WO2019011644A1 - METHOD FOR PRODUCING A PRESS-CURED COMPONENT - Google Patents
METHOD FOR PRODUCING A PRESS-CURED COMPONENT Download PDFInfo
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- WO2019011644A1 WO2019011644A1 PCT/EP2018/067051 EP2018067051W WO2019011644A1 WO 2019011644 A1 WO2019011644 A1 WO 2019011644A1 EP 2018067051 W EP2018067051 W EP 2018067051W WO 2019011644 A1 WO2019011644 A1 WO 2019011644A1
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- Prior art keywords
- coating
- flat steel
- steel product
- weight
- steel component
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/012—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of aluminium or an aluminium alloy
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/673—Quenching devices for die quenching
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/0068—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for particular articles not mentioned below
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/32—Ferrous alloys, e.g. steel alloys containing chromium with boron
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
- C23C2/29—Cooling or quenching
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/34—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the shape of the material to be treated
- C23C2/36—Elongated material
- C23C2/40—Plates; Strips
- C23C2/405—Plates of specific length
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/02—Stamping using rigid devices or tools
- B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
- B21D22/208—Deep-drawing by heating the blank or deep-drawing associated with heat treatment
Definitions
- the present invention relates to methods for producing a steel component comprising a substrate and a coating, a corresponding steel component and its use in the automotive sector.
- WO 2015/036151 A1 discloses a method for producing a steel component provided with a metallic, corrosion-protective coating and a corresponding steel component.
- the method according to this document comprises coating a flat steel product with an alloy of aluminum, zinc, magnesium and optionally silicon and iron, cutting a blank from the flat steel product, heating the blank and reshaping the blank to obtain the desired steel component.
- DE 699 07 816 T2 discloses a method for producing a coated hot and cold rolled steel sheet having very high strength after thermal treatment.
- a flat steel product is provided with a coating and thermally treated.
- the workpiece is heated to a temperature of over 750 ° C.
- the present invention is based on the object to provide a method for the production of steel components comprising a substrate and a coating available, can be obtained with the corresponding steel components, characterized by a particularly high bending angle ⁇ according to VDA 238-100 and thus also characterized by an improved crash behavior when used in the automotive sector. NEN. Furthermore, according to the invention, in coated flat steel products, the average arithmetic mean roughness R a should lie within a certain optimum interval, in order thereby to achieve an optimized bending angle, in order to improve the properties of the flat steel products.
- step (C) forming the heated flat steel product of step (B) in a mold with simultaneous cooling to obtain the steel component.
- Step (A) of the process according to the invention comprises the provision of a flat steel product containing (all data in% by weight)
- 0.15 to 0.50 preferably 0.20 to 0.30, particularly preferably 0.21 to 0.25 C,
- 0.10 to 0.50 preferably 0.15 to 0.40, particularly preferably 0.20 to 0.30 Si,
- Unavoidable impurities in the substrate according to the invention are, for example, Cu, Mo, V, Ni and / or Sn.
- any flat steel product which appears suitable to the person skilled in the art with the corresponding analysis and a corresponding coating can be used.
- the flat steel product used is preferably a strip, in particular a hot strip or a cold strip, around a sheet, ie. H. a piece of a hot strip or a cold strip, or a board made of a hot strip or a board made of a cold strip.
- the present invention preferably relates to the method according to the invention, wherein the flat steel product is a board made of a hot strip or a board made of a cold strip.
- the flat steel product according to the invention is provided with a coating, the coating preferably having 3 to 15, particularly preferably 7 to 12, very particularly preferably 9 to 10 Si, 1 to 3.5, preferably 2 to 3.5 Fe, up to 0, 5 alkali and / or alkaline earth metals, for example magnesium, calcium and / or lithium, the radical AI and unavoidable impurities (all figures in wt .-%).
- the coating can be carried out by a fire coating, an electrolytic coating or by means of a piece coating process.
- the present invention therefore preferably relates to the method according to the invention, wherein the coating takes place by means of a fire coating, an electrolytic coating or by means of a piece coating process.
- the application of the aluminum-silicon-iron alloy is carried out by means of a continuous fire-coating process.
- the temperature of the aluminum molten bath is between 650 ° C and 720 ° C.
- Silicon in the coating acts as a diffusion blocker and serves to calm the melt bath when applying the coating formed from the aluminum alloy by means of fire coating.
- the thickness of the coating according to the invention is preferably from 5 to 60 ⁇ , preferably 10 to 40 ⁇ .
- the present invention therefore preferably relates to the process according to the invention, wherein the coating weight of the double-sided coating is from 30 to 360 g / m 2 .
- the coating may be present on one side of the flat steel product or on both sides of the flat steel product.
- the present invention therefore preferably relates to the process according to the invention, wherein the coating is present on one side of the flat steel product or on both sides of the flat steel product, in particular on both sides of the flat steel product.
- the coated flat steel product from step (A) is preferably transferred directly into the process step (B) according to the invention.
- further steps are carried out, for example separation of areas, in particular sheets or blanks of the flat steel product, for example by shearing or laser cutting, introducing holes by laser machining or punching, preceding heat treatments to change the properties of the coating or substrate, and / or to introduce a pre-deformation.
- Step (B) of the process according to the invention comprises treating the steel flat product at a furnace temperature Ti (in K) for a duration ti (in h) such that pi in accordance with the equation of the general formula (2) has a value from 8 to 30, preferably from 9 to 30, more preferably 9 to 26, most preferably 10 to 22
- step (B) the heat treatment is carried out such that the parameter p1 mentioned in equation (2) has a value of 8 to 30.
- Ti means the furnace temperature in Kelvin, ie. the temperature, which is carried out in the oven, in the step (B) of the method according to the invention is present.
- Ti is preferably from 1070 to 1350 K, particularly preferably from 1100 to 1250 K, wherein it must be satisfied at the same time that pl has a value of from 9 to 30 according to equation (2).
- the present invention therefore preferably relates to the process according to the invention, Ti being from 1070 to 1350 K, particularly preferably from 1100 to 1250 K.
- ti is the duration for which the flat steel product is exposed to the corresponding temperature Ti. This is preferably the period from retraction / insertion of the sample in the oven to the extension / removal of the sample from the oven.
- ti is given in hours (h)
- ti according to the invention is preferably 0.02 to 0.50 h, more preferably 0.04 to 0.50 h, wherein it must be satisfied at the same time that pi has a value according to equation (2) from 8 to 30, preferably from 9 to 30, more preferably from 9 to 26, most preferably from 10 to 22 having.
- the present invention therefore preferably relates to the process according to the invention, where ti is 0.02 to 0.50 h, more preferably 0.04 to 0.50 h.
- a constant temperature Ti it is possible for a constant temperature Ti to prevail during step (B) over the entire time ti. It is also possible according to the invention for temperatures Ti to be present within the time ti which are not constant, for example in one part (a) of the period ti (t la ) there is a temperature Ti a in a further part (b) of the period ti (t lb ) is a temperature T lb , and in a further part (c) of the period ti (t lc ) is a temperature T lc, etc., before.
- the arithmetic mean roughness R a is in a range which can negatively influence the further processing properties, for example tribological properties during forming, heat transfer, paintability.
- step (B) of the process according to the invention in particular the period from the introduction / insertion of the sample into the oven until the sample is extracted / removed from the oven, a desired arithmetic mean roughness value R a is achieved .
