。 The terminal cap 27 is a metal plate-shaped member with no through holes and is located axially above the sealing body 17. The axially upper end face of the terminal cap 27 is exposed to the outside except for the outer edge, and this exposed portion forms the positive electrode terminal. The sealing body 17 further has a metal plate 25. The metal plate 25 is a metal annular member with a through hole.

 各正極リード20は、正極11から正極集電板26の貫通孔26aを経由して、正極集電板26の上面に沿うように折り曲げられる。各正極リード20の先端部は、正極集電板26の上面と金属板25の下面とで挟まれた状態になっている。各正極リード20は、正極集電板26の上面に接合される。正極集電板26と金属板25も接合され、各正極リード20と金属板25も接合される。これらの接合は、例えば、各正極リード20の先端部を正極集電板26と金属板25で挟んだ状態で、上側から金属板25に軸方向にレーザ光を照射してレーザ溶接することで実現できる。正極リード20の先端部を正極集電板26と金属板25で挟んだ状態でレーザ溶接することで、正極リード20を確実かつ容易に正極集電板26に溶接できて、接合できる。 Each positive electrode lead 20 passes from the positive electrode 11 through the through hole 26a of the positive electrode collector plate 26 and is bent along the upper surface of the positive electrode collector plate 26. The tip of each positive electrode lead 20 is sandwiched between the upper surface of the positive electrode collector plate 26 and the lower surface of the metal plate 25. Each positive electrode lead 20 is bonded to the upper surface of the positive electrode collector plate 26. The positive electrode collector plate 26 and the metal plate 25 are also bonded, and each positive electrode lead 20 and the metal plate 25 are also bonded. These bonds can be achieved, for example, by laser welding the tip of each positive electrode lead 20 sandwiched between the positive electrode collector plate 26 and the metal plate 25 by irradiating the metal plate 25 with a laser beam in the axial direction from above. By laser welding the tip of the positive electrode lead 20 sandwiched between the positive electrode collector plate 26 and the metal plate 25, the positive electrode lead 20 can be reliably and easily welded and bonded to the positive electrode collector plate 26.

 封口体17は、端子キャップ27と正極集電板26が積層された積層部30を外周縁部に有する。積層部30に上側からレーザ光を照射することで、端子キャップ27と正極集電板26が、レーザ溶接され、電気的に接続される。正極集電板26の環状の上面は、積層部30よりも径方向内側に環状の凹部31を有する。正極集電板26の上面が下側に窪んだ凹部31を有するため、端子キャップ27と正極集電板26の凹部31との間に、空間が設けられる。各正極リード20は、凹部31内で正極集電板26に接合される。正極集電板26は金属板25に接合されなくてもよく、正極リード20は、金属板25に接合されなくてもよい。また、電池は、金属板25を有さなくてもよい。また、正極リード20は、正極集電板26の下面に接合されてもよい。 The sealing body 17 has a laminated portion 30 on its outer periphery, in which a terminal cap 27 and a positive current collector plate 26 are laminated. By irradiating the laminated portion 30 with a laser beam from above, the terminal cap 27 and the positive current collector plate 26 are laser-welded and electrically connected. The annular upper surface of the positive current collector plate 26 has an annular recess 31 radially inward from the laminated portion 30. Because the upper surface of the positive current collector plate 26 has the recess 31 recessed downward, a space is provided between the terminal cap 27 and the recess 31 of the positive current collector plate 26. Each positive electrode lead 20 is joined to the positive current collector plate 26 within the recess 31. The positive electrode collector plate 26 does not have to be joined to the metal plate 25, and the positive electrode lead 20 does not have to be joined to the metal plate 25. The battery does not have to have a metal plate 25. The positive electrode lead 20 may also be joined to the underside of the positive current collector plate 26.

 電池10は、電極体14よりも軸方向下側に金属製の負極集電板19を有する。図3は、負極集電板19の斜視図であり、図4は、負極集電板19を下側から見たときの平面図である。図3及び図4に示すように、負極集電板19は、径方向中央部に平面視が略円形の平板部51を有する。平板部51は、円形以外の如何なる平板形状でもよく、例えば、矩形の形状等でもよい。また、負極集電板19は、平板部51に繋がる複数の径方向延在部53を有し、本実施形態では、4つの径方向延在部53を有する。径方向延在部53は、柱形状を有し、径方向に延在する。複数の径方向延在部53が、周方向に等間隔に配置されることが好ましい。 The battery 10 has a metallic negative electrode current collector 19 axially below the electrode body 14. Figure 3 is a perspective view of the negative electrode current collector 19, and Figure 4 is a plan view of the negative electrode current collector 19 as viewed from below. As shown in Figures 3 and 4, the negative electrode current collector 19 has a flat plate portion 51 that is approximately circular in plan view in its radial center. The flat plate portion 51 may have any flat plate shape other than circular, such as a rectangular shape. The negative electrode current collector 19 also has multiple radially extending portions 53 connected to the flat plate portion 51; in this embodiment, there are four radially extending portions 53. The radially extending portions 53 have a columnar shape and extend radially. It is preferable that the multiple radially extending portions 53 be arranged at equal intervals around the circumference.

 図1に示すように、径方向延在部53は、段部54を介して平板部51に繋がり、平板部51の底面は、径方向延在部53の底面よりも下側に位置する。このようにすることで、後述する平板部51の接合の際に平板部51の底面を外装缶16の底部68の内面に隙間なく密着させることができ、平板部51の良好な接合を実現し易くなる。図3に示すように、径方向延在部53は、上側に突条部56を有する。突条部56は、径方向延在部53の幅方向中央に設けられて、厚さ方向に突出する。突条部56は、径方向に延在する。径方向延在部53の下面における突条部56に厚さ方向に重なる箇所には、径方向に延在する溝部57が設けられる。径方向延在部53の下面における幅方向中央部を径方向の所定距離だけ、厚さ方向上側にプレス加工する。このプレス加工で、突条部56及び溝部57が形成される。 1, the radially extending portion 53 is connected to the flat portion 51 via a step portion 54, and the bottom surface of the flat portion 51 is located lower than the bottom surface of the radially extending portion 53. By doing so, when joining the flat portion 51 as described below, the bottom surface of the flat portion 51 can be tightly adhered to the inner surface of the bottom 68 of the outer can 16 without any gaps, making it easier to achieve good joining of the flat portion 51. As shown in FIG. 3, the radially extending portion 53 has a protrusion portion 56 on its upper side. The protrusion portion 56 is provided in the widthwise center of the radially extending portion 53 and protrudes in the thickness direction. The protrusion portion 56 extends in the radial direction. A groove portion 57 extending in the radial direction is provided at a location on the underside of the radially extending portion 53 that overlaps the protrusion portion 56 in the thickness direction. The widthwise center portion of the underside of the radially extending portion 53 is pressed upward in the thickness direction by a predetermined radial distance. This press forming process forms the protrusions 56 and grooves 57.

 突条部56には、負極芯体露出部41(図2参照)が接合される。詳しくは、電極体14の下側端部を構成する負極芯体露出部41を突条部56に押圧した状態で、レーザ光を下側から溝部57の底に向けて照射する。このレーザ光の照射により電極体14の負極芯体露出部41が径方向の広範囲に亘ってレーザ溶接で突条部56に接合される。 The negative electrode core exposed portion 41 (see Figure 2) is joined to the protrusion portion 56. More specifically, while the negative electrode core exposed portion 41, which constitutes the lower end of the electrode body 14, is pressed against the protrusion portion 56, laser light is irradiated from below toward the bottom of the groove portion 57. This laser light irradiation joins the negative electrode core exposed portion 41 of the electrode body 14 to the protrusion portion 56 by laser welding over a wide radial area.

 その後、電極体14の中空部14a(図1参照)に上側から挿入された押え棒(図示せず)で平板部51の上面を外装缶16の底部68の内面に押圧した状態で、外装缶16の下側からレーザ光を照射することで、底部68を負極集電板19にレーザ溶接で接合する。これにより、電極体14の負極12が負極集電板19を介して外装缶16に電気的に接続される。負極芯体露出部41を広範囲に亘って負極集電板19の上面に接合することで、電流が長尺状の負極12の負極長手方向に沿って長い距離流れることを抑制でき、電池10の電気抵抗を低減できる。 Then, a presser rod (not shown) inserted from above into the hollow portion 14a of the electrode body 14 (see Figure 1) presses the upper surface of the flat portion 51 against the inner surface of the bottom portion 68 of the outer can 16. With this in place, laser light is irradiated from below the outer can 16 to laser-weld the bottom portion 68 to the negative electrode current collector plate 19. This electrically connects the negative electrode 12 of the electrode body 14 to the outer can 16 via the negative electrode current collector plate 19. By joining the negative electrode core exposed portion 41 over a wide area to the upper surface of the negative electrode current collector plate 19, it is possible to prevent current from flowing long distances along the longitudinal direction of the elongated negative electrode 12, thereby reducing the electrical resistance of the battery 10.

