WO2019198728A1 - 熱間プレス成形品の製造方法、プレス成形品、ダイ金型、及び金型セット - Google Patents
熱間プレス成形品の製造方法、プレス成形品、ダイ金型、及び金型セット Download PDFInfo
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- WO2019198728A1 WO2019198728A1 PCT/JP2019/015517 JP2019015517W WO2019198728A1 WO 2019198728 A1 WO2019198728 A1 WO 2019198728A1 JP 2019015517 W JP2019015517 W JP 2019015517W WO 2019198728 A1 WO2019198728 A1 WO 2019198728A1
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- die
- layer
- mold
- hot press
- hardness
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D37/00—Tools as parts of machines covered by this subclass
- B21D37/01—Selection of materials
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/02—Stamping using rigid devices or tools
- B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
- B21D22/201—Work-pieces; preparation of the work-pieces, e.g. lubricating, coating
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
- B21D22/208—Deep-drawing by heating the blank or deep-drawing associated with heat treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D24/00—Special deep-drawing arrangements in, or in connection with, presses
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D35/00—Combined processes according to or processes combined with methods covered by groups B21D1/00 - B21D31/00
- B21D35/002—Processes combined with methods covered by groups B21D1/00 - B21D31/00
- B21D35/005—Processes combined with methods covered by groups B21D1/00 - B21D31/00 characterized by the material of the blank or the workpiece
- B21D35/007—Layered blanks
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D53/00—Making other particular articles
- B21D53/88—Making other particular articles other parts for vehicles, e.g. cowlings, mudguards
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/012—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of aluminium or an aluminium alloy
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
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- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
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- C—CHEMISTRY; METALLURGY
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- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
- C21D1/25—Hardening, combined with annealing between 300 degrees Celsius and 600 degrees Celsius, i.e. heat refining ("Vergüten")
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing
- C21D8/0421—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for deep-drawing characterised by the working steps
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- C21—METALLURGY OF IRON
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
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- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/02—Pretreatment of the material to be coated
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/10—Oxidising
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/10—Oxidising
- C23C8/12—Oxidising using elemental oxygen or ozone
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
- C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
- C23C8/10—Oxidising
- C23C8/12—Oxidising using elemental oxygen or ozone
- C23C8/14—Oxidising of ferrous surfaces
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
- C21D9/48—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals deep-drawing sheets
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
Definitions
- the present disclosure relates to a method for manufacturing a hot press-formed product, a press-formed product, a die mold, and a mold set.
- a material having a high mechanical strength tends to have a low shape freezing property in a forming process such as a bending process. That is, when processing into a complicated shape, the processing itself becomes difficult.
- One of the means for solving this problem of formability includes so-called “hot press molding (hot press method, high temperature press method, die quench method)”. In this hot press forming, a steel sheet to be formed is once heated to a high temperature, and then the steel sheet softened by heating is pressed and formed, and then cooled.
- the steel plate is once heated to a high temperature and softened, so that the steel plate can be easily pressed. Furthermore, the mechanical strength of the steel sheet can be increased by the quenching effect by cooling after forming. Therefore, by this hot press molding, a molded product having both good shape freezing property and high mechanical strength can be obtained.
- Zinc (Zn) -based plated steel sheets obtained by plating zinc which has a sacrificial anticorrosive action on steel sheets, are widely used in automobile steel sheets and the like from the viewpoints of corrosion resistance and steel sheet production technology.
- the heating temperature in hot press molding 700-1000 ° C
- the surface plating layer evaporates, causing a significant deterioration in surface properties. It may become.
- an Al-based metal-coated steel plate having a boiling point higher than that of a Zn-based metal coating that is, a so-called aluminum (Al) -plated steel plate, for a steel plate subjected to hot press forming heated to a high temperature.
- an Al-based metal coating By applying an Al-based metal coating, it is possible to prevent the scale from adhering to the surface of the steel sheet, and a process such as a descaling process becomes unnecessary, thereby improving productivity. Further, since the Al-based metal coating also has a rust prevention effect, the corrosion resistance after painting is also improved.
- the Al coating When an Al-based metal coating is applied, depending on the preheating conditions before press forming, the Al coating first melts and then changes to an aluminum-iron alloy layer by Fe diffusion from the steel sheet. Furthermore, an aluminum-iron alloy layer may grow to an aluminum-iron alloy layer up to the surface of the steel sheet.
- the aluminum-iron alloy is also referred to as “Al—Fe alloy” or “alloy”. Since this alloy layer is extremely hard, a working rod is formed by contact with a mold during press working. Suppression of this processing flaw is a problem when hot-pressing an Al-plated steel sheet.
- Patent Document 1 discloses a zinc oxide film (hereinafter also referred to as “ZnO film”) and the like for the purpose of improving chemical treatment and corrosion resistance as well as hot lubricity in order to prevent the occurrence of work defects.
- ZnO film a zinc oxide film
- a method of forming a wurtzite type compound film on the surface of an Al-plated steel sheet is disclosed.
- Patent Document 2 discloses a film of one or more Zn compounds selected from the group consisting of Zn hydroxide, Zn phosphate, and organic acid Zn for the purpose of enhancing the adhesion of the ZnO film during press molding. Discloses a method for forming a surface of an Al-plated steel sheet. In the method of Patent Document 2, a ZnO film is formed by heat when hot-pressing an Al-plated steel sheet on which a Zn compound film is formed, and a ZnO film having excellent adhesion is formed. , Film adhesion, spot weldability, and post-coating corrosion resistance can be improved.
- Patent Document 3 discloses a mold having a coating layer on the surface by a physical vapor deposition method. The outermost layer is coated with at least three layers of the a layer, the c layer just above the base material, and the b layer between the a layer and the c layer, and the hardness symbol HV0.025 of the three layers. There is disclosed a metal mold for plastic working in which the hardness and the layer thickness are adjusted to a specific relationship.
- Patent Document 1 International Publication No. 2009/131233
- Patent Document 2 Japanese Unexamined Patent Application Publication No. 2014-139350
- Patent Document 3 Japanese Patent No. 4771223
- each of the plated steel sheets of Patent Documents 1 and 2 is excellent in hot lubricity and can suppress the occurrence of work defects.
- the hot press forming mold slide on which the plated steel plate slides, such as the vertical wall portion and flange portion of the press-formed product. Wear occurs on the moving surface. For this reason, in the high surface pressure portion of hot press molding, it is necessary to care for the die as a countermeasure against wear occurring on the sliding surface of the die.
- An object of the present disclosure is to suppress the occurrence of wear on the sliding surface of a die mold when hot-pressing an Al-plated steel sheet having a zinc compound layer or a metal zinc layer as an outermost layer on an Al-plated layer. It is to provide a method for producing a hot press-formed product.
- the subject of the present disclosure is a die mold that suppresses the occurrence of wear on the sliding surface, a mold set of a die mold and a punch mold, and a mold set of a die mold and a steel plate presser mold. Is to provide. Moreover, the subject of this indication is providing the press molded product which was excellent in surface quality and the generation
- the gist of the present disclosure is as follows. ⁇ 1> A method for producing a hot press-formed product, which is hot press-molded using a die mold on an Al-plated steel sheet having a zinc compound layer or a metal zinc layer as an outermost layer on the Al plating layer, The die mold is formed on the outer surface of the die hole and in the entire area adjacent to the die shoulder portion of the steel plate contact surface that comes into contact with the Al-plated steel plate before hot press forming.
- ⁇ 2> The method for producing a hot press-formed product according to ⁇ 1>, wherein the skewness (Rsk) of the hard layer is ⁇ 5.0 or more.
- ⁇ 3> The method for producing a hot press-formed product according to ⁇ 1> or ⁇ 2>, wherein the hard layer is a layer including a nitride layer and a hard coating layer on a surface of the nitride layer.
- the hard coating layer has a hardness Hv_Die of HV3200 or less.
- ⁇ 5> The method for producing a hot press-formed product according to ⁇ 4>, wherein the hard coating layer is a layer containing Cr.
- ⁇ 6> The method for producing a hot press-formed product according to ⁇ 3>, wherein the hard coating layer is a layer containing Ti and having a hardness Hv_Die of HV3160 or less.
- ⁇ 7> The method for producing a hot press-formed product according to any one of ⁇ 3> to ⁇ 6>, wherein the hard coating layer has a hardness Hv_Die of HV2500 to HV3000.
- the radius of curvature [R min ] at a position where the radius of curvature is minimum in the second ridge line portion is 3 mm or more and less than 10 mm
- the difference [SaA1 ⁇ SaA2] between the smoothness [SaA2] at the central location PA2 min in the horizontal section height direction of the vertical wall portion is 0.20 ⁇ m
- the radius of curvature [R min ] at a position where the radius of curvature is minimum in the second ridge line portion is 3 mm or more and less than 10 mm
- the skewness (Rsk) measured in the direction from the outside to the inside of the die hole is 1. in all regions adjacent to the die shoulder among the outer surface of the die hole and the die shoulder adjacent surface adjacent to the die shoulder.
- the skewness (Rsk) of the hard layer is ⁇ 5.0 or more.
- the hard layer is a layer including a nitride layer and a hard coating layer on a surface of the nitride layer.
- ⁇ 13> The die mold according to ⁇ 12>, wherein the hard coating layer has a hardness Hv_Die of 3200 or less.
- ⁇ 14> The die mold according to ⁇ 13>, wherein the hard coating layer is a layer containing Cr.
- ⁇ 15> The die mold according to ⁇ 12>, wherein the hard coating layer is a layer containing Ti and having a hardness Hv_Die of HV3160 or less.
- ⁇ 16> The die mold according to any one of ⁇ 12> to ⁇ 15>, wherein the hard coating layer has a hardness Hv_Die of HV2500 to HV3000.
- ⁇ 17> ⁇ 10> to ⁇ 16>, the die die according to any one of the above, and a punch die
- the punch mold is directed from the outside to the inside of the punch portion in the entire area facing the portion where the die mold has the hard layer, of the facing surface facing the die shoulder adjacent surface of the die mold.
- ⁇ 18> The mold set according to ⁇ 17>, wherein the skewness (Rsk) of the second hard layer is ⁇ 5.0 or more.
- ⁇ 24> ⁇ 10> to ⁇ 16>, comprising the die mold according to any one of the above and a steel plate presser mold,
- the steel plate presser mold has an inner surface from the outside of the punch insertion portion to the entire area facing the portion where the die mold has the hard layer, of the facing surface facing the die shoulder adjacent surface of the die mold.
- the die set which has the 2nd hard layer whose skewness (Rsk) measured to the direction which goes to 1.3 or less, and hardness Hv_Die is HV2000 or more.
- ⁇ 26> The mold set according to ⁇ 24> or ⁇ 25>, wherein the second hard layer is a layer including a second nitride layer and a second hard coating layer on a surface of the second nitride layer.
- the second hard coating layer has a hardness Hv_Die of HV3200 or less.
- the second hard coating layer is a layer containing Cr.
- the second hard coating layer is a layer containing Ti and having a hardness Hv_Die of HV3160 or less.
- ⁇ 30> The mold set according to any one of ⁇ 26> to ⁇ 29>, wherein the second hard coating layer has a hardness Hv_Die of HV2500 to HV3000.
- the occurrence of wear on the sliding surface of a die mold is suppressed when hot-pressing an Al-plated steel sheet having a zinc compound layer or a metal zinc layer as the outermost layer on the Al-plated layer.
- a method for producing a hot press-formed product can be provided.
- a die mold that suppresses the occurrence of wear on the sliding surface a mold set of a die mold and a punch mold, and a mold set of a die mold and a steel plate presser mold.
- FIG. 4B is a cross-sectional view of the press-formed product shown in FIG.
- FIG. 4A It is a schematic diagram which shows an example of the molded article obtained by the hot press molding shown in FIG. It is a schematic diagram which shows an example of the plated steel plate hot-press-molded with a die die and a punch die. It is a schematic sectional drawing which shows an example of the Al plating steel plate used for this embodiment. It is a schematic block diagram which shows the evaluation apparatus of hot lubricity.
- the method for manufacturing a hot press-formed product according to the present embodiment is a hot press-forming process using a die mold on an Al-plated steel sheet having a zinc compound layer or a metal zinc layer as an outermost layer on an Al plating layer. It is a manufacturing method of a press-formed product.
- the die mold is formed on the entire surface adjacent to the die shoulder portion of the steel plate contact surface which is the outer surface of the die hole and is in contact with the Al-plated steel plate before hot press forming. It has a hard layer having a skewness (Rsk) measured in the direction from the outside to the inside of the hole of 1.3 or less and a hardness Hv_Die of HV2000 or more.
- the manufacturing method of the hot press-formed product according to the present embodiment suppresses the occurrence of wear on the sliding surface of the die mold that occurs at the high surface pressure portion during the hot press forming by the above configuration. And the manufacturing method of the hot press molded product which concerns on this embodiment was discovered by the knowledge shown below.
- Patent Documents 1 and 2 for the purpose of suppressing the adhesion of the aluminum adhesion to the die, a plated steel sheet (hereinafter referred to as “with ZnO film”) on which the surface of the Al plating layer provided on both surfaces of the steel sheet is formed.
- Al-plated steel sheet a plated steel sheet (hereinafter referred to as “with ZnO film”) on which the surface of the Al plating layer provided on both surfaces of the steel sheet is formed.
- Al-plated steel sheet Al-plated steel sheet ”.
- the surface of the Al plating layer is covered with the ZnO film, so that even when hot press-molding, the adhesion of the aluminum adhesion to the surface of the die mold due to seizure is suppressed.
- the coefficient of friction with the surface of the die mold is reduced.
- the outer surface of the die hole of the die mold and adjacent to the die shoulder portion of the steel plate contact surface that comes into contact with the Al-plated steel plate before hot press forming. It has a hard layer in all areas.
- the skewness (Rsk) measured in the direction from the outside of the die hole to the inside of the hard layer is 1.3 or less.
- the skewness Rsk is defined in JIS B 0601 (2001), and is an index representing the symmetry between the peak and the valley with respect to the average line. When this Rsk is positive (0 ⁇ Rsk), it indicates a state in which peaks and valleys are unevenly distributed below the average line.
- the hard layer has a hardness Hv_Die of HV2000 or higher.
- the method for manufacturing a hot press-formed product according to the present embodiment is a method for manufacturing a hot press-formed product in which a plated steel sheet is heated and then pressed with a die die to perform hot press forming. And in hot press molding, the plated steel plate heated to high temperature is press-molded with a metal mold
- a steel plate is drawn into a die hole of a die mold.
- the edge (die shoulder part) of the die hole protrudes and curves toward the outside of the die hole, the steel sheet shrinks and deforms when it is drawn into the die hole.
- the thickness increases as the steel plate approaches the edge of the die hole (die shoulder) in the shrinkage flange deformation.
- a high surface pressure is applied to the steel plate.
- wrinkles are generated in the steel sheet as the steel sheet approaches the edge of the die hole (die shoulder) in the shrinkage flange deformation.
- the die mold of this embodiment includes a hard layer at a location where high surface pressure is generated.
- FIG. 1 shows a plated steel sheet that is hot press formed by a die mold, a holder (steel plate holding mold), and a punch.
- 2A and 2B show a hot press-formed product formed by the die mold of FIG.