- This can be determined by methods known to those skilled in the art, preferably the arithmetic mean roughness R a is determined according to DIN EN 10049: 2014-03 in ⁇ , particularly preferably as an average value of 40 measurements for samples coated on both sides, 20 on each side of the samples, each transverse to the rolling direction of the sample. For samples coated on one side, the measurement is made only on the coated side.
- step (A) and step (B) in a further method step between step (A) and step (B) to the flat steel product at least one particular Range added or further elaborated, so that the particular area of at least one of the attributes of support weight, sheet thickness, chemical composition, which is different from the flat steel product before this further process step, wherein the equation of the general formula (1) applies only to the areas which were already present in the original flat steel product, whereby preferably different mechanical properties are achieved.
- step (C) in a further process step in step (C) at least one particular area of the flat steel product is further developed so that the particular area experiences other cooling conditions in the tool (eg by local heating of the tool) than in a conventional one Press hardening process (with tools cooled to ⁇ 100 ° C), wherein the equation of the general formula (1) applies only to the areas produced by the usual press hardening process, whereby preferably different mechanical properties are obtained.
- tailored blanks for example tailor-welded blanks, tailor-rolled blanks, tailored tempering.
- the flat steel product is reinforced in at least one area by an additionally applied, different or similar flat steel product (for example by joining), than in the unreinforced areas.
- Step (C) of the process of the invention comprises forming the heated flat steel product of step (B) in a mold while cooling to obtain the steel component.
- step (C) of the process according to the invention all processes known to the person skilled in the art can be used for hot forming, for example described in hot forming in automotive engineering - processes, materials, surfaces, Landsberg / Lech: Verl. Moderne Industrie, 2012, Die part dertechnik.
- step (C) of the process according to the invention the desired steel component is obtained from the flat steel product from step (B) by forming.
- the desired hardness structure ie. At least 80% martensite, the remainder bainite, ferrite and retained austenite
- the cooling in step (C) of the process according to the invention is preferably carried out at a rate of 27 to 1000 K / s, preferably 50 to 500 K / s.
- the present invention therefore preferably relates to the process according to the invention, wherein the cooling in step (C) takes place at a cooling rate of 27 to 1000 K / s.
- ⁇ means the bending angle according to VDA 238-100, which the steel component produced according to the invention has.
- the bending angle ⁇ indicated in equation (1) is determined according to the invention with the longitudinal direction of the sample. Bending axis Transverse to rolling direction. If the bending angle ⁇ stated in equation (1) is determined according to the invention with the sample position transverse, that is to say, Bending axis Longitudinally determined to the rolling direction, due to the material anisotropy the determined values are approx. 6.5% lower. Also, for other sample plies (e.g., diagonal), slightly different bending angles may be seen, with the deviations preferably between those of the longitudinal and transverse plies, i. between 0 and 6.5%. The values reflect in their overall tendency the relationship according to equation (1) again. Therefore, the equation (1) according to the invention is preferably for bending angle a, with the longitudinal direction of the sample, ie. Bending axis transverse to the rolling direction.
- the crash suitability of a steel component depends essentially on the bending angle ⁇ at maximum force measured in the "flake bending test for metallic materials" (see Till Laumann, Qualitative and quantitative assessment of the crashworthiness of high-strength steels, Meisenbach Verlag Bamberg, 2010 ( ISBN 978-3-87525-299-6)). High bending angles stand for a good crash suitability.
- R a represents the arithmetic mean roughness and is expressed in ⁇ .
- the arithmetic mean roughness R a according to DIN EN 10049: 2014-03 is 1, 30 to 2.30 ⁇ m, preferably 1.50 to 2.22 ⁇ m, particularly preferably 1.60 to 2.10 ⁇ m and the bending angle ⁇ according to VDA 238-100 is 54 to 70 °, preferably 54 to 66 °, particularly preferably 54 to 62 °, wherein the values according to the invention must be linked together so that the equation of the general formula (1) applies.
- the present invention also relates to a steel component comprising a substrate (all data in% by weight) 0.15 to 0.50, preferably 0.20 to 0.30, particularly preferably 0.21 to 0.25 C,
- 0.10 to 0.50 preferably 0.15 to 0.40, particularly preferably 0.20 to 0.30 Si,
- this steel component according to the invention is obtained by the method according to the invention.
- the present invention relates to the steel component according to the invention, wherein it is obtained by forming a corresponding flat steel product, wherein the flat steel product has been treated prior to forming at a furnace temperature T 1 (in K) for a duration ti (in h) such that p 1 according to the equation of general formula (2) has a value of 8 to 30, preferably from 9 to 30, particularly preferably from 9 to 26, very particularly preferably from 10 to 22, having
- the present invention relates to the steel component according to the invention, wherein the coating weight of the double-sided coating 30 to 360 g / m2, preferably 100 to 200 g / m 2 , particularly preferably 120 to 180 g / m 2 , for example 150 g / m 2 ,
- the present invention also relates to a steel component containing (all data in% by weight)
- Residual Fe and unavoidable impurities as substrate containing a coating (all data in% by weight)
- the present invention also relates to the use of a coated steel component according to the invention in the automotive sector, in particular as a bumper support / reinforcement, door reinforcement, B-pillar reinforcement, A-pillar reinforcement, roof frame or sill.
- a coated steel component according to the invention in the automotive sector, in particular as a bumper support / reinforcement, door reinforcement, B-pillar reinforcement, A-pillar reinforcement, roof frame or sill.
- FIG. 1 shows an exemplary topography measurement in an exaggerated representation to illustrate the surface roughness.
- FIG. 2 shows an exemplary illustration (micrograph) of two different topologies on the surface of steel components according to the invention, in which:
- Steel flat products (cold strip) of the analysis mentioned in Table 1 are used in the form of blanks.
- the cold strip was coated and the boards were cut out.
- the coating of the flat steel products used by way of example is a so-called AlSi coating which can be adjusted, inter alia, by fire coating, consisting of 9 to 10 wt.% Si, 2 to 3.5 wt.% Iron, balance aluminum consists.
- the thus obtained and coated flat steel products are heated to a temperature Ti (see table) for a duration ti (see table), then placed in a press mold, where they are hot formed to the steel component and as quickly as possible by contact with a conventional hot forming tool within approx.
- oven temperature T oven residence time ti plate thickness and coating weight are varied and accordingly samples are prepared for the bending test.
- the measurement is carried out on 5 samples each
- Table 1 Composition of the melt used, all data in wt .-%, balance Fe
- Table 2 shows the process parameters and the resulting bending angles.
- Table 2 Process parameters and obtained bending angles
- the steel component produced according to the invention has an improved crash behavior and can therefore be used advantageously in the automotive sector.
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- Metallurgy (AREA)
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Abstract
Die vorliegende Erfindung betrifft ein Verfahren zur Herstellung eines Stahlbauteils umfassend ein Substrat und einen Überzug, ein entsprechendes Stahlbauteil und dessen Verwendung im Automobilsektor.The present invention relates to a method for producing a steel component comprising a substrate and a coating, a corresponding steel component and its use in the automotive sector.
Description
Verfahren zur Herstellung eines pressgehärteten Bauteils Method for producing a press-hardened component
Technisches Gebiet Technical area
Die vorliegende Erfindung betrifft Verfahren zur Herstellung eines Stahlbauteils umfassend ein Substrat und einen Überzug, ein entsprechendes Stahlbauteil und dessen Verwendung im Automobilsektor. The present invention relates to methods for producing a steel component comprising a substrate and a coating, a corresponding steel component and its use in the automotive sector.
