WO2022248289A1 - Composition - Google Patents

Abstract

Concentrated dishwash detergent composition comprising less than 5% wt. water, anionic surfactant, a solvent, less than 5% wt. non-ionic surfactant and wherein the solvent is selected from dimethyl isosorbide, DMF, 1-butanol, butyl cellosolve, 1-pentanol, N-methyl-2-pyrrolidone, 2-ethyl-1-hexanol, 2-butanol, 3-methyl-1, 3-butane diol, NN-dimethyl decenamide amide, dipropylene glycol butyl ether and mixtures thereof.

Description

COMPOSITION

The present invention relates to a highly concentrated liquid laundry or liquid dishwash composition.

EP-A-1 059350 (Greiter) discloses capsules containing detergents for releasing the same during a cleaning process. Said capsules contain at least one surfactant of the formula [R1-0-(CH2-CH2- 0-)n-L] <-> [R2-NR4H-R3] <+> selected from mono, di or trialkanolammonium salts of alkyl ether sulphates, with a molecular weight of at least 200 g/mol, preferably at least 300 g/mol. In said formula, R1 represents a hydrocarbon radical, comprising at least 6 carbon atoms; n represents a whole number between 1 and 8; L represents -S03; R2 is a linear or branched alcohol group, comprising between 1 and 10 carbons and at least one hydroxyl group; R3 and R4 are identical or different and are selected from the group consisting of hydrogen, linear and/or branched alcohol groups, containing between 1 and 10 carbon atoms and at least one hydroxy group and linear and/or branched alkyl groups with between 1 and 10 carbon atoms. The surfactant can be present either in the capsule jacket or the capsule fill material, or both. The inventive capsule has a high proportion of detergent substances. The capsule jacket material is preferably a macro-molecular native natural substance and/or is chemically and/or physically modified, preferably gelatine.

WO 2000/43476 (P&G) discloses hand dishwashing compositions comprising; a) about 0.1 percent to about 99.9 percent by weight of said composition of an alkylarylsulfonate surfactant system comprising from about 10 percent to about 100 percent by weight of said surfactant system of two or more crystallinity-disrupted alkylarylsulfonate surfactants of formula (B~Ar~

D) _a (M ^q+) _bwherein D is SO 3--, M is a cation or cation mixture, q is the valence of said cation, a and b are numbers selected such that said composition is electroneutral; Ar is selected from benzene, toluene, and combinations thereof; and B comprises the sum of at least one primary hydrocarbyl moiety containing from 5 to 20 carbon atoms and one or more crystallinity-disrupting moieties, wherein said crystallinity-disrupting moieties interrupt or branch from said hydrocarbyl moiety; and wherein said alkylarylsulfonate surfactant system has crystallinity disruption to the extent that its Sodium Critical Solubility Temperature, as measured by the CST Test, is no more than about 40 degrees centigrade; and wherein further said alkylarylsulfonate surfactant system has at least one of the following properties: percentage biodegradation, as measured by the modified SCAS test, that exceeds tetrapropylene benzene sulfonate; and weight ratio of nonquatemary to quaternary carbon atoms in B of at least about 5: 1 ; and b) from about 0.00001 percent to about 99.9 percent by weight of said composition of a conventional hand dishwashing adjunct; c) from about 0.01 percent to about 7 percent by weight of composition of a divalent ion selected from the group consisting of magnesium, calcium and mixtures thereof.

Despite the prior art there remains a need for more concentrated laundry and dishwash detergent compositions.

Accordingly, and in a first aspect, there is provided a concentrated detergent composition comprising less than 5% wt. water, anionic surfactant, a solvent, less than 5% wt. non-ionic surfactant and wherein the solvent is selected from dimethyl isosorbide, DMF, 1-butanol, butyl cellosolve, 1-pentanol, N-methyl-2-pyrrolidone, 2-ethyl- 1-hexanol, 2-butanol, 3-methyl-1, 3-butane diol, NN-dimethyl decenamide amide, dipropylene glycol butyl ether and mixtures thereof.

We have surprisingly found that a composition can be formulated with low non-ionic surfactant levels and which still performs as an ultraconcentrated product for dishwash cleaning use.

