WO2020002189A1 - Active substance combinations - Google Patents

Abstract

The invention relates to active substance combinations that contain known compounds of formula (I) and one or more other active agents and are suitable for controlling animal pests.

Description

 drug combinations

The present application relates to mixtures of compounds of the formula (I) below with at least one further active ingredient or product which is preferably an insecticide or an acaricide or a nematicide or a fungicide, an antimicrobial compound or a biological crop protection agent. These mixtures (combinations of active ingredients) are suitable for controlling animal and microbial pests and as plant strengthening agents.

Compounds of the formula (I) and processes for their preparation are known from WO 2017/005673 A1 and the European patent application with the application number 17204401.8, where their use for controlling animal pests is also described. However, the effectiveness and / or breadth of activity and / or the plant tolerance of this compound, in particular with respect to crop plants, is not always sufficient.

It has now been found that active substance combinations (synonymous with “active substance combinations” in the present application are the terms “active substance mixtures” and “mixtures”) containing a compound of the formula (I) and one or more active substances or products from the groups described below are synergistically effective and are suitable for controlling animal and microbial pests and as plant strengthening agents.

The present invention thus relates to active compound combinations comprising a compound of the formula (I)

wherein a) A ¹ and A ² each represent CH and

R is a radical from the series H, F ₂ HC, F ₂ CIC, H ₃ CF ₂ C, F ₃ C, Br, H ₃ C, F and CI, or b) A ^{1 is} N and A ^{2 is} CH stands and

R is F ₃ C or c) A ^{1 is} CH and A ^{2 is} N and RF ₃ C stands, and one or more active ingredients or products from the groups described below.

The compounds of the formula (I) are therefore the compounds No. 1 to No. 11 listed in the following tables.

It has further been found that active compound combinations comprising a compound of the formula (I) and one or more active compounds or products from the groups described below are synergistically active and are suitable for controlling animal and microbial pests and as plant strengthening agents.

The mixtures according to the invention are preferably suitable for controlling animal and microbial pests.

 The mixtures according to the invention are particularly preferably suitable for controlling animal pests.

The mixtures according to the invention are furthermore particularly preferably suitable for controlling microbial pests.

 The mixtures according to the invention are particularly preferably also suitable as plant strengthening agents.

In one embodiment, the active compound combinations according to the invention contain, in addition to Compound of formula (I) one or more mixing partners from the groups described below.

The active ingredients mentioned here with their "common name" are known and described, for example, in the pesticide manual ("The Pesticide Manual" 14th Ed., British Crop Protection Council 2006) or can be researched on the Internet (e.g. http://www.alanwood.net/pesticides) ).

It is also known that the active substances mentioned can be used alone or in combination with other active substances for controlling animal pests. The combination of tioxazafen and flupyradifurone can, if appropriate also in combination with other active ingredients, be used successfully to control nematodes, insects and other animal pests.

If the short form of the “common name” of an active ingredient is used in the description, all common derivatives, such as the esters and salts, and isomers, in particular optical isomers, are thus included, in particular the commercially available form or forms. If the “common name” denotes an ester or salt, this also includes all other common derivatives such as other esters and salts, which include free acids and neutral compounds, and isomers, in particular optical isomers, in particular the commercially available form or forms. The chemical compound names given denote at least one of the compounds included in the “common name”, often a preferred compound.

(1) Acetylcholinesterase (AChE) inhibitors such as carbamates, e.g. Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, lsoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Xmarbarboxam, Carboxulfate, Trimoxamatex, Carboxane Xylylcarb or organophosphate, e.g. Acephate, Azamethiphos, Azinphos-ethyl, Azinphos-methyl, Cadusafos, Chlorethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos, Chlorpyrifos-methyl, Coumaphos, Cyanophos, Demeton-S-methyl, Diazinon, Dichlorvos / DDVP, Dimicosophonos, Dimicosophonos, Dimicosophos EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazate, Heptenophos, lmicyafos, lsofenphos, lsopropyl 0- (methoxyaminothio-phosphoryl) salicylate, lsoxathion, Malathion, Mecarbam, Methamidophosevophophos, Methidatho, Ominophosate, Methidathos, Methidathos, Methidathos, Methidathos, Methidathos, Methidathos, Methidosphonate Oxydemeton-methyl, Parathion, Parathion-methyl, Phenthoate, Phorate, Phosalone, Phosmet, Phosphamidon, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfachomosos, Temphos Triazophos, Triclorfon and Vamidothion.

(2) GABA-controlled chloride channel antagonists, such as, for example, cyclodiene organochlorins, for example chlordanes and endosulfan or phenylpyrazoles (fiproles), for example ethiprols and fipronil. (3) Sodium channel modulators / voltage-dependent sodium channel blockers, such as pyrethroids, for example acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin , Cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(lRhr) -transin [(lRhr) -transin (EZ) - (lR) -isomers), Esfenvalerate, Etofenprox, Fenpropathrin, Fenvalerate, Flucythrinate, Flumethrin, tau-Fluvalinate, Halfenprox, Imiprothrin, Kadethrin, Momfluorothrin, Permethrin, Phenothrin [(lR), Trans-ishrin-Trans-ishrin Pyrethrins (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethrin, tetramethrin [(IR) isomers)], tralomethrin and transfluthrin or DDT or methoxychlor.

(4) Nicotinic Acetylcholine Receptor (nAChR) agonists such as neonicotinoids e.g. Acetamiprid, Dinotefuran, Imidacloprid, Nitenpyram, Thiacloprid and Thiamethoxam or Nicotine or Sulfoxaflor or Flupyradifurone.

(5) Nicotinergic acetylcholine receptor (nAChR) allosteric activators such as spinosins e.g. Spinetoram and Spinosad.

(6) chloride channel activators such as avermectine / milbemycine e.g. Abamectin, Emamectin benzoate, Lepimectin and Milbemectin.

(7) Juvenile hormone imitators, such as juvenile hormone analogs, e.g. Hydroprene, Kinoprene and Methoprene or Fenoxycarb or Pyriproxyfen.

(8) Active substances with unknown or non-specific mechanisms of action, such as alkyl halides, e.g. Methyl bromide and other alkyl halides; or chloropicrin or sulfuryl fluoride or borax or Brechweinstein.

(9) Selective feeding inhibitors, e.g. Pymetrozine or Flonicamid.

(10) mite growth inhibitors, e.g. Clofentezine, hexythiazox and diflovidazine or etoxazole.

(11) Microbial disruptors of the insect intestinal membrane, e.g. Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and BT plant proteins: CrylAb, CrylAc, CrylFa, Cry2Ab, Cry3Ab, my3Ab, mC3Ab.

(12) Inhibitors of oxidative phosphorylation, ATP disruptors such as diafenthiuron or organotin compounds such as azocyclotin, cyhexatin and fenbutatin oxide or propargite or tetradifone. (13) Decouplers of oxidative phosphorylation by breaking the H proton gradient, such as chlorfenapyr, DNOC and sulfluramide.

(14) Nicotinic acetylcholine receptor antagonists such as bensultap, cartap hydrochloride, thiocyclam and thiosultap sodium.

(15) Inhibitors of chitin biosynthesis, type 0, such as, for example, bistrifluron, chlorofluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, fufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

(16) Chitin biosynthesis inhibitors, type 1, such as buprofezin.

(17) Molting agents, dipteran, such as cyromazine.

(18) Ecdysone receptor agonists such as chromafenozide, halofenozide, methoxyfenozide and tebufenozide.

(19) Octopaminergic agonists such as Amitraz.

(20) Complex III electron transport inhibitors, such as hydramethylnon or acequinocyl or fluacrypyrim.

(21) Complex I electron transport inhibitors, e.g. METI acaricides, e.g. Fenazaquin, Fenpyro ximate, Pyrimidifen, Pyridaben, Tebufenpyrad and Tolfenpyrad or Rotenone (Derris).

(22) Voltage-dependent sodium channel blockers, e.g. Indoxacarb or metaflumizone.

(23) Inhibitors of acetyl-CoA carboxylase, such as tetronic and tetramic acid derivatives, e.g. Spirobudiclofen, Spirodiclofen, Spiromesifen and Spirotetramat.

(24) Complex IV electron transport inhibitors such as phosphines, e.g. Aluminum phosphide, calcium phosphide, phosphine and zinc phosphide or cyanide.

(25) Complex II electron transport inhibitors, such as cyenopyrafen and cyflumetofen.

(28) Ryanodine receptor effectors such as diamides, e.g. chlorantraniliprole,

Cyantraniliprole, Flubendiamide and Tetrachloroantraniliprole.

Further active ingredients, such as, for example, afidopyropen, afoxolaner, azadirachtin, benclothiaz, benzoximate, bifenazate, broflanilide, bromopropylate, quinomethionate, cryolite, cyclaniliprole, cycloxaprid, cyhalodiamide dicloromezotiaz, dicofol, diflovidufen, flifulfonazine, flifulfonazine, flofulfonazine, flofulfonazine, flofulfonazine, flofulfonazine, flofulfonazine, flofulfone, flofulfone Fluralaner, Fluxametamide, Fufenozide, guadipyr, heptafluthrin, imidaclothiz, iprodione, lotilaner, meperfluthrin, oxazosulfyl, paichongding, pyflubumide, pyridalyl, pyrifluquinazone, pyriminostrobin, sarolaner, spiropidione, tetramethylfluthrimole, tetranilimlriphenol, tetranilimlriphenol, tetranilimlriphenol, tetraniloxiprole, tetranilimlriphenol, tetraniloxyrlole, and the following compounds: l- {2-fluoro-4-methyl-5 - [(2,2,2-trifluoroethyl) sulfinyl] phenyl} -3- (trifluoromethyl) -lH-l, 2,4-triazole-5- amine (known from

W02006 / 043635), {r - [(2E) -3- (4-chlorophenyl) prop-2-en-l-yl] -5-fluororspiro [indole-3,4 ^, -piperidine] -l (2H) - yl} (2-chloropyridin-4-yl) methanone (known from W02003 / 106457), 2-chloro-N- [2- {l - [(2E) -3- (4-chlorophenyl) prop-2-en- 1 -yl] piperidin-4-yl} -4- (trifluoromethyl) phenyl] isonicotinamide (known from WO2006 / 003494), 3- (2,5-dimethylphenyl) -4-hydroxy-8-methoxy-l, 8-diazaspiro [4.5] dec-3-en-2-one (known from W02009 / 049851), 3- (2,5-dimethylphenyl) -8-methoxy-2-oxo-l, 8-diazaspiro [4.5] dec-3- en-

4-yl-ethyl carbonate (known from W02009 / 049851), 4- (but-2-in-l-yloxy) -6- (3,5-dimethylpiperidin-l-yl) -

5-fluoropyrimidine (known from W02004 / 099160), 4- (but-2-in-1-yloxy) -6- (3-chlorophenyl) pyrimidine (known from W02003 / 076415), PF1364 (CAS-Reg.No. 1204776 -60-2), methyl-2- [2 - ({[3-bromo-l- (3-chloropyridin-2-yl) -lH-pyrazol-5-yl] carbonyl} amino) -5-chloro-3 -methylbenzoyl] -2- methylhydrazine carboxylate (known from WO2005 / 085216), methyl-2- [2 - ({[3-bromo-l- (3-chloropyridin-2-yl) -lH-pyrazol-5-yl] carbonyl } amino) -5-cyan-3-methylbenzoyl] -2-ethylhydrazine carboxylate (known from W02005 / 085216), methyl 2- [2 - ({[3-bromo-l- (3-chloropyridin-2-yl) - 1H-pyrazol-5-yl] carbonyl} amino) -5-cyan-3-methylbenzoyl] -2-methylhydrazine carboxylate (known from WO2005 / 085216), methyl 2- [3,5-dibromo-2- ({[3 -bromo- 1 - (3-chloropyridin-2-yl) - 1 H-pyrazol-5-yl] carbonyl} amino) benzoyl] -2- ethylhydrazine carboxylate (known from WO2005 / 085216), N- [2- (5- amino-l, 3,4-thiadiazol-2-yl) -4-chloro-

6-methylphenyl] -3-bromo-1 - (3-chloropyridin-2-yl) - 1H-pyrazole-5-carboxamide (known from

CN102057925), 4- [5- (3,5-dichlorophenyl) -5- (trifluoromethyl) -4,5-dihydro-l, 2-oxazol-3-yl] -2-methyl-N- (l-oxidothietane 3-yl) benzamide (known from W02009 / 080250), N - [(2E) -l - [(6-chloropyridin-3-yl) methyl] pyridin-2 (1H) -ylidene] -2,2,2- trifluoroacetamide (known from WO2012 / 029672), l - [(2-chloro-1,3-thiazol-5-yl) methyl] -4-oxo-3-phenyl-4H-pyrido [1,2-a] pyrimidine- l-ium-2-olate (known from WO2009 / 099929), l - [(6-chloropyridin-3-yl) methyl] -4-oxo-3-phenyl-4H-pyrido [l, 2-a] pyrimidine- l-ium-2-olate (known from WO2009 / 099929), 4- (3- {2,6-dichloro-4 - [(3,3-dichloroprop-2-en-l-yl) oxy] phenoxy} propoxy ) -2-methoxy-6- (trifluoromethyl) pyrimidine (known from CN101337940), N- [2- (tert-butylcarbamoyl) -4-chloro-6-methylphenyl] - 1 - (3-chloropyridin-2-yl) - 3- (fluoromethoxy) - lH-pyrazole-5-carboxamide (known from WO2008 / 134969), butyl- [2- (2,4-dichlorophenyl) -3-oxo-4-oxaspiro [4.5] dec-l- en- l-yl] carbonate (known from CN 102060818), 3E) -3- [l - [(6-chloro-3-pyridyl) methyl] -2-pyridylidene] - l, l, l-trifluoropropane-2 -on (known from WO2013 / 1 44213), N- (methylsulfonyl) -6- [2- (pyridin-3-yl) -l, 3-thiazol-5-yl] pyridin-2-carboxamide (known from W02012 / 000896), N- [3- (Benzylcarbamoyl) -4-chlorophenyl] -l-methyl-3- (pentafluoroethyl) -4- (trifluoromethyl) -lH-pyrazole-5-carboxamide (known from W02010 / 051926), 5-bromo-4-chloro-N- [4-chloro-2-methyl-6- (methylcarbamoyl) phenyl] -2- (3-chloro-2-pyridyl) pyrazole-3-carboxamide (known from CN103232431), tioxazafen, 4- [5- (3.5 -Dichlorophenyl) -4,5-dihydro-5- (trifluoromethyl) -3-isoxazolyl] -2-methyl- / V- (cA-l-oxido-3-thietanyl) benzamide, 4- [5- (3, 5 l iiclil or pliciiy I) -4.5 -di liyclro-5 - (t ri 11 uornict liy I) -3-i soxazoly I | -2-methyl- / V - (// vmv- 1 -oxido-3- thictanyl) - benzamide and 4- 1 (5th S ') - 5- (3,5 -dichlorophenyl) -4,5-dihydro-5- (tri iluomicdiyl) -3-i soxazoly I | -2-mctliy I - / V- (ci - 1 -oxido-3-t liictanyl) hciizami d (known from WO 2013050317 A1), V- | 3-chloro-1 - (3-pyridinyl) - 1 H-pyrazol-4-yl] - / V-ethyl-3 - [(3,3,3-trifluoropropyl) sulfmyl] propanamide, (+) - V- | 3 - ('hlor- 1 - (3-pyridinyl) - 1 H-pyra / .ol-4-yl | - W-ct liyl -3- [(3,3,3-tri GI uor propyl) sul l ^' i nyl | -propanamide and (-) - V- | 3 - ('hlor- 1 - (3-pyridinyl) - l / 7-pyrazol-4-yl] - / V-ethyl-3- [(3.3 , 3-trifluoropropyl) sulfinyl] propanamide (known from