 図1に示すように、外装缶16は、筒状部39と底部68を有し、筒状部39は、環状の溝入部22と、環状の肩部29を含む。溝入部22は、筒状部39の一部を、スピニング加工して周方向全周に亘って径方向内側に窪ませることで形成される。封口体17は、溝入部22上に配置され、樹脂製のガスケット28を介して外装缶16の開口部にかしめ固定される。肩部29は、筒状部39の上端部を径方向内側に折り曲げて封口体17の外縁部にかしめる際に形成され、筒状部39の上端部において径方向内側に伸びる。 As shown in FIG. 1, the outer can 16 has a cylindrical portion 39 and a bottom portion 68, and the cylindrical portion 39 includes an annular grooved portion 22 and an annular shoulder portion 29. The grooved portion 22 is formed by spinning a portion of the cylindrical portion 39 to recess it radially inward around the entire circumferential direction. The sealing body 17 is placed on the grooved portion 22 and is crimped and fixed to the opening of the outer can 16 via a resin gasket 28. The shoulder portion 29 is formed when the upper end of the cylindrical portion 39 is bent radially inward and crimped to the outer edge of the sealing body 17, and extends radially inward at the upper end of the cylindrical portion 39.

 外装缶16と、封口体17との間が環状のガスケット28で密封されることで、電池10の内部空間が密閉される。ガスケット28は、外装缶16と封口体17に挟持され、封口体17を外装缶16に対して絶縁する。ガスケット28は、電池内部の気密性を保つためのシール材の役割と、外装缶16と封口体17を絶縁する絶縁材としての役割を有する。正極リード20に電気的に接続された端子キャップ27が正極端子となり、負極芯体露出部41に負極集電板19を介して電気的に接続された外装缶16が負極端子となる。 The internal space of the battery 10 is sealed by sealing the space between the outer can 16 and the sealing body 17 with an annular gasket 28. The gasket 28 is sandwiched between the outer can 16 and the sealing body 17, and insulates the sealing body 17 from the outer can 16. The gasket 28 serves as a sealant to maintain airtightness inside the battery, and as an insulating material to insulate the outer can 16 from the sealing body 17. The terminal cap 27 electrically connected to the positive electrode lead 20 serves as the positive electrode terminal, and the outer can 16 electrically connected to the negative electrode core exposed portion 41 via the negative electrode current collector plate 19 serves as the negative electrode terminal.

 電池10は、外装缶16の底部68に薄肉の易破断部68aを有する。易破断部68aは、例えば、底部68の下面に円形やC字形状の刻印を施すことで形成される。底部68に易破断部68aを設けると、電池10が異常発熱したときに、易破断部68aが破断することで電池10内の高温のガスを外部に排出させことができ、電池10の安全性が高くなる。薄肉の易破断部は、端子キャップに設けられてもよい。 The battery 10 has a thin, easily breakable portion 68a on the bottom 68 of the outer can 16. The easily breakable portion 68a is formed, for example, by stamping a circle or C-shape on the underside of the bottom 68. By providing the easily breakable portion 68a on the bottom 68, if the battery 10 generates abnormal heat, the easily breakable portion 68a will break, allowing high-temperature gas inside the battery 10 to be released to the outside, thereby increasing the safety of the battery 10. The thin, easily breakable portion may also be provided on the terminal cap.

 封口体17が、ラプチャー板を有さず、外装缶の底部68に易破断部68aを設ける場合について説明した。しかし、外装缶の底部は、易破断部を有さなくてもよい。封口体は、2枚のラプチャー板(下弁体及び上弁体)と、ラプチャー板を覆う凸状の端子キャップとを備えてもよい。又は、封口体は、ラプチャー板のみで構成されてもよく、又は、電極体側から順に、内部端子板、絶縁板、及びラプチャー板が積層された構造を有してもよい。 In the above description, the sealing body 17 does not have a rupture plate, and an easily breakable portion 68a is provided on the bottom 68 of the outer can. However, the bottom of the outer can does not have to have an easily breakable portion. The sealing body may also have two rupture plates (a lower valve body and an upper valve body) and a convex terminal cap that covers the rupture plates. Alternatively, the sealing body may be composed of only a rupture plate, or may have a structure in which an internal terminal plate, an insulating plate, and a rupture plate are stacked in this order from the electrode body side.

 次に、上記電池10における電極体14と負極集電板19の接合方法について詳細に説明する。図5は、電極体14と負極集電板19の溶接前(溶接工程前)に、電極体14の下側端部を構成する負極芯体露出部41に対して施す前加工について説明する模式図である。なお、以下で、単に、溶接、溶接時と言及した場合、溶接は、電極体14と負極集電板19の溶接を表し、溶接時は、電極体14と負極集電板19の溶接時を表す。 Next, a method for joining the electrode body 14 and the negative electrode current collector plate 19 in the battery 10 will be described in detail. Figure 5 is a schematic diagram illustrating the pre-processing performed on the negative electrode core exposed portion 41 that constitutes the lower end of the electrode body 14 before welding the electrode body 14 and the negative electrode current collector plate 19 together (before the welding process). Note that below, when simply referring to welding or during welding, welding refers to the welding of the electrode body 14 and the negative electrode current collector plate 19, and during welding refers to the welding of the electrode body 14 and the negative electrode current collector plate 19.

 当該前加工では、先ず、負極芯体露出部41を径方向内側に折り曲げる折り曲げ加工(折り曲げ工程)を行う。図5(a)は、折り曲げ加工を説明する平面図であり、折り曲げ加工を行っている最中の電極体14を高さ方向下側(軸方向下側)から見たときの平面図である。 In this pre-processing, first, a bending process (bending step) is performed to bend the negative electrode substrate exposed portion 41 radially inward. Figure 5(a) is a plan view illustrating the bending process, showing the electrode body 14 as it is being bent, viewed from below in the height direction (below in the axial direction).

 図5(a)を参照して、折り曲げ加工における負極芯体露出部41の径方向内側への折り曲げは、次のように行う。先ず、電極体14を図示しない保持装置により3次元空間の所定位置に固定する。次に、図示しない複数のリニアアクチュエータを用いて複数の平板状の折曲板80,81を電極体高さ方向に略直交する平面上で電極体14の径方向外側から径方向内側に移動させる。このとき折曲板80,81を負極芯体露出部41に接触する高さ位置で移動させる。このようにして、負極芯体露出部41を径方向内側に倒して径方向内側に折り曲げ、径方向内側に癖付けする。 Referring to Figure 5(a), the bending of the negative electrode substrate exposed portion 41 radially inward during the bending process is performed as follows. First, the electrode body 14 is fixed at a predetermined position in three-dimensional space by a holding device (not shown). Next, multiple flat bending plates 80, 81 (not shown) are moved from the radially outer side to the radially inner side of the electrode body 14 on a plane approximately perpendicular to the height direction of the electrode body using multiple linear actuators (not shown). At this time, the bending plates 80, 81 are moved at a height position where they come into contact with the negative electrode substrate exposed portion 41. In this way, the negative electrode substrate exposed portion 41 is tilted radially inward, bent radially inward, and flexed radially inward.

 本実施形態では、4つの第1折曲板80と4つの第2折曲板81を用いて負極芯体露出部41の径方向内側への折り曲げを行う。4つの第1折曲板80は、細長い長方形の平面形状を有する。4つの第1折曲板80は、周方向に等間隔に配置され、図5(a)において第1折曲板80の中心軸80aが電極体14の径方向に略一致する状態で、第1折曲板80は、電極体14の径方向外側から径方向内側に移動する。 In this embodiment, four first bending plates 80 and four second bending plates 81 are used to bend the negative electrode core exposed portion 41 radially inward. The four first bending plates 80 have a long, narrow rectangular planar shape. The four first bending plates 80 are arranged at equal intervals in the circumferential direction, and in Figure 5(a), with the central axis 80a of the first bending plate 80 approximately aligned with the radial direction of the electrode body 14, the first bending plate 80 moves from the radially outer side to the radially inner side of the electrode body 14.

 他方、第2折曲板81の先端部81aは、頂角が90度の直角二等辺三角形の形状を有する。図5(a)において直角二等辺三角形の二等分線81bの延長線が第1折曲板80の中心軸80aと略45度をなしている状態で、第2折曲板81は、電極体14の径方向外側から径方向内側に移動する。第2折曲板81の移動によって、周方向に隣り合う第1折曲板80の移動領域に挟まれた周方向領域の一部の負極芯体露出部41が、径方向内側へ倒されて折り曲げられ、径方向内側に癖付けされる。 On the other hand, the tip 81a of the second folded plate 81 has the shape of a right-angled isosceles triangle with an apex angle of 90 degrees. In Figure 5(a), when the extension line of the bisector 81b of the right-angled isosceles triangle forms approximately 45 degrees with the central axis 80a of the first folded plate 80, the second folded plate 81 moves from the radially outer side to the radially inner side of the electrode body 14. As the second folded plate 81 moves, a portion of the negative electrode core exposed portion 41 in the circumferential region sandwiched between the movement regions of the circumferentially adjacent first folded plates 80 is bent and tilted radially inward, and is formed radially inward.

