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WO2019203040A1 - Composition nettoyante - Google Patents

Composition nettoyante Download PDF

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Publication number
WO2019203040A1
WO2019203040A1 PCT/JP2019/015285 JP2019015285W WO2019203040A1 WO 2019203040 A1 WO2019203040 A1 WO 2019203040A1 JP 2019015285 W JP2019015285 W JP 2019015285W WO 2019203040 A1 WO2019203040 A1 WO 2019203040A1
Authority
WO
WIPO (PCT)
Prior art keywords
mass
component
cleaning composition
composition according
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2019/015285
Other languages
English (en)
Japanese (ja)
Inventor
繁郎 高橋
一明 鈴木
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shiseido Co Ltd
Original Assignee
Shiseido Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shiseido Co Ltd filed Critical Shiseido Co Ltd
Priority to JP2020514087A priority Critical patent/JP7366885B2/ja
Priority to CN201980026509.4A priority patent/CN111936112A/zh
Publication of WO2019203040A1 publication Critical patent/WO2019203040A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/14—Preparations for removing make-up
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/18—Sulfonic acids or sulfuric acid esters; Salts thereof derived from amino alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen

Definitions

  • This disclosure relates to a cleaning composition.
  • the present disclosure relates to a cleaning composition applicable to the skin.
  • Patent Document 1 discloses an aqueous liquid detergent composition applicable to a foam discharge pump container (pump former).
  • the aqueous liquid detergent composition described in Patent Document 1 includes (A) one or more detergent surfactants selected from (A) higher fatty acid salts and / or betaine-type amphoteric surfactants, and (B) HLB 8-12.
  • Patent Document 2 discloses a detergent composition containing an N-methyl taurine alkali metal salt of a fatty acid having a specific structure as an essential component.
  • the aqueous liquid detergent composition described in Patent Document 1 cannot discharge high-quality foam with a pump former.
  • Patent Document 2 cannot exhibit sufficient cleaning power for cosmetics, for example.
  • a cleaning composition (A) a fatty acid having 8 to 24 carbon atoms or a salt thereof, (B) a taurine derivative or a salt thereof, and (C) a glycerin derivative represented by the following chemical formula 1 A cleaning composition is provided.
  • the molar ratio of the component (A) to the component (B) is 0.5 to 2 mol of the component (B) with respect to 1 mol of the component (A).
  • any one of R 1 , R 2 and R 3 is an alkyl group, alkenyl group or acyl group having 4 to 15 carbon atoms, and the other two are hydrogen groups. .
  • the cleaning composition of the present disclosure can be applied to a pump former. Bubbles discharged from the pump former of the cleaning composition of the present disclosure are elastic and difficult to defoam during cleaning. Thereby, the user can obtain a favorable feeling of use. On the other hand, the cleaning composition of the present disclosure can exhibit high detergency even for components that are difficult to clean, such as cosmetics.
  • At least a part of the component (A) and at least a part of the component (B) are ions of the component (A) and the component (B) in the cleaning composition.
  • the taurine derivative is taurine, N-methyltaurine, N, N-dimethyltaurine, N, N-trimethyltaurine, N-ethyltaurine, N, N-diethyltaurine, N, N, N-triethyl taurine, N-propyl taurine, N, N-dipropyl taurine, and N, N, N-tripropyl taurine, and at least one of these salts.
  • the content of component (A) is 0.5% by mass to 7% by mass with respect to the mass of the cleaning composition.
  • the content of component (B) is 0.5% by mass to 7% by mass with respect to the mass of the cleaning composition.
  • the component (C) contains ethylhexyl glycerin.
  • the content of component (C) is 0.5% by mass to 5% by mass with respect to the mass of the cleaning composition.
  • the cleaning composition comprises (D) 2% by mass to 17.5% by mass of an anionic surfactant and (E) 1% by mass to 17.5% by mass. And an amphoteric surfactant.
  • the component (D) contains polyoxyethylene alkyl ether sulfate and / or acylmethyl taurate.
  • the component (E) is a betaine type.
  • the cleaning composition comprises (F) 2.5% by mass to 17% by mass of a nonionic surfactant, and (G) 0.2% by mass to 3% by mass. And an oily component (excluding component (A)).
  • the cleaning composition contains polyoxyethylene fatty acid glyceryl having an HLB of 9 to 14 as the component (F).
  • the cleaning composition further contains (H) 0.5% by mass to 5% by mass of an alkylene oxide derivative represented by the following chemical formula 2.
  • AO is an oxyalkylene group having 3 to 4 carbon atoms
  • EO is an oxyethylene group
  • m and n are average addition moles of oxyalkylene groups and oxyethylene groups having 3 to 4 carbon atoms, respectively.
  • 1 ⁇ m ⁇ 70 and 1 ⁇ n ⁇ 70, and the ratio of the oxyethylene group to the total of the oxyalkylene group and the oxyethylene group is 20 to 80% by mass.
  • R 4 and R 5 may be the same or different and each is a hydrocarbon group having 1 to 4 carbon atoms or a hydrogen atom, and R 4 and R 5 may be the same or different. (The ratio of the number of hydrogen atoms to the number of hydrocarbon groups is 0.15 or less.)