Technischer Hintergrund Technical background
Um die im modernen Karosseriebau geforderte Kombination aus geringem Gewicht, maximaler Festigkeit und Schutzwirkung zu bieten, werden heutzutage in den Bereichen der Karosserie, die im Fall eines Crashs besonders hohen Belastungen ausgesetzt sein können, Bauteile eingesetzt, die aus hochfesten Stählen warmumgeformt werden. Beim Warmumformen, auch Warmpresshärten genannt, werden Stahlplatinen, die zuvor von kalt- oder warmgewalztem Stahlband abgeteilt werden, auf eine Verformungstemperatur erwärmt, die im Allgemeinen oberhalb der Austenitisierungstemperatur des jeweiligen Stahls liegt, und im erwärmten Zustand in das Werkzeug einer Umformpresse gelegt. Im Zuge der anschließend durchgeführten Umformung erfährt der Blechzuschnitt bzw. das aus ihm geformte Bauteil durch den Kontakt mit dem kühlen Werkzeug eine schnelle Abkühlung . Die Abkühlraten sind dabei so eingestellt, dass sich im Bauteil ein Härtegefüge ergibt. In order to provide the combination of low weight, maximum strength and protective effect required in modern body construction, today components are used in the areas of the body, which may be particularly high loads in the event of a crash, which are hot-formed from high-strength steels. In hot forming, also called hot press hardening, steel blanks, previously separated from cold or hot rolled steel strip, are heated to a forming temperature generally above the austenitizing temperature of the respective steel and placed in the mold of a forming press in the heated state. In the course of the subsequent transformation, the sheet metal blank or the component formed from it undergoes rapid cooling due to the contact with the cool tool. The cooling rates are set so that a hardness structure results in the component.
WO 2015/036151 AI offenbart ein Verfahren zur Herstellung eines mit einem metallischen, vor Korrosion schützenden Überzug versehenen Stahlbauteils und ein entsprechendes Stahlbauteil. Das Verfahren gemäß diesem Dokument umfasst das Beschichten eines Stahlflachproduktes mit einer Legierung aus Aluminium, Zink, Magnesium und gegebenenfalls Silizium und Eisen, Schneiden einer Platine aus dem Stahlflachprodukt, Erwärmen der Platine und Umformen der Platine, um das gewünschte Stahlbauteil zu erhalten. WO 2015/036151 A1 discloses a method for producing a steel component provided with a metallic, corrosion-protective coating and a corresponding steel component. The method according to this document comprises coating a flat steel product with an alloy of aluminum, zinc, magnesium and optionally silicon and iron, cutting a blank from the flat steel product, heating the blank and reshaping the blank to obtain the desired steel component.
DE 699 07 816 T2 offenbart ein Verfahren zur Herstellung eines beschichteten warm- und kaltgewalzten Stahlblechs mit sehr hoher Festigkeit nach thermischer Behandlung . Dazu wird ein Stahlflachprodukt mit einem Überzug versehen und thermisch behandelt. Bei der thermischen Behandlung wird das Werkstück auf eine Temperatur von über 750 °C erwärmt. DE 699 07 816 T2 discloses a method for producing a coated hot and cold rolled steel sheet having very high strength after thermal treatment. For this purpose, a flat steel product is provided with a coating and thermally treated. During thermal treatment, the workpiece is heated to a temperature of over 750 ° C.
Der vorliegenden Erfindung liegt die Aufgabe zu Grunde, ein Verfahren zur Herstellung von Stahlbauteilen umfassend ein Substrat und einen Überzug zur Verfügung zu stellen, mit dem entsprechende Stahlbauteile erhalten werden können, die sich durch einen besonders hohen Biegewinkel α gemäß VDA 238-100 und damit auch durch ein verbessertes Crashverhalten bei ihrem Einsatz im Automobilsektor auszeich- nen. Des Weiteren soll erfindungsgemäß in beschichteten Stahlflachprodukten der arithmetische Mittenrauwert Ra in einem bestimmten optimalen Intervall liegen um dadurch einen optimierten Biegewinkel zu erreichen, um die Eigenschaften der Stahlflachprodukte zu verbessern . The present invention is based on the object to provide a method for the production of steel components comprising a substrate and a coating available, can be obtained with the corresponding steel components, characterized by a particularly high bending angle α according to VDA 238-100 and thus also characterized by an improved crash behavior when used in the automotive sector. NEN. Furthermore, according to the invention, in coated flat steel products, the average arithmetic mean roughness R a should lie within a certain optimum interval, in order thereby to achieve an optimized bending angle, in order to improve the properties of the flat steel products.
Gelöst wird diese Aufgabe durch das erfindungsgemäße Verfahren zur Herstellung eines Stahlbauteils umfassend ein Substrat und einen Überzug, wobei der Biegewinkel a des Stahlbauteils (in °) nach VDA238-100 und der arithmetische Mittenrauwert Ra (in μιη) nach DIN EN 10049:2014-03 gemäß der allgemeinen Formel (1) miteinander verknüpft sind, umfassend wenigstens die Schritte: This object is achieved by the inventive method for producing a steel component comprising a substrate and a coating, wherein the bending angle a of the steel component (in °) according to VDA238-100 and the arithmetic mean roughness R a (in μιη) according to DIN EN 10049: 2014- 03 according to the general formula (1) linked together, comprising at least the steps:
(A) Bereitstellen eines Stahlflach Produktes enthaltend (alle Angaben in Gew.-%) (A) Providing a flat steel product containing (all data in% by weight)
0, 15 bis 0,50 C, 0.15 to 0.50 C,
0,50 bis 3,0 Mn, 0.50 to 3.0 Mn,
0, 10 bis 0,50 Si, 0, 10 to 0.50 Si,
0,01 bis 1,00 Cr, 0.01 to 1.00 Cr,
bis zu 0,20 Ti, up to 0.20 Ti,
bis zu 0, 10 AI, up to 0, 10 AI,
bis zu 0, 10 P, up to 0, 10 P,
bis zu 0, 1 Nb, up to 0, 1 Nb,
bis zu 0,01 N , up to 0.01 N,
bis zu 0,05 S und up to 0.05 S and
bis zu 0, 1 B, up to 0, 1 B,
Rest Fe und unvermeidbare Verunreinigungen, mit einem Überzug enthaltend (alle Angaben in Gew.-%) Balance Fe and unavoidable impurities, containing a coating (all figures in% by weight)
3 bis 15 Si, 3 to 15 Si,
1 bis 3,5 Fe, 1 to 3.5 Fe,
bis zu 0,5 Alkali- und/oder Erdalkalimetalle, up to 0.5 alkali and / or alkaline earth metals,
Rest AI und unvermeidbare Verunreinigungen, (B) Behandeln des Stahlflachproduktes bei einer Ofentemperatur T1 (in K) für eine Dauer ti (in h), so dass p1 gemäß der Gleichung der allgemeinen Formel (2) einen Wert von 8 bis 30 aufweist Rest AI and unavoidable impurities, (B) treating the flat steel product at a furnace temperature T 1 (in K) for a duration ti (in h) such that p 1 has a value of 8 to 30 according to the equation of the general formula (2)
(C) Umformen des aufgeheizten Stahlflachproduktes aus Schritt (B) in einem Formwerkzeug unter gleichzeitigem Abkühlen, um das Stahlbauteil zu erhalten. (C) forming the heated flat steel product of step (B) in a mold with simultaneous cooling to obtain the steel component.