 8つの折曲板80,81は、同時に径方向外側から径方向内側に移動してもよく、4つの第1折曲板80が、径方向外側から径方向内側に移動した後に、4つの第2折曲板81が、径方向外側から径方向内側に移動してもよい。又は、4つの第2折曲板81が、径方向外側から径方向内側に移動した後に、4つの第1折曲板80が、径方向外側から径方向内側に移動してもよい。 The eight folded plates 80, 81 may simultaneously move from the radially outer side to the radially inner side, or the four first folded plates 80 may move from the radially outer side to the radially inner side, and then the four second folded plates 81 may move from the radially outer side to the radially inner side. Or, the four second folded plates 81 may move from the radially outer side to the radially inner side, and then the four first folded plates 80 may move from the radially outer side to the radially inner side.

 図5(b)は、折り曲げ加工後の電極体14の負極芯体露出部41側の第1端面85の状態を示す平面図である。図5(b)において、薄いグレーで示す領域46は、径方向内側に折り曲げられた負極芯体露出部41が存在する領域を示し、濃いグレーで示す領域47は、薄いグレーで示す領域46よりも高さ方向下側に盛り上がって下側に突出した負極芯体露出部41が存在する領域を示す。濃いグレーで示す領域47は、負極芯体露出部41の密度が高く、硬い領域である。図5(b)に示すように、折り曲げ加工後における電極体14の第1端面85には、4つの略V字状の負極芯体露出部41の盛り上がり部(濃いグレーで示す領域47)が存在する。 FIG. 5(b) is a plan view showing the state of the first end surface 85 on the negative electrode core exposed portion 41 side of the electrode body 14 after bending. In FIG. 5(b), the light gray region 46 indicates the region where the negative electrode core exposed portion 41 bent radially inward is present, and the dark gray region 47 indicates the region where the negative electrode core exposed portion 41 is present, protruding downward in the height direction from the light gray region 46. The dark gray region 47 is a region where the negative electrode core exposed portion 41 is denser and harder. As shown in FIG. 5(b), four approximately V-shaped protruding portions of the negative electrode core exposed portion 41 (dark gray regions 47) are present on the first end surface 85 of the electrode body 14 after bending.

 折り曲げ加工が終了すると、第1端面85の一部のみに高さ方向の荷重を付与する一部荷重付与加工(一部荷重付与工程)を行う。図5(c)に示す例では、第1端面85を四分割したときに右上に位置する第1領域85aと左下に位置する第3領域85cのみに荷重付与を行い、右下に位置する第2領域85bと左上に位置する第4領域85dには、荷重付与を行わない。各領域85a,85b,85c,85dは、同一の形状及び大きさを有し、平面視において扇形状を有する。各領域85a,85b,85c,85dの内周側の内縁と外周側の外縁は、同心の円弧形状を有している。 Once the bending process is complete, a partial load application process (partial load application step) is performed, in which a load in the height direction is applied only to a portion of the first end face 85. In the example shown in Figure 5(c), when the first end face 85 is divided into four, a load is applied only to the first region 85a located at the upper right and the third region 85c located at the lower left, and no load is applied to the second region 85b located at the lower right and the fourth region 85d located at the upper left. Each of the regions 85a, 85b, 85c, and 85d has the same shape and size, and is fan-shaped in plan view. The inner edge on the inner periphery and the outer edge on the outer periphery of each of the regions 85a, 85b, 85c, and 85d have concentric arc shapes.

 このような一部荷重付与は、例えば、図8に示す製造装置60で行うことができる。なお、図8の製造装置60の説明にあたり、図6の一部荷重付与工程の説明図を適宜参照する。図6は、理解の容易化のため、製造装置60の一部を省略し、電極体14と押圧プレート62およびプレート取付部63の位置関係を示す。製造装置60は、図6に示す押圧面61と、電極体14を押圧面61に相対移動させて第1端面85の一部のみを押圧面61に押圧させる押圧機構(図8の符号65)を備える。本実施形態では、図6に示すように、押圧面61は、3次元空間の所定位置に設けられた押圧プレート62の片側面で構成され、押圧プレート62は、3次元空間の所定位置に設置されたプレート取付部63に固定される。 Such partial load application can be performed, for example, using the manufacturing apparatus 60 shown in Figure 8. Note that when explaining the manufacturing apparatus 60 in Figure 8, the explanatory diagram of the partial load application process in Figure 6 will be referenced as appropriate. For ease of understanding, Figure 6 omits part of the manufacturing apparatus 60 and shows the positional relationship between the electrode body 14, pressure plate 62, and plate mounting portion 63. The manufacturing apparatus 60 includes the pressure surface 61 shown in Figure 6 and a pressure mechanism (reference numeral 65 in Figure 8) that moves the electrode body 14 relative to the pressure surface 61 to press only a portion of the first end surface 85 against the pressure surface 61. In this embodiment, as shown in Figure 6, the pressure surface 61 is formed by one side of the pressure plate 62 provided at a predetermined position in three-dimensional space, and the pressure plate 62 is fixed to the plate mounting portion 63 provided at a predetermined position in three-dimensional space.

 図6に示すように、プレート取付部63は、電極体14の外径よりも僅かに大きな径を有する円筒孔63aが設けられた板状部で構成される。押圧プレート62は、円筒孔63aの底面に固定手段、例えば、両面テープ、接着剤等で固定される。押圧プレート62は、プレート取付部63に着脱可能になっていてもよく、プレート取付部63と一体に構成されてもよい。 As shown in Figure 6, the plate mounting portion 63 is composed of a plate-shaped portion with a cylindrical hole 63a having a diameter slightly larger than the outer diameter of the electrode body 14. The pressure plate 62 is fixed to the bottom surface of the cylindrical hole 63a with fixing means such as double-sided tape or adhesive. The pressure plate 62 may be detachable from the plate mounting portion 63, or may be configured integrally with the plate mounting portion 63.

 図8に示すように、押圧機構65は、ベースステージ65aと、ベースステージ65a上を図8に矢印Aで示す第1方向に相対移動可能な移動ステージ65bと、移動ステージ65bに設置された保持装置65cを備える。移動ステージ65bはベースステージ65aに対して第1方向に摺動可能になっている。本実施形態では、電極体14が保持装置65cに保持され、移動ステージ65bに固定される。 As shown in FIG. 8, the pressing mechanism 65 includes a base stage 65a, a movable stage 65b that is movable relative to the base stage 65a in a first direction indicated by arrow A in FIG. 8, and a holding device 65c installed on the movable stage 65b. The movable stage 65b is slidable in the first direction relative to the base stage 65a. In this embodiment, the electrode body 14 is held by the holding device 65c and fixed to the movable stage 65b.

 上記第1方向は、プレート取付部63の厚さ方向(押圧プレート62の厚さ方向)に略一致する。保持装置65cに保持された電極体14の中心軸の延長線が図6の円筒孔63aの中心軸に略一致している状態で、移動ステージ65bは、ベースステージ65aに対して第1方向に摺動(相対移動)する。押圧機構65は、リニアアクチュエータを含む押圧装置(図示せず)を備える。押圧装置は、伸縮可能なロッドを有し、ロッドの先端面が、保持装置65cに保持されている電極体14の軸方向における負極芯体露出部41側とは反対側の第2端面を第1方向に所定の力で押圧するようになっている。 The first direction roughly coincides with the thickness direction of the plate mounting portion 63 (thickness direction of the pressing plate 62). With the extension of the central axis of the electrode body 14 held by the holding device 65c roughly coincident with the central axis of the cylindrical hole 63a in Figure 6, the moving stage 65b slides (moves relative to) the base stage 65a in the first direction. The pressing mechanism 65 is equipped with a pressing device (not shown) including a linear actuator. The pressing device has an extendable rod, and the tip surface of the rod presses with a predetermined force in the first direction against a second end face of the electrode body 14 held by the holding device 65c on the side opposite the negative electrode core exposed portion 41 in the axial direction.

 図6に示すように、押圧プレート62は、上記領域85a,85b,85c,85dに対応する平面形状を有する。2枚の押圧プレート62が、円筒孔63a内における第1領域85aと第3領域85cに対応する箇所に固定されている状態で、図8の移動ステージ65bを、図8の(a)~(c)に示すようにベースステージ65aに対して第1方向に相対移動させ、電極体14の第1端面85を円筒孔63a内に固定された2枚の押圧プレート62に押圧する。このようにすることで、電極体14の第1端面85の第1領域85aと第3領域85cのみに荷重付与を行うことができる。 As shown in FIG. 6, the pressure plates 62 have a planar shape corresponding to the above-mentioned regions 85a, 85b, 85c, and 85d. With the two pressure plates 62 fixed in the cylindrical hole 63a at locations corresponding to the first region 85a and third region 85c, the moving stage 65b in FIG. 8 is moved relative to the base stage 65a in the first direction as shown in (a) to (c) of FIG. 8, pressing the first end surface 85 of the electrode body 14 against the two pressure plates 62 fixed in the cylindrical hole 63a. In this way, a load can be applied only to the first region 85a and third region 85c of the first end surface 85 of the electrode body 14.