  • AO is an oxypropylene group.
  • m is 5 or more and 45 or less.
  • n is 12 or more and 40 or less.
  • R 4 and R 5 are each a methyl group.
  • component (H) in component (H), the sum of m and n is 10 or more and 80 or less.
  • the cleaning composition further comprises (I) 0.05% by mass to 0.5% by mass of a pH buffering agent.
  • the cleaning composition further contains (J) 0.05% by mass to 0.5% by mass of an inorganic salt.
  • the cleaning composition further contains (K) 60% by mass to 85% by mass of water.
  • the cleaning composition has a viscosity of 50 mPa ⁇ s or less.
  • the cleaning composition is applied to a foaming pump that does not use high-pressure gas.
  • the cleaning composition is used as a cosmetic cleaning agent.
  • the cleaning composition according to the first embodiment of the present disclosure will be described.
  • the cleaning composition of the present disclosure can be applied to, for example, cleaning the skin, and in particular, can be applied to cleaning cosmetics (makeup) on the skin.
  • the “substantial amount” refers to an amount that can produce an effect by adding the compound.
  • POE is an abbreviation for polyoxyethylene and POP is an abbreviation for polyoxypropylene, and the numbers in parentheses after POE or POP represent the average number of moles of POE groups or POP groups in the compound.
  • the cleaning composition of the present disclosure contains (A) a fatty acid or a salt thereof, (B) a taurine derivative or a salt thereof, and (C) a glycerin derivative represented by Chemical Formula 2 below.
  • R 6 can be a saturated hydrocarbon group or an unsaturated hydrocarbon group.
  • R 6 is preferably a saturated hydrocarbon group.
  • R 6 can be a linear hydrocarbon group or a branched hydrocarbon group.
  • R 6 is preferably a linear hydrocarbon group.
  • R 6 has preferably 8 or more carbon atoms, and more preferably 10 or more carbon atoms.
  • R 6 preferably has 24 or less carbon atoms, more preferably 22 or less.
  • Examples of the fatty acid (A) include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, toluic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), and docosahexaene.
  • An acid (DHA) etc. can be mentioned.
  • Examples of fatty acid salts include sodium salts and potassium salts of such fatty acids.
  • the content rate of a fatty acid or its salt is preferably 0.5% by mass or more, more preferably 0.8% by mass or more, and more preferably 1% by mass or more with respect to the mass of the composition. Further preferred. When the component (A) is less than 0.5% by mass, the formation of ion pairs with the component (B) described later is reduced, and the foam quality is lowered.
  • the content rate of a fatty acid or its salt is 7 mass% or less, 6 mass% or less, 5 mass% or less, 4 mass% or less, 3 mass% or less with respect to the mass of a composition, or 2. It can be 5 mass% or less. If it is at least within this range, the foam quality can be improved.
  • taurine derivative or salt thereof examples include taurine, N-methyltaurine, N, N-dimethyltaurine, N, N, N-trimethyltaurine, N-ethyltaurine, N, N-diethyltaurine, N, N, N -Triethyl taurine, N-propyl taurine, N, N-dipropyl taurine, N, N, N-tripropyl taurine, and salts thereof.
  • a salt of a taurine derivative for example, a sodium salt or a potassium salt of such a taurine derivative can be used.
  • component (B) can be sodium N-methyltaurine.
  • the content of the taurine derivative or a salt thereof is preferably 0.5% by mass or more, more preferably 0.8% by mass or more, and 1% by mass or more with respect to the mass of the composition. And more preferred.
  • the component (B) is less than 0.5% by mass, the formation of ion pairs with the component (A) described later is reduced, and the foam quality is lowered.
  • the content rate of a taurine derivative or its salt is 7 mass% or less, 6 mass% or less, 5 mass% or less, 4 mass% or less, 3 mass% or less, or 2 with respect to the mass of a composition, for example. .5% by mass or less. If it is this range, foam quality can be improved.
  • component (A) and component (B) form an ion pair to form a fatty acid soap.
  • component (A) and component (B) are fatty acid N-methyl taurine salt (R 6 —COO ⁇ + NH 2 (CH 3 ) (CH 2 ) 2 SO 3 X) (X represents an alkali metal).
  • the fatty acid N-methyltaurine salt can increase the resilience of the foam formed by the pump former and can increase the persistence of the foam during use.
  • the molar ratio of the component (A) and the component (B) in the cleaning composition is preferably 0.5 mol or more, and 0.7 mol or more with respect to 1 mol of the component (A). And more preferred.
  • the component (B) is preferably 2 mol or less, more preferably 1.8 mol or less, relative to 1 mol of the component (A). With such a molar ratio, it is considered that fatty acid taurine salts are easily formed.
  • the content of the fatty acid taurine salt is preferably 2% by mass or more, and more preferably 3% by mass or more with respect to the mass of the composition.
  • the content of the fatty acid taurine salt is preferably 10% by mass or less, and more preferably 8% by mass or less, based on the mass of the composition.
  • any of the compounds shown in the following chemical formula 3 can be used.
  • any one of R 1 , R 2 and R 3 is an alkyl group, an alkenyl group or an acyl group, and the other two are hydrogen atoms.