Des Weiteren werden diese Aufgaben auch gelöst durch ein entsprechendes Stahlbauteil und durch die Verwendung des erfindungsgemäßen Stahlbauteils im Automobilsektor, insbesondere als Stoßstangen- träger/-verstärkung, Türverstärkung, B-Säulen-Verstärkung, A-Säulen-Verstärkung, Dachrahmen oder Schweller. Furthermore, these objects are also achieved by a corresponding steel component and by the use of the steel component according to the invention in the automotive sector, in particular as bumper support / reinforcement, door reinforcement, B-pillar reinforcement, A-pillar reinforcement, roof frame or sill.
Das erfindungsgemäße Verfahren wird im Folgenden detailliert beschrieben : The process according to the invention is described in detail below:
Schritt (A) des erfindungsgemäßen Verfahrens umfasst das Bereitstellen eines Stahlflachproduktes enthaltend (alle Angaben in Gew.-%) Step (A) of the process according to the invention comprises the provision of a flat steel product containing (all data in% by weight)
0, 15 bis 0,50 bevorzugt 0,20 bis 0,30, besonders bevorzugt 0,21 bis 0,25 C, 0.15 to 0.50, preferably 0.20 to 0.30, particularly preferably 0.21 to 0.25 C,
0,50 bis 3,0, bevorzugt 0,80 bis 2,00, besonders bevorzugt 1 ,00 bis 1,50 Mn, 0.50 to 3.0, preferably 0.80 to 2.00, particularly preferably 1.00 to 1.50 Mn,
0, 10 bis 0,50, bevorzugt 0, 15 bis 0,40, besonders bevorzugt 0,20 bis 0,30 Si, 0.10 to 0.50, preferably 0.15 to 0.40, particularly preferably 0.20 to 0.30 Si,
0,01 bis 1 ,00, bevorzugt 0, 10 bis 0,5, besonders bevorzugt 0, 10 bis 0,40 Cr, 0.01 to 1, 00, preferably 0, 10 to 0.5, particularly preferably 0, 10 to 0.40 Cr,
bis zu 0,20, bevorzugt 0,01 bis 0, 10, besonders bevorzugt 0,01 bis 0,04 Ti, up to 0.20, preferably 0.01 to 0, 10, particularly preferably 0.01 to 0.04, Ti,
bis zu 0, 10, bevorzugt 0,01 bis 0,05, besonders bevorzugt 0,02 bis 0,05 AI, up to 0, 10, preferably 0.01 to 0.05, particularly prefers 0.02 to 0.05 AI,
bis zu 0, 10, bevorzugt 0,00 bis 0,05, besonders bevorzugt 0,00 bis 0,02 P, up to 0.10, preferably 0.00 to 0.05, particularly preferably 0.00 to 0.02 P,
bis zu 0, 1 , bevorzugt 0,001 bis 0, 1 Nb, up to 0, 1, preferably 0.001 to 0, 1 Nb,
bis zu 0,01 N, up to 0.01 N,
bis zu 0,05, bevorzugt 0,00 bis 0,005, besonders bevorzugt 0,00 bis 0,003 S und up to 0.05, preferably 0.00 to 0.005, more preferably 0.00 to 0.003 S and
bis zu 0, 1 , bevorzugt 0,001 bis 0,05, besonders bevorzugt 0,002 bis 0,0035 B, up to 0.1, preferably 0.001 to 0.05, particularly preferably 0.002 to 0.0035 B,
Rest Fe und unvermeidbare Verunreinigungen, mit einem Überzug enthaltend (alle Angaben in Gew.-%) Balance Fe and unavoidable impurities, containing a coating (all figures in% by weight)
3 bis 15 Si, 3 to 15 Si,
1 bis 3,5 Fe, 1 to 3.5 Fe,
bis zu 0,5 Alkali- und/oder Erdalkalimetalle, Rest AI und unvermeidbare Verunreinigungen. up to 0.5 alkali and / or alkaline earth metals, Rest AI and unavoidable impurities.
Unvermeidbare Verunreinigungen im Substrat sind erfindungsgemäß beispielsweise Cu, Mo, V, Ni und/oder Sn. Unavoidable impurities in the substrate according to the invention are, for example, Cu, Mo, V, Ni and / or Sn.
Erfindungsgemäß kann in Schritt (A) des erfindungsgemäßen Verfahrens jedes dem Fachmann als geeignet erscheinende Stahlflachprodukt mit der entsprechenden Analyse und einem entsprechenden Überzug verwendet werden. Bevorzugt handelt es sich bei dem eingesetzten Stahlflachprodukt um ein Band, insbesondere ein Warmband oder ein Kaltband, um ein Blech, d . h. ein Stück eines Warmbandes oder eines Kaltbandes, oder um eine Platine aus einem Warmband oder eine Platine aus einem Kaltband . Die vorliegende Erfindung betrifft bevorzugt das erfindungsgemäße Verfahren, wobei das Stahlflachprodukt eine Platine aus einem Warmband oder eine Platine aus einem Kaltband ist. According to the invention, in step (A) of the process according to the invention, any flat steel product which appears suitable to the person skilled in the art with the corresponding analysis and a corresponding coating can be used. The flat steel product used is preferably a strip, in particular a hot strip or a cold strip, around a sheet, ie. H. a piece of a hot strip or a cold strip, or a board made of a hot strip or a board made of a cold strip. The present invention preferably relates to the method according to the invention, wherein the flat steel product is a board made of a hot strip or a board made of a cold strip.
Verfahren zur Herstellung eines Warmbandes bzw. eines Kaltbandes sind dem Fachmann an sich bekannt und beispielsweise beschrieben in Hoffmann, Hartmut; Neugebauer, Reimund; Spur, Günter (2012): Handbuch Umformen. München : Carl Hanser Verlag GmbH & Co. KG., Seiten 109 bis 165 und Seiten 196 bis 207. Methods for producing a hot strip or a cold strip are known per se to those skilled in the art and described for example in Hoffmann, Hartmut; Neugebauer, Reimund; Spur, Günter (2012): Handbuch Umformen. Munich: Carl Hanser Verlag GmbH & Co. KG., Pages 109 to 165 and pages 196 to 207.
Das erfindungsgemäß beschaffene Stahlflachprodukt wird mit einem Überzug versehen, wobei der Überzug bevorzugt 3 bis 15, besonders bevorzugt 7 bis 12, ganz besonders bevorzugt 9 bis 10 Si, 1 bis 3,5, bevorzugt 2 bis 3,5 Fe, bis zu 0,5 Alkali- und/oder Erdalkalimetalle, beispielsweise Magnesium, Kalzium und/oder Lithium, Rest AI und unvermeidbare Verunreinigungen enthält (alle Angaben in Gew.-%). The flat steel product according to the invention is provided with a coating, the coating preferably having 3 to 15, particularly preferably 7 to 12, very particularly preferably 9 to 10 Si, 1 to 3.5, preferably 2 to 3.5 Fe, up to 0, 5 alkali and / or alkaline earth metals, for example magnesium, calcium and / or lithium, the radical AI and unavoidable impurities (all figures in wt .-%).