 第1領域85aと第3領域85cに位置する負極芯体露出部分は、一部荷重付与加工で電極体14の高さ方向中心側に押し潰される。このため、図5(d)に示すように、一部荷重付与加工後においては、第1領域85aと第3領域85cに位置する負極芯体露出部分は、濃いグレーで示す領域(盛り上がり部)47よりも電極体14の高さ方向中心側に位置する。 The exposed portions of the negative electrode substrate located in the first region 85a and the third region 85c are crushed toward the center of the height direction of the electrode body 14 during the partial load application process. Therefore, as shown in Figure 5(d), after the partial load application process, the exposed portions of the negative electrode substrate located in the first region 85a and the third region 85c are located closer to the center of the height direction of the electrode body 14 than the region (raised portion) 47 shown in dark gray.

 一部荷重付与加工が終了すると、負極芯体露出部41を負極集電板19に溶接する。図7は、その溶接を行う溶接装置90の構造と、当該溶接方法について説明するための図である。図7に示すように、溶接装置90は、金属プレート91と、押圧機構92を備える。金属プレート91は、3次元空間の所定箇所に設置されており、該所定箇所で静止している。また、押圧機構92は、ベースステージ92aと、ベースステージ92a上を図7に矢印Bで示す方向に相対移動可能な移動ステージ92bと、移動ステージ92b上に設置された保持装置92cと、押圧装置(図示せず)を有する。 Once the partial load application process is complete, the negative electrode substrate exposed portion 41 is welded to the negative electrode current collector plate 19. Figure 7 is a diagram illustrating the structure of a welding device 90 used to perform this welding, and the welding method. As shown in Figure 7, the welding device 90 includes a metal plate 91 and a pressing mechanism 92. The metal plate 91 is installed at a predetermined location in three-dimensional space and remains stationary at that location. The pressing mechanism 92 also includes a base stage 92a, a movable stage 92b that is movable relative to the base stage 92a in the direction indicated by arrow B in Figure 7, a holding device 92c installed on the movable stage 92b, and a pressing device (not shown).

金属プレート91は、たとえば矩形状であり、厚み方向に1又は複数のスリットを有する。負極集電板19(図3参照)は、4つの溝部57がスリットに金属プレート91の厚さ方向に重なるように金属プレート91の片側面に磁石で固定される。 The metal plate 91 is, for example, rectangular and has one or more slits in the thickness direction. The negative electrode current collector 19 (see Figure 3) is fixed to one side of the metal plate 91 with a magnet so that the four grooves 57 overlap the slits in the thickness direction of the metal plate 91.

 負極集電板19を金属プレート91に固定した状態で、電極体14の軸方向の負極芯体露出部側とは反対側(軸方向の非溶接側)の第2端面86を押圧して、第1端面85を負極集電板19の突条部56形成側の端面に所定の力で押圧する。 With the negative electrode current collector 19 fixed to the metal plate 91, the second end face 86 on the axial side of the electrode body 14 opposite the exposed negative electrode core portion (the non-welded side in the axial direction) is pressed, and the first end face 85 is pressed with a predetermined force against the end face of the negative electrode current collector 19 on the side where the protrusion portion 56 is formed.

 電極体14の第2端面86に付与された荷重は、金属プレート91が受け、作用反作用の法則により電極体14の第1端面85に付与される。その押圧の際、負極芯体露出部41のうちで4つの第1折曲板80(図5(a)参照)で径方向内側に倒されて癖付けされた癖付部分が、突条部56に押圧されるようにする。 The load applied to the second end surface 86 of the electrode body 14 is received by the metal plate 91 and transferred to the first end surface 85 of the electrode body 14 according to the law of action and reaction. During this pressure, the bent portions of the negative electrode substrate exposed portion 41 that have been bent radially inward by the four first bent plates 80 (see Figure 5(a)) are pressed against the protrusion portions 56.

 癖付部分を突条部56に押圧している状態で、金属プレート91における負極集電板19の固定側とは反対側からスリット向けてレーザ光を出射してレーザ光を負極集電板19の溝部57に照射する。このレーザ光の照射によって上記癖付部分を突条部56にレーザ溶接することで、電極体14が負極集電板19に接合されて負極集電板19と一体化される。レーザ溶接の際、レーザ光照射箇所でスパッタが生じる。金属プレート91は、そのスパッタが電極体14側に飛散することを抑制する。 With the formed portion pressed against the protrusion 56, a laser beam is emitted toward the slit from the side of the metal plate 91 opposite the fixed side of the negative current collector plate 19, irradiating the groove 57 of the negative current collector plate 19. This laser beam welds the formed portion to the protrusion 56, thereby joining the electrode body 14 to the negative current collector plate 19 and integrating them. During laser welding, spatter occurs at the point irradiated with the laser beam. The metal plate 91 prevents this spatter from scattering toward the electrode body 14.

 次に、本件発明者が見出した課題と、本開示の技術の作用効果について図9を用いて説明する。電極体の軸方向の第1端部を負極芯体露出部で構成して、その負極芯体露出部を負極集電板に溶接した後、負極集電板を外装缶の底部に溶接すると、負極における長手方向の広範な領域を負極集電板に確実かつ安定的に電気的に接続することができる。 Next, the problem discovered by the inventors and the effects of the technology disclosed herein will be explained using Figure 9. By configuring the first axial end of the electrode body as a negative electrode substrate exposed portion, welding this negative electrode substrate exposed portion to the negative electrode current collector plate, and then welding the negative electrode current collector plate to the bottom of the outer can, a wide longitudinal area of the negative electrode can be reliably and stably electrically connected to the negative electrode current collector plate.

 また、負極芯体露出部を負極集電板に溶接する際には、電極体の軸方向の第2端部に軸方向に荷重を印加することで負極芯体露出部を負極集電板に押圧して負極芯体露出部を負極集電板に当接させた状態で、負極集電板の外側からレーザ光を照射することによって、負極集電板と負極芯体露出部を溶接する。 Furthermore, when welding the exposed portion of the negative electrode substrate to the negative electrode current collector plate, an axial load is applied to the second axial end of the electrode body to press the exposed portion of the negative electrode substrate against the negative electrode current collector plate, bringing the exposed portion of the negative electrode substrate into contact with the negative electrode current collector plate. Laser light is then irradiated from the outside of the negative electrode current collector plate to weld the negative electrode current collector plate and the exposed portion of the negative electrode substrate.

 係る背景において、負極芯体露出部を負極集電板に確実かつ安定に溶接するために負極芯体露出部を負極集電板に確実に当接させる必要があり、電極体の第2端部に良好な当接性確保に必要な荷重を付与する必要がある。 In this context, in order to reliably and stably weld the exposed portion of the negative electrode substrate to the negative electrode current collector plate, it is necessary to ensure that the exposed portion of the negative electrode substrate is in secure contact with the negative electrode current collector plate, and it is necessary to apply the load required to ensure good contact to the second end of the electrode body.

 一方、当接性確保に必要な荷重を電極体の第2端部に付与すると、電極に不必要な荷重が加わる虞がある。この課題は、次に挙げる例に限定して生ずるものではないが、例えば以下の場合にも顕著な課題となる。すなわち、電極体を巻き芯に巻き取る際、電極(正極、負極)が蛇行することがあり、図9に示すように、蛇行によって電極211,212が局所的に軸方向外側に飛び出ている場合がある。たとえば図9は、電極212の一部、つまり電極部分212aが局所的に軸方向外側に飛び出ている状態を示す。このような場合、上述の当接性確保に必要な荷重を電極体214の第2端部に付与すると、軸方向外側に飛び出た電極部分212aに不必要な荷重が加わる虞がある。 On the other hand, if the load necessary to ensure contact is applied to the second end of the electrode body, there is a risk that unnecessary load will be applied to the electrode. This issue is not limited to the following example, but it also becomes a significant problem in the following cases, for example. That is, when the electrode body is wound onto the winding core, the electrodes (positive and negative electrodes) may meander, and as shown in Figure 9, this meandering may cause electrodes 211 and 212 to locally protrude outward in the axial direction. For example, Figure 9 shows a state in which a part of electrode 212, i.e., electrode portion 212a, locally protrudes outward in the axial direction. In such a case, if the load necessary to ensure the above-mentioned contact is applied to the second end of electrode body 214, there is a risk that unnecessary load will be applied to electrode portion 212a protruding outward in the axial direction.

 これに対し、本開示の技術によれば、上述の一部荷重付与加工によって、電極体14の下側端部を構成する負極芯体露出部41の一部に溶接前に事前に荷重が印加され、負極芯体露出部41の一部が、溶接前に事前に電極体14の高さ方向中央側に潰される。また、一部荷重付与加工で潰す負極芯体露出部部分は、負極芯体露出部41の一部であるので、一部荷重付与加工で電極体14に付与する荷重は、負極芯体露出部41の全てを潰す際に必要となる荷重よりも小さくなる。 In contrast, according to the technology disclosed herein, a load is applied in advance to a portion of the negative electrode substrate exposed portion 41 that constitutes the lower end of the electrode body 14 by the partial load application process described above, before welding, and the portion of the negative electrode substrate exposed portion 41 is crushed toward the center in the height direction of the electrode body 14 in advance before welding. Furthermore, because the portion of the negative electrode substrate exposed portion that is crushed by the partial load application process is only a portion of the negative electrode substrate exposed portion 41, the load applied to the electrode body 14 by the partial load application process is smaller than the load that would be required to crush the entire negative electrode substrate exposed portion 41.

