WO2019022210A1 - 光学構造体および認証体 - Google Patents
光学構造体および認証体 Download PDFInfo
- Publication number
- WO2019022210A1 WO2019022210A1 PCT/JP2018/028161 JP2018028161W WO2019022210A1 WO 2019022210 A1 WO2019022210 A1 WO 2019022210A1 JP 2018028161 W JP2018028161 W JP 2018028161W WO 2019022210 A1 WO2019022210 A1 WO 2019022210A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- quantization
- optical structure
- quantized
- layer
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Images
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/26—Processes or apparatus specially adapted to produce multiple sub- holograms or to obtain images from them, e.g. multicolour technique
- G03H1/30—Processes or apparatus specially adapted to produce multiple sub- holograms or to obtain images from them, e.g. multicolour technique discrete holograms only
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/328—Diffraction gratings; Holograms
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1842—Gratings for image generation
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/18—Diffraction gratings
- G02B5/1861—Reflection gratings characterised by their structure, e.g. step profile, contours of substrate or grooves, pitch variations, materials
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/32—Holograms used as optical elements
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/0005—Adaptation of holography to specific applications
- G03H1/0011—Adaptation of holography to specific applications for security or authentication
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
- G03H1/024—Hologram nature or properties
- G03H1/0244—Surface relief holograms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/373—Metallic materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B42—BOOKBINDING; ALBUMS; FILES; SPECIAL PRINTED MATTER
- B42D—BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- B42D25/00—Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof
- B42D25/30—Identification or security features, e.g. for preventing forgery
- B42D25/36—Identification or security features, e.g. for preventing forgery comprising special materials
- B42D25/378—Special inks
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2210/00—Object characteristics
- G03H2210/40—Synthetic representation, i.e. digital or optical object decomposition
- G03H2210/45—Representation of the decomposed object
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2250/00—Laminate comprising a hologram layer
- G03H2250/36—Conform enhancement layer
Definitions
- the embodiment of the present invention relates to a security or card medium, or an optical structure applied as a forgery prevention means such as a passport or a visa for enhancing security, and an authentication body including the optical structure.
- Computer generated holograms can be embossed for replication, in which case development is not necessary and is a commercially superior technology.
- Patent Document 1 Japanese Patent Laid-Open No. 2011-118034 discloses a method of making a virtual three-dimensional object appear three-dimensional by using anisotropic scattering of light.
- Patent Document 1 when light is incident on a slope that looks like a stereoscopic view, light and dark of the light are switched for each slope, but the three-dimensional effect is lost.
- the three-dimensional reproduced image is blurred.
- holograms that look rainbow-colored can be easily manufactured in recent years, and can not be said to have sufficient forgery-preventing capabilities anymore, and the need for an alternative to rainbow-colored becomes a market trend There is.
- computer holograms formed from common kinoforms are for example for security protection such as securities such as gift certificates, card media such as credit cards, brand products such as passports and visas, and machine parts etc. It can not be applied to
- the hologram is accompanied by a peculiar blur.
- computer holograms formed from common kinoforms are, for example, marketable securities such as gift certificates, card media such as credit cards, brand products such as passports and visas, and machine parts etc.
- ink is also used for these authenticity determinations because it can not be applied for anti-counterfeiting.
- This type of ink is required to have high durability so that it can be used without fading over time.
- it is preferable that the color shift effect in a specific direction is not provided so that the color does not change in any direction.
- Patent document 2 (patent 4916636 specification) is disclosed as a prior art regarding the durability improvement of ink.
- Patent Document 2 discloses a pigment which is provided with two reflective layers to reduce the color shift effect by the interference color.
- the reflective layer is pigmented and printed and used, the inclination angle of the pigment at the time of printing is random, and depending on the direction in which the pigment is fixed, colors appearing in a specific direction may be mixed. This makes it difficult to produce highly saturated colors.
- the hologram by the diffraction grating has an advantage that a high-brightness image can be obtained and the eye-catching effect is high, but there is a disadvantage that the color changes largely at the angle of the label and the stable coloring is not obtained.
- the embodiment of the present invention has been made in view of such circumstances, and solves the color instability and the decrease in luminance, which are the disadvantages in the prior art such as diffraction and interference, by applying the kinoform technology. It is possible that one of the purposes is to display graphic information such as pictures or text information as a means for preventing forgery to enhance security for securities, card media, passports, visas, etc.
- An optical structure capable of three-dimensional expression independent of a light source, improving the iridescent appearance, and further providing an appearance that flashes like a jewel depending on the viewing angle, and the optical structure Authentication body can be provided.
- the second object of the present invention is applied to securities and card media, or ink suitable to be applied to printed materials such as passports and visas, and has high durability and high brightness expression. To provide an optical structure having no color shift effect.
- the optical structure for solving the first object is an optical structure having a quantized retardation structure on one surface of the quantized retardation structure layer, and the quantized retardation structure has a constant size.
- the groove-like recesses aligned in parallel with each other have adjacent and alternately arranged quantized retardation structures in the multiple diffraction region, and the multiple diffraction regions are regularly arranged in a plurality of discrete directions in one direction. It is characterized in that it is a quantized phase difference structure that reproduces a reproduction point.
- the surface roughness of the bottom of the quantization recess of the quantization retardation structure is different from the surface roughness of the top of the quantization recess of the quantization retardation structure.
- a plurality of multiple diffraction regions are regularly arranged in the quantized retardation structure.
- the direction of the spatial frequency component is determined by the direction in which the inclined surface of the convex structure in the multiple diffraction region faces.
- the shortest distance R from the plurality of reproduction points reproduced from the spatial frequency component to the plane on which the reproduction points are arranged is the length D of the entire multiple diffraction area and the light in the multiple diffraction area
- the relationship of R> D 2 / ⁇ is satisfied using the wavelength ⁇ of
- the light intensity of the reproduction point where the incident light is present in the direction of regular reflection on the inclined surface of the polygon is the strongest, and the direction of regular reflection among the plurality of reproduction points
- the light intensity distributions of the plurality of reproduction points are determined such that the light intensity becomes weaker as the reproduction point deviates from the other.
- a plurality of reproduction points are arranged at non-uniform intervals in space.
- the multiple diffraction region is a cell type.
- the depth of the quantized retardation structure is different for each multiple diffraction region.
- a reflective layer is provided on the surface of the convex structure.
- the optical structure has a quantization phase difference structure on one surface of the quantization phase difference structure layer, and the quantization phase difference structure is a convex having a constant size as one element structure.
- the rib-like convex part in which the convex part is aligned in one direction, and the groove-like concave part in which the quantization concave which is a concave having a constant size as the other element structure is aligned parallel to the rib-like convex part are adjacent and alternate
- the depth from the top surface of the rib-like convex portion to the bottom surface of the groove-like concave portion is constant, and is quantized to the element structure of the quantization convex portion and the quantization concave portion.
- the surface roughness of the bottom surface is rougher than the surface roughness of the top surface, and the diffracted light of the quantized retardation structure may be configured to reproduce a plurality of reproduction points separated in one direction.
- An optical structure for solving the second object is an optical structure in which a release layer, an embossed layer, and a reflective layer are sequentially laminated on a film, and the embossed layer has a quantized retardation structure.
- the distance from the top surface of the quantization convex portion of the quantization retardation structure to the bottom surface of the quantization concave portion is constant in the multiple diffraction region.
- a plurality of peak intensities of spatial frequency of the quantized phase difference structure are disposed apart from each other along one direction or a plurality of directions.
- the surface roughness of at least one of the top surface of the quantization convex portion and the bottom surface of the quantization recess is not more than one tenth of this distance.
- the direction of unevenness of the quantized retardation structure is perpendicular to the extending direction of the rib-like recess and the groove-like recess formed by the top face of the quantization protrusion and the bottom of the recess. .
- the optical structure further includes a protective layer for protecting the reflective layer.
- the optical structure is dispersed in a resin and applied as a printable ink. Furthermore, in the above optical structure, the reflective layer has magnetism.
- the reflection spectrum of the structural color possessed by the embossed layer and the reflective layer has a peak at least at a wavelength of 800 nm or more and 1000 nm or less, and the optical structure further reflects visible light and infrared light
- An optical layer that transmits light is laminated.
- a salt adsorbent is further contained in at least one of the embossed layer and the protective layer.
- the number of spatial frequency peaks of the quantized phase difference structure is 5 or more and 200 or less.
- the present optical structure when displaying graphic information such as a design or character information as a forgery preventing means for enhancing security for securities, card media, passports, visas, etc. Unlike in the light source independent three-dimensional expression is possible, the iridescent appearance unique to conventional holograms is improved, and an optical structure that produces an effect that flashes like a jewel depending on the viewing angle. And the authentication body provided with this optical structure can be realized.
- calculation is based on the assumption that light enters from a direction opposite to 180 ° with respect to the normal direction of the carrier, and light is designed to spread around the regular reflection direction. Even when the light enters obliquely, the light is reflected in substantially the same direction as the light reflection direction when there is an actual slope, so it is the same as when there is a virtual three-dimensional object at that place. Since the light and dark of light are observed, it looks as if there is a three-dimensional object there.