Verfahren zur Herstellung eines entsprechenden beschichteten Stahlflachproduktes sind dem Fachmann an sich bekannt, beispielsweise kann der Überzug durch eine Feuerbeschichtung, eine elektrolytische Beschichtung oder mittels eines Stückbeschichtungsprozesses erfolgen. Die vorliegende Erfindung betrifft daher bevorzugt das erfindungsgemäße Verfahren, wobei der Überzug durch eine Feuerbeschichtung, eine elektrolytische Beschichtung oder mittels eines Stückbeschichtungsprozesses erfolgt. Methods for producing a corresponding coated flat steel product are known per se to those skilled in the art, for example, the coating can be carried out by a fire coating, an electrolytic coating or by means of a piece coating process. The present invention therefore preferably relates to the method according to the invention, wherein the coating takes place by means of a fire coating, an electrolytic coating or by means of a piece coating process.
Vorzugsweise erfolgt das Aufbringen der Aluminium-Silizium-Eisen-Legierung mittels eines kontinuierlichen Feuerbeschichtungsprozesses. Preferably, the application of the aluminum-silicon-iron alloy is carried out by means of a continuous fire-coating process.
Vorzugsweise liegt bei der Beschichtung die Temperatur des Aluminium-Schmelzbades zwischen 650 °C und 720 °C. Preferably, in the coating, the temperature of the aluminum molten bath is between 650 ° C and 720 ° C.
Silizium im Überzug wirkt als Diffusionsblocker und dient der Beruhigung des Schmelzenbades beim Aufbringen des aus der Aluminium-Legierung gebildeten Überzuges mittels Feuerbeschichtung. Die Dicke des Überzugs liegt erfindungsgemäß bevorzugt bei 5 bis 60 μιτι, vorzugsweise 10 bis 40 μιτι. Daraus ergibt sich ein erfindungsgemäßes Auflagengewicht des beidseitigen Überzugs von 30 bis 360 g/m2, bevorzugt 100 bis 200 g/m2, besonders bevorzugt 120 bis 180 g/m2, beispielsweise 150 g/m2. Die vorliegende Erfindung betrifft daher bevorzugt das erfindungsgemäße Verfahren, wobei das Auflagegewicht des beidseitigen Überzugs 30 bis 360 g/m2 beträgt. Silicon in the coating acts as a diffusion blocker and serves to calm the melt bath when applying the coating formed from the aluminum alloy by means of fire coating. The thickness of the coating according to the invention is preferably from 5 to 60 μιτι, preferably 10 to 40 μιτι. This results in an inventive overlay weight of the two-sided coating of 30 to 360 g / m 2 , preferably 100 to 200 g / m 2 , particularly preferably 120 to 180 g / m 2 , for example 150 g / m 2 . The present invention therefore preferably relates to the process according to the invention, wherein the coating weight of the double-sided coating is from 30 to 360 g / m 2 .
Erfindungsgemäß kann der Überzug auf einer Seite des Stahlflachproduktes oder auf beiden Seiten des Stahlflachproduktes vorliegen. Die vorliegende Erfindung betrifft daher bevorzugt das erfindungsgemäße Verfahren, wobei der Überzug auf einer Seite des Stahlflachproduktes oder auf beiden Seiten des Stahlflachproduktes, insbesondere auf beiden Seiten des Stahlflach Produktes, vorliegt. According to the invention, the coating may be present on one side of the flat steel product or on both sides of the flat steel product. The present invention therefore preferably relates to the process according to the invention, wherein the coating is present on one side of the flat steel product or on both sides of the flat steel product, in particular on both sides of the flat steel product.
Erfindungsgemäß bevorzugt wird das beschichtete Stahlflachprodukt aus Schritt (A) direkt in den erfindungsgemäßen Verfahrensschritt (B) überführt. Es ist allerdings auch möglich, dass zwischen den Schritten (A) und (B) weitere Schritte durchgeführt werden, beispielsweise Abtrennen von Bereichen, insbesondere Blechen oder Platinen, des Stahlflach Produktes, beispielsweise durch Scherschneiden oder Laserschneiden, Einbringen von Löchern durch Laserbearbeitung oder Stanzen, vorangehende Wärmebehandlungen zur Veränderung der Eigenschaften des Überzugs oder des Substrates, und/oder Einbringen einer Vorumformung. According to the invention, the coated flat steel product from step (A) is preferably transferred directly into the process step (B) according to the invention. However, it is also possible that between the steps (A) and (B) further steps are carried out, for example separation of areas, in particular sheets or blanks of the flat steel product, for example by shearing or laser cutting, introducing holes by laser machining or punching, preceding heat treatments to change the properties of the coating or substrate, and / or to introduce a pre-deformation.
Schritt (B) des erfindungsgemäßen Verfahrens umfasst das Behandeln des Stahlflachproduktes bei einer Ofentemperatur Ti (in K) für eine Dauer ti (in h), so dass pi gemäß der Gleichung der allgemeinen Formel (2) einen Wert von 8 bis 30, bevorzugt von 9 bis 30, besonders bevorzugt von 9 bis 26, ganz besonders bevorzugt von 10 bis 22, aufweist Step (B) of the process according to the invention comprises treating the steel flat product at a furnace temperature Ti (in K) for a duration ti (in h) such that pi in accordance with the equation of the general formula (2) has a value from 8 to 30, preferably from 9 to 30, more preferably 9 to 26, most preferably 10 to 22
Es hat sich erfindungsgemäß herausgestellt, dass besonders vorteilhafte Produkte, insbesondere bezüglich des Biegewinkels α gemäß VDA 238-100, erhalten werden, wenn in Schritt (B) die Wärmebehandlung so durchgeführt wird, dass der in Gleichung (2) genannte Parameter pl einen Wert von 8 bis 30 aufweist. It has been found according to the invention that particularly advantageous products, in particular with respect to the bending angle α according to VDA 238-100, are obtained if in step (B) the heat treatment is carried out such that the parameter p1 mentioned in equation (2) has a value of 8 to 30.
In der Gleichung der allgemeinen Formel (2) bedeutet Ti die Ofentemperatur in Kelvin, d .h . die Temperatur, die im Ofen, in dem Schritt (B) des erfindungsgemäßen Verfahrens durchgeführt wird, vorliegt. Erfindungsgemäß können alle dem Fachmann bekannten Öfen eingesetzt werden, beispielsweise Rollenherdöfen, Kammeröfen, Mehrlagenkammeröfen, Hubbalkenöfen . Ti liegt erfindungsgemäß bevorzugt bei 1070 bis 1350 K, besonders bevorzugt 1100 bis 1250 K, wobei gleichzeitig erfüllt sein muss, dass pl nach Gleichung (2) einen Wert von 9 bis 30 aufweist. Die vorliegende Erfindung betrifft daher bevorzugt das erfindungsgemäße Verfahren, wobei Ti bei 1070 bis 1350 K, besonders bevorzugt 1100 bis 1250 K, beträgt. In the equation of the general formula (2), Ti means the furnace temperature in Kelvin, ie. the temperature, which is carried out in the oven, in the step (B) of the method according to the invention is present. According to the invention, it is possible to use all ovens known to the person skilled in the art, for example roller hearth furnaces, chamber furnaces, multilayer chamber furnaces, lifting beam furnaces. According to the invention, Ti is preferably from 1070 to 1350 K, particularly preferably from 1100 to 1250 K, wherein it must be satisfied at the same time that pl has a value of from 9 to 30 according to equation (2). The present invention therefore preferably relates to the process according to the invention, Ti being from 1070 to 1350 K, particularly preferably from 1100 to 1250 K.
