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WO2024048190A1 - Fil électrique recouvert et procédé de production de fil électrique recouvert - Google Patents

Fil électrique recouvert et procédé de production de fil électrique recouvert Download PDF

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Publication number
WO2024048190A1
WO2024048190A1 PCT/JP2023/028330 JP2023028330W WO2024048190A1 WO 2024048190 A1 WO2024048190 A1 WO 2024048190A1 JP 2023028330 W JP2023028330 W JP 2023028330W WO 2024048190 A1 WO2024048190 A1 WO 2024048190A1
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WO
WIPO (PCT)
Prior art keywords
polymer compound
fluorine
layer
containing polymer
electric wire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2023/028330
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English (en)
Japanese (ja)
Inventor
安利 中谷
英樹 河野
耕一郎 荻田
勝通 助川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daikin Industries Ltd
Original Assignee
Daikin Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daikin Industries Ltd filed Critical Daikin Industries Ltd
Publication of WO2024048190A1 publication Critical patent/WO2024048190A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06—Insulating conductors or cables
    • H01B13/14—Insulating conductors or cables by extrusion
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06—Insulating conductors or cables
    • H01B13/16—Insulating conductors or cables by passing through or dipping in a liquid bath; by spraying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/02—Disposition of insulation

Definitions

  • the present disclosure relates to a covered electric wire and a method for manufacturing the covered electric wire.
  • Patent Document 1 has a conductor and a first insulating layer formed on the outer periphery of the conductor, the first insulating layer is made of a thermosetting resin and a fluororesin, and the first insulating layer is made of a thermosetting resin and a fluororesin.
  • An electric wire characterized by the following is described.
  • the present disclosure aims to provide a covered wire that exhibits sufficient electrical characteristics.
  • a covered electric wire including a flat electric wire base material and a coating layer formed on the outer periphery of the flat electric wire base material, wherein the coating layer is formed on the outer periphery of the flat electric wire base material.
  • a polymer compound (1) comprising a first layer and a second layer formed on the outer periphery of the first layer, the first layer having one or both of an amide group and an imide group;
  • a covered electric wire formed from (2) is provided.
  • a covered electric wire exhibiting sufficient electrical properties is provided.
  • the covered electric wire of the present disclosure includes a rectangular electric wire base material and a coating layer formed on the outer periphery of the flat electric wire base material.
  • the shape of the rectangular electric wire base material is not particularly limited as long as the cross section is the shape of a rectangular wire having a substantially rectangular shape.
  • the corners of the cross section of the flat electric wire base material may be at right angles, or the corners of the cross section of the flat electric wire base material may be rounded.
  • the rectangular electric wire base material may be a single wire, a grouped wire, a stranded wire, etc. as long as the entire cross section is approximately rectangular, but a single wire is preferable.
  • the rectangular wire base material is not particularly limited as long as it is made of a conductive material, but it can be made of materials such as copper, copper alloy, aluminum, aluminum alloy, iron, silver, and nickel. Preferably, it is made of an alloy, aluminum or an aluminum alloy. Further, a rectangular electric wire base material plated with silver plating, nickel plating, etc. can also be used. As the copper, oxygen-free copper, low-oxygen copper, copper alloy, etc. can be used.
  • the width of the cross section of the flat electric wire base material may be 1 to 75 mm, and the thickness of the cross section of the flat electric wire base material may be 0.1 to 30 mm.
  • the outer circumferential diameter of the rectangular electric wire base material may be 6.5 mm or more and 200 mm or less. Further, the ratio of width to thickness may be greater than 1 and less than or equal to 30.
  • the surface roughness Sz of the flat wire base material is preferably 0.2 to 12 ⁇ m, more preferably 1 ⁇ m or more, and even more preferably 5 ⁇ m, since the flat wire base material and the coating layer adhere more firmly. or more, and more preferably 10 ⁇ m or less.
  • the surface roughness of the flat wire base material can be adjusted by surface treating the flat wire base material using a surface treatment method such as etching treatment, blasting treatment, laser treatment, or the like. Further, the surface of the rectangular electric wire base material may be provided with irregularities by surface treatment.
  • the distance between the convex and convex portions is preferably as small as possible, and is, for example, 5 ⁇ m or less. Further, regarding the size of the unevenness, for example, the area of each concave portion when cutting the convex portions on the unprocessed surface is 1 ⁇ m 2 or less.
  • the uneven shape may be a single crater-shaped uneven shape, or may be branched like an ant nest.
  • the covering layer included in the covered wire of the present disclosure includes at least a first layer and a second layer.
  • the first layer is formed on the outer periphery of the flat wire base material
  • the second layer is formed on the outer periphery of the first layer.
  • the covering layer further includes a third layer, the third layer is formed around the second layer.
  • Each layer is a coating formed from a coating composition or an extrudate formed from an extrusion molding composition.
  • a liquid coating composition or a powder coating composition is used as the coating composition.
  • the liquid coating composition contains a solvent along with a polymer compound or a fluorine-containing polymer compound.
  • the powder coating composition contains powder of a polymer compound or a fluorine-containing polymer compound. In the present disclosure, whether the powder coating contains only powder of a polymer compound or only powder of a fluorine-containing polymer compound, the powder coating The term "powder coating composition" is used even when it does not contain multiple components.
  • the extrusion molding composition is a composition containing a fluorine-containing polymer compound, or a composition containing a fluorine-containing polymer compound and other components.
  • the layers included in the covering layer are extrudates formed from the extrusion composition by an extrusion process. Extrudates can easily form thicker layers than coatings.
  • the extrudate thickness may be 90 ⁇ m or more, and the coating thickness (thickness of the layer formed from the coating composition) may be less than 90 ⁇ m. good.
  • the dielectric constant of the coating layer is preferably 2.0 to 2.4, more preferably 2.3 or less. Since the coated wire of the present disclosure is obtained by appropriately combining the constituent materials and formation methods of the layers, the dielectric constant of the coating layer can be lowered.
  • the partial discharge inception voltage of the coating layer is preferably 1,500 to 3,500 (Vp), more preferably 1,700 (Vp) or higher, and even more preferably 1,900 (Vp) or higher. Since the covered wire of the present disclosure has an appropriate combination of layer constituent materials and formation methods, the partial discharge inception voltage of the coating layer can be increased.
  • the partial discharge inception voltage of the coating layer satisfies the following formula. Since the covered wire of the present disclosure has an appropriate combination of layer constituent materials and formation methods, it is possible to increase the partial discharge inception voltage. Partial discharge starting voltage (Vp) ⁇ 6.5 ⁇ t+1100 (t: Thickness of the coating layer ( ⁇ m))
  • the covered wire according to the first embodiment includes a coating layer including at least a first layer and a second layer.
  • the first layer is formed on the outer periphery of the rectangular electric wire base material
  • the second layer is formed on the outer periphery of the first layer.
  • the first layer is formed from a composition (1) containing a polymer compound (1) having one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1).
  • the second layer is formed from the fluorine-containing polymer compound (2) or the composition (2) containing the fluorine-containing polymer compound (2).
  • the covering layer may further contain other layers as long as it contains the first layer and the second layer.
  • the covered wire according to the second embodiment includes a covering layer including a first layer and a second layer.
  • the first layer is formed on the outer periphery of the rectangular electric wire base material
  • the second layer is formed on the outer periphery of the first layer.
  • Fluorine-containing polymer compounds have non-adhesive properties, so when providing a coating layer containing a fluorine-containing polymer compound on a rectangular electric wire base material of a covered electric wire, the flat electric wire base material and the coating layer must be There is a problem that the adhesive does not adhere with sufficient strength. Therefore, when a conventional covered electric wire is bent or bent, there is a problem that the coating layer is lifted from the rectangular electric wire base material or wrinkles are generated in the coating layer.
  • the coating layer is formed of a material that easily adheres to the rectangular wire base material, the dielectric constant of the coating layer of the covered wire will increase, the partial discharge inception voltage of the covered wire will decrease, and the electrical There is a problem in that it is difficult to obtain a coated wire with excellent performance.
  • the covered wire according to the second embodiment is one in which the constituent materials and forming methods of the two layers are appropriately combined. Therefore, the covered wire according to the second embodiment exhibits a low dielectric constant and a high partial discharge inception voltage, and the coating layer is less likely to wrinkle even when bent, and the rectangular wire base material and the coating layer have high adhesion strength. It is closely attached.
