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WO2019163946A1 - Phytoprotecteur ayant un composé biocide pour principe actif, et composition herbicide de phytotoxicité réduite contenant ce phytoprotecteur et un composé herbicide - Google Patents

Phytoprotecteur ayant un composé biocide pour principe actif, et composition herbicide de phytotoxicité réduite contenant ce phytoprotecteur et un composé herbicide Download PDF

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Publication number
WO2019163946A1
WO2019163946A1 PCT/JP2019/006793 JP2019006793W WO2019163946A1 WO 2019163946 A1 WO2019163946 A1 WO 2019163946A1 JP 2019006793 W JP2019006793 W JP 2019006793W WO 2019163946 A1 WO2019163946 A1 WO 2019163946A1
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Prior art keywords
herbicidal
phytotoxicity
compound
herbicidal compound
safener
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Japanese (ja)
Inventor
暉 小石原
陽子 山田
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Mitsui Chemicals Agro Inc
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Mitsui Chemicals Agro Inc
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Priority to JP2019555040A priority Critical patent/JP6774575B2/ja
Publication of WO2019163946A1 publication Critical patent/WO2019163946A1/fr
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/86—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/34—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the groups, e.g. biuret; Thio analogues thereof; Urea-aldehyde condensation products
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof

Definitions

  • the present invention relates to a safener. More specifically, the present invention relates to a phytotoxicity reducing agent containing a bactericidal compound as an active ingredient, and a phytotoxicity-reduced herbicidal composition comprising the phytotoxicity reducing agent and a herbicidal compound.
  • herbicides are indispensable in the cultivation of crops in order to secure an appropriate yield of the crops and to realize efficient cultivation of the crops.
  • the herbicides used are given selectivity to the crops, and except for the plants to be controlled, the crops are not damaged in principle.
  • the crop selectivity of the herbicide is not always sufficient, and depending on the use conditions of the herbicide, the growth failure, growth suppression, growth suppression, brown spot appearance, and tillering suppression of the crop by the herbicide May cause known or unknown undesirable phytotoxicity such as yellowing, leaf wilt, withering, wilting, whitening, torsion, browning, root growth inhibition and the like.
  • Patent Documents 1 to 4 4, Non-Patent Document 1).
  • hydroxyisoxazole 3-hydroxy-5-isoxazole (hereinafter referred to as “hydroxyisoxazole”), which is a bactericidal compound, has an effect of reducing herbicide phytotoxicity in rice (Non-patent Document 2).
  • isoprothiolane having bactericidal activity and insecticidal activity is known to have a phytotoxicity-reducing effect on tefryltrione, which is a herbicide (Patent Document 19).
  • Japanese Unexamined Patent Publication No. 2016-40235 WO2010 / 070822 WO2011 / 145318 WO2011 / 145329
  • Japanese Patent Publication No.42-25660 WO2003 / 016303 JP-A-1-131163 Japanese Patent Publication No.42-6818 US Pat. No. 3,290,353 US Pat. No. 3,631,176 US Patent 4020095 Japanese Examined Patent Publication No. 47-34126 Japanese Patent No. 4438919 JP 2001-187786 A Japanese Patent Laying-Open No. 2005-112738 JP-T-2001-522840 JP 2004-346030 A JP 2007-137833 A JP 2008-69091 A
  • Pesticide Outlook December 2001, pp. 10-15 Studies on growth regulation of crops by 3-hydroxy-5-isoxazole 3rd report: Inundation damage of rice seedlings and reduction of phytotoxicity by herbicides Masaaki Ogawa and Yasuo Ota Journal of the Crop Science Society of Japan, Vol. 43, pp. 531-537 (1974)
  • herbicides that have been confirmed to be effective in reducing the phytotoxicity of hydroxyisoxazole, which is a bactericidal compound include cimetrin and DCPA (propanil; Dimethyl 2,3,5,6-tetrachlorobenzene-1,4- Mainly photosynthesis inhibiting herbicides such as dicarboxylate), MCC (swep), MCP (ethyl 2-methyl-4-chlorophenoxyacetate). Therefore, no knowledge has been obtained regarding the phytotoxicity-reducing effects of herbicides developed in recent years.
  • fungicidal compounds having bactericidal activity such as picalbutrazox, cyazofamide, kasugamycin, chlorothalonil, benomyl, thiophanate methyl, isoprothiolane and amisulbrom have not been clarified at present.
  • the subject of the present invention has biological activity other than the herbicidal effect, exhibits a phytotoxicity-reducing effect for various herbicides that exhibit different actions, and has an excellent phytotoxicity-reducing effect on cultivated plants than the existing phytotoxicity-reducing agents, And it is to find a novel safening agent with a wide range of use in which cultivated plants are not limited.
  • a predetermined fungicidal compound exhibits a herbicide phytotoxicity reducing effect. That is, the present inventors have found that a phytotoxicity reducing agent containing a predetermined bactericidal compound as an active ingredient and a herbicidal composition containing the phytotoxicity reducing agent and a herbicidal compound have a good phytotoxicity reducing effect, and have completed the present invention.
  • the present invention is as follows [1]-[19].
  • crops containing, as an active ingredient, at least one compound selected from the group consisting of hydroxyisoxazole, picalbutrazox, cyazofamide, kasugamycin, chlorothalonil, benomyl, thiophanate methyl, isoprothiolane and amisulbromine as an active ingredient Safener.
  • the safener according to [1], wherein the active ingredient is hydroxyisoxazole, picalbutrazox, amisulbrom or a salt thereof.
  • the crop is rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugarcane, potato, grape, soybean, green beans, pea, broad bean, azuki bean, strawberry, cabbage, Japanese radish, mibuna, mizuna, turnip, nabana, Chinese cabbage, broccoli, cauliflower, lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, capsicum, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, honey bee, ginger, radish, tobacco, carnation, iris
  • the phytotoxicity-reducing agent according to any one of [1] and [2], which is chrysanthemum, fig, citrus, timber (seedling), western turf (bentgrass, ryegrass, bluegrass) or Japanese turf.
  • the herbicidal compound is at least one herbicidal compound or a salt thereof selected from the group consisting of the following (A1) to (A6): (A1) ACCase-inhibiting herbicidal compound, (A2) an acetolactate synthase-inhibiting herbicidal compound, (A3) Whitening type herbicidal compound, (A4) VLCFA-inhibiting herbicidal compound, (A5) Protopolyfilinogen IX oxidase-inhibiting herbicidal compound, (A6) synthetic auxin herbicidal compound, The herbicidal composition according to [5], wherein the active ingredient contained in the safener is at least one compound selected from the group consisting of hydroxyisoxazole, picarbutrazox and amisulbrom or a salt thereof.
  • the crop is rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugarcane, potato, grape, soybean, green beans, pea, broad bean, azuki bean, strawberry, cabbage, radish, mibuna, mizuna, turnip, nabana , Chinese cabbage, broccoli, cauliflower, lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, capsicum, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, honey bee, ginger, radish, tobacco, carnation,
  • the herbicidal composition according to [5] or [6], which is iris, chrysanthemum, fig, citrus, timber (seedling), western turf (bentgrass, ryegrass, bluegrass) or Japanese turf.