 更には、負極芯体露出部41を負極集電板19に溶接する際に、電極体14に付与する荷重は、負極芯体露出部41のうちで一部荷重付与加工において荷重が付与されなかった部分を電極体14の高さ方向中央側に潰すのに必要な荷重でよく、当該荷重で当該部分を優先的に電極体14の高さ方向中央側に潰すことができる。 Furthermore, when welding the negative electrode substrate exposed portion 41 to the negative electrode current collector plate 19, the load applied to the electrode body 14 need only be the load necessary to crush the portion of the negative electrode substrate exposed portion 41 to which no load was applied during the partial load application process toward the center of the height of the electrode body 14, and this load can be used to preferentially crush this portion toward the center of the height of the electrode body 14.

 したがって、負極芯体露出部41を負極集電板19に溶接する際に電極体14に付与する荷重も、負極芯体露出部41の全てを潰す際に必要となる荷重よりも小さくなる。よって、本開示の技術によれば、互いにトレードオフの関係にある、負極芯体露出部41を負極集電板19に確実かつ安定に溶接できるという作用効果と、電極体14の軸方向の負極芯体露出部41側とは反対側の電極端部(正極11端部,負極12端部)に不必要な荷重がかかるのを抑制できるという作用効果を同時に実現できるという格別かつ顕著な作用効果を奏することができる。 Therefore, the load applied to the electrode assembly 14 when welding the negative electrode substrate exposed portion 41 to the negative electrode current collector plate 19 is also smaller than the load required to crush the entire negative electrode substrate exposed portion 41. Therefore, the technology disclosed herein can simultaneously achieve the exceptional and significant effect of reliably and stably welding the negative electrode substrate exposed portion 41 to the negative electrode current collector plate 19, which are in a trade-off relationship, and suppressing the application of unnecessary load to the electrode ends (positive electrode 11 end, negative electrode 12 end) on the axial side of the electrode assembly 14 opposite the negative electrode substrate exposed portion 41.

 本実施形態では、電極体14の第1端面85を構成する負極芯体露出部41のうちの略半分のみに溶接前に荷重を付与するため、負極芯体露出部41の全てを潰す際に必要となる荷重をN荷重とすると、一部荷重付与工程で必要になる荷重と、溶接工程で必要となる荷重を共にN/2荷重程度の荷重とすることができる。つまり、本実施形態によれば、電極体14の負極芯体露出部41側とは反対側の電極端部に付与される荷重を半分程度の荷重まで急激に低減できる。 In this embodiment, a load is applied before welding to only approximately half of the negative electrode substrate exposed portion 41 that constitutes the first end surface 85 of the electrode body 14. Therefore, if the load required to crush the entire negative electrode substrate exposed portion 41 is defined as load N, the load required in the partial load application process and the load required in the welding process can both be approximately load N/2. In other words, according to this embodiment, the load applied to the electrode end portion on the opposite side of the electrode body 14 from the negative electrode substrate exposed portion 41 can be rapidly reduced to approximately half the load.

 図6に示すように、一部荷重付与工程を第1端面85の一部のみを押圧面61で押圧することで行い、溶接工程において溶接を行う負極芯体露出部41の溶接箇所に対応する押圧面61の対応箇所に凸部62aが設けられることが好ましい。本実施形態では、凸部62aが突条部で構成され、凸部62aは押圧プレート62の扇形状の押圧面61を二等分する二等分線上を延在する。凸部62aは、負極集電板19の突条部56(図3参照)に接合される負極芯体露出部部分を押圧するために設けられる。 As shown in FIG. 6, the partial load application process is preferably performed by pressing only a portion of the first end surface 85 with the pressing surface 61, and a protrusion 62a is preferably provided on the pressing surface 61 at a location corresponding to the welding location of the negative electrode substrate exposed portion 41 to be welded in the welding process. In this embodiment, the protrusion 62a is formed as a ridge portion, and extends on a bisector that bisects the fan-shaped pressing surface 61 of the pressing plate 62. The protrusion 62a is provided to press the negative electrode substrate exposed portion that is joined to the ridge portion 56 of the negative electrode current collector plate 19 (see FIG. 3).

 上述のように、平板状の折曲板80,81で負極芯体露出部41を径方向内側に倒して径方向内側に折り曲げると、硬い盛り上がり部(濃いグレーで示す領域47)が生じる。この盛り上がり部は、荷重をかけても潰れにくいので、この盛り上がり部が溶接部側に倒れると良好な溶接を行い難くなる。押圧面61に凸部(突条部)62aを設けることで、盛り上がり部が溶接部側へ倒れることを効果的に抑制できる。 As described above, when the negative electrode substrate exposed portion 41 is bent radially inward using the flat folding plates 80, 81, a hard raised portion (area 47 shown in dark gray) is created. This raised portion is not easily crushed even when a load is applied, so if this raised portion falls toward the welded portion, it becomes difficult to perform a good weld. By providing a convex portion (protruding portion) 62a on the pressing surface 61, it is possible to effectively prevent the raised portion from falling toward the welded portion.

 押圧面61が、第1端面85において最内周に位置する電極に電極体高さ方向に重ならないことが好ましく、一部荷重付与加工において第1端面85において径方向の最内周に位置する電極よりも径方向の外方に位置する領域の一部のみに高さ方向の荷重を付与することが好ましい。電極体14を巻き芯に巻回する際、巻き始め側の極板が蛇行し易い傾向にある。そのようにすることで、巻き始め側の極板に不必要に荷重がかかるのを効果的に抑制できる。 It is preferable that the pressing surface 61 does not overlap the electrode located at the innermost periphery on the first end face 85 in the height direction of the electrode body, and in the partial load application process, it is preferable that a load in the height direction is applied only to a portion of the area located radially outward from the electrode located at the innermost periphery on the first end face 85. When winding the electrode body 14 around the winding core, the electrode plate at the start of winding tends to meander. By doing so, it is possible to effectively prevent unnecessary load from being applied to the electrode plate at the start of winding.

 図10は、第1参考例の負極312を長尺状に展開した模式図であり、図11は、第2参考例の負極412を長尺状に展開した模式図である。また、図12は、第2参考例の負極512を長尺状に展開した模式図である。図10乃至図11における斜線領域は、負極合剤層342,442,542が配置されている領域である。 FIG. 10 is a schematic diagram of the negative electrode 312 of the first reference example unfolded into a long strip, and FIG. 11 is a schematic diagram of the negative electrode 412 of the second reference example unfolded into a long strip. Furthermore, FIG. 12 is a schematic diagram of the negative electrode 512 of the second reference example unfolded into a long strip. The shaded areas in FIGS. 10 and 11 are the areas where the negative electrode mixture layers 342, 442, and 542 are arranged.

 図10に示すように、第1参考例の負極312では、負極芯体露出部341が負極長手方向に間隔をおいて設けられている。また、図11に示すように、第2参考例の負極412では、負極芯体露出部441が負極長手方向の両端部に存在しない。また、図12に示すように、第3参考例の負極512では、負極芯体露出部541に切り込み541aが入れられている。これらの場合、負極芯体露出部341,441,541の剛性が低くなるので、負極芯体露出部341,441,541が電極体の軸方向に潰れやすくなり、負極芯体露出部341,441,541を負極集電板19に溶接する際に電極体に付与する荷重を小さくすることができる。 As shown in FIG. 10, in the negative electrode 312 of the first reference example, the negative electrode substrate exposed portions 341 are provided at intervals in the longitudinal direction of the negative electrode. Furthermore, as shown in FIG. 11, in the negative electrode 412 of the second reference example, the negative electrode substrate exposed portions 441 are not present at either end in the longitudinal direction of the negative electrode. Furthermore, as shown in FIG. 12, in the negative electrode 512 of the third reference example, a notch 541a is made in the negative electrode substrate exposed portion 541. In these cases, the rigidity of the negative electrode substrate exposed portions 341, 441, 541 is reduced, making the negative electrode substrate exposed portions 341, 441, 541 more likely to be crushed in the axial direction of the electrode body, and reducing the load applied to the electrode body when welding the negative electrode substrate exposed portions 341, 441, 541 to the negative electrode current collector plate 19.