- the present optical structure it is possible to define the reflection direction of light when light is incident perpendicularly to the plane by the quantization phase difference structure, and further, by having a plurality of spatial frequency components, reflection of light is achieved.
- the direction can be multiple.
- This effect achieves an effect equivalent to the fact that the specular reflection component is strongly reflected when light strikes an object and reflected light intensity decreases as the angle deviates from the specular reflection direction.
- the spatial frequency component discrete, bright and dark bright spots can be generated, and it becomes possible to generate a glittering effect such as a gem.
- the quantized phase difference structure can be configured by a plurality of multiple diffraction regions.
- the direction of the spatial frequency component can be determined by the direction in which the slope of spatial frequency multiplexing is directed.
- the present optical structure by making the diffraction area of light diffracted from the multiple diffraction area into the Fraunhofer area, light is reflected in the direction of the reproduction point without directly viewing the reproduction point. Effects can be obtained.
- the present optical structure it is possible to realize an effect that light strikes the actual surface by further increasing the light intensity in the regular reflection direction and further weakening the light intensity shifted from the regular reflection. It becomes.
- the present optical structure it is possible to reflect the reproduced image white in the direction in which the reproduction point is dense, and conversely, in the portion where the reproduction point is coarse, the reproduction image of the rainbow color like a conventional hologram. It is possible to control both white and iridescent colors.
- the multiple diffraction region can be made into a cell type.
- the present optical structure it is possible to control the reflection color of light at the time of reflection by the depth of the quantization phase difference structure, and thereby it is possible to express a three-dimensional image in full color.
- optical structure provided with the present reflection layer it is possible to further increase the light reflectance.
- the length from the top surface portion of the quantization convex portion of the quantization phase difference structure to the bottom surface portion of the quantization recess is constant regardless of the position in the embossed layer surface.
- the color shift effect is small and the color becomes uniform from any direction. It is possible to realize such effects.
- the surface roughness of at least one of the top surface of the quantization protrusion and the bottom surface of the quantization recess is one tenth or less of the length from the top surface of the quantization protrusion to the bottom surface of the quantization recess Because of the roughening, by providing the quantization phase difference structure to an extent that does not depend on the wavelength of light, it is possible to slightly randomize the light reflection direction without changing the color.
- the distance from the top surface of the quantization protrusion to the bottom surface of the quantization recess is equal to the design value If it slightly changes due to tolerance, the color as a structural color changes sensitively, but as in this optical structure, surface roughness is applied to either the top of the quantization convex or the bottom of the quantization concave. By having this, even if the length from the top surface of the quantization convex portion to the bottom surface of the quantization recess slightly changes, the color as the structural color does not change so much, and therefore, it is possible to alleviate the manufacturing tolerance to some extent. .
- the asperity direction of the quantized retardation structure having surface roughness is the rib-like recess and the groove-like recess formed by the top surface of the quantization protrusion and the bottom surface of the quantization recess. Being perpendicular to the direction of extension, light associated with structural colors can be scattered in the vertical direction. This makes it possible to scatter the light in a direction that does not change the color of the structural color and to make the structure strong against manufacturing tolerances.
- the present optical structure can protect the surface of the reflective layer by providing a protective layer that protects the reflective layer.
- a protective layer that protects the reflective layer.
- the material of the protective layer the same in refractive index as the material of the embossed layer, it is also possible to make the structural color on the front and back the same.
- the present optical structure can be manufactured by a method in which the resin is cured after being oriented by a magnetic field in a specific direction because the reflective layer has magnetism, and thus the optical structure It also becomes possible to control the direction of the body and to impart an optical effect thereby.
- the reflection spectrum of the structural color of the embossed layer and the reflective layer has a peak at least at a wavelength of 800 nm or more and 1000 nm or less, so it looks different from visible light and looks different from ordinary black printed matter.
- a salt adsorbent in at least one of the embossing layer and the protective layer, it is possible to prevent the deterioration of the reflective layer due to the salt in the air.
- the present optical structure is an optical structure having a quantized retardation structure on one surface of the quantized retardation structure layer.
- the quantization phase difference structure is a quantum structure in which a rib-like convex portion in which a quantization convex portion which is a convex portion having a constant size as one element structure is aligned in one direction and a concave portion having a constant size as another element structure.
- the grooved recesses in which the forming recesses are aligned in parallel with the rib-like protrusions are adjacently and alternately arranged, and the depth from the upper surface of the rib-like protrusions to the bottom of the groove-like recess is constant; It is quantized to the element structure of a convex part and a quantization recessed part.
- the surface roughness of the bottom of the quantized retardation structure is rougher than the surface roughness of the upper surface, and the diffracted light of the quantized retardation structure reproduces a plurality of reproduction points separated in one
- FIG. 1A is a plan view showing multiple diffraction areas provided in an optical structure according to one embodiment of the present invention.
- FIG. 1B is a diagram showing peak intensities of spatial frequency components in the multiple diffraction region shown in FIG. 1A.
- FIG. 2 is a plan view showing an example of an optical structure provided with a plurality of multiple diffraction regions.
- FIG. 3 is a cross-sectional view showing a quantization phase difference structure.
- FIG. 4A is a front view showing a sphere which is an example of a virtual three-dimensional shape.
- FIG. 4B is a plan view of an optical structure for artificially expressing the sphere in FIG. 4A.
- FIG. 4C is a cross-sectional view showing the positional relationship between the optical structure in FIG.
- FIG. 5 is a cross-sectional view showing part of a virtual 3D shaped polygon for a sphere.
- FIG. 6A is a diagram illustrating an embodiment of a spatial frequency distribution.
- FIG. 6B is a diagram illustrating an embodiment of a spatial frequency distribution.
- FIG. 6C illustrates an embodiment of a spatial frequency distribution.
- FIG. 6D illustrates an embodiment of a spatial frequency distribution.
- FIG. 7 is a cross-sectional view showing a state in which the optical structure is attached to the medium.
- FIG. 8 is a cross-sectional view showing another mode in which the optical structure is attached to the medium.
- FIG. 9A is a cross-sectional view schematically showing a configuration example of an optical structure which is a material of an optical structure according to another embodiment of the present invention.
- FIG. 9B is a cross-sectional view schematically showing another configuration example of an optical structure which is a material of an optical structure according to another embodiment of the present invention.
- FIG. 10 is a cross-sectional view schematically showing a configuration example of the embossed layer constituting the optical structure.
- FIG. 11A is a plan view showing an embodiment of the multiple diffraction area formed by the embossed layer.
- FIG. 11B is a diagram showing an example of spatial frequency components in the multiple diffraction region shown in FIG. 11A.
- FIG. 11C is a diagram showing an example of peak intensities in the multiple diffraction region shown in FIG. 11A.
- FIG. 12A is a plan view showing an example of an embodiment of spatial frequency components different from FIG. 11B.
- FIG. 12B is a plan view showing another example of the spatial frequency component embodiment different from that of FIG. 11B.
- FIG. 12C is a plan view showing still another example of the spatial frequency component embodiment different from that of FIG. 11B.
- FIG. 13 is a photomicrograph obtained by observing a part of the surface of the quantized retardation structure of the embossed layer by a scanning electron microscope.
- FIG. 14 is a diagram to which an explanatory note for explaining the microphotograph shown in FIG. 13 is added.
- FIG. 15 is a photograph of an image obtained by an optical structure according to an embodiment of the present invention.
- FIG. 1A is a plan view showing an embodiment of a multiple diffraction region 12 in a quantized phase difference structure provided in an optical structure 10 according to one embodiment of the present invention
- FIG. 1B is a multiple diffraction region.
- FIG. 13 is a diagram showing an example of peak intensities of spatial frequency components F1 to F5 at five reproduction points at Twelve.
- the optical structure 10 has an embossed surface on one side or both sides of the embossed layer.
- the embossed surface has multiple diffraction areas on a part or the whole surface thereof.
- a quantized phase difference structure is formed in the multiple diffraction region.
- the quantization phase difference structure a plurality of quantization projections having a constant size and a plurality of quantization recesses having a constant size are aligned.
- the bright part is a quantization convex part
- the dark part is a quantization concave part.
- the quantization convex portion and the quantization concave portion are arranged at regular intervals.
- the quantization convex portions are arranged adjacent to the quantization convex portions at regular intervals.
- quantization recesses or quantization recesses are arranged.
- the quantization convex portions and the quantization concave portions of the quantization phase difference structure are alternately arranged one by one or plural ones are alternately arranged.
- the multiple diffraction region 12 can be a cell including a quantization phase difference structure.
- a rib-like convex part in which the quantization convex part is aligned in one direction and a quantization concave part which is a concave part having a constant size as an element structure are parallel to the rib-like convex part
- the size of the quantization convex portion in which the groove-like concave portions aligned in a row and adjacent to each other are alternately arranged can be equal to or less than half of the central wavelength of the visible wavelength, or 1/20 or more.
- the size of the quantization recess can be equal to or less than half of the center wavelength of the visible wavelength, or more than 1/20.
- the size of the quantization convex portion can be 250 nm or less and 25 nm or more.
- the size of the quantization recess can be 250 nm or less and 25 nm or more.
- the quantization projections can be square.
- the quantization recess can be square.
- the corners of the quantization projections can be rounded.
- the corners of the quantization recess can be rounded.