  • the first layer is A layer formed from a liquid coating composition (1) containing a polymer compound (1) having one or both of an amide group and an imide group and a fluorine-containing polymer compound (1), or This layer is formed from a powder coating composition (1) containing a polymer compound (1) having either or both of an amide group and an imide group, and a fluorine-containing polymer compound (1).
  • the second layer is A layer formed from a liquid coating composition (2) containing a fluorine-containing polymer compound (2-1), A layer formed from a powder coating composition (2) containing a fluorine-containing polymer compound (2-2), or This is a layer formed by extrusion molding of the fluorine-containing polymer compound (2-3).
  • the first layer is a coating film formed from the liquid coating composition (1) or the powder coating composition (1).
  • the liquid coating composition (1) includes a polymer compound (1) having one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1).
  • the powder coating composition (1) contains a polymer compound (1) having one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1).
  • the second layer is a coating film formed from the liquid coating composition (2) or the powder coating composition (2), or a coating film formed from at least a fluorine-containing polymer compound ( This is an extrudate formed from an extrusion molding composition containing 2-3).
  • the liquid coating composition (2) contains a fluorine-containing polymer compound (2-1).
  • a fluorine-containing polymer compound (2-1) By applying the liquid coating composition (2) to the outer periphery of the first layer to form the second layer, a low dielectric constant and a high partial discharge inception voltage are imparted to the coating layer, and the coating layer is also bonded to the first layer. By adhering sufficiently, it is possible to form a second layer that provides a coating layer with excellent interlayer strength.
  • the powder coating composition (2) contains a fluorine-containing polymer compound (2-2).
  • a fluorine-containing polymer compound (2-2) By applying the powder coating composition (2) to the outer periphery of the first layer to form the second layer, a low dielectric constant and a high partial discharge inception voltage are imparted to the coating layer, and the first layer By sufficiently adhering to the second layer, it is possible to form a second layer that provides a coating layer with excellent interlayer strength.
  • the second layer may be a layer formed by extrusion molding of the fluorine-containing polymer compound (2-3).
  • a low dielectric constant and a high partial discharge inception voltage are imparted to the coating layer, and a second layer is formed on the outer periphery of the first layer.
  • the thickness of the coating layer is preferably 100 to 500 ⁇ m, more preferably 120 ⁇ m or more, still more preferably 140 ⁇ m or more, and even more preferably 400 ⁇ m or less, from the viewpoint of insulation properties. , more preferably 300 ⁇ m or less. If the thickness is too large, it may be difficult to downsize the device when the coated wire is used in a device such as a motor, and if the thickness is too small, sufficient insulation may not be obtained.
  • the thickness of the first layer is preferably 1 to 50 ⁇ m from the viewpoint of sufficiently adhering the rectangular electric wire base material and the coating layer and forming a coating layer that does not easily wrinkle even when bent. It is more preferably 3 ⁇ m or more, still more preferably 6 ⁇ m or more, more preferably 40 ⁇ m or less, and still more preferably 30 ⁇ m or less.
  • the thickness obtained by subtracting the thickness of the first layer from the thickness of the coating layer is preferably 50 to 450 ⁇ m, more preferably 75 ⁇ m or more, and Preferably it is 90 ⁇ m or more, more preferably 300 ⁇ m or less, and still more preferably 250 ⁇ m or less.
  • the thickness of the second layer has a low dielectric constant and From the viewpoint of providing a high partial discharge inception voltage to the coating layer and ensuring sufficient adhesion of the second layer to the first layer, the thickness is preferably 5 to 100 ⁇ m, more preferably 50 ⁇ m or more, and even more preferably 75 ⁇ m. or more, and more preferably less than 90 ⁇ m.
  • the thickness of the second layer has a low dielectric constant and a high partial discharge.
  • the thickness is preferably 25 to 400 ⁇ m, more preferably 50 ⁇ m or more, and even more preferably 75 ⁇ m or more. , still more preferably 90 ⁇ m or more, more preferably 290 ⁇ m or less, still more preferably 240 ⁇ m or less.
  • the coating layer may further include other layers as long as it includes the first layer and the second layer, but even if it does not include other layers, A covered electric wire that exhibits the desired effect can be obtained.
  • the covered wire according to the third embodiment includes a covering layer including a first layer, a second layer, and a third layer.
  • the first layer is formed on the outer periphery of the rectangular electric wire base material
  • the second layer is formed on the outer periphery of the first layer
  • the third layer is formed on the outer periphery of the rectangular electric wire base material. It is formed on the outer periphery of the second layer.
  • Fluorine-containing polymer compounds have non-adhesive properties, so when providing a coating layer containing a fluorine-containing polymer compound on a rectangular electric wire base material of a covered electric wire, the flat electric wire base material and the coating layer must be There is a problem that the adhesive does not adhere with sufficient strength. Therefore, when a conventional covered electric wire is bent or bent, there is a problem that the coating layer is lifted from the rectangular electric wire base material or wrinkles are generated in the coating layer.
  • the coating layer is formed of a material that easily adheres to the rectangular wire base material, the dielectric constant of the coating layer of the covered wire will increase, the partial discharge inception voltage of the covered wire will decrease, and the electrical There is a problem in that it is difficult to obtain a coated wire with excellent performance.
  • the covered wire according to the third embodiment is one in which the constituent materials and forming methods of the three layers are appropriately combined. Therefore, the coated wire according to the third embodiment exhibits a low dielectric constant and a high partial discharge inception voltage, and the coating layer is less likely to wrinkle even when bent, and the rectangular wire base material and the coating layer have high adhesion strength. It is closely attached.
  • the first layer is A layer formed from a liquid coating composition (1) containing a polymer compound (1) having one or both of an amide group and an imide group and a fluorine-containing polymer compound (1), or This layer is formed from a powder coating composition (1) containing a polymer compound (1) having either or both of an amide group and an imide group, and a fluorine-containing polymer compound (1).
  • the second layer is A layer formed from a liquid coating composition (2) containing a fluorine-containing polymer compound (2-1), or This layer is formed from a powder coating composition (2) containing a fluorine-containing polymer compound (2-2).
  • the third layer is This layer is formed by extrusion molding of the fluorine-containing polymer compound (3).
  • the first layer is a coating film formed from the liquid coating composition (1) or the powder coating composition (1).
  • the liquid coating composition (1) includes a polymer compound (1) having one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1).
  • the powder coating composition (1) contains a polymer compound (1) having one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1).
  • the second layer is a coating film formed from the liquid coating composition (1) or the powder coating composition (1).
  • the liquid coating composition (2) contains a fluorine-containing polymer compound (2-1).
  • a fluorine-containing polymer compound (2-1) By applying the liquid coating composition (2) to the outer periphery of the first layer to form the second layer, a low dielectric constant and a high partial discharge inception voltage are imparted to the coating layer, and the first layer and By sufficiently adhering to the third layer, it is possible to form a second layer that provides a coating layer with excellent interlayer strength.
  • the powder coating composition (2) contains a fluorine-containing polymer compound (2-2).
  • a fluorine-containing polymer compound (2-2) By applying the powder coating composition (2) to the outer periphery of the first layer to form the second layer, a low dielectric constant and a high partial discharge inception voltage are imparted to the coating layer, and the first layer By sufficiently adhering to the third layer, it is possible to form a second layer that provides a coating layer with excellent interlayer strength.
  • the third layer is formed from the fluorine-containing polymer compound (3) or an extrusion molding composition containing the fluorine-containing polymer compound (3) and other components by an extrusion method. It is an extrudate.
  • a low dielectric constant and a high partial discharge inception voltage are imparted to the coating layer, and the second layer is By sufficiently adhering to the third layer, it is possible to form a third layer that provides a coating layer with excellent interlayer strength.
  • the thickness of the coating layer is preferably 100 to 500 ⁇ m, more preferably 120 ⁇ m or more, still more preferably 140 ⁇ m or more, and even more preferably 400 ⁇ m or less, from the viewpoint of insulation properties. , more preferably 300 ⁇ m or less. If the thickness is too large, it may be difficult to downsize the device when the coated wire is used in a device such as a motor, and if the thickness is too small, sufficient insulation may not be obtained.