 これに対し、図2に示すように、本実施形態では、負極芯体露出部41が、負極12の長手方向の巻内端から巻外端まで存在する帯形状を有し、負極芯体露出部41が切り込みを有さない。したがって、負極芯体露出部41の剛性が高くて、負極芯体露出部41が軸方向に潰れにくく、負極芯体露出部41を軸方向に押圧する際に必要になる荷重が大きくなる。したがって、本開示の技術で獲得できる作用効果が顕著なものになる。 In contrast, as shown in Figure 2, in this embodiment, the negative electrode substrate exposed portion 41 has a band shape that extends from the inner end of the winding to the outer end of the winding in the longitudinal direction of the negative electrode 12, and the negative electrode substrate exposed portion 41 does not have any notches. Therefore, the rigidity of the negative electrode substrate exposed portion 41 is high, the negative electrode substrate exposed portion 41 is less likely to be crushed in the axial direction, and the load required to press the negative electrode substrate exposed portion 41 in the axial direction is large. Therefore, the effects achieved by the technology disclosed herein are remarkable.

 本実施形態では、2枚の押圧プレート62が、円筒孔63a内における第1領域85aと第3領域85cに対応する箇所に固定されている状態で、電極体14の第1端面85を2枚の押圧プレート62に押圧することで、一部荷重付与加工を1回行った。しかし、一部荷重付与工程は、電極体の高さ方向の荷重を付与する端面領域を変えて複数回行われてもよい。 In this embodiment, the partial load application process was performed once by pressing the first end surface 85 of the electrode body 14 against the two pressure plates 62 while the two pressure plates 62 were fixed at locations corresponding to the first region 85a and third region 85c within the cylindrical hole 63a. However, the partial load application process may be performed multiple times by changing the end surface region to which the load is applied in the height direction of the electrode body.

 例えば、2枚の押圧プレート62が、円筒孔63a内における第1領域85aと第3領域85cに対応する箇所に固定されている状態で行った一部荷重付与加工(図6参照)の後、図13に示すように、追加の2枚の押圧プレート62を円筒孔63a内における第2領域85bと第4領域85dに対応する箇所に固定した状態で、2回目の一部荷重付与加工を行ってもよい。このようにすると、負極芯体露出部41を負極集電板19に溶接する前に周方向全周において負極芯体露出部41を電極体14の高さ方向中央側に潰すことができるので、負極芯体露出部41を負極集電板19に溶接する際に電極体14に付与する荷重を更に低減でき、電極体14の負極芯体露出部41側とは反対側の電極端部に不要な荷重がかかる可能性を格段に低下させることができる。 For example, after performing the partial load application process (see FIG. 6 ) with two pressure plates 62 fixed in positions corresponding to the first region 85a and the third region 85c within the cylindrical hole 63a, a second partial load application process may be performed with two additional pressure plates 62 fixed in positions corresponding to the second region 85b and the fourth region 85d within the cylindrical hole 63a, as shown in FIG. 13 . In this way, the negative electrode substrate exposed portion 41 can be crushed toward the center in the height direction of the electrode body 14 along the entire circumferential direction before welding the negative electrode substrate exposed portion 41 to the negative electrode current collector plate 19. This further reduces the load applied to the electrode body 14 when welding the negative electrode substrate exposed portion 41 to the negative electrode current collector plate 19, significantly reducing the possibility of unnecessary load being applied to the electrode end of the electrode body 14 on the side opposite the negative electrode substrate exposed portion 41.

 又は、一部荷重付与加工を3回以上行ってもよい。例えば、図14に示すように、一つ前の一部荷重付与加工との比較で、押圧プレート62の数を一つ増やした状態で、一部荷重付与加工を4回行ってもよい。また、この場合において、4つの異なるプレート取付部63を第1方向に直交する矢印Cで示す第2方向に間隔をおいて配置し、一部荷重付与加工を行うステーションを4つ設置してもよい。そして、4回目以外の一部荷重付与加工が完了すると、ベースステージ65aを、ボールねじ、リニアスライダー、又はコンベア等を用いて、次の一部荷重付与加工の加工位置(ステーション)まで第2方向に移動させて、次の一部荷重付与加工を行ってもよい。 Alternatively, partial load applying processing may be performed three or more times. For example, as shown in FIG. 14, partial load applying processing may be performed four times with one more pressing plate 62 than in the previous partial load applying processing. In this case, four different plate mounting portions 63 may be spaced apart in a second direction indicated by arrow C, which is perpendicular to the first direction, to provide four stations for performing partial load applying processing. Then, once partial load applying processing other than the fourth is completed, the base stage 65a may be moved in the second direction using a ball screw, linear slider, conveyor, or the like to the processing position (station) for the next partial load applying processing, and the next partial load applying processing may be performed.

 このようにすると、各回の一部荷重付与加工で電極体14に付与する荷重を、負極芯体露出部41の全てを潰す際に必要となる荷重の1/4程度まで更に急激に低減することができ、電極体14の負極芯体露出部41側とは反対側の電極端部に不必要な荷重がかかるのを略確実に防止することができる。なお、図14に示す4回の一部荷重付与加工を行う機構において、4つの異なるプレート取付部63には、互いに異なる位置に1つのみの押圧プレート62が取り付けられていてもよい。 In this way, the load applied to the electrode body 14 in each partial load application process can be further rapidly reduced to approximately one-quarter of the load required to crush the entire negative electrode substrate exposed portion 41, and it is possible to almost reliably prevent unnecessary load from being applied to the electrode end portion of the electrode body 14 on the side opposite the negative electrode substrate exposed portion 41. In addition, in the mechanism that performs four partial load application processes shown in Figure 14, only one pressing plate 62 may be attached to four different plate attachment portions 63 at mutually different positions.

 本開示は、上記実施形態およびその変形例に限定されるものではなく、本願の特許請求の範囲に記載された事項およびその均等な範囲において種々の改良や変更が可能である。例えば、上記実施形態では、電極体14を静止している押圧面61の方に移動させて、電極体14の第1端面85を押圧面61で押圧する場合について説明した。しかし、押圧面を静止している電極体の第1端面の方に移動させて、第1端面を押圧面で押圧してもよく、一部荷重付与加工の際に、電極体と押圧面の両方が移動して、第1端面が押圧面で押圧される構成でもよい。 The present disclosure is not limited to the above-described embodiment and its variations, and various improvements and modifications are possible within the scope of the claims of the present application and their equivalents. For example, in the above-described embodiment, the electrode body 14 is moved toward the stationary pressing surface 61, and the first end surface 85 of the electrode body 14 is pressed by the pressing surface 61. However, the pressing surface may be moved toward the stationary first end surface of the electrode body and the first end surface may be pressed by the pressing surface, or both the electrode body and the pressing surface may move during partial load application processing, and the first end surface may be pressed by the pressing surface.

 図15は、変形例の電池の製造装置160の構造を説明する模式図である。より詳しくは、図15(a)は、製造装置160のロッド162と、ロッド162に接触する前の電極体14を示す側面図であり、図15(b)は、図15(a)に示す状態のロッド162と電極体14を、電極体14の第1端面85の軸方向外側から見たときの平面図である。 Figure 15 is a schematic diagram illustrating the structure of a modified battery manufacturing apparatus 160. More specifically, Figure 15(a) is a side view showing the rod 162 of the manufacturing apparatus 160 and the electrode body 14 before it comes into contact with the rod 162, and Figure 15(b) is a plan view of the rod 162 and electrode body 14 in the state shown in Figure 15(a) when viewed from the axial outside of the first end surface 85 of the electrode body 14.

 図15(b)に示すように、製造装置160は、マトリクス状に2行2列に配置された4つの同一のロッド162を有する。各ロッド162は、リニアアクチュエータのロッドであり、リニアアクチュエータのケース(図示せず)に対して一方向に伸縮可能になっている。ロッド162の先端面161は、上述の押圧プレート62の押圧面61と同一の構造を有し、凸部62aと同一の構造を有する凸部162aを有する。電極体14の軸方向の第2端面は、静止平面に接触している。また、リニアアクチュエータのケースは、3次元空間の所定位置に移動不可能に固定されている。また、電極体14は、図示しない保持装置でその高さ方向に移動可能に保持されている。この状態で、リニアアクチュエータのロッド162を伸長させることで、ロッド162の先端面161で電極体14の第1端面85の一部領域を押圧する。このようにすると、電極体14の第1端面85に対する先端面161の押圧に伴って、電極体14の第2端面が静止平面に押圧される。 As shown in Figure 15(b), the manufacturing apparatus 160 has four identical rods 162 arranged in two rows and two columns in a matrix. Each rod 162 is a rod of a linear actuator and is extendable in one direction relative to the linear actuator case (not shown). The tip surface 161 of the rod 162 has the same structure as the pressing surface 61 of the above-mentioned pressing plate 62, and has a convex portion 162a having the same structure as the convex portion 62a. The second axial end surface of the electrode body 14 is in contact with a stationary plane. The linear actuator case is fixed immovably at a predetermined position in three-dimensional space. The electrode body 14 is held movably in its height direction by a holding device (not shown). In this state, by extending the rod 162 of the linear actuator, the tip surface 161 of the rod 162 presses a partial area of the first end surface 85 of the electrode body 14. In this way, as the tip surface 161 presses against the first end surface 85 of the electrode body 14, the second end surface of the electrode body 14 is pressed against the stationary plane.