  • A2-1 sulfonylurea herbicidal compound, pyrimidinylbenzoic acid herbicidal compound or triazolopyrimidine herbicidal compound
  • A3-1 A pyrazole herbicidal compound or a triketone herbicidal compound.
  • (B1) A method in which the phytotoxicity reducing agent a according to any one of [1] to [4] and the herbicidal composition b not containing the phytotoxicity reducing agent are mixed and applied
  • (B2) A method of independently applying the safener a in any one of [1] to [4] and the herbicidal composition b not containing the safener to the same crop
  • (B3) The phytotoxicity reducing agent a according to any one of [1] to [4] and the herbicidal composition c according to any one of [5] to [10] are independently applied to the same crop.
  • (B4) A method of applying the herbicidal composition c according to any one of [5] to [10].
  • the safener a, the herbicidal composition b, or the herbicidal composition c is treated to the plant body and / or seed, or applied to the soil and / or treated to the root or the rhizome of the plant body.
  • a method for reducing phytotoxicity [11] A method for reducing phytotoxicity.
  • the method for reducing phytotoxicity according to [12], wherein the treatment on the seed is spraying, smearing, dipping, powdering or spraying on the seed.
  • the method for reducing phytotoxicity according to [12] wherein the application to soil is treatment to paddy soil, treatment to the soil surface, irrigation to soil, or mixing with soil.
  • the crop is rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugarcane, potato, grape, soybean, green beans, pea, broad bean, azuki bean, strawberry, cabbage, Japanese radish, mibuna, mizuna, turnip, nabana, Chinese cabbage, blocky, cauliflower, lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, pepper, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, honeybee, ginger, arabic, tobacco, carnation, iris [11] The method of reducing phytotoxicity according to [11], which is chrysanthemum, fig, citrus, timber (seedling), western turf (bentgrass, ryegrass, bluegrass) or Japanese turf.
  • [16] The method for reducing phytotoxicity according to [11] or [15], wherein the crop is rice.
  • the application method selected from the group consisting of (B1) to (B4) is performed once or twice on the plant body before transplantation, or once on the soil and / or the root or rhizome of the plant body. Or the method of reducing the phytotoxicity as described in [11] performed twice.
  • the safener agent a is applied once or twice to the plant body before transplanting, and the herbicidal composition b not containing the safener agent is transplanted into the soil and / or Or the method applied to a plant body,
  • the said crop is rice, The method of reducing the phytotoxicity as described in [11] or [17].
  • the safener a is hydroxyisoxazole, picalbutrazox, amisulbrom or a salt thereof, and the herbicidal composition b is selected from the group consisting of the above (A2-1) and (A3-1)
  • the present invention is based on the finding that the bactericidal compound exhibits a herbicide phytotoxicity-reducing effect. That is, according to the present invention, a disease control effect derived from bactericidal activity can be expected by treating a phytotoxicity-reducing agent before and after herbicide treatment or at the time of herbicide treatment, and universally applied to various cultivated crops. Can be used effectively, and a good phytotoxicity reduction effect can be obtained.
  • “Damage mitigation agent” means that when agricultural materials are used in cultivated crops to control weeds and pests, growth damage, growth suppression, growth suppression, brown spot appearance, and tillering suppression are reduced. , Yellowing, leaf blight, withering, wilting, whitening, torsion, browning, root growth inhibition, etc., when known or unknown undesired phytotoxicity is expected, use together with agricultural materials or use agricultural materials It is a composition that reduces its phytotoxicity by single use before and after.
  • the salt of “a compound selected from the group consisting of hydroxyisoxazole, picarbutrazox, cyazofamide, kasugamycin, chlorothalonil, benomyl, thiophanate methyl, isoprothiolane, and amisulbromine” refers to a metal salt, an acid addition salt, etc. of the compound.
  • alkali metal salts such as lithium, sodium, potassium, for example, alkaline earth metal salts such as calcium, barium, magnesium, for example, aluminum salts or transition metal salts such as manganese, copper, zinc, iron, for example, Hydrohalic acid salts such as hydrofluoric acid, hydrochloric acid, hydrobromic acid, hydroiodic acid, for example, inorganic acid salts such as nitric acid, sulfuric acid, phosphoric acid, chloric acid, perchloric acid, such as methanesulfone Acid, ethanesulfonic acid, trifluoromethanesulfonic acid, benze Salts of sulfonic acids such as sulfonic acid and p-toluenesulfonic acid, such as formic acid, acetic acid, propionic acid, trifluoroacetic acid, fumaric acid, tartaric acid, succinic acid, maleic acid, malic acid, succinic acid, benzoic acid, man
  • ACCase-inhibiting herbicidal compound refers to, for example, allyloxypropionic acid-based compounds, cyclohexadione oxime-based compounds, and the like, for example, propaxahop, quizalofop, haloxyhop, fluazifopbutyl, fluazifop-P-butyl. , Cihalohop butyl, clodinahop propargyl, diclohop methyl, phenoxaprop-P-ethyl, butroxidim, propoxydim, cretodim, tepraxidim, tolalkoxydim, cetoxydim, cycloxydim, pinoxaden and the like.
  • “Acetolactate synthase-inhibiting herbicidal compound” refers to, for example, sulfonylurea compounds, sulfonylaminocarbonyltriazolinone compounds, pyrimidinylbenzoic acid compounds, triazolopyrimidine compounds, imidazolinone compounds, and the like.
  • the “whitening type herbicidal compound” refers to, for example, a pyrazole compound, a triketone compound, and the like.
  • pyrazolate, pyrazoxifene, benzophenap, pyrasul photole, topramone, tolpyralate, mesotrione, sulcotrione, benzobicyclo , Tefryltrione, tembotrione, bicyclopyrone, lancotrione, cyclopyrimolate, fenquinotrione, etc. preferably pyrazolate, pyrazoxifene, benzophenap, mesotrione, sulcotrione, benzobicyclone, tefryltrione , Lancotrione, cyclopyrimolate, fenquinotrione, and the like, and more preferably sulcotrione, tefryltrione, and the like.
  • VLCFA-inhibiting herbicidal compound refers to, for example, a chloroacetamide compound and the like, for example, acetochlor, butachlor, alachlor, dimetachlor, dimethenamide, propachlor, tenyl chlor, metazachlor, metolachlor, S-metolachlor , Pretilachlor, petoxamide, mefenacet, fenfentrol, fentolazamide, ipfencarbazone, phenoxasulfone, and the like.
  • “Protopolyfilinogen IX oxidase-inhibiting herbicidal compound” refers to, for example, a diphenyl ether compound, a triazolinone compound, and the like, for example, acifluophene, bifenox, fomesafen, lactophene, oxyfluorfen, carfentrazone ethyl, Sulfentrazone, pentoxazone, pyraclonyl, oxadiazone, oxadialgyl and the like.
  • the “synthetic auxin-based herbicidal compound” refers to, for example, a phenoxycarboxylic acid-based compound and the like, for example, chromeprop, MCPA, MCPB, 2,4-DB, and fluoropyraloxifene benzyl.