WO 2013162715 A2, WO 2013162716 A2, US 20140213448 A1), 5 - [[(2 £) -3-chloro-2-propen-l-yl] am i iio | - 1 - [2,6-dicli lor-4-ftri 11 uoronict liyl) phcnyl | -4- 1 f tr i GI uormct liyl) sul l ^' i nyl | - 1 // - pyrazole-3-carbonitrile (known from CN 101337937 A), 3-bromo- / V- [4-chloro-2-methyl -6 - [(methylamino) thioxomethyl] phenyl] - 1- (3-chloro-2-pyridinyl) -l / 7-pyrazole-5-carboxamide, (Liudaibenjiaxuanan, known from CN 103109816 A); N- [4-chloro-2- [[(1, 1-dimethylethyl) amino] carbonyl] -6-methylphenyl] - 1 - (3-chloro-2-pyridinyl) -3- (fluoromethoxy) -l // - pyrazole-5-carboxamide (known from WO 2012034403 Al), V- | 2- (5-Aniino-1, 3,4-thiadiazol-2-yl) -4-chloro-6-methylphenyl] -3-bromo-1 - (3-chloro-2-pyridinyl) - l / 7-pyrazole -5-carboxamide (known from WO 2011085575 Al), 4- [3- [2,6-dichloro-4 - [(3,3-dichloro-2-propen-l-yl) oxy] phenoxy] propoxy] -2 -methoxy-6- (tifluoromethyl) pyrimidine (known from CN 101337940 A); (2 E) - and 2 (Z) -2- | 2- (4-cyanophenyl) -1- [3- (trifluoromethyl) phenyl] ethylidenes] - / V- [4- (difluoromethoxy) phenyl] hydrazine carboxamide (known from CN 101715774 A); 3- (2,2-l) icli loroct liciiyl) -2,2-di ctliy l-4- (I H-benzimidazol-2-yl) phenyl-cyclopropane-carboxylic acid ester (known from CN 103524422 A); (4a.V) -7-chloro-2,5-dihydro-2- [[(methoxycarbonyl) [4- [(trifluoromethyl) thio] phenyl] amino] carbonyl] -indeno [1, 2-e] [l, 3,4] oxadiazine-4a (3 //) - carboxylic acid methyl ester (known from CN 102391261 A).

In addition to a compound of the formula (I), the active compound combinations according to the invention preferably contain one or more mixing partners from the active compounds or products (preparations) listed below. This group of preferred mixed partners is referred to below as "Group A mixed partners":

Abamectin, acetamiprid, Afidopyropen, beta-cyfluthrin, bifenthrin, Broflanilide, carbofuran, chlorantraniliprole, Chlorphyriphos, cyantraniliprole, Cyclaniliprole, Cycloxaprid, cypermethrin, ethiprole, fipronil, Fluazaindolizine, flubendiamide, Flupyradifurone, imidacloprid, indoxacarb, lambda-cyhalothrin, methiocarb, Oxazosulfyl, Phorate, Spinetoram, Spinosad, Spiropidione, Sulfoxaflor, Tefluthrin, Tetraniliprole, Thiacloprid, Thiametoxam, Thiodicarb, Tioxazafen, Triflumuron.

Mixtures according to the invention comprising compound no. 1 and one or more mixing partners selected from group A are preferred.

Mixtures according to the invention containing compound no. 1 and exactly one (1) mixing partner selected from group A are also preferred.

Mixtures according to the invention are also preferred, comprising the compound No. 2 and one or several mixed partners selected from group A mixed partners.

Mixtures according to the invention containing compound No.2 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.

Mixtures according to the invention containing compound No.3 and one or more mixing partners selected from Group A are also preferred.

Mixtures according to the invention containing compound No.3 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.

Mixtures according to the invention containing compound no. 4 and one or more mixing partners selected from group A are also preferred.

Mixtures according to the invention containing compound No.4 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.

Mixtures according to the invention containing compound no. 5 and one or more mixing partners selected from group A are also preferred.

Mixtures according to the invention containing compound 5 and exactly one (1) mixing partner selected from group A are also preferred.

Mixtures according to the invention containing compound no. 6 and one or more mixing partners selected from group A are also preferred.

Mixtures according to the invention containing compound no. 6 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.

Mixtures according to the invention are also preferred which contain the compound No. 7 and one or more mixing partners selected from group A mixing partners.

Mixtures according to the invention are also preferred which contain the compound No. 7 and exactly one (1) mixing partner selected from Group A mixing partner.

Mixtures according to the invention containing compound no. 8 and one or more mixing partners selected from group A are also preferred.

Mixtures according to the invention containing compound 8 and exactly one (1) mixing partner selected from group A are also preferred.

Mixtures according to the invention are also preferred, comprising the compound No. 9 and one or several mixed partners selected from group A mixed partners.

Mixtures according to the invention containing compound No.9 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.

Mixtures according to the invention are also preferred, containing compound No.10 and one or more mixing partners selected from Group A mixing partners.

Mixtures according to the invention containing compound No.10 and exactly one (1) mixing partner selected from Group A are also preferred.

Mixtures according to the invention containing compound no. 11 and one or more mixing partners selected from group A are also preferred.

Mixtures according to the invention containing compound 11 and exactly one (1) mixing partner selected from Group A mixing partners are also preferred.

Surprisingly, the insecticidal and / or acaricidal and / or the plant-strengthening and / or yield-increasing effect of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. There is an unforeseeable real synergistic effect and not just an addition to the effect.

The active compound combinations according to the invention can also be mixed with a further active compound, for example an insecticide / acaricide / nematicide.

The active compound combinations according to the invention are suitable with good plant tolerance, favorable warm-blood toxicity and good environmental compatibility for protecting plants and plant organs, for increasing crop yields, improving the quality of the crop and for combating animal pests, in particular insects, arachnids, helminths, nematodes and mollusks , which occur in agriculture, horticulture, animal husbandry, in forests, in gardens and leisure facilities, in the protection of stored goods and materials as well as in the hygiene sector. They can preferably be used as pesticides. They are effective against normally sensitive and resistant species as well as against all or individual stages of development. The pests mentioned above include:

Pests from the Arthropoda strain, in particular from the Arachnida class, for example Acarus spp., Aceria kuko, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Amphitetranychus viennensis, Argas spp., Boophilus spp., Brevipalpus spp. , Bryobia graminum, Bryobia praetiosa, Centruroides spp., Chorioptes spp., Dermanyssus gallinae, Dermatophagoides pteronyssinus, Dermatophagoides farinae, Dermacentor spp., Eotetranychus spp., Epitrimerus pyri, Eutetranychus s. Eriophyes spp., Glycyphagus domesticus, Halotydeus destructor, Hemitarsonemus spp., Hyalomma spp., Ixodes spp., Latrodectus spp., Loxosceles spp., Metatetranychus spp., Neutrombicula autumnalis, Nuphersa spp., Oligonych., Oligonych spp., Panonychus spp., Phyllocoptruta oleivora, Platytetranychus multidigituli, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Steneotarsoneusususus,. Trombicula alfreddugesi, Vaejovis spp., Vasates lycopersici .; from the class of the Chilopoda, for example Geophilus spp., Scutigera spp .; from the order or class of the Collembola, for example Onychiurus armatus, Sminthurus viridis; from the class of the Diplopoda, for example, Blaniulus guttulatus; from the class of the Insecta, for example from the order of the leaf odea, for example Blattella asahinai, Blattella germanica, Blatta orientalis, Leucophaea maderae (Rhypaobia maderae) ,, Panchlora spp., Parcoblatta spp., Periplaneta spp., Supella longipalpa, Loboptera decipiens, Neombifolia , Pycnoscelus surinamensis; from the order of the Coleoptera, for example Acalymma vittatum, Acanthoscelides obtectus, Adoretus spp., Aethina tumida, Agelastica alni, Agriotes spp., Alphitobius diaperinus, Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Anthrenus spp. , Apogonia spp., Atomaria spp., Attagenus spp., Baris caerulescens, Bruchidius obtectus, Bruchus spp., Cassida spp., Cerotoma trifurcata, Ceutorrhynchus spp., Chaetocnema spp., Cleonus mendicus, Conoderus spp., Cosmopolites zealandica, Ctenicera spp., Curculio spp., Cryptolestes ferrugineus, Cryptorhynchus lapathi, Cylindrocopturus spp., Dermestes spp., Diabrotica spp., Dichocrocis spp., Dicladispa armigera, Diloboderus spp., Epicaerachna spp., Epicaerachna spp. , Faustinus spp., Gibbium psylloides, Gnathocerus cornutus, Hellula undalis, Heteronychus arator, Heteronyx spp., Hylamorpha elegans, Hylotrupes bajulus, Hypera postica, Hypomeces squamosus, Hypothenemus spp., Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae, Lathridius spp., Lema spp., Leptinotarsa decemlineata, Leucoptera spp., Lissorhoptrus oryzophilus, Listronotus (= Hyperodes) spp., Lixus spp., Luperodes sppus, Super., Luperomorph. , Melanotus spp., Meligethes aeneus, Melolontha spp., Migdolus spp., Monochamus spp., Naupactus xanthographus, Necrobia spp., Neogalerucella spp., Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamynusisy. , Oulema melanopus, Oulema oryzae, Oxycetonia jucunda, Phaedon cochleariae, Phyllophaga spp., Phyllophaga helleri, Phyllotreta spp., Popillia japonica, Premnotrypes spp., Prostephanus truncatus, Psylliodes spp., Ptyllizobppis, Pt., Pt ., Rhynchophorus ferrugineus, Rhynchophorus palmarum, Sinoxylon perforans, Sitophilus spp., Sitophilus oryzae, Sphenophorus spp., Stegobium paniceum, Sternechus spp., Symphyletes spp., Tanymecus spp., Tenebrio molitor, Tenebrioides mauretanicus, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp .; from the order of Diptera, for example Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Asphondylia spp., Bactrocera spp., Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis spp., Ceratironomus spp., Ceratironom spp. Chrysomyia spp., Chrysops spp., Chrysozona pluvialis, Cochliomyia spp., Contarinia spp., Cordylobia anthropophaga, Cricotopus sylvestris, Culex spp., Culicoides spp., Culiseta spp., Cuterebra spp., Dacne olurae, Dasy ., Dermatobia hominis, Drosophila spp., Drosophila suzukii, Echinocnemus spp., Euleia heraclei, Fannia spp., Gasterophilus spp., Glossina spp., Haematopota spp., Hydrellia spp., Hydrellia griseola, Hylobya spp., Hippylia spp. Hypoderma spp., Liriomyza spp., Lucilia spp., Lutzomyia spp., Mansonia spp., Musca spp., Oestrus spp., Oscinella frit, Paratanytarsus spp., Paralauterborniella subcincta, Pegomyia spp., Phlebotomus spp., Phorbia spp. Phormia spp., Piophila casei, Platyparea poeciloptera, Prodiplosis spp., P sila rosae Rhagoletis spp., Sarcophaga spp., Simulium spp., Stomoxys spp., Tabanus spp., Tetanops spp., Tipula spp., Hippoboscoidea (= Pupipara), Toxotrypana curvicauda; from the subordination of Heteroptera e.g. Aelia spp., Anasa tristis, Antestiopsis spp., Boisea spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Collaria spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris hewetti, Dysdercus spp., Euschistus spp., Eurydema spp., Eurygaster spp., Halyomorpha halys, Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., Leptocorisa varicornis, Leptogyllususidlossal spp., Macropes excavatus, Megacopta cribraria, Miridae, Monalonion atratum, Nezara spp., Nysius spp., Oebalus spp., Pentomidae, Piesma quadrata, Piezodorus spp., Psallus spp., Pseudacysta persea, Rhodnius sppis., Sahlbergella sing castanea, Scotinophora spp., Stephanitis nashi, Tibraca spp., Triatoma spp .; acaciaebaileyanae from the order of Hemiptera, for example Acizzia, Acizzia dodonaeae, Acizzia uncatoides, Acrida turrita, Acyrthosipon spp., Acrogonia spp., Aeneolamia spp., Agonoscena spp., Aleurocanthus spp., Aleyrodes proletella, Aleurolobus barodensis, Aleurothrixus floccosus, Allocaridara malayensis, Amrasca spp., Anuraphis cardui, Aonidiella spp., Aphanostigma piri, Aphis spp., Arboridia apicalis, Arytainilla spp., Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia tabaci, Blastopsyliscaaleogalucalogalucalogalucalogalucalogalucalogalucas, Brastopsyllacaalogalucalogalucalogalucalogalucas, Brastopsyllacaoglucalogalucalogalucas, Brastopsyllacaalogalucalogalucas, Brastopsyllacaoglucalogalucalogalucas, helichrysi, Brachycolus spp., Brevicoryne brassicae, Cacopsylla spp., Calligypona marginata, Capulinia spp., Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefoliisisisidomisis, Chrion Chondaspumisis, Chionaspondisis, Chrion Chondaspidis Chrysomphalus ficus, Cicadulina mbila, Coccomytilus half, Coccus spp., Cryptomyzus ribis, Cryptoneossa spp., Cten arytaina spp., Dalbulus spp., Dialeurodes chittendeni, Dialeurodes citri, Diaphorina citri, Diaspis spp., Diuraphis spp., Drosicha spp., Dysaphis spp., Dysmicoccus spp., Empoasca spp., Eriosoma spp., Erythroneura spp., Eucalyptolyma spp., Euphyllura spp., Euscelis bilobatus, Ferrisia spp., Fiorinia spp., Furcaspis oceanica, Geococcus coffeae, Glycaspis spp., Heteropsylla cubana, Heteropsylla spinulosa, Homaloduscaal ., Idiocerus spp., Idioscopus spp., Faodelphax striatellus, Fecanium spp., Fepidosaphes spp., Fipaphis erysimi, Fopholeucaspis japonica, Fycorma delicatula, Macrosiphum spp., Macrosteies facifrons, Metanaraphiscal , Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Neomaskellia spp., Nephotettix spp., Nettigoniclla spectra, Nilaparvata lugens, Oncometopia spp., Orthezia praelongis, Pachia parisatrab ., Parlatoria spp., Pemphigus spp., Peregrinus maidis, Perkinsiella spp., Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis aspidistrae, Planococcus spp., Prosopidopsylla flava, Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psyllopsis spp., Psylla spp., Pteromalus spp., Pulvinaria spp., Pyrilla spp., Quadraspocidiotus spp. Rhopalosiphum spp., Saissetia spp., Scaphoideus titanus, Schizaphis graminum, Selenaspidus articulatus, Sitobion avenae, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictocephala festina, Siphoninall Tileppa, sappharappa, sappharappa, saphata sara. , Toxoptera spp., Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii, Zygina spp .; from the order of Hymenoptera, for example Acromyrmex spp., Athalia spp., Atta spp., Camponotus spp., Dolichovespula spp., Diprion spp., Hoplocampa spp., Fasius spp., Finepithema (Iridiomyrmex) humile, Monomorium pharaonis, Paratrechina spp. , Paravespula spp., Plagiolepis spp., Sirex spp., Solenopsis invicta, Tapinoma spp., Technomyrmex albipes, Urocerus spp., Vespa spp., Wasmannia auropunctata, Xeris spp .; from the order of the Isopoda, for example Armadillidium vulgare, Oniscus asellus, Porcellio scaber; from the order of the Isoptera, for example Coptotermes spp., Cornitermes cumulans, Cryptotermes spp., Incisitermes spp., Kalotermes spp., Microtermes obesi, Nasutitermes spp., Odontotermes spp., Porotermes spp., Reticulitermes spp .; from the order of Fepidoptera, for example Achroia grisella, Acronicta major, Adoxophyes spp., Aedia leucomelas, Agrotis spp., Alabama spp., Amyelois transitella, Anarsia spp., Anticarsia spp., Argyroploce spp., Autographa spp., Barathraacnaicae atra, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius, Busseola spp., Cacoecia spp., Caloptilia theivora, Capua reticulana, Carpocapsa pomonella, Carposina niponensis, Cheimatobia brumata, Chilo spp., Choreutisysiaiasia , Cnaphalocerus spp., Cnaphalocrocis medinalis, Cnephasia spp., Conopomorpha spp., Conotrachelus spp., Copitarsia spp., Cydia spp., Dalaca noctuides, Diaphania spp., Diatraea saccharalis, Diparopsis spp., Ecariasolop, Elasmopalpus lignosellus, Eldana saccharina, Ephestia spp., Epinotia spp., Epiphyas postvittana, Erannis spp., Schwieroviella musculana, Etiella spp., Eudocima spp., Eulia spp., Eupoecilia ambiguella, Euprouxis spp. , Galleria mellonella, Gracillaria spp., Grapholitha spp., Hedylepta spp., Helicoverpa spp., Heliothis spp., Hofmannophila pseudospretella, Homoeosoma spp., Homona spp., Hyponomeuta padella, Kakivoria flavofasciata, Lampidesgppia, Laphy spp., Laph molesta, Leucinodes orbonalis, Leucoptera spp., Lithocolletis spp., Lithophane antennata, Lobesia spp., Loxagrotis albicosta, Lymantria spp., Lyonetia spp., Malacosoma neustria, Maruca spp., Maruca testulalis, Manisitis spp. , Monopis obviella, Mythimna separata, Nemapogon cloacellus, Nymphula spp., Oiketicus spp., Omphisa spp., Operophtera spp., Oria spp., Orthaga spp., Ostrinia spp., Panolis flammea, Parnara spp., Pectinopileucopter, spp., Phthorimaea s pp., Phyllocnistis citrella, Phyllonorycter spp., Pieris spp., Platynota stultana, Plodia interpunctella, Plusia spp., Plutella xylostella, Prays spp., Prodenia spp., Protoparce spp., Pseudaletia spp., Pseudalusia pseudaletia unopluncia nubilalis, Rachiplusia nu, Schoenobius spp., Scirpophaga spp., Scirpophaga innotata, Scotia segetum, Sesamia spp., Sesamia inferens, Sparganothis spp., Spodoptera spp., Spodoptera praefica, Stathmopodaxpp., Stenomaellapp., Stenomaellapp., Stenomaellapp ., Tecia solanivora, Thaumetopoea spp., Thermesia gemmatalis, Tinea cloacella, Tinea pellionella, Tineola bisselliella, Tortrix spp., Trichophaga tapetzella, Trichoplusia spp., Tryporyza incertulas, Tuta absoluta, Virachola spp .; from the order of the Orthoptera or Saltatoria, for example Acheta domesticus, Dichroplus spp., Gryllotalpa spp., Hieroglyphus spp., Locusta spp., Melanoplus spp., Paratlanticus ussuriensis, Schistocerca gregaria; from the order of the Phthiraptera, for example Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Phylloxera vastatrix, Phtirus pubis, Trichodectes spp .; from the order of Psocoptera, for example Lepinotus spp., Liposcelis spp .; from the order of the Siphonaptera, for example Ceratophyllus spp., Ctenocephalides spp., Pulex irritans, Tunga penetrans, Xenopsylla cheopsis; , Chaetanaphothrips leeuweni from the order of Thysanoptera Anaphothrips obscurus, for example, Baliothrips biformis, Drepanothrips reuteri, Enneothrips flavens, Frankliniella spp., Haplothrips spp., Heliothrips spp., Hercinothrips femoralis, spp Rhipiphorothrips cruentatus, Scirtothrips., Taeniothrips spp cardamomi, Thrips .; from the order of the Zygentoma (= Thysanura), e.g. B. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus, Thermobia domestica; from the class of the Symphyla, for example Scutigerella spp .; Pests from the Mollusca strain, in particular from the Bivalvia class, for example Dreissena spp., And from the Gastropoda class, for example Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea spp., Succinea spp .;

