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WO2020116299A1 - Composition for batter - Google Patents

Composition for batter Download PDF

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Publication number
WO2020116299A1
WO2020116299A1 PCT/JP2019/046520 JP2019046520W WO2020116299A1 WO 2020116299 A1 WO2020116299 A1 WO 2020116299A1 JP 2019046520 W JP2019046520 W JP 2019046520W WO 2020116299 A1 WO2020116299 A1 WO 2020116299A1
Authority
WO
WIPO (PCT)
Prior art keywords
mass
starch
batter
component
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2019/046520
Other languages
French (fr)
Japanese (ja)
Inventor
加藤 健太
温子 藤牧
三四郎 齋藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
J Oil Mills Inc
Original Assignee
J Oil Mills Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by J Oil Mills Inc filed Critical J Oil Mills Inc
Priority to JP2020559111A priority Critical patent/JP7437319B2/en
Publication of WO2020116299A1 publication Critical patent/WO2020116299A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/10General methods of cooking foods, e.g. by roasting or frying
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/157Farinaceous granules for dressing meat, fish or the like
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L13/00Meat products; Meat meal; Preparation or treatment thereof
    • A23L13/50Poultry products, e.g. poultry sausages

Definitions

  • the present invention relates to a composition for batter.
  • Patent Document 1 JP-A-2015-223119.
  • the document describes a water-soluble type fried mix containing wheat flour, oxidized starch, phosphoric acid cross-linked starch and baking soda, respectively.
  • adhesion to ingredients is improved. It is said that fried food can be produced because it has a good appearance and a good texture, and the quality of the oil is not significantly deteriorated even after the passage of time.
  • the following composition for batter, batter, method for producing food, method for improving appearance of food, and method for improving texture of food are provided.
  • the content of the component (A) in the batter composition is 3.0 mass% or more and 55 mass% or less based on the entire batter composition.
  • the batter composition according to [1], wherein the content of the component (B) with respect to the content of the component (A) is 0.4 or more and 8 or less in terms of mass ratio.
  • the component (A) contains, as a starch other than the low-molecular-weight starch, one or more selected from the group consisting of corn starch, wheat starch, potato starch, tapioca starch and cross-linked starch thereof.
  • the batter composition according to [7] wherein the content of the component (C) with respect to the content of the component (A) is 0.5 or more and 10 or less in mass ratio.
  • the batter is a food batter selected from the group consisting of fried chicken, tempura and fritters.
  • the following components (A) and (B) are included, The content of the component (B) with respect to the content of the component (A) is 0.4 or more and 8 or less in mass ratio, When the batter further contains the following component (C), the content of the component (C) with respect to the content of the component (A) is 0.5 or more and 10 or less in mass ratio, The total amount of the component (A) and the component (B), or the total amount of the component (A), the component (B) and the component (C) when the batter further includes the component (C).
  • a batter containing 20% by mass or more and 100% by mass or less of the whole powder raw material (A) Starch-like substance satisfying the following conditions (1) to (5) (1) Starch content of 75% by mass or more (2) Amylose content of 5% by mass or more 3% by mass of low-molecular-weight starch And 45% by mass or more, and the peak molecular weight of the low molecular weight starch is 3 ⁇ 10 3 or more and 5 ⁇ 10 4 or less (3) the degree of cold water swelling at 25° C.
  • the raw material contains wheat flour in an amount of 5% by mass or more and 59% by mass or less based on the entire powder raw material.
  • the total content of the component (A), the component (B), and the component (C) in the batter is 8% by mass or more and 50% by mass or less with respect to the entire batter, [10] or The batter described in [11].
  • a method for producing a food product comprising: [14] The method for producing a food according to [13], further including a step of storing the food in a frozen state after the step of obtaining the food.
  • the method for producing a food according to [14] further comprising a step of heating and thawing the food after the step of freezing and storing.
  • [16] A method for suppressing the deterioration of the appearance of food, which uses the batter according to any one of [10] to [12].
  • [17] A method for suppressing the deterioration of the texture of food by using the batter according to any one of [10] to [12].
  • the present invention it is possible to suppress the deterioration of the appearance and texture of the food obtained by cooking over time, and to favor the appearance and the texture of clothes when reheated after storage. It is possible to obtain food with a feeling.
  • each component may be used alone or in combination of two or more.
  • the freshness in the following embodiments means that there is little deterioration during storage, and that the product has an appearance and texture similar to that immediately after cooking before storage.
  • composition for batter In the present embodiment, the batter composition is used by being dispersed in water and contains the following components (A) and (B).
  • composition for batter when used for a batter, only the composition for batter may be dispersed in water to prepare a liquid batter, or other components may be added to prepare a liquid batter. Good.
  • components (A) and (B) will be described more specifically.
  • the component (A) is specifically a powdery material containing starch as a main component.
  • the component (A) satisfies the following conditions (1) to (5).
  • Amylose content is 5% by mass or more
  • the low molecular weight starch is 3% by mass or more and 45% by mass or less
  • the peak molecular weight of the low molecular weight starch is 3 ⁇ 10.
  • Cold water swelling degree at 25° C. is 5 or more and 20 or less
  • the content on the sieve of a sieve having an opening of 0.5 mm is 30 mass% or less
  • the component (A) contains 75% by mass or more of starch, preferably 80% by mass or more, from the viewpoint of suppressing deterioration of the appearance and texture of the food to which the batter is applied after storage. More preferably, it contains 85 mass% or more.
  • the upper limit of the starch content in the component (A) is not limited and is 100% by mass or less, but it is 99.5% by mass or less, 99% by mass or less depending on the properties of the food to which the batter is applied. Good.
  • the component (A) contains, as the above-mentioned starch, a low-molecular-weight starch made from a starch having an amylose content of 5% by mass or more in a specific ratio, and having a specific size as the low-molecular-weight starch.
  • the starch in the component (A) contains 3% by mass or more and 45% by mass or less of the low molecular weight starch made from starch having an amylose content of 5% by mass or more in the component (A), and the peak of the low molecular weight starch is obtained.
  • the molecular weight is 3 ⁇ 10 3 or more and 5 ⁇ 10 4 or less.
  • the peak molecular weight of the low-molecular-weight starch is 3 ⁇ 10 3 or more, preferably 8 ⁇ 10 3 or more, from the viewpoint of suppressing deterioration of the appearance and texture of the food to which the batter is applied after storage. From the same viewpoint, the peak molecular weight of the low molecular weight starch is 5 ⁇ 10 4 or less, preferably 3 ⁇ 10 4 or less, and more preferably 1.5 ⁇ 10 4 or less.
  • the method for measuring the peak molecular weight of the low molecular weight starch is described in the section of Examples.
  • the low-molecular-weight starch is preferably one or more selected from the group consisting of acid-treated starch, oxidative-treated starch and enzyme-treated starch from the viewpoint of excellent production stability, and more preferably acid-treated starch. It is starch.
  • the conditions of the acid treatment for obtaining the acid-treated starch are not limited, but the treatment can be performed as follows, for example. First, a starch having an amylose content of 5% by mass or more, which is a raw material of a low-molecular-weight starch, and water are charged into a reactor, and then an acid is further charged. Alternatively, acid water obtained by dissolving an inorganic acid in water in advance and starch as a raw material are put into a reactor. From the viewpoint of more stable acid treatment, it is desirable that the total amount of starch in the reaction is in a state of being uniformly dispersed in the aqueous phase or in a state of being slurried.
  • the concentration of the starch slurry during the acid treatment is adjusted to be, for example, 10% by mass or more and 50% by mass or less, preferably 20% by mass or more and 40% by mass or less. If the slurry concentration is too high, the slurry viscosity may increase, and it may be difficult to uniformly stir the slurry.
  • the acid used for the acid treatment include inorganic acids such as hydrochloric acid, sulfuric acid and nitric acid, which can be used regardless of the type and purity.
  • the inorganic acid concentration during acid treatment is preferably 0.05 normality (N) or more and 4N or less, more preferably 0.1N or more and 4N or less, from the viewpoint of stably obtaining acid-treated starch. It is preferably 0.2 N or more and 3 N or less.
  • the reaction temperature is preferably 30°C or higher and 70°C or lower, more preferably 35°C or higher and 70°C or lower, and further preferably 35°C or higher and 65°C or lower.
  • the reaction time is preferably 0.5 hours or more and 120 hours or less, more preferably 1 hour or more and 72 hours or less, still more preferably 1 hour or more and 48 hours or less.
  • the content of the low-molecular-weight starch in the component (A) is 3% by mass or more, and preferably 8% by mass, from the viewpoint of suppressing deterioration of the appearance and texture of the food to which the batter is applied after storage. Or more, More preferably, it is 13 mass% or more. From the same viewpoint, the content of the low molecular weight starch in the component (A) is 45% by mass or less, preferably 35% by mass or less, and more preferably 25% by mass or less.
  • the amylose content in the raw starch of the low-molecular-weight starch is 5% by mass or more, preferably 12% by mass, from the viewpoint of suppressing deterioration of the appearance and texture of the food to which the batter is applied after storage.
  • the amount is more preferably 22% by mass or more, still more preferably 40% by mass or more, still more preferably 45% by mass or more, still more preferably 55% by mass or more.
  • High-amylose cornstarch, cornstarch, tapioca starch, sweet potato starch, potato starch, wheat starch, high-amylose wheat starch, rice starch, and these raw materials are used as a low-molecular-weight starch raw material having an amylose content of 5% by mass or more.
  • One or more selected from the group consisting of chemically, physically or enzymatically modified starch can be used.
  • the starch having an amylose content of 5% by mass or more is preferably selected from high amylose cornstarch, cornstarch, and tapioca starch from the viewpoint of suppressing the deterioration of the appearance and texture of the food to which the batter is applied after storage.
  • High amylose corn starch having an amylose content of 40% by mass or more is available.
  • the starch having an amylose content of 5% by mass or more is more preferably corn starch having an amylose content of 40% by mass or more.
  • the component (A) is configured to satisfy the specific condition (3) regarding the swelling degree in cold water and the particle size satisfying the specific conditions (4) and (5).
  • the degree of cold water swelling of the component (A) is 5 or more, and preferably 6 or more, from the viewpoint of suppressing the deterioration of the appearance and texture after storage of the food to which the batter is applied. Yes, and more preferably 6.5 or more.
  • the degree of cold water swelling of the component (A) is 20 or less, preferably 17 or less, more preferably 15 or less.
  • the method for measuring the cold water swelling degree of the component (A) will be described in the section of Examples.
  • the content of particles under the sieve with a mesh of 0.5 mm and on the sieve with a sieve of 0.075 mm causes deterioration of the appearance and texture of the food to which the batter is applied after storage.
  • the content is 20% by mass or more, preferably 35% by mass or more, more preferably 50% by mass or more, still more preferably 60% by mass or more, based on the entire component (A).
  • the content of particles under the sieve having a mesh of 0.5 mm and on the sieve of a 0.075 mm sieve is 95% by mass or less based on the entire component (A), and from the same viewpoint, it is preferable. It is 91 mass% or less, and more preferably 88 mass% or less.
  • the content of particles on the sieve of a sieve having an opening of 0.5 mm is determined as the component (A) from the viewpoint of suppressing the bruise of the batter-applied food immediately after frying.
  • the amount is 30% by mass or less, preferably 25% by mass or less, and more preferably 20% by mass or less, based on the whole.
  • the content of particles on a sieve having a mesh size of 0.5 mm has no lower limit and is 0% by mass or more based on the entire component (A), but the surface of a food to which the batter is applied after storage. From the viewpoint of making the state and color tone preferable, the content is preferably 3% by mass or more, more preferably 5% by mass or more, still more preferably 10% by mass or more, still more preferably 15% by mass or more.
  • the content of particles on the sieve of a sieve having a mesh size of 0.075 mm is from the viewpoint of making the appearance and color tone of the surface of the food to which the batter is applied after storage favorable. It is preferably 10% by mass or more, more preferably 30% by mass or more, still more preferably 50% by mass or more, and still more preferably 70% by mass or more, based on the entire component (A).
  • the upper limit of the content of particles on a sieve having a mesh of 0.075 mm is not limited and is 100% by mass or less, preferably 99% by mass or less, and more preferably 97% by mass or less.
  • the component (A) contains a starch other than the low molecular weight starch.
  • starch component other than the low molecular weight starch in the component (A) various starches can be used. Specifically, starches that are generally commercially available depending on the application, such as starches for food, may be of any kind, but starches such as cornstarch, potato starch, tapioca starch, wheat starch and the like; and these starches may be used. One or more kinds can be appropriately selected from chemically, physically or enzymatically processed starch and the like.
  • the component (A) preferably contains one or more starches selected from the group consisting of corn starch, wheat starch, potato starch, tapioca starch and cross-linked starch thereof.
  • the component (A) may contain components other than starch.
  • components other than starch include pigments and insoluble salts such as calcium carbonate and calcium sulfate.
  • the component (A) is preferably blended with an insoluble salt, and the blending amount of the insoluble salt is more preferably 0.1% by mass or more and 2% by mass or less.
  • the method for producing the component (A) includes, for example, the following steps.
  • Step of preparing low molecular weight starch A step of low molecular weight starch having an amylose content of 5% by mass or more to obtain a low molecular weight starch having a peak molecular weight of 3 ⁇ 10 3 or more and 5 ⁇ 10 4 or less.
  • Granulation step The raw material contains 3% by mass or more and 45% by mass or less of the low molecular weight starch, and the total amount of the low molecular weight starch and the starch other than the low molecular weight starch is 75% by mass or more. And granulate.
  • the process of preparing low molecular weight starch is a process of decomposing starch having an amylose content of 5% by mass or more to obtain low molecular weight starch.
  • degradation refers to decomposition accompanied by lowering the molecular weight of starch, and typical decomposition methods include acid treatment, oxidation treatment, and enzymatic treatment. Among these, acid treatment is preferable from the viewpoints of decomposition rate, cost, and reproducibility of decomposition reaction.
  • a general method used for granulating starch can be used, but in view of obtaining a predetermined cold water swelling degree, a general method used for heating gelatinization of starch is used. It is preferable to use various methods. Specifically, a method using a machine such as a drum dryer, a jet cooker, an extruder, and a spray dryer is known, but in the present embodiment, the component (A) whose cold water swelling degree satisfies the above-mentioned specific condition (A). From the viewpoint of more surely obtaining the above, heating gelatinization by an extruder or a drum dryer is preferable, and an extruder is more preferable.
  • water is usually added to the starch-containing raw material to adjust the water content to about 10 to 60% by mass, and then the barrel temperature is 30 to 200° C., the outlet temperature is 80 to 180° C., and the screw rotation speed is 100 to Heat expansion is performed under conditions of 1,000 rpm and heat treatment time of 5 to 60 seconds.
  • the component (A) satisfying the conditions (3) to (5) may be obtained by appropriately adjusting.
  • the component (A) obtained as described above is a starch-like substance containing a low-molecular-weight starch and has a constitution satisfying the conditions (1) to (5). Incorporated in the composition, it is possible to suppress the deterioration of the appearance and texture of the food to which the batter is applied over time, and also when the product is reheated after storage, a preferable freshness of appearance and texture Can be given to.
  • the texture one or more kinds selected from the group consisting of a crispy sensation of clothing, suppression of baldness of clothing, and suppression of powderyness of food can be mentioned, and preferably the crispy feeling of clothing is mentioned. Be done.
  • the content of the component (A) in the composition for batter makes the appearance of the surface of the food to which the batter is applied preferable, and from the viewpoint of improving the crispy feeling, it is preferably 3. It is 0% by mass or more, more preferably 5.0% by mass or more, further preferably 10% by mass or more, still more preferably 15% by mass or more. Further, from the viewpoint of suppressing the battering of the batter of the food to which the batter is applied, the content of the component (A) in the composition for batter is preferably 55% by mass or less, more preferably 50% by mass or less, It is more preferably 40% by mass or less, and even more preferably 30% by mass or less.
  • Component (B) is one or two starches selected from the group consisting of oxidized starch and acid-treated starch. Further, the starch may be the same as or different from the low molecular weight starch in the component (A), but is preferably a different starch.
  • the raw starch may be a raw starch or an acetylated oxidized starch that has been processed other than oxidized.
  • the oxidized starch has been subjected to processing other than oxidation, there is no limitation on the order of the oxidation and other processing.
  • the raw starch may be a raw starch or a processed starch other than an acid-treated starch.
  • the acid-treated starch has been subjected to a processing treatment other than the acid treatment, there is no limitation on the order of the acid treatment and the other processing treatments.
  • the source starch is derived from corn, high-amylose corn, corn (waxy corn), rice, glutinous rice, wheat, sweet potato, potato, glutinous potato, cassava, sago palm and the like. ..
  • the origin of the raw material starch of the oxidized starch of the component (B) is preferably cassava.
  • the source starch is derived from corn, high amylose corn, corn corn (waxy corn), rice, glutinous rice, wheat, sweet potato, potato, glutinous potato, cassava, sago palm and the like. Be done.
  • the origin of the raw material starch of the acid-treated starch of component (B) is preferably corn, and more preferably corn. It is corn corn (waxy corn).
  • the origin of the raw material starch of the component (B) is one selected from the group consisting of cassava and corn. is there.
  • the content of the component (B) with respect to the content of the component (A), that is, ((B)/(A)), makes the appearance of the surface of the food obtained by heating and cooking preferable, and deteriorates the texture over time.
  • the mass ratio is preferably 0.4 or more, more preferably 0.6 or more.
  • the mass ratio ((B)/(A)) is preferably 8 or less, more preferably 7 or less, and further preferably 5 or less, from the viewpoint of suppressing battering of foods to which the batter is applied. , And even more preferably 3 or less.
  • the content of the component (A) is preferably based on the entire composition for batter. It is 3.0 mass% or more and 55 mass% or less, and the mass ratio ((B)/(A)) is 0.4 or more and 8 or less.
  • the mass ratio ((B)/(A)) is specifically described above depending on the content of the component (A) in the composition for batter. It can be set to fall within the range.