- the quantization convex portion and the quantization concave portion may be aligned with virtual grids.
- the height of the quantization convex portion can be the same as or an integral multiple of the reference height.
- the depth of the quantization recess can be the same as the reference depth or an integral multiple thereof.
- the reference height and the reference depth can be the same.
- the value of the integer multiple at this time can be 1 to 4. Also, it may be 1 to 8.
- the reference depth and reference height can be 10 nm or more and 500 nm or less.
- the reproduced image of the hologram reproduced by the multiple diffraction area 12 is a reproduction point group of five points, spatial frequency along a predetermined one direction D in the plane of the multiple diffraction area 12 as shown in FIG. 1A.
- FIG. 1B When the components are calculated, as shown in FIG. 1B, there are five discrete peaks at spatial frequency components F1 to F5 corresponding to the reproduction points.
- the horizontal axis in FIG. 1B is the spatial frequency [1 / mm], and the vertical axis is the intensity of the spatial frequency component.
- the reproduced image is iridescent, and when dense, it is white.
- the density of the distribution of spatial frequency components it is possible to make the reproduced image iridescent in a certain angular direction and white at other angles.
- FIG. 2 is a plan view showing an example of an optical structure 10 a provided with a plurality of multiple diffraction regions 12.
- the number of multiple diffraction regions 12 provided in the optical structure 10 is not limited to one as shown in FIG. 1A, but may be plural as shown in FIG.
- region 12 shown by FIG. 1A and FIG. 2 is a rectangular shape, shapes other than a rectangle may be sufficient.
- FIG. 3 is a cross-sectional view showing the quantization phase difference structure 14.
- a reflective layer (not shown) may be provided on the surface of the quantized phase difference structure 14 whose cross section is shown in FIG.
- the reflective layer can be translucent or concealable.
- the reflective layer can be a reflective layer made of a metal material.
- the metal material can be Al, Ag, Sn, Cr, Ni, Cu, Au, and alloys thereof.
- the metal reflection layer can be a concealing reflection layer.
- a dielectric layer having a refractive index different from that of the relief structure forming layer may be used.
- a laminate of dielectric layers different in refractive index between adjacent ones, that is, a dielectric multilayer film may be used. Among the dielectric layers included in the dielectric multilayer film, it is desirable that the refractive index of one in contact with the relief structure forming layer be different from the refractive index of the relief structure forming layer.
- the dielectric layer can be a metal compound or silicon oxide.
- the metal compound can be a metal oxide, a metal sulfide, a metal fluoride or the like.
- the material of the dielectric layer can be TiO 2 , ZnO, Si 2 O 3 , SiO, Fe 2 O 3 , ZnS, CaF, MgF.
- the reflective layer can be formed by vapor deposition. As a vapor deposition method, a vacuum evaporation method, a sputtering method, etc. can be applied.
- the reflective layer of the dielectric layer can be made translucent.
- the reflective layer can be 10 nm or more and 1000 nm or less.
- the reflective layer can be formed using an ink.
- This ink can be an offset ink, a letterpress ink, a gravure ink, etc., depending on the printing method.
- resin ink, oil-based ink and water-based ink may be used.
- an oxidation polymerization ink, a permeation drying ink, an evaporation drying ink, and an ultraviolet curing ink may be used.
- the inclination angle of the polygon is determined, and the inclined surface 15 of the inclination angle (see FIG. 5 described later).
- the corresponding quantized phase difference structure 14 is calculated.
- FIG. 4A is a front view showing a sphere 16 which is an embodiment of a pseudo polygon appearing by the diffracted light of the quantized retardation structure 14.
- FIG. 4B is a plan view showing an optical structure 10b in which a plurality of multiple diffraction regions 12 having a plurality of spatial frequency components different in direction are arranged to artificially express the sphere 16 as shown in FIG. 4A.
- FIG. 4C is a cross-sectional view showing the positional relationship between the optical structure 10 and the sphere 16.
- FIG. 5 is a cross-sectional view showing part of a virtual 3D shaped polygon for the sphere 16. It is formed by an inclined surface 15 having an inclination angle ⁇ 1 with respect to the reference surface 18 of the multiple diffraction region 12.
- the positional relationship between the inclined surface 15 and the reproduction point 20 is also shown in FIG. As shown in FIG. 5, in the embodiment of the present invention, by arranging the reproduction point 20 in the regular reflection direction of the inclined surface 15, a visual effect as if the virtual inclined surface 15 exists when light is incident. To be able to get
- the incident light vector perpendicular to the reference surface 18 is
- the shortest distance R from the reproduction points 20 (# 1) to (# 5) to the reference surface 18 is R, using the length D of the entire multiple diffraction region 12 and the wavelength ⁇ of light in the multiple diffraction region 12 Satisfy the relationship of> D 2 / ⁇ .
- the light intensity of the reproduction point 20 (# 3) existing in the direction in which incident light is specularly reflected on the inclined surface 15 of the polygon is the strongest and specularly reflected.
- reproduction point 20 (# 3) ⁇ reproduction point 20 (# 2) ⁇ reproduction point 20 (# 1), and reproduction point 20 (# 3) ⁇ reproduction point 20 (# 4) The light intensity distributions of the plurality of reproduction points 20 (# 1) to (# 5) are determined so that the light intensity becomes weaker in the order of the reproduction points 20 (# 5).
- FIG. 5 shows an embodiment in which a plurality of reproduction points 20 (# 1) to (# 5) are arranged at equal intervals in space, but a plurality of reproduction points 20 (# 1) to (# 5) may be arranged at non-uniform intervals.
- the horizontal axis indicates the alignment direction of the reproduction points 20, and the vertical axis indicates the intensity of the reproduction points 20. In the horizontal axis
- FIG. 6A shows an embodiment in which six reproduction points 20 of equal intensity are arranged at equal intervals around the regular reflection direction, although the reproduction points 20 are not arranged in the regular reflection direction.
- FIG. 6B shows an embodiment in which eleven reproduction points 20 of equal intensity are coarsely arranged near the specular reflection direction and closely spaced at a distance from the specular reflection direction.
- FIG. 6C shows that although the reproduction points 20 are not arranged in the regular reflection direction, the reproduction points 20 are equally spaced so that the intensity is high near the regular reflection direction and decreases as the distance from the regular reflection direction increases.
- positioned is shown. In FIG.
- the reproduction point 20 is not disposed in the vicinity of the regular reflection direction, the intensity gradually increases as it goes further away from the regular reflection direction, and the intensity increases as it goes further from the regular reflection direction.
- the reproduction image is a gem, and each polygon is a viewpoint, as shown in FIG.
- the light source has a gloss that changes intricately.
- the intricately changing gloss can have a sparkling appearance.
- FIG. 7 is a cross-sectional view showing an embodiment in which the optical structure 10c is attached to the adherend 22 in order to apply it to the authentication body.
- the optical structure 10c includes the quantized retardation structure 14 on the carrier 24, and forms the reflective layer 26 made of a metal thin film on the surface of the quantized retardation structure 14; Furthermore, an adhesive layer 28 is provided on the surface, and is adhered to the adherend 22 by the adhesive layer 28.
- the carrier 24 is transparent in order to reduce the loss of reflected light.
- the material of the carrier 24 may be a rigid body such as glass or a film.
- the film can be a plastic film.
- the plastic film can be a PET (polyethylene terephthalate) film, a PEN (polyethylene naphthalate film), a PP (polypropylene) film or the like.
- PET polyethylene terephthalate
- PEN polyethylene naphthalate film
- PP polypropylene film
- paper, synthetic paper, plastic multilayer paper, resin-impregnated paper, etc. may be used as the carrier.
- the material for forming the quantized retardation structure 14 is a thermoplastic resin such as urethane resin, polycarbonate resin, polystyrene resin, polyvinyl chloride resin, unsaturated polyester resin, melamine resin, epoxy resin, urethane (meth) acrylate, polyester ( Thermosetting resins such as meta) acrylates, epoxy (meth) acrylates, polyol (meth) acrylates, melamine (meth) acrylates, triazine (meth) acrylates, etc., or a mixture of these, as well as heat having a radically polymerizable unsaturated group It is possible to use a formable material or the like.
- FIG. 8 is a cross-sectional view showing another embodiment in which the optical structure 10d is attached to the adherend 22 in order to apply the optical structure 10d to the authentication body.
- the optical structure 10d shown in FIG. 8 differs from the optical structure 10c shown in FIG. 7 in that a release layer 30 is provided between the carrier 24 and the quantized retardation structure 14 in order to separate the carrier 24. .
- the carrier 24 does not have to be transparent because the carrier 24 is peeled off by peeling in the peeling layer 30.
- the material for forming the peeling layer 30 can be a resin.
- the release layer 30 may contain a lubricant.
- the resin may contain a thermoplastic resin, a thermosetting resin, an ultraviolet curable resin, an electron beam curable resin, and the like.
- the resin can be acrylic resin, polyester resin, or polyamide resin.
- the lubricant may be polyethylene powder, paraffin wax, silicone, or wax such as carnauba wax. These can be applied as a release layer 30 on the carrier 24 layer.
- the application can be performed by a known application method.
- the coating can be performed by gravure coating, micro gravure coating, die coating, lip coating, or the like.