  • the alkyl group, alkenyl group or acyl group preferably has 4 or more carbon atoms. If the carbon number is less than 4, sufficient cleaning action cannot be obtained.
  • the alkyl group, alkenyl group or acyl group preferably has 15 or less carbon atoms, more preferably 12 or less. If the carbon number exceeds 15, sufficient cleaning action cannot be obtained.
  • the glycerin derivative can improve the cleaning property and foamability (foam increase property) of the cleaning composition.
  • component (C) examples include ethylhexylglycerin (octoxyglycerin), glyceryl isooctanoate, polyglyceryl-2 laurate, and glyceryl monooctanoate. Of these, ethylhexylglycerin having a C2-C2-ethylhexyl group is preferable from the viewpoint of detergency. Examples of commercially available ethylhexylglycerin include Sensiva® SC50 (manufactured by Schulke® & ® Mayr).
  • the content of the (C) glycerin derivative is preferably 0.5% by mass or more, more preferably 0.7% by mass or more, and further preferably 1% by mass or more with respect to the mass of the composition. preferable. If the component (C) is less than 0.5% by mass, sufficient detergency cannot be obtained.
  • the content rate of the said (C) glycerol derivative can be 5 mass% or less, 4 mass% or less, 3.5 mass% or less, or 3 mass% or less with respect to the mass of a composition.
  • the content of the (C) glycerin derivative is preferably 2.8% by mass or less, more preferably 2.4% by mass or less, and further preferably 2% by mass or less with respect to the mass of the composition. preferable. If the component (C) exceeds 5% by mass, the elasticity of the foam is lowered.
  • the cleaning composition of the present disclosure may further contain an anionic surfactant. By adding an anionic surfactant, foam quality can be improved.
  • anionic surfactant examples include fatty acid soap (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate); alkyl ether sulfates (eg, , POE-lauryl ether sulfate triethanolamine, POE-lauryl ether sulfate sodium, laureth sulfate Na, etc.); N-acyl sarcosine acids (eg, lauroyl sarcosine sodium, etc.); higher fatty acid amide sulfonates (eg, N-stearoyl- N-methyl taurine sodium, N-myristoyl-N-methyl taurine sodium, cocoyl methyl taurine Na, lauryl methyl tauride sodium, etc .; phosphate ester salt (POE-oleyl ether) Acid sodium, POE-stearyl ether phosphoric acid, etc.);
  • the anionic surfactant preferably contains, for example, polyoxyethylene alkyl ether sulfate and / or acylmethyl taurate.
  • the content of the anionic surfactant is preferably 2% by mass or more, more preferably 3% by mass or more, and further preferably 4% by mass or more based on the mass of the composition. When the content of the anionic surfactant is less than 2% by mass, the detergency is lowered and the transparency of the composition is lowered.
  • the content of the anionic surfactant is 17.5% by mass or less, 17% by mass or less, 15% by mass or less, 13% by mass or less, 12% by mass or less, 10% by mass with respect to the mass of the composition. % Or less, 9 mass% or less, or 8 mass% or less. If it is this range, high detergency and foamability can be obtained.
  • the fatty acid taurine salt is not included in the (A) anionic surfactant shown here.
  • the cleaning composition of the present disclosure may further contain an amphoteric surfactant. By adding an amphoteric surfactant, the foam quality can be improved.
  • amphoteric surfactants examples include imidazoline-based amphoteric surfactants (eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide). Side-1-carboxyethyloxy disodium salt, etc.); betaine surfactants (for example, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine) , Sulfobetaine, etc.).
  • imidazoline-based amphoteric surfactants eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide).
  • amphoteric surfactant is preferably a betaine.
  • the amphoteric surfactant preferably includes, for example, cocamidopropyl betaine and / or imidazolinium betaine.
  • the content of the amphoteric surfactant is preferably 1% by mass or more, more preferably 1.5% by mass or more, and further preferably 2% by mass or more with respect to the mass of the composition. .
  • the transparency of a composition will fall that the content rate of an amphoteric surfactant is less than 1 mass%.
  • the content of the amphoteric surfactant is 17.5% by mass or less, 17% by mass or less, 15% by mass or less, 13% by mass or less, 12% by mass or less, and 10% by mass with respect to the mass of the composition.
  • it can be 8 mass% or less, 7 mass% or less, or 6 mass% or less. If it is this range, high detergency and foamability can be obtained.
  • the fatty acid taurine salt is not included in the (E) anionic surfactant shown here.
  • the cleaning composition of the present disclosure may further contain a nonionic surfactant. Detergency can be further improved by containing a nonionic surfactant.
  • Nonionic surfactants include, for example, POE-sorbitan fatty acid esters (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc.); POE- Sorbit fatty acid esters (eg, POE-sorbite monolaurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerin monostearate) , POE-glycerol monoisostearate, POE-glycerol triisostearate, etc., POE-monooleate, etc.); POE-fatty acid esters (eg POE-distearate, POE-mono) Oleate, ethylene glycol distearate, etc.); POE-
  • POE-beeswax lanolin derivatives eg POE-sorbite beeswax
  • alkanolamides eg coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide etc.
  • POE-propylene glycol fatty acid ester eg coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide etc.