  • the thickness of the first layer is preferably 1 to 50 ⁇ m from the viewpoint of sufficiently adhering the rectangular electric wire base material and the coating layer and forming a coating layer that does not easily wrinkle when bent. It is more preferably 3 ⁇ m or more, still more preferably 6 ⁇ m or more, more preferably 40 ⁇ m or less, and still more preferably 30 ⁇ m or less.
  • the thickness obtained by subtracting the thickness of the first layer from the thickness of the coating layer, that is, the sum of the thickness of the second layer and the third thickness is preferably 50 to 450 ⁇ m, more preferably is 75 ⁇ m or more, more preferably 90 ⁇ m or more, more preferably 300 ⁇ m or less, and even more preferably 250 ⁇ m or less.
  • the thickness of the second layer provides the covering layer with a low dielectric constant and a high partial discharge inception voltage, and the thickness of the second layer is such that the second layer is sufficiently thick with the first layer and the third layer.
  • the thickness is preferably 5 to 100 ⁇ m, more preferably 50 ⁇ m or more, even more preferably 75 ⁇ m or more, and even more preferably less than 90 ⁇ m.
  • the thickness of the third layer is determined from the viewpoint of providing a low dielectric constant and a high partial discharge inception voltage to the coating layer, and also ensuring that the third layer is in sufficient contact with the second layer. It is preferably 25 to 400 ⁇ m, more preferably 50 ⁇ m or more, even more preferably 75 ⁇ m or more, even more preferably 90 ⁇ m or more, more preferably 290 ⁇ m or less, and even more preferably 240 ⁇ m or less.
  • the third embodiment may further include other layers, but it does not need to include other layers. , it is possible to obtain a covered electric wire that exhibits the desired effect.
  • the first layer is formed from a liquid coating composition (1) or a powder coating composition (1).
  • the liquid coating composition (1) includes a polymer compound (1) having one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1).
  • the liquid coating composition (1) may contain only a polymer compound (1) having one or both of an amide group and an imide group and a fluorine-containing polymer compound (1) as a polymer compound. .
  • the liquid coating composition (1) may contain a solvent in addition to the polymer compound (1) and the fluorine-containing polymer compound (1).
  • the solvent include water and organic solvents.
  • organic solvents include N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N-butyl-2-pyrrolidone, 3-methoxy-N,N-dimethylpropanamide, N,N-dimethylacetamide, N, Examples include N-dimethylformamide, cresol, and methyl isobutyl ketone.
  • the viscosity of the liquid coating composition (1) is preferably 10 to 10,000 (cP), more preferably 50 (cP) or more, and even more preferably It is 100 (cP) or more, more preferably 1000 (cP) or less, and still more preferably 500 (cP) or less.
  • the viscosity of the liquid coating composition (1) can be adjusted by adjusting the contents of the polymer compound (1) and the fluorine-containing polymer compound (1) in the liquid coating composition (1).
  • the content of the polymer compound (1) and the fluorine-containing polymer compound (1) in the liquid coating composition (1) is preferably 1 to 90% by weight based on the mass of the liquid coating composition (1).
  • the content is more preferably 10% by weight or more, and more preferably 80% by weight or less.
  • the powder coating composition (1) contains a polymer compound (1) having one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1).
  • the polymer compound (1) and the fluorine-containing polymer compound (1) in the powder coating composition (1) are usually both powders.
  • the powder coating composition (1) contains only a polymer compound (1) having one or both of an amide group and an imide group and a fluorine-containing polymer compound (1) as a polymer compound. good.
  • the average particle size of the powder coating composition (1) is preferably 1 to 100 ( ⁇ m), more preferably 5 ⁇ m or more, and even more preferably It is 10 ⁇ m or more, more preferably 90 ⁇ m or less, and still more preferably 80 ⁇ m or less.
  • the volume ratio of the polymer compound (1) and the fluorine-containing polymer compound (1) is such that the coating layer has a low dielectric constant and a high partial discharge. From the viewpoint of sufficiently adhering the coating layer to the rectangular conductor base material without impairing the starting voltage, the ratio is preferably 10/90 to 90/10, more preferably 15/85 or more, and even more preferably 85/ 15 or less.
  • the liquid coating composition (1) or the powder coating composition (1) may contain other components as necessary.
  • Other ingredients include crosslinking agents, antistatic agents, heat stabilizers, foaming agents, foaming nucleating agents, antioxidants, surfactants, photopolymerization initiators, antiwear agents, surface modifiers, organic and inorganic various pigments, copper damage inhibitors, bubble preventers, adhesion promoters, lubricants, processing aids, colorants, phosphorus stabilizers, lubricants, mold release agents, sliding materials, ultraviolet absorbers, dyes and pigments, reinforcements.
  • additives such as materials, anti-drip agents, fillers, curing agents, ultraviolet curing agents, and flame retardants.
  • the content of other components in the liquid coating composition (1) or powder coating composition (1) is as follows: ) and the fluorine-containing polymer compound (1), preferably less than 30% by weight, more preferably less than 10% by weight, even more preferably 5% by weight or less, and the lower limit is not particularly limited. may be 0% by weight or more. That is, the liquid coating composition (1) or the powder coating composition (1) does not need to contain other components.
  • the second layer can be formed from a liquid coating composition (2) or a powder coating composition (2).
  • the liquid coating composition (2) contains a fluorine-containing polymer compound (2-1).
  • the liquid coating composition (2) may contain only the fluorine-containing polymer compound (2-1) as the polymer compound.
  • the liquid coating composition (2) may contain a solvent in addition to the fluorine-containing polymer compound (2-1).
  • the solvent include water and organic solvents.
  • organic solvents include N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N-butyl-2-pyrrolidone, 3-methoxy-N,N-dimethylpropanamide, N,N-dimethylacetamide, N, Examples include N-dimethylformamide, cresol, and methyl isobutyl ketone.
  • the viscosity of the liquid coating composition (2) is preferably 10 to 10,000 (cP), more preferably 50 (cP) or more, and even more preferably It is 100 (cP) or more, more preferably 1000 (cP) or less, and still more preferably 500 (cP) or less.
  • the viscosity of the liquid coating composition (2) can be adjusted by adjusting the content of the fluorine-containing polymer compound (2-1) in the liquid coating composition (2).
  • the content of the fluorine-containing polymer compound (2-1) in the liquid coating composition (2) is preferably 1 to 90% by weight, more preferably 1 to 90% by weight based on the mass of the liquid coating composition (2). It is 10% by weight or more, more preferably 80% by weight or less.
  • the powder coating composition (2) contains a fluorine-containing polymer compound (2-2).
  • the fluorine-containing polymer compound (2-2) in the powder coating composition (2) is usually a powder.
  • the powder coating composition (2) may contain only the fluorine-containing polymer compound (2-2) as the polymer compound.
  • the average particle size of the powder coating composition (2) is preferably 1 to 100 ( ⁇ m), more preferably 5 ⁇ m or more, and even more preferably It is 10 ⁇ m or more, more preferably 90 ⁇ m or less, and still more preferably 80 ⁇ m or less.
  • the liquid coating composition (2) or powder coating composition (2) may contain other components as necessary.
  • Other ingredients include crosslinking agents, antistatic agents, heat stabilizers, foaming agents, foaming nucleating agents, antioxidants, surfactants, photopolymerization initiators, antiwear agents, surface modifiers, organic and inorganic various pigments, copper damage inhibitors, anti-bubble agents, adhesion promoters, lubricants, processing aids, colorants, phosphorus stabilizers, lubricants, mold release agents, sliding materials, ultraviolet absorbers, dyes and pigments, reinforcements.
  • additives such as materials, anti-drip agents, fillers, curing agents, ultraviolet curing agents, and flame retardants.
  • the content of other components in the liquid coating composition (2) or powder coating composition (2) includes the fluorine-containing polymer compound in the liquid coating composition (2) or powder coating composition (2). It is preferably less than 30% by weight, more preferably less than 10% by weight, and even more preferably 5% by weight or less, based on the mass of (2-1) or the fluorine-containing polymer compound (2-2). Although the lower limit is not particularly limited, it may be 0% by weight or more. That is, the liquid coating composition (2) or the powder coating composition (2) does not need to contain other components.
  • the second layer may be formed by extrusion molding of the fluorine-containing polymer compound (2-3).
  • the third layer is formed by extrusion molding of the fluorine-containing polymer compound (3).
