WO2023282292A1 - 樹脂製容器の製造方法および温度調整装置 - Google Patents
樹脂製容器の製造方法および温度調整装置 Download PDFInfo
- Publication number
- WO2023282292A1 WO2023282292A1 PCT/JP2022/026853 JP2022026853W WO2023282292A1 WO 2023282292 A1 WO2023282292 A1 WO 2023282292A1 JP 2022026853 W JP2022026853 W JP 2022026853W WO 2023282292 A1 WO2023282292 A1 WO 2023282292A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- preform
- mold
- temperature
- container
- blow molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/06—Injection blow-moulding
- B29C49/061—Injection blow-moulding with parison holding means displaceable between injection and blow stations
- B29C49/062—Injection blow-moulding with parison holding means displaceable between injection and blow stations following an arcuate path, e.g. rotary or oscillating-type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/06—Injection blow-moulding
- B29C49/061—Injection blow-moulding with parison holding means displaceable between injection and blow stations
- B29C49/064—Injection blow-moulding with parison holding means displaceable between injection and blow stations following a rectilinear path, e.g. shuttle-type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0053—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor combined with a final operation, e.g. shaping
- B29C45/0055—Shaping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/17—Component parts, details or accessories; Auxiliary operations
- B29C45/26—Moulds
- B29C45/261—Moulds having tubular mould cavities
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/64—Heating or cooling preforms, parisons or blown articles
- B29C49/6409—Thermal conditioning of preforms
- B29C49/6427—Cooling of preforms
- B29C49/6435—Cooling of preforms from the outside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/64—Heating or cooling preforms, parisons or blown articles
- B29C49/6409—Thermal conditioning of preforms
- B29C49/6436—Thermal conditioning of preforms characterised by temperature differential
- B29C49/6458—Thermal conditioning of preforms characterised by temperature differential tangentially, i.e. along circumference
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/64—Heating or cooling preforms, parisons or blown articles
- B29C49/6472—Heating or cooling preforms, parisons or blown articles in several stages
- B29C49/648—Heating or cooling preforms, parisons or blown articles in several stages of preforms or parisons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/64—Heating or cooling preforms, parisons or blown articles
- B29C49/68—Ovens specially adapted for heating preforms or parisons
- B29C49/681—Ovens specially adapted for heating preforms or parisons using a conditioning receptacle, e.g. a cavity, e.g. having heated or cooled regions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C2049/023—Combined blow-moulding and manufacture of the preform or the parison using inherent heat of the preform, i.e. 1 step blow moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/0715—Preforms or parisons characterised by their configuration the preform having one end closed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/3032—Preforms or parisons made of several components having components being injected
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
- B29L2031/7158—Bottles
Definitions
- the present invention relates to a method for manufacturing a resin container and a temperature control device.
- a hot parison type blow molding machine has been known as one of the machines for manufacturing resin containers.
- the hot parison type blow molding machine is configured to blow mold resin containers using the heat retained during injection molding of the preform. is advantageous in that it is possible to manufacture
- Patent Document 1 in the formation of a container having a triangular cross-section, a cooling air nozzle is provided at the upper end of a temperature control pot for pre-blowing a preform, and a portion corresponding to the corner portion of the container in the pre-blow preform is provided. Discloses a configuration for cooling by blowing air to the In Patent Document 1, the blowing of air is controlled by a timer so as to coincide with the timing at which the preform passes through the temperature control pot when the preform is taken out.
- Patent Document 1 discloses a technique in which a temperature control pot is provided with cooling means for locally cooling a desired position of the preform, and the preform is locally cooled while the temperature control pot is moving downward at a predetermined speed. ing.
- the timer controls the timing of blowing out the air, which is the cooling means.
- the cooling part changes greatly. Therefore, with the technique of Patent Document 1, adjustment of parameters for appropriately blowing air is very complicated. For example, when performing pinpoint local cooling of a desired position in the axial direction of the preform, it is very difficult to intuitively set the appropriate air blowing timing using a timer.
- the position of the cooling section is fixed for each mold. Therefore, in the above case, a plurality of mold parts (position adjustment parts) are required to adjust the position of the cooling portion of the preform, which greatly increases the manufacturing cost of the container.
- Patent Document 2 there are cases where a blow molding apparatus is additionally provided with a cooling device (attachment device) for locally cooling a desired position of the preform.
- the cooling equipment is not cheap, which increases the production cost of the container.
- it is necessary to install a cooling device in the temperature control section of the blow molding machine.
- the space for arranging the cooling device is limited, and the area where the preform can be cooled is limited. Therefore, it may be difficult to locally cool the desired position of the preform by the temperature control unit.
- a method for manufacturing a resin container includes a first step in which an injection-molded bottomed resin preform is accommodated in a temperature-controlled mold, and the temperature of the preform is controlled by the mold.
- a second step is to move the mold axially by a predetermined amount with respect to the preform by means of an elevating device, then stop the mold, and to make the air ejection portion arranged on the upper surface side of the mold face the part of the preform to be cooled.
- a desired position of the preform can be locally cooled by the cooling section in the temperature adjustment step, and the position of the cooling section can be easily adjusted.
- FIG. 5 is a diagram showing an arrangement example of an air ejection portion of the temperature adjustment portion; It is a flowchart which shows the process of a blow-molding method.