- FIG. 1 is a cross-sectional view corresponding to a cross section in the y direction when the hot press-formed product 30 shown in FIG. 2A is formed by a die mold.
- the longitudinal direction of the hot press-formed product 30 is the x direction
- the direction observed from the vertical wall portion 33 side among the directions orthogonal to the x direction is the y direction
- the x direction and the y direction The direction observed from the top plate portion 31 side is the z direction.
- the hot press-formed product 30 includes two vertical wall portions 33, a top plate portion 31 that connects the two vertical wall portions 33 via the first ridge line portion 32, and two vertical wall portions. And a flange portion 35 connected to the opposite side of the top plate portion 31 via the second ridge line portion 34.
- the flange portion 35 has a shape having a portion PB0 min where the curvature radius is minimum. That is, the flange portion 35 has a portion that is curved in the longitudinal direction (x direction), and the curvature radius of the flange portion 35 as a whole is not constant.
- the top plate portion 31 also has a portion that is curved in the longitudinal direction (x direction).
- the hot press-formed product formed by the die mold according to the present embodiment is not limited to the shape shown in FIGS. 2A and 2B.
- the top plate portion and the flange portion may be a molded product having a flat shape.
- 3B is a cross-sectional view taken along the line AA ′ in FIG. 3A.
- the longitudinal direction of the hot press-formed product 40 is the x direction
- the direction observed from the vertical wall 43 side among the directions orthogonal to the x direction is the y direction
- the direction observed from the top plate 41 side is the z direction.
- the hot press-formed product 40 includes two vertical wall portions 43, a top plate portion 41 connecting the two vertical wall portions 43 via the first ridge line portion 42, and two vertical wall portions. 43, and a flange portion 45 connected to the opposite side of the top plate portion 41 through the second ridge line portion 44.
- this hot press-formed product 40 when a cross section in a direction orthogonal to the longitudinal direction (x direction) (cross section, for example, the cross section shown in FIG. 3B) is observed, the cross section cut is observed where. Is also a shape in which the radius of curvature of the second ridge line portion 44 has the same value. Moreover, it becomes a left-right symmetric shape even if it observes the cross section cut
- the hot press-molded product molded by the die according to the present embodiment is not limited to those having a symmetrical shape in the cross section as shown in FIGS. 3A and 3B, for example, FIG. 4A and FIG. Like the center pillar shown to 4B, the molded product of the shape from which right and left differ in cross-sectional view may be sufficient.
- 4B is a cross-sectional view taken along the line BB ′ in FIG. 4A. 4A and 4B, the longitudinal direction of the hot press-formed product 50 is the x direction, and the direction observed from the vertical wall portion 53a side among the directions orthogonal to the x direction is the y direction, and is orthogonal to the x direction and the y direction.
- the hot press-formed product 50 shown in FIGS. 4A and 4B includes two vertical wall portions 53a and 53b and a top plate portion 51 that connects the two vertical wall portions 53a and 53b via first ridge line portions 52a and 52b, respectively. And flange portions 55a and 55b connected to the two vertical wall portions 53a and 53b on the opposite side of the top plate portion 51 via the second ridge line portions 54a and 54b, respectively.
- there are portions where the left and right shapes are not symmetrical when a cross section (transverse cross section) in a direction orthogonal to the longitudinal direction (x direction) is observed. For example, in the cross section shown in FIG.
- the heights in the z direction of the two first ridge lines 52a and 52b existing on both sides of the flat top plate 51 are different, and the right first ridge line 52a is on the left side. It is a shape that rises and becomes higher in the z direction than the first ridge line portion 52b. 4B, the two flange portions 55a and 55b have different z-direction heights, and the right flange portion 55a has a higher shape than the left flange portion 55b. And in this hot press molded product 50, when the cross section is observed, the second ridge line portions 54a and 54b have different radii of curvature depending on where they are cut, and the second ridge line portion in the cross section shown in FIG. 4B This is a shape in which the radius of curvature of 54a is minimized.
- hot press-formed product 30 for example, hot press-formed product 30
- a punch 13 having a flat top surface is pressed against the plated steel sheet 10 to form a die hole.
- the plated steel sheet 10 flows into the die hole 11D.
- the flange is deformed and the hot press-formed product 20 becomes thicker.
- a die mold (die) 11 is formed on a die shoulder 11B of a steel plate contact surface 11A that is in contact with a plated steel plate 10 that is an outer surface of a die hole 11D and is not hot press-formed.
- the entire adjacent region has the hard layer 11C.
- the holder (steel plate pressing die) 12 has a second hard surface in an entire area of the opposing surface facing the steel plate contact surface 11A of the die die 11 where the die die 11 faces the portion having the hard layer 11C. It is desirable to have layer 12C.
- the second hard layer 12C satisfies the skewness (Rsk) and the hardness Hv_Die, when the Al-plated steel sheet is hot press formed, wear on the sliding surface of the holder 12 generated at the high surface pressure portion occurs. Is suppressed.
- the hard layer 11C is preferably formed over the entire circumference along the die shoulder 11B.
- the second hard layer 12 ⁇ / b> C is preferably formed over the entire circumference along a portion facing the die shoulder 11 ⁇ / b> B of the die die 11.
- the shape of the hot press-formed product to be formed is not limited to the shape shown in FIGS. 2A and 2B, FIGS. 3A and 3B, FIGS. 4A and 4B, and the like.
- various other press-formed products such as a press-formed product having a hat-like shape shown in FIG. 5 can be manufactured.
- the entire area adjacent to the die shoulder portion of the steel plate contact surface which is the outer surface of the die hole and is in contact with the Al-plated steel plate before hot press molding
- the die mold generated at the high surface pressure portion Generation of wear on the sliding surface is suppressed.
- hot press-molded product manufacturing method in hot press molding, for example, blanking (punching) is performed as necessary, and then heated to a high temperature to soften the plated steel sheet. And using the metal mold
- subsequent plating can be easily performed by once softening the plated steel sheet.
- the hot-pressed press-molded product is quenched by heating and cooling, and becomes a molded product having a high tensile strength of about 1500 MPa or more.
- heating method for hot press forming it is possible to adopt a heating method by infrared heating, electric heating, induction heating, etc. in addition to a normal electric furnace and radiant tube furnace. Heating is performed in an oxidizing atmosphere.
- the die mold according to the present embodiment is not particularly limited in its use.
- hot pressing is performed on an Al plated steel sheet having a zinc compound layer or a metal zinc layer as an outermost layer on an Al plated layer. It can be used as a die mold or the like.
- the skewness (Rsk) measured in the direction from the outside of the die hole to the inside of the die shoulder adjacent surface adjacent to the die shoulder of the outer surface of the die hole and the die shoulder adjacent surface. It has a hard layer having a hardness of 1.3 or less and a hardness Hv_Die of HV2000 or more.
- the skewness (Rsk) of the hard layer is more preferably 1.0 or less, and even more preferably 0.8 or less.
- the lower limit of the skewness (Rsk) of the hard layer is preferably ⁇ 5.0 or more, more preferably from the viewpoint of suppressing an increase in manufacturing cost due to surface control for reducing the skewness (Rsk). Is -3.0 or more.
- the lower limit of the skewness (Rsk) of the hard layer is preferably 0 or more from the viewpoint of suppressing adhesion to the mold.
- the range of skewness (Rsk) of the hard layer is preferably 0 or more and 1.3 or less, more preferably 0 or more and 1.0 or less, and further preferably 0 or more and 0.8 or less.
- the skewness Rsk is measured according to JIS B 0601 (2001). Specifically, the skewness Rsk is measured under the following measurement conditions in accordance with JIS B 0601 (2001).
- the method of controlling the skewness (Rsk) measured in the direction from the outside to the inside of the die hole in the hard layer is not particularly limited.
- the surface of the formed hard layer is polished and polished in the direction from the outside to the inside of the die hole during this polishing (that is, the direction in which the plated steel sheet slides during hot press forming).
- the direction in which the abrasive sheet is slid is changed from the outside to the inside of the die hole.
- measuring the skewness (Rsk) for the entire area adjacent to the die shoulder means that the skewness (Rsk) is measured at a dense pitch of 20 mm or less in the area adjacent to the die shoulder.
- the hardness Hv_Die of the hard coating layer is preferably HV3200 or less.
- HV3200 or less scraping of the Al plating and the zinc compound layer or the metal zinc layer in the Al plated steel sheet is suppressed, and adhesion to the die mold is suppressed.
- the hardness Hv_Die is particularly preferably 3200 or less.
- the hardness Hv_Die is more preferably HV3160 or less. By being HV3160 or less, scraping of the Al plating and the zinc compound layer or the metal zinc layer in the Al plated steel sheet is suppressed, and adhesion to the die mold is suppressed.
- the hardness Hv_Die of the hard coating layer is more preferably HV2500 or more and HV3000 or less.
- HV2500 or more and HV3000 or less adhesion to the mold is suppressed.
- the hardness Hv_Die refers to the Vickers hardness specified by JIS-Z-2244 (2009). In this specification, the hardness value with a test load of 0.2452N is used in the Vickers hardness test method. is there. HM-115 manufactured by Mitutoyo Corporation is used for the micro Vickers testing machine.
- a hard coating layer (deposited film) by a physical vapor deposition method (PVD method) can be mentioned.
- PVD method a physical vapor deposition method
- a method for forming a hard layer on a die mold includes a method for forming a deposited film by physical vapor deposition.
- a method for forming a deposited film by physical vapor deposition There are no particular restrictions on the type of physical vapor deposition. Further, a chemical vapor deposition (CVD) method may be used.
- CVD chemical vapor deposition
- the physical vapor deposition method for example, an arc ion plating method and a sputtering method are desirable.
- the metal element portion is preferably one of nitride, carbide, and carbonitride mainly composed of one or more selected from Ti, Cr, and Al. Furthermore, it is more preferable that the metal element portion is any one of nitride, carbide, and carbonitride mainly composed of Ti or Cr.
- Ti, Cr or Al (or Ti or Cr) is 70 (atomic%) or more in a ratio of only the metal (including semi-metal) composition part excluding nitrogen and carbon. Furthermore, it is preferable to be 90 (atomic%) or more (including substantially 100 (atomic%)).
- a PVD film can be formed on the surface of the material.
- a lower nitride layer is formed (surface hardening treatment using diffusion called nitriding treatment). Is preferred.
- the formation of the nitride layer is performed by, for example, ion nitriding treatment on the die mold base material, that is, ion nitriding treatment by adjusting the temperature in an N 2 and H 2 gas atmosphere of a predetermined concentration.
- a compound layer called a nitride layer called a white layer formed by nitriding treatment causes a decrease in adhesion, so it is not formed by controlling processing conditions or removed by polishing or the like. It is desirable to do.
- the metal material of the base material of the die mold is not particularly defined, and known metal materials such as cold die steel, hot die steel, high speed steel and cemented carbide can be used.
- improved metal types that have been proposed as steel types that can be used in conventional molds, including standard metal types (steel types) according to JIS and the like, can also be applied.
- a die set is a combination of a die die and a punch die having a convex portion corresponding to the die hole of the die die and a facing surface facing the steel plate contact surface (die shoulder adjacent surface) of the die die. It is.
- the mold set is a steel plate presser mold having a die mold and a face that faces the steel plate contact surface of the die mold (surface adjacent to the die shoulder) and a hole through which a punch inserted into the die hole passes. Also includes a (holder) combination.
- the first mold set according to this embodiment includes the die mold according to the above-described embodiment and a punch mold.
- the punch mold is directed from the outside to the inside of the punch portion in the entire area facing the location where the die mold has the hard layer, of the facing surface facing the die shoulder adjacent surface (steel plate contact surface) of the die mold.
- the second hard layer has a skewness (Rsk) measured in the direction of 1.3 or less and a hardness Hv_Die of HV2000 or more.
- the die mold (die) 111 shown in FIG. 6 is the die shoulder portion of the steel plate contact surface 111A that is the outer surface of the die hole 111D and is in contact with the plated steel plate 10 before hot press forming.
- the entire region adjacent to 111B has a hard layer 111C.
- the punch (punch mold) 113 has the second hard layer in the entire area facing the portion where the die mold 111 has the hard layer 111C among the facing surfaces facing the steel plate contact surface 111A of the die mold 111. It is desirable to have 113C. This is because the plated steel sheet 10 that is wrinkled when approaching the bottom dead center of forming contacts with a portion where the second hard layer 113C is present.
- the second mold set according to this embodiment includes the above-described die mold according to this embodiment and a steel plate presser mold.
- the steel plate presser mold is the inner surface from the outside of the punch insertion part to the entire area facing the location where the die mold has a hard layer in the facing surface facing the die shoulder adjacent surface (steel plate contact surface) of the die mold.
- the second hard layer has a skewness (Rsk) measured in the direction toward ⁇ 1.3 and a hardness Hv_Die of HV2000 or more.
- the holder (steel plate holding die) 12 shown in FIG. 1 is a portion where the die mold 11 has the hard layer 11C among the opposed surfaces facing the steel plate contact surface 11A of the die mold 11. It is desirable to have the 2nd hard layer 12C in the whole field which counters.
- the Al plated steel sheet has a zinc compound layer or a metal zinc layer as an outermost layer on the Al plated layer.
- aluminum plating layers 114A and 114B are provided on both surfaces (upper surface and lower surface) of the steel plate 112, and a zinc compound layer or metal is used as the outermost layer on the aluminum plating layers 114A and 114B.
- Zinc layers 116A and 116B are provided.
- the steel plate on which plating is applied is, for example, high mechanical strength (for example, tensile strength, yield point, elongation, drawing, hardness, impact value, fatigue strength, creep strength, etc.) Steel sheet having a variety of properties related to deformation and fracture).
- high mechanical strength for example, tensile strength, yield point, elongation, drawing, hardness, impact value, fatigue strength, creep strength, etc.
- Steel sheet having a variety of properties related to deformation and fracture An example of the steel plate (steel plate before plating) that realizes high mechanical strength used in the plated steel plate according to this embodiment is as follows.
- the description of% means the mass% unless there is particular notice.
- a numerical range expressed using “to” means a range including numerical values described before and after “to” as a lower limit value and an upper limit value.
- the steel sheet is, by mass, C: 0.01 to 0.6%, Si: 0.01 to 0.6%, Mn: 0.5 to 3%, Ti: 0.01 to 0.1%, and B: It is preferable that at least one of 0.0001 to 0.1% is contained and only the balance Fe and impurities are contained.
- C is included to ensure the desired mechanical strength.
- C is less than 0.01%, sufficient mechanical strength cannot be improved, and the effect of containing C becomes poor.
- C exceeds 0.6%, the steel sheet can be further hardened, but melt cracking tends to occur. Therefore, the C content is preferably 0.01% or more and 0.6% or less.
- Si is one of the strength improving elements for improving the mechanical strength, and is contained in the same manner as C to ensure the desired mechanical strength.
- Si is less than 0.01%, it is difficult to exert the effect of improving the strength and sufficient mechanical strength cannot be improved.
- Si is also an easily oxidizable element. Therefore, when Si exceeds 0.6%, wettability is lowered when hot-dip aluminum plating is performed, and non-plating may occur. Therefore, the Si content is preferably 0.01% or more and 0.6% or less.