  • POE-propylene glycol fatty acid ester eg coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide etc.
  • POE-propylene glycol fatty acid ester eg coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide etc.
  • POE-propylene glycol fatty acid ester eg coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanol
  • the HLB of the nonionic surfactant is preferably 9 or more, and more preferably 10 or more. When the HLB is less than 9, the transparency of the composition is lowered.
  • the HLB of the nonionic surfactant is preferably 14 or less, and more preferably 13 or less. If the HLB exceeds 14, the cleaning performance is lowered and the foam discharge performance by the pump former is also lowered.
  • the nonionic surfactant preferably contains, for example, polyoxyalkylene fatty acid glyceryl.
  • the nonionic surfactant is preferably, for example, polyoxyethylene glyceryl isostearate.
  • the content of the nonionic surfactant is preferably 2.5% by mass or more, more preferably 3% by mass or more, and more preferably 3.5% by mass or more with respect to the mass of the composition. And more preferably 4% by mass or more. If the nonionic surfactant is less than 2.5% by mass, the detergency deteriorates.
  • the content rate of a nonionic surfactant is 17 mass% or less, 15 mass% or less, 13 mass% or less, 12 mass% or less, 11 mass% or less, 9 mass% with respect to the mass of a composition. Hereinafter, it can be 7 mass% or less, 6 mass% or less, or 5 mass% or less.
  • the cleaning composition of the present disclosure may further contain an oily component. Detergency can be further improved by containing an oil component.
  • oil component for example, liquid fats, solid fats, waxes, hydrocarbons, higher fatty acids, higher alcohols, synthetic ester oils, silicone oils and the like can be used.
  • liquid oils examples include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern castor oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.
  • solid fat examples include cacao butter, palm oil, horse fat, hydrogenated palm oil, palm oil, beef tallow, sheep fat, hydrogenated beef tallow, palm kernel oil, pork fat, beef bone fat, owl kernel oil, hydrogenated oil, cattle Leg fats, moles, hydrogenated castor oil and the like.
  • waxes examples include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, and reduced lanolin.
  • hydrocarbon oil examples include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, and microcrystalline wax.
  • higher fatty acid examples include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, toluic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid ( DHA) and the like.
  • higher alcohols examples include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyl decanol, isostearyl alcohol, octyldodecanol, etc.) can be used.
  • linear alcohols eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol
  • branched chain alcohols eg, monostearyl glycerin ether (batyl alcohol)
  • 2-decyltetradecinol lanolin alcohol
  • cholesterol phytosterol
  • hexyl decanol
  • Synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, apple Acid diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid
  • Silicone oils include dimethylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, stearoxymethylpolysiloxane, polyether-modified organopolysiloxane, fluoroalkyl / polyoxyalkylene co-modified organopolysiloxane, and alkyl-modified organopolysiloxane.
  • silicone compounds such as terminal-modified organopolysiloxane, fluorine-modified organopolysiloxane, amino-modified organopolysiloxane, silicone gel, acrylic silicone, trimethylsiloxysilicic acid, and silicone RTV rubber.
  • the content of the oil component is preferably 0.2% by mass or more, more preferably 0.3% by mass or more, and 0.5% by mass or more with respect to the mass of the composition. Further preferred. If the oil component is less than 0.2% by mass, the detergency deteriorates.
  • the content rate of an oil-based component is preferable in it being 3 mass% or less with respect to the mass of a composition, it is more preferable in it being 2.5 mass% or less, and it is further more preferable in it being 2 mass% or less. When the oil component exceeds 3% by mass, the elasticity of the foam is lowered and the transparency of the composition is also lowered.
  • the oil component may contain fatty acids.
  • the component (A) is not included in the component (G) shown here. That is, the content rate shown here does not include the content rate of the component (A).
  • the ratio of “) anionic surfactant and (E) the total mass of amphoteric surfactant” (referred to herein as “ionic ratio”) is preferably 0.35 or more, and more preferably 0.4 or more. And more preferably 0.5 or more. If the ionicity ratio is less than 0.35, foaming and foam discharge from the pump former are reduced. The ionicity ratio is preferably 0.9 or less, and more preferably 0.85 or less. When the ionicity ratio exceeds 0.9, the detergency is reduced. In Equation 1, the sign indicates the mass of each component.
  • the ratio of “(D) the mass of the anionic surfactant” to “the total mass of the (D) anionic surfactant and (E) the amphoteric surfactant” represented by the following formula 2 is preferably 0.1 or more, more preferably 0.15 or more, more preferably 0.2 or more, and more preferably 0.3 or more. Is more preferably 4 or more, and further preferably 0.5 or more. If the anionic ratio is less than 0.1, the detergency and foaming properties are reduced.
  • the anionic ratio is preferably 0.9 or less, and more preferably 0.8 or less. When the anionic ratio exceeds 0.9, it becomes cloudy and a transparent composition is not formed. Moreover, the foaming property and the foam discharge property by a pump former will also fall.
  • symbol has described the mass of each component.
  • the cleaning composition of the present disclosure may further contain an oily component. Detergency can be further improved by containing an oil component.
  • any of the compounds shown in the following chemical formula 4 can be used.