  • the fluorine-containing polymer compound (2-3) and the fluorine-containing polymer compound (3) will be described in detail later.
  • the second layer or the third layer may contain other components as necessary.
  • Other ingredients include crosslinking agents, antistatic agents, heat stabilizers, foaming agents, foaming nucleating agents, antioxidants, surfactants, photopolymerization initiators, antiwear agents, surface modifiers, organic and inorganic various pigments, copper damage inhibitors, bubble preventers, adhesion promoters, lubricants, processing aids, colorants, phosphorus stabilizers, lubricants, mold release agents, sliding materials, ultraviolet absorbers, dyes and pigments, reinforcements.
  • additives such as materials, anti-drip agents, fillers, curing agents, ultraviolet curing agents, and flame retardants.
  • the content of other components in the second layer or the third layer is as follows: the fluorine-containing polymer compound (2-3) or the fluorine-containing polymer compound (3) in the second layer or the third layer; Based on the mass of good. That is, the second layer or the third layer does not need to contain other components.
  • polymer compound used for the coating layer of the covered electric wire
  • the polymer compound described below can be suitably used as the polymer compound (1) forming the first layer.
  • a "polymer compound” has one or both of an amide group and an imide group, and preferably does not have a fluorine atom.
  • the polymer compound can have an amide group (amide bond) or an imide group (imide bond) in the main chain or side chain of the polymer compound.
  • the polymer compound is preferably at least one selected from the group consisting of polyamideimide, polyetherimide, polyimide, and thermoplastic polyimide from the viewpoint of adhesion to the rectangular wire base material or adhesion to other layers. At least one selected from the group consisting of , polyamideimide, and polyimide is more preferable. Furthermore, as the polymer compound, two or more types of polymer compounds can be used in combination. For example, a combination of polyamideimide and polyimide can be used as the polymer compound.
  • Polyamide-imide is a resin consisting of a polymer having amide bonds and imide bonds in its molecular structure.
  • the polyamideimide is not particularly limited, and includes, for example, a reaction between an aromatic diamine having an amide bond in the molecule and an aromatic tetravalent carboxylic acid such as pyromellitic acid; and a reaction with an aromatic trivalent carboxylic acid such as trimellitic anhydride.
  • Consists of high molecular weight polymers obtained by various reactions such as reaction with diamines such as 4,4-diaminophenyl ether and diisocyanates such as diphenylmethane diisocyanate; reaction with diamines and dibasic acids having an aromatic imide ring in the molecule. Examples include resin.
  • the polyamideimide is preferably a polymer having an aromatic ring in the main chain.
  • Polyimide is a resin made of a polymer that has imide bonds in its molecular structure.
  • the polyimide is not particularly limited, and examples include resins made of high molecular weight polymers obtained by reaction of aromatic tetravalent carboxylic acid anhydrides such as pyromellitic anhydride.
  • the polyimide is preferably a polymer having an aromatic ring in the main chain.
  • the fluorine-containing polymer compounds described below include the fluorine-containing polymer compound (1) forming the first layer, the fluorine-containing polymer compound (2) forming the second layer, and the fluorine-containing polymer compound (2) forming the second layer. -1), the fluorine-containing polymer compound (2-2), the fluorine-containing polymer compound (2-3), and the fluorine-containing polymer compound (3) forming the third layer. can.
  • a fluorine-containing polymer compound is a polymer compound having a fluorine atom.
  • a fluorine-containing polymer compound is usually a polymer compound in which hydrogen atoms bonded to carbon atoms constituting the main chain are partially or completely replaced with fluorine atoms.
  • a perfluorinated polymer compound is preferable because a coating layer exhibiting a lower dielectric constant and a higher partial discharge inception voltage can be obtained.
  • a perfluoro-based polymer compound is a polymer compound in which the content of perfluoro monomer units is 90 mol% or more with respect to all polymerized units constituting the polymer compound.
  • a perfluoromonomer is a monomer that does not contain a carbon atom-hydrogen bond in its molecule.
  • perfluoromonomers may also be monomers in which some of the fluorine atoms bonded to carbon atoms are replaced with chlorine atoms, and in addition to carbon atoms, nitrogen atoms, oxygen atoms, It may contain a sulfur atom, a phosphorus atom, a boron atom, or a silicon atom.
  • the perfluoromonomer is preferably a monomer in which all hydrogen atoms are replaced with fluorine atoms.
  • the dielectric constant of the fluorine-containing polymer compound is preferably 2.0 to 2.2, more preferably 2.0 to 2.2, since a coating layer exhibiting a lower dielectric constant and a higher partial discharge inception voltage can be obtained. 1 or less.
  • the dielectric constant of the fluorine-containing polymer compound can be measured at 23° C. ⁇ 2° C., relative humidity 50%, and frequency 1 KHz in accordance with JIS-C-2138.
  • fluororesin refers to partially crystalline fluoropolymers and fluoroplastics.
  • the fluororesin has a melting point and is thermoplastic, but may be melt processable or non-melt processable.
  • fluororesins examples include polytetrafluoroethylene, tetrafluoroethylene (TFE)/fluoroalkyl vinyl ether (FAVE) copolymer, tetrafluoroethylene (TFE)/hexafluoropropylene (HFP) copolymer, and TFE/FAVE/HFP copolymer.
  • fluororesin at least one selected from the group consisting of polytetrafluoroethylene, TFE/FAVE copolymer, TFE/HFP copolymer, and TFE/FAVE/HFP copolymer is particularly preferred.
  • Polytetrafluoroethylene may be non-melt processable PTFE or melt processable PTFE, but non-melt processable PTFE is preferable.
  • Non-melt processable PTFE typically has stretchability, fibrillation properties, and non-melt fabrication properties.
  • Non-melt fabrication property refers to a property in which the melt flow rate cannot be measured at a temperature higher than the crystallization melting point, that is, a property that does not flow easily even in the melting temperature range, in accordance with ASTM D 1238 and D 2116.
  • PTFE may be a tetrafluoroethylene (TFE) homopolymer or may be a modified PTFE containing a TFE unit and a modified monomer unit.
  • modified PTFE means a product obtained by copolymerizing TFE with a small amount of comonomer that does not impart melt processability to the resulting copolymer.
  • the comonomer is not particularly limited, and examples thereof include hexafluoropropylene [HFP], chlorotrifluoroethylene [CTFE], perfluoro(alkyl vinyl ether) [PAVE], and the like.
  • the proportion of the comonomer added to the modified PTFE varies depending on its type, but for example, it may be 0.001 to 1% by mass based on the total mass of TFE and a small amount of comonomer. preferable.
  • the content of each monomer unit constituting PTFE can be calculated by appropriately combining NMR, FT-IR, elemental analysis, and fluorescent X-ray analysis depending on the type of monomer.
  • the standard specific gravity (SSG) of PTFE is preferably 2.280 or less, more preferably 2.210 or less, even more preferably 2.200 or less, and preferably 2.130 or more. . SSG can be measured by a water displacement method according to ASTM D 792 using a sample molded according to ASTM D 4895-89.
  • PTFE has a peak temperature in the range of 333 to 347°C. More preferably, the temperature is 335°C or higher and 345°C or lower.
  • the peak temperature is the temperature corresponding to the maximum value in the heat of fusion curve when heated at a rate of 10 °C/min using a differential scanning calorimeter [DSC] for PTFE that has no history of being heated to a temperature of 300 °C or higher. be.
  • a melt-processable fluorine-containing polymer compound can also be used.
  • the fluorine-containing polymer compound (2-2) and the fluorine-containing polymer compound (2-3) for forming the second layer, as well as the fluorine-containing polymer compound (2-3) As the fluorine-containing polymer compound (3) for forming layer 3, it is preferable to use a melt-processable fluorine-containing polymer compound.
  • a melt-processable fluorine-containing polymer compound (1) contained in the powder coating composition (1) for forming the first layer is It is preferable to use a fluorine-containing polymer compound.
  • melt processability means that the polymer can be melted and processed using conventional processing equipment such as extruders and injection molding machines. Therefore, melt processable fluorine-containing polymer compounds usually have a melt flow rate of 0.01 to 500 g/10 minutes.
  • the melt flow rate of the fluorine-containing polymer compound is preferably 0.1 to 100 g/10 minutes, more preferably 80 g/10 minutes or less, even more preferably 70 g/10 minutes or less, and preferably 5 g/10 minutes. It is 10 minutes or more, more preferably 10 g/10 minutes or more.