- the thickness of the peeling layer 30 can be in the range of 0.5 ⁇ m to 5 ⁇ m.
- the graphic information such as the design or the character information is rainbow color free, and the appearance has a gloss like jewel by a viewpoint and a light source. It can be. In this appearance, depending on the viewpoint and the light source, the brightness blinks and looks like glittering. This appearance can enhance security for quantized phased structures, card media, or passports, visas, and the like.
- Example (Comparative example)
- a plurality of spatial frequency components are considered, and accordingly, a plurality of reproduction points 20 are considered, but in the present comparative example, for comparison.
- a 250 ⁇ 250 multi-diffraction region 12 consisting of a quantization convex portion aligned with a grit of 240 ⁇ 240 and a quantization concave portion is disposed.
- the size of one side of the quantization convex portion and the quantization concave portion is a square of 100 nm.
- the drawing resolution is a drawing resolution by the electron beam drawing apparatus on the resist.
- Ni sputtering was performed to prepare a Ni plate after Ni electroforming. From this Ni plate, a PET film was embossed with a UV curable resin. Al was vapor-deposited 150 nm on the surface of the structure after embossing.
- ⁇ is equal to the inclination angle of the inclined surface 15, and in FIG.
- the optical structure 10 was produced similarly to the comparative example. That is, the quantization convex part arranged in grit of 240 ⁇ 240 and the multiple diffraction area 12 consisting of the quantization concave are arranged 250 vertical and 250 horizontal, and the size of one side of the quantization convex and the quantization concave is 100 nm.
- Ni sputter is applied, Ni electroformed Ni plate is made, Ni plate is made into Ni plate and UV curing resin is used to emboss the PET film, and Al is formed on the surface of the embossed structure.
- Al is formed on the surface of the embossed structure.
- the optical structure 10 was produced similarly to the comparative example. That is, a 250 ⁇ 250 multi-diffraction region 12 consisting of a quantization convex portion aligned in 240 ⁇ 240 grit and a quantization concave portion is disposed, and the size of one side of the quantization convex portion and the quantization concave portion is 100 nm.
- a 250 ⁇ 250 multi-diffraction region 12 consisting of a quantization convex portion aligned in 240 ⁇ 240 grit and a quantization concave portion is disposed, and the size of one side of the quantization convex portion and the quantization concave portion is 100 nm.
- the reproduced image was reproduced white.
- the brightness was also brighter as compared with the comparative example and the example 1. The reason is that the number of reproduction points N is increased and the scattered component is increased.
- a release layer, an embossed layer, and a reflective layer are sequentially laminated on a film.
- 9A and 9B are cross-sectional views schematically showing the configuration of an optical structure according to an embodiment of the present invention.
- the optical structure 40 is formed by sequentially laminating a release layer 44, an embossed layer 46, and a reflective layer 48 on a film 42.
- a protective layer 49 for protecting the reflective layer 48 may be further laminated on the non-embossed layer side of the reflective layer 48.
- the carrier 42 can be a rigid body such as glass or a film.
- the film can be plastic.
- the plastic film can be a PET (polyethylene terephthalate) film, a PEN (polyethylene naphthalate) film, a PP (polypropylene) film, or the like.
- PET polyethylene terephthalate
- PEN polyethylene naphthalate
- PP polypropylene
- the carrier can be a heat resistant material. The heat-resistant material is less deformed or deteriorated due to heat, pressure or the like applied when laminating the embossed layer 46.
- the formation material of the peeling layer 44 can be made of resin.
- the release layer 44 may contain a lubricant.
- the resin can be acrylic resin, polyester resin, or polyamide resin.
- the resin can be a thermoplastic resin, a thermosetting resin, an ultraviolet curable resin, an electron beam curable resin, or the like.
- the lubricant can be a wax such as polyethylene powder, paraffin wax, silicone, carnauba wax and the like.
- the release layer 44 can be formed by a known application method.
- the release layer 44 can be formed on the carrier 42 by a gravure printing method, a microgravure method, or the like.
- the thickness of the peeling layer 44 can be in the range of 0.5 ⁇ m to 5 ⁇ m.
- FIG. 10 is a cross-sectional view schematically showing the structure of the embossed layer 46 of the optical structure 40. As shown in FIG.
- the embossed layer 46 has a substantially flat shape, and has a quantized retardation structure 50 on one side.
- the length L from the upper surface 52 of the quantization convex portion of the quantization retardation structure 50 to the lower surface 54 of the quantization recess is constant regardless of the position on the surface of the embossed layer 46.
- the upper surface 52 of the quantization protrusion and the lower surface 54 of the quantization recess may be substantially parallel to the carrier 42.
- the color of the reflected light is modulated by the length L.
- the convex-concave direction of the quantized retardation structure 50 that is, the vertical direction in FIG.
- the embossed layer 46 has an embossed surface on one side or both sides.
- the embossed surface includes a phase angle recording area.
- a quantized phase difference structure is formed in the phase angle recording area.
- the quantization convex portion and the quantization concave portion are aligned.
- the quantization convex portion and the quantization concave portion have a width that is an integral multiple of the unit length and a width that is an integer multiple of the unit length.
- the unit length can be half or less, 1/20 or more of the central wavelength of the visible wavelength.
- the unit length can be 250 nm or less and 25 nm or more.
- the quantization convex portion is disposed in a portion where the phase angle to be recorded is 0 or more and less than ⁇ .
- a phase angle of 0 or more and less than ⁇ is quantized to ⁇ / 2.
- the quantized convex portion has a height corresponding to ⁇ / 2 which is quantized.
- quantization is performed at an interval of ⁇ / (2 ⁇ n).
- the quantization convex portion has the respective heights corresponding to the respective phases quantized.
- the quantization recess is disposed in a portion of ⁇ or more and less than 2 ⁇ .
- a phase angle of ⁇ or more and less than 2 ⁇ is quantized to 3 ⁇ / 2 when the depth of the quantization recess is constant.
- quantization is performed at an interval of ⁇ / (2 ⁇ n).
- the quantization recesses have respective depths corresponding to the respective phases quantized.
- the wavelength of light diffracted to a specific angle by the interaction between the quantization convex portion and the quantized phase difference structure in which the quantization concaves are aligned is the spatial frequency and the incident angle determined by the arrangement of the quantum convex and concave portions. It becomes settled by the diffraction angle.
- the spatial frequency of the quantization convex portion and the quantization concave portion is also discrete, so that only diffracted light corresponding to the spatial frequency is diffracted. Since the diffracted light is emitted at a wavelength of a certain interval, the observed diffracted light is a mixture of diffracted lights of a plurality of specific wavelengths.
- the reflected light of the top surface of the quantization recess is due to the interaction with the quantization retardation structure in which the quantization recess is aligned. And the reflected light of the bottom of the quantization recess interfere with each other.
- the depth and height can be 100 nm or more and 400 ⁇ m or less.
- the phase difference between the reflected light on the top surface and the reflected light on the bottom is maximum at integer multiples of 0 or 2 ⁇ , and the phase difference between the reflected light on the top and the reflected light on the bottom is opposite.
- the reflected light that is canceled and interferes at an integral multiple of ⁇ is zero.
- the reflected light changes continuously from zero to zero. Since the phase difference is proportional to the wavelength of the reflected light, the intensity of the reflected light for each wavelength of the reflected light due to interference changes continuously. Therefore, the reflected light due to interference is in a specific band.
- the quantization concave portion has a certain depth
- the height quantization phase difference structure having a certain quantization convex portion also selectively emits the reflected light in the band of the interference light among the diffracted light .
- second-order or higher-order diffracted light which is usually noise, is also emitted, so that the designed reflected light can not be obtained.
- the quantized phase difference structure of the present invention among the diffracted light, the interfering light is selectively reflected, so that the reflected light which does not include the high-order diffracted light can be obtained.
- the top surface of the quantization convex portion or the bottom surface of the quantization concave portion can be roughened. As a result, a band of interference due to the required quantization phase difference structure can be secured.
- the computer is an area where the calculation element section 160 (#A) defined by one reproduction point 220 (#a) and the phase angle recording area 180 (# 1) overlap. It is included in the overlapping area 190 (# 2-1) and the overlapping area 190 (# 2-1) which is an area where the calculation element section 160 (#A) and a part of the phase angle recording area 180 (# 2) overlap.
- the phase W (x, y) of the light from the reproduction point 220 (#a) is calculated for the quantization convex portion and the quantization concave portion.
- One playback point 220 or a plurality of playback points 220 exist. At one reproduction point 220, there is one corresponding calculation element section 160. When there are a plurality of playback points 220, the calculation element sections 160 exist in the same number as the plurality of playback points 220, corresponding to each of the plurality of playback points 220 on a one-to-one basis.
- the computer When there are a plurality of reproduction points 220, the computer further calculates the phase angle recording area 180 (FIG. 6) with the calculation element section 160 (#B) determined by another reproduction point 220 (#b) as shown in FIG.
- the phase W (x, y) of the light from the reproduction point 220 (# b) for the quantization convex portion and the quantization concave portion included in the overlapping area 190 (# 2) which is an area overlapping with # 2) calculate.
