WO2023097382A1 - Processo e sistema de fabricação de um aglomerado sólido - Google Patents
Processo e sistema de fabricação de um aglomerado sólido Download PDFInfo
- Publication number
- WO2023097382A1 WO2023097382A1 PCT/BR2022/050451 BR2022050451W WO2023097382A1 WO 2023097382 A1 WO2023097382 A1 WO 2023097382A1 BR 2022050451 W BR2022050451 W BR 2022050451W WO 2023097382 A1 WO2023097382 A1 WO 2023097382A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- angular portion
- rollers
- upper angular
- supplying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/22—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by pressing in moulds or between rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B11/00—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses
- B30B11/16—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses using pocketed rollers, e.g. two co-operating pocketed rollers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B11/00—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses
- B30B11/34—Presses specially adapted for forming shaped articles from material in particulate or plastic state, e.g. briquetting presses, tabletting presses for coating articles, e.g. tablets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B15/00—Details of, or accessories for, presses; Auxiliary measures in connection with pressing
- B30B15/30—Feeding material to presses
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/06—Methods of shaping, e.g. pelletizing or briquetting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B30—PRESSES
- B30B—PRESSES IN GENERAL
- B30B15/00—Details of, or accessories for, presses; Auxiliary measures in connection with pressing
- B30B15/30—Feeding material to presses
- B30B15/302—Feeding material in particulate or plastic state to moulding presses
- B30B15/308—Feeding material in particulate or plastic state to moulding presses in a continuous manner, e.g. for roller presses, screw extrusion presses
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
- C10L2290/32—Molding or moulds
Definitions
- the present invention is related to solid agglomerates.
- the present invention relates to a process and system for manufacturing solid agglomerates.
- One of the main equipment where the iron reduction process takes place is called a Blast Furnace, and its function is to cause the separation of iron Fe from its FezOa ore.
- This separation occurs through chemical reduction, which involves the separation of a metal from its oxide, and is processed using a reducing agent.
- a reducer is a material that must present a greater attraction for oxygen, under operating conditions, than the metal to be reduced.
- the main reducing agent used in the steel industry is coke, which comes from mineral coal.
- coking coal which is an essential substance in the reduction of iron ore to metallic iron, as it combines with oxygen to create carbon dioxide, iron and slag.
- bituminous coal that forms a solid mass when heated (coking coal); on the other hand, if it does not soften or aggregate on heating, it is called non-coking coal.
- agglomerates in the steel industry is increasingly common.
- the agglomeration process consists of grouping materials with fine granulometry, with the aim of obtaining a product with larger dimensions through the use of binders.
- binders Through this process it is possible to obtain, for example, high quality metal agglomerates or charcoal briquettes, taking advantage of the small fractions that are usually discarded.
- coal agglomerates can replace coking coal and metallic agglomerates can replace iron ore.
- coal briquetting technique has been gaining ground in the industry.
- This technique which can be used for both mineral and charcoal, generally involves the steps of: (i) granulometric balancing of coal or biomass particles; (ii) mixture of binders (binders); (iii) mechanical compaction; and (iv) drying the briquettes.
- the documents below describe examples of charcoal briquettes and their respective production processes.
- Document US8585786B2 describes a method and system for briquetting solid fuel, such as coal.
- solid fuel is conveyed through a continuous feed solid fuel treatment plant, treated with electromagnetic energy and briquetted after treatment.
- WO2014098413A1 describes a charcoal briquette and a method for manufacturing the same.
- This method of manufacturing coal briquettes comprises the steps of (i) supplying coal with a low particle size, (ii) producing a mixture obtained by mixing between 1 and 5 parts by weight of a hardening agent and between 5 and 15 parts by weight of a binder in relation to 100 parts by weight of fine-grained charcoal, and (iii) molding the mixture.
- the low grade coal comprises (i) more than 0 and not more than 50% by weight of low grade coal and (ii) a balance of coal ash.
- Low rank carbon has between 25% by weight and 40% by weight of a volatile fraction (dry basis) and has a crucible swelling number of more than 0 and less than 3.
- Document WO2013152959A1 describes a process for producing a briquette containing coals, where the coals together with a binder system are subjected to mixing with the introduction of steam and the mixture obtained is subjected to pressing to form briquettes.
- the residual steam obtained is used as at least part of the steam introduced during mixing.
- Document AU2008203855B2 describes a process for forming a briquette composed of low classification coal and aggregate material, characterized in that it comprises: drying a low classification coal feed to produce a dry coal with a moisture content between 8 to 16% by weight; mixing the dry charcoal with an aggregate material; and compacting the dry coal and aggregate material mixture into briquettes.
- the main objective of the present invention is to provide a system and a process for manufacturing a solid agglomerate so that it comprises more than one distinct composition in its structure, where each composition would be located in a certain region of it.