  • the composition for batter in the present embodiment contains the components (A) and (B), it is possible to suppress the deterioration of the appearance and texture of the food to which the batter is applied with time, and to reheat after storage. In addition, it is possible to give the food a fresh texture with a favorable appearance and texture.
  • the texture one or more kinds selected from the group consisting of a crispy sensation of clothing and suppression of baldness of the clothing can be mentioned, and a crispy sensation of clothing is preferred.
  • composition for batter may be composed only of the components (A) and (B), or may further contain other components.
  • the composition for batter further contains phosphate cross-linked tapioca starch, preferably as the component (C), from the viewpoint of improving the crispiness of the batter of the food obtained by cooking with heat.
  • the component (C) is starch other than the components (A) and (B) described above.
  • the content of the component (C) with respect to the content of the component (A), that is, ((C)/(A)) is a mass ratio, and represents the color tone of the food. From the viewpoint of making it preferable, it is preferably 0.5 or more, more preferably 1 or more, even more preferably 1.2 or more, still more preferably 1.8 or more. Further, from the viewpoint of improving the crispy feeling of the batter of the food obtained by cooking with heat, the mass ratio ((C)/(A)) is preferably 10 or less, more preferably 9.0 or less, It is more preferably 6.0 or less, and even more preferably 3.0 or less.
  • the content of the component (C) in the batter composition is specifically the above-mentioned mass ratio ((C)/(A)) depending on the content of the component (A) in the batter composition. It can be set to fall within the range.
  • the batter composition may further contain powder raw materials other than the components (A) to (C), and examples of the other raw materials include powder raw materials to be blended with the batter, which will be described later.
  • the batter contains the powder raw material containing the above-mentioned component (A) and component (B) as essential components, and water, and there is no limitation on the mixing order of these components.
  • the batter may be obtained by preparing the composition for batter in the present embodiment described above in advance and mixing it with water and other components as appropriate.
  • the batter may be obtained by mixing the component (A), the component (B), water, and other components as appropriate in a predetermined order.
  • the batter is specifically liquid.
  • the batter preferably contains the component (A) and the component (B) as the powder raw material in the raw material of the batter (powder raw material 1), and the mass ratio ((B)/(A)) is preferable. Is 0.4 or more and 8 or less, and when the batter further contains the component (C) as the powder raw material in the raw material of the batter (powder raw material 2), the mass ratio ((C)/(A)) is It is preferably 0.5 or more and 10 or less. Further, the total amount of the component (A) and the component (B) (or the total amount of the component (A), the component (B) and the component (C) when the batter further contains the component (C)) is a powder. It is preferably 20% by mass or more, more preferably 41% by mass or more, and preferably 100% by mass or less with respect to the entire raw material.
  • the total amount of component (A) and component (B) in the powder raw material, or the total amount of component (A), component (B) and component (C) when the powder raw material further contains component (C) is preferably 20% by mass or more, more preferably 41% by mass or more, still more preferably 45% by mass or more, still more preferably from the viewpoint of improving the color tone of food and the crispiness of clothes. It is preferably 55% by mass or more, more preferably 70% by mass or more, still more preferably 75% by mass or more. In addition, the total amount is preferably 100% by mass or less, and more preferably 95% by mass or less, based on the entire powder raw material, from the viewpoint of the appearance of the surface and suppressing the appearance of clothes. More preferably, it is 92 mass% or less.
  • the total amount ((A)+(B)+(C)) in the batter is preferably 8% by mass or more based on the whole batter from the viewpoint of improving the color tone of food and the crispy feeling of clothing. , More preferably 10% by mass or more, further preferably 15% by mass or more, even more preferably 22% by mass or more, even more preferably 32% by mass or more. Further, the total amount ((A)+(B)+(C)) in the batter is preferably 50% by mass or less, from the viewpoint of the favorable appearance of the surface and the suppression of the scarring of clothes. It is preferably 45% by mass or less, more preferably 42% by mass or less.
  • the mass ratio ((B)/(A)) and the mass ratio ((C)/(A)) in the batter can each be preferably in the ranges described above for the composition for batter.
  • the powder raw material includes powder raw material 1: component (A) and component (B) described above, or powder raw material 2: component (A), component (B) and component (C). It may be configured. Further, in any of the powder raw materials 1 and 2, the powder raw material may further contain components other than the components (A) to (C).
  • the powder raw material may further contain components other than the components (A) to (C).
  • components other than components (A) to (C) raw starch (raw starch), starch other than components (A) to (C) such as processed starch, wheat flour such as soft flour, rice flour, etc. Flour, dried eggs such as whole egg powder, swelling agents such as baking powder, powdered seasonings, coloring agents, and emulsifiers.
  • the powder raw material preferably further contains cereal flour, more preferably soft flour, from the viewpoint of suppressing shrinkage of the batter of the food obtained by cooking with heat.
  • the content thereof is preferably 5% by mass or more, and more preferably 8% by mass with respect to the entire powder raw material, from the viewpoints of improving the crispy feeling of clothing and suppressing hunch. It is at least mass%.
  • the content of the soft flour is preferably 80% by mass or less, more preferably 59% by mass or less, and further preferably 40% by mass with respect to the entire powder raw material. % Or less, even more preferably 30% by mass or less, and even more preferably 20% by mass or less.
  • the batter contains water.
  • the content of water in the batter can be the balance excluding the content of components other than water contained in the batter.
  • the batter is specifically a batter used for food batter, and preferably a food batter selected from the group consisting of fried chicken, tempura and fritters.
  • the batter of this embodiment for example, deterioration of the appearance of food can be suppressed.
  • the appearance is preferably a rough surface and a color tone after heating and thawing.
  • the batter of the present embodiment it is possible to suppress the deterioration of the texture of food, for example.
  • the texture is preferably crispy.
  • the food is obtained by using the composition for batter or the batter described above.
  • the food has a seed and a batter provided on the outside of the seed, and the batter is obtained by using the batter composition or the batter described above.
  • the method for producing food includes, for example, a step of attaching the batter to the outside of the seed and a step of cooking the seed to which the batter is attached to obtain the food.
  • seeds include meat such as chicken; seafood such as fish, shellfish, shrimp; vegetables such as potatoes; confectionery such as donuts, castella, and buns; kneaded products such as kamaboko.
  • the batter may cover a part of the seed or the whole seed.
  • the batter may be attached to a part of the seed or the entire seed.
  • cooking forms in the process of cooking by heating include cooking oil in cooking oil at about 100 to 200°C; frying pan lightly oiled, heating on iron plate; dry heat in oven etc. Microwave heating; heat cooking in a steam convection oven or the like can be mentioned, and from the viewpoint of improving the texture of the batter, oil and fat is preferable. Further, the food is specifically one obtained by heating these foods, and more specifically, a fried food.
  • the method for producing a food may further include a step of freezing and storing the food after the step of obtaining the food.
  • the temperature in frozen storage may be, for example, about -10 to -50°C.
  • the method for producing a food may further include a step of heating and thawing the food after the step of freezing and storing.
  • a step of heating and thawing it is preferable to heat and thaw using a microwave oven or a steam convection oven from the viewpoint of making the mouthfeel favorable.
  • the food in the present embodiment is obtained by using the batter described above, deterioration of the appearance and texture over time is suppressed, and even when reheated after storage, a favorable freshness of appearance and texture of the batter is obtained. can get.
  • J-Oil Mills Corn Starch Y high amylose corn starch made by J-Oil Mills Co., Ltd.: “J-Oil Mills HS-7” made by J-Oil Mills, amylose content 70% by mass Paprika powder: manufactured by SB Foods Co., Ltd.
  • Xanthan gum "Xanthan gum FJ", manufactured by Maruzen Pharmaceutical Co., Ltd.
  • the peak molecular weight was measured using an HPLC unit manufactured by Tosoh Corporation (pump DP-8020, RI detector RS-8021, degassing device SD-8022).
  • the sample was crushed, and a fraction under a sieve of 0.15 mm sieve was collected with a sieve of JIS-Z8801-1 standard. This collected fraction was suspended in the mobile phase so as to be 1 mg/mL, and the suspension was heated at 100° C. for 3 minutes to be completely dissolved.
  • a 0.45 ⁇ m filtration filter manufactured by ADVANTEC, DISMIC-25HP PTFE 0.45 ⁇ m was used for filtration, and the filtrate was used as an analytical sample.
  • the dried heated gelatinized product was crushed with a tabletop crusher and then sieved with a JIS-Z8801-1 standard sieve.
  • the sieved hot gelatinized products were mixed in the following blending ratios to prepare the following starch powders 1 and 2.
  • Table 1 shows the mass ratio of each fraction in the starchy material. The degree of cold water swelling of the obtained starch-like substance is also shown together with the values measured by the method described below.
  • an aqueous solution of sodium hypochlorite was added so as to have a starch dry matter-equivalent mass concentration of 3.0% while stirring at 300 rpm, and a 3 mass% aqueous solution of sodium hydroxide was added. It was dropped to bring the pH to 8.25. Then, an aqueous sodium hydroxide solution was added dropwise at appropriate times to maintain the pH within the set value ⁇ 0.03 until the end of the reaction to obtain oxidized starch. The reaction was completed when a small amount of the slurry was sampled and added dropwise to a saturated potassium iodide aqueous solution so that the purple color disappeared. After confirming the completion of the reaction, 3% by mass hydrochloric acid was added to the slurry to neutralize it to pH 6, washed, dehydrated and dried to obtain oxidized starch.
  • raw waxy corn starch was used as the raw material starch to obtain an acid-treated starch by the following procedure.
  • a 40% by mass waxy cornstarch manufactured by J-Oil Mills Co., Ltd.
  • 80 parts by mass of 6% by mass hydrochloric acid was added, and the mixture was stirred at 40° C. for 24 hours for acid treatment. After the acid treatment, it was neutralized with slaked lime so that the pH became 5, and then washed and dried to obtain acid-treated starch.
  • fried chicken was prepared and evaluated.
  • Production method of fried chicken 1.
  • Chicken thigh meat was cut to about 25 g/piece. 2.1.
  • LAMIZIP Tin type LZ-22, manufactured by Japan Co., Ltd.
  • MZC-300-C manufactured by Hagios Co., Ltd.
  • tumbling was performed at 4° C. for 90 minutes.
  • Air discharge 15 seconds
  • Hermetic seal Medium temperature 2 seconds 3.
  • the buttered chicken was fried in canola oil at 190° C. for 4 minutes and a half. 6. After pouring the oil, the chicken was placed in a vat, and the whole vat was frozen at -20°C. Then, the chicken was transferred to a zipper bag and stored frozen at -20°C for 3 days. 7. Four fried chickens after 3 days of freezing were placed on a paper plate and heated and thawed for 45 seconds in a microwave oven (1400W). 8. The appearance and texture of the fried chicken obtained by the above procedure were evaluated. The evaluation items and scoring criteria are shown below.
  • Example 1 Control Example, Examples 1-1 to 1-3, Comparative Examples 1-1 to 1-3
  • powder raw materials among the raw materials shown in Table 2 were mixed to obtain a batter composition.
  • the obtained composition for batters and cold water were mixed, and the batter of each example was obtained.
  • fried chicken was prepared and evaluated by the method described above.
  • Comparative Example 1-3 powder raw materials among the raw materials shown in Table 2 were mixed to obtain a composition.
  • the obtained composition was used without being dispersed in cold water as it was, after being attached with the batter described above, as a blender, and fried chicken was prepared according to the method described above and evaluated.
  • the evaluation was scored by a consultation between two evaluators.
  • In the evaluation of texture two evaluators agreed and scored.
  • the evaluation results are also shown in Table 2.
  • Example 2 by using the batter composition and the batter of each Example, fried chicken with a freshly-prepared fresh appearance was obtained even when reheated after freezing. Specifically, all the fried chicken prepared using a batter containing a predetermined amount of the component (A) and the component (B) were excellent in the surface and color tone of the fried chicken, and the texture of the clothes was also excellent. When the component (C) was further contained as in Example 1-2, the crispy sensation of clothes was improved. When Example 1-2 containing wheat flour was compared with Example 1-3 containing no wheat flour, Example 1-2 containing wheat flour was superior in terms of crispy feeling and blushing of clothes.
  • Comparative Example 1-3 the same composition as in Example 1-2 was used as a blender, but in this case, the color of the fried chicken was discolored to a slightly dark color, and the crispy sensation was slightly inferior, and a powdery feeling was also felt. It wasn't very good.
  • Example 2 Examples 2-1 to 2-4
  • powder raw materials were mixed to obtain a batter composition.
  • the obtained composition for batters and cold water were mixed, and the batter of each example was obtained.
  • fried chicken was prepared and evaluated by the method described above. In the evaluation of the appearance, the evaluation was scored by a consultation between two evaluators. In evaluating the texture, each of the two evaluators scored their own, and the average score was used as the score.
  • the evaluation results are also shown in Table 3.
  • the batter composition and the batter of each example fried chicken with a favorable freshness in appearance and texture was obtained even when reheated after freezing.
  • the fried chicken made using a batter containing the component (A) in the powder raw material in the range of 4.9 mass% to 27.0 mass% and the component (B) is fried. It had an excellent surface and color tone, and the texture of the clothes was excellent.
  • the state of the fried chicken surface and the boil of the batter it is good when the ingredient (A) is contained in the powder raw material in an amount of 4.9% by mass or more and 27.0% by mass or less, and 19.8% by mass or more and 27.0% by mass. % Or less was better.
  • the ingredient (A) is contained in the powder raw material in an amount of 4.9% by mass or more and 27.0% by mass or less, and better when it is included in the powder raw material of 4.9% by mass or more and 19.8% by mass or less.
  • the crispy feeling it is good when the component (A) is contained in the powder raw material in an amount of 4.9% by mass or more and 27.0% by mass or less, and is better when it is contained in the powder raw material of 9.9% by mass or more and 27.0% by mass or less. , 19.8 mass% or more and 27.0 mass% or less was even better.
  • Example 3 Examples 3-1 to 3-4 and Comparative Example 3-1
  • powder raw materials were mixed to obtain a batter composition.
  • the obtained composition for batters and cold water were mixed, and the batter of each example was obtained.
  • fried chicken was prepared and evaluated by the method described above. In the evaluation of the appearance, each of the three evaluators scored their own, and the average score was used as the score. The evaluation of texture was scored by a panel of 3 evaluators. The evaluation results are also shown in Table 4.
  • Example 4 Examples 4-1, 4-2, Comparative Example 4-1 Of the raw materials shown in Table 5, powder raw materials were mixed to obtain a batter composition. And the obtained composition for batters and cold water were mixed, and the batter of each example was obtained. Using the obtained batter, fried chicken was prepared and evaluated by the method described above. In the evaluation of the appearance, each of the three evaluators scored their own, and the average score was used as the score. The evaluation of texture was scored by a panel of 3 evaluators. The evaluation results are also shown in Table 5.
  • the state of the surface of the fried chicken it was good when the total amount of the components (A), (B) and (C) was 49.5% by mass or more and 90.0% by mass or less in the powder raw material.
  • the crispy feeling it is good when the total amount of the components (A), (B) and (C) is 49.5% by mass or more and 90.0% by mass or less in the powder raw material, and 74.2% by mass or more. It was better when the content was 90.0 mass% or less.
  • the total amount of the components (A), (B) and (C) was 49.5% by mass or more and 90.0% by mass or less in the powder raw material.
  • Example 5 Control Example, Examples 5-1 to 5-3
  • powder raw materials were mixed to obtain a batter composition.
  • the obtained composition for batters and cold water were mixed, and the batter of each example was obtained.
  • fried chicken was prepared by the above method and evaluated by the above method.
  • evaluation was also performed when immediately after frying, and after standing for 4 hours at room temperature after frying and eating as it was.
  • evaluation of the appearance each of the three evaluators scored their own, and the average score was used as the score.
  • the evaluation results are also shown in Table 6.
  • the state of the fried surface immediately after the oil-cooking, the fried color tone, the taste of the batter, and the crispy feeling were all very good. It was good. After 4 hours of fried oil, the surface of the fried chicken, the color of the fried chicken, and the crispy sensation were slightly superior to the acid-treated starch, and the oxidized starch was slightly superior to the haki of the batter.
  • oxidized starch was more preferable in the appearance of fried surface, fried color, and batter of batter, and acid-treated starch was more preferable in terms of crispy feeling.
  • the deep-fried tofu obtained in this example showed less deterioration over time after being cooked for 4 hours and after being reheated after freezing, as compared with immediately after frying, and had a fresh feeling.
  • the fried chicken obtained in the present embodiment has less deterioration at the time of oil frying 4 hours after rehydration and after reheating after freezing, as compared with immediately after frying, and has a favorable fresh feeling.
  • Met When the starch-like substance 2 (Example 5-2) was used, compared to the starch-like substance 1 (Example 5-1), the fresh feeling after 4 hours and after re-freezing and reheating was better. Was excellent.
  • the oxidized starch is used as the component (B) (Example 5-1) and the acid-treated starch (Example 5-3), the oxidized starch has a fresh feeling when reheated after frozen storage. Was better.
  • the shrimp tempura prepared using the batter composition of each example had a better crispy texture of the batter when eaten immediately after cooking and 4 hours after cooking, as compared with the control example. More specifically, when ((A)+(B)+(C))) is contained in the powder raw material in an amount of 25% by mass or more and 50% by mass or less (Examples 6-1 to 6-4), a crispy feeling is obtained. It was excellent, and was more excellent when it contained 42.8% by mass or more and 50% by mass or less (Examples 6-1, 6-2 and 6-4).

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Abstract

Provided is a composition for batter, which contains: component (A), a specific starch powder; and component (B), at least one selected from the group consisting of oxidized starch and acid-treated starch. The composition for batter is used after being dispersed in water.

Description

バッター用組成物Composition for batter

 本発明は、バッター用組成物に関する。 The present invention relates to a composition for batter.

 食品の保存後経時劣化を抑制しようとする技術として、特許文献1(特開2015-223119号公報)に記載のものがある。同文献には、小麦粉、酸化澱粉、リン酸架橋澱粉および重曹をそれぞれ特定量含む、水溶きタイプのから揚げミックスについて記載されており、かかるから揚げミックスを用いることにより、具材への付着性がよく、かつ外観と食感が良好で、油ちょうから時間が経過しても品質の低下が少ないから揚げを製造することができるとされている。 As a technique for suppressing deterioration with time of food after storage, there is a technique described in Patent Document 1 (JP-A-2015-223119). The document describes a water-soluble type fried mix containing wheat flour, oxidized starch, phosphoric acid cross-linked starch and baking soda, respectively. By using such a fried mix, adhesion to ingredients is improved. It is said that fried food can be produced because it has a good appearance and a good texture, and the quality of the oil is not significantly deteriorated even after the passage of time.