- FIG. 1 is a perspective view of a container 10 of this embodiment.
- the container 10 shown in FIG. 1 is a large-capacity (for example, 15 L to 20 L) stackable container used for containing, for example, mineral water, cooking oil, etc., and is manufactured by blow-molding a resin preform 40 described later. be.
- the overall shape of the container 10 shown in FIG. 1 is a prism shape with rounded corners and a substantially rectangular cross section.
- the container 10 includes a neck portion 11 with an upper opening, a shoulder portion 12 connected to the lower portion of the neck portion 11, a trunk portion 13 connected to the lower portion of the shoulder portion 12, and a bottom portion 14 closing the lower end of the trunk portion 13. and
- the bottom portion 14 is formed with a recess 15 for receiving the neck portion 11 of the container 10 placed below when stacked.
- the container 10 can be stacked independently with part of the bottom 14 in contact with part of the shoulder 12 of another container 10 .
- the neck portion 11 sealed with a cap (not shown) in the lower container 10 is accommodated in the recess 15 in the bottom portion 14 of the upper container 10 .
- the storage space for the containers 10 can be reduced, and the stability of the containers 10 when stacked can be enhanced.
- the thickness of the container 10 tends to be thin at the corner portions (heel portions 16) of the bottom portion 14 where the draw ratio from the preform 40 is maximized.
- the heel portion 16 of this type of container 10 is thinned, the container 10 cannot bear the load and is deformed. In order to suppress such a phenomenon, it is required to locally cool the portion corresponding to the heel portion 16 of the preform 40 before blow molding to make it more difficult to stretch than other portions, and to thicken the heel portion 16 .
- FIG. 2 is a diagram schematically showing the configuration of the blow molding apparatus 20 of this embodiment.
- the blow molding apparatus 20 of the present embodiment is a hot parison method (also referred to as a one-stage method) in which the container 10 is blow-molded by utilizing the heat (internal heat) at the time of injection molding without cooling the preform 40 to room temperature. device.
- the blow molding device 20 includes an injection molding section 21 , a temperature adjustment section 22 , a blow molding section 23 , an ejection section 24 and a transport mechanism 26 .
- the injection molding section 21, the temperature adjustment section 22, the blow molding section 23, and the ejection section 24 are arranged at positions rotated by a predetermined angle (for example, 90 degrees) around the transport mechanism .
- the conveying mechanism 26 includes a transfer plate (not shown in FIG. 2) that rotates about an axis perpendicular to the plane of FIG.
- One or more neck molds 27 (not shown in FIG. 1) for holding the necks of the preforms 40 or containers 10 are arranged on the transfer plate 28 at predetermined angles. By moving the transfer plate 28 by 90 degrees, the transport mechanism 26 transfers the preform 40 (or container 10) whose neck is held by the neck mold 27 to the injection molding section 21, the temperature adjustment section 22, and the blow molding section. 23 and take-out section 24 in that order.
- the conveying mechanism 26 further includes a mold opening mechanism for the neck mold 27 and the like.
- the injection molding section 21 includes an injection cavity mold and an injection core mold (not shown), and manufactures a preform 40 shown in FIG. 3 which will be described later.
- the injection molding unit 21 is connected to an injection device 25 that supplies a resin material, which is the raw material of the preform 40 .
- the injection cavity mold, the injection core mold, and the neck mold 27 of the transport mechanism 26 are closed to form a preform-shaped mold space. Then, the preform 40 is manufactured in the injection molding section 21 by pouring the resin material from the injection device 25 into the mold space of such a preform shape.
- the overall shape of the preform 40 is a bottomed cylindrical shape with one end side open and the other end side closed.
- the preform 40 has a neck portion formed on one end side and having an opening, a body portion connected to the neck portion formed in a cylindrical shape, and a bottom portion connected to the body portion and closing the other end side.
- the material of the container 10 and the preform 40 is a thermoplastic synthetic resin, which can be appropriately selected according to the application of the container 10.
- specific types of materials include, for example, PET (polyethylene terephthalate), PEN (polyethylene naphthalate), PCTA (polycyclohexanedimethylene terephthalate), Tritan (Tritan (registered trademark): copolyester manufactured by Eastman Chemical Co.).
- PP polypropylene
- PE polyethylene
- PC polycarbonate
- PES polyethersulfone
- PPSU polyphenylsulfone
- PS polystyrene
- COP/COC cyclic olefin polymer
- PMMA polymethacrylic acid methyl: acryl
- PLA polylactic acid
- the neck mold 27 of the conveying mechanism 26 is not opened and the preform 40 is held and conveyed as it is.
- the number of preforms 40 simultaneously molded by the injection molding section 21 (that is, the number of containers 10 simultaneously molded by the blow molding device 20) can be set as appropriate.
- the temperature adjustment unit 22 has a function of cooling or heating the high-temperature preform 40 after injection molding in the mold to adjust the temperature of the preform 40 , and uniformizing the temperature of the preform 40 and removing uneven temperature.
- the temperature adjustment unit 22 in this embodiment has a function of locally cooling a desired portion of the preform 40 by blowing air onto the preform 40 after the temperature has been adjusted by the mold.