  • the melt flow rate of the fluorine-containing polymer compound is calculated per 10 minutes from a nozzle with an inner diameter of 2.1 mm and a length of 8 mm at 372°C and under a load of 5 kg using a melt indexer (manufactured by Yasuda Seiki Seisakusho Co., Ltd.) according to ASTM D1238. This is the value obtained as the mass of polymer flowing out (g/10 minutes).
  • the melting point of the fluorine-containing polymer compound is preferably 200 to 322°C, more preferably 230°C or higher, even more preferably 250°C or higher, and even more preferably 320°C or lower.
  • the melting point can be measured using a differential scanning calorimeter (DSC).
  • DSC differential scanning calorimeter
  • melt-processable fluorine-containing polymer compound a melt-processable fluororesin is preferable.
  • melt-processable fluororesins include tetrafluoroethylene (TFE)/fluoroalkyl vinyl ether (FAVE) copolymer, tetrafluoroethylene (TFE)/hexafluoropropylene (HFP) copolymer, and TFE/FAVE/HFP copolymer.
  • melt-processable fluororesin at least one selected from the group consisting of TFE/FAVE copolymer, TFE/HFP copolymer, and TFE/FAVE/HFP copolymer is particularly preferred.
  • a TFE/FAVE copolymer is a copolymer containing tetrafluoroethylene (TFE) units and fluoroalkyl vinyl ether (FAVE) units.
  • Y 1 represents F or CF 3
  • Rf represents a perfluoroalkyl group having 1 to 5 carbon atoms
  • p represents an integer of 0 to 5
  • q represents an integer of 0 to 5.
  • a monomer represented by and general formula (2): CFX CXOCF 2 OR 1 (2) (wherein, X is the same or different and represents H, F or CF3 , and R1 represents at least one linear or branched atom selected from the group consisting of H, Cl, Br and I.
  • a fluoroalkyl group having 1 to 6 carbon atoms which may contain 1 to 2 atoms, or 1 to 2 atoms of at least one selected from the group consisting of H, Cl, Br and I
  • At least one type selected from the group consisting of monomers represented by can be mentioned.
  • FAVE is preferably a monomer represented by the general formula (1), consisting of perfluoro(methyl vinyl ether), perfluoro(ethyl vinyl ether) (PEVE), and perfluoro(propyl vinyl ether) (PPVE). At least one selected from the group consisting of PEVE and PPVE is more preferable, at least one selected from the group consisting of PEVE and PPVE is even more preferable, and PPVE is particularly preferable.
  • the content of FAVE units in the TFE/FAVE copolymer is preferably 1.0 to 30.0 mol%, more preferably 1.2 mol% or more, and even more preferably 1.4 mol% or more, still more preferably 1.6 mol% or more, particularly preferably 1.8 mol% or more, more preferably 3.5 mol% or less, even more preferably 3. .2 mol% or less, still more preferably 2.9 mol% or less, particularly preferably 2.6 mol% or less.
  • the content of TFE units in the TFE/FAVE copolymer is preferably 99.0 to 70.0 mol%, more preferably 96.5 mol% or more, and even more preferably 96.8 mol% or more, still more preferably 97.1 mol% or more, particularly preferably 97.4 mol% or more, more preferably 98.8 mol% or less, even more preferably 98 mol% .6 mol% or less, still more preferably 98.4 mol% or less, particularly preferably 98.2 mol% or less.
  • the content of each monomer unit in the copolymer is measured by 19 F-NMR method.
  • the TFE/FAVE copolymer can also contain monomer units derived from monomers copolymerizable with TFE and FAVE.
  • the content of the monomer copolymerizable with TFE and FAVE is preferably 0 to 29.0 mol%, more preferably 0.0 to 29.0 mol%, based on the total monomer units of the TFE/FAVE copolymer.
  • the content is 1 to 5.0 mol%, more preferably 0.1 to 1.0 mol%.
  • the TFE/FAVE copolymer is preferably at least one selected from the group consisting of a copolymer consisting only of TFE units and FAVE units, and the above-mentioned TFE/HFP/FAVE copolymer. More preferred is a copolymer consisting only of the following.
  • the melting point of the TFE/FAVE copolymer is preferably 280 to 322°C, more preferably 285°C or higher, more preferably 320°C or lower, and even more preferably 315°C or lower.
  • the melting point can be measured using a differential scanning calorimeter (DSC).
  • the glass transition temperature (Tg) of the TFE/FAVE copolymer is preferably 70 to 110°C, more preferably 80°C or higher, and even more preferably 100°C or lower. Glass transition temperature can be measured by dynamic viscoelasticity measurement.
  • a TFE/HFP copolymer is a copolymer containing tetrafluoroethylene (TFE) units and hexafluoropropylene (HFP) units.
  • the content of HFP units in the TFE/HFP copolymer is preferably 0.1 to 30.0 mol%, more preferably 0.7 mol% or more, and even more preferably It is 1.4 mol% or more, and more preferably 10.0 mol% or less.
  • the content of TFE units in the TFE/HFP copolymer is preferably 70.0 to 99.9 mol%, more preferably 90.0 mol% or more, and more preferably It is 99.3 mol% or less, more preferably 98.6 mol%.
  • the TFE/HFP copolymer can also contain monomer units derived from monomers copolymerizable with TFE and HFP.
  • the content of the monomer copolymerizable with TFE and HFP is preferably 0 to 29.9 mol %, more preferably 0.9 mol %, based on the total monomer units of the TFE/HFP copolymer.
  • the content is 1 to 5.0 mol%, more preferably 0.1 to 1.0 mol%.
  • the melting point of the TFE/HFP copolymer is preferably 200 to 322°C, more preferably 210°C or higher, even more preferably 220°C or higher, particularly preferably 240°C or higher, and more preferably 320°C or higher. °C or less, more preferably less than 300°C, particularly preferably 280°C or less.
  • the glass transition temperature (Tg) of the TFE/HFP copolymer is preferably 60 to 110°C, more preferably 65°C or higher, and even more preferably 100°C or lower.
  • the fluorine-containing polymer compound may have a functional group.
  • the functional group is preferably at least one selected from the group consisting of a carbonyl group-containing group, an amino group, a hydroxy group, a -CF 2 H group, an olefin group, an epoxy group, and an isocyanate group.
  • R 6 is an alkyl group having 1 to 20 carbon atoms or an alkyl group having 2 to 20 carbon atoms containing an ether-bonding oxygen atom
  • R 3 examples include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, and the like.
  • R 4 examples include a methylene group, -CF 2 - group, -C 6 H 4 - group, etc.
  • R 5 examples include a methyl group, an ethyl group, a propyl group, an isopropyl group, Examples include butyl group.
  • R 7 include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, and the like.
  • R 8 and R 9 include a hydrogen atom, a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a phenyl group, and the like.
  • the hydroxy group is a group represented by -OH or a group containing a group represented by -OH.
  • -OH constituting a carboxyl group is not included in a hydroxy group.
  • Examples of the hydroxy group include -OH, methylol group, and ethylol group.
  • An olefinic group is a group having a carbon-carbon double bond.
  • -CR 10 CR 11 R 12
  • R 10 , R 11 and R 12 may be the same or different and are a hydrogen atom, a fluorine atom, or a monovalent organic group having 1 to 20 carbon atoms.
  • examples of the functional group include non-fluorinated alkyl groups or partially fluorinated alkyl groups such as -CH 3 group and -CFH 2 group.
  • the number of functional groups in the fluorine-containing polymer compound is preferably 5 to 2000 per 10 6 carbon atoms.
  • the number of functional groups per 10 6 carbon atoms is more preferably 50 or more, still more preferably 100 or more, particularly preferably 200 or more, more preferably 1000 or less, and
  • the number is preferably 800 or less, particularly preferably 700 or less, and most preferably 500 or less.
  • the number of functional groups of the fluorine-containing polymer compound may be less than 5 per 10 6 carbon atoms, and may be 0 to 4, since a coating layer with excellent electrical properties can be formed.
  • the fluorine-containing polymer compound has melt processability, it is preferable to have the number of functional groups within the above numerical range.
  • the above-mentioned functional group is a functional group present at the main chain end or side chain end of the fluorine-containing polymer compound, and a functional group present in the main chain or side chain, preferably at the main chain end.