特開2015-223119号公報JP, 2005-223119, A

 しかしながら、上述した技術を用いた場合、加熱調理して得られた食品の外観および食感の経時劣化を抑制し、保存後再加熱した際にも、外観および衣の食感について好ましいできたて感のある食品を得るという点で改善の余地があった。 However, when the above-mentioned technique is used, the deterioration of the appearance and texture of the food obtained by heating and cooking is suppressed, and even when the food is reheated after storage, it is possible to obtain a favorable appearance and texture. There was room for improvement in terms of obtaining food with a feeling.

 本発明によれば、以下のバッター用組成物、バッター、食品の製造方法、食品の外観を向上する方法、および、食品の食感を向上させる方法が提供される。
[1] 以下の成分(A)および(B):
 (A)以下の条件(1)~(5)を満たす澱粉粉状物
  (1)澱粉含量が75質量%以上
  (2)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、前記低分子化澱粉のピーク分子量が3×103以上5×104以下
  (3)25℃における冷水膨潤度が5以上20以下
  (4)目開き0.5mmの篩の篩下かつ0.075mmの篩の篩上の含有量が20質量%以上95質量%以下
  (5)目開き0.5mmの篩の篩上の含有量が30質量%以下
 (B)酸化澱粉および酸処理澱粉からなる群から選択される1種または2種
 を含み、水に分散させて用いられる、バッター用組成物。
[2] 当該バッター用組成物中の前記成分(A)の含有量が、当該バッター用組成物全体に対して3.0質量%以上55質量%以下であり、
 前記成分(A)の含有量に対する前記成分(B)の含有量が、質量比で、0.4以上8以下である、[1]に記載のバッター用組成物。
[3] 前記成分(B)の原料澱粉の由来が、キャッサバおよびとうもろこしからなる群から選ばれる1種である、[1]または[2]に記載のバッター用組成物。
[4] 前記成分(A)において、アミロース含量5質量%以上である前記澱粉が、アミロース含量が40質量%以上のコーンスターチである、[1]乃至[3]いずれか1項に記載のバッター用組成物。
[5] 前記成分(A)において、前記低分子化澱粉が、酸処理澱粉、酸化処理澱粉および酵素処理澱粉からなる群から選択される1種または2種以上である、[1]乃至[4]いずれか1項に記載のバッター用組成物。
[6] 前記成分(A)が、前記低分子化澱粉以外の澱粉として、コーンスターチ、小麦澱粉、馬鈴薯澱粉、タピオカ澱粉およびこれらの架橋澱粉からなる群から選択される1種または2種以上を含有する、[1]乃至[5]いずれか1項に記載のバッター用組成物。
[7] 成分(C)としてリン酸架橋タピオカ澱粉をさらに含む、[1]乃至[6]いずれか1項に記載のバッター用組成物。
[8] 前記成分(A)の含有量に対する前記成分(C)の含有量が、質量比で、0.5以上10以下である、[7]に記載のバッター用組成物。
[9] 前記バッターが、唐揚げ、天ぷらおよびフリッターからなる群から選択される食品のバッターである、[1]乃至[8]いずれか1項に記載のバッター用組成物。
[10] バッターの中の粉体原料として、以下の成分(A)および成分(B)を含み、
 前記成分(A)の含有量に対する前記成分(B)の含有量が、質量比で、0.4以上8以下であり、
 当該バッターが以下の成分(C)をさらに含むとき、前記成分(A)の含有量に対する前記成分(C)の含有量が、質量比で、0.5以上10以下であり、
 前記成分(A)および前記成分(B)の合計量、または、当該バッターが前記成分(C)をさらに含むとき前記成分(A)、前記成分(B)および前記成分(C)の合計量が、前記粉体原料全体に対して20質量%以上100質量%以下である、バッター。
 (A)以下の条件(1)~(5)を満たす澱粉粉状物
  (1)澱粉含量が75質量%以上
  (2)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、前記低分子化澱粉のピーク分子量が3×103以上5×104以下
  (3)25℃における冷水膨潤度が5以上20以下
  (4)目開き0.5mmの篩の篩下かつ0.075mmの篩の篩上の含有量が20質量%以上95質量%以下
  (5)目開き0.5mmの篩の篩上の含有量が30質量%以下
 (B)酸化澱粉および酸処理澱粉からなる群から選択される1種または2種
 (C)リン酸架橋タピオカ澱粉
[11] 前記原料が小麦粉を前記粉体原料全体に対して5質量%以上59質量%以下含む、[10]に記載のバッター。
[12] 当該バッター中の前記成分(A)、成分(B)および成分(C)の含有量の合計が、当該バッター全体に対して8質量%以上50質量%以下である、[10]または[11]に記載のバッター。
[13] [10]乃至[12]いずれか1項に記載のバッターを種物の外側に付着させる工程と、
 前記バッターが付着した前記種物を加熱調理して食品を得る工程と、
 を含む、食品の製造方法。
[14] 食品を得る前記工程の後、前記食品を冷凍保存する工程をさらに含む、[13]に記載の食品の製造方法。
[15] 冷凍保存する前記工程の後、前記食品を加熱解凍する工程をさらに含む、[14]に記載の食品の製造方法。
[16] [10]乃至[12]いずれか1項に記載のバッターを用いる、食品の外観の劣化を抑制する方法。
[17] [10]乃至[12]いずれか1項に記載のバッターを用いる、食品の食感の劣化を抑制する方法。
According to the present invention, the following composition for batter, batter, method for producing food, method for improving appearance of food, and method for improving texture of food are provided.
[1] The following components (A) and (B):
(A) Starch-like substance satisfying the following conditions (1) to (5) (1) Starch content of 75% by mass or more (2) Amylose content of 5% by mass or more 3% by mass of low-molecular-weight starch And 45% by mass or more, and the peak molecular weight of the low molecular weight starch is 3×10 3 or more and 5×10 4 or less (3) the degree of cold water swelling at 25° C. is 5 or more and 20 or less (4) a sieve having an opening of 0.5 mm Content of 20% by mass or more and 95% by mass or less on the sieve of 0.075 mm and (5) a content of 30% by mass or less on the sieve of 0.5 mm mesh (B) oxidized starch And a batter composition containing one or two selected from the group consisting of acid-treated starch and used by dispersing in water.
[2] The content of the component (A) in the batter composition is 3.0 mass% or more and 55 mass% or less based on the entire batter composition.
The batter composition according to [1], wherein the content of the component (B) with respect to the content of the component (A) is 0.4 or more and 8 or less in terms of mass ratio.
[3] The batter composition according to [1] or [2], wherein the origin of the raw material starch of the component (B) is one selected from the group consisting of cassava and corn.
[4] For the batter according to any one of [1] to [3], in the component (A), the starch having an amylose content of 5% by mass or more is corn starch having an amylose content of 40% by mass or more. Composition.
[5] In the component (A), the low-molecular-weight starch is one or two or more selected from the group consisting of acid-treated starch, oxidation-treated starch, and enzyme-treated starch, [1] to [4] ] The composition for batters according to any one of items.
[6] The component (A) contains, as a starch other than the low-molecular-weight starch, one or more selected from the group consisting of corn starch, wheat starch, potato starch, tapioca starch and cross-linked starch thereof. The composition for batter according to any one of [1] to [5].
[7] The batter composition according to any one of [1] to [6], further comprising phosphoric acid-crosslinked tapioca starch as the component (C).
[8] The batter composition according to [7], wherein the content of the component (C) with respect to the content of the component (A) is 0.5 or more and 10 or less in mass ratio.
[9] The batter composition according to any one of [1] to [8], wherein the batter is a food batter selected from the group consisting of fried chicken, tempura and fritters.
[10] As the powder raw material in the batter, the following components (A) and (B) are included,
The content of the component (B) with respect to the content of the component (A) is 0.4 or more and 8 or less in mass ratio,
When the batter further contains the following component (C), the content of the component (C) with respect to the content of the component (A) is 0.5 or more and 10 or less in mass ratio,
The total amount of the component (A) and the component (B), or the total amount of the component (A), the component (B) and the component (C) when the batter further includes the component (C). A batter containing 20% by mass or more and 100% by mass or less of the whole powder raw material.
(A) Starch-like substance satisfying the following conditions (1) to (5) (1) Starch content of 75% by mass or more (2) Amylose content of 5% by mass or more 3% by mass of low-molecular-weight starch And 45% by mass or more, and the peak molecular weight of the low molecular weight starch is 3×10 3 or more and 5×10 4 or less (3) the degree of cold water swelling at 25° C. is 5 or more and 20 or less (4) a sieve having an opening of 0.5 mm Content of 20% by mass or more and 95% by mass or less on the sieve of 0.075 mm and (5) a content of 30% by mass or less on the sieve of 0.5 mm mesh (B) oxidized starch And one or two selected from the group consisting of acid-treated starch (C) Phosphoric acid-crosslinked tapioca starch [11] The raw material contains wheat flour in an amount of 5% by mass or more and 59% by mass or less based on the entire powder raw material. The batter described in [10].
[12] The total content of the component (A), the component (B), and the component (C) in the batter is 8% by mass or more and 50% by mass or less with respect to the entire batter, [10] or The batter described in [11].
[13] A step of attaching the batter according to any one of [10] to [12] to the outside of the seed,
A step of cooking the seed to which the batter is attached to obtain food,
A method for producing a food product, comprising:
[14] The method for producing a food according to [13], further including a step of storing the food in a frozen state after the step of obtaining the food.
[15] The method for producing a food according to [14], further comprising a step of heating and thawing the food after the step of freezing and storing.
[16] A method for suppressing the deterioration of the appearance of food, which uses the batter according to any one of [10] to [12].
[17] A method for suppressing the deterioration of the texture of food by using the batter according to any one of [10] to [12].

 以上説明したように本発明によれば、加熱調理して得られた食品の外観および食感の経時劣化を抑制し、保存後再加熱した際にも、外観および衣の食感について好ましいできたて感のある食品を得ることができる。 As described above, according to the present invention, it is possible to suppress the deterioration of the appearance and texture of the food obtained by cooking over time, and to favor the appearance and the texture of clothes when reheated after storage. It is possible to obtain food with a feeling.

 以下、本発明の実施の形態について、各成分の具体例を挙げて説明する。なお、各成分はいずれも単独でまたは2種以上を組み合わせて用いることができる。
 また、以下の実施形態でいうできたて感とは、保存中の劣化が少なく、保存前の調理直後に近い外観および食感を有するということである。
Hereinafter, embodiments of the present invention will be described with reference to specific examples of each component. Each component may be used alone or in combination of two or more.
In addition, the freshness in the following embodiments means that there is little deterioration during storage, and that the product has an appearance and texture similar to that immediately after cooking before storage.

 (バッター用組成物)
 本実施形態においてバッター用組成物は、水に分散させて用いられ、以下の成分(A)および(B)を含む。
(A)後述の条件(1)~(5)を満たす澱粉粉状物
(B)酸化澱粉および酸処理澱粉からなる群から選択される1種または2種
 バッター用組成物は、具体的には、揚げ物等の食品の衣材として用いられるバッター用の組成物である。
(Composition for batter)
In the present embodiment, the batter composition is used by being dispersed in water and contains the following components (A) and (B).
(A) One or two kinds of batter compositions selected from the group consisting of starch-like substances (B) oxidized starch and acid-treated starch, which satisfy the following conditions (1) to (5), A composition for batters used as a clothing material for foods such as fried foods.

 ここで、バッター用組成物をバッターに用いる際には、バッター用組成物のみを水に分散させて液状のバッターを作製してもよいし、他の成分も加えて液状のバッターを作製してもよい。
 以下、成分(A)および(B)についてさらに具体的に説明する。
Here, when the composition for batter is used for a batter, only the composition for batter may be dispersed in water to prepare a liquid batter, or other components may be added to prepare a liquid batter. Good.
Hereinafter, the components (A) and (B) will be described more specifically.

(成分(A))
 成分(A)は、具体的には、澱粉を主成分としてなる粉状物である。成分(A)は、以下の条件(1)~(5)を満たす。
(1)澱粉含量が75質量%以上
(2)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、前記低分子化澱粉のピーク分子量が3×103以上5×104以下
(3)25℃における冷水膨潤度が5以上20以下
(4)目開き0.5mmの篩の篩下かつ0.75mmの篩の篩上の含有量が20質量%以上95質量%以下
(5)目開き0.5mmの篩の篩上の含有量が30質量%以下
(Component (A))
The component (A) is specifically a powdery material containing starch as a main component. The component (A) satisfies the following conditions (1) to (5).
(1) Starch content is 75% by mass or more (2) Amylose content is 5% by mass or more, and the low molecular weight starch is 3% by mass or more and 45% by mass or less, and the peak molecular weight of the low molecular weight starch is 3×10. 3 or more and 5×10 4 or less (3) Cold water swelling degree at 25° C. is 5 or more and 20 or less (4) Content of 20% by mass under sieve of 0.5 mm mesh and 0.75 mm sieve 95 mass% or less (5) The content on the sieve of a sieve having an opening of 0.5 mm is 30 mass% or less

 条件(1)に関し、成分(A)は、バッターが適用される食品の、保存後の外観および食感の劣化を抑制する観点から、澱粉を75質量%以上含み、好ましくは80質量%以上、さらに好ましくは85質量%以上含む。
 また、成分(A)中の澱粉含量の上限に制限はなく、100質量%以下であるが、バッターが適用される食品の性状等に応じて99.5質量%以下、99質量%以下等としてもよい。
Regarding the condition (1), the component (A) contains 75% by mass or more of starch, preferably 80% by mass or more, from the viewpoint of suppressing deterioration of the appearance and texture of the food to which the batter is applied after storage. More preferably, it contains 85 mass% or more.
The upper limit of the starch content in the component (A) is not limited and is 100% by mass or less, but it is 99.5% by mass or less, 99% by mass or less depending on the properties of the food to which the batter is applied. Good.

 条件(2)に関し、成分(A)は、上記澱粉として、アミロース含量5質量%以上の澱粉を原料とする低分子化澱粉を特定の割合で含み、低分子化澱粉として特定の大きさのものが用いられる。すなわち、成分(A)中の澱粉が、アミロース含量5質量%以上の澱粉を原料とする低分子化澱粉を成分(A)中に3質量%以上45質量%以下含み、低分子化澱粉のピーク分子量が3×103以上5×104以下である。 Concerning the condition (2), the component (A) contains, as the above-mentioned starch, a low-molecular-weight starch made from a starch having an amylose content of 5% by mass or more in a specific ratio, and having a specific size as the low-molecular-weight starch. Is used. That is, the starch in the component (A) contains 3% by mass or more and 45% by mass or less of the low molecular weight starch made from starch having an amylose content of 5% by mass or more in the component (A), and the peak of the low molecular weight starch is obtained. The molecular weight is 3×10 3 or more and 5×10 4 or less.

 低分子化澱粉のピーク分子量は、バッターが適用される食品の、保存後の外観および食感の劣化を抑制する観点から、3×103以上であり、好ましくは8×103以上である。また、同様の観点から、低分子化澱粉のピーク分子量は、5×104以下であり、好ましくは3×104以下であり、さらに好ましくは1.5×104以下である。なお、低分子化澱粉のピーク分子量の測定方法については、実施例の項に記載する。 The peak molecular weight of the low-molecular-weight starch is 3×10 3 or more, preferably 8×10 3 or more, from the viewpoint of suppressing deterioration of the appearance and texture of the food to which the batter is applied after storage. From the same viewpoint, the peak molecular weight of the low molecular weight starch is 5×10 4 or less, preferably 3×10 4 or less, and more preferably 1.5×10 4 or less. The method for measuring the peak molecular weight of the low molecular weight starch is described in the section of Examples.

 低分子化澱粉は、その製造安定性に優れる観点から、好ましくは、酸処理澱粉、酸化処理澱粉および酵素処理澱粉からなる群から選択される1種または2種以上であり、より好ましくは酸処理澱粉である。 The low-molecular-weight starch is preferably one or more selected from the group consisting of acid-treated starch, oxidative-treated starch and enzyme-treated starch from the viewpoint of excellent production stability, and more preferably acid-treated starch. It is starch.

 酸処理澱粉を得る際の酸処理の条件は問わないが、たとえば、以下のように処理することができる。
 まず、低分子化澱粉の原料であるアミロース含量5質量%以上の澱粉と水を反応装置に投入した後、さらに酸を投入する。あるいは水に無機酸をあらかじめ溶解させた酸水と原料の澱粉を反応装置に投入する。酸処理をより安定的におこなう観点からは、反応中の澱粉の全量が水相内に均質に分散した状態、またはスラリー化した状態にあることが望ましい。そのためには、酸処理をおこなう上での澱粉スラリーの濃度を、たとえば10質量%以上50質量%以下、好ましくは20質量%以上40質量%以下の範囲になるように調整する。スラリー濃度が高すぎると、スラリー粘度が上昇し、均一なスラリーの攪拌が難しくなる場合がある。
The conditions of the acid treatment for obtaining the acid-treated starch are not limited, but the treatment can be performed as follows, for example.
First, a starch having an amylose content of 5% by mass or more, which is a raw material of a low-molecular-weight starch, and water are charged into a reactor, and then an acid is further charged. Alternatively, acid water obtained by dissolving an inorganic acid in water in advance and starch as a raw material are put into a reactor. From the viewpoint of more stable acid treatment, it is desirable that the total amount of starch in the reaction is in a state of being uniformly dispersed in the aqueous phase or in a state of being slurried. For that purpose, the concentration of the starch slurry during the acid treatment is adjusted to be, for example, 10% by mass or more and 50% by mass or less, preferably 20% by mass or more and 40% by mass or less. If the slurry concentration is too high, the slurry viscosity may increase, and it may be difficult to uniformly stir the slurry.

 酸処理に用いられる酸として、具体的には塩酸、硫酸、硝酸などの無機酸が挙げられ、種類、純度などを問わず利用できる。 Specific examples of the acid used for the acid treatment include inorganic acids such as hydrochloric acid, sulfuric acid and nitric acid, which can be used regardless of the type and purity.