- the present invention provides a process for manufacturing a solid agglomerate, by means of a roller press comprising two rollers provided with cavities fillable with granulated compositions, the_process comprising the steps of (i ) supplying, from above, a first composition in a first upper angular portion of each of the roll press rolls, (ii) supplying, from above, a second composition in a second upper angular portion of each of rollers of the roller press, in which, for the same roller, the second upper angular portion is located downstream of the first upper angular portion with reference to the direction of rotation of each roller, and (iii) pressing the material supplied onto the rollers so as to form a solid agglomerate comprising a core formed
- the present invention provides a system for manufacturing a solid agglomerate, comprising a roller press having two rollers provided with cavities fillable with granulated compositions, the system comprising (i) means for supplying, from above, a first composition in a first upper angular portion of each of the press rolls, (ii) means for supplying, from above, a second composition in a second upper angular portion of each of the press rolls, wherein, for the same roller, the second upper angular portion is located downstream of the first upper angular portion with reference to the direction of rotation of each roller, and (iii) means for pressing the supplied material onto the rollers so as to form a solid agglomerate comprising a core formed by the second composition and a skin formed by the first composition.
- Figure 1 illustrates a schematic sectional view of a roller press system according to the state of the art.
- Figure 2 illustrates a schematic cross-sectional view of a preferred embodiment of the system of the present invention.
- Figure 3 illustrates a schematic view of the roller press according to a preferred embodiment of the system of the present invention.
- Figure 4 illustrates a schematic view of a solid agglomerate manufactured from the process and system of the present invention.
- the present invention provides a system for manufacturing a solid agglomerate 5, comprising a roller press 10 that has two rollers 10a, 10b rotating in opposite directions and equipped with cavities 11 that can be filled with granulated compositions, as shown in figure 1.
- a technique which is already known from the state of the art, comprises a central feeder equipped with a metering screw 42 for feeding a granulated composition between the rollers 10a, 10b for pressing and forming solid agglomerates 5.
- FIG. 2 and 3 which illustrate a preferred embodiment of the system of the present invention
- means are provided for providing, from above, a first composition in a first upper angular portion 12a of each of the rollers 10a, 10b of the roller press 10.
- the delivery of the first composition is indicated in figures 2 and 3 by green arrows.
- the means for supplying the first composition into a first upper angular portion 12a of each of the rollers 10a, 10b of the roller press 10 may include, for example, (i) at least one side silo 30 adapted to store the first composition, (ii) at least one lateral dispensing screw 32 of the first composition and/or (iii) at least one passage silo 34 adapted to direct the first composition over the first upper angular portion 12a of each of the rollers 10a, 10b of roller press 10.
- the present invention will further comprise means for supplying, from above, a second composition into a second upper angular portion 12b of each of the rollers 10a, 10b of the roller press 10.
- the supply of the second composition is indicated in figures 2 and 3 by red arrows.
- the means for supplying the second composition in a second upper angular portion 12b of each of the rollers 10a, 10b of the roller press 10 may include, for example, (i) at least one central silo 40, which stores the second composition (ii) at least one central dosing screw 42 of the second composition driven by a motor 44.
- the central dosing screw 42 also precompacts the second composition prior to the step of supplying it to the roller press 10 .
- first 12a and second upper angular portions 12b of each roll 10a, 10b correspond to the upper angles complementary to each other of the cylinders (rolls), which together add up to 180°.
- first upper angular portion 12a is represented in each cylinder by the green quarter circle, while the second upper angular portion 12b is represented on each cylinder by the red quarter circle.
- each of the angular portions are represented in Figure 3 by an opening angle of 90° (a quarter of a circle), such portions are not limited to that specific angle, and may vary according to need. The important thing is to ensure that for the same roller 10a, 10b, the second upper angular portion 12b is located downstream of the first upper angular portion 12a with reference to the direction of rotation of each roller 10a, 10b.
- first composition its coating material
- second composition the core material of the solid agglomerate
- the proportion between the amount of material in the core and in the coating of the solid agglomerate 5 will be regulated by the feed rate of each material in the press 10.
- a solid agglomerate with a larger and/or denser core is achieved.
- the present invention also provides a process for manufacturing a solid agglomerate 5, by means of a roller press 10 comprising two rollers 10a, 10b provided with cavities 11 fillable with granulated compositions, the process comprising the steps of: a) supplying, from above, a first composition onto a first upper angular portion 12a of each of the rollers 10a, 10b of the roller press 10; b) supplying, from above, a second composition on a second upper angular portion 12b of each of the rollers 10a, 10b of the roller press 10, whereby, for a same roller 10a, 10b, the upper second angular portion 12b it is located downstream of the first upper angular portion 12a with reference to the direction of rotation of each roller 10a, 10b; and c) pressing the supplied material onto the rollers 10a, 10b so as to form a solid agglomerate 5 comprising a core 5n formed by the second composition and a coating 5r formed by the first composition.