  • -COOH includes a dicarboxylic acid anhydride group (-CO-O-CO-) formed by bonding two -COOHs.
  • Infrared spectroscopy can be used to identify the type of functional group and measure the number of functional groups.
  • the absorption frequencies of -CH 2 CF 2 H, -CH 2 COF, -CH 2 COOH, -CH 2 COOCH 3 and -CH 2 CONH 2 are shown in the table, respectively.
  • the absorption frequency is several tens of Kaiser (cm -1 ) lower than that of COOH free, -COOH bonded, -COOCH 3 , and -CONH 2 . Therefore, for example, the number of functional groups in -COF is the number of functional groups determined from the absorption peak at absorption frequency 1883 cm -1 due to -CF 2 COF and the absorption peak at absorption frequency 1840 cm -1 due to -CH 2 COF. This is the sum of the calculated number of functional groups.
  • the above-mentioned functional group is introduced into the fluorine-containing polymer compound by, for example, a chain transfer agent or a polymerization initiator used in producing the fluorine-containing polymer compound.
  • a chain transfer agent or a polymerization initiator used in producing the fluorine-containing polymer compound.
  • -CH 2 OH is introduced at the end of the main chain of the fluorine-containing polymer compound. be done.
  • the functional group is introduced into the end of the side chain of the fluorine-containing polymer compound.
  • the fluorine-containing polymer compound may contain units derived from a monomer having a functional group.
  • Examples of the monomer having a functional group include a dicarboxylic acid anhydride group ((-CO-O-CO-) and a cyclic carbonized monomer having a polymerizable unsaturated group in the ring) described in JP-A No. 2006-152234. Hydrogen monomers, monomers having a functional group (f) described in International Publication No. 2017/122743, etc. are mentioned. Examples of monomers having a functional group include monomers having a carboxy group (maleic, etc.).
  • monomers having an acid anhydride group examples include monomers having a hydroxyl group or an epoxy group (hydroxybutyl vinyl ether, glycidyl vinyl ether, etc.).
  • the fluorine-containing polymer compound can be produced by conventionally known methods such as, for example, appropriately mixing monomers serving as its constituent units and additives such as a polymerization initiator, and performing emulsion polymerization or suspension polymerization. .
  • the covered wire according to the first embodiment is, for example, Forming a first layer on the outer periphery of a rectangular electric wire base material using composition (1), Produced by a manufacturing method in which a second layer is formed on the outer periphery of a first layer using a fluorine-containing polymer compound (2) or a composition (2) containing a fluorine-containing polymer compound (2). Can be done.
  • the covered wire according to the second embodiment is, for example, Forming a first layer by applying a liquid coating composition (1) or a powder coating composition (1) to the outer periphery of a rectangular electric wire base material,
  • the second layer is formed by applying the liquid coating composition (2) or the powder coating composition (2) to the outer periphery of the first layer, or the fluorine-containing polymer compound is formed by extrusion molding. (2-3) can be manufactured by a manufacturing method in which the second layer is formed by extruding it onto the outer periphery of the first layer.
  • the covered wire according to the third embodiment is Forming a first layer by applying a liquid coating composition (1) or a powder coating composition (1) to the outer periphery of a rectangular electric wire base material, Forming a second layer by applying a liquid coating composition (2) or a powder coating composition (2) to the outer periphery of the first layer,
  • the third layer can be produced by extruding the fluorine-containing polymer compound (3) onto the outer periphery of the second layer using an extrusion method.
  • the method of forming a layer by applying a liquid coating composition is not particularly limited, and examples include methods such as spray coating, roll coating, coating with a doctor blade, dip coating, and impregnation coating.
  • a layer may be formed by applying the liquid coating composition and then drying and/or baking the resulting coating film. Drying can be carried out by a conventionally known method, and is preferably carried out at a temperature of 60 to 200°C for 5 to 60 minutes.
  • the firing can be carried out by a conventionally known method, but it is preferably carried out for 5 to 60 minutes at a temperature equal to or higher than the melting point or curing temperature of the polymer compound or fluorine-containing polymer compound.
  • the baking may be performed each time the coating composition is applied, or after the coating composition is applied multiple times to form a plurality of layers (coating films).
  • the method of forming a layer by applying the powder coating composition is not particularly limited, and examples include methods such as electrostatic coating and fluidized dip coating.
  • the layer may be formed by applying the powder coating composition and then baking the resulting coating film.
  • the firing can be carried out by a conventionally known method, but it is preferably carried out for 5 to 60 minutes at a temperature equal to or higher than the melting point or curing temperature of the polymer compound or fluorine-containing polymer compound.
  • the baking may be performed each time the coating composition is applied, or after the coating composition is applied multiple times to form a plurality of layers (coating films).
  • An extrusion molding method is used to form a layer by extruding a fluorine-containing polymer compound. For example, using an extruder, a fluorine-containing polymer compound is heated and melted, and the molten fluorine-containing polymer compound is extruded onto a first layer or a second layer to form a layer. Can be done.
  • the type of extruder is not particularly limited, and the shape of the screw included in the extruder is also not particularly limited.
  • the extruder barrel is 30 mm ⁇
  • L/D is 24, the screw is in full flight
  • the compression ratio is 2.8
  • the temperature conditions for extrusion are C1 below the hopper, then C2, C3, and C4 in order, adjusting the temperature of the cylinder, head, and die.
  • the shape of the die is such that a rectangular electric wire base material is inserted perpendicularly to extrusion using a crosshead and coated with a fluorine-containing polymer compound.
  • the die/chip one adjusted according to the desired shape of the rectangular electric wire base material and coating thickness is used.
  • Cooling of the resin after extrusion coating can be controlled by taking into consideration air cooling, water cooling, thermal insulation cooling, and the desired physical properties of the fluorine-containing polymer compound and the physical properties of the electric wire.
  • the temperature setting when extruding the fluorine-containing polymer compound is adjusted by considering the melt viscosity and melting point of the fluorine-containing polymer compound.
  • the temperature at which the fluoropolymer compound is propelled forward is preferably 180 to 320°C.
  • C2, C3, and C4 are desirably 290 to 420°C so that the fluorine-containing polymer compound when melted can be stably sent to the head and die. If the temperature is low, productivity will deteriorate, while if the temperature is high, it will also cause deterioration of the fluorine-containing polymer compound. Molding is carried out by adjusting the residence time of the fluorine-containing polymer compound in the extruder, taking into consideration the screw rotation speed.
  • the temperature of each part of the head, die, and die is set at a temperature of 290 to 420° C., taking into consideration the shear rate of the fluorine-containing polymer compound. Furthermore, it is preferable to heat the rectangular electric wire base material and the rectangular electric wire base material coated with the inner layer before entering the crosshead because the adhesion can be improved. The temperature of the rectangular electric wire base material can be controlled within ⁇ 50° C. with respect to the temperature of the coating resin at the die exit.
  • the covered wire may be heat treated.
  • the heat treatment may be performed after forming the outermost layer, either before or after cooling.
  • the temperature of the heat treatment is usually higher than the glass transition point of the fluororesin, preferably 10 to 15° C. lower than the melting point of the fluororesin.
  • the coated electric wire of the present disclosure is, for example, a LAN cable, a USB cable, a Lightning cable, an HDMI cable, a QSFP cable, an aerospace electric wire, an underground power transmission cable, a submarine power cable, a high-voltage cable, a superconducting cable, a wrapped electric wire, and an automobile.
  • the coated wire of the present disclosure can be wound and used as a coil.
  • the coated wire and coil of the present disclosure can be suitably used in electrical equipment or electronic equipment such as motors, generators, and inductors. Further, the coated wire and coil of the present disclosure can be suitably used for on-vehicle electric equipment or on-vehicle electronic equipment, such as on-vehicle motors, on-vehicle generators, and on-vehicle inductors.
  • a covered electric wire comprising a flat electric wire base material and a coating layer formed on the outer periphery of the flat electric wire base material
  • the coating layer includes a first layer formed on the outer periphery of the rectangular electric wire base material, and a second layer formed on the outer periphery of the first layer
  • the first layer is formed from a composition (1) containing a polymer compound (1) having one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1)
  • a covered electric wire is provided in which the second layer is formed from a fluorine-containing polymer compound (2) or a composition (2) containing a fluorine-containing polymer compound (2).
