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WO2024228165A1 - Pelletisation d'un produit minéral - Google Patents

Pelletisation d'un produit minéral Download PDF

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Publication number
WO2024228165A1
WO2024228165A1 PCT/IB2024/054313 IB2024054313W WO2024228165A1 WO 2024228165 A1 WO2024228165 A1 WO 2024228165A1 IB 2024054313 W IB2024054313 W IB 2024054313W WO 2024228165 A1 WO2024228165 A1 WO 2024228165A1
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WO
WIPO (PCT)
Prior art keywords
pellets
binder
powder
fraction
mixer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
PCT/IB2024/054313
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English (en)
Inventor
Alex Richard FISHER
Garry LONSDALE
Rudolph Johannes FOUCHEE
Wesley Robin GOUNDER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anglo American Woodsmith Ltd
Original Assignee
Anglo American Woodsmith Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anglo American Woodsmith Ltd filed Critical Anglo American Woodsmith Ltd
Publication of WO2024228165A1 publication Critical patent/WO2024228165A1/fr
Anticipated expiration legal-status Critical
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00—Fertilisers containing potassium
    • C05D1/04—Fertilisers containing potassium from minerals or volcanic rocks
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/14—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic in rotating dishes or pans
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00—Fertilisers containing potassium
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00—Fertilisers characterised by their form
    • C05G5/10—Solid or semi-solid fertilisers, e.g. powders
    • C05G5/12—Granules or flakes

Definitions

  • This invention relates to forming pelletised mineral products, for example, for use as fertiliser.
  • this invention relates to a method of pelletising evaporite mineral powder mixed with a binder and water utilising screening to maximise efficiency.
  • Polyhalite is an evaporite mineral. It is a complex hydrated sulphate of potassium, calcium and magnesium. Deposits of polyhalite occur in, amongst other countries, Austria, China, Germany, India, Iran, Turkey, Ukraine, the UK and the USA.
  • Polyhalite has the capacity to be valuable as a source of agricultural fertiliser.
  • it has been proposed to decompose natural polyhalite to extract specific nutrients. See, for example, WO 2013/074328, US 1 ,946,068 and US 4,246,019.
  • intact polyhalite is also usable as a fertiliser, being able to supply sulphur, potassium, calcium and magnesium to the soil.
  • Mineral polyhalite can be spread in raw, crushed or chipped form. That involves low material processing costs, but it has a number of agronomic disadvantages. Once applied to the soil the raw mineral takes some time to break down, delaying the bioavailability of its constituents. If applied in chipped form, the polyhalite tends to be of irregular shape and size, meaning that there can be issues in applying it uniformly, and that it can be difficult to apply with some types of agricultural spreading machinery. Untreated powdered polyhalite might in some circumstances be capable of being uniformly spread. However, it can have a tendency to flocculate or clump in some storage conditions, making it difficult to spread evenly with some types of machinery.
  • urea into fertiliser pellets and to form limestone into pellets for dressing to increase soil pH. This can be done by mixing powdered urea or limestone with a binder and then processing it in a pan pelletiser.
  • GB 2 533 490 and GB 2 530 757 disclose forming powdered polyhalite into pellets, the powder being bound by starch.
  • GB2 577 866 teaches a method for forming a pelletised evaporite mineral product, the method comprising: pulverising an evaporite mineral feedstock to form a powder; mixing the powder with a binder in the presence of a liquid to form a blend; processing the blend using a pelletiser to form a quantity of pellets principally composed of the evaporite mineral; separating at least one of an oversized fraction and an undersized fraction from the quantity of pellets; disaggregating the pellets of the oversized and/or undersized fraction to form disaggregated material; and re-pelletising the disaggregated material.
  • a method for forming a pelletised evaporite mineral product comprising: pulverising an evaporite mineral feedstock to form a powder; mixing the powder with a binder in the presence of a liquid to form a mixture; wet screening the mixture to separate a granule fraction and a fines fraction; and processing the fines fraction using a pelletiser to form a quantity of pellets principally composed of the evaporite mineral.
  • the method may further comprise separating at least one of an oversized fraction and an undersized fraction from the quantity of pellets; disaggregating the pellets of the oversized and/or undersized fraction to form disaggregated material; and re-pelletising the disaggregated material.
  • the wet screening involves the application of a rotary drum screen which may be a self cleaning trommel screen.