  • AO is an oxyalkylene group having 3 to 4 carbon atoms, preferably oxypropylene.
  • EO is an oxyethylene group.
  • m and n are the average added mole numbers of oxyalkylene groups and oxyethylene groups having 3 to 4 carbon atoms, respectively.
  • m is preferably 1 or more, and more preferably 5 or more.
  • m is preferably 70 or less, and more preferably 45 or less.
  • n is preferably 1 or more, and more preferably 12 or more.
  • n is preferably 70 or less, and more preferably 40 or less.
  • the total number of m and n is preferably 10 or more, more preferably 20 or more, and more preferably 30 or more.
  • the total number of m and n is preferably 120 or less, more preferably 100 or less, and further preferably 80 or less.
  • the ratio of the oxyethylene group to the total of the oxyalkylene group and the oxyethylene group is preferably 20% by mass to 80% by mass.
  • the oxyalkylene group and the oxyethylene group may be added in a block form or may be added in a random form.
  • R 4 and R 5 are a C 1-4 hydrocarbon group or hydrogen atom which may be the same or different.
  • the ratio of the number of hydrogen atoms to the number of hydrocarbon groups of R 4 and R 5 is preferably 0.15 or less.
  • R 4 and R 5 are each preferably a methyl group.
  • the content of the (H) alkylene oxide derivative is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and 0.5% by mass or more with respect to the mass of the composition. More preferably, it is more preferably 1% by mass or more, and further preferably 2% by mass or more. When the component (H) is less than 0.05% by mass, a foam with good foam quality cannot be produced.
  • the content rate of a component (H) can also be 1.5 mass% or more, 2 mass% or more, or 2.5 mass% or more with respect to the mass of a composition.
  • the content of the (H) alkylene oxide derivative is, for example, 10% by mass or less, 7% by mass or less, 5% by mass or less, 3% by mass or less, 2.5% by mass or less, or the mass of the composition, or It can be 2 mass% or less.
  • the cleaning composition of the present disclosure may further contain a pH buffer.
  • a pH buffering agent By adding a pH buffering agent, it is possible to suppress the pH drop and increase the foam persistence.
  • pH buffering agent examples include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.
  • the content of the pH buffering agent is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and 0.2% by mass or more with respect to the mass of the composition. And more preferably 0.25% by mass or more. If the pH buffer is less than 0.05% by mass, the pH cannot be adjusted sufficiently.
  • the content of the pH buffering agent is preferably 1% by mass or less, and more preferably 0.5% by mass or less, based on the mass of the composition.
  • the cleaning composition of the present disclosure may further contain an inorganic salt.
  • foam quality can be improved.
  • inorganic salts include sodium chloride, potassium chloride, potassium nitrate, and potassium sulfate.
  • the content of the inorganic salt is preferably 0.05% by mass or more and more preferably 0.1% by mass or more with respect to the mass of the composition. If the component (J) is less than 0.05% by mass, the foam quality cannot be sufficiently improved.
  • the content rate of a component (J) can also be 0.2 mass% or more or 0.25 mass% or more with respect to the mass of a composition, for example.
  • the content rate of a component (J) can be 1 mass% or less, 0.5 mass% or less, or 0.3 mass% or less with respect to the mass of a composition, for example.
  • the cleaning composition of the present disclosure can further contain water in addition to the components described above.
  • water the water used for cosmetics, a quasi-drug, etc. can be used, For example, purified water, ion-exchange water, tap water, etc. can be used.
  • the aqueous phase can further contain a water-soluble alcohol depending on the purpose.
  • the water content can be 60% by mass or more based on the mass of the composition.
  • the content rate of water can be 85 mass% or less with respect to the mass of a composition.
  • the composition of the present disclosure can be suitably used in a pump former.
  • the cleaning composition of the present disclosure has other components such as an aqueous solvent, a cationic surfactant, a lipophilic nonionic surfactant, a powder, a humectant, and a water-soluble component as long as the effects of the present disclosure are not impaired.
  • aqueous solvent a cationic surfactant
  • a lipophilic nonionic surfactant a powder
  • a humectant a humectant
  • a water-soluble component as long as the effects of the present disclosure are not impaired.
  • aqueous solvent examples include water, alcohol, and a mixture thereof.
  • water-soluble alcohols include lower alcohols, polyhydric alcohols, polyhydric alcohol polymers, divalent alcohol alkyl ethers, dihydric alcohol alkyl ethers, dihydric alcohol ether esters, glycerin monoalkyl ethers, sugar alcohols, Examples thereof include at least one selected from monosaccharides, oligosaccharides, polysaccharides and derivatives thereof.
  • lower alcohols examples include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.