- Mn is one of the strengthening elements that strengthens steel and is also one of the elements that enhances hardenability. Further, Mn is effective in preventing hot brittleness due to S which is one of impurities. When Mn is less than 0.5%, these effects cannot be obtained, and the above effects are exhibited when 0.5% or more. On the other hand, when Mn exceeds 3%, there is a possibility that the residual ⁇ phase becomes excessive and the strength is lowered. Therefore, the Mn content is preferably 0.5% or more and 3% or less.
- Ti is one of strength-enhancing elements and is an element that improves the heat resistance of the Al plating layer.
- Ti is less than 0.01%, the effect of improving the strength and the effect of improving the oxidation resistance cannot be obtained, and these effects are exhibited when the content is 0.01% or more.
- the Ti content is preferably 0.01% or more and 0.1% or less.
- B has the effect of increasing the strength by acting during quenching.
- B is less than 0.0001%, such an effect of improving the strength is low.
- B exceeds 0.1%, inclusions are formed and become brittle, which may reduce the fatigue strength. Therefore, the B content is preferably 0.0001% or more and 0.1% or less.
- this steel plate may contain impurities that are mixed in in other manufacturing processes.
- a steel plate formed of such chemical components can be quenched by heating such as hot press forming and have a mechanical strength of about 1500 MPa or more. Although it is a steel plate having such a high mechanical strength, since it can be hot-pressed in a state of being softened by heating if it is processed by hot press-forming, it can be easily formed. Further, the steel sheet can realize high mechanical strength, and can maintain or improve the mechanical strength even if it is thinned for weight reduction.
- Al plating layer The Al plating layer will be described.
- the component composition of the Al plating layer may contain 50% or more of Al.
- Elements other than Al are not particularly limited, but Si may be positively contained for the following reasons.
- the Si content in the Al plating layer is preferably 3 to 15%.
- the Al plating layer prevents corrosion of the steel sheet.
- the Al plating layer does not generate scale (iron oxide) by oxidizing the surface even when heated to a high temperature.
- the scale removal process, the surface cleaning process, the surface treatment process, and the like can be omitted, and the productivity of the molded product is improved.
- the Al plating layer has a boiling point and a melting point higher than those of a plating layer made of an organic material or a plating layer made of another metal material (for example, a Zn material).
- the Al plating layer is hard to evaporate, so that hot press molding at a high temperature is possible. Therefore, the moldability in the hot press molding can be further enhanced and molding can be easily performed.
- the Al plating layer can be alloyed with Fe in the steel sheet by heating during hot dipping and hot press forming. Therefore, the Al plating layer is not necessarily formed of a single layer having a constant component composition, and includes a partially alloyed layer (alloy layer).
- the adhesion amount of the Al plating layer is preferably 20 to 100 g / m 2 in terms of Al amount.
- the adhesion amount of the Al plating layer 20 g / m 2 or more, an appropriate amount of aluminum adherent is adhered to the sliding surface of the die mold, and the effect of suppressing wear of the sliding surface of the die mold is enhanced. .
- the corrosion resistance of the press-formed product is increased.
- the adhesion amount of the Al plating layer exceeds 100 g / m 2 , a large amount of aluminum adherent adheres to the sliding surface of the lower mold, and wear of the sliding surface of the die mold tends to occur. Rise.
- the adhesion amount of the Al plating layer is evaluated by the adhesion amount in terms of Al amount.
- the measurement of the adhesion amount of the Al plating layer uses the fluorescent X-ray method. Specifically, a calibration curve is created by fluorescent X-ray method using several kinds of standard samples with known adhesion amount (Al amount conversion) of the Al plating layer. Then, using the calibration curve, the Al strength of the sample to be measured is converted into the adhesion amount of the Al plating layer to obtain the adhesion amount of the Al plating layer.
- the Zn compound layer or the metal Zn layer is a ZnO film or a layer that becomes a ZnO film during hot press molding. Prior to hot press forming, the plated steel sheet is heated in an oxidizing atmosphere. At this time, the Zn compound layer or the metal Zn layer other than the ZnO film is oxidized to become a ZnO film.
- the Zn compound layer or metal Zn layer other than the ZnO film is not particularly limited as long as it is oxidized to become a ZnO film. Examples of the Zn compound layer other than the ZnO film include a zinc phosphate layer and a Zn-based metal soap layer.
- the Zn compound and the metal Zn may be mixed with a resin that is burned away by heating to form a Zn compound layer or a metal Zn layer other than the ZnO film.
- the amount of Zn contained in the Zn compound layer or the metal Zn layer is adjusted according to the amount of ZnO film deposited on the target product.
- the ZnO film is a film that is in contact with the die mold and is an outer surface of the press-formed product.
- the formation method of the ZnO film is not particularly limited, and can be formed on the Al plating layer by the methods described in Patent Documents 1 and 2, for example.
- the adhesion amount of the ZnO film is preferably 0.4 to 4.0 g / m 2 in terms of Zn amount from the viewpoint of the corrosion resistance of the product.
- the adhesion amount of the ZnO film is 0.4 g / m 2 or more in terms of Zn amount, the corrosion resistance of the press-formed product is increased.
- the adhesion amount of the ZnO film exceeds 4.0 g / m 2 in terms of Zn amount, the thickness of the Al plating layer and the ZnO film becomes too thick, and the weldability and paint adhesion may decrease.
- the adhesion amount of the ZnO film is more preferably 0.4 to 2.0 g / m 2 in terms of Zn amount.
- the adhesion amount of the Al plating layer is low, it is desirable that the adhesion amount of the ZnO film is high in the above range.
- a fluorescent X ray method is utilized as a measuring method of the adhesion amount of a ZnO film
- the press-formed product according to the present embodiment includes a steel base material, an alloyed hot-dip galvanized (Al plated) layer on the steel base material, and a zinc oxide (ZnO) layer as an outermost layer on the Al plated layer.
- the zinc oxide (ZnO) layer as the outermost layer is formed by heating when hot press forming is performed on the Al-plated steel sheet.
- the steel base material (steel plate) has a hardness Hv_Parts of HV400 or higher, preferably HV450 or higher, and more preferably HV550 or higher, from the viewpoint of obtaining high mechanical strength.
- the press-formed product according to the present embodiment includes a top plate portion, a vertical wall portion connected to the top plate portion via the first ridge line portion, and a flange portion connected to the vertical wall portion via the second ridge line portion. And a shape having For example, the hot press-formed product 40 having a flat hat-shaped cross section with the top plate portion having the shape shown in FIGS. 3A and 3B and the hot press-formed product 30 having the shape shown in FIGS. 2A and 2B.
- the hot press-formed product 30 includes two vertical wall portions 33, a top plate portion 31 that connects the two vertical wall portions 33 via the first ridge line portion 32, and two vertical wall portions. And a flange portion 35 connected to the opposite side of the top plate portion 31 via the second ridge line portion 34.
- the top plate portion 31 is a portion corresponding to the top surface of the punch during hot press forming
- the vertical wall portion 33 is a portion that slides with the punch and die mold
- the flange portion 35 is hot pressed. This is the part where molding is not performed.
- the first ridge line portion 32 is a curved portion that connects the top plate portion 31 and the vertical wall portion 33
- the second ridge line portion 34 is a curved portion that connects the vertical wall portion 33 and the flange portion 35.
- the top plate 31 also has a shape with a constant curvature radius as a whole.
- the radius of curvature [R min ] at a location where the radius of curvature is the smallest in the second ridge line portion 34 (that is, the location where bending is most severe) is 3 mm or more and less than 10 mm.
- the minimum curvature radius [R min ] at the second ridge line portion 34 is less than 10 when the press-molded product 30 is manufactured by hot pressing the Al-plated steel plate 33. It shows that a high surface pressure is applied to the location.
- the vertical wall portion 33 to which high surface pressure is applied is a press-molded product that has been hot press-molded under a condition in which abrasion due to sliding is likely to occur.
- the upper limit value of the minimum curvature radius [R min ] at the second ridge line portion 34 is 8 mm or less, it can be said that the vertical wall portion 33 is more likely to be scratched by sliding.
- the lower limit value of the minimum radius of curvature [R min ] at the second ridge line portion 34 is 3 mm or more, preferably 4 mm or more, from the viewpoint of preventing cracking during press molding.
- the radius of curvature is measured as follows.
- the three-dimensional shape on the outer surface of the second ridge line portion 34 is measured with a three-dimensional shape measuring instrument.
- the curvature radius [ Rmin ] in the location where a curvature radius becomes the smallest in a cross section is obtained.
- a difference in smoothness occurs between the top plate portion 31 and the vertical wall portion 33.
- Corresponding position that is, when observing from the y direction as shown in FIG. 2B, it is possible to reach the top plate portion without shifting in the x direction only by shifting in the z direction with respect to the location PB0 min on the flange portion 35.
- the smoothness [SaB1] is measured at a central location PB1 min in the width direction (that is, the y direction) of the top panel 31. Further, with respect to the vertical wall portion 33, the portion corresponding to the portion PB0 min when observed from the side surface side (that is, the portion PB0 min on the flange portion 35 when observed from the y direction as shown in FIG. 2B). at a central position PB2 min in the height direction (that is, the z direction) of the vertical wall portion 33). The smoothness [SaB2] is measured. It should be noted that the measurement is performed on the outer surface, that is, the surface that is in contact with the die during hot press molding at both the location PB1 min and the location PB2 min .
- the difference [SaB1-SaB2] is 0.30 ⁇ m or more.
- the difference [SaB1-SaB2] in the smoothness between the top plate portion 31 and the vertical wall portion 33 is in the above range when the press-formed product 30 is manufactured by performing hot press forming on an Al-plated steel plate.
- a higher surface pressure is applied to a portion that becomes the vertical wall portion 33 than a portion that becomes the top plate portion 31. This is because the surface of the vertical wall portion 33 becomes smoother than the top plate portion 31 by sliding the vertical wall portion 33 with high surface pressure.
- the difference in smoothness [SaB1 ⁇ SaB2] is 0.35 ⁇ m or more, it can be said that the vertical wall portion 33 is molded under the condition that a scratch due to sliding is likely to occur.
- the upper limit value of the difference in smoothness [SaB1-SaB2] is more preferably 2.0 ⁇ m or less from the viewpoint of sharpness after coating.
- the smoothness [SaB1] and [SaB2] refer to the arithmetic average height Sa (unit: ⁇ m) defined in ISO25178-2 (2012).
- the measuring apparatus and measurement conditions are as follows. Measuring device: VK-X250 / 150 shape analysis laser microscope manufactured by Keyence Co., Ltd. Measuring range: 5 mm ⁇ 5 mm centering on the center point of PB1 min and PB2 min Measurement conditions: Gaussian filter used S filter: Not used L filter: 4 mm
- the difference in the aspect ratio of the surface property between the top plate portion 31 and the vertical wall portion 33 is small.
- the surface texture aspect ratio [StrB1] and the surface texture aspect ratio [StrB2] at the location PB1 min and the location PB2 min are the same as the smoothness. taking measurement. As with the smoothness, all are measured on the outer surface, that is, the surface that is in contact with the die during hot press molding.
- the difference [StrB1-StrB2] is 0.50 or less.
- the surface pressure is higher than that of the portion to be, it is indicated that the product is a press-molded product in which the occurrence of scratches due to sliding in the vertical wall portion 33 is suppressed.
- the scratch due to sliding occurs remarkably, the scratch is streak, and thus the aspect ratio Str of the surface property of the portion is lowered.
- the part where the scratches are generated becomes a glossy part before coating. Furthermore, since the difference in glossiness appears after painting, it is visually recognized like a pattern and the surface quality is inferior.
- the press-formed product according to the first aspect in which the difference in gloss after coating is 25 or less can be realized, and excellent surface quality can be achieved.
- a press-molded product using a steel base material having a hardness Hv_Parts of HV400 or higher delayed fracture occurs due to reasons such as hydrogen embrittlement, particularly in a place where stress is concentrated during press molding. It is easy to generate.
- the press-molded product according to the first aspect since the occurrence of scratches in the vertical wall portion 33 is suppressed as described above, the concentration of stress on the vertical wall portion 33 is also suppressed. I can say that. Therefore, delayed fracture that is likely to occur at a stress concentration location is also suppressed.
- the difference in surface texture aspect ratio [StrB1-StrB2] is preferably 0.50 or less, and more preferably 0.40 or less, from the viewpoint of excellent surface quality and suppression of delayed fracture.
- the surface texture aspect ratios [StrB1] and [StrB2] refer to the surface texture aspect ratio Str defined in ISO25178-2 (2012).
- the measuring apparatus and measurement conditions are as follows. Measuring device: VK-X250 / 150 shape analysis laser microscope manufactured by Keyence Co., Ltd. Measuring range: 5 mm ⁇ 5 mm centering on the center point of PB1 min and PB2 min Measurement conditions: Gaussian filter used S filter: Not used L filter: 4 mm
- the method of controlling the difference in surface property aspect ratio [StrB1 ⁇ StrB2] between the top plate portion 31 and the vertical wall portion 33 within the above range is not particularly limited.
- molding a press molded product by the manufacturing method of the hot press molded product which concerns on a form is mentioned.
- adhesion to the die mold is suppressed. If a large amount of adherent adheres, the friction coefficient increases and scratches due to sliding easily occur.
- the increase in the friction coefficient is suppressed by reducing the adherend, and the vertical wall portion 33 Generation of scratches due to sliding is suppressed.
- the difference in surface texture aspect ratio [Str1-Str2] can be controlled within the above range.
- the hot press-formed product 40 includes two vertical wall portions 43, a flat top plate portion 41 connecting the two vertical wall portions 43 via the first ridge line portion 42, and two vertical wall portions 43.
- the flange portion 45 is connected to the wall portion 43 on the opposite side of the top plate portion 41 via the second ridge line portion 44.
- the top plate portion 41 is a portion corresponding to the top surface of the punch during hot press forming
- the vertical wall portion 43 is a portion that slides with the punch and die mold
- the flange portion 45 is hot pressed. This is the part where molding is not performed.
- the first ridge line portion 42 is a curved portion that connects the top plate portion 41 and the vertical wall portion 43
- the second ridge line portion 44 is a curved portion that connects the vertical wall portion 43 and the flange portion 45.
- the hot press-formed product 40 when observing a cross section (cross section, for example, the cross section shown in FIG. 3B) in a direction orthogonal to the longitudinal direction (x direction), the cross section cut is observed where Is also symmetrical. Further, the hot press-formed product 40 has a shape in which the radius of curvature of the second ridge line portion 44 has the same value regardless of where the cross section cut is observed. That is, the radius of curvature of the second ridge line portion 44 is constant in the cross section cut anywhere, in other words, the radius of curvature of the second ridge line portion 44 is the minimum value in the cross section cut anywhere.
- the hot press-formed product 50 shown in FIGS. 4A and 4B is a center pillar for automobiles, and includes two vertical wall portions 53a and 53b, two vertical wall portions 53a and 53b, and first ridge line portions 52a and 52b, respectively.
- a flat top plate portion 51 connected through the flange portions 55a and 55b connected to the two vertical wall portions 53a and 53b on the opposite side of the top plate portion 51 via the second ridge line portions 54a and 54b, respectively.
- Have The top plate portion 51 is a portion corresponding to the top surface of the punch during hot press forming, and the vertical wall portions 53a and 53b are portions that slide with the punch and die mold, and flange portions 55a and 55b. Is a portion where hot press molding is not performed.