  • the granules from the wet screening may be directed through an oversize screen to separate product granules from non-product granules.
  • the product granules may be directed to a drier to form pellets.
  • the non-product granules may be directed to a secondary mixer which in turn is fed back to the wet screening.
  • the method according to the present invention may comprise disaggregating the pellets of the oversized and/or undersized fraction in an operating chamber of a mixer/granulator and re-pelletising the disaggregated material in that same operating chamber. That may be a different operating chamber from an operating chamber in which the blend or mixture is processed to form the quantity of pellets.
  • the method may further comprise mixing the powder with the binder in an operating chamber of a mixer/granulator and processing the mixture to form pellets in the operating chamber.
  • the method may comprises separating only an oversized fraction.
  • the method may comprise separating only an undersized fraction.
  • the said disaggregating step may involve the application of a higher shear than the mixing step.
  • the method may comprise disaggregating the pellets without substantially drying them subsequent to the re-pelletising step.
  • the water content of the disaggregated material input to the re-pelletising step may comprise substantially the same proportion of water by mass (e.g. plus or minus 5 or 10 percent) as the oversized and/or undersized fraction at the time when it is separated. This can assist in re-pelletising the material efficiently and without the need to add additional water.
  • the oversized fraction may comprise those of the formed pellets that exceed a predetermined size, e.g. diameter.
  • the undersized fraction may comprise those of the formed pellets that are below a predetermined size, e.g. diameter.
  • the mixing step may comprise holding the powder and the binder in a vessel and agitating the powder and the binder by the operative region of a mixing tool, at least a part of the operative region having an instantaneous linear speed of at least 14 m/s relative to the vessel during the mixing step.
  • the said disaggregating step may comprise holding the oversized and/or undersized pellets in a vessel and agitating those pellets by the operative region of an agitating tool, at least a part of the operative region having an instantaneous linear speed of at least 2 m/s relative to the vessel during the disaggregating step.
  • the highest instantaneous linear speed of any part of the operative region of the tool during the disaggregating step may be less than 10 m/s or less than 5 m/s.
  • the highest instantaneous velocity of at least a part of the operative region of the mixing tool relative to the mixing vessel may be in the range from 5 to 10 times the highest instantaneous velocity of at least a part of the operative region of the agitating tool relative to the agitating vessel.
  • the binder is preferably a farinaceous material, i.e. comprising starch, for example in the form of flour.
  • the powder may have a mass average grain size in the range from 50 to 400pm.
  • the liquid may comprise or may be water.
  • the pellets of the quantity of pellets may contain greater than 80%, preferably greater than 90% by mass of the evaporite mineral.
  • the evaporite mineral may be polyhalite.
  • an evaporite mineral feedstock e.g. a polyhalite feedstock
  • a dry powder can then be mixed with a binder to form an intermediate mixture.
  • the intermediate mixture can be processed using a pelletiser to form pellets that are principally composed of the evaporite mineral.
  • the pellets can be processed (e.g. by drying) to stabilise them structurally.
  • polyhalite is a complex hydrated sulphate of potassium, calcium and magnesium.
  • Polyhalite may have the general formula K2Ca2Mg(SO4)4.2H20, or substantially such. Polyhalite has a Moh's hardness of around 2.5 to 3.5.
  • As-mined polyhalite may be intimately combined with gangue.
  • the gangue may include other evaporite minerals such as halite (NaCI) and anhydrite (CaSO4).
  • the gangue is preferably in low proportions (e.g. less than 10% or less than 5% in good quality ore).
  • polyhalite may be broken into blocks or chips of suitable size for transport and processing.
  • the as-mined rock may be fed to crushers such as jaw crushers and/or cone crushers in order to yield a chipped material of generally uniform size. It may be desirable to limit the moisture uptake of the chipped polyhalite in order to reduce any variation in the subsequent processing steps as a result of, for example, variations in the weather.
  • polyhalite may be desired to form the polyhalite into pellets, e.g. to act as a spreadable fertiliser product.
  • a spreadable fertiliser product e.g. to act as a spreadable fertiliser product.
  • the raw or chipped polyhalite is processed to form a powder essentially of polyhalite.
  • This may suitably be done using high pressure grinding roller (HPGR) equipment, or in a ball mill (e.g. a continuous "Hardinge” ball mill) or an attritor mill.