In der Gleichung der allgemeinen Formel (2) bedeutet ti die Dauer, für die das Stahlflachprodukt der entsprechenden Temperatur Ti ausgesetzt ist. Bevorzugt ist dies der Zeitraum vom Einfahren/Einlegen der Probe in den Ofen bis zum Ausfahren/zur Entnahme der Probe aus dem Ofen. Erfindungsgemäß wird ti in Stunden (h) angegeben, ti liegt erfindungsgemäß bevorzugt bei 0,02 bis 0,50 h, besonders bevorzugt 0,04 bis 0,50 h, wobei gleichzeitig erfüllt sein muss, dass pi nach Gleichung (2) einen Wert von 8 bis 30, bevorzugt von 9 bis 30, besonders bevorzugt von 9 bis 26, ganz besonders bevorzugt von 10 bis 22, aufweist. Die vorliegende Erfindung betrifft daher bevorzugt das erfindungsgemäße Verfahren, wobei ti 0,02 bis 0,50 h, besonders bevorzugt 0,04 bis 0,50 h, beträgt. In the equation of the general formula (2), ti is the duration for which the flat steel product is exposed to the corresponding temperature Ti. This is preferably the period from retraction / insertion of the sample in the oven to the extension / removal of the sample from the oven. According to the invention, ti is given in hours (h), ti according to the invention is preferably 0.02 to 0.50 h, more preferably 0.04 to 0.50 h, wherein it must be satisfied at the same time that pi has a value according to equation (2) from 8 to 30, preferably from 9 to 30, more preferably from 9 to 26, most preferably from 10 to 22 having. The present invention therefore preferably relates to the process according to the invention, where ti is 0.02 to 0.50 h, more preferably 0.04 to 0.50 h.
Erfindungsgemäß ist es möglich, dass während Schritt (B) über die gesamte Zeit ti eine konstante Temperatur Ti vorherrscht. Es ist erfindungsgemäß auch möglich, dass innerhalb der Zeit ti Temperaturen Ti vorliegen, die nicht konstant sind, beispielweise liegt in einem Teil (a) des Zeitraums ti (tla) eine Temperatur Tia vor, in einem weiteren Teil (b) des Zeitraums ti (tlb) liegt eine Temperatur Tlb, und in einem weiteren Teil (c) des Zeitraums ti (tlc) liegt eine Temperatur Tlc etc., vor. In dieser Ausführungsform wird in die Gleichung der allgemeinen Formel (2) der entsprechende Zeitraum ti (ti=tla+tlb+tlc+ ...) und der arithmetische Mittelwert der entsprechend zugehörigen Temperaturen, beispielsweise Tla, Tlb, Tlc etc , für Ti eingesetzt, sofern die Temperatur des Ofens 550 °C überschreitet. According to the invention, it is possible for a constant temperature Ti to prevail during step (B) over the entire time ti. It is also possible according to the invention for temperatures Ti to be present within the time ti which are not constant, for example in one part (a) of the period ti (t la ) there is a temperature Ti a in a further part (b) of the period ti (t lb ) is a temperature T lb , and in a further part (c) of the period ti (t lc ) is a temperature T lc, etc., before. In this embodiment, in the equation of the general formula (2), the corresponding period ti (ti = t la + t lb + t lc + ...) and the arithmetic mean of the corresponding associated temperatures, for example, T la , T lb , T lc etc, used for Ti, if the temperature of the oven exceeds 550 ° C.
Bei Werten von pi unterhalb von 9 liegt der arithmetische Mittenrauwert Ra in einem Bereich, der die weiteren Verarbeitungseigenschaften negativ beeinflussen kann, beispielsweise tribologische Eigenschaften bei der Umformung, Wärmeübergang, Lackierbarkeit. At values of pi below 9, the arithmetic mean roughness R a is in a range which can negatively influence the further processing properties, for example tribological properties during forming, heat transfer, paintability.
Während Schritt (B) des erfindungsgemäßen Verfahrens, insbesondere der Zeitraum vom Einfahren/Einlegen der Probe in den Ofen bis zum Ausfahren/zur Entnahme der Probe aus dem Ofen, kommt es zur Ausbildung eines erfindungsgemäß gewünschten arithmetischen Mittenrauwertes Ra. Dieser kann nach dem Fachmann bekannten Verfahren bestimmt werden, bevorzugt wird der arithmetische Mittenrauwert Ra nach DIN EN 10049:2014-03 in μιη bestimmt, besonders bevorzugt als Durchschnittswert aus 40 Messungen bei beidseitig beschichteten Proben, 20 auf jeder Seite der Proben, jeweils quer zur Walzrichtung der Probe. Bei einseitig beschichteten Proben erfolgt die Messung nur auf der beschichteten Seite. During step (B) of the process according to the invention, in particular the period from the introduction / insertion of the sample into the oven until the sample is extracted / removed from the oven, a desired arithmetic mean roughness value R a is achieved . This can be determined by methods known to those skilled in the art, preferably the arithmetic mean roughness R a is determined according to DIN EN 10049: 2014-03 in μιη, particularly preferably as an average value of 40 measurements for samples coated on both sides, 20 on each side of the samples, each transverse to the rolling direction of the sample. For samples coated on one side, the measurement is made only on the coated side.
In einer bevorzugten Ausführungsform des erfindungsgemäßen Verfahrens wird in einem weiteren Verfahrensschritt zwischen Schritt (A) und Schritt (B) an das Stahlflachprodukt zumindest ein besonderer Bereich angefügt oder weiter ausgearbeitet, so dass der besondere Bereich zumindest eines der Attribute Auflagegewicht, Blechdicke, chemische Zusammensetzung, aufweist, das abweichend von dem Stahlflachprodukt vor diesem weiteren Verfahrensschritt ist, wobei die Gleichung der allgemeinen Formel (1) nur für die Bereiche gilt, die im ursprünglichen Stahlflachprodukt bereits vorhanden waren, wodurch bevorzugt abweichende mechanische Eigenschaften erzielt werden . In einer anderen bevorzugten Ausführungsform des erfindungsgemäßen Verfahrens wird in einem weiteren Verfahrensschritt in Schritt (C) zumindest ein besonderer Bereich des Stahlflachproduktes weiter ausgearbeitet, so dass der besondere Bereich andere Abkühlbedingungen im Werkzeug (z.B. durch lokale Erwärmung des Werkzeugs) erfährt, als in einem üblichen Presshärteprozess (mit auf < 100°C gekühlten Werkzeugen), wobei die Gleichung der allgemeinen Formel (1) nur für die Bereiche gilt, die mittels üblichem Presshärteprozess erzeugt wurden, wodurch bevorzugt abweichende mechanische Eigenschaften erzielt werden . Diese Ausführungsformen sind dem Fachmann als sogenannte Tailored Blanks, z.B. Tailor-Welded Blanks, Tailor-Rolled Blanks, Tailored Tempering, bekannt. In a preferred embodiment of the method according to the invention, in a further method step between step (A) and step (B) to the flat steel product at least one particular Range added or further elaborated, so that the particular area of at least one of the attributes of support weight, sheet thickness, chemical composition, which is different from the flat steel product before this further process step, wherein the equation of the general formula (1) applies only to the areas which were already present in the original flat steel product, whereby preferably different mechanical properties are achieved. In another preferred embodiment of the method according to the invention, in a further process step in step (C) at least one particular area of the flat steel product is further developed so that the particular area experiences other cooling conditions in the tool (eg by local heating of the tool) than in a conventional one Press hardening process (with tools cooled to <100 ° C), wherein the equation of the general formula (1) applies only to the areas produced by the usual press hardening process, whereby preferably different mechanical properties are obtained. These embodiments are known to the person skilled in the art as tailored blanks, for example tailor-welded blanks, tailor-rolled blanks, tailored tempering.