- the first ridge line parts 52a and 52b are curved parts connecting the top plate part 51 and the vertical wall parts 53a and 53b
- the second ridge line parts 54a and 54b are the vertical wall parts 53a and 53b and the flange parts 55a and 55b. It is the curved part which connects.
- this hot press-formed product 50 there are portions where the left and right shapes are not symmetrical when a cross section (transverse cross section) in a direction orthogonal to the longitudinal direction (x direction) is observed.
- the heights in the z direction of the two first ridge lines 52a and 52b existing on both sides of the flat top plate 51 are different, and the right first ridge line 52a is on the left side.
- the hot press-formed product 50 has a shape in which the curvature radii of the second ridge line portions 54a and 54b are different depending on the portion to be cut when the cross section is observed, and the cross section shown in FIG. 4B (B-- in FIG. 4A). This is a shape in which the radius of curvature of the second ridge line portion 54a at the B 'cross section) is minimized.
- the radius of curvature [R min ] at a portion where the radius of curvature is the smallest in the second ridge line portion 44, 54a or 54b is 3 mm or more. It is less than 10 mm.
- the fact that the minimum radius of curvature [ Rmin ] at the second ridge line portion 44, 54a or 54b is less than 10 means that when the press-formed products 40 and 50 are manufactured by hot-pressing an Al-plated steel sheet. 3 shows that a high surface pressure is applied to a portion that becomes the vertical wall portion 43, 53a, or 53b.
- the vertical wall portion 43, 53a or 53b to which a high surface pressure is applied is a press-molded product that has been hot press-molded under a condition in which abrasion due to sliding is likely to occur.
- the upper limit of the minimum radius of curvature [R min ] at the second ridge line portion 44, 54a or 54b is 8 mm or less, it can be said that the vertical wall portion 43, 53a or 53b is more likely to be scratched by sliding.
- the lower limit value of the minimum radius of curvature [R min ] at the second ridge line portion 44, 54a or 54b is 3 mm or more, preferably 4 mm or more from the viewpoint of preventing cracking during press molding.
- the measurement of a curvature radius is performed according to the measuring method of the curvature radius in the 2nd ridgeline part in the above-mentioned 1st aspect.
- a difference in smoothness occurs between the top plate portion and the vertical wall portion.
- a cross section (transverse section) in a direction orthogonal to the longitudinal direction (x direction) of the press-formed product is observed, a cross section where the radius of curvature of the second ridge line portion is minimum is set as the measurement target. That is, in the case of the press-formed product 40 shown in FIGS. 3A and 3B, the curvature radius of the second ridge line portion 44 is the minimum value in any cross section cut at any location, and any cross section may be measured, and preferably The cross section at the center position in the longitudinal direction (x direction) is recommended.
- the radius of curvature of the second ridge line portion 54a in the cross section shown in FIG. 4B (the BB ′ cross section in FIG. 4A) is minimized.
- the cross section shown in FIG. And in the cross section where the radius of curvature is the smallest, the central location in the width direction of the cross section of the top plate portion (41, 51) (for example, in the middle of the length W in the y direction of the top plate portion 41 in FIG. 3B). (W / 2))
- the smoothness [SaA1] is measured at PA1 min .
- the cross section (cross section) in the direction perpendicular to the longitudinal direction (x direction) of the press-formed product is observed, the cross section where the radius of curvature of the second ridge line portion is minimized is measured. set to target. And in the cross section where this curvature radius becomes the minimum, the center location in the cross section height direction of the vertical wall portions (43, 53a) (for example, the length H in the z direction of the vertical wall portion 43 in FIG. 3B). In the middle (H / 2)) PA2 min , the smoothness [SaA2] is measured.
- the difference [SaA1 ⁇ SaA2] is 0.20 ⁇ m or more.
- the difference in smoothness [SaA1-SaA2] between the top plate portion and the vertical wall portion is in the above range. This is because when hot-press forming is performed on an Al-plated steel plate to produce a press-formed product. It shows that a higher surface pressure is applied to a portion that becomes the wall portion than a portion that becomes the top plate portion. This is because the surface of the vertical wall portion becomes smoother than the top plate portion by sliding the vertical wall portion with high surface pressure.
- the difference in smoothness [SaA1-SaA2] is 0.30 ⁇ m or more, it can be said that the molding is performed under the condition that the vertical wall portion is liable to be scratched by sliding.
- the upper limit value of the difference in smoothness [SaA1-SaA2] is more preferably 2.0 ⁇ m or less from the viewpoint of sharpness after coating.
- the smoothness [SaA1] and [SaA2] refer to the arithmetic average height Sa (unit: ⁇ m) defined in ISO25178-2 (2012).
- the measuring apparatus and measurement conditions are as follows. Measuring device: VK-X250 / 150 shape analysis laser microscope manufactured by Keyence Co., Ltd. Measuring range: 5 mm ⁇ 5 mm with the center point of PA1 min and PA2 min as the center Measurement conditions: Gaussian filter used S filter: Not used L filter: 4 mm
- the press-formed product according to the second aspect has a small difference in the aspect ratio of the surface property between the top plate portion and the vertical wall portion.
- the points PA1 min and PA2 In min the surface texture aspect ratio [StrA1] and the surface texture aspect ratio [StrA2] are measured.
- the difference [StrA1-StrA2] is 0.50 or less.
- the product is a press-formed product in which the occurrence of scratches due to sliding in the vertical wall portion is suppressed despite high surface pressure.
- the scratch due to sliding occurs remarkably, the scratch is streak, and thus the aspect ratio Str of the surface property of the portion is lowered.
- the part where the scratches are generated becomes a glossy part before coating. Furthermore, since the difference in glossiness appears after painting, it is visually recognized like a pattern and the surface quality is inferior.
- a press-formed product according to the second aspect in which the difference in gloss after coating is 25 or less can be realized, and excellent surface quality is achieved.
- a press-molded product using a steel base material having a hardness Hv_Parts of HV400 or higher delayed fracture occurs due to reasons such as hydrogen embrittlement, particularly in a place where stress is concentrated during press molding. It is easy to generate.
- the press molded product according to the second aspect since the generation of scratches in the vertical wall portion is suppressed as described above, it can be said that the concentration of stress on the vertical wall portion is also suppressed. Therefore, delayed fracture that is likely to occur at a stress concentration location is also suppressed.
- the difference in surface texture aspect ratio [StrA1-StrA2] is preferably 0.50 or less, and more preferably 0.40 or less, from the viewpoint of excellent surface quality and suppression of delayed fracture.
- the surface texture aspect ratios [StrA1] and [StrA2] indicate the surface texture aspect ratio Str defined in ISO25178-2 (2012).
- the measuring apparatus and measurement conditions are as follows. Measuring device: VK-X250 / 150 shape analysis laser microscope manufactured by Keyence Co., Ltd. Measuring range: 5 mm ⁇ 5 mm with the center point of PA1 min and PA2 min as the center Measurement conditions: Gaussian filter used S filter: Not used L filter: 4 mm
- the method for controlling the difference in aspect ratio [StrA1-StrA2] between the top panel portion and the vertical wall portion to the above range is not particularly limited, but for example, in the above-described embodiment.
- molding a press molded product by the manufacturing method of the hot press molded product which concerns is mentioned.
- adhesion to the die mold is suppressed. If a large amount of adherent adheres, the friction coefficient increases and scratches are likely to occur due to sliding, but as described above, the increase in the friction coefficient is suppressed by reducing the adherend, and the sliding at the vertical wall portion is suppressed. Generation of scratches due to movement is suppressed.
- it is considered that the difference in surface texture aspect ratio [Str1-Str2] can be controlled within the above range.
- the average thickness of the zinc oxide (ZnO) layer as the outermost layer is preferably 0.3 ⁇ m or more and 2.0 ⁇ m or less, and 0.4 ⁇ m or more and 1.5 ⁇ m. The following is more preferable.
- the average thickness referred to here is a place where there is little sliding at the time of hot press forming, specifically, if the press-formed product 30, 40, or 50 shown in FIG. 2A, FIG. 3B, or FIG. It refers to the thickness of the ZnO layer inside the plate portion 31, 41, or 51.
- the average thickness of the ZnO layer is 0.3 ⁇ m or more, adhesion to the die mold during hot press molding is suppressed. On the other hand, when the average thickness of the ZnO layer is 2.0 ⁇ m or less, excellent weldability is obtained, and since the Al plating layer does not become too thin, high corrosion resistance is maintained.
- the average thickness of a ZnO layer can be adjusted with the holding time of the time of hot press molding, and application
- the average thickness of the ZnO layer is measured at locations where there is little sliding during hot press molding as described above. Specifically, the thickness is measured by the following method. The press-molded product is cut in a cross section, and the plating layer structure on the outermost layer of the top plate section of the cross section is observed and analyzed using an electron microscope JSM-7001F manufactured by JEOL. And the thickness direction thickness of the maximum part of the thickness of the ZnO layer which exists in the outermost surface is measured. In addition, it measures about three places inside the top plate part chosen at random, and takes the average value.
- the adhesion amount (weight per unit area) of the Al plating layer after plating is adjusted by the gas wiping method, and the adhesion amount (weight per unit area) of the Al plating layer formed on both surfaces (upper surface and lower surface) of the cold rolled steel sheet is 40 g / after a m 2, and then cooled.
- Zn equivalent 0.8 g / m 2 of ZnO film was formed on both sides. In this way, a test material of an Al plated steel sheet (A1) was obtained.
- Al-plated steel sheet (A2, M3, K4, and Z5)>
- the amount of adhesion (weight per unit area) on the upper and lower surfaces of the Al plating layer, the presence or absence of the coating, the material of the coating, and the amount of deposition (Zn equivalent) on the upper and lower surfaces of the coating are changed as shown in Table 1 below. Except that, an Al-plated steel sheet specimen was obtained in the same manner as the Al-plated steel sheet (A1).
- Example A- ⁇ Die mold making ⁇ -Base material Prepare steels of the materials shown in Table 1, and in an annealed state, rough-process into a shape similar to the upper mold 102A and the lower mold 102B shown in Fig. 8, and heat and hold nitrogen at 1180 ° C in vacuum. After quenching by cooling, it was tempered to 64 HRC by tempering at 540-580 ° C. Thereafter, finishing was performed to obtain a base material for the die mold.
- a nitride layer was formed on the steel plate contact surface in contact (sliding) with the plated steel plate 10 in the upper mold 102A and the lower mold 102B.
- the base material was subjected to ion nitriding treatment under the following conditions. That is, after performing ion nitriding treatment in a flow rate ratio of 5% N 2 (remaining H 2 ) atmosphere at 500 ° C. for 5 hours, each test surface was finished by polishing to form a nitride layer.
- PVD film was formed at the location where the nitride layer of the base material is formed, an arc ion plating apparatus is used, and a bias voltage of -400 V is applied to the base material in an Ar atmosphere at a pressure of 0.5 Pa, and heat is applied for 60 minutes. Plasma cleaning with a filament was performed. Thereafter, various metal targets that are evaporation sources of metal components and N 2 gas as a reaction gas, using CH 4 gas as necessary, with a base material temperature of 500 ° C., a reaction gas pressure of 3.0 Pa, and ⁇ 50V. A PVD film was formed at a Bias voltage.
- Example 1 According to the method described in «Preparation of die mold», the composition of the PVD film shall be described in Table 2 below, and the hardness of the PVD film should be adjusted to the value described in Table 2 below.
- Die molds (upper mold 102A and lower mold 102B) were produced.
- the skewness (Rsk) in the sliding direction of the plated steel sheet 10 to be contacted (sliding) on the steel sheet contact surface of the obtained die mold was measured by the method described above.
- hardness Hv_Die was measured by the above-mentioned method about the steel plate contact surface of the obtained die metal mold
- Example 2 According to the method described in «Preparation of die mold», the composition of the PVD film shall be described in Table 2 below, and the hardness of the PVD film should be adjusted to the value described in Table 2 below. Die molds (upper mold 102A and lower mold 102B) were produced. Using the plated steel sheet and die mold shown in Table 2, the evaluation described later was performed.
- Example 7 since the “DLC film” in Example 5 (condition number 7) could not secure a sufficient film thickness by the PVD method, a hard layer having a film thickness of 2 ⁇ m was formed by using the plasma CVD method.
- Example 11 condition number 13
- Example 20 condition number 25
- a laminated film was formed by laminating an AlVN film on an AlCrN film.
- Example 2 Die molds (upper mold 102A and lower mold 102B) were fabricated in the same manner as in Example 1 except that the PVD film was not formed in the fabrication of the die mold. Using the plated steel sheet and die mold shown in Table 2, the evaluation described later was performed.
- the hot lubricity evaluation apparatus shown in FIG. 8 includes a near-infrared heating furnace 100 and a mold including only an upper mold 102A and a lower mold 102B.
- the upper mold 102A and the lower mold 102B have a convex part with a width of 10 mm extending in a direction orthogonal to the drawing direction of the plated steel sheet, and a predetermined test piece is sandwiched between the top surfaces of the convex parts. Apply a pressing load.
- the hot lubricity evaluation apparatus is also provided with a plated steel sheet heated in the near-infrared heating furnace 100 and a thermocouple (not shown) for measuring the temperature of the plated steel sheet when sandwiched between molds. Yes.
- 10 shows the test material of a plated steel plate.
- a hot lubricity evaluation apparatus shown in FIG. 8 a 30 mm ⁇ 500 mm specimen was heated at 920 ° C. in a near-infrared heating furnace 100 in a nitrogen atmosphere.
- the mold was composed of only the upper mold 102A and the lower mold 102B, and was pulled out while applying a pressing load of 3 kN (that is, sliding the test material on the mold).
- the drawing length was 100 mm and the drawing speed was 40 mm / s.
- the average temperature increase rate at the time of heating to 920 ° C. was set to 7.5 ° C./second.
- the amount of wear was measured. Specifically, the amount of wear of the mold was measured by measuring the profile of the mold surface at the sliding part before and after sliding using a contact-type shape measuring machine. The die wear amount was calculated by calculating the average wear amount from the profile of the surface of each of the upper die and the lower die, and taking them as an average value. From the obtained mold wear amount, the following evaluation criteria were used for evaluation. A: Mold wear amount of 0.5 ⁇ m or less B: Mold wear amount of 0.5 ⁇ m to 1 ⁇ m or less C: Mold wear amount of 1 ⁇ m to 2 ⁇ m or less D: Mold wear amount of 2 ⁇ m or more
- Adhesion to the mold was evaluated by the following test.
- the amount of adhesion was measured. Specifically, using a contact-type shape measuring machine, measure the profile of the mold surface in the sliding part before and after sliding, and the adhesion height at the position where the height of the adhered material adhesion part becomes the maximum. (Hereinafter, the maximum adhesion height of the mold) was measured.
- the mold maximum adhesion height was set to the maximum value among the adhesion heights of the upper mold and the lower mold.