  • HPGR high pressure grinding roller
  • the average grain size of the powder is dependent on various process parameters including the dwell time of the feedstock in the powdering equipment and the configuration of the powdering equipment. Oversized particles exiting the powdering equipment may be returned to the equipment for further processing.
  • the desired powder size will depend on the nature of the subsequent processing steps, but it has been found that air classifying the output of the powdering process with a 500pm air classifier (AC) and accepting the material passing the AC for further processing yields good results.
  • AC air classifier
  • a convenient profile of the powder passed to the next step of the process is: 100% passing a 500pm screen and 80% (by mass) passing a 200pm screen.
  • at least 50% or more preferably at least 70% of the mass of the powder is composed of grains having a grain size, or a largest or average diameter, in the range from 50 to 400pm.
  • the grain size may be as measured by means of a Malvern Mastersizer 2000 or as measured by means of a sieve shaker.
  • Gangue may be separated before the mined rock is powdered. Alternatively, if the gangue is in reasonably low proportion to the desired mineral then it may be retained and powdered.
  • the powdered polyhalite may comprise other minerals too.
  • the powder preferably comprises greater than 80% by mass polyhalite, more preferably greater than 90% by mass polyhalite.
  • the powder preferably comprises greater than 90% by mass of evaporite minerals.
  • Water and a binder are added to the powdered polyhalite.
  • the additions of water and binder are specified by mass with reference to the mass of the powder to which they are added.
  • the amount of water to be added will depend on the inherent water content of the powdered polyhalite and the nature of the subsequent processing steps. However, it has been found that when the binder is a starch-based binder such as starch itself or flour, acceptable results can be achieved by adding water in the range of 5% to 10% by mass, more preferably between 7% and 8% by mass. At a subsequent stage in the process excess water is removed from the formed pellets by drying. That can consume energy, so it is preferred to minimise the amount of water added, provided that is consistent with the production of an acceptably bound pellet product.
  • the preferred amount of water can readily be determined by testing.
  • the amount of binder to be added will depend on the qualities of the binder. For typical binders, e.g. starch or flour, the amount added may be in the range of 0.5% to 1 .5% by mass.
  • the binder may be a farinaceous material including a starch-based binder such as a purified starch or a flour, or an adhesive such as PVA.
  • the binder may be added directly to the powder, or it may first be added to the water and then the water and binder combination may be added to the powder.
  • One option as a binder is purified starch. This can be added in the range 0.5% to 3.0% by mass.
  • the flour may be formed by grinding a starchy vegetable base such as one or more types of vegetable root or seed.
  • the flour may, for example be formed from the seeds of a cereal such as wheat, corn or rye or of a pulse such as pea.
  • the flour may be a raw flour: that is a flour formed by the grinding of the base biological material with no substantial bleaching or refinement.
  • the flour may be a wholegrain flour.
  • the flour may be formed from material from which the germ and/or the bran has not been separated.
  • the flour may comprise starch together with fat (e.g. oil) or protein or both.
  • the germ is a significant source of fat.
  • the flour may comprise greater than 1 .0% or greater than 2.0% germ by mass.
  • the flour may comprise greater than 0.05% or greater than 0.1 % or greater than 0.2% fat by mass or greater than 0.4% fat by mass.
  • the bran is a significant source of protein.
  • the flour may comprise greater than 8% or greater than 12% bran by mass.
  • the flour may comprise greater than 0.5% or greater than 1 .0% or greater than 4.0% or greater than 8.0% or greater than 10% of protein by mass.
  • the flour may comprise greater than 50% or greater than 55% or greater than 60% starch by mass.
  • the flour may comprise less than 90% or less than 80% or less than 70% starch by mass.
  • the flour may comprise greater than 1% or greater than 2% lipids by mass.
  • the flour may comprise greater than 0.2% or 0.4% fatty acids by mass.
  • a suitable example composition of the flour is: lipids 3%, protein 7.5%, moisture 13.5%, fibre 3.6%, fatty acids 0.5%, ash 2.5%, starch 69.4%,
  • the flour may comprise gluten.
  • the flour may comprise greater than 5.0% or greater than 8.0% or greater than 10% gluten by mass.
  • a pelletised fertiliser bound with flour is introduced to a growing medium (e.g. soil) and breaks down, the protein and oil in flour can be released to the growing medium.