- FIG. 3 is a longitudinal sectional view showing a configuration example of the temperature adjustment section 22.
- the temperature control unit 22 shown in FIG. 3 preliminarily blows the preform 40 manufactured by the injection molding unit 21 to form a bottomed cylindrical intermediate molded body 41 having a body portion larger in diameter than the preform 40. is. It should be noted that the intermediate molded body 41 is an example of the preform 40 to be pre-blown.
- the temperature control unit 22 includes a cavity mold (temperature control pot mold) 31 that can accommodate the preform 40 manufactured by the injection molding unit 21, an upper support plate 32 that is an example of a plate, a lower support plate 33, A movable table 34 , a shaft (guide member) 35 , a drive cylinder 36 , an air ejection part 37 and a lower fixed plate 38 are provided.
- a cavity mold temperature control pot mold
- the temperature control unit 22 includes a cavity mold (temperature control pot mold) 31 that can accommodate the preform 40 manufactured by the injection molding unit 21, an upper support plate 32 that is an example of a plate, a lower support plate 33, A movable table 34 , a shaft (guide member) 35 , a drive cylinder 36 , an air ejection part 37 and a lower fixed plate 38 are provided.
- the cavity mold 31 is a mold that is open on the upper side and has a mold space corresponding to the shape of the intermediate molded body 41 inside.
- the cavity mold 31 is used to equalize the temperature of the intermediate molded body 41 and remove the uneven temperature, and adjust the temperature of the intermediate molded body 41 to a temperature suitable for blow molding (for example, about 90 ° C. to 105 ° C.) and the shape of the container to be formed. Adjust to provide a temperature distribution suitable for
- the temperature adjustment unit 22 also has a function of cooling the intermediate molded body 41 in a high temperature state.
- the cavity mold 31 is configured so that different temperatures can be set in the axial direction of the preform.
- the cavity mold 31 is divided into at least two or more of an upper cavity mold and a lower cavity mold in the axial direction of the preform.
- the cavity mold 31 has a four-part structure. It is a structure in which three molds 31c and a fourth mold 31d are stacked.
- An upper support plate 32 is arranged on the upper surface side of the first mold 31a, and a lower support plate 33 is arranged between the lower surface of the outer peripheral portion of the first mold 31a and the upper surface of the outer peripheral portion of the second mold 31b. ing.
- the lower support plate 33 abuts on the stepped portion formed on the outer periphery of the second mold 31b, and is arranged in a non-contact state with the lower end of the outer periphery of the first mold 31a. is preferred.
- the upper support plate 32 is arranged in a non-contact state with the upper surface of the first mold 31a.
- the fourth mold 31d is placed on the upper surface of the movable table 34 (or a spacer 34a, which will be described later).
- a spacer 34a for adjusting the axial position of the cavity mold 31 is arranged between the cavity mold 31 and the movable table 34. As shown in FIG.
- the lower support plate 33 and the movable table 34 are connected and integrated by a plurality of struts (not shown) extending in the axial direction of the preform 40 .
- the second mold 31b to the fourth mold 31d are fixed to the movable table 34 by being connected and integrated, or sandwiched between the lower support plate 33 and the movable table 34 .
- the lower support plate 33 has two block-shaped members 33a at opposing positions on its upper surface.
- the upper support plate 32 is fixed to the upper surface of the block-shaped member 33a by a connecting member 32c such as a bolt.
- the first mold 31a is a mold that faces the outer peripheral surface of the preform 40 near the neck.
- the first mold 31a is composed of a pair of split molds, and can be opened and closed in the depth direction in the figure by a driving mechanism (eg, air cylinder) (not shown).
- a driving mechanism eg, air cylinder
- the pair of first molds 31a are horizontally movably supported between a mold closing position and a mold opening position by a guide mechanism provided in the block-shaped member 33a.
- the second mold 31b and the third mold 31c are molds facing the outer peripheral surface of the body of the preform 40, respectively.
- the fourth mold 31d is a mold that faces the outer peripheral surface of the bottom of the preform 40 .
- the bottom surface of the second mold 31b and the top surface of the third mold 31c, as well as the bottom surface of the third mold 31c and the top surface of the fourth mold 31d, are engaged by a spigot structure, for example, with a heat insulating member sandwiched between the molds. are combined.
- the first to fourth molds 31a to 31d of the cavity mold 31 are formed with channels (not shown) through which the temperature control medium (refrigerant) flows. Therefore, the temperatures of the first mold 31a to the fourth mold 31d are kept at a predetermined temperature by the temperature control medium.
- the temperature of the temperature control medium is not particularly limited, but can be appropriately selected within a range of, for example, 5°C to 80°C, preferably 30°C to 60°C.
- the temperature distribution in the axial direction of the intermediate compact 41 can also be changed by changing the temperature of each of the first mold 31a to the fourth mold 31d.
- the temperature control unit 22 has a core member (not shown) that supplies and discharges compressed air into the preform 1 .
- the core member is inserted inside the neck mold 27 and the preform 40 from above, and is abutted on the neck of the preform 40 in an airtight manner while being inserted into the neck mold 27 .
- the preform 40 swells so as to adhere to the cavity mold 31 and is shaped into the shape of the intermediate molded body 41. .