- the computer further calculates the phase angle ⁇ (x, y) based on the calculated phase W (x, y), and the numerical information of the calculated phase angle ⁇ (x, y) corresponds to the corresponding overlap.
- the region 190 is recorded as retardation.
- the equation for calculating the phase angle ⁇ (x, y) from the phase is as follows.
- W n (kx, ky) is the phase of the reproduction point n at coordinates (kx, ky) in the calculation element section 160 of the n-th reproduction point
- W (x, y) is the coordinates (x, y, 0)
- amp n is the light amplitude of the n-th reproduction point
- i is an imaginary number
- ⁇ is a set of reproduction points 220 in the wavelength of light in reproducing reproduction image to be reproduced
- O n (x) is the x-coordinate value of the reproduction points
- O n (y) is the value of y coordinate of the reproduction points
- O n (z) is played
- the value of the z coordinate of the point, (kx, ky, 0) is the quantization convex portion, the coordinate of the quantization concave portion
- phase W n (kx, ky) is determined at all points of the calculation element section 160, and the phase of the reproduction point n is the same at the same distance from the reproduction point 220, and thus the calculated phase information You can copy Also, as described below, O n (z) is the z-coordinate value of the reproduction point, that is, the phase W n (kx, ky) of the reproduction point having the same distance from the recording surface has the same phase distribution. It can copy calculated phase information.
- the phase of the reproduction point 220 for recording numerical information in the quantization convex portion and the quantization concave portion increases, the amount of information also increases accordingly, and the calculation time also increases. If the phase of the reproduction point 220 to be recorded is too large, the contrast of the reproduced image to be reproduced at the reproduction point 220 may be lowered. Therefore, for example, in order to obtain a clearer reproduced image in a portion where the phase angle recording areas 180 of the plurality of reproduction points 220 (#a, #b) overlap, as in the overlapping area 190 (# 2-1).
- the overlapping of the calculation element sections 160 is small, that is, the number of calculation element sections in the phase angle recording area 180 is small.
- the calculation element sections 160 may not overlap, ie, the calculation element sections 160 may be one.
- the number of calculation element sections 160 in the phase angle recording area 180 can be 256 or less. In this case, the calculation can be made more efficient.
- the number of calculation element sections 160 in the phase angle recording area 180 can be 16 or less. In this case, it is easy to obtain a clear reproduction image.
- phase W (x, y) with respect to the quantization convex portion and the quantization concave portion in the overlapping area 190 which is an area where the calculation element section 160 defined by the viewing angle ⁇ and the phase angle recording area 180 overlap.
- the phase angle ⁇ (x, y) is calculated from the phase W (x, y).
- the calculation time is shortened.
- the calculated phase angle ⁇ is recorded as retardation in the corresponding quantization convex portion and quantization concave portion in the overlapping area 190.
- FIG. 7 is a SEM image showing a quantized convex portion and a quantized concave portion in which the phase angle ⁇ is recorded.
- the quantization convex portion and the quantization concave portion illustrated in FIG. 7 are square having a side length d, and are two-dimensionally arranged at an arrangement interval d in both the X direction and the Y direction.
- the recording surface 140 may have a phase angle non-recording area 200. Even if the phase angle non-recording area 200 overlaps with the calculation element section 160, the computer does not calculate it, and no phase angle is recorded in the phase angle non-recording area 200.
- information other than the phase angle may be recorded in the phase angle non-recording area 200, for example, information on light scattering, reflection, and diffraction characteristics.
- the phase angle non-recording area 200 may be made translucent, and printing may be provided in the phase angle non-recording area 200. This makes it possible to enhance the design of the phase modulation structure 240 having the recording surface.
- the embossing layer 46 is not limited to such a structure, Several different It may have a pitch P, a plurality of different lengths L, a length T of the top surface 52 of the plurality of different quantization protrusions, and a length B of the bottom surface 54 of the plurality of different quantization recesses. As described later, since the embossed layer 46 has a plurality of spatial frequency components in the quantized retardation structure 50, the pitch P, the length L, the length T, and the length B of the unevenness are locally different. It has a quantized phase difference structure 50.
- this quantization phase difference structure 50 is composed of a quantization convex portion and a quantization concave portion of a fixed size, a structure smaller than the size of the quantization convex portion and the quantization concave portion is not formed.
- a structure of an integral multiple of the quantization convex portion and the quantization concave portion is formed in a region in which the quantization convex portion is continuous or in a region in which the quantization concave portion is continuous.
- FIG. 11A is a plan view showing multiple diffraction areas formed by the embossed layer 46 having the quantized retardation structure 50.
- FIG. 11A as in FIG. 1A, it is shown that the quantized retardation structure 50 having many different pitches P is disposed over the entire surface of the embossed layer 46.
- 11B is a plan view showing five spatial frequency components f1 to f5 in the multiple diffraction region of FIG. 11A.
- FIG. 11C is a diagram showing peak intensities of the spatial frequency components f1 to f5 shown in FIG. 11B.
- the horizontal axis indicates the distance (pixel) on the plane, and the vertical axis indicates the gray value.
- the optical structure 40 also corresponds to each of a plurality of reproduction points discretely arranged along one predetermined direction on a plane, as in the embodiment of the present invention.
- Multiple diffractive regions, each having unique spatial frequency components f1 to f5 are arranged on the planar quantized phase difference structure 50.
- a plurality of spatial frequency components f1 to f5 are arranged at intervals in one direction.
- five spatial frequency components f1 to f5 are shown as an example, but in the embodiment of the present invention, the number of spatial frequency components is 5 or more and 200 or less.
- 12A, 12B and 12C are plan views showing spatial frequency components different from those of FIG. 11B for comparison.
- the five spatial frequency components f1 to f5 shown in FIG. 11B to be compared can be separated in one direction to limit the range of color shift of the color of reflected light. And, by the interval between adjacent spatial frequency components, it is possible to suppress the decrease in brightness when viewed visually or when sensing with a measuring instrument or the like, and to suppress the decrease in luminance of the reflected light.
- one spatial frequency component f6 shown in FIG. 12A can enhance the effect of suppressing the color shift more than that in FIG. 11B by being linear, but when it is visually observed or measured The brightness decreases when sensing with an instrument or the like, so it becomes darker than in the case of FIG. 11B.
- the three spatial frequency components f7 to f9 shown in FIG. 12B are linear spatial frequency components, the light diffuses in a plurality of directions.
- the effect of suppressing the color shift can be enhanced more than in FIG. 11B, but since the luminance decreases when viewed visually or when sensing with a measuring instrument or the like, FIG. It is darker than in the case of.
- the embossed layer 46 may contain a salt adsorbent. Further, as shown in FIG. 9B, in the case of the optical structure 40 provided with the protective layer 49, at least one of the embossed layer 46 and the protective layer 49 may contain a salt adsorbent.
- FIG. 13 is a photomicrograph obtained by observation with a scanning electron microscope of a part of the surface of the quantized retardation structure 50 of the embossed layer 46.
- the quantization phase difference structure 50 is a rib-like convex portion in which a quantization convex portion which is a convex portion having a constant size as one element structure is aligned in one direction and a concave portion having a constant size as another element structure.
- Groove-shaped recesses in which the quantization recesses are aligned in parallel with the rib-shaped protrusions, are adjacently and alternately arranged.
- the depth from the top surface 52 of the quantization convex part of the rib-like convex part to the bottom surface 54 of the quantization concave part of the groove-like concave part is constant, and it is quantized to the element structure of the quantization convex part and the quantization concave ing.
- the surface roughness of the bottom surface 54 of the quantization concave portion of the quantization retardation structure 50 is rougher than the surface roughness of the top surface 52 of the quantization convex portion, and the diffracted light of the quantization retardation structure 50 is dispersed in one direction Play the playback point of.
- the surface of the quantized retardation structure 50 of the embossed layer 46 has a somewhat regular and complicated structure as shown in FIG. .
- the bottom surface 54 of the quantization recess is a constant depth, and the variation in the depth of the bottom surface 54 of the quantization recess is long. It is less than one tenth of L.
- the surface of the bottom surface 54 of the quantization recess may be rough.
- the material of the embossed layer 46 is a thermoplastic resin such as urethane resin, polycarbonate resin, polystyrene resin, polyvinyl chloride resin, unsaturated polyester resin, melamine resin, epoxy resin, urethane (meth) acrylate, polyester (meth) acrylate, Thermosetting resins such as epoxy (meth) acrylates, polyol (meth) acrylates, melamine (meth) acrylates, triazine (meth) acrylates, or mixtures thereof, and thermoforming materials having a radically polymerizable unsaturated group can do.
- a thermoplastic resin such as urethane resin, polycarbonate resin, polystyrene resin, polyvinyl chloride resin, unsaturated polyester resin, melamine resin, epoxy resin, urethane (meth) acrylate, polyester (meth) acrylate, Thermosetting resins such as epoxy (meth) acrylates, polyol (meth) acryl
- the reflective layer 48 can be formed by applying an ink.
- This ink can be an offset ink, a letterpress ink, a gravure ink, etc., depending on the printing method.
- it can be set as a non-solvent ink, an oil-based ink and an aqueous ink.
- the reflective layer 48 can be a functional ink whose color changes in accordance with the illumination angle or the observation angle.
- functional ink optical variable ink, color shift ink and pearl ink can be used.