Preferably, the anionic surfactant comprises an alkyl ether sulphate with a monoisopropanolamine (MIPA) counterion. More preferably, this comprises from 20 to 70% wt. of the anionic surfactant, more preferably from 30% to 60% and more preferably from 45 to 55% wt. of the anionic surfactant.

Preferably, the anionic surfactant with a MIPA counterion is a C10-18 alkyl ether sulphate. Most preferably, it is a C12 based alkyl ether sulphate. The most preferred is MIPA LES, a C12 alkyl ether sulphate with MIPA counterion.

Weight proportions are calculated for the protonated form of the appropriate surfactant.

Preferably, the composition is visually clear. By visually clear means that the composition when diluted 1 part premix in 3 parts water is less than 20 NTU.

The composition may also comprise linear alkyl benzene sulphonate as anionic surfactant and preferably the proportion of LAS forming the anionic surfactant is from 20 to 70% wt. of the anionic surfactant, more preferably from 30% to 60% and more preferably from 45 to 55% wt. of the anionic surfactant.

The term “surfactant’ in the context of particulate detergent formulations denotes a surfactant which provides a detersive (i.e. cleaning) effect to dishwash compositions. The composition comprises less than 5% wt. non-ionic surfactant. Preferably the composition comprises less than 1 % and preferably 0% wt. non-ionic surfactant by weight of the composition.

Anionic surfactants

The composition comprises an anionic surfactant. Non-soap anionic surfactants for use in the invention are typically salts of organic sulfates and sulfonates having alkyl radicals containing from about 8 to about 22 carbon atoms, the term “alkyl” being used to include the alkyl portion of higher acyl radicals. Examples of such materials include alkyl sulfates, C12-C14 alkyl ether sulfates, alkaryl sulfonates, alpha-olefin sulfonates and mixtures thereof. The alkyl radicals preferably contain from 10 to 18 carbon atoms and may be unsaturated. The C12-C14 alkyl ether sulfates may contain from one to ten ethylene oxide or propylene oxide units per molecule, and preferably contain one to three ethylene oxide units per molecule.

Commonly used in laundry liquid compositions are C12-C14 alkyl ether sulfates (AES)( having a straight or branched chain alkyl group having 12 to 14 carbon atoms and containing an average of 1 to 3EO units per molecule. A preferred example is sodium lauryl ether sulfate (SLES) in which the predominantly C12 lauryl alkyl group has been ethoxylated with an average of 3EO units per molecule.

The C12-C14 alkyl ether sulphate may be provided in a single raw material component or by way of a mixture of components.

The counterion for any of the anionic surfactants used in the compositions described herein is principally a monoisopropanolamine (MIPA), but others are additionally available. Generally an alkali metal such as sodium or potassium; or an ammoniacal counterion such as ammonium, monoethanolamine, (MEA), diethanolamine (DEA) or triethanolamine (TEA). Mixtures of such counterions may also be employed.

The compositions according to the invention may preferably include alkylbenzene sulfonates, particularly linear alkylbenzene sulfonates (LAS) with an alkyl chain length of from 10 to 18 carbon atoms. Commercial LAS is a mixture of closely related isomers and homologues alkyl chain homologues, each containing an aromatic ring sulfonated at the “pa/a” position and attached to a linear alkyl chain at any position except the terminal carbons. The linear alkyl chain typically has a chain length of from 11 to 15 carbon atoms, with the predominant materials having a chain length of about C12. Each alkyl chain homologue consists of a mixture of all the possible sulfophenyl isomers except for the 1 -phenyl isomer. LAS is normally formulated into compositions in acid (i.e. HLAS) form and then at least partially neutralized in-situ.

Some alkyl sulfate surfactant (PAS) may be used, such as non-ethoxylated primary and secondary alkyl sulphates with an alkyl chain length of from 10 to 18.

The composition comprises an anionic surfactant. Preferably the composition comprises from 10 to 80% wt. anionic surfactant based on the total weight of composition, more preferably from 30 to 60% wt. anionic surfactant by weight of the composition.