  • Crop refers to a plant that protects and manages human propagation and growth. Crop is categorized by comprehensively judging its cultivation method, commercial value, purpose of use, use part, botany classification, etc. Generally, crops are roughly classified into agricultural crops and horticultural crops. The Agricultural crops are divided into food crops, craft crops, feed crops, and green manure crops according to the purpose of use.
  • the “plant” in the present invention is a general term for all parts constituting the “crop”, and examples thereof include stems, leaves, roots, seeds, flowers, fruits and the like.
  • the “seed” as used in the present invention refers to a seed that stores nutrients for germination of young plants and is used for agricultural propagation. Specifically, for example, seeds such as corn, soybean, cotton, rice, sugar beet, wheat, barley, sunflower, tomato, cucumber, eggplant, spinach, sweet pea, pumpkin, sugar cane, tobacco, green pepper, rape, potato, potato, etc.
  • Seed potatoes such as sweet potato and konjac, edible lily, bulbs such as tulips, and seed balls such as raccoon, etc .; it is a plant produced by artificially manipulating genes, etc., and does not exist in nature Genetically modified crops; for example, soybeans, corn, cotton, etc. that have been given herbicide tolerance, adapted to cold regions, such as rice, tobacco, etc .; or, for example, seeds of corn, cotton, etc., that have been given the ability to produce insecticides, potatoes Tuber etc., but is not limited to these .
  • a phytotoxicity-reducing agent comprising the fungicidal compound of the present invention as an active ingredient
  • a phytotoxicity-reduced herbicidal composition containing the phytotoxicity-reducing agent and a herbicidal compound
  • the safener of the present invention comprises, as an active ingredient, at least one compound selected from the group consisting of hydroxyisoxazole, picarbutrazox, cyazofamide, kasugamycin, chlorothalonil, benomyl, thiophanate methyl, isoprothiolane, and amisulbrom. contains. What are the active ingredients? From the viewpoint of the effect of the present invention, hydroxyisoxazole, picalbutrazox, amisulbrom or a salt thereof is preferable.
  • the phytotoxicity reducing agent of the present invention may be used as it is, but is usually used by mixing with a carrier, and if necessary, a surfactant, a binder, a disintegrant, a stabilizer, a pH adjuster, an antibacterial agent.
  • a surfactant such as sodium sulfate, sodium EDTA, sodium EDTA, sodium EDTA, sodium EDTA, sodium EDTA, sodium EDTA, sodium sulfate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium bicarbonate, sodium sulfate, sodium bicarbonate, sodium sulfate, sodium bicarbonate, sodium sulfate, sodium bicarbonate, sodium sulfate, sodium bicarbonate, sodium sulfate, sodium bicarbonate, sodium sulf
  • the carrier used in the safener of the present invention is a synthetic or natural compound formulated to help the active ingredient reach the site to be treated and to facilitate the storage, transport and handling of the active ingredient compound.
  • it is an inorganic or organic substance and is usually used for agricultural and horticultural agents, it can be used in either solid or liquid form and is not limited to a specific one.
  • solid carrier examples include inorganic substances such as bentonite, montmorillonite, diatomaceous earth, white clay, talc and clay; plant organic substances such as wood flour and sawdust; Can be mentioned.
  • liquid carrier examples include aromatic hydrocarbons such as toluene; naphthenes; paraffinic hydrocarbons such as n-paraffin, liquid paraffin, and kerosene; acetone and methyl ethyl ketone. Ketones such as dioxane and diethylene glycol dimethyl ether; alcohols such as ethanol and ethylene glycol; carbonates such as ethylene carbonate; aprotic solvents such as dimethylformamide; and water.
  • aromatic hydrocarbons such as toluene; naphthenes; paraffinic hydrocarbons such as n-paraffin, liquid paraffin, and kerosene; acetone and methyl ethyl ketone.
  • Ketones such as dioxane and diethylene glycol dimethyl ether
  • alcohols such as ethanol and ethylene glycol
  • carbonates such as ethylene carbonate
  • aprotic solvents such as dimethylformamide
  • adjuvants include surfactants, binders, disintegrants, stabilizers, pH adjusters, antibacterial / antifungal agents, thickeners, antifoaming agents, antifreeze agents and the like.
  • a surfactant that is usually used for the purpose of emulsifying, dispersing, spreading, and / or wetting the agricultural chemical preparation can be used.
  • a surfactant that is usually used for the purpose of emulsifying, dispersing, spreading, and / or wetting the agricultural chemical preparation can be used.
  • sorbitan fatty acid ester such as, for example, sorbitan fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene polyoxypropylene block polymer, alkyl polyoxyethylene polyoxypropylene block polymer
  • Nonionic interfaces such as ethers, polyoxyethylene alkylamines, polyoxyethylene fatty acid amides, polyoxyethylene bisphenyl ethers, polyoxyalkylene adducts of higher alcohols and polyoxyethylene ethers and ester type silicones and fluorosurfactants Active agent; Alkyl sulfate, polyoxy
  • binder examples include sodium alginate, polyvinyl alcohol, gum arabic, carboxymethyl cellulose (hereinafter referred to as “CMC sodium”), bentonite and the like.
  • Examples of the disintegrant include CMC sodium and croscarmellose sodium.
  • stabilizer examples include hindered phenol-based antioxidants; or benzotriazole-based and hindered amine-based ultraviolet absorbers.
  • Examples of the pH adjuster include phosphoric acid, acetic acid, sodium hydroxide and the like.
  • antibacterial / antifungal agent examples include industrial bactericides such as 1,2-benzisothiazolin-3-one, and antibacterial / antifungal agents.
  • thickener examples include xanthan gum, guar gum, sodium CMC, gum arabic, polyvinyl alcohol, montmorillonite and the like.
  • antifoaming agents examples include silicone compounds.
  • antifreezing agent examples include propylene glycol and ethylene glycol.
  • the adjuvants described above are examples, and the adjuvant of the present invention is not limited to the above.
  • the content of the active ingredient in the safener of the present invention is usually in the range of 0.1 to 100% by weight, preferably in the range of 0.1 to 90%, more preferably 1 It is in the range of ⁇ 80%, particularly preferably in the range of 5 to 50%.
  • the phytotoxicity reducing agent of the present invention can exert an effect on various phytotoxicity to cultivated crops, for example, phytotoxicity to crops caused by herbicidal compounds, for example, growth disorder, growth inhibition, growth inhibition, appearance of brown spots It is possible to reduce phytotoxicity such as tillering suppression, yellowing, leaf wilt, withering, wilting, whitening, torsion, browning, root growth inhibition and the like.
  • the phytotoxicity reducing agent of this invention is especially excellent in the phytotoxicity suppression effect with respect to the crop resulting from a herbicidal compound.
  • the phytotoxicity reducing agent comprising the fungicidal compound of the present invention as an active ingredient is phytotoxicity to crops caused by the herbicidal compound, for example, growth disorder, growth inhibition, growth inhibition, appearance of brown spots, tillering inhibition, yellowing, It is possible to avoid leaf blight, death, wilting, whitening, torsion, browning, root growth inhibition, and the like.