 係る場合において、例えば、2つのロッド162を同時かつ先行的に伸長させた後で、残りの2つのロッド162を同時に伸長させると、上述の2段階の一部荷重付与加工と同等の加工を実現できる。また、4つのロッド162を、時間差を設けて別のタイミングで伸長させると、図14を用いて説明した4段階の一部荷重付与加工と同等の加工を実現できる。変形例の製造装置160は、製造装置60との比較で、コンパクトに構築され易く、短時間で加工を行い易い。よって、製造装置160を用いて一部荷重付与加工を行えば、サイクルタイムを短縮し易く、電池10の量産性を向上させ易い。 In such a case, for example, if two rods 162 are extended simultaneously and first, and then the remaining two rods 162 are extended simultaneously, a process equivalent to the two-stage partial load application process described above can be achieved. Furthermore, if four rods 162 are extended at different times with a time lag, a process equivalent to the four-stage partial load application process described using FIG. 14 can be achieved. Compared to manufacturing apparatus 60, the manufacturing apparatus 160 of the modified example can be constructed more compactly and can easily perform processing in a shorter time. Therefore, if the manufacturing apparatus 160 is used to perform partial load application processing, it is easy to shorten the cycle time and improve the mass productivity of the battery 10.

 なお、製造装置は、ロッド162を1つのみ有してもよい。そして、リニアアクチュエータのケースを回転ステージに固定して、回転ステージを回動することで、ロッド162の加工位置を電極体の周方向に移動させるようにしてもよい。 The manufacturing device may have only one rod 162. The case of the linear actuator may then be fixed to a rotary stage, and the rotary stage may be rotated to move the processing position of the rod 162 in the circumferential direction of the electrode body.

 また、一部荷重付与加工で荷重が付与される電極体14の第1端面85の一部領域が、第1端面85における周方向の一部領域である場合について説明した。しかし、一部荷重付与加工で荷重が付与される領域は、電極体の電極芯体露出部側の端面における何れの一部領域でもよい。例えば、一部荷重付与加工で荷重が付与される一部領域は、電極体の電極芯体露出部側の端面において周方向全周にわたって径方向外側に位置する外周側領域でもよく、電極体の電極芯体露出部側の端面において周方向全周にわたって径方向内側に位置する内周側領域でもよい。 Furthermore, the partial region of the first end face 85 of the electrode body 14 to which a load is applied by the partial load application process has been described as being a partial region in the circumferential direction of the first end face 85. However, the region to which a load is applied by the partial load application process may be any partial region on the end face on the electrode core exposed portion side of the electrode body. For example, the partial region to which a load is applied by the partial load application process may be an outer peripheral region located radially outward over the entire circumferential direction on the end face on the electrode core exposed portion side of the electrode body, or an inner peripheral region located radially inward over the entire circumferential direction on the end face on the electrode core exposed portion side of the electrode body.

 また、電極芯体露出部が、電極体14の高さ方向の端部を構成する負極芯体露出部41であって、本開示の技術を、負極集電板19に対する負極芯体露出部41の溶接において電極(正極11及び負極12)に不必要な荷重がかかるのを抑制するために用いる場合について説明した。しかし、電極芯体露出部が、電極体の高さ方向の端部を構成する正極芯体露出部であって、本開示の技術を、正極集電板に対する正極芯体露出部の溶接において電極(正極及び負極)に不必要な荷重がかかるのを抑制するために用いてもよい。 Furthermore, in the above description, the electrode core exposed portion is the negative electrode core exposed portion 41 that constitutes the end portion in the height direction of the electrode body 14, and the technology disclosed herein is used to prevent unnecessary loads from being applied to the electrodes (positive electrode 11 and negative electrode 12) when welding the negative electrode core exposed portion 41 to the negative electrode current collector plate 19. However, the electrode core exposed portion may also be a positive electrode core exposed portion that constitutes the end portion in the height direction of the electrode body, and the technology disclosed herein may also be used to prevent unnecessary loads from being applied to the electrodes (positive electrode and negative electrode) when welding the positive electrode core exposed portion to the positive electrode current collector plate.

 また、本開示の円筒形電池の製造方法、円筒形電池の製造装置、及び円筒形電池は、以下の構成でもよい。
 構成1:電極体の高さ方向の端部を構成する電極芯体露出部を集電板に溶接する溶接工程を含む円筒形電池の製造方法であって、前記溶接工程の前に、前記電極体の高さ方向の前記端部側の端面の一部のみに高さ方向の荷重を付与する一部荷重付与工程を含む、円筒形電池の製造方法。
 構成2:前記一部荷重付与工程において、前記端面において径方向の最内周に位置する電極よりも径方向の外方に位置する領域の一部のみに高さ方向の荷重を付与する、構成1に記載の円筒形電池の製造方法。
 構成3:前記一部荷重付与工程が、高さ方向の荷重を付与する前記端面の領域を変えて複数回行われる、構成1又は2に記載の円筒形電池の製造方法。
 構成4:前記一部荷重付与工程は、前記端面の一部のみを押圧面に押圧することで行い、前記溶接工程において溶接を行う電極芯体露出部の溶接箇所に対応する前記押圧面の対応箇所に凸部が設けられている、構成1から3のいずれか1つに記載の円筒形電池の製造方法。
 構成5:前記端面の一部が、前記端面における周方向の一部の領域に含まれる、構成1から4のいずれか1つに記載の円筒形電池の製造方法。
 構成6:前記電極芯体露出部が、電極の長手方向の巻内端から巻外端まで存在する帯形状を有し、前記電極芯体露出部が切り込みを有さない、構成1から5のいずれか1つに記載の円筒形電池の製造方法。
 構成7:押圧面と、前記電極体を前記押圧面に相対移動させて前記電極体の高さ方向の端面の一部のみを前記押圧面に押圧させる押圧機構と、を備える、円筒形電池の製造装置。
 構成8:前記端面の一部が前記押圧面に押圧されている状態において、前記押圧面が前記端面の径方向の内周側に対して径方向に間隔をおいて位置する、構成7に記載の円筒形電池の製造装置。
 構成9:前記押圧機構が伸縮可能な1以上のロッドを有するリニアアクチュエータを備え、少なくとも1つの前記ロッドの先端面が、前記押圧面を構成する、構成7又は8に記載の円筒形電池の製造装置。
 構成10:前記端面の一部が、前記端面における周方向の一部の領域に含まれる、構成7から9のいずれか1つに記載の円筒形電池の製造装置。
 構成11:構成1から6のいずれか1つに記載の円筒形電池の製造方法で製造された円筒形電池。
The cylindrical battery manufacturing method, cylindrical battery manufacturing apparatus, and cylindrical battery of the present disclosure may also have the following configurations.
Configuration 1: A method for manufacturing a cylindrical battery, which includes a welding step of welding an exposed portion of an electrode core that constitutes an end portion in the height direction of an electrode body to a current collector plate, and which includes a partial load application step of applying a height direction load to only a portion of the end face on the end side in the height direction of the electrode body before the welding step.
Configuration 2: The method for manufacturing a cylindrical battery according to Configuration 1, wherein in the partial load application step, a height direction load is applied only to a portion of a region located radially outward from an electrode located radially innermost on the end face.
Configuration 3: The method for manufacturing a cylindrical battery according to Configuration 1 or 2, wherein the partial load application step is performed multiple times by changing the region of the end face to which the height direction load is applied.
Configuration 4: The method for manufacturing a cylindrical battery according to any one of Configurations 1 to 3, wherein the partial load application step is performed by pressing only a portion of the end face against a pressing surface, and a convex portion is provided on the pressing surface at a corresponding location that corresponds to a welding location of the electrode core exposed portion that is to be welded in the welding step.
Configuration 5: The method for manufacturing a cylindrical battery according to any one of Configurations 1 to 4, wherein the portion of the end face is included in a partial region of the end face in the circumferential direction.
Configuration 6: The method for manufacturing a cylindrical battery according to any one of Configurations 1 to 5, wherein the electrode substrate exposed portion has a band shape that extends from the inner end of the electrode to the outer end of the electrode in the longitudinal direction of the electrode, and the electrode substrate exposed portion does not have a notch.
Configuration 7: A cylindrical battery manufacturing device comprising: a pressing surface; and a pressing mechanism that moves the electrode body relative to the pressing surface to press only a portion of the height-wise end surface of the electrode body against the pressing surface.
Configuration 8: The cylindrical battery manufacturing apparatus according to Configuration 7, wherein, when a portion of the end face is pressed against the pressing surface, the pressing surface is positioned radially spaced apart from the radially inner side of the end face.
Configuration 9: A cylindrical battery manufacturing apparatus according to configuration 7 or 8, wherein the pressing mechanism comprises a linear actuator having one or more extendable rods, and the tip surface of at least one of the rods constitutes the pressing surface.
Configuration 10: The cylindrical battery manufacturing apparatus according to any one of Configurations 7 to 9, wherein the portion of the end face is included in a partial region of the end face in the circumferential direction.
Configuration 11: A cylindrical battery manufactured by the method for manufacturing a cylindrical battery according to any one of configurations 1 to 6.