Animal parasites from the strains of the Plathelminthes and Nematoda, e.g. Aelurostrongylus spp., Amidostomum spp., Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Angiostrongylus spp., Anisakis spp., Anoplocephala spp., Ascarid sppia. Brugpp, spp , Bunostomum spp., Capillaria spp., Chabertia spp., Clonorchis spp., Cooperia spp., Crenosoma spp., Cyathostoma spp., Dicrocoelium spp., Dictyocaulus filaria, Diphyllobothrium latum, Dipylidium spp., Draofilisulus, Dirofilaria spp., Dirofilaria spp. Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Eucoleus spp., Fasciola spp., Fascioloides spp., Fasciolopsis spp., Filaroides spp., Gongylonema spp., Gyrodactylus spp., Habronema spp., Haemonchus spp., Hymenolepis nana, Hyostrongulus spp., Litomosoides spp., Loa Loa, Metastrongylus spp., Metorchis spp., Mesocestoides spp., Moniezia spp., Muellerius spp., Necator spp., Nematodirus spp., Nppostronges omum spp., Ollulanus spp., Onchocerca volvulus, Opisthorchis spp., Oslerus spp.,, Ostertagia spp., Oxyuris spp., Paracapillaria spp., Parafilaria spp., Paragonimus spp., Paramphistomum spp., Parppop ., Passalurus spp., Protostrongylus spp., Schistosom spp., Setaria spp., Spirocerca spp., Stephanofilaria spp., Stephanurus spp., Strongyloides fuelleborni, Strongyloides stercoralis, Strongylus spp., Syngamus spp., Taenia sagiumata, Taenia Teladorsagia spp., Thelazia spp., Toxascaris spp., Toxocara spp., Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichobilharzia spp., Trichostrongylus spp., Trichuri.

Plant pests from the Nematoda tribe, i.e. plant-parasitic nematodes, in particular Aglenchus spp., Anguina spp., Aphelenchoides spp., Belonolaimus spp., Bursaphelenchus spp., Cacopaurus spp., Criconemella spp., Criconemoides spp., Ditylenchus spp., Dolichodericotpp ., Hemicriconemoides spp., Hemicycliophora spp., Heterodera spp., Hoplolaimus spp., Longidorus spp., Meloidogyne spp., Meloinema spp., Nacobbus spp., Neotylenchus spp., Paralongidorus spp., Paraphelenchichus spp. Pratylenchus spp., Pseudohalenchus spp., Psilenchus spp., Punctodera spp., Quinisulcius spp., Radopholus spp., Rotylenchulus spp., Rotylenchus spp., Scutellonema spp., Subanguina spp., Trichodorus spp., Tylenchch ., Xiphinema spp .;

Furthermore, the order of Coccidia, for example Eimeria spp. fight. It has further been found that active compound combinations comprising compounds of the formula (I) and one or more fungicidal active compounds from the groups described below and / or one or more biological crop protection agents are synergistically active and are suitable for controlling animal and microbial pests and as plant strengthening agents.

The active ingredients specified here with their “Common Name” are known and described, for example, in the “Pesticide Manual” (16th edition of the British Crop Protection Council) or can be researched on the Internet (for example: http://www.alanwood.net/pesticides).

All of the above-mentioned mixing partners of classes (1) to (15) can, if they are capable of doing so on account of their functional groups, form salts with suitable bases or acids. All of the fungicidal mixture partners mentioned in classes (1) to (15) can optionally include tautomeric forms.

Examples of such fungicidal mixture partners are:

1) Inhibitors of ergosterol biosynthesis, for example (1,001) cyproconazole, (1,002) difenoconazole, (1,003) epoxiconazole, (1,004) fenhexamide, (1,005) fenpropidine, (1,006) fenpropimorph, (1,007) fenpyrazamine, (1,008) fluquinconazole, ( 1,009) flutriafol, (1,010) imazalil, (1,011) imazalil sulfate, (1,012) ipconazole, (1,013) metconazole, (1,014) myclobutanil, (1,015) paclobutrazole, (1,016) prochloraz, (1,017) propiconazole, (1,018) prothioconazole (1,019) pyrisoxazole, (1,020) spiroxamine, (1,021) tebuconazole, (1,022) tetraconazole, (1,023) triadimenol, (1,024) tridemorph, (1,025) triticonazole, (1,026) (IR, 2S, 5S) -5- (4th -Chlorobenzyl) -2- (chloromethyl) -2-methyl-l- (lH-l, 2,4-triazol-l-ylmethyl) cyclopentanol, (1,027) (1 S, 2R, 5R) -5- (4- Chlorobenzyl) -2- (chloromethyl) -2-methyl-l- (lH-1,2,4-triazol-l-ylmethyl) cyclopentanol, (1,028) (2R) -2- (l-chlorocyclopropyl) -4- [ (IR) -2, 2-dichlorocyclopropyl] - 1 - (1 H-1, 2,4-triazol-1-yl) butan-2-ol (1,029) (2R) -2- (1-chi orcy clopropyl ) -4- [(1 S) -2,2- dichlo rcyclopropyl] - 1 - (1H- 1, 2,4-triazol-1-yl) butan-2-ol, (1,030) (2R) -2- [4- (4-chlorophenoxy) -2-

(trifluoromethyl) phenyl] - 1 - (1 H- 1, 2,4-triazol-1-yl) propan-2-ol, (1,031) (2S) -2- (1-chloro orcy clopropyl) -4-

[(lR) -2,2-dichlorocyclopropyl] - 1 - (1 H-1, 2,4-triazol-1-yl) butan-2-ol, (1,032) (2S) -2- (1-chlorocyclopropyl) - 4 - [(1 S) -2,2-dichlorocyclopropyl] - 1 - (1 H- 1, 2,4-triazol-1-yl) butan-2-ol, (1,033) (2S) -2- [ 4- (4-

Chlorophenoxy) -2- (trifluoromethyl) phenyl] - 1 - (1 H-1, 2,4-triazol-1-yl) propan-2-ol, (1,034) (R) - [3- (4-chloro 2-fluorophenyl) -5- (2,4-difluorophenyl) -1, 2-oxazol-4-yl] (pyridin-3-yl) methanol, (1,035) (S) - [3- (4-chloro-2 - fluorophenyl) -5- (2,4-difluorophenyl) -1, 2-oxazol-4-yl] (pyridin-3-yl) methanol, (1,036) [3- (4-chloro-2-fluorophenyl) -5 - (2,4-difluorophenyl) - 1,2-oxazol-4-yl] (pyridin-3-yl) methanol, (1,037) 1 - ({(2R, 4S) -2- [2- chloro-4- (4-chlorophenoxy) phenyl] -4-methyl-1, 3-dioxolan-2-yl} methyl) - 1 H-1, 2,4-triazole, (1,038) 1 - ({(2S, 4S) -2 - [2-chloro-4- (4-chlorophenoxy) phenyl] -4-methyl-1, 3-dioxolan-2-yl} nictliyl) - 1 I I- 1, 2,4-triazole,

(1,039) 1 - {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} - 1 H-1, 2,4-triazol-5-yl-thiocyanate, (1,040) l- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -lH- 1,2.4-triazol-5-yl thiocyanate, (1,041) 1- {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl } - 1H-1, 2,4-triazol-5-yl-thiocyanate, (1,042) 2- [(2R, 4R, 5R) - 1 - (2,4-dichlorophenyl) -5-hydroxy-2,6 , 6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazol-3-thione, (1,043) 2 - [(2R, 4R, 5S) -l- (2,4 -

Dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazol-3-thione, (1,044) 2- [(2R, 4S , 5R) -l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazol-3-thione , (1,045) 2 - [(2R, 4S, 5S) -l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H- l, 2,4-triazol-3-thione, (1,046) 2 - [(2S, 4R, 5R) -l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane-4- yl] -2,4-dihydro-3H-l, 2,4-triazol-3-thione, (1,047) 2 - [(2S, 4R, 5S) -l- (2,4-

Dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H-l, 2,4-triazol-3-thione, (1,048) 2- [(2S, 4S , 5R) -l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptane-4-yl] -2,4-dihydro-3H-l, 2,4-triazol-

3-thione, (1,049) 2 - [(2S, 4S, 5S) -l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro -3H-l, 2,4-triazol-3-thione, (1,050) 2- [l- (2,4-dichlorophenyl) -5-hydroxy-2,6,6-trimethylheptan-4-yl] -2, 4-dihydro-3H-1, 2,4-triazol-3-thione, (1,051) 2- [2-chloro-4- (2,4-dichlorophenoxy) phenyl] -1 - (1 H-

1,2.4-triazol-1-yl) propan-2-ol, (1,052) 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1 - (1H-1, 2,4-triazol-1 - yl) butan-2-ol, (1,053) 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1 - (1 H-1, 2,4-triazol-1-yl) butane - 2-ol, (1,054) 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1 - (1 H-1, 2,4-triazol-1-yl) pentan-2-ol .