Preferably, the composition comprises from 20 to 70% wt. LAS, more preferably from 40 to 60% wt. LAS.

Preferably, the composition comprises from 20 to 70% wt. alkyl ether sulphate, more preferably from 40 to 60% wt. of the composition.

Most preferably, the composition comprises LAS and alkyl ether sulphate.

In a preferred embodiment the composition comprises LAS and AES in a weight ratio of from 0.8: 1 to 1.2:1, more preferably, from 0.9:1 to 1.1:1.

Solvents

The composition comprises a solvent.

Preferred solvents include:

-glycol ethers (preferably selected from diethylene glycol alkyl ether (diethylene glycol butyl ether) and diethylene glycol alkyl ether (dipropylene glycol butyl ether).

-alcohols (preferably selected from linear and branched having carbon, more preferably C3 to C12 (1 -butanol, 1-pentanol, 2-ethyl-1 -hexanol, and 2-butanol).

-C1-6 alkyl glycols (preferably selected from linear and branched alkyl glycols, more preferably 3-methyl-1 , 3-butane diol); -C1-12 alkyl/alkenyl amides, preferably selected from (N, N-dimethyl amide, more preferably N, N-dimethyl formamide (DMF), N, N-dimethyl alkenamide, more preferably N, N-dimethyl decenamide (NDD amide)).

-alkyl esters (preferably selected from alkyl levulinate, preferably where alkyl is C1-C4 and more preferably where alkyl is methyl and ethyl).

- N-alkyl(C1-C4) pyrrolidone (preferably selected from linear or branched, more preferably N-methyl-2-pyrrolidone);

- isosorbide alkyl ethers (preferably selected from linear or branched, more preferably, isosorbide dimethyl ether)

More preferably, the solvent is selected from dimethyl isosorbide, DMF, 1-butanol, butyl cellosolve, 1-pentanol, N-methyl-2-pyrrolidone, 2-ethyl- 1-hexanol, 2-butanol, 3-methyl-1 , 3-butane diol, NDD amide, dipropylene glycol butyl ether and mixtures thereof.

Fatty Amides

Where the composition is a dishwash composition it preferably comprises a fatty amide. Suitable fatty amides include cocoamidopropyl betaine (CAPB), coco a ido propyl amine oxide (CAPAO), cocodiethanol amide (CDEA) and cocomonoethanol amide (CMEA). Most preferred amphoteric surfactant is cocoamidopropyl betaine.

Preferably, the fatty amide is present at from 0.1 to 10% wt. of the composition.

Fatty Acids

Suitable fatty acids for laundry liquid compositions in the context of this invention include aliphatic carboxylic acids of formula RCOOH, where R is a linear or branched alkyl or alkenyl chain containing from 6 to 24, more preferably 10 to 22, most preferably from 12 to 18 carbon atoms and 0 or 1 double bond. Preferred examples of such materials include saturated C 12-18 fatty acids such as lauric acid, myristic acid, palmitic acid or stearic acid; and fatty acid mixtures in which 50 to 100% (by weight based on the total weight of the mixture) consists of saturated C12-18 fatty acids. Such mixtures may typically be derived from natural fats and/or optionally hydrogenated natural oils (such as coconut oil, palm kernel oil or tallow). The fatty adds may be present in the form of their sodium, potassium or ammonium salts and/or in the form of soluble salts of organic bases, such as mono-, di- or triethanolamine.

Mixtures of any of the above described materials may also be used.

Fatty adds and/or their salts, when included, may be present in an amount ranging from about 0.25 to 5%, more preferably from 0.5 to 5%, most preferably from 0.75 to 4% (by weight based on the total weight of the composition).

For formula accounting purposes, in the formulation, fatty acids and/or their salts (as defined above) are not included in the level of surfactant or in the level of builder.