 10 電池、 11 正極、 12 負極、 13 セパレータ、 14 電極体、 14a 中空部、 16 外装缶、 17 封口体、 18 絶縁板、 19 負極集電板、 20 正極リード、 22 溝入部、 25 金属板、 26 正極集電板、 26a 貫通孔、 27 端子キャップ、 28 ガスケット、 29 肩部、 30 積層部、 31 凹部、 39 筒状部、 40 負極芯体、 41 負極芯体露出部、 
42 負極合剤層、 51 平板部、 53 径方向延在部、 54 段部、 56 突条部、 57 溝部、 60 製造装置、 61 押圧面、 62 押圧プレート、 62a 凸部、 63 プレート取付部、 63a 円筒孔、 65 押圧機構、 65a ベースステージ、 65b 移動ステージ、 65c 保持装置、  68 底部、 68a 易破断部、 80 第1折曲板、 80a 中心軸、 81 第2折曲板、 81a 第2折曲板の先端部、 81b 二等分線、 85 電極体の第1端面、 85a 平面視における第1端面の第1領域、 85b 平面視における第1端面の第2領域、 85c 平面視における第1端面の第3領域、 85d 平面視における第1端面の第4領域、 86 電極体の第2端面、 90 溶接装置、 91 金属プレート、  92 押圧機構、 92a ベースステージ、 92b 移動ステージ、 92c 保持装置、 160 製造装置、 161 先端面、 162 ロッド、 162a 凸部。
REFERENCE SIGNS LIST 10 battery, 11 positive electrode, 12 negative electrode, 13 separator, 14 electrode body, 14a hollow portion, 16 outer can, 17 sealing body, 18 insulating plate, 19 negative electrode current collector plate, 20 positive electrode lead, 22 grooved portion, 25 metal plate, 26 positive electrode current collector plate, 26a through hole, 27 terminal cap, 28 gasket, 29 shoulder portion, 30 stacked portion, 31 recessed portion, 39 cylindrical portion, 40 negative electrode core, 41 negative electrode core exposed portion
42 Negative electrode mixture layer, 51 Flat plate portion, 53 Radial extending portion, 54 Step portion, 56 Protrusion portion, 57 Groove portion, 60 Manufacturing device, 61 Pressing surface, 62 Pressing plate, 62a Convex portion, 63 Plate mounting portion, 63a Cylindrical hole, 65 Pressing mechanism, 65a Base stage, 65b Moving stage, 65c Holding device, 68 Bottom portion, 68a Easy-to-break portion, 80 First folded plate, 80a Central axis, 81 Second folded plate, 81a Tip portion of second folded plate, 81b Bisector, 85 First end surface of electrode body, 85a First region of first end surface in plan view, 85b Second region of first end surface in plan view, 85c a third region of the first end surface in plan view; 85d a fourth region of the first end surface in plan view; 86 a second end surface of the electrode body; 90 welding device; 91 metal plate; 92 pressing mechanism; 92a base stage; 92b moving stage; 92c holding device; 160 manufacturing device; 161 tip surface; 162 rod; 162a convex portion.

Claims (11)

 電極体の高さ方向の端部を構成する電極芯体露出部を集電板に溶接する溶接工程を含む円筒形電池の製造方法であって、
 前記溶接工程の前に、前記電極体の高さ方向の前記端部側の端面の一部のみに高さ方向の荷重を付与する一部荷重付与工程を含む、円筒形電池の製造方法。
A method for manufacturing a cylindrical battery, comprising a welding step of welding an electrode core exposed portion that constitutes an end portion in the height direction of an electrode body to a current collector plate,
A method for manufacturing a cylindrical battery, comprising, before the welding step, a partial load applying step of applying a load in the height direction to only a portion of the end face on the end side in the height direction of the electrode body.
 前記一部荷重付与工程において、前記端面において径方向の最内周に位置する電極よりも径方向の外方に位置する領域の一部のみに高さ方向の荷重を付与する、請求項1に記載の円筒形電池の製造方法。 The method for manufacturing a cylindrical battery described in claim 1, wherein, in the partial load application step, a height direction load is applied only to a portion of an area of the end face that is located radially outward from the electrode located at the innermost periphery in the radial direction.  前記一部荷重付与工程が、高さ方向の荷重を付与する前記端面の領域を変えて複数回行われる、請求項1又は2に記載の円筒形電池の製造方法。 The method for manufacturing a cylindrical battery described in claim 1 or 2, wherein the partial load application process is performed multiple times by changing the area of the end face to which the height direction load is applied.  前記一部荷重付与工程は、前記端面の一部のみを押圧面に押圧することで行い、
 前記溶接工程において溶接を行う電極芯体露出部の溶接箇所に対応する前記押圧面の対応箇所に凸部が設けられている、請求項1又は2に記載の円筒形電池の製造方法。
the partial load applying step is performed by pressing only a portion of the end surface against a pressing surface,
The method for manufacturing a cylindrical battery according to claim 1 or 2, wherein a protrusion is provided on the pressing surface at a position corresponding to a welding position of the electrode core exposed portion to be welded in the welding step.
 前記端面の一部が、前記端面における周方向の一部の領域に含まれる、請求項1又は2に記載の円筒形電池の製造方法。 The method for manufacturing a cylindrical battery according to claim 1 or 2, wherein a portion of the end face is included in a circumferential region of the end face.  前記電極芯体露出部が、電極の長手方向の巻内端から巻外端まで存在する帯形状を有し、前記電極芯体露出部が切り込みを有さない、請求項1又は2に記載の円筒形電池の製造方法。 The method for manufacturing a cylindrical battery described in claim 1 or 2, wherein the electrode substrate exposed portion has a band shape extending from the inner end of the electrode to the outer end of the electrode in the longitudinal direction of the electrode, and the electrode substrate exposed portion does not have a notch.  押圧面と、
 前記電極体を前記押圧面に相対移動させて前記電極体の高さ方向の端面の一部のみを前記押圧面に押圧させる押圧機構と、
を備える、円筒形電池の製造装置。
A pressing surface;
a pressing mechanism that moves the electrode body relative to the pressing surface to press only a portion of the end surface in the height direction of the electrode body against the pressing surface;
A cylindrical battery manufacturing apparatus comprising:
 前記端面の一部が前記押圧面に押圧されている状態において、前記押圧面が前記端面の径方向の内周側に対して径方向に間隔をおいて位置する、請求項7に記載の円筒形電池の製造装置。 The cylindrical battery manufacturing apparatus of claim 7, wherein, when a portion of the end face is pressed against the pressing surface, the pressing surface is positioned radially away from the radially inner side of the end face.  前記押圧機構が伸縮可能な1以上のロッドを有するリニアアクチュエータを備え、
 少なくとも1つの前記ロッドの先端面が、前記押圧面を構成する、請求項7又は8に記載の円筒形電池の製造装置。
the pressing mechanism includes a linear actuator having one or more extendable rods;
The cylindrical battery manufacturing apparatus according to claim 7 or 8, wherein a tip surface of at least one of the rods constitutes the pressing surface.
 前記端面の一部が、前記端面における周方向の一部の領域に含まれる、請求項7又は8に記載の円筒形電池の製造装置。 The cylindrical battery manufacturing apparatus of claim 7 or 8, wherein a portion of the end face is included in a circumferential region of the end face.  請求項1に記載の円筒形電池の製造方法で製造された円筒形電池。 A cylindrical battery manufactured using the cylindrical battery manufacturing method described in claim 1.
PCT/JP2025/009732 2024-03-28 2025-03-13 Method for producing cylindrical battery, device for producing cylindrical battery, and cylindrical battery Pending WO2025205032A1 (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000348689A (en) * 1999-06-07 2000-12-15 Hitachi Maxell Ltd Manufacturing method of cylindrical battery
JP2008021644A (en) * 2006-06-16 2008-01-31 Matsushita Electric Ind Co Ltd Nonaqueous electrolyte secondary battery
JP2008066075A (en) * 2006-09-06 2008-03-21 Hitachi Ltd Nonaqueous electrolyte secondary battery
JP2015519689A (en) * 2012-04-24 2015-07-09 シーリエン アペックス チャイナ ホールディング カンパニー リミテッドShihlien Apex China Holding Co., Limited Large capacity cylindrical lithium ion battery and method for manufacturing the same
WO2023281983A1 (en) * 2021-07-07 2023-01-12 三洋電機株式会社 Cylindrical battery

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000348689A (en) * 1999-06-07 2000-12-15 Hitachi Maxell Ltd Manufacturing method of cylindrical battery
JP2008021644A (en) * 2006-06-16 2008-01-31 Matsushita Electric Ind Co Ltd Nonaqueous electrolyte secondary battery
JP2008066075A (en) * 2006-09-06 2008-03-21 Hitachi Ltd Nonaqueous electrolyte secondary battery
JP2015519689A (en) * 2012-04-24 2015-07-09 シーリエン アペックス チャイナ ホールディング カンパニー リミテッドShihlien Apex China Holding Co., Limited Large capacity cylindrical lithium ion battery and method for manufacturing the same
WO2023281983A1 (en) * 2021-07-07 2023-01-12 三洋電機株式会社 Cylindrical battery

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