  • target crops include rice, wheat, barley, potato, corn, grape, apple, pear, peach, nectarine, ume, apricot, sweet potato, oyster, quince, quince, chestnut, cucumber fruit, blueberry, loquat, banana, citrus , Figs, olives, papaya, akebi, oil palm, soybean, groundnut, green beans, peas, green peas, broad bean, azuki bean, strawberry, cabbage, radish, mizuna, mibuna, turnip, komatsuna, Chinese cabbage, broccoli, cauliflower, nabana, lettuce, tomato , Eggplant, pepper, capsicum, tougan, leek, onion, scallop, cucumber, bitter melon, melon, watermelon, pumpkin, zucchini, carrot, ginger, ginger, burdock, ud, taranki, spinach, sugar beet, Sparagas, okra, seri, safflower, rapeseed, honeybee, sweet potato, sugar be
  • rice refers to an annual plant of the genus Oryza, and is classified into two ecotypes, japonica species (O. sativa subsp. Japonica) and indica species (O. sativa subsp. Indica).
  • the Starch the main component of the edible portion of rice, is classified into amylose and amylopectin due to the difference in molecular structure, and varieties containing about 20% amylose are cultivated ( ⁇ ), and the amylose content is 0% due to genetic defects. Varieties that are categorized as Mochi ( ⁇ ).
  • upland rice, black rice, red rice, green rice and special varieties bred using disease resistance and insect resistance as an index, herbicide resistance, insecticidal effect, pest resistance by classical breeding methods or genetic recombination techniques Also included are varieties that have been given sex.
  • target crops include rice, wheat, barley, corn, rapeseed, cotton, sunflower, sugarcane, potato, grape, soybean, green beans, pea, broad bean, azuki bean, strawberry, cabbage, radish, mibuna, mizuna, turnip , Nabana, cabbage, broccoli, cauliflower, lettuce, non-headed lettuce, tomato, cherry tomato, eggplant, pepper, capsicum, onion, cucumber, melon, watermelon, pumpkin, spinach, sugar beet, okra, honey bee, ginger, red pepper, tobacco, Carnation, iris, chrysanthemum, fig, citrus, timber (seedling), western turf (bentgrass, ryegrass, bluegrass) or Japanese turf are preferred.
  • the phytotoxicity reducing agent of the present invention is particularly excellent in the effect of reducing phytotoxicity caused by herbicidal compounds in these crops.
  • the safener that contains the fungicidal compound of the present invention as an active ingredient can also be used for controlling plant diseases caused by the original fungicidal activity.
  • diseases that can be controlled For example, rice blast (Magnaporthe grisea), blight blight (Thanatephorus cucumeris), brown sclerotia (Ceratobasidium setariae), brown sclerotia nuclei (Waiteria circinata), brown rot eucalyptus (T) Disease (Sclerotium hydrophilum), red sclerotia (Wairrea circinata), scab (Entyloma dactylidis), staphylococcal sclerotia (Magnaporthe salivinii), gray sclerotia (Ceratobasidoma) Sphaerulina ory ina), messy seedling disease (Gibberella fujikuroi), seedling blight (Pythium spp
  • Wheat powdery mildew Bacterial disease (Ceratobasminidia) Blight (Phaeosphaeria nodorum), Seedling blight (Fusarium spp., Pythium spp., Rhizotonia
  • Corn mold blight (Gibberella zeae, etc.), seedling blight (Fusarium avenaceum, Penicillium spp, Phythium spp., Rhizoctonia spr.), Rust disease (Puccinia sorghihos disease, black leaves) Ustilago maydis, Colletotrichum graminicola, Northern spot disease (Cochliobolus carbonum), Brown disease (Acidovorax avenae subb. Avenis), Bacterial disease, Burr disease disease, Burr. hemi pv.
  • zeae wilt bacterial disease (Erwinia stewartii); grape downy mildew (Plasmopara avitolicola), rust disease (Physopella ampelopdisidi), powdery mildew (Uncinulane black and white rot) Diseases (Glomerella cingulata, Colletotrichum accutatum), black rot (Guignardia bidwelliii), vine split disease (Phomopsis vitipedra), scab (Zyophialajaisensis disease) Hermaphroditis (H licobasidium mompa), Shiromon rot (Rosellinia necatrix), crown gall temple petitioner disease (Agrobacterium vitis);
  • Apple powdery mildew Podosphaera leukotricha
  • black spot disease Venturia inaequalis
  • spotted leaf disease Alternaria maria
  • red star disease Gymnosporium yamadae
  • Monilia disease Monilia disease
  • Botryosphaeria berengeriana Anthracnose (Colletotrichum accutatum, Glomerella cingula), Soot spot (Zyophiala jamicensis), Soot spot (Gloodesporum) sidium mompa, white leaf blight (Rosellinia necatrix), blight (Phomopsis mary, Diaporthe tanakae), brown spot (Diplocaromia terumiarumiatrum), burn injury (Erwiniaorumiarumia head disease) ), Hair root disease (Agrobacterium rhizogenes); pear black spot disease (Alternaria kikuchiana), black star disease (Venturi
  • Pests of pear Phytophthora cactorum, Phytophthora syringae
  • blight blight Erwinia sp.
  • Peach black scab Cyladosporium carpophilum
  • homoposis rot Colletotrichum gloe osporioides
  • leaf curl disease Taphrina deformans
  • perforated bacterial disease Xhanthomonas campestris pv.
  • Syringae oyster anthracnose (Glomerella cinulata), deciduous leaf disease (Cercospora kakii; Mycosphaerella nawae, ivy aquatic palae) s); citrus black spot disease (Diaporthe citri), green mold disease (Penicillium digitatum), blue mold disease (Penicillium italicum), common scab (Elsinophaephathophorthophorthopathia) citri), brown spot bacterial disease (Pseudomonas syringae pv. syringae), greening disease (Liberactor asiaticus), root cancer tumor (Agrobacterium tumefaciens);
  • Gray mold disease such as tomato, cucumber, beans, strawberry, potato, cabbage, eggplant, lettuce
  • sclerotia disease such as tomato, cucumber, legume, strawberry, potato, rapeseed, cabbage, eggplant, lettuce, etc.
  • Seedling blight of various vegetables such as tomato, cucumber, beans, radish, watermelon, eggplant, rapeseed, pepper, spinach, sugar beet (Rhizotonia spp., Phythium spp., Fusarium spp., Phytophthora spp., Sclero, etc.)
  • Bacterial wilt of solanaceous plants (Ralstonia solanacearum); downy mildew of cucurbits (Pseudoperonospora) cubensis), powdery mildew (Sphaerotheca fuliginea), anthracnose (Colletotrichum orbiculare), vine
  • Phytophthora infestans brown rot disease (Phytophthora capsici), brown spot bacterial disease (Pseudomonas citrichii), stem rot (Pseudomonas corrugata), stem rot wilt disease .
  • Arotovora subsp carotovora spot bacterial disease (Pseudomonas sp).