(1,055) 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1 - (1 H-1, 2,4-triazol-1-yl) propan-2-ol, (1,056) 2 - {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-l, 2,4-triazol-3-thione, ( 1,057) 2- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -2,4-dihydro-3H-

1,2.4-triazol-3-thione, (1,058) 2- {[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} - 2,4-dihydro-3H-l, 2,4-triazol-3-thione, (1,059) 5- (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1 - (1 H-1, 2 , 4-triazol-1-methyl) cyclopentanol, (1,060) 5 - (allylsulfany 1) - 1 - {[3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} - 1H- 1,2,4-triazole, (1,061) 5- (allylsulfanyl) - 1- {[rel (2R, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxirane 2-yl] methyl} - 1 H- 1, 2,4-triazole, (1,062) 5- (allylsulfanyl) - 1 -

{[rel (2R, 3S) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) oxiran-2-yl] methyl} -lH- 1,2,4-triazole, (1,063) N ' - (2,5-Dimethyl-4- {[3- (1,1,2,2-tetrafluoroethoxy) phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1,064) N '- (2,5 -Dimethyl-4- {[3- (2,2,2-trifluoroethoxy) phenyl] sulfanyl} phenyl) - N-ethyl-N-methylimidoformamide, (1,065) N '- (2,5-dimethyl-4- {[ 3- (2, 2,3,3-tetrafluoropropoxy) phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1,066) N '- (2,5-dimethyl-

4- {[3- (pentafluoroethoxy) phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamide, (1,067) N '- (2,5-

Dimethyl-4- {3 - [(1, 1, 2,2-tetrafluoroethyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1,068) N ^, - (2,5-dimethyl-4- { 3 - [(2,2,2-trifluoroethyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1,069) N '- (2,5-dimethyl-4- {3 - [(2, 2 , 3,3-tetrafluoropropyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1,070) N '- (2,5-dimethyl- 4- {3 - [(pentafluoroethyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamide, (1,071) N '- (2,5-dimethyl-4-phenoxyphenyl) -N-ethyl-N-methylimidoformamide, (1,072) N' - (4- {[3-

(Difluoromethoxy) phenyl] sulfanyl} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, (1,073) N'- (4- {3 - [(difluoromethyl) sulfanyl] phenoxy} -2,5-dimethylphenyl) -N-ethyl-N-methylimidoformamide, (1,074) N '- [5-bromo-6- (2,3-dihydro- 1H-inden-2-yloxy) -2-methylpyridin-3-yl] -N-ethyl-N-methylimidoformamide, (1,075) N'- {4- [(4,5-dichloro-1,3-thiazol-2 -yl) oxy] -2,5 -dimethylphenyl} -N-ethyl-N -methylimidoformamide, (1,076) N '- {5-bromo-6 - [(IR) -l- (3,5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (1,077) N '- {5-bromo-6 - [(IS) -l- (3,5-difluorophenyl) ethoxy] -2- methylpyridin-3-yl} -N-ethyl-N -methylimidoformamide, (1,078) N'- {5-bromo-6- [(cis-4-isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N- ethyl-N -methylimidoformamide, (1,079) N '- {5-

Bromo-6 - [(trans-4-isopropylcyclohexyl) oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (1,080) N'- {5-bromo-6- [1 - (3rd , 5-difluorophenyl) ethoxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamide, (1,081) mefentrifluconazole, (1,082) apple trifluconazole.

2) Respiratory chain inhibitors on complex I or II, for example (2,001) benzovindiflupyr, (2,002) bixafen, (2,003) boscalid, (2,004) carboxin, (2,006) flutolanil, (2,007) fluxapyroxad, (2,008) furametpyr, (2,009) isofetamide , (2,010) isopyrazam (anti-epimeric enantiomer 1R, 4S, 9S), (2,011) isopyrazam (anti-epimeric enantiomer 1S, 4R, 9R), (2,012) isopyrazam (anti-epimeric racemat 1RS, 4SR, 9SR), ( 2.013) isopyrazam (mixture of the syn-epimeric racemate 1RS, 4SR, 9RS and the anti-epimeric racemate 1RS, 4SR, 9SR), (2.014) isopyrazam (syn-epimeric enantiomer 1R, 4S, 9R), (2.015) isopyrazam (syn -epimeric enantiomer 1S, 4R, 9S), (2,016) isopyrazam (syn-epimeric racemat 1RS, 4SR, 9RS), (2,017) Penflufen, (2,018) penthiopyrad, (2,019) pydiflumetofen, (2,020) pyraziflumid, (2,021) sedaxanes , (2,022) l, 3-dimethyl-N- (l, l, 3-trimethyl-2,3-dihydro-lH-inden-4-yl) -lH-pyrazole-4-carboxamide, (2.023) 1,3 -Dimethyl-N- [(3R) - 1, 1, 3-trimethyl-2,3-dihydro-1H-inden-4-yl] - 1H-pyrazole-4-carboxamide, (2,024) 1, 3-dimethyl -N - [(3S) - 1, 1, 3-trimethyl-2,3-dihydro-1 H-inden-4-yl] - 1 H-pyrazole-4-carboxamide, (2,025) l-methyl-3- (trifluoromethyl) -N- [2 '- (trifluoromethyl) biphenyl-2-yl] -lH-pyrazole-4-carboxamide, (2,026) 2-fluoro-6- (trifluoromethyl) -N- (l, l, 3- trimethyl-2,3-dihydro-lH-inden-4-yl) benzamide, (2,027) 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethyl-2,3-dihydro-lH- inden-4-yl) - 1H-pyrazole-4-carboxamide, (2,028) 3- (difluoromethyl) -l-methyl-N - [(3R) -l, 1,3-trimethyl-2,3-dihydro-1H - inden-4-yl] -lH-pyrazol-4-carboxamide, (2,029) 3- (difluoromethyl) -l-methyl-N - [(3S) -l, 1,3-trimethyl-2,3-dihydro- 1 H-inden-4-yl] - 1 H-pyrazole-4-carboxamide, (2,030) 3- (difluoromethyl) -N- (7 -fluoro-1,1,3-trimethyl-2,3-dihydro-1H -inden-4-yl) - 1 -methyl-1H-pyrazole-4-carboxamide, (2.031) 3- (difluoromethyl) - N- [(3R) -7-fluoro-1, 1, 3-trimethyl-2, 3-dihydro-1H-inden-4-yl] -1-methyl-1H-pyrazole-4-carboxamide,

(2,032) 3- (Difluoromethyl) -N - [(3S) -7-fluoro-1, 1,3-trimethyl-2,3-dihydro-lH-inden-4-yl] - 1-methyl-1H-pyrazole -4-carboxamide, (2,033) 5,8-difluoro-N- [2- (2-fluoro-4- {[4- (trifluoromethyl) pyridin-2-yl] oxy} phenyl) ethyl] quinazolin-4-amine , (2,034) N- (2-cyclopentyl-5-fluorobenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-l-methyl-lH-pyrazole-4-carboxamide, (2.035) N- (2- tert-butyl-5-methylbenzyl) - N-cyclopropyl-3- (difluoromethyl) -5-fluoro-l-methyl-1H-pyrazole-4-carboxamide, (2,036) N- (2-tert-butylbenzyl) -N- cyclopropyl-3- (difluoromethyl) -5-fluoro-l-methyl-1H-pyrazole-4-carboxamide, (2,037) N- (5-chloro-2-ethylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5 -fluoro-l-methyl-lH-pyrazole-4-carboxamide, (2,038) N- (5-chloro-2-isopropylbenzyl) -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-l-methyl-lH-pyrazole-

4-carboxamide, (2,039) N - [(IR, 4S) -9- (dichloromethylene) -l, 2,3,4-tetrahydro-l, 4-methanonaphthalene-5-yl] -3- (difluoromethyl) -l -methyl-lH-pyrazole-4-carboxamide, (2,040) N - [(IS, 4R) -9- (dichloromethylene) - l, 2,3,4-tetrahydro-l, 4-methanonaphthalene-5-yl] - 3- (difluoromethyl) -l-methyl-1H-pyrazole-4-carboxamide, (2,041) N- [l- (2,4-dichlorophenyl) -l-methoxypropan-2-yl] -3- (difluoromethyl) -l -methyl-1H-pyrazole-4-carboxamide, (2,042) N- [2-chloro-6- (trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole -4-carboxamide, (2,043) N- [3-chloro-2-fluoro-6- (trifluoromethyl) benzyl] -N-cyclopropyl- 3- (difluoromethyl) -5 -fluoro-1-methyl-1 H-pyrazole- 4-carboxamide, (2,044) N- [5-chloro-2-

(trifluoromethyl) benzyl] -N-cyclopropyl-3- (difluoromethyl) -5-fluoro-l-methyl-lH-pyrazole-4-carboxamide, (2,045) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-l -methyl-N- [5-methyl-2- (trifluoromethyl) benzyl] -lH-pyrazole-4-carboxamide, (2,046) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-fluoro- 6-isopropylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (2,047) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (2-isopropyl-

5-methylbenzyl) -1-methyl-1H-pyrazole-4-carboxamide, (2,048) N-cyclopropyl-3- (difluoromethyl) -5-fluorine

N- (2-isopropylbenzyl) -l -methyl-1H-pyrazole-4-carbothioamide, (2,049) N-cyclopropyl-3-

(difluoromethyl) -5-fluoro-N- (2-isopropylbenzyl) -l-methyl-1H-pyrazole-4-carboxamide, (2,050) N-cyclopropyl-3- (difluoromethyl) -5-fluoro-N- (5- fluoro-2-isopropylbenzyl) -l -methyl-1H-pyrazole-4-carboxamide, (2,051) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-4,5-dimethylbenzyl) -5-fluorine 1-methyl-1H-pyrazole-4-carboxamide, (2,052) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-fluorobenzyl) -5-fluoro-1-methyl-1H-pyrazole-4 -carboxamide, (2,053) N-cyclopropyl-3- (difluoromethyl) -N- (2-ethyl-5-methylbenzyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2,054) N-cyclopropyl -N- (2-cyclopropyl-5-fluorobenzyl) -3- (difluoromethyl) -5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2,055) N-cyclopropyl-N- (2-cyclopropyl-5 -methylbenzyl) -3- (difluoromethyl) -5-fluoro-l-methyl-1H-pyrazole-4-carboxamide, (2,056) N-cyclopropyl-N- (2-cyclopropylbenzyl) -3- (difluoromethyl) -5-fluorine -l -methyl-1H-pyrazole-4-carboxamide.

3) Respiratory chain inhibitors on complex III, for example (3,001) ametoctradine, (3,002) amisulbromo, (3,003) azoxystrobin, (3,004) coumethoxystrobin, (3,005) coumoxystrobin, (3,006) cyazofamide, (3,007) dimoxystrobin, (3,007) (3,009) famoxadone, (3,010) fenamidon, (3,011) flufenoxystrobin, (3,012) fluoxastrobin, (3,013) kresoxim-methyl, (3,014) metominostrobin, (3,015) orysastrobin, (3,016) picoxystrobin, (3,017) pyraclostrobin, (3,018) Pyrametostrobin, (3.019) pyraoxystrobin, (3.020) trifloxystrobin (3.021) (2E) -2- {2 - [({[(IE) -l- (3- {[(E) -l-fluoro-2-pheny 1 vinyl] oxy} phenyl) ethylidene] amino} oxy) methyl] phenyl} -2- (methoxyimino) -N-methylacetamide, (3.022) (2E, 3Z) -5- {[l- (4-chlorophenyl) -lH- pyrazol-3-yl] oxy} -2- (methoxyimino) -N, 3-dimethylpent-3-enamide, (3.023) (2R) -2- {2- [(2,5-dimethylphenoxy) methyl] phenyl} - 2-methoxy-N-methylacetamide,

(3.024) (2S) -2- {2 - [(2,5-dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3.025)

(3S, 6S, 7R, 8R) -8-benzyl-3 - [({3 - [(isobutyryloxy) methoxy] -4-methoxypyridin-2-yl} carbonyl) amino] -6-methyl-4,9-dioxo -l, 5-dioxonan-7-yl-2-methylpropanoate, (3.026) 2- {2 - [(2,5- Dimethylphenoxy) methyl] phenyl} -2-methoxy-N-methylacetamide, (3,027) N- (3-ethyl-3,5,5-trimethylcyclohexyl) -3-formamido-2-hydroxybenzamide, (3,028) (2E, 3Z) -5- {[l- (4-Chloro-2-fluorophenyl) - 1H-pyrazol-3-yl] oxy} -2- (methoxyimino) -N, 3-dimethylpent-3-enamide, (3,029) methyl {5 - [3- (2,4-dimethylphenyl) - 1 11-pyrazol-1 -yl | -2-mctliylcncyl [carhaniatc.

4) inhibitors of mitosis and cell division, for example (4,001) carbendazim, (4,002) diethofencarb,

(4.003) ethaboxam, (4.004) fluopicolide, (4.005) pencycuron, (4.006) thiabendazole, (4.007) thiophanate methyl, (4.008) zoxamide,, (4.009) 3-chloro-4- (2,6-difluorophenyl) - 6-methyl-5-phenylpyridazine, (4,010) 3-chloro-5- (4-chlorophenyl) -4- (2,6-difluorophenyl) -6-methylpyridazine, (4,011) 3-chloro-5- (6-chloropyridine -3-yl) -6-methyl-4- (2,4,6-trifhiorphenyl) pyridazine, (4,012) 4- (2-bromo-4-fluorophenyl) -N- (2,6-difluorophenyl) -l, 3-dimethyl-1H-pyrazole-5-amine, (4.013) 4- (2-bromo-4-fluorophenyl) -N- (2-bromo-6-fluorophenyl) -l, 3-dimethyl-1H-pyrazole-5 -amine, (4.014) 4- (2-bromo-4-fluorophenyl) -N- (2-bromophenyl) -l, 3-dimethyl-lH-pyrazol-5-amine, (4.015) 4- (2-bromo- 4-fluorophenyl) -N- (2-chloro-6-fluorophenyl) -l, 3-dimethyl-1H-pyrazol-5-amine, (4.016) 4- (2-bromo-4-fluorophenyl) -N- (2nd - chlorophenyl) -l, 3-dimethyl-lH-pyrazol-5-amine, (4.017) 4- (2-bromo-4-fluorophenyl) -N- (2-fluorophenyl) - l, 3-dimethyl-lH-pyrazole -5-amine, (4.018) 4- (2-chloro-4-fluorophenyl) -N- (2,6-difluorophenyl) -l, 3-dimethyl-1H-pyrazole-5-amine, (4.019) 4- ( 2-chloro-4-fluorophenyl) - N- (2-chloro-6-fluorophenyl) -l, 3-dimethyl-1H-pyrazol-5-amine, (4,020) 4- (2-chloro-4-fluorophenyl) -N- (2-chlorophenyl) -l , 3-dimethyl-1H-pyrazol-5-amine, (4,021) 4- (2-chloro-4-fluorophenyl) -N- (2-fluorophenyl) -l, 3-dimethyl-1H-pyrazol-5-amine, (4.022) 4- (4-chlorophenyl) -5- (2,6-difluorophenyl) -3,6-dimethylpyridazine, (4.023) N- (2-bromo-6-fluorophenyl) -4- (2-chloro-4 -fluorophenyl) -1, 3-dimethyl-1H-pyrazole-5-amine, (4,024) N- (2-bromophenyl) -4- (2-chloro-4-fluorophenyl) -l, 3-dimethyl-1H-pyrazole -5-amine, (4,025) N- (4-chloro-2,6-difluorophenyl) -4- (2-chloro-4-fluorophenyl) - 1,3-dimethyl-1H-pyrazole-5-amine.