 酸処理反応条件については、たとえば酸処理時の無機酸濃度は、酸処理澱粉を安定的に得る観点から、0.05規定度(N)以上4N以下が好ましく、0.1N以上4N以下がより好ましく、0.2N以上3N以下がさらに好ましい。また、同様の観点から、反応温度は、30℃以上70℃以下が好ましく、35℃以上70℃以下がより好ましく、35℃以上65℃以下がさらに好ましい。反応時間は、同様の観点から、0.5時間以上120時間以下が好ましく、1時間以上72時間以下がより好ましく、1時間以上48時間以下がさらに好ましい。 Regarding the acid treatment reaction conditions, for example, the inorganic acid concentration during acid treatment is preferably 0.05 normality (N) or more and 4N or less, more preferably 0.1N or more and 4N or less, from the viewpoint of stably obtaining acid-treated starch. It is preferably 0.2 N or more and 3 N or less. From the same viewpoint, the reaction temperature is preferably 30°C or higher and 70°C or lower, more preferably 35°C or higher and 70°C or lower, and further preferably 35°C or higher and 65°C or lower. From the same viewpoint, the reaction time is preferably 0.5 hours or more and 120 hours or less, more preferably 1 hour or more and 72 hours or less, still more preferably 1 hour or more and 48 hours or less.

 成分(A)中の低分子化澱粉の含有量は、バッターが適用される食品の、保存後の外観および食感の劣化を抑制する観点から、3質量%以上であり、好ましくは8質量%以上、さらに好ましくは13質量%以上である。
 また、同様の観点から、成分(A)中の低分子化澱粉の含有量は、45質量%以下であり、好ましくは35質量%以下、さらに好ましくは25質量%以下である。
The content of the low-molecular-weight starch in the component (A) is 3% by mass or more, and preferably 8% by mass, from the viewpoint of suppressing deterioration of the appearance and texture of the food to which the batter is applied after storage. Or more, More preferably, it is 13 mass% or more.
From the same viewpoint, the content of the low molecular weight starch in the component (A) is 45% by mass or less, preferably 35% by mass or less, and more preferably 25% by mass or less.

 また、低分子化澱粉の原料澱粉中のアミロース含量は、バッターが適用される食品の、保存後の外観および食感の劣化を抑制する観点から、5質量%以上であり、好ましくは12質量%以上、さらに好ましくは22質量%以上、さらにより好ましくは40質量%以上、よりいっそう好ましくは45質量%以上、さらにまた好ましくは55質量%以上である。なお、低分子化澱粉の原料澱粉中のアミロース含量の上限に制限はなく、100質量%以下であり、好ましくは90質量%以下である。 The amylose content in the raw starch of the low-molecular-weight starch is 5% by mass or more, preferably 12% by mass, from the viewpoint of suppressing deterioration of the appearance and texture of the food to which the batter is applied after storage. The amount is more preferably 22% by mass or more, still more preferably 40% by mass or more, still more preferably 45% by mass or more, still more preferably 55% by mass or more. There is no upper limit on the amylose content in the raw starch of the low molecular weight starch, and it is 100% by mass or less, preferably 90% by mass or less.

 低分子化澱粉の原料であるアミロース含量5質量%以上の澱粉として、ハイアミロースコーンスターチ、コーンスターチ、タピオカ澱粉、甘藷澱粉、馬鈴薯澱粉、小麦澱粉、ハイアミロース小麦澱粉、米澱粉、および、これらの原料を化学的、物理的または酵素的に加工した加工澱粉からなる群から選択される1種または2種以上を用いることができる。バッターが適用される食品の、保存後の外観および食感の劣化を抑制する観点から、アミロース含量5質量%以上の澱粉は、好ましくはハイアミロースコーンスターチ、コーンスターチ、および、タピオカ澱粉から選択される1種または2種以上であり、より好ましくはハイアミロースコーンスターチである。ハイアミロースコーンスターチのアミロース含量は、40質量%以上のものが入手可能である。アミロース含量5質量%以上の澱粉は、より好ましくはアミロース含量が40質量%以上のコーンスターチである。 High-amylose cornstarch, cornstarch, tapioca starch, sweet potato starch, potato starch, wheat starch, high-amylose wheat starch, rice starch, and these raw materials are used as a low-molecular-weight starch raw material having an amylose content of 5% by mass or more. One or more selected from the group consisting of chemically, physically or enzymatically modified starch can be used. The starch having an amylose content of 5% by mass or more is preferably selected from high amylose cornstarch, cornstarch, and tapioca starch from the viewpoint of suppressing the deterioration of the appearance and texture of the food to which the batter is applied after storage. There are two or more species, more preferably high amylose corn starch. High amylose corn starch having an amylose content of 40% by mass or more is available. The starch having an amylose content of 5% by mass or more is more preferably corn starch having an amylose content of 40% by mass or more.

 また、成分(A)は、冷水膨潤度について特定の条件(3)を満たすとともに、粒度が特定の条件(4)および(5)を満たす構成となっている。
 まず、条件(3)に関し、バッターが適用される食品の、保存後の外観および食感の劣化を抑制する観点から、成分(A)の冷水膨潤度は5以上であり、好ましくは6以上であり、さらに好ましくは6.5以上である。
 また、同様の観点から、成分(A)の冷水膨潤度は20以下であり、好ましくは17以下、さらに好ましくは15以下である。
 ここで、成分(A)の冷水膨潤度の測定方法については、実施例の項に記載する。
Further, the component (A) is configured to satisfy the specific condition (3) regarding the swelling degree in cold water and the particle size satisfying the specific conditions (4) and (5).
First, regarding the condition (3), the degree of cold water swelling of the component (A) is 5 or more, and preferably 6 or more, from the viewpoint of suppressing the deterioration of the appearance and texture after storage of the food to which the batter is applied. Yes, and more preferably 6.5 or more.
From the same viewpoint, the degree of cold water swelling of the component (A) is 20 or less, preferably 17 or less, more preferably 15 or less.
Here, the method for measuring the cold water swelling degree of the component (A) will be described in the section of Examples.

 次に、成分(A)の粒度を説明する。
 条件(4)に関し、目開き0.5mmの篩の篩下かつ0.075mmの篩の篩上の粒子の含有量は、バッターが適用される食品の、保存後の外観および食感の劣化を抑制する観点から、成分(A)全体に対して20質量%以上であり、好ましくは35質量%以上、さらに好ましくは50質量%以上、さらにより好ましくは60質量%以上である。
 また、目開き0.5mmの篩の篩下かつ0.075mmの篩の篩上の粒子の含有量は、成分(A)全体に対して95質量%以下であり、同様の観点から、好ましくは91質量%以下であり、より好ましくは88質量%以下である。
Next, the particle size of the component (A) will be described.
Regarding the condition (4), the content of particles under the sieve with a mesh of 0.5 mm and on the sieve with a sieve of 0.075 mm causes deterioration of the appearance and texture of the food to which the batter is applied after storage. From the viewpoint of suppressing, the content is 20% by mass or more, preferably 35% by mass or more, more preferably 50% by mass or more, still more preferably 60% by mass or more, based on the entire component (A).
In addition, the content of particles under the sieve having a mesh of 0.5 mm and on the sieve of a 0.075 mm sieve is 95% by mass or less based on the entire component (A), and from the same viewpoint, it is preferable. It is 91 mass% or less, and more preferably 88 mass% or less.

 また、条件(5)に関し、目開き0.5mmの篩の篩上の粒子の含有量は、バッターが適用される食品の、油ちょう直後の衣のヒキを抑制する観点から、成分(A)全体に対して30質量%以下であり、好ましくは25質量%以下、さらに好ましくは20質量%以下である。
 また、目開き0.5mmの篩の篩上の粒子の含有量に下限はなく、成分(A)全体に対して0質量%以上であるが、バッターが適用される食品の、保存後の表面の様子や色調を好ましいものとする観点から、好ましくは3質量%以上であり、より好ましくは5質量%以上、さらに好ましくは10質量%以上、さらにより好ましくは15質量%以上である。
Further, regarding the condition (5), the content of particles on the sieve of a sieve having an opening of 0.5 mm is determined as the component (A) from the viewpoint of suppressing the bruise of the batter-applied food immediately after frying. The amount is 30% by mass or less, preferably 25% by mass or less, and more preferably 20% by mass or less, based on the whole.
In addition, the content of particles on a sieve having a mesh size of 0.5 mm has no lower limit and is 0% by mass or more based on the entire component (A), but the surface of a food to which the batter is applied after storage. From the viewpoint of making the state and color tone preferable, the content is preferably 3% by mass or more, more preferably 5% by mass or more, still more preferably 10% by mass or more, still more preferably 15% by mass or more.

 また、成分(A)の粒度について、目開き0.075mmの篩の篩上の粒子の含有量は、バッターが適用される食品の、保存後の表面の様子や色調を好ましいものとする観点から、成分(A)全体に対して好ましくは10質量%以上であり、さらに好ましくは30質量%以上、よりいっそう好ましくは50質量%以上、さらにまた好ましくは70質量%以上である。
 また、目開き0.075mmの篩の篩上の粒子の含有量の上限に制限はなく、100質量%以下であるが、好ましくは99質量%以下、さらに好ましくは97質量%以下である。
Regarding the particle size of the component (A), the content of particles on the sieve of a sieve having a mesh size of 0.075 mm is from the viewpoint of making the appearance and color tone of the surface of the food to which the batter is applied after storage favorable. It is preferably 10% by mass or more, more preferably 30% by mass or more, still more preferably 50% by mass or more, and still more preferably 70% by mass or more, based on the entire component (A).
The upper limit of the content of particles on a sieve having a mesh of 0.075 mm is not limited and is 100% by mass or less, preferably 99% by mass or less, and more preferably 97% by mass or less.

 本実施形態において、成分(A)は、上記低分子化澱粉以外の澱粉を含む。成分(A)中の低分子化澱粉以外の澱粉成分としては、様々な澱粉を使用することができる。具体的には、用途に応じて一般に市販されている澱粉、たとえば食品用の澱粉であれば、種類を問わないが、コーンスターチ、馬鈴薯澱粉、タピオカ澱粉、小麦澱粉などの澱粉;およびこれらの澱粉を化学的、物理的または酵素的に加工した加工澱粉などから、1種以上を適宜選ぶことができる。成分(A)は、好ましくは、コーンスターチ、小麦澱粉、馬鈴薯澱粉、タピオカ澱粉およびこれらの架橋澱粉からなる群から選択される1種または2種以上の澱粉を含有するのがよい。 In the present embodiment, the component (A) contains a starch other than the low molecular weight starch. As the starch component other than the low molecular weight starch in the component (A), various starches can be used. Specifically, starches that are generally commercially available depending on the application, such as starches for food, may be of any kind, but starches such as cornstarch, potato starch, tapioca starch, wheat starch and the like; and these starches may be used. One or more kinds can be appropriately selected from chemically, physically or enzymatically processed starch and the like. The component (A) preferably contains one or more starches selected from the group consisting of corn starch, wheat starch, potato starch, tapioca starch and cross-linked starch thereof.

 また、成分(A)は、澱粉以外の成分を含んでもよい。澱粉以外の成分の具体例としては、色素や炭酸カルシウム、硫酸カルシウムなどの不溶性塩が挙げられる。
 成分(A)は、不溶性塩を配合することが好ましく、不溶性塩の配合量は、0.1質量%以上2質量%以下であることがより好ましい。
Further, the component (A) may contain components other than starch. Specific examples of components other than starch include pigments and insoluble salts such as calcium carbonate and calcium sulfate.
The component (A) is preferably blended with an insoluble salt, and the blending amount of the insoluble salt is more preferably 0.1% by mass or more and 2% by mass or less.

 次に、成分(A)の製造方法を説明する。成分(A)の製造方法は、たとえば、以下の工程を含む。
(低分子化澱粉の調製工程)アミロース含量5質量%以上の澱粉を低分子化処理してピーク分子量が3×103以上5×104以下の低分子化澱粉を得る工程。
(造粒工程)原料に低分子化澱粉を3質量%以上45質量%以下含み、かつ低分子化澱粉と低分子化澱粉以外の澱粉の合計が75質量%以上である、原料を加熱糊化して造粒する工程。
Next, a method for producing the component (A) will be described. The method for producing the component (A) includes, for example, the following steps.
(Step of preparing low molecular weight starch) A step of low molecular weight starch having an amylose content of 5% by mass or more to obtain a low molecular weight starch having a peak molecular weight of 3×10 3 or more and 5×10 4 or less.
(Granulation step) The raw material contains 3% by mass or more and 45% by mass or less of the low molecular weight starch, and the total amount of the low molecular weight starch and the starch other than the low molecular weight starch is 75% by mass or more. And granulate.

 低分子化澱粉の調製工程は、アミロース含量5質量%以上の澱粉を分解して低分子化澱粉とする工程である。ここでいう分解とは、澱粉の低分子化を伴う分解をいい、代表的な分解方法として酸処理や酸化処理、酵素処理による分解が挙げられる。この中でも、分解速度やコスト、分解反応の再現性の観点から、好ましくは酸処理である。 The process of preparing low molecular weight starch is a process of decomposing starch having an amylose content of 5% by mass or more to obtain low molecular weight starch. The term "degradation" as used herein refers to decomposition accompanied by lowering the molecular weight of starch, and typical decomposition methods include acid treatment, oxidation treatment, and enzymatic treatment. Among these, acid treatment is preferable from the viewpoints of decomposition rate, cost, and reproducibility of decomposition reaction.

 また、造粒工程には、澱粉の造粒に使用されている一般的な方法を用いることができるが、所定の冷水膨潤度とする点で、澱粉の加熱糊化に使用されている一般的な方法を用いることが好ましい。具体的には、ドラムドライヤー、ジェットクッカー、エクストルーダー、スプレードライヤーなどの機械を使用した方法が知られているが、本実施形態において、冷水膨潤度が上述した特定の条件を満たす成分(A)をより確実に得る観点から、エクストルーダーやドラムドライヤーによる加熱糊化が好ましく、エクストルーダーがより好ましい。エクストルーダー処理する場合は通常、澱粉を含む原料に加水して水分含量を10~60質量%程度に調整した後、たとえばバレル温度30~200℃、出口温度80~180℃、スクリュー回転数100~1,000rpm、熱処理時間5~60秒の条件で、加熱膨化させる。 Further, in the granulation step, a general method used for granulating starch can be used, but in view of obtaining a predetermined cold water swelling degree, a general method used for heating gelatinization of starch is used. It is preferable to use various methods. Specifically, a method using a machine such as a drum dryer, a jet cooker, an extruder, and a spray dryer is known, but in the present embodiment, the component (A) whose cold water swelling degree satisfies the above-mentioned specific condition (A). From the viewpoint of more surely obtaining the above, heating gelatinization by an extruder or a drum dryer is preferable, and an extruder is more preferable. In the case of the extruder treatment, water is usually added to the starch-containing raw material to adjust the water content to about 10 to 60% by mass, and then the barrel temperature is 30 to 200° C., the outlet temperature is 80 to 180° C., and the screw rotation speed is 100 to Heat expansion is performed under conditions of 1,000 rpm and heat treatment time of 5 to 60 seconds.

 本実施形態において、たとえば上記特定の原料を加熱糊化する工程、および、前記工程により加熱糊化して得られた造粒物を、必要に応じて、粉砕し、篩い分けをし、大きさを適宜調整することにより、条件(3)~(5)を満たす成分(A)を得るとよい。 In the present embodiment, for example, the step of heating and gelatinizing the above-mentioned specific raw material, and the granulated product obtained by heating and gelatinizing in the above step, if necessary, crushed and sieved to obtain a size. The component (A) satisfying the conditions (3) to (5) may be obtained by appropriately adjusting.

 以上により得られる成分(A)は、低分子化澱粉を含む澱粉粉状物であって、条件(1)~(5)を満たす構成となっているため、後述の成分(B)とともにバッター用組成物に配合されて、バッターが適用される食品の外観および食感の経時劣化を抑制することができるとともに、保存後再加熱した際にも、外観および食感の好ましいできたて感を食品に与えることができる。ここで、食感として、衣のクリスピー感、衣のヒキの抑制、および、食品の粉っぽさの抑制からなる群から選択される1種以上が挙げられ、好ましくは衣のクリスピー感が挙げられる。 The component (A) obtained as described above is a starch-like substance containing a low-molecular-weight starch and has a constitution satisfying the conditions (1) to (5). Incorporated in the composition, it is possible to suppress the deterioration of the appearance and texture of the food to which the batter is applied over time, and also when the product is reheated after storage, a preferable freshness of appearance and texture Can be given to. Here, as the texture, one or more kinds selected from the group consisting of a crispy sensation of clothing, suppression of baldness of clothing, and suppression of powderyness of food can be mentioned, and preferably the crispy feeling of clothing is mentioned. Be done.

 バッター用組成物中の成分(A)の含有量は、バッターが適用される食品の表面の様子を好ましいものとし、クリスピー感を向上する観点から、バッター用組成物全体に対して好ましくは3.0質量%以上であり、より好ましくは5.0質量%以上、さらに好ましくは10質量%以上、さらにより好ましくは15質量%以上である。
 また、バッターが適用される食品の衣のヒキを抑制する観点から、バッター用組成物中の成分(A)の含有量は、好ましくは55質量%以下であり、より好ましくは50質量%以下、さらに好ましくは40質量%以下、さらにより好ましくは30質量%以下である。
The content of the component (A) in the composition for batter makes the appearance of the surface of the food to which the batter is applied preferable, and from the viewpoint of improving the crispy feeling, it is preferably 3. It is 0% by mass or more, more preferably 5.0% by mass or more, further preferably 10% by mass or more, still more preferably 15% by mass or more.
Further, from the viewpoint of suppressing the battering of the batter of the food to which the batter is applied, the content of the component (A) in the composition for batter is preferably 55% by mass or less, more preferably 50% by mass or less, It is more preferably 40% by mass or less, and even more preferably 30% by mass or less.

(成分(B))
 成分(B)は、酸化澱粉および酸処理澱粉からなる群から選択される1種または2種の澱粉である。また、成分(A)における低分子化澱粉と同じであってもよく、異なっていてもよいが、好ましくは異なった澱粉である。
(Component (B))
Component (B) is one or two starches selected from the group consisting of oxidized starch and acid-treated starch. Further, the starch may be the same as or different from the low molecular weight starch in the component (A), but is preferably a different starch.