  • Rapeseed black spot disease (Alternaria brassicae), black rot (Xhanthomonas campestris pv. Campestris), black spot bacterial disease (Pseudomonas syringae pav. Maculicola or black rot) Etc.), white spot disease (Cercosporella brassicae), root rot disease (Phoma lingam), root-knot disease (Plasmodiophora brassicasae), downy mildew (Peronospora parasitica), black rot (Xhanthompastrastocristocralcristocrustacto). (Pseudomonas syringae pv.
  • Soybean purpura (Cercospora kikuchiii), Black scab (Elsinores) porthe phaseolorum), Rhizoctonia root rot (Rhizoctonia solani), stems late blight (Phytophthora sojae), downy mildew (Peronospora manshurica), rust (Phakopsora pachyrhizi), anthracnose (Colletotrichum truncatum, etc.), leaf grilled disease (Xhanthomonas campestris pv . Lycines), spotted bacterial disease (Pseudomonas syringae pv. Glycinea);
  • Kidney anthracnose (Colletotrichum lindemuthianum), bacterial wilt (Ralstonia solanacearum), bacterial wilt (Pseudomonas syringaee pv. Black astringent disease (Mycosphaerella berkeleyi), brown spot disease (Mycosphaerella arachidis), bacterial wilt (Ralstonia solanacearum); pea powdery mildew (Erysiphe pisi), downy mildew (Peronisporum) (Pseudomonas syringae pv. Pisi), vine rot fungus (Xhanthomonas campestris pv.
  • Pisi cucumeris, plague (Phytophthora infestans), silver scab (Helminthosporum solani), dry rot (Fusarium oxysporum, Fusarium solani), powdery scab (Spongosporasora teresa) anacearum), black foot disease (Erwinia carotovora subsp. atroseptica), scab (Streptomyces scabies, Streptomyces acidiscabies), soft rot (Erwinia carotovora subsp. carotovora), viscous rot (Crostridium spp.), Wakusabyo (Clavibacter michiganensis subsp.
  • sweet potato blight Streptomyces ipomoea
  • sugar beet brown spot Cercospora beticola
  • downy mildew Peronospora schachtii
  • black root disease Aphanomyces
  • snake eye disease Phoma betae
  • root cancer tumor Agrobacterium tumefaciens
  • scab Streptomyces scabies
  • spot bacterial disease Pseudomonas syringae pv. Aptta
  • Carrot black leaf blight (Alternaria dauci), knot disease (Rhizobacter dauci), root cancer disease (Agrobacterium tumefaciens), Streptomyces orporosis, roinva spr.
  • Strawberry powdery mildew (Sphaerotheca aphanis var. Aphanis), plague (Phytophthora nicotianae, etc.), anthracnose (Glomerella cingulata, etc.), fruit rot (Pythium vomtum), and bacterial rot (Xanthomas) c mpestris), Bacterial Blight (Pseudomonas marginalis pv.
  • Tan Nuclear disease (Typhula incarnata), Snow rot black granule nuclei (Typhula ishikariiensis), Snow rot large particle nuclei (Myriosclerotinia borealis), Fairy ring disease (Marasmius oreides, etc.), Phium disease (Pyum disease, etc.) Pyricularia grisea) and the like.
  • herbicidal composition comprising a safener and herbicidal compound” (hereinafter referred to as herbicidal composition) of the present invention. it can.
  • herbicidal compound contained in the herbicidal composition of the present invention include, in addition to herbicidal compounds selected from the group consisting of the following (A1) to (A6) or salts thereof, for example, bromobutide, cimethrin, dimetamethrin, bentazone. , Daimlon, Cumyluron, Oxadichromene, Esprocarb, Pyributicarb, Molinate, Synmethylin and the like.
  • the herbicidal composition of the present invention is preferably at least one herbicidal compound selected from the group consisting of the following (A1) to (A6) or a salt thereof, More preferably, it is at least one herbicidal compound selected from the group consisting of the following (A2) and (A3) or a salt thereof.
  • the (A2) is preferably (A2-1) a sulfonylurea herbicidal compound, a pyrimidinylsalicylic acid herbicidal compound or a triazolopyrimidine herbicidal compound
  • the (A3) is (A3-1) a pyrazole herbicidal compound Or triketone herbicidal compounds are preferred.
  • At least one herbicidal compound selected from the group consisting of (A2-1) and (A3-1) or a salt thereof is more preferable.
  • the herbicidal composition of the present invention can contain the carrier and the adjuvants exemplified in the phytotoxicity reducing agent in addition to these herbicidal compounds.
  • the content of the herbicidal compound in the composition of the present invention is usually in the range of 0.1 to 90% by weight, preferably in the range of 1 to 80%, and more preferably in the range of 5 to 50. % Range.
  • the total content of the safener and the herbicidal compound in the composition of the present invention is usually in the range of 0.1 to 90% by weight, preferably in the range of 1 to 80%, Preferably, it is in the range of 5 to 50%.
  • the mixing ratio of the safener and the herbicidal compound in the composition of the present invention is usually a ratio of 0.001 to 1000 of the safener with respect to the herbicidal compound by weight, preferably 0.01 to 1,000. A ratio of 100.
  • the herbicidal composition of the present invention can be produced according to a conventional method relating to the production of general agricultural chemicals. At least two kinds of active ingredients, a bactericidal compound and a herbicidal compound, which are active ingredients of a safener, are mixed, and if necessary, the above-mentioned carrier, the above-mentioned auxiliary agent, etc. are mixed as necessary. A composition containing either a fungicidal compound or a herbicidal compound that is an active ingredient of a safener or the herbicidal compound, and then adding the other to the composition. A herbicidal composition with reduced phytotoxicity containing both active ingredients may be produced.
  • the herbicidal composition of the present invention can be formulated into dosage forms such as wettable powders, flowable powders, granular wettable powders, OD drugs, powders, liquids, emulsions, granules, and packs.
  • the herbicidal composition of the present invention is such that the active ingredient contained in the safener is at least one selected from the group consisting of hydroxyisoxazole, picalbutrazox and amisulbrom.
  • the compound or a salt thereof, and the herbicidal compound is preferably at least one compound selected from the group consisting of (A1) to (A6) or a salt thereof.
  • the herbicidal composition of the present invention has bactericidal activity and can also be used as weed control due to the original herbicidal activity.
  • Weeds that can be controlled include, for example, barb, bean bark, enokirogusa, akinoenokorogusa, kienokorokusa, inubibies, okisakiki, texas panicum, melicennium millet, seiban sorghum, shutter cane, gypsywheat, oats, blackgrass, blackgrass, blackgrass Canary Creek Saeyoshi, Alaska Plover, Vulgaris, Shibumugi, Kogomegatsutsu, Hamasuge, Kihamasuge, Surihiyu, Blue-headed Oyster, Hagaga Ogatetou, Ichibibi, American King Deer, Buckwheat , Inuta, Inu Dazuki, White-bellied morning glory, Malba morning glory, American morning glory, Ma North American morning glory
  • the herbicidal composition of the present invention contains the phytotoxicity reducing agent of the present invention, avoiding phytotoxicity to crops caused by the herbicidal compound, for example, growth inhibition, appearance of brown spots, yellowing, withering, wilt etc. Is possible.
  • target crops include crops exemplified in the safeners.