Hydrotrope

A composition of the invention may incorporate non-aqueous carriers such as hydrotropes, co-solvents and phase stabilizers. Such materials are typically low molecular weight, water- soluble or water-miscible organic liquids such as C1 to C5 monohydric alcohols (such as ethanol and n- or i-propanol); C2 to C6 diols (such as monopropylene glycol and dipropylene glycol); C3 to C9 triols (such as glycerol); polyethylene glycols having a weight average molecular weight (M_w) ranging from about 200 to 600; C1 to C3 alkanolamines such as mono-, di- and triethanolamines; and alkyl aryl sulfonates having up to 3 carbon atoms in the lower alkyl group (such as the sodium and potassium xylene, toluene, ethylbenzene and isopropyl benzene (cumene) sulfonates).

Mixtures of any of the above described materials may also be used.

Non-aqueous carriers, when included, may be present in an amount ranging from 0.1 to 20%, preferably from 2 to 15%, and more preferably from 10 to 14% (by weight based on the total weight of the composition). The level of hydrotrope used is linked to the level of surfactant and it is desirable to use hydrotrope level to manage the viscosity in such compositions. The preferred hydrotropes are monopropylene glycol and glycerol.

Water

Preferably, the composition comprises less than 5% water. By free water is meant water which is added to the composition and does not include water which is added along with a further raw material in which it is incorporated. For example, many surfactants are commercially available as aqueous solutions or suspensions of surfactants. Most preferably, the composition comprises less than 1 % wt. water.

Water-Soluble Film Compositions

The unit dose composition of the invention is preferably contained within a pouch formed by a water dissoluble film.

Such water-soluble film compositions, optional ingredients for use therein, and methods of making the same are well known in the art, whether being used for making relatively thin water-soluble films (e.g., as pouch materials) or otherwise.

In one class of embodiments, the water-soluble film includes a water dissoluble material. Preferred such materials include polyvinyl alcohol (PVOH), including homopolymers thereof (e.g., including substantially only vinyl alcohol and vinyl acetate monomer units) and copolymers thereof (e.g., including one or more other monomer units in addition to vinyl alcohol and vinyl acetate units). PVOH is a synthetic resin generally prepared by the alcoholysis, usually termed hydrolysis or saponification, of polyvinyl acetate. Fully hydrolyzed PVOH, wherein virtually all the acetate groups have been converted to alcohol groups, is a strongly hydrogen-bonded, highly crystalline polymer which dissolves only in hot water- greater than about 140 degrees Fahrenheit (60 degrees C). If a sufficient number of acetate groups are allowed to remain after the hydrolysis of polyvinyl acetate, the PVOH polymer then being known as partially hydrolyzed, it is more weakly hydrogen-bonded and less crystalline and is soluble in cold water- less than about 50 degrees Fahrenheit (10 degrees C). An intermediate cold or hot water soluble film can include, for example, intermediate partially- hydrolyzed PVOH (e.g., with degrees of hydrolysis of about 94 percent to about 98 percent), and is readily soluble only in warm water- e.g., rapid dissolution at temperatures of about 40 degrees centigrade and greater. Both fully and partially hydrolyzed PVOH types are commonly referred to as PVOH homopolymers although the partially hydrolyzed type is technically a vinyl alcohol- vinyl acetate copolymer.

The degree of hydrolysis (DH) of the PVOH polymers and PVOH copolymers included in the water-soluble films of the present disclosure can be in a range of about 75 percent to about 99 percent (e.g., about 79 percent to about 92 percent, about 86.5 percent to about 89 percent, or about 88 percent, such as for cold-water soluble compositions; about 90 percent to about 99 percent, about 92 percent to about 99 percent, or about 95 percent to about 99 percent). As the degree of hydrolysis is reduced, a film made from the resin will have reduced mechanical strength but faster solubility at temperatures below about 20 degrees centigrade As the degree of hydrolysis increases, a film made from the polymer will tend to be mechanically stronger and the thermoformability will tend to decrease. The degree of hydrolysis of the PVOH can be chosen such that the water- solubility of the polymer is temperature dependent, and thus the solubility of a film made from the polymer, any compatibilizer polymer, and additional ingredients is also influenced. In one option the film is cold water-soluble. A cold water-soluble film, soluble in water at a temperature of less than

10 degrees centigrade, can include PVOH with a degree of hydrolysis in a range of about 75 percent to about 90 percent, or in a range of about 80 percent to about 90 percent, or in a range of about 85 percent to about 90 percent. In another option the film is hot water-soluble. A hot water-soluble film, soluble in water at a temperature of at least about 60 degrees centigrade, can include PVOH with a degree of hydrolysis of at least about 98 percent.