- the reflective layer 48 can be made of metal or metal compound.
- the metal compound can be TiO 2 , Si 2 O 3 , SiO, Fe 2 O 3 , ZnS or the like. These metal compounds have a high refractive index and are easily made to have a high reflectance.
- the metal can be Al, Ag, Sn, Cr, Ni, Cu, Au or the like. These metals tend to have high reflectance.
- the reflective layer 48 may have magnetism.
- the protective layer 49 can be of the same type of material as the embossed layer 46. Also, the protective layer 49 may be the same material as the embossed layer 46. By using the same material as the embossed layer 46, the refractive index can be made the same as that of the embossed layer 46, so that the color on the front and back of the optical structure 40 can be made identical.
- an optical layer (not shown) that reflects visible light and transmits infrared light may be stacked on the optical structure 40.
- the structural colors of the embossed layer 46 and the reflective layer 48 have a reflection spectrum having a peak at least at a wavelength of 800 nm or more and 1000 nm or less.
- the optical structure according to the embodiment of the present invention peels the embossed layer 46 and the reflective layer 48 from the carrier 42 of such an optical structure 40 via the peeling layer 44 as a material for the optical structure, and this optical It is produced by finely pulverizing a structural material.
- the optical structure thus produced is dispersed in a resin and applied as a printable ink.
- the length L from the top surface 52 of the quantization convex portion of the quantization phase difference structure 50 to the bottom surface 54 of the quantization concave portion It is possible to make it easy to reflect light of a specific wavelength by adjusting the value of the length L.
- the peak intensities of the plurality of spatial frequency distributions f1 to f5 are spaced apart along one direction or a plurality of directions in a plane.
- the color shift is small, and the change in color accompanying the change in the observation direction and the illumination direction can be reduced.
- the embossed layer 46 is a simple single-pitch P diffraction grating as shown in FIG. 10, but in this case, the direction of reflection is too small. Leading to a decrease in
- the surface roughness of the bottom surface 54 of the quantization recess is roughened at 1/10 or less of the length L.
- the color L changes sensitively to the design value due to the change due to the tolerance.
- the embossed layer 46 has the surface roughness of the bottom surface 54 of the quantization recess, the degree of color change with respect to the length L is reduced. It is possible to ease the tolerance. Such an effect is not limited to that exhibited only by the surface roughness of the bottom surface 54 of the quantization recess, but is similarly exhibited by the surface roughness of the top surface 52 of the quantization protrusion.
- the average of the surface roughness of at least one of the top surface 52 of the quantization convex portion and the bottom surface 54 of the quantization recess may be roughened at 1/10 or less of the reference length L.
- Arithmetic mean roughness (Ra) can be applied as the surface roughness. That is, the arithmetic mean roughness (Ra) is 0.1 or less.
- the surface roughness of the top surface 52 of the quantization convex portion can be smaller than the surface roughness of the bottom surface 54 of the quantization recess. In this case, it is possible to reduce the tolerance of the structural color and to suppress the decrease in the saturation of the structural color. That is, the stability of structural color and the colorability of structural color can be compatible. Further, the surface roughness of the bottom surface 54 of the quantization recess may be smaller than the surface roughness of the top surface 54 of the quantization protrusion. That is, the surface roughness of the top surface 52 of the quantization protrusion and the surface roughness of the bottom surface 54 of the quantization recess are different.
- the asperity direction (that is, the vertical direction in FIG. 10) of the quantization retardation structure 50 is formed by the top surface 52 of the quantization convex portion and the bottom surface 54 of the quantization concave portion
- the protective layer 49 when manufactured from the optical structure 40 on which the protective layer 49 is laminated, the protective layer 49 is the same as the embossed layer 46.
- a material having a refractive index it is possible to make the structural color on the front and back the same.
- the reflective layer 48 is magnetic, it can be manufactured by a method in which the resin is cured after orienting the optical structure with a magnetic field in a specific direction. It is also possible to control the direction and to impart an optical effect thereby.
- the reflection spectrum of the structural color of the embossed layer 46 and the reflective layer 48 has a peak at least at a wavelength of 800 nm or more and 1000 nm or less, so that it looks black in visible light and printed in normal black Although it is not different from the printed matter, it becomes possible to produce a printed matter that responds to infrared light.
- the optical structure according to the embodiment of the present invention can also be applied to the determination of deterioration of a material such as concrete.
- the test material such as concrete contains the optical structure according to the embodiment of the present invention, the contrast between the cracked portion and the non-cracked portion is emphasized in the infrared light inspection. Is possible.
- the atmosphere containing the salt adsorbent in at least one of the embossed layer 46 and the protective layer 49 can be used. It is possible to prevent the deterioration of the reflective layer 48 due to the salt content therein.
- interference and diffraction effects are provided by aligning the convex portion and the concave portion having a constant length L in one direction, and further, the quantization position
- the bottom surface 54 of the quantization recess of the phase difference structure 50 can be roughened to impart excessive scattering.
- stable high-intensity color development can be realized by interference, high-intensity color development of diffraction, and scattering by a rough surface.
- the quantization phase difference structure 50 is a quantization structure based on the element structure, it is possible to exclude an extremely small structure or an extremely large structure which is difficult to mold.
- the flakes of the optical structure of the embodiment of the present invention as a pigment of an ink for a print that is required to be durable, it is possible to realize an ink that does not fade even if time passes. Is possible. Moreover, according to this ink, since the color shift effect in a specific direction can be eliminated, it is also possible to realize a tint that is unlikely to change in any direction. Therefore, it is extremely suitable for use as an identification means for authenticity determination in forgery of securities such as gift certificates, credit cards, and brand products and device parts.
- the optical structure according to the embodiment of the present invention is applied to an ink for infrared light, it is usually invisible to human eyes, but can be detected by an infrared detector or the like. Is also possible. Furthermore, it is also possible to utilize this for the detection of the crack of the concrete in infrared light by including the ink for infrared light in concrete.
- the image does not become an iridescent image like a conventional diffraction grating, and the image realized by Patent Document 3 A brighter image can be obtained.
- the embossed layer 46 was first designed to produce an optical structure according to an embodiment of the present invention. Specifically, 90 spatial frequency components are arranged separately in the quantization phase difference structure 50, and when light is vertically incident, the distance between adjacent light beams is about 2 degrees, and the light is 180 degrees in a planar shape. The embossed layer 46 was designed to spread in the direction.
- a positive resist with a film thickness of 0.6 ⁇ m was coated on a glass original plate, and a quantized retardation structure 50 was drawn on the positive resist surface using an electron beam drawing machine.
- the dose amount of the positive resist to be applied was determined while adjusting the length of the positive resist to be about 220 nm.
- a conductive thin film of Ni is provided by sputtering method on the glass original plate on the side on which the quantized retardation structure 50 is formed, and then Ni plating is applied to separate it from the glass original plate. A plate was made and an embossed plate was obtained.
- the thickness of the dry film of Dencapoval (R) (polyvinyl alcohol) is It applied by the gravure coating method so that it might be set to 2 micrometers, and the peeling layer 44 was provided.
- a UV curable resin ("Polyster 200", manufactured by Washin Chemical Industry Co., Ltd.) is applied to a thickness of 2 ⁇ m on the release layer 44, and the embossed plate described above is pressed against the coated surface.
- the embossed layer 46 was formed on the release layer 44 by irradiating an ultraviolet ray of 200 mJ / cm 2 from the side on which the release layer 44 is not applied, and curing the UV curable resin. Then, the embossed plate was peeled off to form an embossed layer 46 provided with the quantized retardation structure 50 on the peeling layer 44.
- a reflective layer 48 covering the embossed layer 46 was formed by forming an Al vapor deposition thin film with a film thickness of 50 nm over the entire surface of the embossed layer 46.
- a protective layer 49 was formed by applying a UV curable resin ("Polyster 200" manufactured by Washin Chemical Industry Co., Ltd.) to a film thickness of 2 ⁇ m on the reflective layer 48 again.
- a UV curable resin Polyster 200 manufactured by Washin Chemical Industry Co., Ltd.
- the material for an optical structure comprising the embossed layer 46, the reflective layer 48, and the protective layer 49 is obtained from the carrier 42. separated.
- the material for an optical structure is immersed in MEK solvent, separated, and then powdered by a planetary mill to produce an optical structure.
- the particle size of this optical structure was confirmed by a stereomicroscope, it was approximately ⁇ 20 ⁇ m.
- 50 cm3 of a concrete test sample B is prepared by adding an appropriate amount of water while mixing cement: sand: gravel in a ratio of 1: 3: 1 without mixing the optical structure. did.
- the shape of the hole can not be determined, but in the concrete test body A in which the optical structure is mixed, the shape of the circular hole may be confirmed did it. Moreover, the change of the shape by a temperature difference was also confirmed.