  • phytotoxicity to crops can be reduced by an application method selected from the group consisting of the following (B1) to (B4).
  • the phytotoxicity reducing agent of the present invention hereinafter referred to as phytotoxicity reducing agent a
  • the herbicidal composition not containing phytotoxicity reducing agent a hereinafter referred to as herbicidal composition b
  • the same herbicidal composition of the present invention can be used except that it does not contain a safener.
  • the safener a is hydroxyisoxazole, picalbutrazox, amisulbrom or a salt thereof, and the herbicidal composition b is selected from the group consisting of the above (A2-1) and (A3-1) And at least one herbicidal compound or a salt thereof.
  • the application method selected from the group consisting of (B1) to (B4) is performed once or twice on the plant body before transplanting, or on the soil and / or the root or rhizome of the plant body. Can be performed once or twice.
  • the safener agent a is applied once or twice to the plant body before transplanting, and the herbicidal composition b not containing the safener agent is transplanted into the soil and / or the plant body. It is preferable that the crop is rice.
  • the safener a, the herbicidal composition b or the herbicidal composition c is treated to the plant body and / or seed, or applied to the soil and / or the root or rhizome of the plant body.
  • or (B4) is demonstrated in detail.
  • Examples of the method for applying the safener agent a, the herbicidal composition b or the herbicidal composition c in the above (B1) to (B4) include, for example, foliage spraying treatment, seedling box treatment, paddy field soil to plant individuals Treatment, application to the soil surface, soil mixing after application to the soil surface, injection into the soil, soil mixing after injection in the soil, soil irrigation, soil mixing after soil irrigation, Examples include spraying treatment on plant seeds, smearing treatment on plant seeds, dipping treatment on plant seeds, dressing treatment on plant seeds, spraying treatment on plant seeds, etc., which are usually used by those skilled in the art. Even in such application methods, it exhibits sufficient efficacy.
  • the dosage and application concentration of the safener a, the herbicidal composition b or the herbicidal composition c are the target crop, the target disease, the degree of occurrence of the disease, although it varies depending on the dosage form, application method, various environmental conditions, etc., when spraying or irrigating, the amount of active ingredient is suitably 50 to 1,000,000 g per hectare, preferably 100 to 500 per hectare. 1,000 g.
  • the amount used for seed treatment is 0.001 to 50 g, preferably 0.01 to 10 g, per 1 kg of seed.
  • herbicidal composition b or herbicidal composition c When the safener a, herbicidal composition b or herbicidal composition c is applied to a plant individual, foliage spraying treatment, soil surface spraying treatment, soil injection treatment, soil irrigation treatment, suitable carrier The treatment may be performed after dilution to an appropriate concentration. When contacting with plant seeds, they may be used after being diluted to an appropriate concentration and then dipped, dressed, sprayed, sprayed or smeared on plant seeds. In the case of powder coating, spraying, spraying and smearing treatment, the amount of preparation used is usually about 0.05 to 50%, more preferably 0.1 to 30% of the dry plant seed weight. The amount used is not limited to these ranges, and may vary depending on the form of the preparation and the type of plant seed to be treated.
  • the safener a, herbicidal composition b or herbicidal composition c may be treated alone and in combination with fungicides, insecticides, acaricides, nematicides or planting agents, simultaneously or sequentially. May be processed.
  • fungicides to be treated in combination include phenylamide fungicides, mitotic and mitotic inhibitors, succinate dehydrogenase inhibitors (SDHI agents), quinone external inhibitors (QoI agents), quinone internals Inhibitor (QiI killer), oxidative phosphorylation uncoupling inhibitor, quinone external stigmateline binding subsite inhibitor (QoSI agent), amino acid biosynthesis inhibitor, protein biosynthesis inhibitor, signal transduction inhibitor, lipid and cell membrane Biosynthesis inhibitors, demethylation inhibitors (DMI agents), amine fungicides, 3-ketoreductase inhibitors in C4-demethylation of sterol biosynthesis, squalene epoxidase inhibitors of sterol biosynthesis, cell wall biosynthesis Synthesis inhibitor, melanin biosynthesis inhibitor, host plant resistance inducer, dithiocarbamate fungicide, phthalimide fungicide, gua Jin fungicides, multifunctional point contact active fungicides, mention may be made of other
  • insecticides examples include carbamate acetylcholinesterase (AChE) inhibitors, organophosphorus acetylcholinesterase (AChE) inhibitors, GABAergic chloride channel blockers , Sodium channel modulator, nicotinic acetylcholine receptor (nAChR) competitive modulator, nicotinic acetylcholine receptor (nAChR) allosteric modulator, glutamatergic chloride channel (GluCl) allosteric modulator, juvenile hormone analog, non-specific ( Multisite) inhibitors, mite growth inhibitors, mitochondrial ATP synthase inhibitors, oxidative phosphorylation uncouplers that disrupt proton gradients, nicotinic acetylcholine receptors (n ChR) channel blocker, chitin biosynthesis inhibitor type 0, chitin biosynthesis inhibitor type 1, fly insect molting inhibitor, molting hormone (ec
  • fungicides include, for example, benalaxyl, benalaxyl M or chiralaxyl (benalaxyl-M or kiralaxyl), furalaxyl, metalaxyl (x), metalaxyl (x), or mephenoxam (x).
  • Phenylamide fungicides such as ofurase; Carbendazim (carbendazim), fuberidazole (fuberidazole), thiabendazole (thiabendazole), thiophanate (thiophanate), diethofencarb (diethofencarb), zoxamide (zoxamide), ethaboxam (ethaboxam), pencycuron (pencycuron), fluopicolide (fluopicolide), Fenamakuriru (phenamacril) Mitotic and mitotic inhibitors such as; Benodanil, benzovindiflupyr, bixafen, boscalid, carboxin, fenfuram, fluopyram, flupyranf, fluxilaf ), Furametopyr, isofetamide, isopyrazam, mepronil, oxycarboxin, penthiopyrad, flufluto n), sedaxane, thifluzamide, pyr
  • Conazole epoxiconazole
  • etaconazole fenarimol
  • fenbuconazole fluquinconazole
  • fluconconole fluconconole
  • fluconazole Hall flutia fol
  • hexaconazole hexazolole
  • imidazole imiconazole (imazoleol)
  • Oxpoconazole fumarate pefurazoate
  • penconazole prochloraz
  • propiconazole, prothioconol Pyrifenox, pyrisoxazole, simeconazole, tebuconazole, tetraconiole, triaditrifone, triazidifonol Demethylation inhibitors (DMI agents) such as (trifoline), triticonazole, mefentrifluconazole, ipfentrifluconazole, etc .