  • polyhydric alcohol examples include divalent alcohols (for example, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, Pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohol (eg, glycerin, trimethylolpropane, etc.); tetravalent alcohol (eg, 1, 2, 6) Pentaerythritol, such as hexanetriol, etc .; pentavalent alcohol (eg, xylitol, etc.); hexavalent alcohol (eg, sorbitol, mannitol, etc.); polyhydric alcohol polymer (eg, diethylene glycol, dipropylene glycol, Ethylene glycol, polypropylene glycol, tetraethylene glycol,
  • monosaccharides include tricarbon sugars (for example, D-glyceryl aldehyde, dihydroxyacetone, etc.), tetracarbon sugars (for example, D-erythrose, D-erythrose, D-threoose, erythritol, etc.), Pentose sugars (for example, L-arabinose, D-xylos, L-lyxose, D-arabinose, D-ribose, D-ribose, D-xylulose, L- Xylose, etc.), hexose (eg, D-glucose, D-talose, D-psicose, D-galactose, D-fructose, L-galactose, L- Mannose, D-tagatose, etc.), heptose sugar (eg, aldoheptose, heptulose, etc.), octose sugar (
  • the oligosaccharide is, for example, at least one selected from sucrose, gunthianose, umbelliferose, lactose, planteose, isoliquinoses, ⁇ , ⁇ -trehalose, raffinose, lycnose, umbilicin, stachyose, verbusose, etc. Can be mentioned.
  • polysaccharide examples include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran, kerato sulfate. And at least one selected from locust bean gum, succinoglucan, and caronic acid.
  • Examples of other polyols include at least one selected from polyoxyethylene methyl glucoside (Glucam E-10), polyoxypropylene methyl glucoside (Glucam P-10) and the like.
  • Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (eg, cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N′-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salt; alkyldimethylbenzylammonium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; POE-alkylamine; Examples include alkylamine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride and the like.
  • alkyltrimethylammonium salts eg, stearyltrimethylammonium chloride, lauryltrimethyl
  • lipophilic nonionic surfactant examples include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan Trioleate, penta-2-ethylhexyl diglycerol sorbitan, tetra-2-ethylhexyl diglycerol sorbitan, etc.); glycerin polyglycerin fatty acid (eg mono cottonseed oil fatty acid glycerin, monoerucic acid glycerin, sesquioleate glycerin, glyceryl monostearate) , ⁇ , ⁇ '-oleic acid pyroglutamate glycerin, monostearate glycerin malate, etc.); propylene glycol fatty acid esters (eg mono
  • the term “powder” used in this specification is synonymous with “powder”.
  • the powder is not particularly limited as long as it can be generally used for cosmetics and the like.
  • examples of the powder include inorganic powders (for example, talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, red mica, biotite, lithia mica, calcined mica, calcined talc, permiculite, Magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, glass, barium sulfate, calcined calcium sulfate (baked gypsum), Calcium phosphate, fluorapatite, hydroxyapatite, ceramic powder, metal soap (eg, zinc myristate, calcium palmitate, aluminum stearate), boron
  • humectant examples include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate Sodium lactate, bile salt, dl-pyrrolidone carboxylate, alkylene oxide derivative, short-chain soluble collagen, diglycerin (EO) PO adduct, Izayoi rose extract, yarrow extract, merirot extract and the like.
  • EO diglycerin
  • natural water-soluble polymers include plant-based polymers (for example, gum arabic, tragacanth gum, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (guckweed extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid); microbial polymer (eg, xanthan gum, dextran, succinoglucan, pullulan, etc.); animal polymer (eg, collagen, casein, albumin, gelatin, etc.), etc. Is mentioned.
  • plant-based polymers for example, gum arabic, tragacanth gum, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (guckweed extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid);
  • Semi-synthetic water-soluble polymers include, for example, starch polymers (eg, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate) Hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder and the like); alginic acid polymers (for example, sodium alginate, propylene glycol alginate, etc.) and the like.
  • starch polymers eg, carboxymethyl starch, methylhydroxypropyl starch, etc.
  • cellulose polymers methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate Hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder and the like
  • alginic acid polymers for example, sodium
  • Synthetic water-soluble polymers include, for example, vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer); polyoxyethylene polymers (eg, polyethylene glycol 20,000, 40). , 000, 60,000 polyoxyethylene polyoxypropylene copolymer, etc.); acrylic polymers (for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimine; cationic polymers, and the like.
  • vinyl polymers eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer
  • polyoxyethylene polymers eg, polyethylene glycol 20,000, 40. , 000, 60,000 polyoxyethylene polyoxypropylene copolymer, etc.
  • acrylic polymers for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.
  • polyethyleneimine
  • thickener examples include gum arabic, carrageenan, caraya gum, gum tragacanth, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, carboxymethylcellulose (CMC), hydroxyethylcellulose , Hydroxypropyl cellulose, polyvinyl alcohol (PVA), polyvinyl methyl ether (PVM), PVP (polyvinyl pyrrolidone), sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarint gum, dialkyldimethylammonium sulfate cellulose, xanthan gum, silica Magnesium aluminum silicate, bentonite, hectorite, silicic acid Mini um magnesium (Veegum), laponite, silicic anhydride, taurates based synthetic polymers, acrylate-based synthetic polymers, and the like
  • the coating agent examples include an anionic coating agent (for example, (meth) acrylic acid / (meth) acrylic acid ester copolymer, methyl vinyl ether / maleic anhydride polymer), and a cationic coating agent (for example, cation Cellulose, dimethyldiallylammonium chloride polymer, dimethyldiallylammonium chloride / acrylamide copolymer, etc.), nonionic coating agent (eg, polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl acetate, polyacrylate copolymer, (meth) Acrylamide, polymer silicone, silicone resin, trimethylsiloxysilicate, etc.).