- Mold maximum adhesion height 0.5 ⁇ m or less
- B Mold maximum adhesion height 0.5 ⁇ m to 1 ⁇ m
- C Mold maximum adhesion height 1 ⁇ m to 3 ⁇ m
- D Mold maximum adhesion height Over 3 ⁇ m
- Example B- ⁇ Die mold making ⁇ In the die mold produced in the condition numbers 1, 3, 6, 10, 11, 14, 15, 17, and 19 in the “Example A”, the press-molded product whose shape is shown in FIG. 2A and FIG. In addition to the shape that can be molded, the radius of curvature [R min ] at the location where the radius of curvature is minimized at the second ridge line portion is changed to a shape having the values described in Tables 3 and 4 below. And the die metal mold
- the aspect ratio [StrA1] of the surface property at the location PA1 min in the top plate portion and the aspect ratio [StrA2] of the surface property at the location PA2 min in the vertical wall portion were measured by the methods described above. Table 3 shows the measurement results.
- Molded product number 8-10 This is an example in which the base material strength of the press-formed product is different.
- Molded product number 11 This is an example of different film types.
- the “base metal vertical wall portion HV_Parts (HV, 20 ° C.)” shown in Tables 3 and 4 is the hardness measured by sampling from a position of 1 ⁇ 4 of the thickness of the vertical wall portion of the press-formed product. HV_Parts.
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Abstract
Description
[特許文献2]特開2014-139350号公報
[特許文献3]特許第4771223号公報
ところで、一般に非めっき材やめっき鋼板を使用して熱間プレス成形したとき、プレス成形品の縦壁部及びフランジ部となる部分等、めっき鋼板が摺動する熱間プレス成形用金型の摺動面に摩耗が発生する。このため、熱間プレス成形の高面圧部においては金型の摺動面に生じる摩耗対応として、金型手入れが必要である。特許文献1~2のめっき鋼板により金型摩耗が軽減されることが期待されたが、特許文献1~2をもってしても他の非めっき材やめっき鋼板と同様に金型摩耗を解決できなかった。
また、特許文献3に記載されるように表面に被覆層を備えた塑性加工用金型を用いても、熱間プレス成形の高面圧部においては金型の摺動面に生じる摩耗を解決できなかった。
また、本開示の課題は、摺動面の摩耗の発生を抑制するダイ金型、ダイ金型とパンチ金型との金型セット、およびダイ金型と鋼板おさえ金型との金型セットを提供することである。
また、本開示の課題は、表面品位に優れ且つ遅れ破壊の発生が抑制されたプレス成形品を提供することである。
<1>
Alめっき層の上に最表層として亜鉛化合物層または金属亜鉛層を有するAlめっき鋼板にダイ金型を用いて熱間プレス成形する熱間プレス成形品の製造方法であって、
前記ダイ金型は、ダイ穴の外側の表面であって且つ熱間プレス成形される前の前記Alめっき鋼板と接触する鋼板接触面のうち、ダイ肩部に隣接する全領域に、ダイ穴の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である硬質層を有する熱間プレス成形品の製造方法。
<2>
前記硬質層の前記スキューネス(Rsk)が-5.0以上である<1>に記載の熱間プレス成形品の製造方法。
<3>
前記硬質層は、窒化層と、前記窒化層の表面にある硬質コーティング層と、を含む層である<1>または<2>に記載の熱間プレス成形品の製造方法。
<4>
前記硬質コーティング層は、硬さHv_DieがHV3200以下である<3>に記載の熱間プレス成形品の製造方法。
<5>
前記硬質コーティング層がCrを含有する層である<4>に記載の熱間プレス成形品の製造方法。
<6>
前記硬質コーティング層が、Tiを含有しかつ硬さHv_DieがHV3160以下である層である<3>に記載の熱間プレス成形品の製造方法。
<7>
前記硬質コーティング層は、硬さHv_DieがHV2500以上HV3000以下である<3>~<6>のいずれか1に記載の熱間プレス成形品の製造方法。
硬さHv_PartsがHV400以上である鋼母材と、前記鋼母材上にAlめっき層と、前記Alめっき層上に最表層として酸化亜鉛層と、を有し、
天板部と、前記天板部に第1稜線部を介して接続する縦壁部と、前記縦壁部に第2稜線部を介して接続するフランジ部と、を有し、
前記第2稜線部において曲率半径が最小となる箇所での該曲率半径[Rmin]が3mm以上10mm未満であり、
プレス成形品の横断面を観察した場合に前記第2稜線部の曲率半径が最小となる横断面において、前記天板部の横断面幅方向での中心箇所PA1minでの平滑度[SaA1]と、前記縦壁部の横断面高さ方向での中心箇所PA2minでの平滑度[SaA2]と、の差[SaA1-SaA2]が0.20μm以上であり、
前記天板部における前記箇所PA1minでの表面性状のアスペクト比[StrA1]と、前記縦壁部における前記箇所PA2minでの表面性状のアスペクト比[StrA2]と、の差[StrA1-StrA2]が0.50以下であるプレス成形品。
<9>
硬さHv_PartsがHV400以上である鋼母材と、前記鋼母材上にAlめっき層と、前記Alめっき層上に最表層として酸化亜鉛層と、を有し、
天板部と、前記天板部に第1稜線部を介して接続する縦壁部と、前記縦壁部に第2稜線部を介して接続するフランジ部と、を有し、
前記第2稜線部において曲率半径が最小となる箇所での該曲率半径[Rmin]が3mm以上10mm未満であり、
側面側から観察した場合に前記フランジ部の曲率半径が最小となる箇所PB0minに対応する前記天板部における幅方向での中心箇所PB1minでの平滑度[SaB1]と、側面側から観察した場合に前記箇所PB0minに対応する前記縦壁部における高さ方向での中心箇所PB2minでの平滑度[SaB2]と、の差[SaB1-SaB2]が0.30μm以上であり、
前記天板部における前記箇所PB1minでの表面性状のアスペクト比[StrB1]と、前記縦壁部における前記箇所PB2minでの表面性状のアスペクト比[StrB2]と、の差[StrB1-StrB2]が0.50以下であるプレス成形品。
ダイ穴の外側の表面且つダイ肩部に隣接するダイ肩隣接面のうち、前記ダイ肩部に隣接する全領域に、ダイ穴の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である硬質層を有するダイ金型。
<11>
前記硬質層の前記スキューネス(Rsk)が-5.0以上である<10>に記載のダイ金型。
<12>
前記硬質層は、窒化層と、前記窒化層の表面にある硬質コーティング層と、を含む層である<10>または<11>に記載のダイ金型。
<13>
前記硬質コーティング層は、硬さHv_Dieが3200以下である<12>に記載のダイ金型。
<14>
前記硬質コーティング層がCrを含有する層である<13>に記載のダイ金型。
<15>
前記硬質コーティング層が、Tiを含有しかつ硬さHv_DieがHV3160以下である層である<12>に記載のダイ金型。
<16>
前記硬質コーティング層は、硬さHv_DieがHV2500以上HV3000以下である<12>~<15>のいずれか1に記載のダイ金型。
<10>~<16>のいずれか1に記載のダイ金型と、パンチ金型と、を備え、
前記パンチ金型は、前記ダイ金型の前記ダイ肩隣接面に対向する対向面のうち、前記ダイ金型が前記硬質層を有する箇所と対向する全領域に、パンチ部の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である第二硬質層を有する金型セット。
<18>
前記第二硬質層の前記スキューネス(Rsk)が-5.0以上である<17>に記載の金型セット。
<19>
前記第二硬質層は、第二窒化層と、前記第二窒化層の表面にある第二硬質コーティング層と、を含む層である<17>または<18>に記載の金型セット。
<20>
前記第二硬質コーティング層は、硬さHv_DieがHV3200以下である<19>に記載の金型セット。
<21>
前記第二硬質コーティング層がCrを含有する層である<20>に記載の金型セット。
<22>
前記第二硬質コーティング層が、Tiを含有しかつ硬さHv_DieがHV3160以下である層である<19>に記載の金型セット。
<23>
前記第二硬質コーティング層は、硬さHv_DieがHV2500以上HV3000以下である<19>~<22>のいずれか1に記載の金型セット。
<10>~<16>のいずれか1に記載のダイ金型と、鋼板おさえ金型と、を備え、
前記鋼板おさえ金型は、前記ダイ金型の前記ダイ肩隣接面に対向する対向面のうち、前記ダイ金型が前記硬質層を有する箇所と対向する全領域に、パンチ挿通部の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である第二硬質層を有する金型セット。
<25>
前記第二硬質層の前記スキューネス(Rsk)が-5.0以上である<24>に記載の金型セット。
<26>
前記第二硬質層は、第二窒化層と、前記第二窒化層の表面にある第二硬質コーティング層と、を含む層である<24>または<25>に記載の金型セット。
<27>
前記第二硬質コーティング層は、硬さHv_DieがHV3200以下である<26>に記載の金型セット。
<28>
前記第二硬質コーティング層がCrを含有する層である<27>に記載の金型セット。
<29>
前記第二硬質コーティング層が、Tiを含有しかつ硬さHv_DieがHV3160以下である層である<26>に記載の金型セット。
<30>
前記第二硬質コーティング層は、硬さHv_DieがHV2500以上HV3000以下である<26>~<29>のいずれか1に記載の金型セット。
また、本開示によれば、摺動面の摩耗の発生を抑制するダイ金型、ダイ金型とパンチ金型との金型セット、およびダイ金型と鋼板おさえ金型との金型セットを提供することができる。
また、本開示によれば、表面品位に優れ且つ遅れ破壊の発生が抑制されたプレス成形品を提供することができる。
本開示の一実施形態に係る熱間プレス成形品の製造方法について説明する。
本実施形態に係る熱間プレス成形品の製造方法は、Alめっき層の上に最表層として亜鉛化合物層または金属亜鉛層を有するAlめっき鋼板にダイ金型を用いて熱間プレス成形する熱間プレス成形品の製造方法である。
そして、前記ダイ金型は、ダイ穴の外側の表面であって且つ熱間プレス成形される前の前記Alめっき鋼板と接触する鋼板接触面のうち、ダイ肩部に隣接する全領域に、ダイ穴の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である硬質層を有する。
ZnO皮膜付きAlめっき鋼板は、Alめっき層の表面がZnO皮膜で覆われているため、熱間プレス成形したときでも、焼き付きによるアルミ凝着物のダイ金型の表面への凝着が抑えられる。その結果、ダイ金型の表面との摩擦係数が低減される。
ここで、スキューネスRskとは、JIS B 0601(2001年)に定義され、平均線に対しての山部と谷部の対称性を表す指標である。このRskが正(0<Rsk)のときは、山部及び谷部が平均線よりも下側へ偏在している状態を示す。一方、このRskが負(Rsk<0)のときは、山部及び谷部が平均線よりも上側へ偏在している状態を示す。つまり、Rskが負(Rsk<0)の場合、表面に突出する山部が少ない状態となっている。スキューネス(Rsk)が上記範囲であるということは、ダイ穴の外側から内側に向かう方向において、硬質層の表面が突出する山部が少ない状態である。つまり熱間プレス成形の際にダイ金型に対してAlめっき鋼板が摺動する方向において、硬質層の表面が突出する山部が少ない状態となっている。これにより、めっき鋼板と摺動する表面のダイ肩部に隣接する領域つまり高面圧がかかる箇所においても、摩耗が抑制される。
また、上記硬質層は、硬さHv_DieがHV2000以上である。最表面層である硬質層の硬さが上記範囲であることで、硬質であるAlめっき鋼板との摺動によっても硬質層自体の摩耗が抑制され、ダイ金型の摩耗が抑制される。
プレス成形では、鋼板がダイ金型のダイ穴に引き込まれて成形される。ダイ穴の縁(ダイ肩部)がダイ穴の外側に向かって張り出して湾曲している場合、鋼板はダイ穴に引き込まれる際、縮みフランジ変形する。
絞り成形の場合、縮みフランジ変形では鋼板がダイ穴の縁(ダイ肩部)に近づくに従い厚みが増加する。鋼板の厚みが増加すると、鋼板に高い面圧が付与される。
曲げ成形の場合、縮みフランジ変形では鋼板がダイ穴の縁(ダイ肩部)に近づくに従い鋼板にしわが発生する。鋼板にしわが発生すると、ダイ穴の近傍でしわになった鋼板がダイ金型に接触し、接触した箇所が高面圧になる。
これらは熱間プレス成形でも同じである。本実施形態のダイ金型は高い面圧が生じる箇所に硬質層を備える。
図2A及び図2Bに示す熱間プレス成形品30は、2つの縦壁部33と、2つの縦壁部33を第1稜線部32を介して結ぶ天板部31と、2つの縦壁部33に対しそれぞれ第2稜線部34を介して天板部31とは反対側で接続するフランジ部35と、を有する。また、熱間プレス成形品30を側面側から観察した場合、つまり図2Bに示すようにy方向から観察した場合、フランジ部35のうち曲率半径が最小となる箇所PB0minを有する形状である。即ち、フランジ部35が長手方向(x方向)において湾曲する箇所を有しており、フランジ部35全体として曲率半径が一定でない形状である。また、フランジ部35と同様に天板部31も長手方向(x方向)において湾曲する箇所を有している。
図3A及び図3Bでは、熱間プレス成形品40の長手方向をx方向とし、x方向に直交する方向のうち縦壁部43側から観察する方向をy方向とし、x方向及びy方向に直交する方向であって天板部41側から観察する方向をz方向とする。