  • the protein and potentially also the oil can attract and support the growth of mycorrhizal organisms. Those organisms can promote the growth of the target plants and supplement the nutrient-giving effects of the fertiliser composition itself.
  • Flour is typically less flammable than refined starch, which can even be explosive. This improves safety and makes flour less expensive to handle.
  • Flour is significantly cheaper than some alternative binders, such as refined starch, and has a lower carbon footprint.
  • the type of flour selected for use can depend on the availability of suitable starchy crops convenient to the pelletising plant, and may vary seasonally without significantly affecting pellet yield.
  • the binder When the binder is starch or flour, it is convenient to mix it with water, and then subsequently to add the mixture of binder and water to the polyhalite powder. This can improve the intermixing of the binder and the mineral powder.
  • Starch contained in the binder may be gelatinised prior to being mixed with the mineral powder. This may, for example be done by atmospheric cooking or by jet cooking. To this end the binder may be added to water at a temperature of greater than 55°C, more preferably greater than 80°C; or the binder may be added to water and the binder/water mixture heated to a temperature in that range.
  • the binder may be added to the water in equal proportion to the intended additions of the same to the powder, or alternatively additional water may be added after the water/binder mix is added to the mineral powder.
  • water may be added to the binder in liquid form or in the form of steam.
  • the process of cooking the starch may be performed at atmospheric pressure and/or at greater than atmospheric pressure. The cooking process may be completed before the binder mixture is added to the polyhalite powder.
  • the powder/blender mixture is mixed until it is homogeneous, and pelletised.
  • the powder/binder mixture is mixed in a suitable mixer (e.g. a ribbon blender) and then pelletised in a suitable pelletiser (e.g. a pan pelletiser).
  • a suitable mixer e.g. a ribbon blender
  • a suitable pelletiser e.g. a pan pelletiser
  • the powder/binder mixture is passed to equipment that can both mix and pelletise.
  • An example of such equipment is an intensive mixer/granulator, e.g. as available from Maschinenfabrik Gustav Eirich GmbH & Co KG.
  • a pelletiser may be configured to expel processed material as it operates, allowing it to run continuously. Alternatively the pelletiser may operate on a batch basis, with material being processed according to a defined programme and then expelled en masse.
  • a wet screening step is introduced between the mixing and pelletisation step, using a rotary drum screen which may be a trommel screen and which may be self cleaning.
  • a trommel screen also known as a rotary screen, is a mechanical screening machine used to separate materials, mainly in the mineral and solid-waste processing industries. It consists of a perforated cylindrical drum that is normally elevated at an angle at the feed end. Physical size separation is achieved as the feed material spirals down the rotating drum, where the undersized material smaller than the screen apertures passes through the screen, while the oversized material exits at the other end of the drum.
  • Trommel screens are typically used in a variety of applications such as classification of solid waste and recovery of valuable minerals from raw materials. Trommel screens come in many designs such as concentric screens, series or parallel arrangement and each component has a few configurations. Considerations for a trommel screen include the screening rate, screening efficiency and residence time of particles in the screen. When designing a trommel screen, the main factors affecting the screening efficiency and production rate are the rotational velocity of the drum, mass flow rate of feed particles, size of the drum, inclination of trommel screen, aperture size and type of screening media, for example polyurethane panels vs woven mesh. Depending on desired application of trommel screen, a balance has to be made between the screening efficiency and production rate.
  • pelletisation efficiency is greatly improved through pre-screening of the wet mineral / binder / water mixture using a rotary drum screen as described.
  • smaller recycle streams are created which results in lower capital and operating costs, lower maintenance, particularly of the screens, all of which results in maximised plant run time.
  • the pelletisation process according to the prior art resulted in fouling of the screens as taught because the material being screened was still wet.
  • the fines from the wet screening are directed to a pelletiser (granulator) for a pelletisation step.
  • the formed pellets Before or after being expelled from the pelletiser, the formed pellets may be coated with dry powder before subsequently being screened. This can help to resist them sticking or breaking up during the screening or related processing.
  • Further polyhalite powder may be added to the pelletiser towards the end of the pelletising process.
  • the polyhalite powder may coat the pellets with a dry coating which can assist with subsequent processing.
  • the amount of polyhalite powder added at this stage may be between 5 and 15% by mass of the content of the pelletiser, more preferably between 8 and 12% by mass.