- the step of supplying a first composition in a first upper angular portion 12a is carried out simultaneously and separately for each roller 10a, 10b, as shown in figures 2 and 3.
- the step of supplying a second composition on a second upper angular portion 12b is carried out at the same location for both rollers 10a, 10b. More preferably, this step is carried out between rollers 10a, 10b.
- the process of the present invention additionally comprises the step of pre-compacting the second composition prior to the step of supplying a second composition in a second upper angular portion 12b of each of the rollers 10a, 10b of the roller press 10.
- this step is preferably carried out by the central dosing screw 42.
- the solid agglomerate 5 formed by the process and system described above is illustrated in Figure 4 and comprises a core 5n formed by the second composition and a coating 5r formed by the first composition.
- the solid agglomerate 5 of the present invention can be, for example, a coal fuel briquette or a metallic agglomerate, such as a pellet or a ferrous briquette.
- the second composition, which forms the 5n core comprises at least one coking coal and at least one binder.
- the 5n core material is the coking material commonly used in fuel briquettes.
- the second composition, which forms the 5n core comprises 60 to 70% by mass of coking coal and 6 to 10% by mass of binder.
- the first composition, which forms the coating 5r comprises a non-coking coal, or a residue thereof, and at least one binder.
- the carbon in the composition of the coating 5r can be, for example, coke powder or coal residues in general, low quality coals, etc.
- any inert (non-coking) coal residue can be used in the composition of the 5r coating. In this way, when heating inside the reduction furnace, the coating material 5r will not coke, which prevents sticking between the surfaces of the agglomerates and, consequently, the formation of curls.
- the first composition, which forms the coating 5r comprises 70 to 95% by mass of non-coking coal, coke powder, coal residues or any combination thereof, and 5 to 15% by mass of binder.
- the solid agglomerate 5 is a metallic agglomerate, such as a pellet or ferrous briquette.
- an inert material preferably metallic, is used in the 5r coating of the agglomerate to serve as a sacrificial material.
- the 5n core would be formed by the material of interest.
- the solid agglomerate 5 of the present invention can be manufactured in any existing geometric shape, so that the scope of protection of the present invention is not limited to the oval shape shown in figure 4.
- the present invention provides a system and a process for manufacturing a solid agglomerate so that it comprises more than one distinct composition in its structure, where each composition would be located in a certain region of it ( cladding and core).
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Glanulating (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Coke Industry (AREA)
- Press Drives And Press Lines (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
Claims
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP22899666.6A EP4442846A4 (en) | 2021-12-03 | 2022-11-17 | METHOD AND SYSTEM FOR MANUFACTURING A SOLID ACGLOMERATE |
| AU2022401060A AU2022401060B2 (en) | 2021-12-03 | 2022-11-17 | Method and system for manufacturing a solid agglomerate |
| US18/715,404 US20250019793A1 (en) | 2021-12-03 | 2022-11-17 | Process and system for manufacturing a solid agglomerate |
| CN202280080149.8A CN118525106A (zh) | 2021-12-03 | 2022-11-17 | 用于制造固体附聚物的方法和系统 |
| KR1020247021176A KR20240144107A (ko) | 2021-12-03 | 2022-11-17 | 고체 응집체 제조 공정 및 시스템 |
| CA3239583A CA3239583A1 (en) | 2021-12-03 | 2022-11-17 | Process and system for manufacturing a solid agglomerate |
| MX2024006619A MX2024006619A (es) | 2021-12-03 | 2022-11-17 | Proceso y sistema para fabricar un aglomerado solido. |
| JP2024532912A JP2024546627A (ja) | 2021-12-03 | 2022-11-17 | 固体凝集体を製造するためのプロセスおよびシステム |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRBR102021024501-8 | 2021-12-03 | ||
| BR102021024501A BR102021024501A2 (pt) | 2021-12-03 | 2021-12-03 | Processo e sistema de fabricação de um aglomerado sólido |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2023097382A1 true WO2023097382A1 (pt) | 2023-06-08 |