 成分(B)が酸化澱粉の場合、原料澱粉は未加工澱粉、またはアセチル化酸化澱粉等、酸化以外の加工処理がなされたものであってもよい。酸化澱粉が、酸化以外の加工処理がなされたものであるとき、酸化処理および他の加工処理の順番に制限はない。
 成分(B)が酸処理澱粉の場合、原料澱粉は未加工澱粉、または酸処理以外の加工処理がなされたものであってもよい。酸処理澱粉が、酸処理以外の加工処理がなされたものであるとき、酸処理および他の加工処理の順番に制限はない。
When the component (B) is an oxidized starch, the raw starch may be a raw starch or an acetylated oxidized starch that has been processed other than oxidized. When the oxidized starch has been subjected to processing other than oxidation, there is no limitation on the order of the oxidation and other processing.
When the component (B) is an acid-treated starch, the raw starch may be a raw starch or a processed starch other than an acid-treated starch. When the acid-treated starch has been subjected to a processing treatment other than the acid treatment, there is no limitation on the order of the acid treatment and the other processing treatments.

 成分(B)が酸化澱粉の場合、原料澱粉の由来として、とうもろこし、高アミロースとうもろこし、もちとうもろこし(ワキシーコーン)、米、もち米、小麦、甘藷、馬鈴薯、もち馬鈴薯、キャッサバ、サゴヤシ等が挙げられる。
 バッターが適用される食品の表面の様子を好ましいものとし、クリスピー感を向上する観点から、成分(B)の酸化澱粉の原料澱粉の由来は、好ましくはキャッサバである。
When the component (B) is an oxidized starch, the source starch is derived from corn, high-amylose corn, corn (waxy corn), rice, glutinous rice, wheat, sweet potato, potato, glutinous potato, cassava, sago palm and the like. ..
From the viewpoint of making the appearance of the surface of the food to which the batter is applied preferable and improving the crispiness, the origin of the raw material starch of the oxidized starch of the component (B) is preferably cassava.

 成分(B)が酸処理澱粉の場合、原料澱粉の由来として、とうもろこし、高アミロースとうもろこし、もちとうもろこし(ワキシーコーン)、米、もち米、小麦、甘藷、馬鈴薯、もち馬鈴薯、キャッサバ、サゴヤシ等が挙げられる。
 加熱調理して得られた食品の表面の様子を好ましいものとし、食感の経時劣化を抑制する観点から、成分(B)の酸処理澱粉の原料澱粉の由来は、好ましくはとうもろこしでありより好ましくはもちとうもろこし(ワキシーコーン)である。
When the component (B) is an acid-treated starch, the source starch is derived from corn, high amylose corn, corn corn (waxy corn), rice, glutinous rice, wheat, sweet potato, potato, glutinous potato, cassava, sago palm and the like. Be done.
From the viewpoint of making the appearance of the surface of the food obtained by heating and cooking preferable, and suppressing the deterioration of texture over time, the origin of the raw material starch of the acid-treated starch of component (B) is preferably corn, and more preferably corn. It is corn corn (waxy corn).

 また、バッターが適用される食品の表面の様子を好ましいものとする観点および入手容易性に優れる観点から、成分(B)の原料澱粉の由来が、キャッサバおよびとうもろこしからなる群から選ばれる1種である。 Further, from the viewpoint of making the appearance of the surface of the food to which the batter is applied preferable and the viewpoint of being easily available, the origin of the raw material starch of the component (B) is one selected from the group consisting of cassava and corn. is there.

 成分(A)の含有量に対する成分(B)の含有量すなわち((B)/(A))は、加熱調理して得られた食品の表面の様子を好ましいものとし、食感の経時劣化を抑制する観点から、質量比で、好ましくは0.4以上であり、より好ましくは0.6以上である。
 また、バッターが適用される食品の衣のヒキを抑制する観点から、上記質量比((B)/(A))は、好ましくは8以下であり、より好ましくは7以下、さらに好ましくは5以下、さらにより好ましくは3以下である。
The content of the component (B) with respect to the content of the component (A), that is, ((B)/(A)), makes the appearance of the surface of the food obtained by heating and cooking preferable, and deteriorates the texture over time. From the viewpoint of suppressing, the mass ratio is preferably 0.4 or more, more preferably 0.6 or more.
In addition, the mass ratio ((B)/(A)) is preferably 8 or less, more preferably 7 or less, and further preferably 5 or less, from the viewpoint of suppressing battering of foods to which the batter is applied. , And even more preferably 3 or less.

 また、加熱調理して得られた食品の外観および食感の経時劣化を抑制する観点から、バッター用組成物において、好ましくは、成分(A)の含有量が、バッター用組成物全体に対して3.0質量%以上55質量%以下であり、かつ、質量比((B)/(A))が0.4以上8以下である。 Further, from the viewpoint of suppressing the deterioration of the appearance and texture of the food obtained by heating and cooking with time, in the composition for batter, the content of the component (A) is preferably based on the entire composition for batter. It is 3.0 mass% or more and 55 mass% or less, and the mass ratio ((B)/(A)) is 0.4 or more and 8 or less.

 バッター用組成物中の成分(B)の含有量は、具体的には、バッター用組成物中の成分(A)の含有量に応じて、質量比((B)/(A))が上述の範囲になるように設定することができる。 Regarding the content of the component (B) in the composition for batter, the mass ratio ((B)/(A)) is specifically described above depending on the content of the component (A) in the composition for batter. It can be set to fall within the range.

 本実施形態におけるバッター用組成物は、成分(A)および(B)を含むため、バッターが適用される食品の外観および食感の経時劣化を抑制することができるとともに、保存後再加熱した際にも、外観および食感の好ましいできたて感を食品に与えることができる。
 ここで、食感として、衣のクリスピー感、および、衣のヒキの抑制からなる群から選択される1種以上が挙げられ、好ましくは衣のクリスピー感が挙げられる。
Since the composition for batter in the present embodiment contains the components (A) and (B), it is possible to suppress the deterioration of the appearance and texture of the food to which the batter is applied with time, and to reheat after storage. In addition, it is possible to give the food a fresh texture with a favorable appearance and texture.
Here, as the texture, one or more kinds selected from the group consisting of a crispy sensation of clothing and suppression of baldness of the clothing can be mentioned, and a crispy sensation of clothing is preferred.

 バッター用組成物は、成分(A)および(B)のみから構成されてもよいし、他の成分をさらに含んでもよい。 The composition for batter may be composed only of the components (A) and (B), or may further contain other components.

 たとえば、バッター用組成物は、加熱調理して得られた食品の衣のクリスピー感を向上させる観点から、好ましくは成分(C)として、リン酸架橋タピオカ澱粉をさらに含む。なお、成分(C)は、前述の成分(A)および(B)以外の澱粉である。 For example, the composition for batter further contains phosphate cross-linked tapioca starch, preferably as the component (C), from the viewpoint of improving the crispiness of the batter of the food obtained by cooking with heat. The component (C) is starch other than the components (A) and (B) described above.

 バッター用組成物が成分(C)をさらに含むとき、成分(A)の含有量に対する前記成分(C)の含有量すなわち((C)/(A))は、質量比で、食品の色調を好ましいものとする観点から、好ましくは0.5以上であり、より好ましくは1以上、さらに好ましくは1.2以上、さらにより好ましくは1.8以上である。
 また、加熱調理して得られた食品の衣のクリスピー感を向上させる観点から、上記質量比((C)/(A))は、好ましくは10以下であり、より好ましくは9.0以下、さらに好ましくは6.0以下、さらにより好ましくは3.0以下である。
When the composition for batter further contains the component (C), the content of the component (C) with respect to the content of the component (A), that is, ((C)/(A)) is a mass ratio, and represents the color tone of the food. From the viewpoint of making it preferable, it is preferably 0.5 or more, more preferably 1 or more, even more preferably 1.2 or more, still more preferably 1.8 or more.
Further, from the viewpoint of improving the crispy feeling of the batter of the food obtained by cooking with heat, the mass ratio ((C)/(A)) is preferably 10 or less, more preferably 9.0 or less, It is more preferably 6.0 or less, and even more preferably 3.0 or less.

 バッター用組成物中の成分(C)の含有量は、具体的には、バッター用組成物中の成分(A)の含有量に応じて、質量比((C)/(A))が上述の範囲になるように設定することができる。 The content of the component (C) in the batter composition is specifically the above-mentioned mass ratio ((C)/(A)) depending on the content of the component (A) in the batter composition. It can be set to fall within the range.

 また、バッター用組成物は、成分(A)~(C)以外の粉体原料をさらに含んでもよく、他の成分として、バッターに配合される粉体原料として後述するものが挙げられる。 The batter composition may further contain powder raw materials other than the components (A) to (C), and examples of the other raw materials include powder raw materials to be blended with the batter, which will be described later.

 (バッター)
 本実施形態において、バッターは、上述した成分(A)、成分(B)を必須成分とする粉体原料と、水と、を含み、これらの成分の配合順序に制限はない。たとえば、バッターは、上述した本実施形態におけるバッター用組成物を予め調製し、水および適宜他の成分と混合して得られるものであってもよい。また、バッターは、成分(A)、成分(B)および水ならびに適宜他の成分を所定の順序で混合して得られるものであってもよい。
 バッターは、具体的には液状である。
(Batter)
In the present embodiment, the batter contains the powder raw material containing the above-mentioned component (A) and component (B) as essential components, and water, and there is no limitation on the mixing order of these components. For example, the batter may be obtained by preparing the composition for batter in the present embodiment described above in advance and mixing it with water and other components as appropriate. In addition, the batter may be obtained by mixing the component (A), the component (B), water, and other components as appropriate in a predetermined order.
The batter is specifically liquid.

 さらに具体的には、バッターは、バッターの原料中の粉体原料として、成分(A)および成分(B)を含み(粉体原料1)、質量比((B)/(A))が好ましくは0.4以上8以下であり、バッターが、バッターの原料中の粉体原料として、成分(C)をさらに含む(粉体原料2)とき、質量比((C)/(A))が好ましくは0.5以上10以下である。
 また、成分(A)および成分(B)の合計量(または、バッターが成分(C)をさらに含む場合は成分(A)、成分(B)および成分(C)の合計量)が、粉体原料全体に対して好ましくは20質量%以上であり、より好ましくは41質量%以上であり、また、好ましくは100質量%以下である。
More specifically, the batter preferably contains the component (A) and the component (B) as the powder raw material in the raw material of the batter (powder raw material 1), and the mass ratio ((B)/(A)) is preferable. Is 0.4 or more and 8 or less, and when the batter further contains the component (C) as the powder raw material in the raw material of the batter (powder raw material 2), the mass ratio ((C)/(A)) is It is preferably 0.5 or more and 10 or less.
Further, the total amount of the component (A) and the component (B) (or the total amount of the component (A), the component (B) and the component (C) when the batter further contains the component (C)) is a powder. It is preferably 20% by mass or more, more preferably 41% by mass or more, and preferably 100% by mass or less with respect to the entire raw material.

 粉体原料中の成分(A)および成分(B)の合計量、または、粉体原料が成分(C)をさらに含む場合は成分(A)、成分(B)および成分(C)の合計量は、食品の色調および衣のクリスピー感の向上の観点から、粉体原料全体に対して好ましくは20質量%以上であり、より好ましくは41質量%以上、さらに好ましくは45質量%以上、さらにより好ましくは55質量%以上、よりいっそう好ましくは70質量%以上、さらにまた好ましくは75質量%以上である。
 また、表面の様子の好ましさおよび衣のヒキを抑制する観点から、上記合計量は、粉体原料全体に対して好ましくは100質量%以下であり、より好ましくは95質量%以下であり、さらに好ましくは92質量%以下である。
The total amount of component (A) and component (B) in the powder raw material, or the total amount of component (A), component (B) and component (C) when the powder raw material further contains component (C) Is preferably 20% by mass or more, more preferably 41% by mass or more, still more preferably 45% by mass or more, still more preferably from the viewpoint of improving the color tone of food and the crispiness of clothes. It is preferably 55% by mass or more, more preferably 70% by mass or more, still more preferably 75% by mass or more.
In addition, the total amount is preferably 100% by mass or less, and more preferably 95% by mass or less, based on the entire powder raw material, from the viewpoint of the appearance of the surface and suppressing the appearance of clothes. More preferably, it is 92 mass% or less.

 また、バッター中の上記合計量((A)+(B)+(C))は、食品の色調および衣のクリスピー感の向上の観点から、バッター全体に対して好ましくは8質量%以上であり、より好ましくは10質量%以上、さらに好ましくは15質量%以上、さらにより好ましくは22質量%以上、よりいっそう好ましくは32質量%以上である。
 また、表面の様子の好ましさおよび衣のヒキを抑制する観点から、バッター中の上記合計量((A)+(B)+(C))は、好ましくは50質量%以下であり、より好ましくは45質量%以下、さらに好ましくは42質量%以下である。
 バッターにおける質量比((B)/(A))および質量比((C)/(A))については、それぞれ、好ましくはバッター用組成物について前述した範囲とすることができる。
Further, the total amount ((A)+(B)+(C)) in the batter is preferably 8% by mass or more based on the whole batter from the viewpoint of improving the color tone of food and the crispy feeling of clothing. , More preferably 10% by mass or more, further preferably 15% by mass or more, even more preferably 22% by mass or more, even more preferably 32% by mass or more.
Further, the total amount ((A)+(B)+(C)) in the batter is preferably 50% by mass or less, from the viewpoint of the favorable appearance of the surface and the suppression of the scarring of clothes. It is preferably 45% by mass or less, more preferably 42% by mass or less.
The mass ratio ((B)/(A)) and the mass ratio ((C)/(A)) in the batter can each be preferably in the ranges described above for the composition for batter.

 バッターの原料のうち、粉体原料は、粉体原料1:前述の成分(A)および成分(B)、または、粉体原料2:成分(A)、成分(B)および成分(C)から構成されてもよい。また、粉体原料1および2のいずれの場合にも、粉体原料が成分(A)~(C)以外の成分をさらに含んでもよい。粉体原料のうち、成分(A)~(C)以外の成分として、未加工澱粉(生澱粉)、加工澱粉等の成分(A)~(C)以外の澱粉;薄力粉等の小麦粉、米粉等の穀粉;全卵粉等の乾燥卵;ベーキングパウダー等の膨張剤;粉末状の調味料;着色料;乳化剤が挙げられる。 Among the raw materials of the batter, the powder raw material includes powder raw material 1: component (A) and component (B) described above, or powder raw material 2: component (A), component (B) and component (C). It may be configured. Further, in any of the powder raw materials 1 and 2, the powder raw material may further contain components other than the components (A) to (C). Of the raw materials for powder, as components other than components (A) to (C), raw starch (raw starch), starch other than components (A) to (C) such as processed starch, wheat flour such as soft flour, rice flour, etc. Flour, dried eggs such as whole egg powder, swelling agents such as baking powder, powdered seasonings, coloring agents, and emulsifiers.

 粉体原料は、加熱調理して得られた食品の衣のヒキを抑制する観点から、好ましくは穀粉をさらに含み、より好ましくは薄力粉をさらに含む。
 粉体原料が薄力粉をさらに含むとき、その含有量は、衣のクリスピー感を向上し、ヒキを抑制する観点から、粉体原料全体に対して好ましくは5質量%以上であり、より好ましくは8質量%以上である。
 また、食品の表面の様子を好ましいものとする観点から、薄力粉の含有量は、粉体原料全体に対して好ましくは80質量%以下であり、より好ましくは59質量%以下、さらに好ましくは40質量%以下、さらにより好ましくは30質量%以下、よりいっそう好ましくは20質量%以下である。
The powder raw material preferably further contains cereal flour, more preferably soft flour, from the viewpoint of suppressing shrinkage of the batter of the food obtained by cooking with heat.
When the powder raw material further contains soft flour, the content thereof is preferably 5% by mass or more, and more preferably 8% by mass with respect to the entire powder raw material, from the viewpoints of improving the crispy feeling of clothing and suppressing hunch. It is at least mass%.
Further, from the viewpoint of making the appearance of the surface of the food preferable, the content of the soft flour is preferably 80% by mass or less, more preferably 59% by mass or less, and further preferably 40% by mass with respect to the entire powder raw material. % Or less, even more preferably 30% by mass or less, and even more preferably 20% by mass or less.

 また、バッターは水を含む。バッター中の水の含有量は、バッターに含まれる水以外の成分の含有量を除いた残部とすることができる。 Also, the batter contains water. The content of water in the batter can be the balance excluding the content of components other than water contained in the batter.

 本実施形態において、バッターは、具体的には、食品の衣に用いられるバッターであり、好ましくは唐揚げ、天ぷらおよびフリッターからなる群から選択される食品のバッターである。 In the present embodiment, the batter is specifically a batter used for food batter, and preferably a food batter selected from the group consisting of fried chicken, tempura and fritters.

 本実施形態のバッターを用いることにより、たとえば、食品の外観の劣化を抑制することができる。外観とは、好ましくは表面のごつごつ感と加熱解凍後の色調である。
 また、本実施形態のバッターを用いることにより、たとえば、食品の食感の劣化を抑制することができる。食感とは、好ましくはクリスピー感である。
By using the batter of this embodiment, for example, deterioration of the appearance of food can be suppressed. The appearance is preferably a rough surface and a color tone after heating and thawing.
Further, by using the batter of the present embodiment, it is possible to suppress the deterioration of the texture of food, for example. The texture is preferably crispy.

 (食品)
 本実施形態において、食品は、前述のバッター用組成物またはバッターを用いて得られる。食品は、具体的には、種物と種物の外側に設けられた衣とを有し、衣は、前述のバッター用組成物またはバッターを用いて得られるものである。
 また、食品の製造方法は、たとえば、前述のバッターを種物の外側に付着させる工程と、バッターが付着した種物を加熱調理して食品を得る工程と、を含む。
(Food)
In the present embodiment, the food is obtained by using the composition for batter or the batter described above. Specifically, the food has a seed and a batter provided on the outside of the seed, and the batter is obtained by using the batter composition or the batter described above.
In addition, the method for producing food includes, for example, a step of attaching the batter to the outside of the seed and a step of cooking the seed to which the batter is attached to obtain the food.