図3A及び図3Bに示す熱間プレス成形品40は、2つの縦壁部43と、2つの縦壁部43を第1稜線部42を介して結ぶ天板部41と、2つの縦壁部43に対しそれぞれ第2稜線部44を介して天板部41とは反対側で接続するフランジ部45と、を有する。なお、この熱間プレス成形品40では、長手方向(x方向)に直交する方向の断面(横断面、例えば図3Bに示す断面など)を観察した場合に、どこで切断した横断面を観察しても第2稜線部44の曲率半径が同じ値となる形状である。また、どこで切断した横断面を観察しても左右対称の形状となっている。
図4A及び図4Bでは、熱間プレス成形品50の長手方向をx方向とし、x方向に直交する方向のうち縦壁部53a側から観察する方向をy方向とし、x方向及びy方向に直交する方向であって天板部51側から観察する方向をz方向とする。
図4A及び図4Bに示す熱間プレス成形品50は、2つの縦壁部53a、53bと、2つの縦壁部53a、53bをそれぞれ第1稜線部52a、52bを介して結ぶ天板部51と、2つの縦壁部53a、53bに対しそれぞれ第2稜線部54a、54bを介して天板部51とは反対側で接続するフランジ部55a、55bと、を有する。なお、この熱間プレス成形品50では、長手方向(x方向)に直交する方向の断面(横断面)を観察した場合に左右の形状が対称ではない箇所が存在する。例えば、図4Bに示す横断面では、平坦な天板部51の両側に存在する2つの第1稜線部52a、52bのz方向高さが異なり、右側の第1稜線部52aの方が左側の第1稜線部52bよりもz方向に盛り上がって高くなった形状である。また、図4Bに示す横断面では、2つのフランジ部55a、55bのz方向高さも異なり、右側のフランジ部55aの方が左側のフランジ部55bよりも高い形状である。そして、この熱間プレス成形品50では、横断面を観察した場合に切断する箇所によって第2稜線部54a、54bの曲率半径が異なる形状であり、図4Bに示す横断面での第2稜線部54aの曲率半径が最小となる形状である。
この硬質層11Cが前記スキューネス(Rsk)及び硬さHv_Dieを満たすことで、Alめっき鋼板を熱間プレス成形する際に、高面圧部で生じるダイ金型11の摺動面での摩耗の発生が抑制される。
この第二硬質層12Cが前記スキューネス(Rsk)及び硬さHv_Dieを満たすことで、Alめっき鋼板を熱間プレス成形する際に、高面圧部で生じるホルダー12の摺動面での摩耗の発生が抑制される。
また、ホルダー12の摩耗抑制の観点では、第二硬質層12Cはダイ金型11のダイ肩部11Bに対向する箇所に沿って全周にわたり形成されていることが好ましい。一方、コスト等の観点から形成する領域を低減する場合、特に高い面圧が生じる箇所を選択して第二硬質層12Cを形成してもよい。
そして、そのプレス成形に用いるダイ金型として、ダイ穴の外側の表面であって且つ熱間プレス成形される前のAlめっき鋼板と接触する鋼板接触面のうち、ダイ肩部に隣接する全領域に、ダイ穴の外側から内側に向かう方向に測定したスキューネス(Rsk)及び硬さHv_Dieが前記範囲を満たす硬質層を有するダイ金型を適用することで、高面圧部で生じるダイ金型の摺動面での摩耗の発生が抑制される。
次いで、本実施形態に係る熱間プレス成形品の製造方法に用いられるダイ金型について詳述する。
そして、ダイ穴の外側の表面且つダイ肩部に隣接するダイ肩隣接面のうち、前記ダイ肩部に隣接する全領域に、ダイ穴の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である硬質層を有する。
ダイ金型が備える硬質層の、ダイ穴の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下であることで、熱間プレス成形の際に高面圧部で生じるダイ金型の摺動面での摩耗の発生が抑制される。
硬質層のスキューネス(Rsk)は、より好ましくは1.0以下であり、さらに好ましくは0.8以下である。
また、硬質層のスキューネス(Rsk)の下限値は、スキューネス(Rsk)を低くするための表面制御による製造時のコスト増大を抑制する観点から、-5.0以上であることが好ましく、より好ましくは-3.0以上である。なお、硬質層のスキューネス(Rsk)の下限値は、金型への凝着を抑制する観点では、0以上であることが好ましい。
硬質層のスキューネス(Rsk)の範囲としては、0以上1.3以下が好ましく、0以上1.0以下がより好ましく、0以上0.8以下がさらに好ましい。
(測定条件)
測定装置:株式会社ミツトヨ製「表面粗さ・輪郭形状測定機 フォームトレーサ」
測定長さL:9.6mm
カットオフ波長λc:0.8mm
触針先端形状:先端角度60°円錐
触針先端半径:2μm
測定速度:1mm/sec
また、ダイ肩部に隣接する全領域についてスキューネス(Rsk)を測定するとは、ダイ肩部に隣接する領域を20mm以下の密なピッチでスキューネス(Rsk)を測定することを意味する。
ダイ金型が備える硬質層の、硬さHv_DieがHV2000以上であることで、熱間プレス成形の際に高面圧部で生じるダイ金型の摺動面での摩耗の発生が抑制される。
なお、特に硬質コーティング層がCrを含有する層である場合には、特に硬さHv_Dieが3200以下であることが好ましい。
マイクロビッカース試験機には、株式会社ミツトヨ製HM-115を用いる。
本実施形態では、ダイ金型に形成される硬質層は、前述のスキューネスRsk及び硬さHv_Dieを満たすものであれば、その材質や形成方法に制限はない。
例えば、物理蒸着法(PVD法)による硬質コーティング層(蒸着膜)が挙げられ、具体的にはTi、Cr及びAlから選ばれる1種又は2種以上を主体とする窒化膜、炭化膜、炭窒化膜、ダイヤモンドライクカーボン(DLC)膜、等が挙げられる。
なお、その主体とすることについては、窒素及び炭素を除いた、金属(半金属を含む)組成部のみの割合で、Ti、CrもしくはAl(又はTiもしくはCr)が70(原子%)以上、更には90(原子%)以上とすることがよい(実質100(原子%)を含む)。
窒化層の形成は、ダイ金型の母材に、例えばイオン窒化処理、つまり所定濃度のN2及びH2ガス雰囲気中で、温度を調整してイオン窒化処理を施すことで行われる。
ダイ金型の母材の金属材質については、特段に定めるものではなく、例えば冷間ダイス鋼、熱間ダイス鋼、高速度鋼および超硬合金等の公知の金属材料が使用できる。これについては、JIS等による規格金属種(鋼種)を含め、従来金型への使用が可能な鋼種として提案のされてきた改良金属種も適用できる。
次いで、本実施形態に係る熱間プレス成形品の製造方法に用いられる金型セットについて詳述する。金型セットとは、ダイ金型と、ダイ金型のダイ穴に対応する凸部を備えると共にダイ金型の鋼板接触面(ダイ肩隣接面)に対向する対向面を備えるパンチ金型の組合せである。また、金型セットとは、ダイ金型と、ダイ金型の鋼板接触面(ダイ肩隣接面)に対向する対向面を備えると共にダイ穴に挿通されるパンチが通る穴を備える鋼板おさえ金型(ホルダー)の組合せも含む。
パンチ金型は、ダイ金型のダイ肩隣接面(鋼板接触面)に対向する対向面のうち、ダイ金型が硬質層を有する箇所と対向する全領域に、パンチ部の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である第二硬質層を有する。
鋼板おさえ金型は、ダイ金型のダイ肩隣接面(鋼板接触面)に対向する対向面のうち、ダイ金型が硬質層を有する箇所と対向する全領域に、パンチ挿通部の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である第二硬質層を有する。
Alめっき鋼板は、Alめっき層の上に最表層として亜鉛化合物層または金属亜鉛層を有する。
なお、%の表記は、特に断りがない場合は質量%を意味する。また、本明細書において「~」を用いて表される数値範囲は、「~」の前後に記載される数値を下限値及び上限値として含む範囲を意味する。
Alめっき層について説明する。
Alめっき層の表面にごく薄い(たとえば厚さ0.1μm)酸化Al皮膜が存在する場合がある。この場合、酸化Al皮膜は無いものとみなす。なぜなら、熱間プレス成形前のこの酸化Al皮膜は、熱間プレス成形と熱間プレス成形品に特に影響しないからである。
Zn化合物層または金属Zn層は、ZnO皮膜、又は、熱間プレス成形時にZnO皮膜になる層である。熱間プレス成形の前にめっき鋼板は酸化雰囲気で加熱される。このときZnO皮膜以外のZn化合物層または金属Zn層は酸化されてZnO皮膜になる。ZnO皮膜以外のZn化合物層または金属Zn層は酸化してZnO皮膜になるのであれば特に種類は問わない。ZnO皮膜以外のZn化合物層には、リン酸亜鉛層、Zn系金属石鹸層等が例示できる。また、Zn化合物と金属Znは加熱により燃えて無くなる樹脂と混合し、ZnO皮膜以外のZn化合物層または金属Zn層としてもよい。Zn化合物層または金属Zn層に含まれるZnの量は、目標とする製品のZnO皮膜の付着量に応じて調節する。
ZnO皮膜は、ダイ金型と接触する面であって、プレス成形品の外側の面となる皮膜である。
なお、ZnO皮膜の付着量の測定方法としては、蛍光X線法を利用する。具体的には、蛍光X線法により、ZnO皮膜の付着量(Zn量換算)が既知である数種類の標準試料を用いて検量線を作成し、測定対象である試料のZn強度をZnO皮膜の付着量に換算して、ZnO皮膜の付着量を求める。
次いで、本実施形態に係るプレス成形品について詳述する。
最表層としての酸化亜鉛(ZnO)層は、Alめっき鋼板に熱間プレス成形を施す際の加熱によって形成される。
まず、第1の態様に係るプレス成形品として、側面側から観察した場合にフランジ部の曲率半径が最小となる箇所PB0minを有する形状のプレス成形品について説明する。なお、第1の態様に係るプレス成形品の一例として、図2A及び図2Bに示す成形品を例に挙げる。
図2A及び図2Bに示す熱間プレス成形品30は、2つの縦壁部33と、2つの縦壁部33を第1稜線部32を介して結ぶ天板部31と、2つの縦壁部33に対しそれぞれ第2稜線部34を介して天板部31とは反対側で接続するフランジ部35と、を有する。なお、天板部31は熱間プレス成形の際にパンチの頂面に相当する部分であり、縦壁部33はパンチ及びダイ金型と摺動する部分であり、フランジ部35は熱間プレス成形による成形が行われない部分である。また、第1稜線部32は天板部31と縦壁部33とを結ぶ湾曲部であり、第2稜線部34は縦壁部33とフランジ部35とを結ぶ湾曲部である。
また、熱間プレス成形品30を側面側から観察した場合、つまり図2Bに示すようにy方向から観察した場合、天板部31、縦壁部33、及びフランジ部35がいずれも一部で湾曲しており、天板部31の外側方向に向かって一部が膨らんだ形状である。そのため、この膨らんだ箇所のフランジ部35では、曲率半径が最小となる箇所(つまり曲げが最も厳しい箇所)PB0minが存在し、側面側から観察した場合にフランジ部35全体として曲率半径が一定でなく、また天板部31も全体として曲率半径が一定でない形状である。
そして、第1の態様にかかるプレス成形品では、第2稜線部34において曲率半径が最も小さくなる箇所(つまり曲げが最も厳しい箇所)での該曲率半径[Rmin]が3mm以上10mm未満である。ここで、第2稜線部34での最小曲率半径[Rmin]が10未満であることは、Alめっき鋼板に熱間プレス成形を行ってプレス成形品30を製造する際に、縦壁部33となる箇所に高面圧が掛かっていることを示す。そのため、高面圧が掛かる縦壁部33において、摺動による擦り傷が発生し易い条件で熱間プレス成形が施されたプレス成形品であると言える。なお、第2稜線部34での最小曲率半径[Rmin]の上限値が8mm以下であると、さらに縦壁部33に摺動による擦り傷が発生し易いと言える。
一方で、第2稜線部34での最小曲率半径[Rmin]の下限値は、プレス成形時の割れ防止の観点から、3mm以上であり、好ましくは4mm以上である。
ここで、曲率半径は次の通り測定する。まず、第2稜線部34の外側の面つまり熱間プレス成形の際にダイ金型と接触した方の面における三次元形状を、三次元形状測定器により測定する。そして、横断面において曲率半径が最も小さくなる箇所での曲率半径[Rmin]を得る。
また、第1の態様にかかるプレス成形品は、天板部31と縦壁部33とにおいて平滑度に差が生じる。具体的には、天板部31に関しては、側面側から観察した場合(つまり図2Bに示すようにy方向から観察した場合)に、フランジ部35での曲率半径が最小となる箇所PB0minに対応する位置(つまり図2Bに示すようにy方向から観察した場合に、フランジ部35上の箇所PB0minに対してz方向にずらすだけで、x方向にはずらさずに到達し得る天板部31上の位置)であって、且つ天板部31における幅方向(つまりy方向)での中心箇所PB1minにおいて、平滑度[SaB1]を測定する。また、縦壁部33に関しては、側面側から観察した場合に箇所PB0minに対応する箇所(つまり図2Bに示すようにy方向から観察した場合に、フランジ部35上の箇所PB0minに対してz方向にずらすだけで、x方向にはずらさずに到達し得る縦壁部33上の位置)であって、且つ縦壁部33における高さ方向(つまりz方向)での中心箇所PB2minにおいて、平滑度[SaB2]を測定する。なお、箇所PB1min及び箇所PB2minのいずれにおいても外側の面、つまり熱間プレス成形の際にダイ金型と接触した方の面において測定する。
そして、この差[SaB1-SaB2]が0.30μm以上である。
ここで、天板部31と縦壁部33との平滑度の差[SaB1-SaB2]が上記範囲であることは、Alめっき鋼板に熱間プレス成形を行ってプレス成形品30を製造する際に、縦壁部33となる箇所に対し、天板部31となる箇所よりも高面圧が掛かっていることを示す。縦壁部33に高面圧が掛かって摺動することで、天板部31よりも縦壁部33の表面の方が平滑になるためである。そして、高面圧が掛かる縦壁部33において、摺動による擦り傷が発生し易い条件で熱間プレス成形が施されたプレス成形品であると言える。なお、平滑度の差[SaB1-SaB2]が0.35μm以上であると、さらに縦壁部33に摺動による擦り傷が発生し易い条件で成形されていると言える。
一方で、平滑度の差[SaB1-SaB2]の上限値としては、塗装後の鮮鋭性の観点から、2.0μm以下がより好ましい。
測定装置:(株)キーエンス製 VK-X250/150形状解析レーザ顕微鏡
測定範囲:PB1min、PB2minの中心点を中心として、5mm×5mm
測定条件:ガウシアンフィルターを使用
Sフィルター:使用無し
Lフィルター:4mm
また、第1の態様に係るプレス成形品は、天板部31と縦壁部33とにおいて表面性状のアスペクト比の差が小さい。具体的には、天板部31及び縦壁部33のいずれに関しても、前記平滑度と同じく箇所PB1min及び箇所PB2minにおいて表面性状のアスペクト比[StrB1]及び表面性状のアスペクト比[StrB2]を測定する。なお、平滑度と同じく、いずれも外側の面つまり熱間プレス成形の際にダイ金型と接触した方の面において測定する。
そして、この差[StrB1-StrB2]が0.50以下である。
ここで、天板部31と縦壁部33との表面性状のアスペクト比の差[StrB1-StrB2]が小さいほど、熱間プレス成形の際に縦壁部33となる箇所に対し天板部31となる箇所よりも高面圧が掛かっているにもかかわらず、縦壁部33において摺動による擦り傷の発生が抑制されたプレス成形品であることを示す。摺動による擦り傷が顕著に発生した場合、その擦り傷は筋状であるため、その部分の表面性状のアスペクト比Strが低下する。さらに擦り傷が発生した部分は塗装前においては光沢部となる。さらに、塗装後においては光沢度に差が出るため、模様のように視認され、表面品位が劣る。しかし、表面性状のアスペクト比の差[StrB1-StrB2]を小さくすることによって、塗装後の光沢度の差が25以下である第1の態様に係るプレス成形品が実現でき、優れた表面品位を備える。