5) Compounds capable of multisite activity, for example (5.001) Bordeaux mixture, (5.002) captafol, (5.003) captan, (5.004) chlorothalonil, (5.005) copper hydroxide, (5.006) copper naphthenate, (5.007) copper oxide, (5.008) copper oxychloride , (5.009) copper (2 +) - sulfate, (5.010) dithianon, (5.011) dodine, (5.012) folpet, (5.013) mancozeb, (5.014) maneb, (5.015) metiram, (5.016) zinc metiram, (5.017) Copper oxyne, (5,018) propineb, (5,019) sulfur and sulfur preparations including calcium polysulfide, (5,020) thiram, (5,021) zineb, (5,022) ziram, (5,023) 6-ethyl-5,7-dioxo-6,7- dihydro-5H-pyrrolo [3 ', ^4,: 5,6] [l, 4] dithiino [2,3-c] [l, 2] thiazole-3-carbonitrile.

6) Compounds capable of triggering host defense, for example (6.001) acibenzolar-S-methyl, (6.002) isotianil, (6.003) probenazole, (6.004) tiadinil.

7) Inhibitors of amino acid and / or protein biosynthesis, for example (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline (7.005) pyrimethanil, (7.006) 3- (5-fluoro- 3,3,4,4-tetramethyl-3,4-dihydroisoquinoline-l-yl) quinoline. (8) inhibitors of ATP production, for example (8.001) silthiofam.

9) Inhibitors of cell wall synthesis, for example (9.001) benthiavalicarb, (9.002) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, (9.005) mandipropamide, (9.006) pyrimorph, (9.007) valifenalate, (9.008) (2E) -3 - (4-tert-butylphenyl) -3- (2-chloropyridin-4-yl) -l- (morpholin-4-yl) prop-2-en- 1 -one, (9.009) (2Z) -3- (4-tert-Butylphenyl) -3- (2-chloropyridin-4-yl) - 1 - (morpholin-4-yl) prop-2-en-1 -one.

10) Inhibitors of lipid and membrane synthesis, for example (10.001) propamocarb, (10.002) propamocarb hydrochloride, (10.003) tolclofos-methyl.

11) Inhibitors of melanin biosynthesis, for example (11,001) tricyclazole, (11,002) 2,2,2-trifluoroethyl- {3-nicthyl-1 - [(4-mct liy I heu zoy I) ani i no | hutan -2-y I [carbaniat.

12) Inhibitors of nucleic acid synthesis, for example (12.001) benalaxyl, (12.002) benalaxyl-M (kiralaxyl), (12.003) metalaxyl, (12.004) metalaxyl-M (mefenoxam).

13) Signal transduction inhibitors, for example (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazide, (13.005) quinoxyfen, (13.006) vinclozolin.

14) Compounds that can act as decouplers, for example (14.001) fluazinam, (14.002) meptyldinocap.

15) Other compounds, for example (15.001) abscisic acid, (15.002) benthiazole, (15.003)

Bethoxazin, (15.004) capsimycin, (15.005) carvone, (15.006) quinomethionate, (15.007) cufraneb, (15.008) cyflufenamid, (15.009) cymoxanil, (15.010) cyprosulfamide, (15.011) flutianil, (15.012) fosetyl aluminum, 15.013) fosetyl calcium, (15.014) fosetyl sodium, (15.015) methyl isothiocyanate, (15.016) metrafenone, (15.017) mildiomycin, (15.018) natamycin, (15.019) nickel dimethyldithiocarbamate, (15.020) nitrothal isopropyl, (15.020) Oxamocarb, (15.022)

Oxathiapiproline, (15.023) oxyfenthiine, (15.024) pentachlorophenol and salts, (15.025) phosphonic acid and its salts, (15.026) propamocarb-fosetylate, (15.027) pyriofenone (chlazafenone) (15.028) tebufloquin, (15.029) tifloft , (15.031) l- (4- {4 - [(5R) -5- (2,6-difluorophenyl) - 4,5-dihydro-l, 2-oxazol-3-yl] -l, 3-thiazole- 2-yl} piperidin-l-yl) -2- [5-methyl-3- (trifluoromethyl) -lH-pyrazol-l-yl] ethanone, (15.032) l- (4- {4 - [(5S) - 5- (2,6-difluorophenyl) -4,5-dihydro-l, 2-oxazol-3-yl] -l, 3-thiazol-2-yl} piperidin-l-yl) -2- [5-methyl -3- (trifluoromethyl) -lH-pyrazol-l-yl] ethanone, (15.033) 2- (6-

Benzylpyridin-2-yl) quinazoline, (15,034) 2,6-dimethyl-1H, 5H- [1,4] dithiino [2,3-c: 5,6-c '] dipyrrol-

1, 3,5,7 (2H, 6H) -tetron, (15,035) 2- [3,5-bis (difluoromethyl) - 1 H-pyrazol-1-yl] - 1 - [4- (4- {5 - [2- (prop-2-yn-1-yloxy) phenyl] -4,5 -dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl ] ethanone, (15,036) 2- [3,5-bis (difluoromethyl) - 1 H-pyrazol-1-yl] - 1 - [4- (4- {5- [2-chloro-6- (prop-2 -in-1 -yloxy) phenyl] -4,5 -dihydro-1,2-oxazol-3-yl] -1, 3-thiazol-2-yl) piperidin-1-yl] ethanone, (15,037) 2- [3,5-bis (difluoromethyl) -lH-pyrazol-l-yl] - 1 - [4- (4- {5- [2-fluoro-6- (prop-2-yn-1-yloxy) phenyl] -4,5 -dihydro- 1,2-oxazol-3-yl} -1,3-thiazol-2- yl) piperidin-l-yl] ethanone, (15.038) 2- [6- (3-fluoro-4-methoxyphenyl) -5-methylpyridin-2-yl] quinazoline, (15.039) 2- {(5R) -3- [2- (1 - {[3,5-bis (difluoromethyl) -1 H-pyrazol-1-yl] acetyl} piperidin-4-yl) - 1,3-thiazol-4-yl] -4,5- dihydro-l, 2-oxazol-5-yl} -3-chlorophenyl methanesulfonate, (15.040) 2 - {(5S) -3- [2- (l- {[3,5-

Bis (difluoromethyl) - 1 H-pyrazol-1-yl] acetyl} piperidin-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl methanesulfonate, (15,041) 2- {2 - [(7,8-difluoro-2-methylquinolin-3-yl) oxy] -6-fluorophenyl} propan-2-ol, (15.042) 2- {2 -Fluoro-6 - [(8-fluoro-2-methylquinolin-3-yl) oxy] phenyl} propan-2-ol, (15.043) 2- {3 - [2- (1 - {[3,5 -Bis (difluoromethyl) - 1 H-pyrazol-1-yl] acetyl} piperidin-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-l, 2-oxazol-5-yl] - 3-chlorophenyl methanesulfonate, (15.044) 2- {3- [2- (l- {[3,5-

Bis (difluoromethyl) - 1 H-pyrazol-1-yl] acetyl} piperidin-4-yl) - 1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl [ phenyl methanesulfonate, (15.045) 2-phenylphenol and its salts, (15.046) 3- (4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-l-yl) quinoline, (15.047) 3- (4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-l-yl) quinoline, (15,048) 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidine -2 (1H) -one), (15,049) 4-oxo-4 - [(2-phenylethyl) amino] butyric acid, (15,050) 5-amino-l, 3,4-thiadiazol-2-thiol, (15.051) 5-chloro-N'-phenyl-N '- (prop-2-yn-l-yl) thiophene-2-sulfonohydrazide, (15.052) 5-fluoro-2 - [(4-fluorobenzyl) oxy] pyrimidine-4- amine, (15.053) 5-fluoro-2 - [(4-methylbenzyl) oxy] pyrimidin-4-amine, (15.054) 9-fluoro-2,2-dimethyl-5- (quinolin-3-yl) -2, 3-dihydro-l, 4-benzoxazepine, (15,055) but-3-yn-l-yl [6 - [({[(Z) - (l-methyl-lH-tetrazol-5-yl) (phenyl) methylene ] amino} oxy) methyl] pyridin-2-yl jcarbamate, (15.056) ethyl (2Z) -3-amino-2-cyano-3-phenyl acrylate, (15.057) phenazin-1-carbo acid, (15.058) propyl 3,4,5-trihydroxybenzoate, (15.059) quinolin-8-ol, (15.060) quinolin-8-ol sulfate (2: 1), (15.061) tert-butyl [6 - [({ [(l-methyl-1H-tetrazol-5-yl) (phenyl) methylene] amino] oxy) methyl] pyridin-2-yl} carbamate, (15.062) 5-fluoro-4-imino-3-methyl-l- [(4-methylphenyl) sulfonyl] -3,4-dihydropyrimidin-2 (lH) -one, (15.063) inpyrfluxam, (15.064) isoflucypram, (15.065) picarbutrazox, (15.066) quinofumelin, (15.067) 2- {3- [2- (l- {[3,5- bis (difluoromethyl) -1 H-pyrazol-1-yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5- dihydro-1,2-oxazol-5-yl} -3-chlorophenyl methanesulfonate.

In addition to a compound of the formula (I), the active compound combinations according to the invention preferably contain one or more mixing partners from the active compounds listed below. This group of preferred mixed partners is referred to below as "Group B mixed partners":

Azoxystrobin, benzovindiflupyr, bixafen, carbendazim, carboxin, cyproconazole, cyprodinil, difenoconazole, diniconazole, dimethomorph, ethaboxam, fenamidone, fludioxonil, fluopicolide, fluoxastrobin, flutriafol, flutoluxpoloxilil, fluxifoxanil, fluxifoxanil mefenoxam, Mefentrifluconazole, metalaxyl, metconazole, myclobutanil, Oxathiapiprolin, pencycuron, penflufen, penthiopyrad, picoxystrobin Picarbutrazox, prochloraz, prothioconazole, Pydiflumetofen, pyraclostrobin, pyrimethanil, Quinofumelin, sedaxane, silthiofam, tebuconazole, tetraconazole, thiabendazole, thiophanate-methyl, thiram, Tolclophos -methyl, trifloxystrobin, triflumizole, triticonazole, ziram, compound of the formula 2- {3- [2- (1 - {[3,5-bis (difluoromethyl) - 1 H-pyrazol-1-yl] acetyl} piperidin-4-yl) - 1,3-thiazol-4- yl] -4,5-dihydro-1,2-oxazol-5-yl} -3-chlorophenyl methanesulfonate.

Mixtures according to the invention containing compound no. 1 and one or more mixing partners selected from group B mixing partners are preferred.

Mixtures according to the invention containing compound no. 1 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.

Mixtures according to the invention containing compound no. 2 and one or more mixing partners selected from group B are also preferred.

Mixtures according to the invention containing compound No.2 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.

Mixtures according to the invention comprising compound no. 3 and one or more mixing partners selected from group B mixing partners are also preferred.

Mixtures according to the invention containing compound No.3 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.

Mixtures according to the invention containing compound no. 4 and one or more mixing partners selected from group B are also preferred.

Mixtures according to the invention containing compound no. 4 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.

Mixtures according to the invention containing compound no. 5 and one or more mixing partners selected from group B are also preferred.

Mixtures according to the invention containing compound No.5 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.

Mixtures according to the invention containing compound no. 6 and one or more mixing partners selected from group B are also preferred.

Mixtures according to the invention containing compound 6 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.

Mixtures according to the invention containing compound no. 7 and one or more mixing partners selected from group B are also preferred. Mixtures according to the invention containing compound no. 7 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.

Mixtures according to the invention containing compound no. 8 and one or more mixing partners selected from group B mixing partners are also preferred.

Mixtures according to the invention containing compound no. 8 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.

Mixtures according to the invention containing compound no. 9 and one or more mixing partners selected from group B are also preferred.

Mixtures according to the invention containing compound No.9 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.

Mixtures according to the invention containing compound No.10 and one or more mixing partners selected from Group B mixing partners are also preferred.

Mixtures according to the invention containing compound No.10 and exactly one (1) mixing partner selected from Group B mixing partners are also preferred.

Mixtures according to the invention containing compound 11 and one or more mixing partners selected from group B mixing partners are also preferred.

Mixtures according to the invention containing compound 11 and exactly one (1) mixing partner selected from group B mixing partner are also preferred.

If a fungicide, in particular one of classes (1) to (15), is added to the active compound combinations according to the invention, the resulting mixtures have an increased microbicidal action (compared to the microbial compound (s) within classes (1) to (15) ) and can be used to combat unwanted microorganisms such as fungi and bacteria in crop protection and material protection.

Fungicides can be used in crop protection to combat Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.

Bactericides can be used in crop protection to combat Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.

Some pathogens of fungal and bacterial diseases that fall under the generic names listed above may be mentioned as examples, but not by way of limitation: Diseases caused by powdery mildew pathogens such as

 Blumeria species, such as, for example, Blumeria graminis;

 Podosphaera species, such as, for example, Podosphaera leucotricha;

 Sphaerotheca species, such as, for example, Sphaerotheca fuliginea;

Uncinula species, such as, for example, Uncinula necator;

 Diseases caused by rust pathogens such as

Gymnosporangium species, such as, for example, Gymnosporangium sabinae

Hemileia species, such as, for example, Hemileia vastatrix;

 Phakopsora species, such as, for example, Phakopsora pachyrhizi and Phakopsora meibomiae; Puccinia species, such as, for example, Puccinia recondita;

 Uromyces species, such as, for example, Uromyces appendiculatus;

 Diseases caused by pathogens from the Oomycetes group, e.g.

 Bremia species, such as, for example, Bremia lactucae;

 Peronospora species, such as, for example, Peronospora pisi or P. brassicae;

Phytophthora species, such as, for example, Phytophthora infestans;

 Plasmopara species, such as, for example, Plasmopara viticola;

 Pseudoperonospora species, such as, for example, Pseudoperonospora humuli or

Pseudoperonospora cubensis;

 Pythium species, such as, for example, Pythium ultimum;

Leaf blotch diseases and leaf wilting, caused by e.g.