Family
ID=82458284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/BR2022/050451 Ceased WO2023097382A1 (pt) | 2021-12-03 | 2022-11-17 | Processo e sistema de fabricação de um aglomerado sólido |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20250019793A1 (pt) |
| EP (1) | EP4442846A4 (pt) |
| JP (1) | JP2024546627A (pt) |
| KR (1) | KR20240144107A (pt) |
| CN (1) | CN118525106A (pt) |
| AU (1) | AU2022401060B2 (pt) |
| BR (1) | BR102021024501A2 (pt) |
| CA (1) | CA3239583A1 (pt) |
| MX (1) | MX2024006619A (pt) |
| WO (1) | WO2023097382A1 (pt) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119099163A (zh) * | 2024-11-08 | 2024-12-10 | 原平市聚源液压机械股份有限公司 | 一种煤块成型装置及成型方法 |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58135800A (ja) * | 1982-02-04 | 1983-08-12 | Shintou Baauindo Kk | ブリケツトの成形方法 |
| US4504306A (en) * | 1981-07-10 | 1985-03-12 | Nippon Kokan Kabushiki Kaisha | Method of producing agglomerates |
| WO2013152959A1 (de) | 2012-04-10 | 2013-10-17 | Siemens Vai Metals Technologies Gmbh | Verfahren und vorrichtung zur brikettherstellung |
| US8585786B2 (en) | 2006-03-31 | 2013-11-19 | Coaltek, Inc. | Methods and systems for briquetting solid fuel |
| WO2014098413A1 (ko) | 2012-12-21 | 2014-06-26 | 주식회사 포스코 | 성형탄 및 그 제조 방법 |
| AU2008203855B2 (en) | 2008-08-13 | 2015-07-23 | Mecrus Pty Ltd | Process of forming a composite briquette |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE288292C (de) * | 1913-05-11 | 1915-10-26 | Verfahren und Vorrichtung zur Herstellung von Formlingen aus Zementrohmasse durch Halbtrockenpressung. | |
| FR559356A (fr) * | 1921-12-08 | 1923-09-14 | Machine rotative pour la fabrication des briques, briquettes, etc. | |
| JPS5079744U (pt) * | 1973-11-29 | 1975-07-10 | ||
| JPS5387903A (en) * | 1977-01-13 | 1978-08-02 | Nippon Steel Corp | Production of multi-layer pieces |
| DE19731975C2 (de) * | 1997-07-24 | 2003-08-07 | Koeppern & Co Kg Maschf | Verfahren zum Verhindern des Anhaftens von zu briketierendem Gut an einer Walzenoberfläche und Brikettierwalzenpresse |
-
2021
- 2021-12-03 BR BR102021024501A patent/BR102021024501A2/pt unknown
-
2022
- 2022-11-17 US US18/715,404 patent/US20250019793A1/en active Pending
- 2022-11-17 CN CN202280080149.8A patent/CN118525106A/zh active Pending
- 2022-11-17 MX MX2024006619A patent/MX2024006619A/es unknown
- 2022-11-17 JP JP2024532912A patent/JP2024546627A/ja active Pending
- 2022-11-17 WO PCT/BR2022/050451 patent/WO2023097382A1/pt not_active Ceased
- 2022-11-17 AU AU2022401060A patent/AU2022401060B2/en active Active
- 2022-11-17 KR KR1020247021176A patent/KR20240144107A/ko active Pending
- 2022-11-17 CA CA3239583A patent/CA3239583A1/en active Pending
- 2022-11-17 EP EP22899666.6A patent/EP4442846A4/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4504306A (en) * | 1981-07-10 | 1985-03-12 | Nippon Kokan Kabushiki Kaisha | Method of producing agglomerates |
| JPS58135800A (ja) * | 1982-02-04 | 1983-08-12 | Shintou Baauindo Kk | ブリケツトの成形方法 |
| US8585786B2 (en) | 2006-03-31 | 2013-11-19 | Coaltek, Inc. | Methods and systems for briquetting solid fuel |
| AU2008203855B2 (en) | 2008-08-13 | 2015-07-23 | Mecrus Pty Ltd | Process of forming a composite briquette |
| WO2013152959A1 (de) | 2012-04-10 | 2013-10-17 | Siemens Vai Metals Technologies Gmbh | Verfahren und vorrichtung zur brikettherstellung |
| WO2014098413A1 (ko) | 2012-12-21 | 2014-06-26 | 주식회사 포스코 | 성형탄 및 그 제조 방법 |
Non-Patent Citations (1)
| Title |
|---|
| See also references of EP4442846A4 |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN119099163A (zh) * | 2024-11-08 | 2024-12-10 | 原平市聚源液压机械股份有限公司 | 一种煤块成型装置及成型方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| MX2024006619A (es) | 2024-09-17 |
| BR102021024501A2 (pt) | 2022-06-21 |
| AU2022401060B2 (en) | 2025-11-27 |
| KR20240144107A (ko) | 2024-10-02 |
| US20250019793A1 (en) | 2025-01-16 |
| AU2022401060A1 (en) | 2024-06-13 |
| CN118525106A (zh) | 2024-08-20 |
| EP4442846A4 (en) | 2025-10-29 |
| JP2024546627A (ja) | 2024-12-26 |
| CA3239583A1 (en) | 2023-06-08 |
| EP4442846A1 (en) | 2024-10-09 |
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