- the movable base 34 , the shaft 35 , the drive cylinder 36 and the lower fixed plate 38 are arranged below the machine base 29 of the blow molding apparatus 20 .
- Four shafts 35 are provided.
- FIG. 3 shows only a pair of left and right shafts 35 . These shafts 35 extend in parallel in the vertical direction and connect the machine base 29 and the lower fixed plate 38 .
- the movable table 34 is at the standby position (lowest position), for example, the machine of the blow molding device 20. It may be arranged above the table 29 .
- the shaft 35 , the driving cylinder 36 and the lower fixing plate 38 may also be arranged above the machine base 29 if the blow molding apparatus 20 has enough space.
- a movable base 34 arranged between the machine base 29 and the lower fixed plate 38 is loosely fitted on each shaft 35 .
- the movable table 34 can translate vertically along the shaft 35 below the machine base 29 .
- the drive cylinder 36 is an example of an elevating device, and is composed of, for example, an air cylinder.
- the drive cylinder 36 vertically moves the movable table 34 via a piston rod 36a.
- the lifting device may be configured using an electric motor (for example, a servomotor or the like).
- the cavity mold 31 is lowered from the first position (upper end position, temperature adjustment position) in FIG. 3 to the second position (intermediate position, local cooling position). state.
- the driving cylinder 36 or the lifting device also functions to adjust the axial position of the air ejection portion 37 with respect to the intermediate molded body 41 by positioning and stopping the movable table 34 in the vertical direction.
- the drive cylinder 36 or the lifting device is provided with a rod fixing mechanism (or a position fixing mechanism of the lifting device) capable of fixing the piston rod 36a at an arbitrary lifting position and making the position immovable.
- the rod fixing mechanism (or the position fixing mechanism of the lifting device) is released, and the cavity mold 31 is positioned so as not to interfere with the intermediate molded body 41 ( lower end position, standby position).
- the air ejection part 37 is attached to the upper side of the upper support plate 32 and has the function of locally cooling the intermediate molded body 41 by ejecting air. As shown in FIG. 5, at least one or more air ejection portions 37 are provided around the opening 32b of the upper support plate 32 (or the opening of the cavity mold 31), for example, at intervals of 90 degrees. 4 are installed. Each of the air ejection portions 37 is arranged facing inward so that a surface 37a having an air ejection port faces the opening portion 32b.
- the air ejection ports of the plurality (for example, four) of air ejection portions 37 are arranged at positions corresponding to the heel portion 16 of the container 10 in the circumferential direction of the intermediate molded body 41 .
- the opening 32b is a through hole that allows the intermediate molded body 41 to move up and down without interference, and is formed in a circular shape when viewed from above, for example.
- the air ejection portion 37 is arranged outside the opening portion 32b.
- one or more arc-shaped grooves 32a are formed in the upper support plate 32 so as to form an annular shape around the opening 32b.
- four grooves 32a are formed.
- the groove 32a formed in the upper support plate 32 extends along the circumference around the preform 40 (intermediate molded body 41) or along the circumference around the opening 32b.
- the air ejection part 37 is attached to the groove 32a and positioned. Then, the air ejection part 37 can adjust the circumferential mounting position relative to the preform or the opening 32b along the groove 32a.
- blow molding section 23 performs stretch blow molding on the preform 40 (intermediate molded body 41) temperature-controlled by the temperature control section 22 to manufacture a container.
- the blow molding section 23 includes a blow cavity mold that is a pair of split molds corresponding to the shape of the container, a bottom mold, an extension rod, and an air introducing member (blow core mold, none of which are shown).
- the blow molding section 23 blow molds the intermediate molded body 41 while stretching it.
- the container 10 can be manufactured by forming the intermediate molded body 41 into a blow cavity shape.
- the take-out part 24 is configured to release the neck part 11 of the container 10 manufactured in the blow molding part 23 from the neck mold 27 and take out the container 10 to the outside of the blow molding apparatus 20 .
- FIG. 6 is a flow chart showing the steps of the blow molding method.
- Step S101 Injection molding step
- a preform 40 is manufactured by injecting resin from the injection device 25 into a preform-shaped mold space formed by the injection cavity mold, the injection core mold, and the neck mold 27 of the transport mechanism 26. be done.
- step S101 when the injection molding of the preform 40 is completed, the injection molding part 21 is opened and the preform 40 is released from the injection cavity mold and the injection core mold. Next, the transfer plate 28 of the transfer mechanism 26 is rotated by a predetermined angle, and the preform 40 held by the neck mold 27 is transferred to the temperature adjustment section 22 .
- Step S102 temperature adjustment step
- the temperature adjustment unit 22 adjusts the temperature of the preform 40 to bring it closer to the temperature suitable for final blowing.
- pre-blow of the preform 40 and temperature adjustment of the intermediate compact 41 after the pre-blow are performed.
- the cavity mold 31 is at a position (standby position) retracted downward with respect to the preform 40 .
- the drive cylinder 36 is driven to raise the cavity mold 31 together with the movable table 34 to a predetermined position (temperature adjustment position).
- the preform 40 held by the neck mold 27 is housed in the cavity mold 31, as shown in FIG.
- the core member is inserted into the neck portion of the preform 40 accommodated in the cavity mold 31, and the neck portion of the preform 40 and the core member are brought into close contact with each other to keep airtightness therebetween.