また、硬さHv_PartsがHV400以上と高硬度である鋼母材を用いたプレス成形品では、特にプレス成形の際に応力が集中して掛かった箇所において、水素脆化等の理由により遅れ破壊が発生し易い。しかし、これに対し第1の態様に係るプレス成形品は、上記の通り縦壁部33における擦り傷の発生が抑制されていることから、縦壁部33への応力の集中も抑制されていると言える。そのため、応力集中箇所で生じ易い遅れ破壊も抑制される。
測定装置:(株)キーエンス製 VK-X250/150形状解析レーザ顕微鏡
測定範囲:PB1min、PB2minの中心点を中心として、5mm×5mm
測定条件:ガウシアンフィルターを使用
Sフィルター:使用無し
Lフィルター:4mm
本実施形態に係る熱間プレス成形品の製造方法によってプレス成形品を成形することで、ダイ金型への凝着が抑制される。凝着物が多量に付着すると摩擦係数が上昇して、摺動による擦り傷が発生し易くなるが、上記の通り凝着物が低減されることで摩擦係数の上昇も抑制され、縦壁部33での摺動による擦り傷の発生が抑制される。その結果、表面性状のアスペクト比の差[Str1-Str2]を上記の範囲に制御し得るものと考えられる。
次いで、第2の態様に係るプレス成形品について説明する。なお、第2の態様に係るプレス成形品の一例として、図3A及び図3B、並びに図4A及び図4Bに示す成形品を例に挙げる。
図3A及び図3Bに示す熱間プレス成形品40は、2つの縦壁部43と、2つの縦壁部43を第1稜線部42を介して結ぶ平坦な天板部41と、2つの縦壁部43に対しそれぞれ第2稜線部44を介して天板部41とは反対側で接続するフランジ部45と、を有する。なお、天板部41は熱間プレス成形の際にパンチの頂面に相当する部分であり、縦壁部43はパンチ及びダイ金型と摺動する部分であり、フランジ部45は熱間プレス成形による成形が行われない部分である。また、第1稜線部42は天板部41と縦壁部43とを結ぶ湾曲部であり、第2稜線部44は縦壁部43とフランジ部45とを結ぶ湾曲部である。
また、熱間プレス成形品40を側面側から観察した場合、つまり図3Aに示すようにy方向から観察した場合、天板部41、縦壁部43、及びフランジ部45がいずれも平坦な形状である。そして、この熱間プレス成形品40では、長手方向(x方向)に直交する方向の断面(横断面、例えば図3Bに示す断面など)を観察した場合に、どこで切断した横断面を観察しても左右対称の形状となっている。また、熱間プレス成形品40は、どこで切断した横断面を観察しても第2稜線部44の曲率半径が同じ値となる形状である。つまり、どこで切断した横断面においても第2稜線部44の曲率半径は一定であり、言い換えればどこで切断した横断面においても第2稜線部44の曲率半径は最小値である。
この熱間プレス成形品50では、長手方向(x方向)に直交する方向の断面(横断面)を観察した場合に左右の形状が対称ではない箇所が存在する。例えば、図4Bに示す横断面では、平坦な天板部51の両側に存在する2つの第1稜線部52a、52bのz方向高さが異なり、右側の第1稜線部52aの方が左側の第1稜線部52bよりもz方向に盛り上がって高くなった形状である。また、図4Bに示す横断面では、2つのフランジ部55a、55bのz方向高さも異なり、右側のフランジ部55aの方が左側のフランジ部55bよりも高い形状である。そして、この熱間プレス成形品50では、横断面を観察した場合に切断する箇所によって第2稜線部54a、54bの曲率半径が異なる形状であり、図4Bに示す横断面(図4AのB-B’断面)での第2稜線部54aの曲率半径が最小となる形状である。
そして、第2の態様にかかるプレス成形品では、第2稜線部44、54a又は54bにおいて曲率半径が最も小さくなる箇所(つまり曲げが最も厳しい箇所)での該曲率半径[Rmin]が3mm以上10mm未満である。ここで、第2稜線部44、54a又は54bでの最小曲率半径[Rmin]が10未満であることは、Alめっき鋼板に熱間プレス成形を行ってプレス成形品40、50を製造する際に、縦壁部43、53a又は53bとなる箇所に高面圧が掛かっていることを示す。そのため、高面圧が掛かる縦壁部43、53a又は53bにおいて、摺動による擦り傷が発生し易い条件で熱間プレス成形が施されたプレス成形品であると言える。なお、第2稜線部44、54a又は54bでの最小曲率半径[Rmin]の上限値が8mm以下であると、さらに縦壁部43、53a又は53bに摺動による擦り傷が発生し易いと言える。
一方で、第2稜線部44、54a又は54bでの最小曲率半径[Rmin]の下限値は、プレス成形時の割れ防止の観点から、3mm以上であり、好ましくは4mm以上である。
なお、曲率半径の測定は、前述の第1の態様における第2稜線部での曲率半径の測定方法に準じて行う。
また、第2の態様にかかるプレス成形品は、天板部と縦壁部とにおいて平滑度に差が生じる。具体的には、プレス成形品の長手方向(x方向)に直交する方向の断面(横断面)を観察した場合に第2稜線部の曲率半径が最小となる横断面を測定対象とする。つまり、図3A及び図3Bに示すプレス成形品40であれば、どこで切断した横断面においても第2稜線部44の曲率半径は最小値となるため、どの横断面を測定対象としてもよく、好ましくは長手方向(x方向)の中心位置での横断面が推奨される。また、図4A及び図4Bに示すプレス成形品50であれば、図4Bに示す横断面(図4AのB-B’断面)での第2稜線部54aの曲率半径が最小となるため、この図4Bに示す横断面を測定対象とする。そして、この曲率半径が最小となる横断面において、天板部(41、51)の横断面幅方向での中心箇所(例えば、図3Bであれば天板部41のy方向長さWの真ん中(W/2)の箇所)PA1minにおいて、平滑度[SaA1]を測定する。
また、縦壁部に関しても、同様にプレス成形品の長手方向(x方向)に直交する方向の断面(横断面)を観察した場合に第2稜線部の曲率半径が最小となる横断面を測定対象とする。そして、この曲率半径が最小となる横断面において、縦壁部(43、53a)の横断面高さ方向での中心箇所(例えば、図3Bであれば縦壁部43のz方向長さHの真ん中(H/2)の箇所)PA2minにおいて、平滑度[SaA2]を測定する。
なお、箇所PA1min及び箇所PA2minのいずれにおいても外側の面、つまり熱間プレス成形の際にダイ金型と接触した方の面において測定する。
そして、この差[SaA1-SaA2]が0.20μm以上である。
ここで、天板部と縦壁部との平滑度の差[SaA1-SaA2]が上記範囲であることは、Alめっき鋼板に熱間プレス成形を行ってプレス成形品を製造する際に、縦壁部となる箇所に対し、天板部となる箇所よりも高面圧が掛かっていることを示す。縦壁部に高面圧が掛かって摺動することで、天板部よりも縦壁部の表面の方が平滑になるためである。そして、高面圧が掛かる縦壁部において、摺動による擦り傷が発生し易い条件で熱間プレス成形が施されたプレス成形品であると言える。なお、平滑度の差[SaA1-SaA2]が0.30μm以上であると、さらに縦壁部に摺動による擦り傷が発生し易い条件で成形されていると言える。
一方で、平滑度の差[SaA1-SaA2]の上限値としては、塗装後の鮮鋭性の観点から、2.0μm以下がより好ましい。
測定装置:(株)キーエンス製 VK-X250/150形状解析レーザ顕微鏡
測定範囲:PA1min、PA2minの中心点を中心として、5mm×5mm
測定条件:ガウシアンフィルターを使用
Sフィルター:使用無し
Lフィルター:4mm
また、第2の態様に係るプレス成形品は、天板部と縦壁部とにおいて表面性状のアスペクト比の差が小さい。具体的には、天板部(図3Bにおける41、図4Bにおける51)及び縦壁部(図3Bにおける43、図4Bにおける53a)のいずれに関しても、前記平滑度と同じく箇所PA1min及び箇所PA2minにおいて表面性状のアスペクト比[StrA1]及び表面性状のアスペクト比[StrA2]を測定する。なお、平滑度と同じく、いずれも外側の面つまり熱間プレス成形の際にダイ金型と接触した方の面において測定する。
そして、この差[StrA1-StrA2]が0.50以下である。
ここで、天板部と縦壁部との表面性状のアスペクト比の差[StrA1-StrA2]が小さいほど、熱間プレス成形の際に縦壁部となる箇所に対し天板部となる箇所よりも高面圧が掛かっているにもかかわらず、縦壁部において摺動による擦り傷の発生が抑制されたプレス成形品であることを示す。摺動による擦り傷が顕著に発生した場合、その擦り傷は筋状であるため、その部分の表面性状のアスペクト比Strが低下する。さらに擦り傷が発生した部分は塗装前においては光沢部となる。さらに、塗装後においては光沢度に差が出るため、模様のように視認され、表面品位が劣る。しかし、表面性状のアスペクト比の差[StrA1-StrA2]を小さくすることによって、塗装後の光沢度の差が25以下である第2の態様に係るプレス成形品が実現でき、優れた表面品位を備える。
また、硬さHv_PartsがHV400以上と高硬度である鋼母材を用いたプレス成形品では、特にプレス成形の際に応力が集中して掛かった箇所において、水素脆化等の理由により遅れ破壊が発生し易い。しかし、これに対し第2の態様に係るプレス成形品は、上記の通り縦壁部における擦り傷の発生が抑制されていることから、縦壁部への応力の集中も抑制されていると言える。そのため、応力集中箇所で生じ易い遅れ破壊も抑制される。
測定装置:(株)キーエンス製 VK-X250/150形状解析レーザ顕微鏡
測定範囲:PA1min、PA2minの中心点を中心として、5mm×5mm
測定条件:ガウシアンフィルターを使用
Sフィルター:使用無し
Lフィルター:4mm
本実施形態に係る熱間プレス成形品の製造方法によってプレス成形品を成形することで、ダイ金型への凝着が抑制される。凝着物が多量に付着すると摩擦係数が上昇して、摺動による擦り傷が発生し易くなるが、上記の通り凝着物が低減されることで摩擦係数の上昇も抑制され、縦壁部での摺動による擦り傷の発生が抑制される。その結果、表面性状のアスペクト比の差[Str1-Str2]を上記の範囲に制御し得るものと考えられる。
第1及び第2の態様に係るプレス成形品では、最表層である酸化亜鉛(ZnO)層の平均厚さが0.3μm以上2.0μm以下であることが好ましく、0.4μm以上1.5μm以下であることがより好ましい。
なお、ここで言う平均厚さとは、熱間プレス成形時に摺動が少ない箇所、具体的には図2A、図3B、又は図4Bに示すプレス成形品30、40、又は50であれば、天板部31、41、又は51の内側におけるZnO層の厚さを指す。
ZnO層の平均厚さが0.3μm以上であることで、熱間プレス成形の際のダイ金型への凝着が抑制される。一方、ZnO層の平均厚さが2.0μm以下であることで、優れた溶接性が得られ、またAlめっき層が薄くなり過ぎないため高い耐食性も維持される。
なお、ZnO層の平均厚さは、熱間プレス成形の際の加熱の保持時間や、成形前のZnO皮膜の塗布によって調整し得る。
プレス成形品を横断面で切断し、断面の天板部の最表層におけるめっき層構造を、日本電子製の電子顕微鏡JSM-7001Fを用いて観察・分析する。そして、最表面に存在するZnO層の厚さの最大部の板厚方向厚さを測定する。
なお、無作為に選んだ天板部の内側3箇所について測定し、その平均値をとる。
<Alめっき鋼板(A1)>
板厚1.6mmの冷延鋼板(質量%で、C:0.21%、Si:0.12%、Mn:1.21%、P:0.02%、S:0.012%、Ti:0.02%、B:0.03%、Al:0.04%、並びに残部:Fe及び不純物)の両面に、ゼンジマー法でAlめっき層を形成した。焼鈍温度は約800℃とし、Alめっき浴はSiを9質量%含有し、他に冷延鋼板から溶出するFeを含有していた。めっき後のAlめっき層の付着量(目付量)をガスワイピング法で調整し、冷延鋼板の両面(上面及び下面)に形成するAlめっき層の付着量(目付量)を、いずれも40g/m2とした後、冷却した。その後、両面のAlめっき層上に、薬液(シーアイ化成(株)社製nanotek slurry、酸化亜鉛粒の粒径=70nm)をロールコーターで塗布し、約80℃で焼きつける作業をそれぞれ施し、付着量(Zn換算量)0.8g/m2のZnO皮膜を、両面に形成した。
このようにして、Alめっき鋼板(A1)の供試材を得た。
Alめっき層の上面及び下面での付着量(目付量)、皮膜の有無、皮膜の材質、皮膜の上面及び下面での付着量(Zn換算量)を、それぞれ下記表1に記載の通りに変更したこと以外は、Alめっき鋼板(A1)と同様にしてAlめっき鋼板の供試材を得た。
≪ダイ金型の作製≫
・母材
表1に記載される材質の鋼を用意し、焼鈍状態にて図8に示す上型102A及び下型102Bに近似した形状に粗加工し、真空中1180℃の加熱保持より窒素ガス冷却により焼入れ後、540~580℃での焼戻しにより64HRCに調質した。その後、仕上げ加工を行って、ダイ金型の母材を得た。
次いで、上型102A及び下型102Bにおけるめっき鋼板10と接触(摺動)する鋼板接触面に、窒化層を形成した。
前記母材に、次に示す条件にてイオン窒化処理を施した。つまり、流量比5%N2(残H2)雰囲気中で、500℃、5時間保持の条件でイオン窒化処理を施した後、それぞれの試験面を研磨によって仕上げ、窒化層を形成した。
母材の窒化層を形成した箇所に、アークイオンプレーティング装置を用い、圧力0.5PaのAr雰囲気中で、母材に-400VのBias電圧を印加し、60分の熱フィラメントによるプラズマクリーニングを行った。この後、金属成分の蒸発源である各種金属製ターゲット及び反応ガスとしてN2ガスをベースに、必要に応じCH4ガスを用い、母材温度500℃、反応ガス圧力3.0Pa、-50VのBias電圧にてPVD膜の成膜を行った。
前記≪ダイ金型の作製≫に記載の方法に準じて、PVD膜の組成を下記表2に記載ものとし、かつそのPVD膜の硬度を下記表2に記載の値となるよう調整して、ダイ金型(上型102A及び下型102B)を作製した。
得られたダイ金型の鋼板接触面について、接触(摺動)するめっき鋼板10の摺動方向におけるスキューネス(Rsk)を、前述の方法により測定した。また、得られたダイ金型の鋼板接触面について、硬さHv_Dieを、前述の方法により測定した。
表2に示すめっき鋼板及びダイ金型を用いて、後述の評価を実施した。
前記≪ダイ金型の作製≫に記載の方法に準じて、PVD膜の組成を下記表2に記載ものとし、かつそのPVD膜の硬度を下記表2に記載の値となるよう調整して、ダイ金型(上型102A及び下型102B)を作製した。
表2に示すめっき鋼板及びダイ金型を用いて、後述の評価を実施した。
ダイ金型の作製において、窒化層及びPVD膜を形成しなかったこと以外、実施例1と同様にしてダイ金型(上型102A及び下型102B)を作製した。
表2に示すめっき鋼板及びダイ金型を用いて、後述の評価を実施した。
ダイ金型の作製において、PVD膜を形成しなかったこと以外、実施例1と同様にしてダイ金型(上型102A及び下型102B)を作製した。
表2に示すめっき鋼板及びダイ金型を用いて、後述の評価を実施した。
ダイ金型の作製において、AlCrNのPVD膜の上にさらに「WC膜」を形成したこと以外、実施例1と同様にしてダイ金型(上型102A及び下型102B)を作製した。
表2に示すめっき鋼板及びダイ金型を用いて、後述の評価を実施した。
前記≪ダイ金型の作製≫に記載の方法に準じて、PVD膜の組成を下記表2に記載ものとし、かつそのPVD膜の硬度を下記表2に記載の値となるよう調整して、ダイ金型(上型102A及び下型102B)を作製した。
表2に示すめっき鋼板及びダイ金型を用いて、後述の評価を実施した。
・金型摩耗