  • an anionic coating agent for example, (meth) acrylic acid / (meth) acrylic acid ester copolymer, methyl vinyl ether / maleic anhydride polymer
  • a cationic coating agent for example, cation Cellulose, dimethyldiallylammonium chloride polymer, dimethyldially
  • ultraviolet absorber examples include benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester.
  • PABA paraaminobenzoic acid
  • PABA monoglycerin ester N, N-dipropoxy PABA ethyl ester
  • N, N-diethoxy PABA ethyl ester examples include benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester.
  • PABA paraaminobenzoic acid
  • sequestering agent examples include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate.
  • amino acids examples include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.), and the like.
  • amino acid derivatives include acyl sarcosine sodium (lauroyl sarcosine sodium), acyl glutamate, acyl ⁇ -alanine sodium, glutathione, and pyrrolidone carboxylic acid.
  • organic amines examples include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. Is mentioned.
  • polymer emulsion examples include acrylic resin emulsion, polyethyl acrylate emulsion, acrylic resin liquid, polyacryl alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, and the like.
  • vitamins examples include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, and biotin.
  • antioxidants examples include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.
  • antioxidant assistant examples include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, ethylenediaminetetraacetic acid and the like.
  • ingredients that can be blended include, for example, preservatives (ethyl paraben, butyl paraben, chlorphenesin, phenoxyethanol, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.
  • preservatives ethyl paraben, butyl paraben, chlorphenesin, phenoxyethanol, etc.
  • anti-inflammatory agents eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.
  • Whitening agent eg, placenta extract, saxifrage extract, arbutin, etc.
  • various extracts eg, buckwheat, auren, shikon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape , Yokuinin, Loofah, Lily, Saffron, Senkyu, Pepper, Hypericum, Onis, Garlic, Pepper, Chimpi, Toki, Seaweed, etc.
  • Activator eg, Royal Jelly, Photosensitizer, Cholesterol Derivative, etc.
  • composition of the present disclosure includes caffeine, tannin, verapamil, tranexamic acid and derivatives thereof, various herbal extracts such as licorice, karin, and yew, etc., tocopherol acetate, glycyrrhizic acid, glycyrrhizic acid and derivatives or salts thereof, etc.
  • Drugs, vitamin C, magnesium ascorbate phosphate, glucoside ascorbate, whitening agents such as arbutin and kojic acid, amino acids such as arginine and lysine, and derivatives thereof can also be contained as appropriate.
  • the viscosity of the cleaning composition of the present disclosure is preferably 100 mPa ⁇ s or less, and more preferably 50 mPa ⁇ s or less.
  • the cleaning composition of this indication can be used conveniently with a pump former as it is 100 mPa * s or less.
  • the viscosity can be measured with a Brookfield viscometer (spindle number 1, rotation speed 60 rpm) at 30 ° C.
  • the cleaning composition of the present disclosure can be applied to a pump former (foaming pump) that manually pushes a nozzle into a container and generates the cleaning agent as foam without using a high-pressure gas.
  • a pump former foaming pump
  • the foam obtained by foaming the cleaning composition of the present disclosure with a pump former has high resilience, and the maintenance (holding) of foam is further enhanced. By increasing the persistence of the foam, it is possible to increase the cleaning power and give the user a good feel.
  • the cleaning composition of the present disclosure further has a high cleaning power.
  • the detergent composition of the present disclosure can be suitably applied to, for example, a cosmetic removal detergent, a hand soap, a body soap, a hair cleaner, a kitchen cleaner, and the like.
  • the cleaning composition of the present disclosure can be easily removed even if it is a water-proof cosmetic (makeup).
  • composition of the present disclosure has a transparent appearance that gives a favorable impression to the user.
  • the cleaning composition of the present disclosure can be produced by a generally known method without using a specific method.
  • a detergent composition can be prepared by mixing the above components.
  • the fatty acid taurine salt which is a complex of the component (A) and the component (B)
  • the fatty acid taurine salt can be prepared by warming and dissolving the component (A) in water and adding the component (B) to the aqueous solution of the component (A).
  • the detergent composition of this indication can be manufactured by adding the fatty acid taurine salt prepared previously.
  • the behavior of each component may be unknown.
  • the component (A) and the component (B) are considered to form a fatty acid taurine salt, but the structure or behavior of the component (A) and the component (B) is directly specified. It is difficult or not nearly practical. Accordingly, the cleaning composition of the present disclosure should be allowed to be described by its manufacturing method if it cannot be directly identified by composition.
  • the cleaning composition of the present disclosure will be described below with examples. However, the cleaning composition of the present disclosure is not limited to the following examples. Moreover, although the following example demonstrates the example which applied the cleaning composition of each test example to washing
  • the unit of the content rate of each component shown in each table is mass%.
  • Test Examples 1 to 9 A cleaning composition was prepared and discharged from a pump former, and the discharged bubbles were evaluated according to the following criteria.
  • the used pump former is a commonly used type in which the nozzle is manually pushed into the container from the top to the bottom, and bubbles are discharged from the nozzle.