- the preform 40 is pre-blown by introducing compressed air from the core member to the preform 40 (S102a: first step).
- the preform 40 into which compressed air has been introduced by preliminary blowing expands the body portion so as to be in close contact with the mold space of the cavity mold 31 and is shaped into the shape of the intermediate molded body 41 .
- the intermediate molded body 41 continues to be in contact with the cavity mold 31 kept at a predetermined temperature until it is released from the mold. Therefore, in the temperature control unit 22, the temperature of the intermediate molded body 41 is controlled so that the temperature does not fall below the temperature suitable for blow molding from the outside, and the temperature deviation that occurs during injection molding is also reduced (S102a).
- the core member rises and retreats, and the first mold 31 a slides to separate from the intermediate molded body 41 .
- the cavity mold 31 can move downward without interfering with the shoulder portion of the intermediate molded body 41 .
- the cavity mold 31 descends by a predetermined height together with the movable table 34 and stops at a predetermined position (local cooling position) (S102b: second step).
- the air ejection portion 37 faces the vicinity of the bottom portion of the intermediate molded body 41 .
- the movable table 34, the cavity mold 31, or the upper support plate 32 is fixed immovably by operating the rod fixing mechanism (or the position fixing mechanism of the lifting device).
- the position fixing by the rod fixing mechanism (or the position fixing mechanism of the lifting device) is released, and the cavity mold 31 is further lowered by driving the drive cylinder 36 to the initial position. (standby position). Thereafter, the transfer plate 28 of the transfer mechanism 26 is rotated by a predetermined angle, and the temperature-adjusted intermediate molded body 41 held by the neck mold 27 is transferred to the blow molding section 23 .
- Step S103 blow molding step
- the blow molding of the container 10 is performed in the blow molding section 23 .
- the blow cavity mold is closed to accommodate the intermediate molded body 41 in the mold space, and the air introduction member (blow core) is lowered so that the neck portion of the intermediate molded body 41 is brought into contact with the air introduction member.
- the stretching rod (longitudinal axis stretching member) is lowered to hold the bottom of the intermediate molded body 41 from the inner surface, and the intermediate molding is carried out by supplying blow air from the air introduction member while performing vertical axis stretching as necessary.
- the body 41 is transversely stretched.
- the intermediate molded body 41 is swelled and shaped so as to be in close contact with the mold space of the blow cavity mold, and is blow molded into the container 10 .
- the bottom mold waits at a lower position where it does not come into contact with the bottom of the intermediate molded body 41, and quickly rises to the molding position before or after closing the mold.
- Step S104 container removal step
- the blow cavity mold and the bottom mold are opened. This allows the container 10 to be moved from the blow molding section 23 . Subsequently, the transport plate 28 of the transport mechanism 26 is rotated by a predetermined angle, and the container 10 is transported to the pick-up section 24 . At the ejection section 24 , the neck 11 of the container 10 is released from the neck mold 27 and the container 10 is ejected to the outside of the blow molding apparatus 20 .
- temperature deviation is reduced in the temperature-controlled cavity mold 31 for the preform (the intermediate molded body 41 as an example) (S102a).
- the driving cylinder 36 is driven to move the cavity mold 31 axially by a predetermined amount with respect to the intermediate molded body 41, and then stopped (S102b).
- the air ejection part 37 arranged on the upper surface side of the cavity mold 31 faces the part of the intermediate molded body 41 to be cooled.
- air is jetted from the air jetting portion 37 to locally cool the portion to be cooled of the intermediate formed body 41 positioned in the axial direction (S102c).
- the piston rod 36a (or the lifting device) of the driving cylinder 36 by positioning the piston rod 36a (or the lifting device) of the driving cylinder 36 by the rod fixing mechanism (or the position fixing mechanism of the lifting device), air is jetted to the part of the intermediate molded body 41 to be cooled.
- a portion 37 is axially positioned.
- air can be jetted to the portion of the intermediate molded body 41 to be cooled to locally cool the portion.
- the driving cylinder 36 or the lifting mechanism moves the movable table 34 or the cavity mold 31 in the axial direction of the preform, the axial alignment of the air ejection part 37 can be performed intuitively, and the local cooling can be performed in the axial direction. It is also easy to improve the positional accuracy of the portion of the intermediate molded body 41 (preform 40). Therefore, the operator can easily adjust the drive amount of the drive cylinder 36 so that the air ejection part 37 faces the position where the preform 40 is locally cooled. Furthermore, by stopping and positioning the drive cylinder 36, the desired position of the
- the device for local cooling of the preform provided outside the cavity mold 31 is space-saving, even if a gate cut device or the like is arranged near the cavity mold 31 of the temperature adjustment part, The bottom of the preform can be locally cooled without problems.
- the position of the air ejection part 37 can be adjusted in the circumferential direction along the groove 32a formed in the upper support plate 32, the portion of the preform to be locally cooled can be adjusted in the circumferential direction with high accuracy. is also easy.
- air when manufacturing a container with a handle, air may be blown to a portion corresponding to the root portion of the handle in the axial direction of the preform for local cooling.
- a cooling blow for cooling the intermediate molded body 41 may be performed.