  • Aldimorph dodemorph
  • fenpropyl ep
  • 3-keto reductase inhibitors in C4-demethylation of sterol biosynthesis such as fenhexamide, fenpyrazamine; Squalene epoxidase inhibitors of sterol biosynthesis, such as piributicalb, [b-15.2] naphthifine, [b-15.3] terbinafine; Polyoxins, dimethomorph, dimorphorph, pyrimorph, benthiavalicrub, benchavalipropyl Cell wall biosynthesis inhibitors such as varifenate; Phthalide or fthalide, pyroquilon, tricyclazole, carpropamide, diclocymet, phenoxanil, olprocarbin, olprocarbin, olprocarbin Host plant resistance inducers such as acibenzolar-S-methyl, probenazole, thiadinyl, isothianil, laminarin, dicloventiazox, etc .; Mancozeb,
  • Phthalimide fungicide Guanidine fungicides such as guazatine, iminoctadin, iminoctaine albecylate, iminoctaine triacetate; Basic copper chloride, cupric hydroxide (copper (II) hydroxide), basic copper sulfate, organic copper compound (organocopper compound), bisethylenediamine copper complex salt of dodecylbenzenesulfonate ] (Dodecyl benzene sulphonic acid bisethylene diamine copper [II] salt, DBEDC), sulfur, fluorimide, dicyclofluanid, dilfluanide, diluluanide Multi-acting point contact active fungicides such as onato (chinomesionat or quinomethionate), extract from cotyledons of lumberjack seedlings (BLAD); Dicloventiazox, fenpicoxamide, dip
  • Insecticides include phosphocarb, aranicarb, butocarboxim, butoxycarboxim, thiodicarb, thiophanodib, thiophanodib, thiophanodix, , Benfuracarb, carbaryl, carbofuran, carbosulfan, etiofencarb, fenobucarb, formethanate, formetanate b), isoprocarb, methiocarb, methomyl, oxamyl, pirimicarb, propoxyur, trimetacarb, trimetacarb, trimetacarb, trimetacarb, trimetacarb, trimetacarb allylcarb, aldoxycarb, bufencarb, butacarb, carbanolate, metocarb, xylylcarb, xylylcarb, xylylcarb, xylylcarb, x
  • Chlorphoxim Chlorphoxim, Sulprofos, Diamidafos, Tetrachlorvinphos, Propaphos, Mesulfenfos, Dioxabenzofos (dioxen) offos), etrimfos, oxydeprofos, formothion, fensulfothion, isazofos, imiciafos, osamifoth, osamifos Organic phosphorus acetylcholinesterase (AChE) inhibitors; GABAergic chloride ion blockers such as chlordane, endosulfan, lindane, dienochlor, etiprole, fipronil, and acetoprole; Acrinathrin, Allethrin [(1R) -isomer] (Allethrin [(1R) -isomer]), Bifenthrin, Bioallethrin, Bioarethrin
  • Phenothrin [(1R) -trans-isomer] (cyphenothrin [(1R) -trans-isomer]), deltamethrin (deltamethrin), empentrin [(EZ)-(1R) -isomer] (empentrin [(EZ)-(1R) -Isomer]), esfenvalerate, etofenprox (ethofenprox) rox), fenpropatrin, fenvalerate, flucitrate, flumethrinate, flumethrin, tau-fluvalinate, halfenproxin, iproprothrin Methotrin, methfluthrin, epsilon-methfluthrin, monfluorothrin, epsilon-monfluthrin, persil-methrintrin, persilin [(1R) -trans-isomer] (phenothrin [(1R)
  • sodium channel modulators such as phenothrin, fluvalinate; Acetamiprid, clothianidin, dinotefuran, imidacloprid, itenocropride, ti, thimethoxam, thimethoxam ), Nicotinic acetylcholine receptor (nAChR) competitive modulators such as flupiradifurone, triflumezopyrim; Nicotinic acetylcholine receptor (nAChR) allosteric modulators such as spinosad, spinetoram; Glutamatergic chloride channel (GluCl) allosteric modulators such as abamectin, emamectin benzoate, lepimectin, milbemectin; Juvenile hormone analogs such as hydroprene, kinoprene, methoprene, phenoxycarb, pyriproxyfen, etc .; Methyl bromide, chloropicrin, cryolite
  • Afoxolaner fluazaindolizine, aphidopyropene, cyhalodiamide, thioxafenel, fluhexaflurane Roll (tetrachloranlaniprole), saloraner (sarolaner), rotilaner (rotilaner), cycloxapride, fluenesulfone (fluensulfone), TPIC (tripropropyl isocyanurate), D-D (1,3-Dichloropropene), peroxocarbonate, MB-599 (verbutin), bis (2,3,3,3-tetrachloropropyl) ether (bis (2,3,3,3-tetrachloropropyl)) ether), DCIP (bis (2-chloro-1-methylethyl) ether), ENT-8184 (N- (2-Ethylhexyl) bicyclohept-5-ene-2,3-dicarboximide), Bayer 224
  • the following shows formulation examples, test examples, and application examples of a phytotoxicity-reducing agent comprising the bactericidal compound of the present invention as an active ingredient, and a phytotoxicity-reduced herbicidal composition comprising the phytotoxicity-reducing agent and a herbicidal compound,
  • a phytotoxicity-reducing agent comprising the bactericidal compound of the present invention as an active ingredient
  • a phytotoxicity-reduced herbicidal composition comprising the phytotoxicity-reducing agent and a herbicidal compound
  • Chlorothalonyl sulcotrione wettable powder Chlorotalonyl: 30 parts, Sulcotrione: 10 parts, Neogen Powder (registered trademark): 0.5 part, Carplex (registered trademark): 0.5 part, Gohsenol (registered trademark): 0.2 part, Radiolite ( (Registered trademark): 0.8 parts, H fine powder: remainder, 100 parts in total were ground and mixed to obtain a wettable powder.
  • ⁇ Formulation example 7 (benomyl tenyl chlor wettable powder)> Benomyl: 20 parts, Tenilchlor: 5 parts: 50 parts, Neogen Powder (registered trademark): 0.5 part, Carplex (registered trademark): 0.5 part, Gohsenol (registered trademark): 0.2 part, Radio Light (registered trademark): 0.8 part, H fine powder: remaining part, 100 parts in total were pulverized and mixed to obtain a wettable powder.
  • ⁇ Formulation Example 14 (Kasugamycin / Pyrazolate Granules)> Kasugamycin: 0.1 parts, pyrazolate: 20 parts, polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, clay 53.7 parts, talc 21.7 parts, after uniformly grinding and mixing Then, water was added and kneaded and granulated and dried to obtain granules.
  • Chlorothalonyl sulcotrione granules Chlorotalonyl: 4 parts, Sulcotrione: 1 part, Polyoxyethylene / polyoxypropylene condensate 1.5 parts, CMC sodium 3 parts, clay 65.8 parts, talc 33.7 parts Water was added and kneaded and granulated and dried to obtain granules.
  • ⁇ Formulation example 16 (benomyl tenyl chlor granules)> Benomyl: 5 parts, Tenylchlor: 1 part, 1.5 parts of polyoxyethylene / polyoxypropylene condensate, 3 parts of CMC sodium, 68.8 parts of clay, 29.7 parts of talc And kneaded, granulated and dried to obtain granules.