Other water soluble polymers for use in addition to the PVOH polymers and PVOH copolymers in the blend can include, but are not limited to modified polyvinyl alcohols, polyacrylates, water- soluble acrylate copolymers, polyvinyl pyrrolidone, polyethyleneimine, pullulan, water-soluble natural polymers including, but not limited to, guar gum, gum Acacia, xanthan gum, carrageenan, and starch, water-soluble polymer derivatives including, but not limited to, modified starches, ethoxylated starch, and hydroxypropylated starch, copolymers of the forgoing and combinations of any of the foregoing. Yet other water-soluble polymers can include polyalkylene oxides, polyacrylamides, polyacrylic acids and salts thereof, celluloses, cellulose ethers, cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts thereof, polyaminoacids, polyamides, gelatines, methylcelluloses, carboxymethylcelluloses and salts thereof, dextrins, ethylcelluloses, hydroxyethyl celluloses, hydroxypropyl methylcelluloses, maltodextrins, and polymethacrylates. Such water-soluble polymers, whether PVOH or otherwise are commercially available from a variety of sources. Any of the foregoing water-soluble polymers are generally suitable for use as film-forming polymers. In general, the water- soluble film can include copolymers and/or blends of the foregoing resins.

The water-soluble polymers (e.g., the PVOH resin blend alone or in combination with other water- soluble polymers) can be included in the film in an amount in a range of about 30 weight percent or 50 weight percent to about 90 weight percent or 95 weight percent, for example. The weight ratio of the amount of all water-soluble polymers as compared to the combined amount of all plasticizers, compatibilizing agents, and secondary additives can be in a range of about 0.5 to about 18, about 0.5 to about 15, about 0.5 to about 9, about 0.5 to about 5, about 1 to 3, or about 1 to 2, for example. The specific amounts of plasticizers and other non-polymer component can be selected in a particular embodiment based on an intended application of the water-soluble film to adjust film flexibility and to impart processing benefits in view of desired mechanical film properties. Water-soluble polymers for use in the film described herein (including, but not limited to PVOH polymers and PVOH copolymers) can be characterized by a viscosity in a range of about 3.0 to about 27.0 cP, about 4.0 to about 24.0 cP, about 4.0 to about 23.0 cP, about 4.0 cP to about 15 cP, or about 6.0 to about 10.0 cP, for example. The viscosity of a polymer is determined by measuring a freshly made solution using a Brookfield LV type viscometer with UL adapter as described in British Standard EN IS0 15023-2:2006 Annex E Brookfield Test method. It is international practice to state the viscosity of 4 percent aqueous polyvinyl alcohol solutions at 20 degrees centigrade Polymeric viscosities specified herein in cP should be understood to refer to the viscosity of a 4 percent aqueous water-soluble polymer solution at 20 degrees centigrade, unless specified otherwise.

It is well known in the art that the viscosity of a water-soluble polymer (PVOH or otherwise) is correlated with the weight- average molecular weig ht (W) of the same polymer, and often the viscosity is used as a proxy for Mw. Thus, the weight- average molecular weight of the water- soluble polymers, including the first PVOH copolymer and second PVOH polymer, can be in a range of about 30,000 to about 175,000, or about 30,000 to about 100,000, or about 55,000 to about 80,000, for example.

The water-soluble film can contain other auxiliary agents and processing agents, such as, but not limited to, plasticizers, plasticizer compatibilizers, surfactants, lubricants, release agents, fillers, extenders, cross-linking agents, antiblocking agents, antioxidants, detackifying agents, antifoams, nanoparticles such as layered silicate-type nanoclays (e.g., sodium montmorillonite), bleaching agents (e.g., sodium metabisulfite, sodium bisulfite or others), aversive agents such as bitterants (e.g., denatonium salts such as denatonium benzoate, denatonium saccharide, and denatonium chloride; sucrose octaacetate; quinine; flavonoids such as quercetin and naringen; and quassinoids such as quassin and brucine) and pungents (e.g., capsaicin, pipeline, allyl isothiocyanate, and resinferatoxin), and other functional ingredients, in amounts suitable for their intended purposes. Embodiments including plasticizers are preferred. The amount of such agents can be up to about 50 wt. , 20 wt percent, 15 wt percent, 10 wt percent, 5 weight percent, 4 wt percent and/or at least 0.01 weight percent, 0.1 wt percent, 1 wt percent, or 5 wt, individually or collectively.