- the cooling blow is performed by the temperature control unit 22, the intermediate molded body 41 in a high temperature state is rapidly cooled, so that whitening (clouding) due to spherulite generation crystallization that may occur when the intermediate body is slowly cooled can be more easily suppressed. Become.
- the temperature adjustment unit 22 may apply a heating pot type as the cavity mold 31 without performing preliminary blowing.
- the temperature of the heating pot mold is adjusted by a heating member (not shown) such as a band heater (ring-shaped heater) or a rod-shaped heater, and the preform is heated from the heating pot mold without coming into contact with the heating pot mold. is heated from the outer peripheral side to adjust the temperature (S102a when preliminary blowing is not performed: first step).
- a mold member for temperature adjustment inserted inside the preform such as a temperature adjustment rod (directly contacting the inner peripheral surface of the preform).
- the lower support plate 33 may be omitted from the cavity mold 31 that does not undergo preliminary blowing.
- the upper support plate 32 and the movable table 34 (or spacers 34a) are connected by a plurality of posts (not shown) to be integrated, and between the upper cavity mold (first mold 31a) and the lower cavity mold ( The cavity mold 31 may be configured by stacking the first mold 31b, etc.).
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
Description
実施形態では説明を分かり易くするため、本発明の主要部以外の構造や要素については、簡略化または省略して説明する。また、図面において、同じ要素には同じ符号を付す。なお、図面に示す各要素の形状、寸法などは模式的に示したもので、実際の形状、寸法などを示すものではない。
まず、図1を参照して、本実施形態に係る樹脂製容器(以下、単に容器とも称する)の構成例を説明する。図1は、本実施形態の容器10の斜視図である。
次に、本実施形態のブロー成形装置の構成について説明する。図2は、本実施形態のブロー成形装置20の構成を模式的に示す図である。本実施形態のブロー成形装置20は、プリフォーム40を室温まで冷却せずに射出成形時の保有熱(内部熱量)を活用して容器10をブロー成形するホットパリソン方式(1ステージ方式とも称する)の装置である。
搬送機構26は、図2の紙面垂直方向の軸を中心に回転するように移動する移送板(図2では不図示)を備える。移送板28には、プリフォーム40または容器10の首部を保持するネック型27(図1では不図示)が、所定角度ごとにそれぞれ1以上配置されている。搬送機構26は、移送板28を90度分ずつ移動させることで、ネック型27で首部が保持されたプリフォーム40(または容器10)を、射出成形部21、温度調整部22、ブロー成形部23、取り出し部24の順に搬送する。なお、搬送機構26は、ネック型27の型開き機構などもさらに備える。
射出成形部21は、それぞれ図示を省略する射出キャビティ型、射出コア型を備え、後述の図3に示すプリフォーム40を製造する。射出成形部21には、プリフォーム40の原材料である樹脂材料を供給する射出装置25が接続されている。
温度調整部22は、射出成形後の高温状態のプリフォーム40を金型内で冷却または加熱して温度調整し、プリフォーム40の均温化や偏温除去を行う機能を担う。また、本実施形態での温度調整部22は、金型で温度調整された後のプリフォーム40に対してエアを吹き付けて、プリフォーム40の所望部位を局所冷却する機能を有している。
なお、プリフォーム40が短い場合やネック型27を支持する回転板(移送板)が昇降する場合、少なくとも可動台34は、待機位置(最下降位置)において、例えば、それぞれブロー成形装置20の機台29の上側に配置されていてもよい。ブロー成形装置20のスペースに余裕があれば、シャフト35、駆動シリンダ36および下部固定板38も機台29の上側に配置されていてもよい。
図2に戻って、ブロー成形部23は、温度調整部22で温度調整されたプリフォーム40(中間成形体41)に対して延伸ブロー成形を行い、容器を製造する。
ブロー成形部23は、容器の形状に対応した一対の割型であるブローキャビティ型と、底型と、延伸ロッドおよびエア導入部材(ブローコア型、いずれも不図示)を備える。ブロー成形部23は、中間成形体41を延伸しながらブロー成形する。これにより、中間成形体41がブローキャビティ型の形状に賦形されて容器10を製造することができる。
取り出し部24は、ブロー成形部23で製造された容器10の首部11をネック型27から開放し、容器10をブロー成形装置20の外部へ取り出すように構成されている。
次に、本実施形態のブロー成形装置によるブロー成形方法について説明する。図6は、ブロー成形方法の工程を示すフローチャートである。
ステップS101では、射出成形部21において、射出キャビティ型、射出コア型および搬送機構26のネック型27で形成されたプリフォーム形状の型空間に射出装置25から樹脂を射出し、プリフォーム40が製造される。
続いて、温度調整部22において、プリフォーム40の温度を最終ブローに適した温度に近づけるための温度調整が行われる。本実施形態の温度調整部22では、プリフォーム40の予備ブローと、予備ブロー後の中間成形体41の温度調整が行われる。
続いて、ブロー成形部23において、容器10のブロー成形が行われる。