- the optical structure according to the embodiment of the present invention can be easily measured for the shape of concrete and can be applied for deterioration determination.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Computer Security & Cryptography (AREA)
- Credit Cards Or The Like (AREA)
- Diffracting Gratings Or Hologram Optical Elements (AREA)
- Holo Graphy (AREA)
Abstract
Description
図1Aは、本発明の一つの実施形態に係る光学構造体10に備えられた量子化位相差構造にある多重回折領域12の実施形態を示す平面図であり、図1Bは、この多重回折領域12における5つの再生点における空間周波数成分F1~F5のピーク強度の一例を示す図である。光学構造体10は、エンボス層の片面または両面にエンボス面を有する。エンボス面は、その一部または全面に多重回折領域を有する。多重回折領域には、量子化位相差構造が形成されている。
(比較例)
本発明の実施形態では、図6A~図6Dに示すように、複数の空間周波数成分が考慮され、これに応じて、複数の再生点20が考慮されるが、本比較例では、比較のために、再生点数N=1として、ホログラムの計算を行った。
上記比較例と比較すべく、本実施例1では、再生点数N=5、再生点の光強度をcos(θ)^sとし、s=20とした条件において、ホログラムの計算を行った。
上記比較例および実施例1と比較すべく、本実施例2では、再生点数N=91とし、他の条件は変えることなく、位相の計算を行った。
本発明の他の実施形態に係る光学構造体について説明する。
次に、上述したような本発明の実施形態に係る光学構造体を実際の作製し、その特性を確認し、さらに、コンクリート劣化検出用に適用した例を、実施例として以下に説明する。
本発明の実施形態に係る光学構造体を作製するために、先ず、エンボス層46を設計した。具体的には、量子化位相差構造50に、空間周波数成分を90個離間させて配置し、光が垂直入射した際に、隣り合う光線の間隔が2deg程度で、光が面状に180度方向に広がるようにエンボス層46を設計した。
上記のようにして作製した光学構造体を、UV硬化性樹脂に30W%分散させ、アプリケータにてDry膜厚100μmとなるようにPET上に塗工し、UV光にて硬化させたところ、カラーシフト青色の反射光を目視にて確認することができた。
上記のような光学構造体を、コンクリート劣化検出のために適用するために、セメント:砂:砂利:光学構造体を、1:3:1:3の割合で混合した後に撹拌しながら、適量の水を加えることによって、50cm立方のコンクリート試験体Aを作製した。
Claims (22)
- 量子化位相差構造層の一方の面に、量子化位相差構造を有した光学構造体であって、
量子化位相差構造は、サイズが一定の複数の量子化凸部と、サイズが一定の複数の量子化凹部とが整列しており、
前記量子化凸部が一方向に整列されたリブ状凸部と、前記量子化凹部が前記リブ状凸部と並行して整列された溝状凹部とが、隣接し交互に配置された量子化位相差構造を多重回折領域に有し、
前記多重回折領域は、1方向に離散した複数の規則的に配置した再生点を再生する量子化位相差構造であることを特徴とする、光学構造体。 - 前記量子化位相差構造の量子化凹部の底面の表面粗さと、前記量子化位相差構造の量子化凹部の頂面の表面粗さが異なることを特徴とする、請求項1に記載の光学構造体。
- 複数の前記多重回折領域が、前記量子化位相差構造に規則的に配置されてなることを特徴とする、請求項1に記載の光学構造体。
- 前記多重回折領域における凸構造の傾斜面が向く方向によって空間周波数成分の方向が決定されることを特徴とする、請求項3に記載の光学構造体。
- 前記空間周波数成分から再生される前記複数の再生点から、前記再生点が配置された平面までの最短距離Rは、前記多重回折領域全体の長さD、および前記多重回折領域における光の波長λを用いて、R>D2/λの関係を満足することを特徴とする、請求項4に記載の光学構造体。
- 前記複数の再生点のうち、入射光が前記ポリゴンの傾斜面において正反射する方向に存在する再生点の光強度が最も強く、前記複数の再生点のうち、正反射する方向からずれた再生点ほど、光強度が弱くなるように、前記複数の再生点の光強度分布を決定したことを特徴とする、請求項6に記載の光学構造体。
- 前記複数の再生点を、空間において非均等な間隔で配置したことを特徴とする、請求項6に記載の光学構造体。
- 前記多重回折領域がセル型であることを特徴とする、請求項3に記載の光学構造体。
- 前記多重回折領域毎に、前記量子化位相差構造の深さが異なることを特徴とする、請求項3に記載の光学構造体。
- 前記量子化位相差構造の表面に、反射層を備えたことを特徴とする、請求項3に記載の光学構造体。
- 請求項1に記載の光学構造体を備えたことを特徴とする認証体。
- フィルム上に剥離層、エンボス層、および反射層が順に積層されてなる光学構造体から作製される光学構造体であって、
前記エンボス層は量子化位相差構造を有し、前記量子化位相差構造の量子化凸部の頂面から量子化凹部の底面までの距離は、多重回折領域内の位置によらず一定であり、
前記量子化位相差構造の空間周波数のピーク強度が、前記エンボス層において、1方向または複数の方向に沿って、互いに離間して複数配置されたことを特徴とする、
光学構造体。 - 前記量子化凸部の頂面または前記量子化凹部の底面のうちの少なくとも何れかの表面粗さが、前記距離の10分の1以下であることを特徴とする、請求項13に記載の光学構造体。
- 前記量子化位相差構造の凹凸方向は、前記量子化凸部の頂面と前記量子化凹部の底面によって形成されるリブ状凹部と溝状凹部の延在方向に対して垂直であることを特徴とする、請求項13に記載の光学構造体。
- 前記光学構造体はさらに、前記反射層を保護する保護層が積層されてなることを特徴とする、請求項13に記載の光学構造体。
- 樹脂内に分散され、印刷可能なインキとして適用されることを特徴とする、請求項13に記載の光学構造体。
- 前記反射層が磁性を有することを特徴とする、請求項13に記載の光学構造体。
- 前記エンボス層および前記反射層が有する構造色の反射スペクトルが、少なくとも波長800nm以上、1000nm以下においてピークを有し、前記光学構造体はさらに、可視光を反射し、赤外光を透過する光学層が積層されてなることを特徴とする、請求項13に記載の光学構造体。
- 前記光学構造体はさらに、前記エンボス層および前記保護層のうちの少なくとも何れかに、塩分吸着剤を内包したことを特徴とする、請求項16に記載の光学構造体。
- 前記量子化位相差構造の空間周波数のピークの数を、5以上、200以下としたことを特徴とする、請求項13に記載の光学構造体。
- 量子化位相差構造層の一方の面に、量子化位相差構造を有した光学構造体であって、
前記量子化位相差構造は、一方の要素構造としてサイズが一定の凸部である量子化凸部が一方向に整列されたリブ状凸部と、他方の要素構造としてサイズが一定の凹部である量子化凹部が前記リブ状凸部と平行に整列された溝状凹部とが、隣接し交互して配置され、前記リブ状凸部の上面から前記溝状凹部の底面までの深さが一定であり、前記量子化凸部と前記量子化凹部との要素構造とに量子化され、
量子化位相差構造の前記底面の表面粗さは、前記上面の表面粗さより粗く、
前記量子化位相差構造の回折光は、一方向に離散した複数の再生点を再生することを特徴とする、光学構造体。
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020207002290A KR102566919B1 (ko) | 2017-07-26 | 2018-07-26 | 광학 구조체 및 인증체 |
| CN201880044654.0A CN110832366B (zh) | 2017-07-26 | 2018-07-26 | 光学构造体以及认证体 |
| EP18838018.2A EP3660558B1 (en) | 2017-07-26 | 2018-07-26 | Optical structure and authentication body |
| JP2019532871A JP7140123B2 (ja) | 2017-07-26 | 2018-07-26 | 光学構造体および認証体 |
| AU2018307307A AU2018307307B9 (en) | 2017-07-26 | 2018-07-26 | Optical structure and authentication body |
| US16/752,108 US11247505B2 (en) | 2017-07-26 | 2020-01-24 | Optical structure and authentication body |
| JP2022142350A JP7383238B2 (ja) | 2017-07-26 | 2022-09-07 | 光学構造体および認証体 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017-144769 | 2017-07-26 | ||
| JP2017144769 | 2017-07-26 | ||
| JP2017252240 | 2017-12-27 | ||
| JP2017-252240 | 2017-12-27 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US16/752,108 Continuation US11247505B2 (en) | 2017-07-26 | 2020-01-24 | Optical structure and authentication body |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2019022210A1 true WO2019022210A1 (ja) | 2019-01-31 |
Family
ID=65041211
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2018/028161 Ceased WO2019022210A1 (ja) | 2017-07-26 | 2018-07-26 | 光学構造体および認証体 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11247505B2 (ja) |
| EP (1) | EP3660558B1 (ja) |
| JP (2) | JP7140123B2 (ja) |
| KR (1) | KR102566919B1 (ja) |
| CN (1) | CN110832366B (ja) |
| AU (1) | AU2018307307B9 (ja) |
| WO (1) | WO2019022210A1 (ja) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU196408U1 (ru) * | 2019-11-27 | 2020-02-28 | Общество С Ограниченной Ответственностью "Центр Компьютерной Голографии" | Микрооптическая система для формирования 2d изображений |
| WO2020162449A1 (ja) * | 2019-02-07 | 2020-08-13 | 凸版印刷株式会社 | 光学構造体およびアーティファクト低減方法 |
| JP2022102699A (ja) * | 2020-12-25 | 2022-07-07 | 大日本印刷株式会社 | コンピュータプログラム、真贋判定方法、真贋判定装置及び偽造防止媒体 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7555856B2 (ja) * | 2021-03-05 | 2024-09-25 | Toppanホールディングス株式会社 | 光学部材、及び液晶表示装置 |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4916636B1 (ja) | 1965-07-12 | 1974-04-23 | ||
| JP2005215570A (ja) * | 2004-02-02 | 2005-08-11 | Dainippon Printing Co Ltd | 光学素子 |
| WO2007131375A1 (en) | 2006-05-12 | 2007-11-22 | Rolic Ag | Optically effective surface relief microstructures and method of making them |
| JP2009237457A (ja) * | 2008-03-28 | 2009-10-15 | Dainippon Printing Co Ltd | ホログラム記録媒体ならびにその製造方法および製造装置 |
| JP2011118034A (ja) | 2009-12-01 | 2011-06-16 | Toppan Printing Co Ltd | 画像形成体 |