  • the additional polyhalite powder may be added between 10 and 15 seconds prior to completion of the pelletising process. At completion of the pelletising process may be when the pellets are expelled from the pelletiser.
  • the material expelled from the pelletiser can be screened to separate undersized or oversized pellets from pellets of a desired size range.
  • the desired size range may, for example, be that which passes a 4mm screen but does not pass a 2mm screen. Alternatively, other sizes may be chosen as appropriate to the desired application.
  • the outsized pellets may be recirculated. Any pellets that are oversize can be ground and then returned to the pelletiser. Undersize pellets can be returned directly to the pelletiser.
  • the output of the pelletiser is wet, substantially spherical pellets.
  • the pellets that meet the desired size are conveniently dried before packaging. To achieve this the pellets that have been output from the pelletiser can be passed to a drier.
  • the granules separated by the rotary drum screen and possibly also the oversize screen can also be passed to the drier.
  • a retention time of around 20 minutes in a drier capable of heating the pellets to a temperature of around 150°C is sufficient to adequately dry the pellets. This can harden them.
  • Pellets manufactured using polyhalite powder and with flour as a binder can have a crush strength in excess of 4.0kgf and/or in excess of 5.0kgf. This compares favourably with a generally accepted lower limit of 2.2kgf for acceptable agricultural pellets.
  • Moisture can be extracted from the dryer using a reverse jet air filter. The operating temperature and retention time in the dryer can be selected to provide pellets of the desired strength for subsequent handling.
  • the mineral powder, binder and water are subject to a first mixing step.
  • the first mixing step is performed so as to provide a homogeneous mixture of the constituents.
  • the wet mixture is subject to a wet screening step to separate granules and overside from fines.
  • the fines are directed to a pelletising step.
  • the output of the pelletising step may be tested for size. Pellets within the desired size range are accepted for drying. Pellets above or below the desired size are rejected. The sizing may be performed using suitably sized screens. 4. The accepted pellets and the granules from the wet screening step are dried to harden them, e.g., by heating.
  • the oversized rejected pellets are, without having been subjected to a heating step, agglomerated to a second mixing step.
  • the second mixing process is performed at sufficiently high shear to break the pellets down. This can be done in a mixer rather than a grinder or crusher because the oversized rejected pellets have not been dried after the first pelletising step.
  • the undersized rejected pellets may be passed to the second mixing process or returned to the first pelletising step.
  • the output of the second mixing process is directed back to the wet screening step.
  • Figure 1 shows a generalised overview of a pelletising process according to the prior art.
  • Figure 2 shows an alternative overview of a pelletising process according to the prior art.
  • Figure 3 shows a first embodiment of the present invention.
  • Figure 4 shows a second embodiment of the present invention.
  • Figure 1 shows as-mined raw polyhalite 12 is primary crushed in one or more comminution devices such as a jaw crusher 1 and secondary crushed in a cone crusher 2. This produces a crushed polyhalite product. Roll sizers, hammer mills or vertical shaft impact crushers may also be used.
  • the crushed polyhalite may be stored, e.g., in a warehouse 3, until shortly before it is to be processed by the subsequent steps. Preferably the steps illustrated at 4, 6 and 7 follow quickly one after the other, reducing the scope for the polyhalite powder to absorb ambient moisture.
  • the crushed polyhalite can be withdrawn from the store 3 and passed to an HPGR mill 4 where it is rendered to a powder.
  • the HPGR mill may preferably operate in a closed circuit with an air classifier.
  • the binder (flour) 13 is combined with water 14 in a first mixer 5.
  • the polyhalite powder is combined with the binder/water mixture in a second mixer 6.
  • the mixture can be passed to a pelletiser 7.
  • the mixer 6 and the pelletiser 7 may be implemented by a single mixer/pelletiser. Additional water may, if needed, be added to mixer 6 and/or pelletiser 7 to achieve proper operation of the process.
  • the pelletiser 7 causes the mixture to aggregate into substantially spherical pellets and dry polyhalite powder may be added to the pelletiser to coat the pellets.
  • the pellets exit the pelletiser gradually or in batches.
  • the exiting pellets are sized by a set of screens 8.
  • Undersize pellets are returned to the pelletiser as indicated at 9, or to the second mixer as indicated at 10. Oversize pellets may be returned to the second mixer indicated at 10.