 Alternaria species, such as, for example, Alternaria solani;

 Cerco spora species, such as, for example, Cercospora beticola;

Cladosporium species, such as, for example, Cladosporium cucumerinum; Cochliobolus species, such as, for example, Cochliobolus sativus

(Conidial form: Drechslera, Syn: Helminthosporium);

 Colletotrichum species, such as, for example, Colletotrichum lindemuthanium;

 Cycloconium species, such as, for example, Cycloconium oleaginum;

Diaporthe species, such as, for example, Diaporthe citri;

 Elsinoe species, such as, for example, Elsinoe fawcettii;

 Gloeosporium species, such as, for example, Gloeosporium laeticolor;

 Glomerella species, such as, for example, Glomerella cingulata;

 Guignardia species, such as, for example, Guignardia bidwelli;

Leptosphaeria species, such as, for example, Leptosphaeria maculans;

 Magnaporthe species, such as, for example, Magnaporthe grisea;

 Mycosphaerella species, such as, for example, Mycosphaerella graminicola and Mycosphaerella fijiensis; Phaeosphaeria species, such as, for example, Phaeosphaeria nodorum;

 Pyrenophora species, such as, for example, Pyrenophora teres;

Ramularia species, such as, for example, Ramularia collo-cygni;

 Rhynchosporium species, such as, for example, Rhynchosporium secalis;

 Septoria species, such as, for example, Septoria apii;

 Typhula species, such as, for example, Typhula incarnata;

 Venturia species, such as, for example, Venturia inaequalis;

Root and stem diseases caused by e.g.

 Corticium species, such as, for example, Corticium graminearum;

 Fusarium species, such as, for example, Fusarium oxysporum;

Gaeumannomyces species, such as, for example, Gaeumannomyces graminis; Rhizoctonia species, such as, for example, Rhizoctonia solani;

 Tapesia species, such as, for example, Tapesia acuformis;

 Thielaviopsis species, such as, for example, Thielaviopsis basicola;

 Ear and panicle diseases (including corn on the cob), caused by e.g.

Alternaria species, such as, for example, Alternaria spp .;

 Aspergillus species, such as, for example, Aspergillus flavus;

 Cladosporium species, such as, for example, Cladosporium cladosporioides;

 Claviceps species, such as, for example, Claviceps purpurea;

 Fusarium species, such as, for example, Fusarium culmorum;

Gibberella species, such as, for example, Gibberella zeae;

 Monographella species, such as, for example, Monographella nivalis;

 Diseases caused by smut such as

 Sphacelotheca species, such as, for example, Sphacelotheca reiliana;

 Tilletia species, such as, for example, Tilletia caries;

Urocystis species, such as, for example, Urocystis occulta;

 Ustilago species, such as, for example, Ustilago nuda;

 Fruit rot caused by e.g.

 Aspergillus species, such as, for example, Aspergillus flavus;

 Botrytis species, such as, for example, Botrytis cinerea;

Penicillium species, such as, for example, Penicillium expansum and Penicillium purpurogenum;

Sclerotinia species, such as, for example, Sclerotinia sclerotiorum;

 Verticilium species, such as, for example, Verticilium alboatrum;

Seed and soil-borne rot and wilt as well as seedling diseases caused by eg Fusarium species, such as, for example, Fusarium culmorum;

Phytophthora species, such as, for example, Phytophthora cactorum;

Pythium species, such as, for example, Pythium ultimum;

Rhizoctonia species, such as, for example, Rhizoctonia solani; Sclerotium species, such as, for example, Sclerotium rolfsii;

Cancer, galls and witches' broom caused by e.g.

Nectria species, such as, for example, Nectria galligena;

Wilting diseases caused by e.g.

Monilinia species, such as, for example, Monilinia laxa; Deformations of leaves, flowers and fruits caused by e.g.

Taphrina species, such as, for example, Taphrina deformans;

Degenerative diseases of woody plants caused by e.g.

Esca species, such as, for example, Phaeomoniella chlamydospora and Phaeoacremonium aleophilum and Fomitiporia mediterranea; Flower and seed diseases caused by e.g.

Botrytis species, such as, for example, Botrytis cinerea;

Diseases of plant tubers caused by e.g.

Rhizoctonia species, such as, for example, Rhizoctonia solani;

Helminthosporium species, such as, for example, Helminthosporium solani; Diseases caused by bacterial pathogens such as

Xanthomonas species, such as, for example, Xanthomonas campestris pv. Oryzae;

Pseudomonas species, such as, for example, Pseudomonas syringae pv. Lachrymans;

Erwinia species, such as, for example, Erwinia amylovora; The following diseases of soybeans can preferably be combated:

Fungal diseases on leaves, stems, pods and seeds caused by e.g.

Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var. Truncatum), Brown spot (Septoria glycines), Cercospora leaf spot and blight (Cercospora kikuchii), Choanephora leaf blight (Choanephora) infundaulifera. , Dactuliophora leaf spot (Dactuliophora glycines), Downy Mildew (Peronospora manshurica), Drechslera blight (Drechslera glycini), Frogeye Leaf spot (Cercospora sojina), Leptosphaerulina Leaf Spot (Leptosphaerulina trifoliicta, Phyllostica leaf, Star Blight (Phomopsis sojae), Powdery Mildew (Microsphaera diffusa), Pyrenochaeta Leaf Spot (Pyrenochaeta glycines), Rhizoctonia Aerial, Foliage, and Web Blight (Rhizoctonia solani), Rust (Phakopsora pachyrhizi), Scab (Sphaceloma Glycines Leaf, Stemphylium botryosum), target spot (Corynespora cassiicola)

Fungal diseases on roots and the stem base caused by e.g.

Black Root Rot (Calonectria crotalariae), Charcoal Rot (Macrophomina phaseolina), Fusarium Blight or Wilt, Root Rot, and Pod and Collar Rot (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Rot (Mycol Neocosmospora (Neocosmopspora vasinfecta), Pod and Stern Blight (Diaporthe phaseolorum), Stern Canker (Diaporthe phaseolorum var. Caulivora), Phytophthora Rot (Phytophthora megasperma), Brown Stern Rot (Phialophora gregata), Pythium Rotythium (Pythium Rotythium (Pythium Rotythium) , Pythium debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Rot, Stern Decay, and Damping-Off (Rhizoctonia solani), Sclerotinia Stern Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsiiisopsiopsiopsi), Thiel ,

Preferred mixing ratios in which a compound of the formula (I) can be combined with the specified mixing partners are 3000: 1 to 1: 3000, 1000: 1 to 1: 1000, 750: 1 to 1: 750, 500: 1 to 1 : 500, 250: 1 to 1: 250, 200: 1 to 1: 200, 100: 1 to 1: 100, 95: 1 to 1: 95, 90: 1 to 1: 90, 85: 1 to 1: 85 , 80: 1 to 1:80, 75: 1 to 1: 75, 70: 1 to 1: 70, 65: 1 to 1: 65, 60: 1 to 1: 60, 55: 1 to 1:55, 45 : 1 to 1: 45, 40: 1 to 1:40, 35: 1 to 1:35, 30: 1 to 1:30, 20: 1 to 1:20, 15: 1 to 1:15, 10: 1 to 1:10, 9: 1 to 1: 9, 8: 1 to 1: 8, 7: 1 to 1: 7, 6: 1 to 1: 6 4: 1 to 1: 4, 3: 1 to 1: 3, 2: 1 to 1: 2, 1: 1, 0, 001: 1 to 1: 0.001.

Furthermore, compounds of the formula (I) can be mixed with herbicides. The same applies to the mixtures according to the invention mentioned, which can likewise be mixed with herbicides and applied to plants or parts of plants. In many cases, these mixtures have synergistic effects with herbicides.

Examples of such herbicidal mixture partners are: Acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, allidochlor, alloxydim, alloxydim- sodium, ametryn, amicarbazone, amidochlor, amidosulfuron, aminocyclopyrachlor, aminocyclopyrachlor-potassium, aminocyclopyrachlor-ammonium, aminopolachyramethyl, aminopolachyridium amyl amine aminate amine amine amine amine amine aminate amine amine amine amine amine amine amine aminophenachloromethyl amine aminate amine amine amine amine amine amine amine aminocyclopyrachloromethyl amine amine amine amine amine aminocyclopyrachloromethyl amine amine amine aminocyclopyrachloromethane atrazine, azafenidin, azimsulfuron, beflubutamid, benazolin, benazolin-ethyl, benfluralin, benfuresate, bensulfuron, bensulfuron-methyl, bensulide, bentazone, benzobicyclon, benzofenap, bicyclopyron, bifenox, bilanafos, bilanafosac-sodium, bispyribac-sodium, bispyrimac-bis, sodium, bispyribac-bis, sodium, bispyryrac-bis, sodium, bispyribac-bis, sodium, bispyryrac-bisp, bromobutide, bromofenoxim, bromoxynil, bromoxynil-butyrate, -potassium, -heptanoate and -octanoate, busoxinone, butachlor, butafenacil, butamifos, butenachlor, butralin, butroxydim, butylate, cafenstrole, carbetamide, carfentrazone, chloruron, chloruron, chlorofentrazone, chlorfur , chlorfenac-sodium, chlorfenprop, chlorflurenol, chlorflurenol-methyl, chloridazon, chlorimuron, chlorimuron-ethyl, chlorophth alim, chlorotoluron, chlorothal-dimethyl, chlorosulfuron, cinidon, cinidon-ethyl, cinmethylin, cinosulfuron, clacyfos, clethodim, clodinafop, clodinafop-propargyl, clomazone, clomeprop, clopyralid, cloransulam, cyclanamide, cyanoamide, cyanoamide, cyanoamide cyclopyrimorate, cyclosulfamuron, cycloxydim, cyhalofop, cyhalofop-butyl, cyprazine, 2,4-D, 2,4-D-butotyl, -butyl, -dimethylammonium, -diolamine, -ethyl, 2-ethylhexyl, -isobutyl, -isooctyl, isopropylammonium, potassium, triisopropanolammonium and trolamine, 2,4-DB, 2,4-DB-butyl, dimethylammonium, isooctyl, potassium and sodium, daimuron (dymron), dalapon, dazomet, n-decanol, desmedipham, detosyl-pyrazolate (DTP), dicamba, dichlobenil, dichlorprop, dichlorprop-P, diclofop, diclofop-methyl, diclofop-P-methyl, diclosulam, difenzoquat, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimethuryl, dimethuryl, dim , dimethenamid, dimethenamid-P, dimetrasulfuron, dinitramine, dinoterb, diph enamide, diquat, diquat-dibromid, dithiopyr, diuron, DNOC, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron, ethametsulfuron-methyl, ethiozin, ethofumesate, ethoxyfen, ethoxyfen-ethyl, ethoxysulfuron, etobenzanide, N- 5231 2-chloro-4-fluoro-5- [4- (3-fluoropropyl) -4,5-dihydro-5-oxo-1 H-tetrazole-1-yl] -phenyl] -ethanesulfonamide, F-7967, ie 3 - [7-Chloro-5-fluoro-2- (trifluoromethyl) -IH-benzimidazol-4-yl] -l-methyl-6- (trifluoromethyl) pyrimidine-2,4 (1H, 3H) -dione, fenoxaprop , fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop-P-ethyl, fenoxasulfone, fentrazamide, flamprop, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, florasulam, fluazifop, fluazifop-P, fluazifop-butyl, fluazifop-P -butyl, flucarbazone, flucarbazone- sodium, flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flufenpyr-ethyl, flumetsulam, flumiclorac, flumiclorac-pentyl, flumioxazin, fluometuron, flurenol, flurenol-butonium, -dimethyl-fluorogly-, -dimethyl-fluorogly-, -dimethyl-fluorogly-, -dimethyl-fluorogly-, -dimethyl-fluorogly-, -dimethyl-fluorogly-, methyl-fluoryl , flupropanate, flupyrs ulfuron, flupyrsulfuron-methyl-sodium, fluridone, flurochloridone, fluroxypyr, fluroxypyr-meptyl, flurtamone, fluthiacet, fluthiacet-methyl, fomesafen, fomesafen-sodium, foramsulfuron, fosamine, glufosinate, glufosinate-ammonium, pufsinate-ammonium, puf P-ammonium, glufosinate-P-sodium, glyphosate, glyphosate-ammonium, -isopropylammonium, -diammonium, -dimethylammonium, -potassium, -sodium and - trimesium, H-9201, ie 0- (2,4-dimethyl-6- nitrophenyl) -0-ethyl-isopropylphosphoramidothioat, halauxifen, halosafen, halosulfuron, halosulfuron-methyl, haloxyfop, haloxyfop-P, haloxyfop- ethoxyethyl, haloxyfop-P-ethoxyethyl, haloxyfop-methyl, haloxyfop-P-methyl, hexazinone, HW-02, ie l- (dimethoxyphosphoryl) ethyl- (2,4-dichlorophenoxy) acetate, imazamethabenz, imazamethabenz-methyl, imazamox, imazamox-ammonium, imazapic, imazapic-ammonium, imazapyr, imazapyr-isopropylammonium, imazaquin, imazaquin-ammonium, imazethapyr, imazethapyr-immonium, imazosulfuron, indanofan, indaziflam, iodosulfuron, methyl-iodosanooxynyl, sodium iodosulfuron-iodosulfonilynyl-iodosulfate-iodine-iodosulfuril-iodosulfoniloxynyl-iodosulfate-iodosulfate-iodosulfate-iodosulfoniloxynyl-iodosulfonyl-iodosulfate-iodosulfate-iodosulfate-iodosulfonyl-iodosulfate-iodosulfate-iodosulfate-iodosulfonyl-iodosulfate-iodine-iodosulfate-iodosulfonyl-iodosulfoniloxynyl-iodosulfate-iodine-sulfate and sodium, ipfencarbazone, isoproturon, isouron, isoxaben, isoxaflutole, carbutilate, KUH-043, ie 3 - ({[5- (difluoromethyl) -l-methyl-3- (trifluoromethyl) -lH-pyrazol-4-yl] methyl } sulfonyl) -5,5-dimethyl-4,5-dihydro-l, 2-oxazole, ketospiradox, lactofen, lenacil, linuron, MCPA, MCPA-butotyl, dimethylammonium, -2-ethylhexyl, isopropylammonium, potassium and - sodium, MCPB, MCPB-methyl, -ethyl and -sodium, mecoprop, mecoprop-sodium, and -butotyl, mecoprop-P, mecoprop-P-butotyl, -dimethylammonium, -2-ethylhexyl and -potassium , mefenacet, mefluidide, mesosulfuron, mesosulfuron-methyl, mesotrione, methabenzthiazuron, metam, metamifop, metamitron, metazachlor, metazosulfuron, methabenzthiazuron, methiopyrsulfuron, methiozolon, metolachon, metolachuron, metolachuryl, metolachoxuryl, metolachuryl, metolachuryl, metolachuron, metholamoxin, chlorol metsulfuron-methyl, molinate, monolinuron, monosulfuron, monosulfuron ester, MT-5950, ie N- [3-chloro-4- (l-methylethyl) phenyl] -2-methylpentanamide, NGGC-011, napropamide, NC-310 , ie 4- (2,4-dichlorobenzoyl) -l-methyl-5-benzyloxypyrazole, neburon, nicosulfuron, nonanoic acid (pelargonic acid), norflurazon, oleic acid (fatty acids), orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron , oxaziclomefon, oxyfluorfen, paraquat, paraquat dichloride, pebulate, pendimethalin, penoxsulam, pentachlorphenol, pentoxazone, pethoxamid, petroleum oils, phenmedipham, picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfodiamine, primisulfuron, methylsulfuron in, prometon, prometryn, propachlor, propanil, propaquizafop, propazine, propham, propisochlor, propoxycarbazone, propoxycarbazone-sodium, propyrisulfuron, Propyzamide, prosulfocarb, prosulfuron, pyraclonil, pyraflufen, pyraflufen-ethyl, pyrasulfotole, pyrazolynate (pyrazolate), pyrazosulfuron, pyrazosulfuron -ethyl, pyrazoxyfen, pyribambenz, pyribambenz-isopropyl, pyribambenz-propyl, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac, pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyrithiobac-sodium, pyroxasulfam, quinacoracoracinacoracoracoracoracinacoracoracoracoracomacoracoracomacoracoracinocinacoracomacoracoracinocinacoracinacinacoracinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacinacylacinacylacinacylacinaccharide, , quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, rimsulfuron, saflufenacil, sethoxydim, siduron, simazine, simetryn, sulcotrion, sulfentrazone, sulfometuron, sulfometuron-methyl, SYNSulfur- 52, SYP-249, ie l-ethoxy-3-methyl-l-oxobut-3-en-2-yl-5- [2-chloro-4- (trifluoromethyl) phenoxy] -2-nitrobenzoate, S YP-300, ie 1 - [7-Fluoro-3-oxo-4- (prop-2-in-1-yl) -3,4-dih ydro-2H-1,4-benzoxazin-6-yl] - 3-propyl-2-thioxoimidazolidin-4,5-dione, 2,3,6-TBA, TCA (trifluoroacetic acid), TCA-sodium, tebuthiuron, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbumeton, terbuthylazine, terbutryn, thenylchlor, thiazopyr, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron- methyl, thiobencarb, topramezone tiafenacil, tralkoxydim, triafamone, tri-allate, triasulfuron, triaziflam, tribenuron, tribenuron -methyl, triclopyr, trietazine, trifloxysulfuron, trifloxysulfuron-sodium, trifluralin, triflusulfuron, triflusulfuron-methyl, tritosulfuron, urea sulfate, vernolate, ZJ-0862, ie 3,4-dichloro-N- {2 - [(4,6-dimethoxypyrimidin-2-yl) oxy] benzyl} aniline, and the following Links:

Fruit / Vegetable Herbicides: Atrazine, Bromacil, Diuron, Glyphosate, Linuron, Metribuzin, Simazine, Trifluralin, Fluazifop, Glufosinate, Halosulfuron Gowan, Paraquat, Propyzamide, Sethoxydim, Butafenacil, Halosulfuron, Indaziflam;

Cereal herbicides: isoproturon, bromoxynil, ioxynil, phenoxies, chlorosulfuron, clodinafop, diclofop, diflufenican, fenoxaprop, florasulam, fluroxypyr, metsulfuron, triasulfuron, flucarbazone, iodosulfuron, propolinidoxonosulfonone, propoxyidoxonazuronesulfonone Sulfosulfuron, pyrasulfotole, pyroxsulam, flufenacet, tralkoxydim, pyroxasulfone;

Corn herbicides: Atrazine. Alachlor, Bromoxynil, Acetochlor, Dicamba, Clopyralid, (.S ') - I) micthcnainid, Glufosinate, Glyphosate, Isoxaflutole, (.S') - Metolachlor, Mesotrione, Nicosulfuron, Primisulfuron, Rimsulfuron, Sulcotrione, Topione Sulfurzone, Foramsulfurone Zone Saflufenacil, Thiencarbazone, Flufenacet, Pyroxasulfon; Rice herbicides: butachlor. Propanil, azimsulfuron, bensulfuron, cyhalofop, daimuron, Fentrazamide, imazosulfuron, mefenacet, Oxaziclomefone, pyrazosulfuron, pyributicarb, quinclorac, thiobencarb, indanofan, flufenacet, Fentrazamide, halosulfuron, Oxaziclomefone, benzobicyclon, pyriftalid, penoxsulam, bispyribac, oxadiargyl, ethoxysulfuron, pretilachlor, Mesotrione, tefuryltrione, oxadiazone, fenoxaprop, pyrimisulfan; Cotton herbicides: Diuron, Fluometuron, MSMA, Oxyfluorfen, Prometryn, Trifluralin, Carfentrazone, Clethodim, Fluazifop-butyl, Glyphosate, Norflurazon, Pendimethalin, Pyrithiobac-sodium, Trifloxysulfuron, Tepraloxydim, Flufurosazinate; Soya herbicides: Alachlor, Bentazone, Trifluralin, Chlorimuron-Ethyl, Cloransulam-Methyl, Fenoxaprop, Fomesafen, Fluazifop, Glyphosate, Imazamox, Imazaquin, Imazethapyr, (.S ') - Metolachlor, Metribuzin, Pendimoxydinin, Teufaloxinin, Teuf

Sugar beet herbicides: Chloridazon, Desmedipham, Ethofumesate, Phenmedipham, Triallate, Clopyralid, Fluazifop, Fenacil, Metamitron, Quinmerac, Cycloxydim, Triflusulfuron, Tepraloxydim, Quizalofop;

Rapeseed herbicides: Clopyralid, Diclofop, Fluazifop, Glufosinate, Glyphosate, Metazachlor, Trifluralin Ethametsulfuron, Quinmerac, Quizalofop, Clethodim, Tepraloxydim;

Mixtures of the compound of the formula (Ia) or mixtures of the active compound combinations according to the invention with glyphosate are particularly preferred. Mixtures of the compound of the formula (Ia) or mixtures of the active compound combinations according to the invention with glufosinates are also particularly preferred.

Compounds of the formula (I) and mixtures according to the invention can also advantageously be mixed with safeners or used in conjunction with safeners. Suitable safeners are e.g. B. Cyprosulfamide, Isoxadifen-ethyl and Mefenpyr-diethyl.

Compounds of the formula (I) and mixtures according to the invention can also advantageously be mixed with FCOs or used in conjunction with FCOs.

Fipo-chito-oligosaccharides (FCO) are able to influence plant growth and development. FCOs, mainly from Rhizobia spp. secreted play a key role in the stimulation of nodules in feguminoses by activating signals in certain growth hormones, nutrients and in plant metabolism. FCOs have direct and indirect effects on various physiological processes. They supply the rhizosphere, microbial population with minerals, biochemical substances and nutrients and transport trace elements and growth regulators to stimulate plant growth. Fipo-chito-oligosaccharides (FCO) secreted by rhizosphere bacteria play a key role in stimulating nodules in the roots of feguminoses by activating signals at very low concentrations that initiate cell division at different locations in the root. The structure of FCOs from different nodule bacteria (or rhizobia) has been elucidated (V. Suganaya et al., IJTA, 33 (1), 2015 and the literature cited therein).

The present invention further relates to formulations and use forms prepared therefrom as crop protection agents and / or pesticides such. B. drench, drip and spray broths, comprising at least one of the active compounds according to the invention. If appropriate, the use forms contain further crop protection agents and / or pesticides and / or effect-enhancing adjuvants such as penetration enhancers, e.g. B. vegetative oils such as rapeseed oil, sunflower oil, mineral oils such as paraffin oils, alkyl esters of vegetative fatty acids such as rapeseed oil or soybean oil methyl esters or alkanol alkoxylates and / or spreading agents such as alkylsiloxanes and / or salts z. B. organic or inorganic ammonium or phosphomium salts such as ammonium sulfate or diammonium hydrogen phosphate and / or the retention-promoting agents such. B. dioctyl sulfosuccinate or hydroxypropyl guar polymers and / or humectants such as. B. glycerol and / or fertilizers such as ammonium, potassium or phosphorus-containing fertilizers.

Typical formulations are, for example, water-soluble liquids (SL), emulsion concentrates (EC), emulsions in water (EW), suspension concentrates (SC, SE, FS, OD), water-dispersible granules (WG), granules (GR) and capsule concentrates (CS) ; these and other possible types of formulations are described, for example, by Crop Life International and in Pesticide Specifications, Manual on development and use of FAO and WHO specifications for pesticides, FAO Plant Production and Protection Papers - 173, prepared by the FAO / WHO Joint Meeting on Pesticide Specifications, 2004, ISBN: 9251048576. The formulations may contain, in addition to one or more active substances according to the invention, further agrochemical active substances.

These are preferably formulations or use forms which contain auxiliaries, such as, for example, extenders, solvents, promoters of spontaneity, carriers, emulsifiers, dispersants, antifreezes, biocides, thickeners and / or other auxiliaries, such as, for example, adjuvants. An adjuvant in this context is a component that improves the biological effect of the formulation without the component itself having a biological effect. Examples of adjuvants are agents which promote retention, spreading behavior, adherence to the leaf surface or penetration.

These formulations are made in a known manner, e.g. by mixing the active ingredients with auxiliaries such as extenders, solvents and / or solid carriers and / or other auxiliaries such as surface-active substances. The formulations are prepared either in suitable plants or before or during use.

Auxiliaries that can be used are substances that are suitable for imparting special properties, such as certain physical, technical and / or biological properties, to the formulation of the active ingredient or the use forms prepared from these formulations (such as usable crop protection agents such as spray liquors or seed dressings).

Suitable extenders are, for example, water, polar and non-polar organic chemical liquids, for example from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, can be etherified and / or esterified), the ketones (such as acetone, cyclohexanone), esters (also fats and oils) and (poly) ethers, the simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, the sulfones and sulfoxides (such as dimethyl sulfoxide).

If water is used as an extender, e.g. organic solvents can also be used as auxiliary solvents. The following are essentially suitable as liquid solvents: aromatics, such as xylene, toluene or alkylnaphthalenes, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. Petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethylformamide and dimethyl sulfoxide, and water.

In principle, all suitable solvents can be used. Suitable solvents are, for example, aromatic hydrocarbons, e.g. Xylene, toluene or alkylnaphthalenes, chlorinated aromatic or aliphatic hydrocarbons, e.g. Chlorobenzene, chloroethylene, or methylene chloride, aliphatic hydrocarbons such as e.g. Cyclohexane, paraffins, petroleum fractions, mineral and vegetable oils, alcohols, e.g. Methanol, ethanol, iso-propanol, butanol or glycol and their ethers and esters, ketones such as e.g. Acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl sulfoxide and water.

In principle, all suitable carriers can be used. The following are particularly suitable as carriers: e.g. Ammonium salts and natural rock meals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock meals, such as highly disperse silica, aluminum oxide and natural or synthetic silicates, resins, waxes and / or solid fertilizers. Mixtures of such carriers can also be used. Suitable carriers for granules are: e.g. broken and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic material such as sawdust, paper, coconut shells, corn cobs and tobacco stems.

Liquefied gaseous extenders or solvents can also be used. Particularly suitable extenders or carriers are those which are gaseous at normal temperature and pressure, e.g. Aerosol propellants, such as halogenated hydrocarbons, as well as butane, propane, nitrogen and carbon dioxide.

Examples of emulsifiers and / or foaming agents, dispersants or wetting agents with ionic or nonionic properties or mixtures of these surface-active substances are salts of polyacrylic acid, salts of lignosulphonic acid, salts of phenolsulphonic acid or Naphthalenesulphonic acid, polycondensates of ethylene oxide with fatty alcohols or with fatty acids or with fatty amines, with substituted phenols (preferably alkylphenols or arylphenols), salts of sulphosuccinic acid esters, taurine derivatives (preferably alkyl taurate derivatives), phosphoric acid esters of polyethoxylated alcohols or phenols, fatty acid esters of polyols, and derivatives of the compounds Sulphates, sulphonates and phosphates, for example alkylaryl polyglycol ethers, alkyl sulfonates, alkyl sulfates, aryl sulfonates, protein hydrolyzates, fignin sulfite waste liquors and methyl cellulose. The presence of a surface-active substance is advantageous if one of the active ingredients and / or one of the inert carriers is not soluble in water and if the application is carried out in water.

In the formulations and the use forms derived therefrom, dyes such as inorganic pigments, e.g. Iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and nutrient and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc are present.

Stabilizers such as cold stabilizers, preservatives, antioxidants, anti-leveling agents or other agents which improve chemical and / or physical stability can also be present. Foam-producing agents or defoamers may also be present.

Furthermore, the formulations and use forms derived therefrom can also contain, as additional auxiliaries, adhesives such as carboxymethyl cellulose, natural and synthetic powdery, granular or latex-shaped polymers, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and also natural phospholipids, such as cephalins and fecithins, and synthetic phospholipids. Other auxiliaries can be mineral and vegetable oils.

If appropriate, further auxiliaries can be contained in the formulations and the use forms derived therefrom. Such additives are, for example, fragrances, protective colloids, binders, adhesives, thickeners, thixotropic substances, penetration promoters, retention promoters, stabilizers, sequestering agents, complexing agents, humectans, spreading agents. In general, the active ingredients can be combined with any solid or liquid additive that is commonly used for formulation purposes.

All substances which reduce the dynamic surface tension, for example dioctylsulfosuccinate or which increase the visco-elasticity, for example hydroxypropyl guar polymers, are suitable as retention promoters.

In the present context, penetration promoters are all those substances that are usually used to improve the penetration of agrochemical active substances into plants. Penetration promoters are defined in this context by the fact that they flow from the (usually aqueous) application broth and / or from the spray coating into the cuticle of the plant penetrate and thereby increase the mobility of the active substances in the cuticle. The method described in the literature (Baur et al., 1997, Pesticide Science 51, 131-152) can be used to determine this property. Examples include alcohol alkoxylates such as coconut fat ethoxylate (10) or isotridecyl ethoxylate (12), fatty acid esters such as rapeseed oil or soybean oil methyl esters, fatty amine alkoxylates such as tallowamine ethoxylate (15) or ammonium and / or phosphonium salts such as ammonium sulfate or diammonium hydrogen phosphate.