 種物として、たとえば鶏肉等の肉類;魚、貝、エビ等の魚介類;イモ類等の野菜類;ドーナツ、カステラ、饅頭等の菓子類;かまぼこ等の水練り製品などが挙げられる。 Examples of seeds include meat such as chicken; seafood such as fish, shellfish, shrimp; vegetables such as potatoes; confectionery such as donuts, castella, and buns; kneaded products such as kamaboko.

 バッターを種物の外側に付着させる工程において、バッターは、種物の一部を被覆してもよいし、種物全体を被覆してもよい。また、バッターは、種物の一部に付着してもよいし、種物全体に付着してもよい。 In the step of attaching the batter to the outside of the seed, the batter may cover a part of the seed or the whole seed. The batter may be attached to a part of the seed or the entire seed.

 加熱調理して食品を得る工程における調理形態の具体例としては、100~200℃程度の食用油中での油ちょう;薄く油をひいたフライパン、鉄板上での加熱;オーブン等での乾熱;マイクロ波加熱調理;スチームコンベクションオーブン等での加熱調理が挙げられ、衣の食感を向上する観点から、好ましくは油ちょうである。また、食品は、具体的にはこれらの加熱調理を経て得られるものであり、さらに具体的には揚げ物である。 Specific examples of cooking forms in the process of cooking by heating include cooking oil in cooking oil at about 100 to 200°C; frying pan lightly oiled, heating on iron plate; dry heat in oven etc. Microwave heating; heat cooking in a steam convection oven or the like can be mentioned, and from the viewpoint of improving the texture of the batter, oil and fat is preferable. Further, the food is specifically one obtained by heating these foods, and more specifically, a fried food.

 また、食品の製造方法は、食品を得る工程の後、食品を冷凍保存する工程をさらに含んでもよい。冷凍保存における温度は、たとえば-10~-50℃程度とすることができる。 Also, the method for producing a food may further include a step of freezing and storing the food after the step of obtaining the food. The temperature in frozen storage may be, for example, about -10 to -50°C.

 また、食品の製造方法は、冷凍保存する工程の後、食品を加熱解凍する工程をさらに含んでもよい。加熱解凍する工程においては、食感を好ましいものとする観点から、好ましくは電子レンジまたはスチームコンベクションオーブンを用いて加熱解凍する。 Also, the method for producing a food may further include a step of heating and thawing the food after the step of freezing and storing. In the step of heating and thawing, it is preferable to heat and thaw using a microwave oven or a steam convection oven from the viewpoint of making the mouthfeel favorable.

 本実施形態における食品は、前述のバッターを用いて得られるため、外観および食感の経時劣化が抑制され、保存後再加熱した際にも、外観および衣の食感について好ましいできたて感が得られる。 Since the food in the present embodiment is obtained by using the batter described above, deterioration of the appearance and texture over time is suppressed, and even when reheated after storage, a favorable freshness of appearance and texture of the batter is obtained. can get.

 以下に本発明の実施例を示すが、本発明の趣旨はこれらに限定されるものではない。
 以下の例において、断りのない場合、「%」とは、「質量%」である。また、断りのない場合、「部」とは、「質量部」である。
Examples of the present invention will be shown below, but the gist of the present invention is not limited thereto.
In the following examples, "%" means "% by mass" unless otherwise specified. Further, unless otherwise specified, the “part” is “part by mass”.

 (原材料)
 原材料として、主に以下のものを使用した。
薄力粉:「フラワー」、日清製粉株式会社製
低分子化澱粉:後述する製造例1で製造した酸処理ハイアミロースコーンスターチ
澱粉粉状物1および2:製造例2で得られた澱粉粉状物
酸化澱粉:製造例3で得られた酸化澱粉
酸処理澱粉:製造例4で得られた酸処理澱粉
リン酸架橋タピオカ澱粉:「アクトボディー TP-4W」、株式会社J-オイルミルズ製
コーンスターチ(β澱粉):「J-オイルミルズ コーンスターチY」、株式会社J-オイルミルズ製
ハイアミロースコーンスターチ:「J-オイルミルズ HS-7」株式会社J-オイルミルズ製、アミロース含量70質量%
パプリカパウダー:エスビー食品株式会社製
キサンタンガム:「キサンタンガムFJ」、丸善薬品産業株式会社製
(raw materials)
The following materials were mainly used as raw materials.
Soft flour: "Flower", Nisshin Seifun Co., Ltd. Low molecular weight starch: Acid-treated high amylose corn starch starch powder 1 and 2 produced in Production Example 1 described later: Oxidation of starch powder obtained in Production Example 2 Starch: Oxidized starch Acid-treated starch obtained in Production Example 3: Acid-treated starch obtained in Production Example 4 Phosphate-crosslinked tapioca starch: "Actbody TP-4W", corn starch (β-starch manufactured by J-Oil Mills Co., Ltd. ): “J-Oil Mills Corn Starch Y”, high amylose corn starch made by J-Oil Mills Co., Ltd.: “J-Oil Mills HS-7” made by J-Oil Mills, amylose content 70% by mass
Paprika powder: manufactured by SB Foods Co., Ltd. Xanthan gum: "Xanthan gum FJ", manufactured by Maruzen Pharmaceutical Co., Ltd.

 (製造例1)低分子化澱粉の製造
 本例では、澱粉組成物1および2の原料となる低分子化澱粉として酸処理ハイアミロースコーンスターチを製造した。
(Production Example 1) Production of low-molecular-weight starch In this example, acid-treated high-amylose corn starch was produced as the low-molecular-weight starch used as a raw material for starch compositions 1 and 2.

(酸処理ハイアミロースコーンスターチの製造方法)
 ハイアミロースコーンスターチを水に懸濁して35.6%(w/w)スラリーを調製し、50℃に加温した。そこへ、攪拌しながら4.25Nに調製した塩酸水溶液をスラリー質量比で1/9倍量加え反応を開始した。16時間反応後、3%NaOHで中和し、水洗、脱水、乾燥し、酸処理ハイアミロースコーンスターチを得た。
 得られた酸処理ハイアミロースコーンスターチのピーク分子量を以下の方法で測定したところ、ピーク分子量は1.2×104であった。
(Method for producing acid-treated high amylose corn starch)
High amylose corn starch was suspended in water to prepare a 35.6% (w/w) slurry, which was heated to 50°C. The hydrochloric acid aqueous solution adjusted to 4.25N was added thereto with stirring in an amount of 1/9 times the slurry mass ratio to start the reaction. After reacting for 16 hours, it was neutralized with 3% NaOH, washed with water, dehydrated and dried to obtain acid-treated high amylose corn starch.
When the peak molecular weight of the obtained acid-treated high amylose corn starch was measured by the following method, the peak molecular weight was 1.2×10 4 .

(ピーク分子量の測定方法)
 ピーク分子量の測定は、東ソー株式会社製HPLCユニットを使用しておこなった(ポンプDP-8020、RI検出器RS-8021、脱気装置SD-8022)。
(1)試料を粉砕し、JIS-Z8801-1規格の篩で、目開き0.15mm篩下の画分を回収した。この回収画分を移動相に1mg/mLとなるように懸濁し、懸濁液を100℃3分間加熱して完全に溶解した。0.45μmろ過フィルター(ADVANTEC社製、DISMIC-25HP PTFE 0.45μm)を用いてろ過をおこない、ろ液を分析試料とした。
(2)以下の分析条件で分子量を測定した。
カラム:TSKgel α-M(7.8mmφ、30cm)(東ソー株式会社製)2本
流速:0.5mL/min
移動相:5mM NaNO3含有90%(v/v)ジメチルスルホキシド溶液
カラム温度:40℃
分析量:0.2mL
(3)検出器データを、ソフトウェア(マルチステーションGPC-8020modelIIデータ収集ver5.70、東ソー株式会社製)にて収集し、分子量ピークを計算した。
 検量線には、分子量既知のプルラン(Shodex Standard P-82、昭和電工株式会社製)を使用した。
(Measurement method of peak molecular weight)
The peak molecular weight was measured using an HPLC unit manufactured by Tosoh Corporation (pump DP-8020, RI detector RS-8021, degassing device SD-8022).
(1) The sample was crushed, and a fraction under a sieve of 0.15 mm sieve was collected with a sieve of JIS-Z8801-1 standard. This collected fraction was suspended in the mobile phase so as to be 1 mg/mL, and the suspension was heated at 100° C. for 3 minutes to be completely dissolved. A 0.45 μm filtration filter (manufactured by ADVANTEC, DISMIC-25HP PTFE 0.45 μm) was used for filtration, and the filtrate was used as an analytical sample.
(2) The molecular weight was measured under the following analysis conditions.
Column: TSKgel α-M (7.8 mmφ, 30 cm) (manufactured by Tosoh Corporation) 2 Flow rate: 0.5 mL/min
Mobile phase: 90 mM (v/v) dimethyl sulfoxide solution containing 5 mM NaNO 3 Column temperature: 40° C.
Analytical amount: 0.2 mL
(3) The detector data was collected by software (multi-station GPC-8020 model II data collection ver 5.70, manufactured by Tosoh Corporation), and the molecular weight peak was calculated.
For the calibration curve, pullulan with a known molecular weight (Shodex Standard P-82, manufactured by Showa Denko KK) was used.

(製造例2)澱粉粉状物1および2の製造
 β澱粉79質量%、上述の方法で得られた酸処理ハイアミロースコーンスターチ20質量%、および、炭酸カルシウム1質量%を充分に均一になるまで袋内で混合した。2軸エクストルーダー(幸和工業社製KEI-45)を用いて、混合物を加圧加熱処理した。処理条件は、以下の通りである。
原料供給:450g/分
加水:17質量%
バレル温度:原料入口から出口に向かって50℃、70℃および100℃
出口温度:100~110℃
スクリューの回転数250rpm
 このようにしてエクストルーダー処理により得られた加熱糊化物を110℃にて乾燥し、水分含量を約10質量%に調整した。
(Production Example 2) Production of starch-like substances 1 and 2 79% by mass of β-starch, 20% by mass of acid-treated high amylose cornstarch obtained by the above-mentioned method, and 1% by mass of calcium carbonate were sufficiently homogenized. Mixed in bag. The mixture was heated under pressure using a twin-screw extruder (KEI-45 manufactured by Kowa Kogyo Co., Ltd.). The processing conditions are as follows.
Raw material supply: 450 g/min Water addition: 17% by mass
Barrel temperature: 50°C, 70°C and 100°C from the raw material inlet to the outlet
Outlet temperature: 100-110°C
Screw rotation speed 250 rpm
The hot gelatinized product thus obtained by the extruder treatment was dried at 110° C. to adjust the water content to about 10 mass %.

 次いで、乾燥した加熱糊化物を、卓上カッター粉砕機で粉砕した後、JIS-Z8801-1規格の篩で篩分けした。篩分けした加熱糊化物を、以下の配合割合で混合し、以下の澱粉粉状物1および2を調製した。澱粉粉状物中の各画分の質量比を表1に示す。また、得られた澱粉粉状物の冷水膨潤度を、後述の方法で測定した値を合わせて示す。 Next, the dried heated gelatinized product was crushed with a tabletop crusher and then sieved with a JIS-Z8801-1 standard sieve. The sieved hot gelatinized products were mixed in the following blending ratios to prepare the following starch powders 1 and 2. Table 1 shows the mass ratio of each fraction in the starchy material. The degree of cold water swelling of the obtained starch-like substance is also shown together with the values measured by the method described below.

Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001

(冷水膨潤度の測定方法)
(1)試料を、水分計(研精工業株式会社、型番MX-50)を用いて、125℃で加熱乾燥させて水分測定し、得られた水分値から乾燥物質量を算出した。
(2)この乾燥物質量換算で試料1gを25℃の水50mLに分散した状態にし、30分間25℃の恒温槽の中でゆるやかに撹拌した後、3000rpmで10分間遠心分離(遠心分離機:日立工機社製、日立卓上遠心機CT6E型;ローター:T4SS型スイングローター;アダプター:50TC×2Sアダプタ)し、沈殿層と上澄層に分けた。
(3)上澄層を取り除き、沈殿層質量を測定し、これをB(g)とした。
(4)沈殿層を乾固(105℃、恒量)したときの質量をC(g)とした。
(5)BをCで割った値を冷水膨潤度とした。
(Measuring method of cold water swelling degree)
(1) The sample was heated and dried at 125° C. using a moisture meter (Kenseiki Co., Ltd., model number MX-50) to measure the moisture content, and the amount of dry substance was calculated from the obtained moisture value.
(2) 1 g of the sample in terms of dry matter amount was dispersed in 50 mL of water at 25° C., gently stirred in a thermostat at 25° C. for 30 minutes, and then centrifuged at 3000 rpm for 10 minutes (centrifuge: Hitachi tabletop centrifuge CT6E type; rotor: T4SS type swing rotor; adapter: 50TC×2S adapter) and separated into a precipitation layer and a supernatant layer.
(3) The supernatant layer was removed, the mass of the sediment layer was measured, and this was designated as B(g).
(4) The mass of the precipitate layer when dried (105°C, constant weight) was defined as C (g).
(5) The value obtained by dividing B by C was taken as the degree of cold water swelling.

 (製造例3)
 本例では、未加工のタピオカ澱粉を原料澱粉として、以下の手順で酸化澱粉を得た。
 500mLセパラブルフラスコに、タピオカ澱粉(株式会社J-オイルミルズ製)を用い、澱粉160gにスラリー質量に対する澱粉乾物換算質量濃度が38%(dry starch weight/slurry weight)となるよう水を加えたスラリーを調製した。
 得られたスラリーの温度を38℃にした後、300rpmで撹拌しながら次亜塩素酸ナトリウム水溶液を澱粉乾物換算質量濃度で3.0%となるように投入し、3質量%水酸化ナトリウム水溶液を滴下して、pH8.25にした。
 その後、適時水酸化ナトリウム水溶液を滴下して、反応終了までpHを設定値±0.03以内に維持し、酸化澱粉を得た。反応終了は、スラリーを少量サンプリングして飽和ヨウ化カリウム水溶液に滴下し、紫色を呈しなくなった時点とした。
 反応終了を確認後、スラリーに3質量%塩酸を添加してpH6まで中和し、洗浄脱水したのち乾燥させ、酸化澱粉を得た。
(Production Example 3)
In this example, raw tapioca starch was used as a raw material starch to obtain an oxidized starch by the following procedure.
A slurry in which tapioca starch (manufactured by J-Oil Mills Co., Ltd.) was added to a 500 mL separable flask, and water was added to 160 g of the starch so that the mass concentration of starch dry matter converted to the slurry mass was 38% (dry starch weight/slurry weight). Was prepared.
After the temperature of the obtained slurry was set to 38° C., an aqueous solution of sodium hypochlorite was added so as to have a starch dry matter-equivalent mass concentration of 3.0% while stirring at 300 rpm, and a 3 mass% aqueous solution of sodium hydroxide was added. It was dropped to bring the pH to 8.25.
Then, an aqueous sodium hydroxide solution was added dropwise at appropriate times to maintain the pH within the set value ±0.03 until the end of the reaction to obtain oxidized starch. The reaction was completed when a small amount of the slurry was sampled and added dropwise to a saturated potassium iodide aqueous solution so that the purple color disappeared.
After confirming the completion of the reaction, 3% by mass hydrochloric acid was added to the slurry to neutralize it to pH 6, washed, dehydrated and dried to obtain oxidized starch.

 (製造例4)
 本例では、未加工のワキシーコーンスターチを原料澱粉として、以下の手順で酸処理澱粉を得た。
 40質量%のワキシーコーンスターチ(株式会社J-オイルミルズ製)の水分散液320質量部に6質量%塩酸を80質量部添加し、40℃で24時間攪拌することで酸処理を行った。酸処理後、pHが5になるように消石灰を用いて中和した後、洗浄、乾燥をおこない、酸処理澱粉を得た。
(Production Example 4)
In this example, raw waxy corn starch was used as the raw material starch to obtain an acid-treated starch by the following procedure.
To 320 parts by mass of a 40% by mass waxy cornstarch (manufactured by J-Oil Mills Co., Ltd.), 80 parts by mass of 6% by mass hydrochloric acid was added, and the mixture was stirred at 40° C. for 24 hours for acid treatment. After the acid treatment, it was neutralized with slaked lime so that the pH became 5, and then washed and dried to obtain acid-treated starch.

 (実験例1~6)
 本例では、唐揚げの作製および評価をおこなった。
(唐揚げの製造方法)
1.鶏モモ肉をカットし、約25g/個とした。
2.1.の鶏肉をラミジップ(スタンドタイプLZ―22、株式会社生産日本社製)に入れ、後述する組成のピックル液を加えて真空包装機(MZC-300-C、株式会社ハギオス社製)にて、以下の条件で真空にした後、4℃、90分タンブリングした。
(真空条件)
空気の排出:15秒
密閉シール:中温2秒
3.タンブリング後の鶏肉に、打ち粉(「HB-5000」、株式会社J-オイルミルズ製)を鶏肉に対して4質量%添加し、まぶした。
4.打ち粉をまぶした鶏肉を、表1~表6に記載の各例のバッター液を鶏肉に対し20質量%添加し、バッタリングした。なお、比較例1-3については、バッター液として薄力粉11.4質量部、増粘多糖類0.09質量部、パプリカパウダー0.06質量部、水18.45質量部を混合したものを使用し、表1の組成でブレッダーを作製し、前述のバッターをつけた鶏肉にまぶした。
5.バッタリング後の鶏肉を、キャノーラ油中で190℃、4分半油ちょうした。
6.油ちょう後の鶏肉をバットにならべ、バットごと-20℃にて冷凍し、その後、鶏肉をチャック袋に移して-20℃にて3日間冷凍保存した。
7.冷凍3日後の唐揚げ4個を紙皿に並べ、電子レンジ強(1400W)で45秒加熱解凍した。
8.以上の手順により得られた唐揚げの外観および食感を評価した。評価項目および採点基準を以下に示す。
(Experimental Examples 1 to 6)
In this example, fried chicken was prepared and evaluated.
(Production method of fried chicken)
1. Chicken thigh meat was cut to about 25 g/piece.
2.1. Put the chicken meat in LAMIZIP (Stand type LZ-22, manufactured by Japan Co., Ltd.), add the pickle liquid of the composition described below, and in a vacuum packaging machine (MZC-300-C, manufactured by Hagios Co., Ltd.) After evacuating under the above conditions, tumbling was performed at 4° C. for 90 minutes.
(Vacuum condition)
Air discharge: 15 seconds Hermetic seal: Medium temperature 2 seconds 3. To the chicken meat after tumbling, 4% by mass of dusting powder (“HB-5000”, manufactured by J-Oil Mills Co., Ltd.) was added to the chicken meat and sprinkled.
4. 20% by mass of the batter solution of each example described in Tables 1 to 6 was added to the chicken meat sprinkled with dusting powder, and the chicken meat was battered. For Comparative Example 1-3, a mixture of 11.4 parts by mass of soft flour, 0.09 parts by mass of thickening polysaccharide, 0.06 parts by mass of paprika powder, and 18.45 parts by mass of water was used as the batter liquid. Then, a blender having the composition shown in Table 1 was prepared and sprinkled on the above-mentioned battered chicken.
5. The buttered chicken was fried in canola oil at 190° C. for 4 minutes and a half.
6. After pouring the oil, the chicken was placed in a vat, and the whole vat was frozen at -20°C. Then, the chicken was transferred to a zipper bag and stored frozen at -20°C for 3 days.
7. Four fried chickens after 3 days of freezing were placed on a paper plate and heated and thawed for 45 seconds in a microwave oven (1400W).
8. The appearance and texture of the fried chicken obtained by the above procedure were evaluated. The evaluation items and scoring criteria are shown below.