  • the output of the sizing step is pellets of substantially spherical form and within the size limits defined by the screens 8. Those pellets are dried at 1 1 .
  • the resulting hardened pellets 12 can then be packaged and supplied for agricultural use. Finally, they can be spread on a field or other agricultural or horticultural substrate to act as a fertiliser.
  • Conveyor belts, auger conveyors or other handling apparatus can be used to move the components between processing stations.
  • additives may be included in the pellets.
  • Such additives may be one or more of the following, in any combination: - a component having the effect of chemically and/or mechanically stabilising and/or preserving the pellets: for example to increase their shelf life, reduce their susceptibility to environmental contaminants or to reduce the likelihood of them being broken up during spreading; - a component having the effect of enhancing the fertilising effect of the polyhalite: for example by accelerating or retarding the breakdown of the polyhalite in the field; - a component having the effect of protecting or enhancing the growth of crops by means other than fertilising: for example a herbicide, fungicide, insecticide, rodenticide, hormone, plant stimulant or mycorrhizal fungus or spore; - a seed: which may be a seed of an angiosperm and/or of a crop species (e.g.
  • a cereal such as wheat, maize, rice, millet, barley, oats or rye
  • a further fertiliser composition in addition to the polyhalite for example a source of nitrogen and/or phosphorus
  • - a pigment for example a component having the effect of altering soil pH: for example lime, sulphur or a sulphate.
  • Such a component may be added at various stages in the process, for example it could be combined with the polyhalite powder prior to or during the first mixing stage as described above, or with the binder prior to the first mixing stage as described above, or with the polyhalite/binder mix between the first and second mixing steps as described above, or during the second mixing step as described above, or it could be added to the pan pelletiser, or it could be sprayed or otherwise coated on to the pellets before or after drying.
  • the polyhalite content of the resulting pellets is preferably greater than 75% by weight, more preferably greater than 80% and most preferably greater than 90%. In the case of pellets that contain seeds this may optionally be varied such that the polyhalite content of the pellets excluding the weight of the seeds may be greater than 75% by weight, more preferably 80%, most preferably greater than 90%.
  • the pellets are preferably substantially spherical, and of substantially uniform volume and mass.
  • the pellets may have a mean Wadell sphericity of greater than 0.85, 0.90 or 0.95.
  • the pellets are preferably substantially free from voids, for example having not more than 1 %, 2% or 5% by volume of air.
  • the polyhalite powder, binder and water are provided as indicated at 20.
  • the polyhalite may be a powder as described above.
  • the binder may be any suitable binder, for example starch, flour or a synthetic adhesive. If the binder comprises starch then it may already have been gelatinised.
  • the proportions of the constituents may be as indicated above.
  • the constituents may be combined before being introduced to a mixer 21 or on introduction into the mixer.
  • the mixer 21 is a combined mixer/granulator, for example an intensive mixer/granulator, e.g., as available from Maschinenfabrik Gustav Eirich GmbH & Co KG.
  • the mixer/granulator may comprise a rotatable drum defining the operating chamber of the device.
  • the floor of the drum may be tilted to horizontal.
  • the drum may be configured to be driven to rotate about an axis. That axis may be inclined to vertical.
  • a mixing paddle may be located in the drum.
  • the mixing paddle may be configured to be driven relative to the drum, for example by rotating about the axis of the drum but in the opposite direction to the drum.
  • the operative part of the paddle contacts the constituents to be mixed during the mixing step.
  • the rotation of the drum and the mixing paddle may be driven by respective motors.
  • the motors may be controlled by a controller which is pre-programmed to cause the drum and the paddle to operate according to a predetermined programme. That programme can be such as to (i) in a first stage agitate the constituents so as to mix them and (ii) in a second, subsequent stage induce the constituents to bind together into pellets.
  • the device may operate to apply a higher shear to the contents of the drum in the first step than in the second step.
  • the first stage may operate at a tool speed with a lower limit of 14 m/s and the second stage at a tool speed with a lower limit of 2 m/s.
  • the tool speed for the first stage may be from 5 to 10 times the tool speed in the second stage.
  • the tool speed may be taken to be the greatest instantaneous linear velocity relative to the vessel holding the contents to be mixed, of the part of the tool furthest from the axis of rotation.