まず、熱間潤滑性の評価装置を準備した。図8に示す熱間潤滑性の評価装置は、近赤外線加熱炉100と、上型102A及び下型102Bのみからなる金型とを備えている。上型102A及び下型102Bは、めっき鋼板の引き抜き方向に直交する方向に伸びた幅10mmの凸部を有しており、互いの凸部の頂面で供試材を挟み込むことで、所定の押付け荷重を掛ける。また、熱間潤滑性の評価装置には、近赤外線加熱炉100で加熱しためっき鋼板、及び、金型で挟み込むときのめっき鋼板の温度を測定するための熱電対(不図示)も設けられている。なお、図8中、10はめっき鋼板の供試材を示す。
図8に示す熱間潤滑性の評価装置を用いて、近赤外線加熱炉100により、窒素雰囲気で、30mm×500mmの供試材を920℃加熱した後、約700℃となった供試材を、上型102A及び下型102Bのみからなる金型で3kNの押付け荷重をかけつつ(つまり供試材を金型に摺動させつつ)、引き抜いた。なお、引抜き長さは100mm、引抜き速度は40mm/sとした。なお、920℃に加熱する際の平均昇温速度は、7.5℃/秒とした。
得られた金型摩耗量から、以下の評価基準により評価した。
A:金型摩耗量0.5μm以下
B:金型摩耗量0.5μm超え1μm以下
C:金型摩耗量1μm超え2μm以下
D:金型摩耗量2μm超え
金型への凝着について、以下の試験により評価した。
上記の熱間潤滑性の評価試験前後における「熱間潤滑性の測定装置の金型」のめっき鋼板10と接触(摺動)する鋼板接触面の表面形状差分を分析することで、金型の凝着量を測定した。具体的には、接触式の形状測定機を用いて、摺動前後の摺動部における金型表面のプロファイルを計測して、凝着物付着部の高さが最大となる位置での凝着高さ(以下、金型最大凝着高さ)を測定した。なお、金型最大凝着高さは、上型及び下型の凝着高さのうちの最大値とした。
得られた金型最大凝着高さから、以下の評価基準により評価した。
A:金型最大凝着高さ0.5μm以下
B:金型最大凝着高さ0.5μm超え1μm以下
C:金型最大凝着高さ1μm超え3μm以下
D:金型最大凝着高さ3μm超え
また、実施例8~11、16~20では、ダイ金型の鋼板接触面に、摺動方向へのスキューネス(Rsk)が0以上1.3以下、かつ硬さHv_DieがHV2500以上HV3000以下である硬質層を形成したことで、ダイ金型の摺動面の磨耗を低減しつつ、且つ金型への凝着も抑制できることを確認した。
≪ダイ金型の作製≫
前記「実施例A」における条件番号1、3、6、10、11、14、15、17、及び19にて作製したダイ金型において、その形状を図2A及び図2Bに示すプレス成形品を成形し得る形状のものにすると共に、第2稜線部において曲率半径が最小となる箇所での該曲率半径[Rmin]が下記表3及び表4に記載の値となる形状のものに変更し、且つ母材を縦壁部での硬さHv_Dieが下記表3及び表4に記載のものに変更したこと以外、「実施例A」における各条件番号と同様にしてダイ金型を作製した。
なお、窒化層及びPVD膜の成形箇所は、プレス成形時に金型と材料が接触すると想定される全域にわたり形成した。
表3及び表4に記載の条件番号のダイ金型を用い、炉温設定:920℃、材炉5分(成形品番号11のみ材炉6分)、成形開始温度:700℃にて熱間プレス成形を行った。
得られたプレス成形品について、第2稜線部において曲率半径が最小となる箇所での該曲率半径[Rmin]、プレス成形品の横断面を観察した場合に第2稜線部の曲率半径が最小となる横断面において天板部の横断面幅方向での中心箇所PA1minでの平滑度[SaA1]、縦壁部の横断面高さ方向での中心箇所PA2minでの平滑度[SaA2]、天板部における箇所PA1minでの表面性状のアスペクト比[StrA1]、縦壁部における箇所PA2minでの表面性状のアスペクト比[StrA2]を、前述の方法により測定した。測定結果を表3に示す。
さらに、表3及び表4に示すプレス成形品を用いて、後述の評価を実施した。
・縦壁部の表面品位
得られた各成形品番号のプレス成形品に対し、膜厚15μmの電着塗装、さらに膜厚20μmの上塗りを実施した後の製品に対し、縦壁部での表面品位を、以下の基準により判定した。
A:表面品位優(光沢度差<15,表面に傷なし)
B:表面品位OK(15≦光沢度差<30,表面に傷なし)
C:表面品位NG(光沢度差≧30,表面に傷なし)
D:表面欠陥ありNG(製品表面に筋状の傷あり)
天板部のうち側面側から観察した場合にフランジ部の曲率半径が最小となる箇所PB0minに対応する天板部における幅方向での中心箇所PB1minと、縦壁部のうち側面側から観察した場合に箇所PB0minに対応する縦壁部における高さ方向での中心箇所PB2minとの光沢度を、それぞれ以下の方法により測定し、この2箇所での光沢度の差を算出した。
なお、光沢度の測定は、JIS Z 8741(1997)に規定される、黒色鏡面ガラスn=1.567の反射率を基準100とした反射率の相対値を、光の入射角度60°で計測した。
第2稜線部での最小曲率半径[Rmin]が大きく、縦壁部に掛かる面圧が低いと考えられ、平滑度の差[SaB1-SaB2]が小さくなっている。
第2稜線部での最小曲率半径[Rmin]が成形品番号1より小さく、縦壁部に掛かる面圧が高いと考えられ、平滑度の差[SaB1-SaB2]が大きくなっている。
硬さHv_DieがHV2000未満との条件及びスキューネス(Rsk)が1.3超えとの条件の少なくとも一方を満たす金型を用いた熱間プレス成形では、金型へのめっき凝着が発生し、縦壁にスクラッチ傷が発生するため、表面状態の異方性を示すパラメータである縦壁部表面性状のアスペクト比[StrA2]、[StrB2]が大きく低下し、0に近くなっている。
また、縦壁部のスクラッチ傷部分とZnO層の光の反射度合に差があるため、光沢度の差が大きくなっている。
第2稜線部での最小曲率半径[Rmin]が成形品番号1よりも小さく、縦壁部に掛かる面圧が高いと考えられ、平滑度の差[SaB1-SaB2]が大きくなっている。
しかし、スキューネス(Rsk)が1.3以下との条件及び硬さHv_DieがHV2000以上HV3200以下との条件の両方を満たす金型を用いた熱間プレス成形では、縦壁部でのスクラッチ傷の発生が抑制され、表面状態の異方性を示すパラメータである縦壁部表面性状のアスペクト比[StrA2]、[StrB2]の低下も抑制される。
そのため、縦壁部と天板部の光沢度の差は小さくなっている。
プレス成形品の母材強度が異なる例である。
皮膜種が異なる例である。
本明細書に記載された全ての文献、特許出願、および技術規格は、個々の文献、特許出願、および技術規格が参照により取り込まれることが具体的かつ個々に記された場合と同程度に、本明細書中に参照により取り込まれる。
11、111 ダイ金型(ダイス)
11A、111A 鋼板接触面
11B、111B ダイ肩部
11C、111C 硬質層
11D、111D ダイ穴
12 ホルダー(鋼板おさえ金型)
12C 第二硬質層
13 パンチ
100 近赤外線加熱炉
102A 上型
102B 下型
112 鋼板
113 パンチ金型
113C 第二硬質層
114A、114B アルミめっき層
116A、116B 亜鉛化合物層または金属亜鉛層
Claims (30)
- Alめっき層の上に最表層として亜鉛化合物層または金属亜鉛層を有するAlめっき鋼板にダイ金型を用いて熱間プレス成形する熱間プレス成形品の製造方法であって、
前記ダイ金型は、ダイ穴の外側の表面であって且つ熱間プレス成形される前の前記Alめっき鋼板と接触する鋼板接触面のうち、ダイ肩部に隣接する全領域に、ダイ穴の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である硬質層を有する熱間プレス成形品の製造方法。 - 前記硬質層の前記スキューネス(Rsk)が-5.0以上である請求項1に記載の熱間プレス成形品の製造方法。
- 前記硬質層は、窒化層と、前記窒化層の表面にある硬質コーティング層と、を含む層である請求項1または請求項2に記載の熱間プレス成形品の製造方法。
- 前記硬質コーティング層は、硬さHv_DieがHV3200以下である請求項3に記載の熱間プレス成形品の製造方法。
- 前記硬質コーティング層がCrを含有する層である請求項4に記載の熱間プレス成形品の製造方法。
- 前記硬質コーティング層が、Tiを含有しかつ硬さHv_DieがHV3160以下である層である請求項3に記載の熱間プレス成形品の製造方法。
- 前記硬質コーティング層は、硬さHv_DieがHV2500以上HV3000以下である請求項3~請求項6のいずれか1項に記載の熱間プレス成形品の製造方法。
- 硬さHv_PartsがHV400以上である鋼母材と、前記鋼母材上にAlめっき層と、前記Alめっき層上に最表層として酸化亜鉛層と、を有し、
天板部と、前記天板部に第1稜線部を介して接続する縦壁部と、前記縦壁部に第2稜線部を介して接続するフランジ部と、を有し、
前記第2稜線部において曲率半径が最小となる箇所での該曲率半径[Rmin]が3mm以上10mm未満であり、
プレス成形品の横断面を観察した場合に前記第2稜線部の曲率半径が最小となる横断面において、前記天板部の横断面幅方向での中心箇所PA1minでの平滑度[SaA1]と、前記縦壁部の横断面高さ方向での中心箇所PA2minでの平滑度[SaA2]と、の差[SaA1-SaA2]が0.20μm以上であり、
前記天板部における前記箇所PA1minでの表面性状のアスペクト比[StrA1]と、前記縦壁部における前記箇所PA2minでの表面性状のアスペクト比[StrA2]と、の差[StrA1-StrA2]が0.50以下であるプレス成形品。 - 硬さHv_PartsがHV400以上である鋼母材と、前記鋼母材上にAlめっき層と、前記Alめっき層上に最表層として酸化亜鉛層と、を有し、
天板部と、前記天板部に第1稜線部を介して接続する縦壁部と、前記縦壁部に第2稜線部を介して接続するフランジ部と、を有し、
前記第2稜線部において曲率半径が最小となる箇所での該曲率半径[Rmin]が3mm以上10mm未満であり、
側面側から観察した場合に前記フランジ部の曲率半径が最小となる箇所PB0minに対応する前記天板部における幅方向での中心箇所PB1minでの平滑度[SaB1]と、側面側から観察した場合に前記箇所PB0minに対応する前記縦壁部における高さ方向での中心箇所PB2minでの平滑度[SaB2]と、の差[SaB1-SaB2]が0.30μm以上であり、
前記天板部における前記箇所PB1minでの表面性状のアスペクト比[StrB1]と、前記縦壁部における前記箇所PB2minでの表面性状のアスペクト比[StrB2]と、の差[StrB1-StrB2]が0.50以下であるプレス成形品。 - ダイ穴の外側の表面且つダイ肩部に隣接するダイ肩隣接面のうち、前記ダイ肩部に隣接する全領域に、ダイ穴の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である硬質層を有するダイ金型。
- 前記硬質層の前記スキューネス(Rsk)が-5.0以上である請求項10に記載のダイ金型。
- 前記硬質層は、窒化層と、前記窒化層の表面にある硬質コーティング層と、を含む層である請求項10または請求項11に記載のダイ金型。
- 前記硬質コーティング層は、硬さHv_Dieが3200以下である請求項12に記載のダイ金型。
- 前記硬質コーティング層がCrを含有する層である請求項13記載のダイ金型。
- 前記硬質コーティング層が、Tiを含有しかつ硬さHv_DieがHV3160以下である層である請求項12に記載のダイ金型。
- 前記硬質コーティング層は、硬さHv_DieがHV2500以上HV3000以下である請求項12~請求項15のいずれか1項に記載のダイ金型。
- 請求項10~請求項16のいずれか1項に記載のダイ金型と、パンチ金型と、を備え、
前記パンチ金型は、前記ダイ金型の前記ダイ肩隣接面に対向する対向面のうち、前記ダイ金型が前記硬質層を有する箇所と対向する全領域に、パンチ部の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である第二硬質層を有する金型セット。 - 前記第二硬質層の前記スキューネス(Rsk)が-5.0以上である請求項17に記載の金型セット。
- 前記第二硬質層は、第二窒化層と、前記第二窒化層の表面にある第二硬質コーティング層と、を含む層である請求項17または請求項18に記載の金型セット。
- 前記第二硬質コーティング層は、硬さHv_DieがHV3200以下である請求項19に記載の金型セット。
- 前記第二硬質コーティング層がCrを含有する層である請求項20に記載の金型セット。
- 前記第二硬質コーティング層が、Tiを含有しかつ硬さHv_DieがHV3160以下である層である請求項19に記載の金型セット。
- 前記第二硬質コーティング層は、硬さHv_DieがHV2500以上HV3000以下である請求項19~請求項22のいずれか1項に記載の金型セット。
- 請求項10~請求項16のいずれか1項に記載のダイ金型と、鋼板おさえ金型と、を備え、
前記鋼板おさえ金型は、前記ダイ金型の前記ダイ肩隣接面に対向する対向面のうち、前記ダイ金型が前記硬質層を有する箇所と対向する全領域に、パンチ挿通部の外側から内側に向かう方向に測定したスキューネス(Rsk)が1.3以下、かつ硬さHv_DieがHV2000以上である第二硬質層を有する金型セット。 - 前記第二硬質層の前記スキューネス(Rsk)が-5.0以上である請求項24に記載の金型セット。
- 前記第二硬質層は、第二窒化層と、前記第二窒化層の表面にある第二硬質コーティング層と、を含む層である請求項24または請求項25に記載の金型セット。
- 前記第二硬質コーティング層は、硬さHv_DieがHV3200以下である請求項26に記載の金型セット。
- 前記第二硬質コーティング層がCrを含有する層である請求項27に記載の金型セット。
- 前記第二硬質コーティング層が、Tiを含有しかつ硬さHv_DieがHV3160以下である層である請求項26に記載の金型セット。
- 前記第二硬質コーティング層は、硬さHv_DieがHV2500以上HV3000以下である請求項26~請求項29のいずれか1項に記載の金型セット。
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| JPWO2021215418A1 (ja) * | 2020-04-20 | 2021-10-28 | ||
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Also Published As
| Publication number | Publication date |
|---|---|
| KR102385301B1 (ko) | 2022-04-11 |
| EP4186611B1 (en) | 2024-05-29 |
| JPWO2019198728A1 (ja) | 2021-04-22 |
| KR20200125702A (ko) | 2020-11-04 |
| US12179246B2 (en) | 2024-12-31 |
| EP4186611A1 (en) | 2023-05-31 |
| EP3778060A1 (en) | 2021-02-17 |
| CN111936248B (zh) | 2022-08-30 |
| EP3778060B1 (en) | 2025-01-29 |
| EP3778060A4 (en) | 2022-04-13 |
| JP7081662B2 (ja) | 2022-06-07 |
| CN111936248A (zh) | 2020-11-13 |
| MX2020010666A (es) | 2020-10-28 |
| US20210114074A1 (en) | 2021-04-22 |
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