In einer besonders bevorzugten Ausführungsform wird das Stahlflachprodukt in dem weiteren Verfahrensschritt in zumindest einem Bereich durch ein zusätzlich aufgebrachtes, anderes oder gleichartiges Stahlflachprodukt (z.B. durch Fügen) verstärkt bzw. dicker ausgeführt, als in den nicht verstärkten Bereichen . In a particularly preferred embodiment, in the further process step, the flat steel product is reinforced in at least one area by an additionally applied, different or similar flat steel product (for example by joining), than in the unreinforced areas.
Schritt (C) des erfindungsgemäßen Verfahrens umfasst das Umformen des aufgeheizten Stahlflachproduktes aus Schritt (B) in einem Formwerkzeug unter gleichzeitigem Abkühlen, um das Stahlbauteil zu erhalten. Step (C) of the process of the invention comprises forming the heated flat steel product of step (B) in a mold while cooling to obtain the steel component.
Im Allgemeinen können in Schritt (C) des erfindungsgemäßen Verfahrens alle dem Fachmann bekannten Verfahren zum Warmumformen eingesetzt werden, beispielsweise beschrieben in Warmumformung im Automobilbau - Verfahren, Werkstoffe, Oberflächen, Landsberg/Lech: Verl. Moderne Industrie, 2012, Die Bibliothek der Technik. In general, in step (C) of the process according to the invention, all processes known to the person skilled in the art can be used for hot forming, for example described in hot forming in automotive engineering - processes, materials, surfaces, Landsberg / Lech: Verl. Moderne Industrie, 2012, Die Bibliothek der Technik.
In Schritt (C) des erfindungsgemäßen Verfahrens wird aus dem Stahlflachprodukt aus Schritt (B) durch Umformen das gewünschte Stahlbauteil erhalten. Damit sich in dem Stahlbauteil das gewünschte Härte- gefüge, d .h . mindestens 80% Martensit, Rest Bainit, Ferrit und Restaustenit, ausbildet, erfolgt das Umformen unter gleichzeitigem Abkühlen . Das Abkühlen in Schritt (C) des erfindungsgemäßen Verfahrens erfolgt dabei bevorzugt mit einer Rate von 27 bis 1000 K/s, bevorzugt 50 bis 500 K/s. Die vorliegende Erfindung betrifft daher bevorzugt das erfindungsgemäße Verfahren, wobei das Abkühlen in Schritt (C) bei einer Abkühlrate von 27 bis 1000 K/s erfolgt. Durch das erfindungsgemäße Verfahren wird ein Stahlbauteil erhalten, umfassend ein Substrat und einen Überzug, wobei der Biegewinkel α (in °) des Stahlbauteils und der arithmetische Mittenrauwert Ra In step (C) of the process according to the invention, the desired steel component is obtained from the flat steel product from step (B) by forming. Thus, in the steel component, the desired hardness structure, ie. At least 80% martensite, the remainder bainite, ferrite and retained austenite, is formed, the forming takes place with simultaneous cooling. The cooling in step (C) of the process according to the invention is preferably carried out at a rate of 27 to 1000 K / s, preferably 50 to 500 K / s. The present invention therefore preferably relates to the process according to the invention, wherein the cooling in step (C) takes place at a cooling rate of 27 to 1000 K / s. By the method according to the invention, a steel component is obtained, comprising a substrate and a coating, wherein the bending angle α (in °) of the steel component and the arithmetic mean roughness R a
(in μηι) nach DIN EN 10049:2014-03 gemäß der allgemeinen Formel (1) miteinander verknüpft sind . In der allgemeinen Formel (1) bedeutet α den Biegewinkel gemäß VDA 238- 100, den das erfindungsgemäß hergestellte Stahlbauteil aufweist. (in μηι) according to DIN EN 10049: 2014-03 according to the general formula (1) linked together. In the general formula (1), α means the bending angle according to VDA 238-100, which the steel component produced according to the invention has.
Der in Gleichung (1) angegebene Biegewinkel α wird erfindungsgemäß mit der Probenlage Längs, d.h. Biegeachse Quer zur Walzrichtung, bestimmt. Wird der in Gleichung (1) angegebene Biegewinkel α erfindungsgemäß mit der Probenlage Quer, d .h. Biegeachse Längs zur Walzrichtung bestimmt, so sind aufgrund der Werkstoffanisotropie die ermittelten Werte ca . 6,5% niedriger. Ebenfalls können sich für andere Probenlagen (z.B. Diagonal) etwas abweichende Biegewinkel zeigen, wobei die Abweichungen bevorzugt zwischen denen aus Längs- und Querlage, d .h . zwischen 0 und 6,5% liegen . Die Werte spiegeln in ihrer gesamten Tendenz den Zusammenhang gemäß Gleichung (1) wieder. Daher gilt die Gleichung (1) erfindungsgemäß bevorzugt für Biegewinkel a, die mit der Probenlage Längs, d.h . Biegeachse Quer zur Walzrichtung, bestimmt worden sind. The bending angle α indicated in equation (1) is determined according to the invention with the longitudinal direction of the sample. Bending axis Transverse to rolling direction. If the bending angle α stated in equation (1) is determined according to the invention with the sample position transverse, that is to say, Bending axis Longitudinally determined to the rolling direction, due to the material anisotropy the determined values are approx. 6.5% lower. Also, for other sample plies (e.g., diagonal), slightly different bending angles may be seen, with the deviations preferably between those of the longitudinal and transverse plies, i. between 0 and 6.5%. The values reflect in their overall tendency the relationship according to equation (1) again. Therefore, the equation (1) according to the invention is preferably for bending angle a, with the longitudinal direction of the sample, ie. Bending axis transverse to the rolling direction.
Die Crasheignung eines Stahlbauteils hängt wesentlich von dem im„Plättchen-Biegeversuch für metallische Werkstoffe" (VDA238-100) gemessenen Biegewinkel α bei Kraftmaximum ab (siehe dazu Till Laumann; Qualitative und quantitative Bewertung der Crashtauglichkeit von höchstfesten Stählen; Meisenbach Verlag Bamberg, 2010 (ISBN 978-3-87525-299-6)). Hohe Biegewinkel stehen dabei für eine gute Crasheignung . The crash suitability of a steel component depends essentially on the bending angle α at maximum force measured in the "flake bending test for metallic materials" (see Till Laumann, Qualitative and quantitative assessment of the crashworthiness of high-strength steels, Meisenbach Verlag Bamberg, 2010 ( ISBN 978-3-87525-299-6)). High bending angles stand for a good crash suitability.
In der allgemeinen Gleichung (2) bedeutet Ra den arithmetischen Mittenrauwert und wird in μιη angegeben . In general equation (2), R a represents the arithmetic mean roughness and is expressed in μιη.