  • a tool speed of 15 m/s may be applied for 60 seconds after which, in granulation mode, a tool speed of 3 m/s may then be employed for 120 seconds.
  • the output of the mixer 21 is passed to a screening station 22.
  • a screening station 22 At the screening station in-size pellets are extracted and passed to a drier 23 for drying so as to form a dried pellet product 24 at the output of the drier.
  • Undersized material may be returned to the first mixer 21 , as indicated at 25.
  • undersized material may be passed to a second mixer 26. This may be preferable to avoid disruption of the primary pelletising process. Oversized pellets are passed to the second mixer 26.
  • the second mixer 26 is also a combined mixer/granulator, for example an intensive mixer/granulator, e.g. as available from Maschinenfabrik Gustav Eirich GmbH & Co KG.
  • the mixer/granulator may comprise a rotatable drum defining the operating chamber of the device.
  • the floor of the drum may be tilted to horizontal.
  • the drum may be configured to be driven to rotate about an axis. That axis may be inclined to vertical.
  • a mixing paddle may be located in the drum.
  • the mixing paddle may be configured to be driven relative to the drum, for example by rotating about the axis of the drum but in the opposite direction to the drum. The rotation of the drum and the mixing paddle may be driven by respective motors.
  • the motors may be controlled by a controller which is pre-programmed to cause the drum and the paddle to operate according to a predetermined programme. That programme can be such as to (i) in a first stage agitate the oversized pellets so as to disaggregate them and (ii) in a second, subsequent stage induce the contents of the device to bind together into pellets.
  • the device may operate to apply a higher shear to the contents of the drum in the first step than in the second step.
  • the first stage may operate at a tool speed with a lower limit of 14 m/s and the second stage at a tool speed with a lower limit of 2 m/s.
  • the second mixer may comprise a mixing chamber in which the oversize pellets are disaggregated and then subsequently re-pelletised.
  • the first and second mixers may operate on cycles.
  • the operating chamber of the respective mixer may be charged with material to be processed. It may then implement its first and second operational stages, and then the processed material may be discharged from the operating chamber for sizing.
  • the first step of the second mixer may operate at a higher shear than the first step of the first mixer.
  • the first step of the second mixer may impart greater energy than the first step of the first mixer, the energy in each case being per unit time and per unit mass of the contents of the respective mixer. This may facilitate breakdown of the previously formed pellets in the first step of the second mixer.
  • These operational characteristics may be brought about by suitable programming of the mixer controllers.
  • the geometry and form of the mixing tools contained within the first and second mixers may be so optimised to promote the application of shear forces and the subsequent balance between mixing, pelletising and disaggregating.
  • the first and second mixers may also be configured to contain multiple tools which may be of the same or differing design.
  • the duration of the first/mixing step of the first mixer may be greater than the second/disaggregation step of the second mixer.
  • the undersized particles from the screening station 22 may be passed to the second mixer 26.
  • a coating agent may be applied to the pellets.
  • the coating agent may, for example, be a wax or wax-like coating.
  • the coating agent may act as a moisture barrier and/or an anti-caking agent and/or a dust suppressant.
  • pellets can be cooled and packaged, for example in 600kg bags or 25kg sacks, or shipped loose for use or further processing elsewhere
  • the product can then be shipped for use as a fertiliser.
  • the product may be used as a fertiliser by spreading the pellets on the surface of a growing medium such as soil, or by intermixing the pellets in the growing medium.
  • Figure 3 shows a preferred embodiment 30 according to the present invention.
  • the mineral powder, liquid and binder 31 are mixed in a primary mixer 32 to form a wet mixture which is passed to a trommel screen 33.
  • a trommel screen 33 removes these granules and other oversize 34 which are then preferably separated again through a subsequent oversize screen 35 with the granules 36 being sent to drying 37 to form pellets and oversize 371 being recycled back to the deagglomeration step 38.
  • the fines 39 from the trommel (wet) screening step 33 are then directed to a pan granulator 331 (pelletisation process).
  • On-specification pellets 333 are fed to the dryer 37 and oversize 332 are fed to the oversize screen 35.
  • the wet trommel screen classification 33 prevents energy waste on off-specification material.
  • the high efficiency pelletisation minimises a recycle stream resulting in significant cost savings.