まず、ブローキャビティ型を型閉じして中間成形体41を型空間に収容し、エア導入部材(ブローコア)を下降させることで、中間成形体41の首部にエア導入部材が当接される。そして、延伸ロッド(縦軸延伸部材)を降下させて中間成形体41の底部を内面から抑えて、必要に応じて縦軸延伸を行いつつ、エア導入部材からブローエアを供給することで、中間成形体41を横軸延伸する。これにより、中間成形体41は、ブローキャビティ型の型空間に密着するように膨出して賦形され、容器10にブロー成形される。なお、底型は、ブローキャビティ型の型閉じ前は中間成形体41の底部と接触しない下方の位置で待機し、型閉前または型閉後に成形位置まで素早く上昇する。
ブロー成形が終了すると、ブローキャビティ型および底型が型開きされる。これにより、ブロー成形部23から容器10が移動可能となる。
続いて、搬送機構26の移送板28が所定角度回転するように移動し、容器10が取り出し部24に搬送される。取り出し部24において、容器10の首部11がネック型27から開放され、容器10がブロー成形装置20の外部へ取り出される。
ブロー成形装置20の温度調整部22では、プリフォーム(一例として中間成形体41)について温度調整されたキャビティ金型31内で偏温を低減させる(S102a)。その後、駆動シリンダ36を駆動させて中間成形体41に対してキャビティ金型31を軸方向に所定量移動させてから停止させる(S102b)。これにより、キャビティ金型31の上面側に配置されたエア噴出部37が中間成形体41の冷却すべき部位と対向した状態となる。そして、エア噴出部37からエアを噴出し、軸方向に位置決めされた中間成形体41の冷却すべき部位を局所的に冷却する(S102c)。
Claims (6)
- 射出成形された有底形状の樹脂製プリフォームを温度調整された金型内に収容し、前記プリフォームを前記金型により温度調整する第1の工程と、
昇降装置により前記プリフォームに対して前記金型を軸方向に所定量移動させてから停止させ、前記金型の上面側に配置したエア噴出部を前記プリフォームの冷却すべき部位と対向させる第2の工程と、
前記エア噴出部からエアを噴出し、前記軸方向に位置決めされた前記プリフォームの前記冷却すべき部位を局所的に冷却する第3の工程と、
前記第1から第3の各工程を経て温度調整された前記プリフォームをブロー成形して樹脂製容器を製造するブロー成形工程と、を有する
樹脂製容器の製造方法。 - 前記エア噴出部は、前記プリフォームの周方向に複数配置される
請求項1に記載の樹脂製容器の製造方法。 - 前記エア噴出部は、前記プリフォームを中心とする円周に沿った円弧状の溝を有するプレート上に配置され、前記溝に沿って前記プリフォームに対する周方向位置を調整可能である
請求項1または請求項2に記載の樹脂製容器の製造方法。 - 前記プリフォームを射出成形する射出成形工程をさらに備え、
前記プリフォームを金型により温度調整する第1の工程と前記プリフォームを局所的に冷却する第3の工程は、前記射出成形工程と前記ブロー成形工程の間に、射出成形時の保有熱を含んだ前記プリフォームに対して実行される
請求項1から請求項3のいずれか1項に記載の樹脂製容器の製造方法。 - 前記樹脂製容器は、他の容器の肩部に容器底部を接触させた状態で前記他の容器との積み重ねが可能なスタッカブル容器である
請求項1から請求項4のいずれか1項に記載の樹脂製容器の製造方法。 - 射出成形された有底形状の樹脂製プリフォームをブロー成形の前に温度調整する樹脂製容器の製造装置であって、
前記プリフォームを温度調整する温度調整部と、温度調整された前記プリフォームをブロー成形するブロー成形部と、を少なくとも備え、
前記温度調整部は、
前記プリフォームを収容する金型を軸方向に駆動させる昇降装置と、
前記金型の上面側に配置されたプレートに取り付けられるエア噴出部と、を備え、
前記プレートは、前記プリフォームを中心とする円周に沿った円弧状の溝を有し、
前記エア噴出部は、前記溝に沿って前記プリフォームに対する周方向位置を調整可能である
樹脂製容器の製造装置。
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202280059849.9A CN117940266A (zh) | 2021-07-07 | 2022-07-06 | 树脂制容器的制造方法及温度调整装置 |
| EP22837706.5A EP4368365A4 (en) | 2021-07-07 | 2022-07-06 | Method for producing a resin container and temperature control device |
| JP2023533167A JP7682272B2 (ja) | 2021-07-07 | 2022-07-06 | 樹脂製容器の製造方法および温度調整装置 |
| US18/575,978 US20240335998A1 (en) | 2021-07-07 | 2022-07-06 | Method for producing resin container and temperature control device |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021-112869 | 2021-07-07 | ||
| JP2021112869 | 2021-07-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2023282292A1 true WO2023282292A1 (ja) | 2023-01-12 |
Family
ID=84801798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2022/026853 Ceased WO2023282292A1 (ja) | 2021-07-07 | 2022-07-06 | 樹脂製容器の製造方法および温度調整装置 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20240335998A1 (ja) |
| EP (1) | EP4368365A4 (ja) |
| JP (1) | JP7682272B2 (ja) |
| CN (1) | CN117940266A (ja) |
| WO (1) | WO2023282292A1 (ja) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6189014A (ja) * | 1984-10-06 | 1986-05-07 | Nissei Ee S B Kikai Kk | パリソン射出成形方法 |
| JPH06170923A (ja) * | 1992-12-04 | 1994-06-21 | Ube Ind Ltd | ブロー成形における偏肉防止方法 |
| JP2000033644A (ja) * | 1998-07-17 | 2000-02-02 | Ube Ind Ltd | 貼り合わせブロー成形方法 |
| JP3340183B2 (ja) | 1993-04-01 | 2002-11-05 | 日精エー・エス・ビー機械株式会社 | 成形装置 |
| JP3893067B2 (ja) | 2002-02-19 | 2007-03-14 | 日精エー・エス・ビー機械株式会社 | プリフォームの温調方法 |
| JP2021054068A (ja) * | 2019-01-31 | 2021-04-08 | 日精エー・エス・ビー機械株式会社 | 樹脂製容器の製造装置および製造方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102008041575A1 (de) * | 2008-08-26 | 2010-03-04 | Geiger Technologies Gmbh | Verfahren und Vorrichtung zur Herstellung eines Kunststoffbauteils |