  • the viscosity was measured using the Brookfield type viscometer (spindle number 1, rotation speed 60rpm) in 30 degreeC.
  • Tables 1 and 2 show the composition and evaluation of each composition.
  • the foam quality evaluation shown in the table was evaluated according to the following criteria.
  • the component (H) has a notation corresponding to the chemical formula shown in Chemical Formula 2, and PO indicates that AO in the chemical formula shown in Chemical Formula 2 is an oxypropylene group.
  • the fatty acid can improve the foam quality if it is 0.5% by mass or more, preferably 1% by mass or more with respect to the mass of the composition.
  • a taurine derivative can improve foam quality if it is 0.5 mass% or more with respect to the mass of a composition, Preferably it is 1 mass% or more.
  • the molar ratio of the component (A) to the component (B) in the composition is preferably 0.1 mol or more, and 0.5 mol or more with respect to 1 mol of the component (A). More preferably.
  • the molar ratio of the component (A) to the component (B) is preferably 10 mol or less and more preferably 5 mol or less with respect to 1 mol of the component (A).
  • Test Examples 8 to 10 In Test Examples 8 to 10, the influence of (C) glycerin derivative on foam quality and detergency was mainly examined. The test method and evaluation criteria are the same as in Test Examples 1-7. Table 3 shows the composition and evaluation of each composition.
  • glycerin derivative is 0.5% by mass or more, preferably 1% by mass or more based on the mass of the composition, it is considered that the detergency can be sufficiently improved.
  • a glycerol derivative can be 5 mass% or less with respect to the mass of a composition.
  • Test Examples 11 to 17 In Test Examples 11 to 17, the effects of components other than the components (A) to (C) were tested.
  • the component (J) Comparing Test Example 11 in which the inorganic salt was not added with Test Examples 12 to 15 in which the component (J) was added, the compositions of Test Examples 12 to 15 showed higher foam elasticity. did it. From this, it is thought that addition of an inorganic salt is effective in improving foam quality.
  • the component (J) is preferably 0.05% by mass or more and more preferably 0.1% by mass or more with respect to the mass of the composition.
  • the foam quality of the composition of Test Example 13 was the best. This is considered to be due to an increase in the amount of the component (H) alkylene oxide derivative. Accordingly, the component (H) is more preferably 0.05% by mass or more, more preferably 0.5% by mass or more, and more preferably 1% by mass or more with respect to the mass of the composition. It is considered that 2% by mass or more is more preferable.
  • the content of (D) anionic surfactant is preferably 2% by mass or more with respect to the mass of the composition. Moreover, a component (D) can be 12 mass% or less with respect to the mass of a composition. (E) It is thought that the content rate of an amphoteric surfactant is preferable in it being 1 mass% or more with respect to the mass of a composition. Moreover, a component (E) can be 8 mass% or less with respect to the mass of a composition. It is considered that the anionic ratio is preferably 0.2 or more. The anionic ratio is considered to be preferably 0.9 or less.
  • test Examples 2 to 7 and 11 to 17 (F) a nonionic surfactant and (G) an oil component are added. Compared with Test Examples 9 and 10 to which Component (F) and Component (G) were not added, Test Examples 2 to 7 and 11 to 17 showed improved detergency. From this, it is considered that the component (F) and the component (G) are effective for improving the cleaning property.
  • the component (F) is preferably 2.5% by mass or more, more preferably 3% by mass or more, more preferably 3.5% by mass or more, and more preferably 4% by mass with respect to the mass of the composition. It is considered that the above is more preferable.
  • the component (G) is preferably 0.2% by mass or more, more preferably 0.3% by mass or more, and further preferably 0.5% by mass or more with respect to the mass of the composition. Get it. It is considered that the ionicity ratio is preferably 0.35 or more. It is considered that the ionicity ratio is preferably 0.9 or less.
  • the cleaning composition of the present disclosure can be suitably used for skin cleaning.
  • the composition of the present disclosure can be suitably used for cleaning for removing cosmetics on the skin.
  • the composition of the present disclosure can be suitably applied as a content to be put in a pump former.

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Abstract

La composition nettoyante contient (A) un acide gras en C8-24 ou un sel de celui-ci, (B) un dérivé de taurine ou un sel de celui-ci, et (C) un dérivé de glycérine. Le rapport molaire du composant (A) et du composant (B) est de 0,5 à 2 moles de composant (B) par mole de composant (A).
PCT/JP2019/015285 2018-04-18 2019-04-08 Composition nettoyante Ceased WO2019203040A1 (fr)

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CN201980026509.4A CN111936112A (zh) 2018-04-18 2019-04-08 洗涤剂组合物

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WO2019203040A1 true WO2019203040A1 (fr) 2019-10-24

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WO2022014487A1 (fr) * 2020-07-16 2022-01-20 株式会社Adeka Procédé d'amélioration de l'effervescence et de la qualité de mousse d'une composition d'agent de nettoyage, et procédé de nettoyage de la peau ou des cheveux
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EP4183452A4 (fr) * 2020-07-16 2024-07-24 Adeka Corporation Procédé d'amélioration de l'effervescence et de la qualité de mousse d'une composition d'agent de nettoyage, et procédé de nettoyage de la peau ou des cheveux
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