  • Figure 4 shows a process 40 whereby the granules and oversize 47 screened through the trommel screen 43 are passed directly to the drier 48, thereby foregoing the oversize screening.
  • This circuit therefor goes without oversize screening or secondary agglomeration/granulation/pelletisation resulting in significant costs savings.
  • the process according to the invention as described above may be used for pelletising minerals other than polyhalite, and in particular for pelletising feedstocks composed principally of one or more evaporite minerals, especially other chloride minerals. These may include any one or more of Anyhdrite, Carnalite, Gypsum, Halite, Kainite, Kieserite, Langbeinite and/or Sylvite.
  • the process is especially suitable for pelletising feedstocks composed principally of minerals that are substantially hygroscopic in recently powdered form and/or that have a Moh's hardness in the range from 2 to 4.
  • the resulting pellets may be used for purposes other than fertilisation.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Investigation Of Foundation Soil And Reinforcement Of Foundation Soil By Compacting Or Drainage (AREA)
  • Fodder In General (AREA)

Abstract

L'invention concerne un procédé de formation d'un produit minéral d'évaporite sous forme de pastilles, le procédé comprenant la pulvérisation d'une charge minérale d'évaporite pour former une poudre, le mélange de la poudre avec un liant en présence d'un liquide pour former un mélange, le criblage par voie humide du mélange pour séparer une fraction de granules et une fraction de fines et le traitement de la fraction de fines à l'aide d'un granulateur pour former une quantité de pastilles principalement composées du minéral d'évaporite. Le produit d'évaporite est de préférence de la polyhalite.
PCT/IB2024/054313 2023-05-04 2024-05-03 Pelletisation d'un produit minéral Pending WO2024228165A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB2306624.4A GB2629628A (en) 2023-05-04 2023-05-04 Pelletisation of a mineral product
GB2306624.4 2023-05-04

Publications (1)

Publication Number Publication Date
WO2024228165A1 true WO2024228165A1 (fr) 2024-11-07

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WO (1) WO2024228165A1 (fr)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1946068A (en) 1930-08-01 1934-02-06 Friedrich Hans Method of treating polyhalite
US4246019A (en) 1979-02-21 1981-01-20 Sokolov Igor D Method of producing a complex mineral fertilizer
WO2013074328A1 (fr) 2011-11-14 2013-05-23 Intercontinential Potash Corp. (Usa) Procédés de traitement d'un minerai de polyhalite, procédés de production de sulfate de potassium, et systèmes associés
GB2530757A (en) 2014-09-30 2016-04-06 Sirius Minerals Plc Pelletising process
GB2533490A (en) 2015-12-29 2016-06-22 Christopher Holt John Thermally broken truss
WO2019167036A1 (fr) * 2018-02-27 2019-09-06 Dead Sea Works Ltd. Processus de granulation de poussière de potasse
GB2577866A (en) 2018-09-27 2020-04-15 York Potash Ltd Pellet re-processing
GB2577865A (en) * 2018-09-27 2020-04-15 York Potash Ltd Binder compositions
GB2586121A (en) * 2019-07-30 2021-02-10 York Potash Ltd Composite fertiliser pellet

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1946068A (en) 1930-08-01 1934-02-06 Friedrich Hans Method of treating polyhalite
US4246019A (en) 1979-02-21 1981-01-20 Sokolov Igor D Method of producing a complex mineral fertilizer
WO2013074328A1 (fr) 2011-11-14 2013-05-23 Intercontinential Potash Corp. (Usa) Procédés de traitement d'un minerai de polyhalite, procédés de production de sulfate de potassium, et systèmes associés
GB2530757A (en) 2014-09-30 2016-04-06 Sirius Minerals Plc Pelletising process
GB2533490A (en) 2015-12-29 2016-06-22 Christopher Holt John Thermally broken truss
WO2019167036A1 (fr) * 2018-02-27 2019-09-06 Dead Sea Works Ltd. Processus de granulation de poussière de potasse
GB2577866A (en) 2018-09-27 2020-04-15 York Potash Ltd Pellet re-processing
GB2577865A (en) * 2018-09-27 2020-04-15 York Potash Ltd Binder compositions
GB2586121A (en) * 2019-07-30 2021-02-10 York Potash Ltd Composite fertiliser pellet

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GB202306624D0 (en) 2023-06-21
GB2629628A (en) 2024-11-06

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