  • the first layer is A layer formed from a liquid coating composition (1) containing a polymer compound (1) having one or both of an amide group and an imide group and a fluorine-containing polymer compound (1), or A layer formed from a powder coating composition (1) containing a polymer compound (1) having either one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1)
  • the second layer is A layer formed from a liquid coating composition (2) containing a fluorine-containing polymer compound (2-1), A layer formed from a powder coating composition (2) containing a fluorine-containing polymer compound (2-2), or A covered wire according to the first aspect is provided, which is a layer formed by extrusion molding of the fluorine-containing polymer compound (2-3).
  • the fluorine-containing polymer compound (1), the fluorine-containing polymer compound (2-1), the fluorine-containing polymer compound (2-2), or the fluorine-containing polymer compound (2-3) is a perfluorinated polymer compound.
  • a covered wire according to a second aspect is provided.
  • the dielectric constant of the fluorine-containing polymer compound (1), the fluorine-containing polymer compound (2-1), the fluorine-containing polymer compound (2-2), or the fluorine-containing polymer compound (2-3) is 2.0.
  • a coated wire according to the second or third aspect is provided which is ⁇ 2.2.
  • a covered electric wire according to any one of the second to fourth aspects is provided, wherein the fluorine-containing polymer compound (2-2) or the fluorine-containing polymer compound (2-3) has a melting point of 250 to 320°C.
  • the fluorine-containing polymer compound (1), the fluorine-containing polymer compound (2-1), the fluorine-containing polymer compound (2-2), or the fluorine-containing polymer compound (2-3) contains 5 carbon atoms per 10 6 carbon atoms.
  • a covered electric wire according to any one of the second to fifth aspects having 1000 pieces.
  • the coating layer further includes a third layer formed around the second layer
  • the first layer is A layer formed from a liquid coating composition (1) containing a polymer compound (1) having one or both of an amide group and an imide group and a fluorine-containing polymer compound (1), or A layer formed from a powder coating composition (1) containing a polymer compound (1) having either one or both of an amide group and an imide group, and a fluorine-containing polymer compound (1)
  • the second layer is A layer formed from a liquid coating composition (2) containing a fluorine-containing polymer compound (2-1), or A layer formed from a powder coating composition (2) containing a fluorine-containing polymer compound (2-2),
  • the third layer is A covered electric wire according to the first aspect is provided, which is a layer formed by extrusion molding of the fluorine-containing polymer compound (3).
  • the fluorine-containing polymer compound (1), the fluorine-containing polymer compound (2-1), the fluorine-containing polymer compound (2-2), or the fluorine-containing polymer compound (3) is a perfluorinated polymer compound.
  • a covered wire according to aspect 9 is provided.
  • the relative dielectric constant of the fluorine-containing polymer compound (1), the fluorine-containing polymer compound (2-1), the fluorine-containing polymer compound (2-2), or the fluorine-containing polymer compound (3) is 2.0 to 2.
  • any of the 9th to 11th fluorine-containing polymer compounds (2-2) or fluorine-containing polymer compounds (3) are at least one perfluorinated polymer compound having a melting point of 250 to 320°C.
  • a covered electric wire according to this aspect is provided.
  • the fluorine-containing polymer compound (1), the fluorine-containing polymer compound (2-1), the fluorine-containing polymer compound (2-2), or the fluorine-containing polymer compound (3) contains 5 to 1000 carbon atoms per 10 6 carbon atoms.
  • a covered electric wire according to any one of the ninth to twelfth aspects is provided.
  • MFR melt flow rate
  • a covered electric wire according to any one of the second to fifteenth aspects is provided, wherein the liquid coating composition (1) or the liquid coating composition (2) has a viscosity of 10 to 10,000 (cP).
  • the powder coating composition (1) or the powder coating composition (2) has an average particle size of 1 to 100 ( ⁇ m).
  • a covered wire according to any one of the first to seventeenth aspects wherein the polymer compound (1) is at least one selected from the group consisting of polyamideimide, polyetherimide, polyimide, and thermoplastic polyimide.
  • the polymer compound (1) is at least one selected from the group consisting of polyamideimide, polyetherimide, polyimide, and thermoplastic polyimide.
  • the volume ratio of the polymer compound (1) to the fluorine-containing polymer compound (1) is from 10/90 to 90/10.
  • a covered electric wire according to any one of the first to nineteenth aspects wherein the material forming the rectangular electric wire base material is at least one selected from the group consisting of copper, copper alloy, aluminum, and aluminum alloy.
  • the flat electric wire base material has a surface roughness Sz in a range of 0.2 to 12 ⁇ m.
  • a covered wire according to any one of the first to twenty-first aspects wherein the thickness of the coating layer is 100 to 500 ⁇ m, and the dielectric constant of the coating layer is 2.0 to 2.4.
  • the thickness obtained by subtracting the thickness of the first layer from the thickness of the coating layer is 50 to 300 ⁇ m.
  • the partial discharge inception voltage of the coating layer satisfies the following formula.
  • a method for manufacturing a covered electric wire according to a first aspect comprising: Forming a first layer on the outer periphery of the rectangular electric wire base material using the composition (1), A manufacturing method is provided in which a second layer is formed on the outer periphery of a first layer using a fluorine-containing polymer compound (2) or a composition (2) containing a fluorine-containing polymer compound (2). .
  • a method for manufacturing a covered electric wire comprising: Forming a first layer by applying a liquid coating composition (1) or a powder coating composition (1) to the outer periphery of the rectangular electric wire base material, The second layer is formed by applying the liquid coating composition (2) or the powder coating composition (2) to the outer periphery of the first layer, or the fluorine-containing polymer compound is formed by extrusion molding.
  • a manufacturing method is provided in which the second layer is formed by extruding (2-3) onto the outer periphery of the first layer.
  • a method for manufacturing a covered electric wire according to any one of the ninth to fifteenth aspects comprising: Forming a first layer by applying a liquid coating composition (1) or a powder coating composition (1) to the outer periphery of the rectangular electric wire base material, Forming a second layer by applying a liquid coating composition (2) or a powder coating composition (2) to the outer periphery of the first layer, A manufacturing method is provided in which the third layer is formed by extruding the fluorine-containing polymer compound (3) onto the outer periphery of the second layer using an extrusion method.
  • a motor including a covered electric wire according to any one of the first to twenty-fourth aspects is provided.
  • the fluorine-containing polymer compound was melted at 330 to 340° C. for 30 minutes and compression molded to produce a film with a thickness of 0.20 to 0.25 mm. This film was scanned 40 times using a Fourier transform infrared spectrometer [FT-IR (product name: Model 1760X, manufactured by PerkinElmer) and analyzed to obtain an infrared absorption spectrum. A difference spectrum was obtained from the base spectrum that does not exist. From the absorption peak of a specific functional group appearing in this difference spectrum, the number N of functional groups per 10 6 carbon atoms in the fluorine-containing polymer compound was calculated according to the following formula (A).
  • FT-IR product name: Model 1760X, manufactured by PerkinElmer
  • N I ⁇ K/t (A) I: Absorbance K: Correction coefficient t: Film thickness (mm)
  • the viscosity of the coating composition was measured using a B-type viscometer (BII-type viscometer manufactured by Toki Sangyo Co., Ltd.) as described in JIS Z8803. Rotating rotor #4 was used for the measurement. The measurement temperature was 25°C.
  • the average particle size of the powder coating composition was measured using a laser diffraction/scattering particle size distribution analyzer manufactured by Nikkiso Co., Ltd.
  • the median particle size (median diameter) in the volume-based particle size distribution was defined as the average particle size.
  • MFR Melt flow rate
  • melting point It was determined as the temperature corresponding to the maximum value in the heat of fusion curve when the temperature was raised at a rate of 10° C./min using a differential scanning calorimeter (DSC).
  • the relative dielectric constant ( ⁇ ) of the entire coating layer was calculated from the following formula by obtaining the capacitance using LCR Hitester 3522-50 manufactured by HIOKI.
  • C Ca+Cb
  • C is the capacitance per unit length of the coating (pf/m), which is the combination of the capacitance Ca of the flat part and the capacitance Cb of the corner part.