  • Reagent (B1) Hydroxyisoxazole solution (trade name / Tatigalen (registered trademark) solution, active ingredient hydroxyisoxazole, 30% by weight, manufactured by Mitsui Chemicals Agro Co., Ltd.) (B2) Picalbutrazox wettable powder obtained in Formulation Example 1 (B3) Amisulbrom granule wettable powder (trade name / Oracle (registered trademark) granule wettable powder, active ingredient amisulbrom, 50% by weight, Nissan Chemical Industries (Made by Co., Ltd.) (B4) Ciazofamide wettable powder (trade name / Ranman (registered trademark) flowable, active ingredient cyazofamide, 9.4% by weight, manufactured by Ishihara Bioscience Co., Ltd.) (B5) Kasugamycin solution (trade name / Kasmin (registered trademark) solution, active ingredient kasugamycin, 2% by weight, manufactured by Hokuko Chemical Co., Ltd.) (B6) Chlorothalonil
  • the seedlings (about 2.1 leaf stage) grown in a greenhouse at 26 ° C. for 17 days were again irrigated with the chemical solutions (B1) to (B8) diluted to a predetermined concentration or 50 g / (B9). After the treatment in the nursery box, the drug-treated and transplanted seedlings were obtained.
  • the transplanted seedlings that were not treated with drugs and transplanted were transplanted at 10 cm depth, with two at one transplantation depth of 1.5 cm. .
  • the pyrimylsulfur 0.66% granule (trade name / Best Partner (registered trademark) granule, manufactured by Kumiai Chemical Industry Co., Ltd.) was treated in an amount equivalent to 20 kg / ha. did.
  • a complete weeding area where only weeds were removed was set up. After 21 days of drug treatment, a sampling survey of the plant body was conducted.
  • ⁇ Test Example 2> Dilute the hydroxyisoxazole solution (B1), picalbutrazox wettable powder (B2), and amisulbrom granule wettable powder (B3) to concentrations of 600 ppm, 100 ppm and 250 ppm, respectively (500 times, 1000 times and 2000 times) Times), after irrigating the soil (500 ml / nursery box equivalent), a prototype (rice cultivar: Koshihikari) was sown. The seedlings grown in a greenhouse at 26 ° C. for 17 days (about 2.1 leaf stage) are once again diluted with the chemical solutions (B1) to (B3) diluted to a predetermined concentration, and then treated with chemicals and transplanted seedlings. It was.
  • transplanted seedlings that were not treated with drugs and transplanted were transplanted at 10 cm depth, with two at one transplantation depth of 1.5 cm. . 4 days after transplantation, with a water depth of 2 cm, oxadichromephone 0.8%, tefriltrione 3% granule (trade name / A1 (registered trademark) granule, manufactured by Hokuko Chemical Co., Ltd.) equivalent to 20 kg / ha Amount processed. Moreover, 20 kg / ha equivalent amount of the pyrimyl fan 0.67% granule was processed into another container.
  • a complete weeding area where only weeds were removed was set up. Twenty-six days after the drug treatment, a sampling survey of the plant body was conducted. In addition, dry weight cut into the above-ground part and a root part, and measured the weight dried at 100 degreeC for 1 hour and 80 degreeC for 2 days.
  • the safeners can be universally used for various cultivated crops, and the safeners containing the safeners and herbicidal compounds are reduced.
  • a herbicidal composition can be obtained.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)
  • Catching Or Destruction (AREA)

Abstract

Le phytoprotecteur de l'invention comprend en tant que principe actif au moins une sorte de composé choisie dans un groupe constitué d'un hydroxyisoxazole, un picarbutrazox, un cyazofamid, une kasugamycine, un chlorthalonil, un bénomyl, un thiophanate-méthyl, un isoprothiolane et un amisulbrom, ou un sel de ce composé.
PCT/JP2019/006793 2018-02-23 2019-02-22 Phytoprotecteur ayant un composé biocide pour principe actif, et composition herbicide de phytotoxicité réduite contenant ce phytoprotecteur et un composé herbicide Ceased WO2019163946A1 (fr)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2022158382A1 (fr) * 2021-01-19 2022-07-28
WO2023171593A1 (fr) 2022-03-07 2023-09-14 日本曹達株式会社 Procédé de réduction ou de prévention de l'effet de stress salin sur une plante

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005289845A (ja) * 2004-03-31 2005-10-20 Nisso Green:Kk 芝生に発生する藻類の防除方法
JP2010006746A (ja) * 2008-06-27 2010-01-14 Mitsui Chemicals Agro Inc 植物病害防除組成物及びそれを施用する植物病害の防除方法
DE102011080004A1 (de) * 2011-07-28 2012-09-13 Bayer Cropscience Ag Verwendung von Saatgutbehandlungs-Wirkstoffen aus der Gruppe der Carbamat-Fungizide als Safener
DE102011080007A1 (de) * 2011-07-28 2012-09-13 Bayer Cropscience Ag Verwendung von Saatgutbehandlungs-Wirkstoffen aus den Gruppen der Conazole- und Triazol-Fungizide als Safener
WO2013047441A1 (fr) * 2011-09-26 2013-04-04 日本曹達株式会社 Composition bactéricide pour l'agriculture et l'horticulture

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2613136B2 (ja) * 1991-05-14 1997-05-21 株式会社コスモ総合研究所 植物成長促進剤
JP5052052B2 (ja) 2006-06-20 2012-10-17 バイエル・クロップサイエンス・アーゲー 薬害軽減された除草剤組成物
JP5213320B2 (ja) 2006-09-13 2013-06-19 バイエル・クロップサイエンス・アーゲー 薬害軽減された除草剤組成物
WO2014189126A1 (fr) 2013-05-24 2014-11-27 三井化学アグロ株式会社 Graines de riz paddy traitées avec une composition herbicide et procédé de lutte contre les mauvaises herbes
WO2017183664A1 (fr) * 2016-04-20 2017-10-26 三井化学アグロ株式会社 Composition agricole/horticole

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005289845A (ja) * 2004-03-31 2005-10-20 Nisso Green:Kk 芝生に発生する藻類の防除方法
JP2010006746A (ja) * 2008-06-27 2010-01-14 Mitsui Chemicals Agro Inc 植物病害防除組成物及びそれを施用する植物病害の防除方法
DE102011080004A1 (de) * 2011-07-28 2012-09-13 Bayer Cropscience Ag Verwendung von Saatgutbehandlungs-Wirkstoffen aus der Gruppe der Carbamat-Fungizide als Safener
DE102011080007A1 (de) * 2011-07-28 2012-09-13 Bayer Cropscience Ag Verwendung von Saatgutbehandlungs-Wirkstoffen aus den Gruppen der Conazole- und Triazol-Fungizide als Safener
WO2013047441A1 (fr) * 2011-09-26 2013-04-04 日本曹達株式会社 Composition bactéricide pour l'agriculture et l'horticulture

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2022158382A1 (fr) * 2021-01-19 2022-07-28
WO2022158382A1 (fr) * 2021-01-19 2022-07-28 日本曹達株式会社 Mélange
JP7516572B2 (ja) 2021-01-19 2024-07-16 日本曹達株式会社 混合剤
WO2023171593A1 (fr) 2022-03-07 2023-09-14 日本曹達株式会社 Procédé de réduction ou de prévention de l'effet de stress salin sur une plante

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JP2020015762A (ja) 2020-01-30

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