| JP2012252306A (ja) * | 2011-06-07 | 2012-12-20 | Toppan Printing Co Ltd | 偽造防止媒体 |
| JP2014047284A (ja) * | 2012-08-31 | 2014-03-17 | Toppan Printing Co Ltd | 顔料フレークとそれを用いた画像形成体及びその画像形成体の製造方法 |
| JP2014215619A (ja) * | 2013-04-22 | 2014-11-17 | 株式会社デンソーウェーブ | 情報コード表示媒体及び情報コード読取システム |
| JP2017013474A (ja) * | 2015-07-07 | 2017-01-19 | アサヒボンド工業株式会社 | 水性防食塗装及び、水性防食塗装方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4846552A (en) * | 1986-04-16 | 1989-07-11 | The United States Of America As Represented By The Secretary Of The Air Force | Method of fabricating high efficiency binary planar optical elements |
| JPH0812285B2 (ja) * | 1988-09-07 | 1996-02-07 | 凸版印刷株式会社 | 回折格子パターンを有するディスプレイとその作製方法 |
| JPH06110371A (ja) * | 1992-09-30 | 1994-04-22 | Fujitsu Ltd | 立体表示方法及び装置 |
| EP0712012A1 (en) * | 1994-11-09 | 1996-05-15 | International Business Machines Corporation | Authentication label and authenticating pattern incorporating diffracting structure and method of fabricating them |
| US6695905B2 (en) | 2000-02-16 | 2004-02-24 | Sicpa Holding S.A. | Pigments having a viewing angle dependent shift of color, method for producing said pigments, use of said pigments in security applications, coating composition comprising said pigments and a detecting device |
| DE10054503B4 (de) | 2000-11-03 | 2005-02-03 | Ovd Kinegram Ag | Lichtbeugende binäre Gitterstruktur und Sicherheitselement mit einer solchen Gitterstruktur |
| DE102010050031A1 (de) * | 2010-11-02 | 2012-05-03 | Ovd Kinegram Ag | Sicherheitselement und Verfahren zur Herstellung eines Sicherheitselements |
| CN109313410B (zh) | 2016-06-03 | 2021-04-23 | 凸版印刷株式会社 | 光学膜及显示体 |
-
2018
- 2018-07-26 JP JP2019532871A patent/JP7140123B2/ja active Active
- 2018-07-26 EP EP18838018.2A patent/EP3660558B1/en active Active
- 2018-07-26 WO PCT/JP2018/028161 patent/WO2019022210A1/ja not_active Ceased
- 2018-07-26 CN CN201880044654.0A patent/CN110832366B/zh active Active
- 2018-07-26 AU AU2018307307A patent/AU2018307307B9/en active Active
- 2018-07-26 KR KR1020207002290A patent/KR102566919B1/ko active Active
-
2020
- 2020-01-24 US US16/752,108 patent/US11247505B2/en active Active
-
2022
- 2022-09-07 JP JP2022142350A patent/JP7383238B2/ja active Active
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4916636B1 (ja) | 1965-07-12 | 1974-04-23 | ||
| JP2005215570A (ja) * | 2004-02-02 | 2005-08-11 | Dainippon Printing Co Ltd | 光学素子 |
| WO2007131375A1 (en) | 2006-05-12 | 2007-11-22 | Rolic Ag | Optically effective surface relief microstructures and method of making them |
| JP2009237457A (ja) * | 2008-03-28 | 2009-10-15 | Dainippon Printing Co Ltd | ホログラム記録媒体ならびにその製造方法および製造装置 |
| JP2011118034A (ja) | 2009-12-01 | 2011-06-16 | Toppan Printing Co Ltd | 画像形成体 |
| JP2012252306A (ja) * | 2011-06-07 | 2012-12-20 | Toppan Printing Co Ltd | 偽造防止媒体 |
| JP2014047284A (ja) * | 2012-08-31 | 2014-03-17 | Toppan Printing Co Ltd | 顔料フレークとそれを用いた画像形成体及びその画像形成体の製造方法 |
| JP2014215619A (ja) * | 2013-04-22 | 2014-11-17 | 株式会社デンソーウェーブ | 情報コード表示媒体及び情報コード読取システム |
| JP2017013474A (ja) * | 2015-07-07 | 2017-01-19 | アサヒボンド工業株式会社 | 水性防食塗装及び、水性防食塗装方法 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020162449A1 (ja) * | 2019-02-07 | 2020-08-13 | 凸版印刷株式会社 | 光学構造体およびアーティファクト低減方法 |
| JPWO2020162449A1 (ja) * | 2019-02-07 | 2021-12-09 | 凸版印刷株式会社 | 光学構造体およびアーティファクト低減方法 |
| JP7487667B2 (ja) | 2019-02-07 | 2024-05-21 | Toppanホールディングス株式会社 | 光学構造体およびアーティファクト低減方法 |
| RU196408U1 (ru) * | 2019-11-27 | 2020-02-28 | Общество С Ограниченной Ответственностью "Центр Компьютерной Голографии" | Микрооптическая система для формирования 2d изображений |
| JP2022102699A (ja) * | 2020-12-25 | 2022-07-07 | 大日本印刷株式会社 | コンピュータプログラム、真贋判定方法、真贋判定装置及び偽造防止媒体 |
| JP7581867B2 (ja) | 2020-12-25 | 2024-11-13 | 大日本印刷株式会社 | コンピュータプログラム、真贋判定方法、真贋判定装置及び偽造防止媒体 |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2018307307A1 (en) | 2020-02-20 |
| KR20200029487A (ko) | 2020-03-18 |
| EP3660558A1 (en) | 2020-06-03 |
| CN110832366B (zh) | 2021-12-28 |
| EP3660558A4 (en) | 2020-08-19 |
| EP3660558B1 (en) | 2024-11-27 |
| US20200156399A1 (en) | 2020-05-21 |
| JP7140123B2 (ja) | 2022-09-21 |
| AU2018307307B9 (en) | 2023-10-26 |
| KR102566919B1 (ko) | 2023-08-14 |
| JP2022180429A (ja) | 2022-12-06 |
| JPWO2019022210A1 (ja) | 2020-05-28 |
| AU2018307307B2 (en) | 2023-09-28 |
| JP7383238B2 (ja) | 2023-11-20 |
| CN110832366A (zh) | 2020-02-21 |
| US11247505B2 (en) | 2022-02-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102905909B (zh) | 防伪元件、具有这种防伪元件的有价文件和这种防伪元件的制造方法 | |
| JP7383238B2 (ja) | 光学構造体および認証体 | |
| US10473831B2 (en) | Display having light-scattering property | |
| AU2006230761C1 (en) | Patterned optical structures with enhanced security feature | |
| JP5434144B2 (ja) | 表示体及びラベル付き物品 | |
| JP4983948B2 (ja) | 表示体及び表示体付き物品 | |
| JP5143855B2 (ja) | 表示体及びラベル付き物品 | |
| KR102437351B1 (ko) | 광학 필름 및 표시체 | |
| JPWO2017068769A1 (ja) | 表示体、および表示体付き物品、ならびに表示体の観察方法 | |
| EP3770654A1 (en) | Optical element, transfer foil, authentication object, and method for verifying authentication object | |
| JP6171291B2 (ja) | 表示体の真偽判定方法 | |
| JP5163137B2 (ja) | 表示体及び表示体付き物品 | |
| JP2012078447A (ja) | 表示体及びラベル付き物品 | |
| JP5504825B2 (ja) | 表示体 | |
| JP2013020084A (ja) | 計算機ホログラムを有する表示体及びラベル付き物品 | |
| WO2018097315A1 (ja) | 光学フィルム |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 18838018 Country of ref document: EP Kind code of ref document: A1 |
|
| ENP | Entry into the national phase |
Ref document number: 2019532871 Country of ref document: JP Kind code of ref document: A |
|
| ENP | Entry into the national phase |
Ref document number: 20207002290 Country of ref document: KR Kind code of ref document: A |
|
| NENP | Non-entry into the national phase |
Ref country code: DE |
|
| ENP | Entry into the national phase |
Ref document number: 2018307307 Country of ref document: AU Date of ref document: 20180726 Kind code of ref document: A |
|
| ENP | Entry into the national phase |
Ref document number: 2018838018 Country of ref document: EP Effective date: 20200226 |