  • Ca ( ⁇ / ⁇ 0 ) ⁇ 2 ⁇ (L 1 +L 2 )/T
  • Cb ( ⁇ / ⁇ 0 ) ⁇ 2 ⁇ 0 /Log ⁇ (r+T)/r ⁇ /r
  • ⁇ 0 is the permittivity of vacuum
  • L 1 is the length of the long side of the flat part of the flat wire base material
  • L 2 is the length of the short side of the flat part of the flat wire base material
  • T is the entire wire is the coating thickness
  • r is the radius of curvature of the conductor corner.
  • PDIV Partial discharge inception voltage
  • a test piece was prepared by overlapping two coated electric wires (length 140 mm), including the long sides of their cross-sectional shapes, over a length of 100 mm with no gap. After that, the insulation coating of 10 mm from the end of the sample was removed, and using a partial discharge meter (DAC-PD-7 manufactured by Soken Electric Co., Ltd.), the distance between the rectangular wire base materials of the two covered wires was measured in an atmosphere of 50% relative humidity. The measurement was performed by applying a 50 Hz sine wave alternating current voltage. Assuming a voltage increase rate of 50 V/sec, a voltage decrease rate of 50 V/sec, and a voltage holding time of 0 sec, the voltage at which a discharge of 10 pC or more occurred was defined as the partial discharge inception voltage.
  • Adhesion strength between base material and coating layer Measurement was performed using AGS-J Autograph (50N) (manufactured by Shimadzu Corporation). Two pieces were cut approximately parallel to each other by 50 mm in the long axis direction, and the coating was cut at right angles in the short axis direction at both ends, and the ends were peeled off by 10 cm, and the pieces were sandwiched between upper chucks. The conductor was fixed at the bottom so that its long surface was horizontal. When the device was moved in the tensile direction, a jig was used that moved in the lateral direction according to the distance moved in the vertical direction, and the angle was adjusted so that the peeled film was always perpendicular to the long conductor.
  • the tensile stress when the film was pulled at 100 mm/min until it was peeled off by 30 mm was measured, and the maximum point stress was taken as the adhesion strength. If the adhesion strength was 0.1 N/mm or more, it was determined that the adhesion was sufficient and was rated as ⁇ . Less than 0.1 N/mm was marked as x.
  • Example 1 Liquid coating composition B was applied onto the outer periphery of a rectangular copper wire base material having a surface roughness Sz of 0.45 ⁇ m and baked to form a first layer. Furthermore, liquid coating composition G was applied to the outer periphery and baked to form a second layer. Furthermore, a third layer was formed on the outer periphery by extruding the fluorine-containing polymer compound L using an extrusion molding method. Details of the method for forming the first layer using liquid coating composition B and the method for forming the second layer using liquid coating composition G will be described later. Various properties of the obtained covered wire were measured. The results are shown in Table 3.
  • Examples 2 to 10 Coating was carried out in the same manner as in Example 1, except that the composition and fluorine-containing polymer compound for forming the first layer, second layer, and third layer were changed as shown in Table 3. Got the wire. Various properties of the obtained covered wire were measured. The results are shown in Table 3.
  • Example 11 Liquid coating composition B was applied onto the outer periphery of a rectangular copper wire base material having a surface roughness Sz of 0.45 ⁇ m and baked to form a first layer. Furthermore, a second layer was formed on the outer periphery by extruding the fluorine-containing polymer compound L using an extrusion molding method. Various properties of the obtained covered wire were measured. The results are shown in Table 3.
  • Comparative example 1 Liquid coating composition I was applied to the outer periphery of a rectangular copper wire base material having a surface roughness Sz of 0.1 ⁇ m and baked to form a first layer. Furthermore, a second layer was formed on the outer periphery by extruding the fluorine-containing polymer compound L using an extrusion molding method. Various properties of the obtained covered wire were measured. The results are shown in Table 3.
  • PAI Polyamideimide
  • PI polyimide
  • This liquid coating composition D was spray-painted, dried at 100°C for 15 minutes, and then baked at 380°C for 20 minutes to obtain a coating film with a thickness of 22 ⁇ m.
  • This powder coating composition E was applied electrostatically and baked at 380° C. for 20 minutes to obtain a coating film with a thickness of 20 ⁇ m.
  • This powder coating composition F was applied electrostatically and baked at 320° C. for 20 minutes to obtain a coating film with a thickness of 18 ⁇ m.
  • Powder coating composition I PFA powder (TFE/PPVE copolymer, number of functional groups: 220 per 106 carbon atoms, MFR: 27 g/10 min, melting point: 301°C, average particle size: 24 ⁇ m) was used as powder coating composition I. .
  • This powder coating composition I was applied electrostatically and baked at 380° C. for 20 minutes to obtain a coating film with a thickness of 47 ⁇ m.
  • liquid coating composition G Water was added to an aqueous dispersion composition of PTFE (solid content: 60% by weight, number of functional groups: 18 per 10 6 carbon atoms) to obtain a liquid coating composition G. This viscosity was 292 cP. This liquid coating composition G was spray coated, dried at 100°C for 15 minutes, and then baked at 380°C for 20 minutes to obtain a coating film with a thickness of 28 ⁇ m.
  • liquid coating composition H Water was added to an aqueous dispersion composition of PFA (TFE/PPVE copolymer) (solid content: 60% by weight, number of functional groups: 133 per 10 6 carbon atoms) to obtain a liquid coating composition H. This viscosity was 224 cP. This liquid coating composition H was spray coated, dried at 100°C for 15 minutes, and then baked at 380°C for 20 minutes to obtain a coating film with a thickness of 31 ⁇ m.
  • PFA TFE/PPVE copolymer
  • Powder coating composition I PFA powder (TFE/PPVE copolymer, number of functional groups: 220 per 106 carbon atoms, MFR: 27 g/10 min, melting point: 301°C, average particle size: 24 ⁇ m) was used as powder coating composition I. .
  • This powder coating composition I was applied electrostatically and baked at 380° C. for 20 minutes to obtain a coating film with a thickness of 47 ⁇ m.
  • Powder coating composition J PFA powder (TFE/PPVE copolymer, number of functional groups: 2 per 10 6 carbon atoms, MFR: 28 g/10 min, melting point: 301°C, average particle size: 23 ⁇ m) was used as powder coating composition J. .
  • This powder coating composition J was applied electrostatically and baked at 380° C. for 20 minutes to obtain a coating film with a thickness of 75 ⁇ m.
  • powder coating composition K FEP powder (TFE/HFP copolymer, number of functional groups: 625 per 106 carbon atoms, MFR: 38 g/10 min, melting point: 258°C, average particle size: 41 ⁇ m) was used as powder coating composition K. .
  • This powder coating composition K was applied electrostatically and baked at 320° C. for 20 minutes to obtain a coating film with a thickness of 52 ⁇ m.
  • FEP pellets (TFE/HFP copolymer, number of functional groups: 625 per 10 6 carbon atoms, MFR: 38 g/10 min, melting point: 258° C.) were used as the fluorine-containing polymer compound O.

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Insulated Conductors (AREA)
  • Processes Specially Adapted For Manufacturing Cables (AREA)
  • Organic Insulating Materials (AREA)

Abstract

L'invention concerne un fil électrique guipé comprenant : un matériau de base de fil électrique plat ; et une couche de revêtement formée sur la périphérie externe du matériau de base de fil électrique plat, la couche de revêtement comprenant une première couche formée sur la périphérie externe du matériau de base de fil électrique plat, et une seconde couche formée sur la périphérie externe de la première couche, la première couche étant constituée d'une composition (1) contenant un composé polymère renfermant du fluor (1) et un composé polymère (1) ayant un groupe amide et/ou un groupe imide, et la seconde couche étant constituée d'un composé polymère contenant du fluor (2) ou d'une composition (2) contenant le composé polymère renfermant du fluor (2).
PCT/JP2023/028330 2022-08-29 2023-08-02 Fil électrique recouvert et procédé de production de fil électrique recouvert Ceased WO2024048190A1 (fr)

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JP6508405B1 (ja) * 2017-11-21 2019-05-08 三菱マテリアル株式会社 絶縁導体および絶縁導体の製造方法

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JP5423800B2 (ja) 2009-08-24 2014-02-19 ダイキン工業株式会社 電線及びその製造方法
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JP6194976B1 (ja) 2016-03-31 2017-09-13 株式会社オートネットワーク技術研究所 絶縁電線
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