The plasticizer can include, but is not limited to, glycerin, diglycerin, sorbitol, ethylene glycol, diethylene glycol, triethylene glycol, dipropylene glycol, tetraethylene glycol, propylene glycol, polyethylene glycols up to 400 MW, neopentyl glycol, trimethylolpropane, polyether polyols, sorbitol, 2-methyl-l, 3-propanediol, ethanolamines, and a mixture thereof. A preferred plasticizer is glycerin, sorbitol, triethyleneglycol, propylene glycol, diproyplene glycol, 2-methyl-l, 3-propanediol, trimethylolpropane, or a combination thereof. The total amount of the plasticizer can be in a range of about 10 weight percent to about 40 wt., or about 15 weight percent to about 35 wt, or about 20 weight percent to about 30 wt., for example about 25 wt., based on total film weight. Combinations of glycerin, dipropylene glycol, and sorbitol can be used. Optionally, glycerin can be used in an amount of about 5 wt percent to about 30 wt, or 5 wt percent to about 20 wt, e.g., about 13 wt percent.

Optionally, dipropylene glycol can be used in an amount of about 1 weight percent to about 20 wt., or about 3 weight percent to about 10 wt., for example 6 weight percent. Optionally, sorbitol can be used in an amount of about 1 wt percent to about 20 wt, or about 2 wt percent to about 10 wt, e.g., about 5 wt percent. The specific amounts of plasticizers can be selected in a particular embodiment based on desired film flexibility and processability features of the water-soluble film.

At low plasticizer levels, films may become brittle, difficult to process, or prone to breaking. At elevated plasticizer levels, films may be too soft, weak, or difficult to process for a desired use.

In a preferred embodiment the composition comprises a taste aversive such as denatonium benzoate and/or a pungent agent such as capsaicin.

Preferably the composition is a unit dosed composition of from 4 to 12ml and contained within a water dissoluble pouch as described above.

Optional Components

A composition may also contain one or more cosurfactants (such as amphoteric (zwitterionic) and/or cationic surfactants) in addition to the non-soap anionic and/or non-ionic detersive surfactants described above.

Specific cationic surfactants include Cs to Cie alkyl dimethyl ammonium halides and derivatives thereof in which one or two hydroxyethyl groups replace one or two of the methyl groups, and mixtures thereof. Cationic surfactant, when included, may be present in an amount ranging from 0.1 to 5% (by weight based on the total weight of the premix composition).

Specific amphoteric (zwitterionic) surfactants include alkyl amine oxides, alkyl betaines, alkyl amidopropyl betaines, alkyl sulphobetaines (sultaines), alkyl glycinates, alkyl carboxyglycinates, alkyl amphoacetates, alkyl amphopropionates, alkylamphoglycinates, alkyl amidopropyl hydroxysultaines, acyl taurates and acyl glutamates, having alkyl radicals containing from about 8 to about 22 carbon atoms, the term “alkyl” being used to include the alkyl portion of higher acyl radicals. Amphoteric (zwitterionic) surfactant, when included, may be present in an amount ranging from 0.1 to 5% (by weight based on the total weight of the composition).

A composition may also contain one or more chelating agents for transition metal ions. Such chelating agents may also have calcium and magnesium chelation capacity, but preferentially bind heavy metal ions such as iron, manganese and copper. Such chelating agents may help to improve the stability of the composition and protect for example against transition metal catalyzed decomposition of certain ingredients.

Suitable transition metal ion chelating agents include phosphonates, in acid and/or salt form.