According to the invention, all plants and parts of plants can be treated. Plants are understood here to mean all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant cultivars which can or cannot be protected by plant breeders' rights. The plants which can be treated with the active compound combinations according to the invention include, for. B. the following types of plants: turf, vines, cereals, for example wheat, barley, rye, oats, rice, corn and millet, triticale; Beets, for example sugar beets and fodder beets; Fruits, for example pome fruit, stone fruit and soft fruit, for example apples, pears, plums, peaches, almonds, cherries and berries, e.g. B. strawberries, raspberries, blackberries; Legumes, for example beans, lentils, peas and soybeans; Oil crops, for example rapeseed, mustard, poppy seeds, olives, sunflowers, coconut, castor oil plants, cocoa beans and peanuts; Cucumber plants, for example pumpkin, cucumber and melons; Fiber plants, for example cotton, flax, hemp and jute; Citrus fruits, for example oranges, lemons, grapefruit and mandarins; Vegetables, for example spinach, (head) salad, asparagus, cabbages, carrots, onions, tomatoes, potatoes and peppers; Laurel plants, for example avocado, cinnamomum, camphor, or plants such as tobacco, nuts, coffee, eggplant, sugar cane, tea, pepper, grapevines, hops, bananas, natural rubber plants and ornamental plants, for example flowers, shrubs, deciduous trees and conifers such as conifers. This list is not a limitation.

Plant parts are to be understood to mean all above-ground and underground parts and organs of plants, such as shoots, leaves, flowers and roots, examples being leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, and roots, tubers and rhizomes , The plant parts also include crops and vegetative and generative propagation material, for example cuttings, tubers, rhiozomes, offshoots and seeds.

The treatment of the plants and plant parts according to the invention with the active compound combinations is carried out directly or by acting on their environment, habitat or storage space according to usual treatment methods, e.g. by dipping, (spraying) spraying, (spraying), sprinkling, vaporizing, atomizing, pouring, atomizing, (scattering) scattering, foaming, brushing, spreading, injecting, pouring (drenching), drip irrigation and in the case of propagation material, in particular seeds, also by means of dry pickling, wet pickling, slurry pickling, incrustation, single- or multi-layer coating.

A preferred direct treatment for the plants is leaf application, i.e. the active compound combinations according to the invention are applied to the foliage, the treatment frequency and the application rate being adapted to the infestation pressure of the respective pest.

In the case of systemically active compounds, the active compound combinations according to the invention reach the plants via the root system. The plants are then treated by the action of the active compound combinations according to the invention on the plant's habitat. This can be, for example, by drenching, mixing into the soil or the nutrient solution, i.e. the location of the plant (e.g. soil or hydroponic systems) is impregnated with a liquid form of the active compound combinations according to the invention, or by the soil application, i.e. the active compound combinations according to the invention are introduced in solid form (e.g. in the form of granules) into the location of the plants. In the case of water rice crops, this can also be done by metering the invention into a solid application form (e.g. as granules) in a flooded rice field.

The present invention therefore also relates in particular to a method for protecting seed and germinating plants from attack by pests by treating the seed with the active compound combinations according to the invention. The method according to the invention for protecting seed and germinating plants from pest infestation comprises a method in which the seed is treated simultaneously with the active ingredient of the formula (Ia) and mixing partner in one operation. It also includes a process in which the seed is treated at different times with the active ingredient of the formula (Ia) and mixing partner.

The invention also relates to the use of the active compound combinations according to the invention for the treatment of seeds for protecting the seeds and the plant resulting therefrom from animal pests.

The invention further relates to seeds which have been treated with the active compound combinations according to the invention for protection against animal pests. The invention also relates to seeds which have been treated at the same time with the active ingredient of the formula (Ia) and mixing partner. The invention further relates to seeds which have been treated at different times with the active ingredient of the formula (Ia) and mixing partner. In the case of seed which has been treated at different times with the active ingredient of the formula (Ia) and mixing partner, the individual active ingredients of the composition according to the invention can be present on the seed in different layers his. The layers which contain the active ingredient of the formula (Ia) and mixing partner can optionally be separated by an intermediate layer. The invention also relates to seeds in which the active ingredient of the formula (Ia) and mixing partner are applied as part of a coating or as a further layer or further layers in addition to a coating.

Furthermore, the invention relates to seeds which, after treatment with the active compound combinations according to the invention, are subjected to a film coating process in order to avoid dust abrasion on the seeds.

One of the advantages of the present invention is that, because of the special systemic properties of the agents according to the invention, the treatment of the seeds with these agents not only protects the seeds themselves, but also the plants resulting therefrom after emergence from animal pests. In this way, the immediate treatment of the crop at the time of sowing or shortly thereafter can be omitted.

Another advantage can be seen in the fact that the treatment of the seed with the active compound combinations according to the invention can promote germination and emergence of the treated seed.

It is also to be regarded as advantageous that active ingredient combinations according to the invention can also be used in particular with transgenic seeds.

As already mentioned above, according to the invention, all plants and their parts can be treated. In a preferred embodiment, plant species and plant cultivars which occur wildly or are obtained by conventional biological breeding methods, such as hybridization or protoplast fusion, and parts thereof are treated. The traditional propagation and breeding methods can be supported or supplemented by one or more biotechnological methods, such as the use of double haploids, random and directed mutagenesis, molecular or genetic markers, or by bioengineering methods and genetic engineering methods. In a further preferred embodiment, transgenic plants and plant cultivars which have been obtained by genetic engineering methods, if appropriate in combination with conventional methods (genetic modified organisms) and their parts are treated. Genetically modified plants (or transgenic plants) are plants in which a heterologous gene has been stably integrated into the genome. The term "heterologous gene" essentially means a gene that is provided or assembled outside of the plant or plant cell and that, when introduced into the nuclear genome, the chloroplast genome or the mitochondrial genome, gives the transformed plant new or improved agronomic or other characteristics imparts by expressing a protein or polypeptide of interest or by down-regulating or switching off another gene present in the plant or other genes present in the plant (eg using antisense technology, cosuppression technology, RNA interference technology (RNAi technology) or microRNA technology (miRNA technology)). A heterologous gene that has been integrated into the genome is also called a transgene. A transgene that has been integrated into the plant genome is called a transformation event or transgenic event. The terms "parts" or "parts of plants" or "plant parts" were explained above.

Plants of the plant varieties which are in each case commercially available or in use are particularly preferably treated according to the invention.

Depending on the plant species or plant cultivars, their location and growth conditions (soils, climate, growing season, nutrition), the treatment according to the invention can also cause superadditive ("synergistic") effects. For example, reduced application rates and / or widening of the spectrum of action and / or an increase in the action of the substances and agents which can be used according to the invention, better plant growth, increased tolerance to high or low temperatures, increased tolerance to dryness or to water or soil salt content, increased flowering performance , easier harvesting, acceleration of ripening, higher crop yields, larger fruits, higher plant height, more intense green color of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruit, higher storage life and / or workability of the harvested products possible that go beyond the expected effects.

The preferred transgenic (genetically engineered) plants or plant cultivars to be treated according to the invention include all plants which, through the genetic engineering modification, have received genetic material which gives these plants particularly advantageous, valuable properties (“traits”). Examples of such properties are better plant growth, increased tolerance to high or low temperatures, increased tolerance to drought or to water or soil salt content, increased flowering performance, easier harvesting, accelerated ripening, higher harvest yields, higher quality and / or higher nutritional value of the harvested products , higher shelf life and / or workability of the harvested products. Further and particularly highlighted examples of such properties are an increased defense of the plants against animal and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and / or viruses, and an increased tolerance of the plants to certain herbicidal active ingredients. Examples of transgenic plants are the important crop plants, such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, rapeseed and fruit plants (with the fruits apples, pears, citrus fruits and grapes), with corn, soybeans, potatoes and cotton and rapeseed are highlighted. The traits are particularly emphasized as the increased defense of the plants against insects by toxins arising in the plants, in particular those which are caused by the genetic material from Bacillus thuringiensis (for example by the genes CrylA (a), CrylA (b), CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c, Cry2Ab, Cry3Bb and CrylF as well as their combinations) are produced in the plants (hereinafter "Bt plants"). The properties (“traits”) which are particularly emphasized are the increased tolerance of the plants to certain herbicidal active compounds, for example imidazolinones, sulfonylureas, glyphosate or phosphinotricin (for example “PAT” gene). The genes conferring the desired properties (“traits”) can also occur in combinations with one another in the transgenic plants. Examples of "Bt plants" are corn varieties, cotton varieties, soy varieties and potato varieties which are marketed under the trade names YIELD GARD ^® (e.g. corn, cotton, soy), KnockOut ^® (e.g. corn), StarLink ^® (e.g. corn), Bollgard ^® ( Cotton), Nucotn ^® (cotton) and NewLeaf ^® (potato). Examples of herbicide-tolerant plants are maize varieties, cotton varieties and soy varieties that are sold under the trade names Roundup Ready ^® (tolerance to glyphosate e.g. corn, cotton, soy), Liberty Link ^® (tolerance to phosphinotricin, e.g. rape), IMI ^® (tolerance to Imidazolinone) and STS ^® (tolerance to sulfonylureas such as maize). Herbicide-resistant plants (bred conventionally for herbicide tolerance) plants also sold under the name Clearfield ^® varieties (eg maize) are mentioned. Of course, these statements also apply to plant varieties developed in the future or coming onto the market in the future with these or future-developed genetic properties ("traits").

The plants listed can be treated particularly advantageously according to the invention with the active compound mixtures according to the invention. The preferred ranges given above for the active ingredient combinations also apply to the treatment of these plants. Plant treatment with the active ingredient combinations specifically listed in the present text should be particularly emphasized.

The good effects of the active compound combinations according to the invention can be seen from the examples below. While the individual active ingredients have weaknesses in their effects, the combinations show an effect that goes beyond a simple summation of effects.

A synergistic effect is always present when the effect of the active ingredient combinations is greater than the expected effect calculated according to Colby from the effects of the individually applied active ingredients. applications

Formula for killing a combination of two active ingredients

The expected effect for a given combination of two active ingredients can, according to S.R. Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15, 20-22, 1967) can be calculated as follows:

If

X means the degree of destruction, expressed in% of the untreated control, when the active compound A is used in an application rate of m g / ha or in a concentration of m ppm,

Y means the degree of destruction, expressed in% of the untreated control, when the active compound B is used in an application rate of n g / ha or in a concentration of n ppm and

Ist der tatsächliche Abtötungsgrad größer als der berechnet Abtötungsgrad (E), so ist die Kombination in ihrer Abtötung überadditiv, d.h. es liegt ein synergistischer Effekt vor. E means the degree of destruction, expressed in% of the untreated control, when the active compounds A and B are used in application rates of m and ng / ha or in a concentration of m and n ppm, then

If the actual kill rate is greater than the calculated kill rate (E), the combination is superadditive in its kill, ie there is a synergistic effect.

Example A

Mvzus persicae - spray test

Solvent: 78 parts by weight of acetone

 1.5 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the specified parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further test concentrations are obtained by diluting with water containing emulsifier. Chinese cabbage leaf slices (Brassica pekinensis), which are affected by all stages of the green peach aphid (Myzus persicae), are sprayed with an active ingredient preparation of the desired concentration.

After the desired time, the effect is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed. The determined kill rates are calculated using the Colby formula (see sheet 1).

In this test, the following combinations of active substances according to the present application showed a synergistically enhanced effectiveness compared to the individually used active substances:

Table A: Myzus persicae - spray test

 * found = effect found; calc. = Effect calculated according to the Colby formula

Example B

Aphis gossypii - spray test

Solvent: 7 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the specified parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further test concentrations are obtained by diluting with water containing emulsifier. Cotton plants (Gossypium hirsutum) that are heavily infested with the cotton aphid (Aphis gossypii) are sprayed with an active ingredient preparation of the desired concentration.

After the desired time, the kill is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed. The determined kill rates are calculated using the Colby formula (see sheet 1). In these tests, the following combinations of active substances according to the present application showed a synergistically enhanced effectiveness compared to the individually used active substances:

Test 1

 Table B-l. 1: Aphis gossypii - spray test

 * found = effect found; calc. = Effect calculated according to the Colby formula

Test 2

 Table B-2.1: Aphis gossypii - spray test

 Table B-2.2: Aphis gossypii - spray test

 Table B-2.3: Aphis gossypii - spray test

 * found = effect found; calc. = Effect calculated according to the Colby formula

Example C

Nilaparvata lugens spray application

Solvent: 78.0 parts by weight of acetone

 1.5 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the specified parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. To prepare further test concentrations, dilute with water containing emulsifier.

Rice plants (Oryza sativa) are sprayed with the active ingredient preparation of the desired concentration and then infected with the brown-backed rice leafhopper (Nilaparvata lugens).

After the desired time, the effect is determined in%. 100% means that all aphids have been killed and 0% means that no aphids have been killed. The determined kill rates are calculated using the Colby formula (see sheet 1).

In this test, the following combinations of active substances according to the present application showed a synergistically enhanced activity compared to the individually used active substances:

Table C: Nilaparvata lugens - spray test

 * found = effect found; calc. = Effect calculated according to the Colby formula

Example D

Myzus persicae - spray test

Solvent: 7 parts by weight of dimethylformamide

 Emulsifier: alkylaryl polyglycol ether

To produce a suitable preparation of active compound, 1 part by weight of active compound is dissolved with the specified parts by weight of solvent and the mixture is filled with water which contains an emulsifier concentration of 1000 ppm until the desired concentration is reached. Further Test concentrations are obtained by dilution with water containing emulsifiers. If it is necessary to add ammonium salts and / or penetration enhancers, these are each added to the preparation solution in a concentration of 1000 ppm.

Savoy plants (Brassica oleracea), which are heavily infested with the green peach aphid (Myzus persicae), are treated by spraying with the active ingredient preparation in the desired concentration.

After the desired time, the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed. The determined mortality values are calculated using the Colby formula (see sheet 1). In this test, the following combinations of active substances according to the present application showed a synergistically enhanced effectiveness compared to the individually used active substances:

Table D-1: Myzus persicae - spray test

 Table D-2: Myzus persicae - spray test

Table D-3: Myzus persicae - spray test

 Table D-4: Myzus persicae - spray test

 * found = effect found; calc. = Effect calculated according to the Colby formula

Claims

claims 1. Active substance combinations containing a compound of the formula (Ia)

wherein a) A ¹ and A ² each represent CH and R is a radical from the series H, F ₂ HC, F ₂ CIC, H ₃ CF ₂ C, F ₃ C, Br, H ₃ C, F and CI, or b) A ^{1 is} N and A ^{2 is} CH stands and R stands for F ₃ C or c) A ¹ stands for CH and A ² stands for N and R stands for F3C, and at least one further active ingredient or product which is an insecticide or an acaricide or a nematicide or a Is a fungicide, an antimicrobial compound or a biological plant protection product. 2. Use of an active ingredient combination according to claim 1 for combating animal Pests. 3. Use of an active ingredient combination according to claim 1 for the treatment of seeds. 4. Use of an active ingredient combination according to claim 1 on transgenic plants. 5. A process for the preparation of a crop protection agent, characterized in that an active ingredient combination according to claim 1 is mixed with extenders and / or surface-active substances.