| WO2017073791A1 (ja) * | 2015-10-30 | 2017-05-04 | 日精エー・エス・ビー機械株式会社 | ブロー成形装置 |
-
2022
- 2022-07-06 EP EP22837706.5A patent/EP4368365A4/en active Pending
- 2022-07-06 WO PCT/JP2022/026853 patent/WO2023282292A1/ja not_active Ceased
- 2022-07-06 JP JP2023533167A patent/JP7682272B2/ja active Active
- 2022-07-06 US US18/575,978 patent/US20240335998A1/en active Pending
- 2022-07-06 CN CN202280059849.9A patent/CN117940266A/zh active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6189014A (ja) * | 1984-10-06 | 1986-05-07 | Nissei Ee S B Kikai Kk | パリソン射出成形方法 |
| JPH06170923A (ja) * | 1992-12-04 | 1994-06-21 | Ube Ind Ltd | ブロー成形における偏肉防止方法 |
| JP3340183B2 (ja) | 1993-04-01 | 2002-11-05 | 日精エー・エス・ビー機械株式会社 | 成形装置 |
| JP2000033644A (ja) * | 1998-07-17 | 2000-02-02 | Ube Ind Ltd | 貼り合わせブロー成形方法 |
| JP3893067B2 (ja) | 2002-02-19 | 2007-03-14 | 日精エー・エス・ビー機械株式会社 | プリフォームの温調方法 |
| JP2021054068A (ja) * | 2019-01-31 | 2021-04-08 | 日精エー・エス・ビー機械株式会社 | 樹脂製容器の製造装置および製造方法 |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP4368365A4 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN117940266A (zh) | 2024-04-26 |
| EP4368365A1 (en) | 2024-05-15 |
| EP4368365A4 (en) | 2025-05-21 |
| JPWO2023282292A1 (ja) | 2023-01-12 |
| JP7682272B2 (ja) | 2025-05-23 |
| US20240335998A1 (en) | 2024-10-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US11731337B2 (en) | Blow molding device and blow molding method | |
| EP3476567B1 (en) | Injection molding unit and blow molding device provided with same | |
| US11472091B2 (en) | Two step blow molding unit, apparatus and method | |
| JP7259044B2 (ja) | 金型ユニット、ブロー成形装置およびブロー成形方法 | |
| CN107921663B (zh) | 预成型件,制作该预成型件的模具堆叠,以及操纵该预成型件的预成型件操纵设备 | |
| JP7554902B2 (ja) | 温度調整用金型、樹脂製容器の製造装置および製造方法 | |
| CN114728460B (zh) | 吹塑成型装置及吹塑成型方法 | |
| WO2023282292A1 (ja) | 樹脂製容器の製造方法および温度調整装置 | |
| CN117382147A (zh) | 手柄瓶的一体成型装置和方法 | |
| US11858194B2 (en) | Container mold and method of manufacturing a container | |
| JP7399301B2 (ja) | ブロー成形装置 | |
| EP4512591A1 (en) | Method and device for producing resin container | |
| US20240123670A1 (en) | Temperature adjustment mold, and device and method for manufacturing resin container | |
| CN112721104B (zh) | 一步法注拉吹塑料容器成型装置及成型方法 | |
| WO2025216235A1 (ja) | 射出成形金型、樹脂製容器の製造装置および製造方法 | |
| WO2024048442A1 (ja) | プリフォームの製造装置、製造方法および冷却用金型 | |
| WO2023145775A1 (ja) | 温度調整用金型、樹脂製容器の製造装置 | |
| WO2025084209A1 (ja) | 温度調整用金型、樹脂製容器の製造装置および製造方法 | |
| WO2023157863A1 (ja) | 温度調整用金型、温度調整方法および樹脂製容器の製造装置 | |
| WO2025084312A1 (ja) | 金型ユニット、ブロー成形装置およびブロー成形方法 | |
| WO2020204098A1 (ja) | ブロー成形装置およびブロー成形方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 22837706 Country of ref document: EP Kind code of ref document: A1 |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 2023533167 Country of ref document: JP |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 2022837706 Country of ref document: EP |
|
| ENP | Entry into the national phase |
Ref document number: 2022837706 Country of ref document: EP Effective date: 20240207 |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 202280059849.9 Country of ref document: CN |
|
| WWE | Wipo information: entry into national phase |
Ref document number: 18575978 Country of ref document: US |