(ピックル液の組成)
原材料                         配合率(%)
「ハイトラストTC-500」(株式会社J-オイルミルズ製) 10
上白糖                           4
食塩                            4
グルタミン酸Na                      1.4
白コショウ                         0.16
醤油                           20
氷水                           60.44
合計                          100
(Pickle liquid composition)
Raw material mix ratio (%)
"High Trust TC-500" (J-Oil Mills Co., Ltd.) 10
White sugar 4
Salt 4
Glutamic acid Na 1.4
White pepper 0.16
Soy sauce 20
Ice water 60.44
Total 100

(外観評価)
 専門パネラーが目視にて唐揚げの表面の様子および色調を以下の採点基準で評価し、2点超のものを合格とした。
(唐揚げ表面の様子)
5:ゴツゴツ(チリチリが多く凹凸がはっきりしている状態)
4:ややゴツゴツ(チリチリがあり凹凸がややはっきりしている状態)
3:やや滑らか(チリチリはないが凹凸がわずかに見られる状態)
2:滑らか(チリチリがなく凹凸がない状態)
1:衣が薄く肉がところどころ露出した素揚げ状
(唐揚げ色調)
5:唐揚げらしい非常に良好なきつね色
4:わずかに薄いまたはわずかに濃いが、唐揚げらしい良好なきつね色
3:やや薄いきつね色またはやや濃いきつね色
2:やや加熱不足を思わせる薄いきつね色またはやや加熱過剰を思わせる濃いきつね色
1:加熱不足を思わせる白色または加熱過剰を思わせる焦げ色
(Appearance evaluation)
A specialized panelist visually evaluated the appearance and color tone of the fried chicken surface according to the following scoring criteria, and those with more than 2 points were regarded as passing.
(State of fried chicken surface)
5: lumpy (state with a lot of dust and unevenness)
4: Slightly lumpy (state with unevenness and slight irregularities)
3: Slightly smooth (there is no dust, but there are slight irregularities)
2: Smooth (no dust and no unevenness)
1: Deep fried (thin fried color) with thin batter and exposed meat
5: Very good fox color like fried chicken 4: Slightly or slightly dark but good fox color like fried chicken 3: Slightly light fox color or slightly dark fox color 2: Light fox that seems to be slightly underheated Color or dark red color that reminds slightly overheating 1: White that resembles insufficient heating or burnt color that resembles overheating

(食感評価)
 専門パネラーが唐揚げ衣のクリスピー感、衣にヒキがあるかどうか(以下、単に「衣にヒキ」ともいう。)、および、食感の粉っぽさを以下の採点基準で官能評価し、2点超のものを合格とした。ここで、衣にヒキがあるとは、衣の歯切れが悪く、噛みきりにくい状態を指す。
(衣のクリスピー感)
6:大変クリスピーである
5:かなりクリスピーである
4:クリスピーである
3:ややクリスピーである
2:あまりクリスピーではない
1:全くクリスピーではない
(衣にヒキ)
6:全くヒキがない食感
5:ほとんどヒキがない食感
4:あまりヒキがない食感
3:わずかにヒキがある食感
2:ややヒキがある食感
1:とてもヒキがある食感
(Texture evaluation)
The expert panelists sensory-evaluate the crispy feeling of fried chicken, whether there is huki in the garment (hereinafter, also referred to simply as "hiki to garment"), and the powdery texture of the texture according to the following scoring criteria, Those with more than 2 points were accepted. Here, the fact that the garment has a crack means that the garment is not crisp and is difficult to bite.
(Crispy feeling of clothes)
6: Very crispy 5: Quite crispy 4: Crispy 3: Slightly crispy 2: Not very crispy 1: Not at all crispy (blown on clothes)
6: Texture without any huki 5: Texture with almost no huki 4: Texture with little huki 3: Texture with a slight hull 2: Texture with a slight hull 1: Texture with a very huki

(実験例1:対照例、実施例1-1~1-3、比較例1-1~1-3)
 比較例1-3以外の例については、表2に記載の原材料のうち、粉体原料を混合してバッター用組成物を得た。そして、得られたバッター用組成物と冷水とを混合し、各例のバッターを得た。得られたバッターを用いて前述の方法で唐揚げを作製し、評価した。
 比較例1-3については、表2に記載の原材料のうち、粉体原料を混合して組成物を得た。そして、得られた上記組成物を、冷水に分散させずにそのまま、前述のバッターを付けた後ブレッダーとして用いて前述の方法に準じて唐揚げを作製し、評価した。
 外観の評価では、評価者2名の合議により採点した。食感の評価では、評価者2名の合議により採点した。評価結果を表2にあわせて示す。
(Experimental Example 1: Control Example, Examples 1-1 to 1-3, Comparative Examples 1-1 to 1-3)
For the examples other than Comparative Examples 1-3, powder raw materials among the raw materials shown in Table 2 were mixed to obtain a batter composition. And the obtained composition for batters and cold water were mixed, and the batter of each example was obtained. Using the obtained batter, fried chicken was prepared and evaluated by the method described above.
In Comparative Example 1-3, powder raw materials among the raw materials shown in Table 2 were mixed to obtain a composition. Then, the obtained composition was used without being dispersed in cold water as it was, after being attached with the batter described above, as a blender, and fried chicken was prepared according to the method described above and evaluated.
In the evaluation of the appearance, the evaluation was scored by a consultation between two evaluators. In the evaluation of texture, two evaluators agreed and scored. The evaluation results are also shown in Table 2.

Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002

 表2より、各実施例のバッター組成物およびバッターを用いることにより、冷凍後再加熱した際にも、外観および食感について、好ましいできたて感のある唐揚げが得られた。
 具体的には、成分(A)と成分(B)を所定量含むバッターを用いて作製した唐揚げはいずれも、唐揚げの表面や色調に優れ、衣の食感にも優れていた。また、実施例1-2のように成分(C)をさらに含む場合、衣のクリスピー感が向上した。また小麦粉を含む実施例1-2と小麦粉を含まない実施例1-3を比較した場合、小麦粉を含む実施例1-2の方がクリスピー感や衣のヒキの点で優れていた。比較例1-3では、実施例1-2と同じ組成の物をブレッダーとして用いたが、この場合、唐揚げの色調がやや暗く変色し、かつクリスピー感がやや劣り粉っぽさも感じられ、あまり好ましいものではなかった。
From Table 2, by using the batter composition and the batter of each Example, fried chicken with a freshly-prepared fresh appearance was obtained even when reheated after freezing.
Specifically, all the fried chicken prepared using a batter containing a predetermined amount of the component (A) and the component (B) were excellent in the surface and color tone of the fried chicken, and the texture of the clothes was also excellent. When the component (C) was further contained as in Example 1-2, the crispy sensation of clothes was improved. When Example 1-2 containing wheat flour was compared with Example 1-3 containing no wheat flour, Example 1-2 containing wheat flour was superior in terms of crispy feeling and blushing of clothes. In Comparative Example 1-3, the same composition as in Example 1-2 was used as a blender, but in this case, the color of the fried chicken was discolored to a slightly dark color, and the crispy sensation was slightly inferior, and a powdery feeling was also felt. It wasn't very good.

(実験例2:実施例2-1~2-4)
 表3に記載の原材料のうち、粉体原料を混合してバッター用組成物を得た。そして、得られたバッター用組成物と冷水とを混合し、各例のバッターを得た。得られたバッターを用いて前述の方法で唐揚げを作製し、評価した。外観の評価では、評価者2名の合議により採点した。食感の評価では、評価者2名が各自採点し、その平均点を評点とした。評価結果を表3にあわせて示す。
(Experimental Example 2: Examples 2-1 to 2-4)
Of the raw materials shown in Table 3, powder raw materials were mixed to obtain a batter composition. And the obtained composition for batters and cold water were mixed, and the batter of each example was obtained. Using the obtained batter, fried chicken was prepared and evaluated by the method described above. In the evaluation of the appearance, the evaluation was scored by a consultation between two evaluators. In evaluating the texture, each of the two evaluators scored their own, and the average score was used as the score. The evaluation results are also shown in Table 3.

Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003

 表3より、各実施例のバッター組成物およびバッターを用いることにより、冷凍後再加熱した際にも、外観および食感について、好ましいできたて感のある唐揚げが得られた。
 具体的には、成分(A)を粉体原料中4.9質量%から27.0質量%の範囲で含み、成分(B)を含むバッターを用いて作製した唐揚げは、いずれも唐揚げの表面や色調に優れ、衣の食感にも優れていた。
 唐揚げの表面の様子および衣のヒキに関しては、成分(A)を粉体原料中4.9質量%以上27.0質量%以下含む場合良好であり、19.8質量%以上27.0質量%以下含む場合により良好であった。唐揚げの色調に関しては成分(A)を粉体原料中4.9質量%以上27.0質量%以下含む場合良好であり、4.9質量%以上19.8質量%以下含む場合、より良好であった。クリスピー感に関しては、成分(A)を粉体原料中4.9質量%以上27.0質量%以下含む場合良好であり、9.9質量%以上27.0質量%以下含む場合により良好であり、19.8質量%以上27.0質量%以下含む場合さらにより良好であった。
From Table 3, by using the batter composition and the batter of each example, fried chicken with a favorable freshness in appearance and texture was obtained even when reheated after freezing.
Specifically, the fried chicken made using a batter containing the component (A) in the powder raw material in the range of 4.9 mass% to 27.0 mass% and the component (B) is fried. It had an excellent surface and color tone, and the texture of the clothes was excellent.
Regarding the state of the fried chicken surface and the boil of the batter, it is good when the ingredient (A) is contained in the powder raw material in an amount of 4.9% by mass or more and 27.0% by mass or less, and 19.8% by mass or more and 27.0% by mass. % Or less was better. Regarding the color tone of fried chicken, it is good when the ingredient (A) is contained in the powder raw material in an amount of 4.9% by mass or more and 27.0% by mass or less, and better when it is included in the powder raw material of 4.9% by mass or more and 19.8% by mass or less. Met. Regarding the crispy feeling, it is good when the component (A) is contained in the powder raw material in an amount of 4.9% by mass or more and 27.0% by mass or less, and is better when it is contained in the powder raw material of 9.9% by mass or more and 27.0% by mass or less. , 19.8 mass% or more and 27.0 mass% or less was even better.

(実験例3:実施例3-1~3-4、比較例3-1)
 表4に記載の原材料のうち、粉体原料を混合してバッター用組成物を得た。そして、得られたバッター用組成物と冷水とを混合し、各例のバッターを得た。得られたバッターを用いて前述の方法で唐揚げを作製し、評価した。外観の評価では、評価者3名が各自採点し、その平均点を評点とした。食感の評価では、評価者3名の合議により採点した。評価結果を表4にあわせて示す。
(Experimental Example 3: Examples 3-1 to 3-4 and Comparative Example 3-1)
Among the raw materials shown in Table 4, powder raw materials were mixed to obtain a batter composition. And the obtained composition for batters and cold water were mixed, and the batter of each example was obtained. Using the obtained batter, fried chicken was prepared and evaluated by the method described above. In the evaluation of the appearance, each of the three evaluators scored their own, and the average score was used as the score. The evaluation of texture was scored by a panel of 3 evaluators. The evaluation results are also shown in Table 4.

Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004

 表4より、各実施例のバッター組成物およびバッターを用いることにより、冷凍後再加熱した際にも、外観および食感について、好ましいできたて感のある唐揚げが得られた。
 唐揚げの表面の様子に関しては、成分(A)に対する成分(B)の質量比((B)/(A))が1.0以上2.0以下の場合、良好であり、1.5以上2.0以下の場合、より良好であった。唐揚げの色調および衣のヒキに関しては、質量比((B)/(A))が1.0以上2.0以下の場合、良好であり、1.5の場合、より良好であった。クリスピー感に関しては、質量比((B)/(A))が1.0以上2.0以下の場合、良好であり、1.5以上2.0以下の場合、より良好であった。
From Table 4, by using the batter composition and the batter of each example, fried chicken with a favorable freshness in appearance and texture was obtained even when reheated after freezing.
Regarding the state of the surface of fried chicken, when the mass ratio of the component (B) to the component (A) ((B)/(A)) is 1.0 or more and 2.0 or less, it is good, and 1.5 or more. It was better when it was 2.0 or less. Regarding the color tone of deep-fried chicken and the huki of batter, when the mass ratio ((B)/(A)) was 1.0 or more and 2.0 or less, it was good, and when it was 1.5, it was better. Regarding the crispy feeling, when the mass ratio ((B)/(A)) was 1.0 or more and 2.0 or less, it was good, and when it was 1.5 or more and 2.0 or less, it was better.

 (実験例4:実施例4-1、4-2、比較例4-1)
 表5に記載の原材料のうち、粉体原料を混合してバッター用組成物を得た。そして、得られたバッター用組成物と冷水とを混合し、各例のバッターを得た。得られたバッターを用いて前述の方法で唐揚げを作製し、評価した。外観の評価では、評価者3名が各自採点し、その平均点を評点とした。食感の評価では、評価者3名の合議により採点した。評価結果を表5にあわせて示す。
(Experimental Example 4: Examples 4-1, 4-2, Comparative Example 4-1)
Of the raw materials shown in Table 5, powder raw materials were mixed to obtain a batter composition. And the obtained composition for batters and cold water were mixed, and the batter of each example was obtained. Using the obtained batter, fried chicken was prepared and evaluated by the method described above. In the evaluation of the appearance, each of the three evaluators scored their own, and the average score was used as the score. The evaluation of texture was scored by a panel of 3 evaluators. The evaluation results are also shown in Table 5.

Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005

 表5より、各実施例のバッター組成物およびバッターを用いることにより、冷凍後再加熱した際にも、外観および食感について、好ましいできたて感のある唐揚げが得られた。
 一方、比較例4-1のバッター組成物およびバッターは、成分(B)を含まないため、冷凍後再加熱した際に、唐揚げの色調および衣のヒキについて、好ましいできたて感が得られなかった。
 また、表2~表5より、成分(A)、(B)および(C)の合計量が粉体原料中49.5質量%から90.0質量%の範囲であるバッターを用いて作製した唐揚げは、いずれも唐揚げの表面や色調に優れ、衣の食感にも優れていた。
 唐揚げの表面の様子に関しては、成分(A)、(B)および(C)の合計量が粉体原料中、49.5質量%以上90.0質量%以下の場合良好であった。クリスピー感に関しては、成分(A)、(B)および(C)の合計量が粉体原料中、49.5質量%以上90.0質量%以下の場合良好であり、74.2質量%以上90.0質量%以下の場合により良好であった。衣のヒキに関しては、成分(A)、(B)および(C)の合計量が粉体原料中、49.5質量%以上90.0質量%以下の場合良好であった。
From Table 5, by using the batter composition and the batter of each example, fried chicken with favorable freshness in appearance and texture was obtained even when reheated after freezing.
On the other hand, since the batter composition and the batter of Comparative Example 4-1 do not contain the component (B), when they are reheated after being frozen, a favorable freshness feeling can be obtained with respect to the color tone of deep-fried chicken and the blush of the batter. There wasn't.
Further, from Tables 2 to 5, it was produced using a batter in which the total amount of the components (A), (B) and (C) is in the range of 49.5% by mass to 90.0% by mass in the powder raw material. The fried chickens were excellent in the surface and color tone of the fried chicken, and the texture of the batter was also excellent.
Regarding the state of the surface of the fried chicken, it was good when the total amount of the components (A), (B) and (C) was 49.5% by mass or more and 90.0% by mass or less in the powder raw material. Regarding the crispy feeling, it is good when the total amount of the components (A), (B) and (C) is 49.5% by mass or more and 90.0% by mass or less in the powder raw material, and 74.2% by mass or more. It was better when the content was 90.0 mass% or less. With respect to clothing hiding, it was good when the total amount of the components (A), (B) and (C) was 49.5% by mass or more and 90.0% by mass or less in the powder raw material.

 (実験例5:対照例、実施例5-1~5-3)
 表6に記載の原材料のうち、粉体原料を混合してバッター用組成物を得た。そして、得られたバッター用組成物と冷水とを混合し、各例のバッターを得た。得られたバッターを用いて前述の方法で唐揚げを作製し、前述の方法で評価した。ただし、本実験では、前述の評価方法に加え、油ちょう直後、油ちょう後室温で4時間静置しそのまま喫食した場合の評価も併せておこなった。
 外観の評価では、評価者3名が各自採点し、その平均点を評点とした。食感の評価では、評価者2名が各自採点し、その平均点を評点とした。評価結果を表6にあわせて示す。
(Experimental Example 5: Control Example, Examples 5-1 to 5-3)
Among the raw materials shown in Table 6, powder raw materials were mixed to obtain a batter composition. And the obtained composition for batters and cold water were mixed, and the batter of each example was obtained. Using the obtained batter, fried chicken was prepared by the above method and evaluated by the above method. However, in this experiment, in addition to the above-described evaluation method, evaluation was also performed when immediately after frying, and after standing for 4 hours at room temperature after frying and eating as it was.
In the evaluation of the appearance, each of the three evaluators scored their own, and the average score was used as the score. In evaluating the texture, each of the two evaluators scored their own, and the average score was used as the score. The evaluation results are also shown in Table 6.