When utilized in salt form, alkali metal (e.g. sodium and potassium) or alkanolammonium salts are preferred. Specific examples of such materials include aminotris(methylene phosphonic acid) (ATMP), 1-hydroxyethylidene diphosphonic acid (HEDP) and diethylenetriamine penta(methylene phosphonic acid (DTPMP) and their respective sodium or potassium salts. HEDP is preferred. Mixtures of any of the above described materials may also be used.

Transition metal ion chelating agents, when included, may be present in an amount ranging from about 0.1 to about 10%, preferably from about 0.1 to about 3% (by weight based on the total weight of the composition). Mixtures of any of the above described materials may also be used.

A composition may also comprise an effective amount of one or more enzyme selected from the group comprising, pectate lyase, protease, amylase, cellulase, lipase, mannanase and mixtures thereof. The enzymes are preferably present with corresponding enzyme stabilizers.

A composition may contain further optional ingredients to enhance performance and/or consumer acceptability. Examples of such ingredients include foam control agents, preservatives (e.g. bactericides), fluorescers and pearlisers. Each of these ingredients will be present in an amount effective to accomplish its purpose. Generally, these optional ingredients are included individually at an amount of up to 5% (by weight based on the total weight of the composition).

Packaging and dosing

A composition of the invention may be packaged as unit dose in polymeric film soluble in the wash water. Alternatively, a composition of the invention may be supplied in multidose plastics packs with a top or bottom closure. A dosing measure may be supplied with the pack either as a part of the cap or as an integrated system.

In a second aspect there is provided a method for forming a dishwash or laundry liquid composition by taking a composition as described herein and adding from 3 to 100 parts of water to one part of composition and mixing. The resulting laundry or dishwash liquid composition is stable and may be kept by the consumer until ready for use as a liquid detergent composition.

In a third aspect there is provided a packaged product comprising a composition as described herein.

In a fourth aspect there is provided a method for forming a laundry or dishwash liquid composition by taking a composition as described herein and adding from 3 to 100 parts of water to one part of composition and mixing. The resulting laundry or dishwash liquid composition is stable and may be kept by the consumer until ready for use as a liquid detergent composition.

EXAMPLES

EXAMPLE 1

The following are formulations according to embodiments of the invention.

EXAMPLE 2

The following is a comparative formulation:

The following is an inventive formulation:

The two formulations were compared for their foaming performance.

Foam generation done with a manual cylinder shake method. Foam stability is tested with addition of water.

The figures represent the foam volume-liquid volume (ml). The data shows that the test formulation provides improved foam performance over repeated rinses when compared to the comparative.

EXAMPLE 3

The table shows the ability to produce an isotropic formulation using different solvents.

Claims

1. Concentrated dishwash detergent composition comprising less than 5% wt. water, anionic surfactant, less than 5% wt. non-ionic surfactant and a solvent selected from dimethyl isosorbide, DMF, 1-butanol, butyl cellosolve, 1-pentanol, N-methyl-2-pyrrolidone, 2-ethyl-1- hexanol, 2-butanol, 3-methyl-1, 3-butane diol, NN-dimethyl decenamide amide, dipropylene glycol butyl ether and mixtures thereof, and wherein said anionic surfactant comprises linear alkyl benzene sulphonate and an alkyl ether sulphate.

2. Composition according to claim 1 wherein the alkyl ether sulphate comprises a mono- isopropanolamine (MIPA) counterion.

3. Composition according to claim 1 or 2 wherein comprising less than 1 % wt. non-ionic surfactant.

4. Composition according to any preceding claim comprising less than 1 % wt. water.

5. Composition according to any preceding claim in a unit dose format.

6. Composition according to claim 5 wherein a unit dose of composition is disposed in a water dissoluble pouch.

7. Composition according to any preceding claim comprising from 20-70% wt. LAS.

8. Composition according to any preceding claim comprising from 20-70% wt. alkyl ether sulphate.

9. A method for forming a liquid dishwash detergent composition by dispersing a dose of a composition according to any of claims 1-6 in water.

10. A method of forming a dishwash liquor by dispersing a dose of a composition according to any of claims 1-6 in water.