Figure JPOXMLDOC01-appb-T000006
Figure JPOXMLDOC01-appb-T000006

 表6より、各実施例のバッター組成物およびバッターを用いることにより、油ちょう直後、油ちょう4時間後および冷凍後再加熱した際にも、外観および食感について、好ましいできたて感のある唐揚げが得られた。
 成分(A)として、澱粉粉状物1を使用した場合と澱粉粉状物2を使用した場合では、油ちょう直後の唐揚げ表面の様子、唐揚げ色調、クリスピー感はいずれも好ましく、衣のヒキに関しては澱粉粉状物1がより優れていた。油ちょう4時間後では、唐揚げ表面の様子、唐揚げ色調、クリスピー感は澱粉粉状物2がより優れていた。冷凍後再加熱した際には、唐揚げ表面の様子、唐揚げ色調において、澱粉粉状物1がわずかに優れていた。
 また、成分(B)として、酸化澱粉を使用した場合と酸処理澱粉を使用した場合では、油ちょう直後の唐揚げ表面の様子、唐揚げ色調、衣のヒキ、クリスピー感はいずれも非常に好ましかった。油ちょう4時間後では、唐揚げ表面の様子、唐揚げ色調、クリスピー感は酸処理澱粉がやや優れており、衣のヒキに関しては酸化澱粉がやや優れていた。冷凍後再加熱した際には、唐揚げ表面の様子、唐揚げ色調、衣のヒキにおいて、酸化澱粉がより好ましく、クリスピー感に関しては酸処理澱粉の方が好ましかった。
 本実施例で得られた唐揚げは、油ちょう直後と比較して、油ちょう4時間後および冷凍後再加熱した際の経時劣化が少なく、好ましいできたて感のあるものであった。
From Table 6, by using the batter composition of each example and the batter, there is a favorable freshness in appearance and texture even immediately after fried oil, after 4 hours of fried oil and when reheated after freezing. The fried chicken was obtained.
When the starch-like substance 1 and the starch-like substance 2 are used as the component (A), the state of the fried surface immediately after the oil frying, the fried color tone, and the crispy feeling are all preferable. Starch 1 was better with regard to Hiki. After 4 hours of fried oil, the starchy material 2 was more excellent in the appearance of the fried chicken surface, the fried chicken color tone and the crispy sensation. When re-heated after freezing, the starchy substance 1 was slightly superior in the appearance of the fried chicken surface and the fried chicken color tone.
In addition, when the oxidized starch and the acid-treated starch were used as the component (B), the state of the fried surface immediately after the oil-cooking, the fried color tone, the taste of the batter, and the crispy feeling were all very good. It was good. After 4 hours of fried oil, the surface of the fried chicken, the color of the fried chicken, and the crispy sensation were slightly superior to the acid-treated starch, and the oxidized starch was slightly superior to the haki of the batter. When re-heated after freezing, oxidized starch was more preferable in the appearance of fried surface, fried color, and batter of batter, and acid-treated starch was more preferable in terms of crispy feeling.
The deep-fried tofu obtained in this example showed less deterioration over time after being cooked for 4 hours and after being reheated after freezing, as compared with immediately after frying, and had a fresh feeling.

 (実験例6)
 前述の実験例5における実施例5-1~5-3について、油ちょう直後、油ちょう後室温で4時間静置、および冷凍保存後再加熱した各唐揚げについて、外観および食感のできたて感を油ちょう直後のものと比較し、評価した。以下の評価基準で評価者2名が各自採点し、その平均点を評点とし、2点超のものを合格とした。評価結果を表7に示す。
(できたて感)
6:できたてものと全く同等である
5:できたてものとほぼ同等である
4:できたてものとおおむね同等である
3:できたてものに比べ少し劣る
2:できたてものに比べ劣る
1:できたてものに比べ大きく劣る
(Experimental example 6)
Regarding Examples 5-1 to 5-3 in Experimental Example 5 described above, the appearance and texture of fresh fried chicken immediately after frying, leaving still for 4 hours at room temperature after frying, and re-heating after frozen storage were obtained. The feeling was evaluated by comparing it with that immediately after frying. Two evaluators scored each by the following evaluation criteria, and the average score was used as a score, and a score of more than 2 was regarded as a pass. The evaluation results are shown in Table 7.
(Fresh feeling)
6: Completely equivalent to what was made 5: Almost equivalent to what was created 4: Almost equal to what was created 3: A little inferior to what was created 2: What was created Inferior to 1: Greatly inferior to what was made

Figure JPOXMLDOC01-appb-T000007
Figure JPOXMLDOC01-appb-T000007

 表7より、本実施形態で得られた唐揚げは、油ちょう直後と比較して、油ちょう4時間後および冷凍後再加熱した際の継時劣化が少なく、好ましいできたて感のあるものであった。澱粉粉状物2(実施例5-2)を使用した場合、澱粉粉状物1(実施例5-1)と比べて4時間後、および冷凍保存後再加熱の際のできたて感がより優れていた。
 また、成分(B)として、酸化澱粉を使用した場合(実施例5-1)と酸処理澱粉(実施例5-3)では、酸化澱粉の方が冷凍保存後再加熱の際のできたて感がより優れていた。
From Table 7, the fried chicken obtained in the present embodiment has less deterioration at the time of oil frying 4 hours after rehydration and after reheating after freezing, as compared with immediately after frying, and has a favorable fresh feeling. Met. When the starch-like substance 2 (Example 5-2) was used, compared to the starch-like substance 1 (Example 5-1), the fresh feeling after 4 hours and after re-freezing and reheating was better. Was excellent.
Further, in the case where the oxidized starch is used as the component (B) (Example 5-1) and the acid-treated starch (Example 5-3), the oxidized starch has a fresh feeling when reheated after frozen storage. Was better.

 (実験例7:対照例、実施例6-1~6-4)
 本例では、エビの天ぷらの製造および評価をおこなった。
(Experimental Example 7: Control Example, Examples 6-1 to 6-4)
In this example, shrimp tempura was produced and evaluated.

 (原材料)
 原材料として、以下のものを使用した。
天ぷら粉:「黄金」、昭和産業株式会社製
その他の原材料は前述のものを用いた。
(raw materials)
The following were used as raw materials.
Tempura powder: "Golden", manufactured by Showa Sangyo Co., Ltd., and other raw materials used above.

(エビの天ぷらの製造方法)
 表8に記載の原材料のうち、粉体原料を混合してバッター用組成物を得た。そして、得られたバッター用組成物と冷水とを混合し、各例のバッターを得た。
 解凍した尾付きのばしエビ(約10cm/1尾)に、打ち粉をまぶしたのち、各例のバッターをまぶした。
 キャノーラ油で170℃、3分間揚げてエビの天ぷらを得た。
 4時間室温で静置した後、喫食し、パネラー2名で評価した。
(Production method of shrimp tempura)
Of the raw materials shown in Table 8, powder raw materials were mixed to obtain a batter composition. And the obtained composition for batters and cold water were mixed, and the batter of each example was obtained.
Thawed shrimp with tail (about 10 cm/1) was sprinkled with dusting powder, and then sprinkled with the batter of each example.
Fried canola oil at 170° C. for 3 minutes to obtain shrimp tempura.
After standing at room temperature for 4 hours, they were eaten and evaluated by two panelists.

Figure JPOXMLDOC01-appb-T000008
Figure JPOXMLDOC01-appb-T000008

 各実施例のバッター用組成物を用いて作製されたエビの天ぷらは、対照例と比較して、調理直後および調理から4時間後でも、喫食した際の衣のクリスピー感が優れていた。さらに具体的には、((A)+(B)+(C)))を、粉体原料中25質量%以上50質量%以下含む場合(実施例6-1~6-4)クリスピー感が優れており、42.8質量%以上50質量%以下含む場合(実施例6-1、6-2および6-4)、より優れていた。 The shrimp tempura prepared using the batter composition of each example had a better crispy texture of the batter when eaten immediately after cooking and 4 hours after cooking, as compared with the control example. More specifically, when ((A)+(B)+(C))) is contained in the powder raw material in an amount of 25% by mass or more and 50% by mass or less (Examples 6-1 to 6-4), a crispy feeling is obtained. It was excellent, and was more excellent when it contained 42.8% by mass or more and 50% by mass or less (Examples 6-1, 6-2 and 6-4).

 この出願は、2018年12月4日に出願された日本出願特願2018-227443号を基礎とする優先権を主張し、その開示のすべてをここに取り込む。 This application claims the priority right based on Japanese Patent Application No. 2018-227443 filed on December 4, 2018, and incorporates all the disclosure thereof.

Claims (17)

 以下の成分(A)および(B):
 (A)以下の条件(1)~(5)を満たす澱粉粉状物
  (1)澱粉含量が75質量%以上
  (2)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、前記低分子化澱粉のピーク分子量が3×103以上5×104以下
  (3)25℃における冷水膨潤度が5以上20以下
  (4)目開き0.5mmの篩の篩下かつ0.075mmの篩の篩上の含有量が20質量%以上95質量%以下
  (5)目開き0.5mmの篩の篩上の含有量が30質量%以下
 (B)酸化澱粉および酸処理澱粉からなる群から選択される1種または2種
 を含み、水に分散させて用いられる、バッター用組成物。
The following components (A) and (B):
(A) Starch-like substance satisfying the following conditions (1) to (5) (1) Starch content of 75% by mass or more (2) Amylose content of 5% by mass or more of low-molecular-weight starch 3% by mass And 45% by mass or less, and the peak molecular weight of the low-molecular-weight starch is 3×10 3 or more and 5×10 4 or less (3) the degree of cold water swelling at 25° C. is 5 or more and 20 or less (4) a sieve with an opening of 0.5 mm Content of 20% by mass or more and 95% by mass or less on a sieve of 0.075 mm and (5) a content of 30% by mass or less on a sieve of 0.5 mm mesh (B) oxidized starch And a batter composition containing one or two selected from the group consisting of acid-treated starch and used by dispersing in water.
 当該バッター用組成物中の前記成分(A)の含有量が、当該バッター用組成物全体に対して3.0質量%以上55質量%以下であり、
 前記成分(A)の含有量に対する前記成分(B)の含有量が、質量比で、0.4以上8以下である、請求項1に記載のバッター用組成物。
The content of the component (A) in the batter composition is 3.0 mass% or more and 55 mass% or less with respect to the entire batter composition,
The batter composition according to claim 1, wherein the content of the component (B) with respect to the content of the component (A) is 0.4 or more and 8 or less in terms of mass ratio.
 前記成分(B)の原料澱粉の由来が、キャッサバおよびとうもろこしからなる群から選ばれる1種である、請求項1または2に記載のバッター用組成物。 The batter composition according to claim 1 or 2, wherein the origin of the raw material starch of the component (B) is one selected from the group consisting of cassava and corn.  前記成分(A)において、アミロース含量5質量%以上である前記澱粉が、アミロース含量が40質量%以上のコーンスターチである、請求項1乃至3いずれか1項に記載のバッター用組成物。 The composition for batter according to any one of claims 1 to 3, wherein in the component (A), the starch having an amylose content of 5% by mass or more is corn starch having an amylose content of 40% by mass or more.  前記成分(A)において、前記低分子化澱粉が、酸処理澱粉、酸化処理澱粉および酵素処理澱粉からなる群から選択される1種または2種以上である、請求項1乃至4いずれか1項に記載のバッター用組成物。 5. In the component (A), the low-molecular-weight starch is one kind or two or more kinds selected from the group consisting of an acid-treated starch, an oxidation-treated starch and an enzyme-treated starch. The composition for batter according to [4].  前記成分(A)が、前記低分子化澱粉以外の澱粉として、コーンスターチ、小麦澱粉、馬鈴薯澱粉、タピオカ澱粉およびこれらの架橋澱粉からなる群から選択される1種または2種以上を含有する、請求項1乃至5いずれか1項に記載のバッター用組成物。 The component (A) contains, as a starch other than the low-molecular-weight starch, one or more selected from the group consisting of corn starch, wheat starch, potato starch, tapioca starch, and cross-linked starch thereof. Item 11. A batter composition according to any one of items 1 to 5.  成分(C)としてリン酸架橋タピオカ澱粉をさらに含む、請求項1乃至6いずれか1項に記載のバッター用組成物。 The batter composition according to any one of claims 1 to 6, further comprising phosphoric acid-crosslinked tapioca starch as the component (C).  前記成分(A)の含有量に対する前記成分(C)の含有量が、質量比で、0.5以上10以下である、請求項7に記載のバッター用組成物。 The batter composition according to claim 7, wherein the content of the component (C) with respect to the content of the component (A) is 0.5 or more and 10 or less in mass ratio.  前記バッターが、唐揚げ、天ぷらおよびフリッターからなる群から選択される食品のバッターである、請求項1乃至8いずれか1項に記載のバッター用組成物。 The batter composition according to any one of claims 1 to 8, wherein the batter is a food batter selected from the group consisting of fried chicken, tempura and fritters.  バッターの中の粉体原料として、以下の成分(A)および成分(B)を含み、
 前記成分(A)の含有量に対する前記成分(B)の含有量が、質量比で、0.4以上8以下であり、
 当該バッターが以下の成分(C)をさらに含むとき、前記成分(A)の含有量に対する前記成分(C)の含有量が、質量比で、0.5以上10以下であり、
 前記成分(A)および前記成分(B)の合計量、または、当該バッターが前記成分(C)をさらに含むとき前記成分(A)、前記成分(B)および前記成分(C)の合計量が、前記粉体原料全体に対して20質量%以上100質量%以下である、バッター。
 (A)以下の条件(1)~(5)を満たす澱粉粉状物
  (1)澱粉含量が75質量%以上
  (2)アミロース含量5質量%以上である澱粉の低分子化澱粉を3質量%以上45質量%以下含み、前記低分子化澱粉のピーク分子量が3×103以上5×104以下
  (3)25℃における冷水膨潤度が5以上20以下
  (4)目開き0.5mmの篩の篩下かつ0.075mmの篩の篩上の含有量が20質量%以上95質量%以下
  (5)目開き0.5mmの篩の篩上の含有量が30質量%以下
 (B)酸化澱粉および酸処理澱粉からなる群から選択される1種または2種
 (C)リン酸架橋タピオカ澱粉
The powder raw material in the batter contains the following component (A) and component (B),
The content of the component (B) with respect to the content of the component (A) is 0.4 or more and 8 or less in mass ratio,
When the batter further contains the following component (C), the content of the component (C) with respect to the content of the component (A) is 0.5 or more and 10 or less in mass ratio,
The total amount of the component (A) and the component (B), or the total amount of the component (A), the component (B) and the component (C) when the batter further includes the component (C). A batter containing 20% by mass or more and 100% by mass or less of the entire powder raw material.
(A) Starch-like substance satisfying the following conditions (1) to (5) (1) Starch content of 75% by mass or more (2) Amylose content of 5% by mass or more of low-molecular-weight starch 3% by mass And 45% by mass or less, and the peak molecular weight of the low-molecular-weight starch is 3×10 3 or more and 5×10 4 or less (3) the degree of cold water swelling at 25° C. is 5 or more and 20 or less (4) a sieve with an opening of 0.5 mm Content of 20% by mass or more and 95% by mass or less on a sieve of 0.075 mm and (5) a content of 30% by mass or less on a sieve of 0.5 mm mesh (B) oxidized starch Or two selected from the group consisting of acid-treated starch and (C) phosphoric acid-crosslinked tapioca starch
 前記粉体原料が小麦粉を前記粉体原料全体に対して5質量%以上59質量%以下含む、請求項10に記載のバッター。 The batter according to claim 10, wherein the powder raw material contains wheat flour in an amount of 5% by mass or more and 59% by mass or less with respect to the entire powder raw material.  当該バッター中の前記成分(A)、成分(B)および成分(C)の含有量の合計が、当該バッター全体に対して8質量%以上50質量%以下である、請求項10または11に記載のバッター。 The total of the content of the component (A), the component (B), and the component (C) in the batter is 8% by mass or more and 50% by mass or less with respect to the entire batter. Batter.  請求項10乃至12いずれか1項に記載のバッターを種物の外側に付着させる工程と、
 前記バッターが付着した前記種物を加熱調理して食品を得る工程と、
 を含む、食品の製造方法。
Adhering the batter according to any one of claims 10 to 12 to the outside of the seed,
A step of cooking the seeds to which the batter is attached to obtain food,
A method for producing a food product, comprising:
 食品を得る前記工程の後、前記食品を冷凍保存する工程をさらに含む、請求項13に記載の食品の製造方法。 The method for producing a food according to claim 13, further comprising a step of storing the food in a frozen state after the step of obtaining the food.  冷凍保存する前記工程の後、前記食品を加熱解凍する工程をさらに含む、請求項14に記載の食品の製造方法。 The method for producing a food according to claim 14, further comprising a step of heating and thawing the food after the step of freezing and storing.  請求項10乃至12いずれか1項に記載のバッターを用いる、食品の外観の劣化を抑制する方法。 A method for suppressing the deterioration of the appearance of food, which uses the batter according to any one of claims 10 to 12.  請求項10乃至12いずれか1項に記載のバッターを用いる、食品の食感の劣化を抑制する方法。 A method for suppressing the deterioration of food texture using the batter according to any one of claims 10 to 12.
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JP7162547B2 (en) 2019-02-04 2022-10-28 日清食品ホールディングス株式会社 Method for producing dried tempura for instant food
JP2020124140A (en) * 2019-02-04 2020-08-20 日清食品ホールディングス株式会社 Method for producing instant food dry tempura
WO2021153285A1 (en) * 2020-01-31 2021-08-05 株式会社J-オイルミルズ Method for suppressing texture deterioration in bakery food
JPWO2021153285A1 (en) * 2020-01-31 2021-08-05
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JP2022035907A (en) * 2020-08-19 2022-03-04 株式会社J-オイルミルズ How to make fried chicken
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WO2023189466A1 (en) * 2022-03-28 2023-10-05 株式会社J-オイルミルズ Method for suppressing deterioration of flavor
WO2023233982A1 (en) * 2022-05-31 2023-12-07 株式会社J-オイルミルズ Frying oil stain inhibitor
JP2024122917A (en) * 2023-02-28 2024-09-09 マルハニチロ株式会社 frozen food

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