Bevorzugt beträgt in dem erfindungsgemäß hergestellten Stahlbauteil der arithmetische Mittenrauwert Ra nach DIN EN 10049:2014-03 1 ,30 bis 2,30 μιη, bevorzugt 1 ,50 bis 2,22 μιη, besonders bevorzugt 1 ,60 bis 2, 10 μιη und der Biegewinkel α nach VDA 238-100 beträgt 54 bis 70°, bevorzugt 54 bis 66°, besonders bevorzugt 54 bis 62°, wobei die Werte erfindungsgemäß so miteinander verknüpft sein müssen, dass die Gleichung der allgemeinen Formel (1) gilt. Preferably, in the steel component according to the invention, the arithmetic mean roughness R a according to DIN EN 10049: 2014-03 is 1, 30 to 2.30 μm, preferably 1.50 to 2.22 μm, particularly preferably 1.60 to 2.10 μm and the bending angle α according to VDA 238-100 is 54 to 70 °, preferably 54 to 66 °, particularly preferably 54 to 62 °, wherein the values according to the invention must be linked together so that the equation of the general formula (1) applies.
Die vorliegende Erfindung betrifft auch ein Stahlbauteil umfassend ein Substrat enthaltend (alle Angaben in Gew.-%) 0, 15 bis 0,50 bevorzugt 0,20 bis 0,30, besonders bevorzugt 0,21 bis 0,25 C, The present invention also relates to a steel component comprising a substrate (all data in% by weight) 0.15 to 0.50, preferably 0.20 to 0.30, particularly preferably 0.21 to 0.25 C,
0,50 bis 3,0, bevorzugt 0,80 bis 2,00, besonders bevorzugt 1 ,00 bis 1,50 Mn, 0.50 to 3.0, preferably 0.80 to 2.00, particularly preferably 1.00 to 1.50 Mn,
0, 10 bis 0,50, bevorzugt 0, 15 bis 0,40, besonders bevorzugt 0,20 bis 0,30 Si, 0.10 to 0.50, preferably 0.15 to 0.40, particularly preferably 0.20 to 0.30 Si,
0,01 bis 1 ,00, bevorzugt 0, 10 bis 0,5, besonders bevorzugt 0, 10 bis 0,40 Cr, 0.01 to 1, 00, preferably 0, 10 to 0.5, particularly preferably 0, 10 to 0.40 Cr,
bis zu 0,20, bevorzugt 0,01 bis 0, 10, besonders bevorzugt 0,01 bis 0,04 Ti, up to 0.20, preferably 0.01 to 0, 10, particularly preferably 0.01 to 0.04, Ti,
bis zu 0, 10, bevorzugt 0,01 bis 0,05, besonders bevorzugt 0,02 bis 0,05 AI, up to 0, 10, preferably 0.01 to 0.05, particularly prefers 0.02 to 0.05 AI,
bis zu 0, 10, bevorzugt 0,00 bis 0,05, besonders bevorzugt 0,00 bis 0,02 P, up to 0.10, preferably 0.00 to 0.05, particularly preferably 0.00 to 0.02 P,
bis zu 0, 1 , bevorzugt 0,001 bis 0, 1 Nb, up to 0, 1, preferably 0.001 to 0, 1 Nb,
bis zu 0,01 N, up to 0.01 N,
bis zu 0,05, bevorzugt 0,00 bis 0,005, besonders bevorzugt 0,00 bis 0,003 S und up to 0.05, preferably 0.00 to 0.005, more preferably 0.00 to 0.003 S and
bis zu 0, 1 , bevorzugt 0,001 bis 0,05, besonders bevorzugt 0,002 bis 0,0035 B, up to 0.1, preferably 0.001 to 0.05, particularly preferably 0.002 to 0.0035 B,
Rest Fe und unvermeidbare Verunreinigungen, und einen Überzug enthaltend (alle Angaben in Gew.-%) Balance Fe and unavoidable impurities, and containing a coating (all figures in% by weight)
3 bis 15 Si, 3 to 15 Si,
1 bis 3,5 Fe, 1 to 3.5 Fe,
bis zu 0,5 Alkali- und/oder Erdalkalimetalle, up to 0.5 alkali and / or alkaline earth metals,
Rest AI und unvermeidbare Verunreinigungen, wobei der Biegewinkel a des Stahlbauteils (in °) und der arithmetische Mittenrauwert Ra (in μιη) nach DI N EN 10049:2014-03 gemäß der allgemeinen Formel (1) miteinander verknüpft sind . Bevorzugt wird dieses erfindungsgemäße Stahlbauteil durch das erfindungsgemäße Verfahren erhalten. Rest AI and unavoidable impurities, the bending angle a of the steel component (in °) and the arithmetic mean roughness R a (in μιη) according to DI N EN 10049: 2014-03 according to the general formula (1) linked together. Preferably, this steel component according to the invention is obtained by the method according to the invention.
Insbesondere betrifft die vorliegende Erfindung das erfindungsgemäße Stahlbauteil, wobei es durch Umformen eines entsprechenden Stahlflachproduktes erhalten wird, wobei das Stahlflachprodukt vor dem Umformen bei einer Ofentemperatur T1 (in K) für eine Dauert ti (in h) behandelt worden ist, so dass p1 gemäß der Gleichung der allgemeinen Formel (2) einen Wert von 8 bis 30, bevorzugt von 9 bis 30, besonders bevorzugt von 9 bis 26, ganz besonders bevorzugt von 10 bis 22, aufweist In particular, the present invention relates to the steel component according to the invention, wherein it is obtained by forming a corresponding flat steel product, wherein the flat steel product has been treated prior to forming at a furnace temperature T 1 (in K) for a duration ti (in h) such that p 1 according to the equation of general formula (2) has a value of 8 to 30, preferably from 9 to 30, particularly preferably from 9 to 26, very particularly preferably from 10 to 22, having
Weiter bevorzugt betrifft die vorliegende Erfindung das erfindungsgemäße Stahlbauteil, wobei das Auflagegewicht des beidseitigen Überzugs 30 bis 360 g/m2, bevorzugt 100 bis 200 g/m2, besonders bevorzugt 120 bis 180 g/m2, beispielsweise 150 g/m2, beträgt. More preferably, the present invention relates to the steel component according to the invention, wherein the coating weight of the double-sided coating 30 to 360 g / m2, preferably 100 to 200 g / m 2 , particularly preferably 120 to 180 g / m 2 , for example 150 g / m 2 ,
Bezüglich der einzelnen Merkmale des erfindungsgemäßen Stahlbauteils und der bevorzugten Ausführungsformen gilt das bezüglich des erfindungsgemäßen Verfahrens Gesagte entsprechend . With regard to the individual features of the steel component according to the invention and the preferred embodiments, what has been said regarding the method according to the invention applies correspondingly.
Die vorliegende Erfindung betrifft auch ein Stahlbauteil enthaltend (alle Angaben in Gew.-%) The present invention also relates to a steel component containing (all data in% by weight)
0, 15 bis 0,50 C, 0.15 to 0.50 C,
0,50 bis 3,0 Mn, 0.50 to 3.0 Mn,
0, 10 bis 0,50 Si, 0, 10 to 0.50 Si,
0,01 bis 1 ,00 Cr, 0.01 to 1.00 Cr,
bis zu 0,20 Ti, up to 0.20 Ti,
bis zu 0, 10 AI, up to 0, 10 AI,
bis zu 0, 10 P, up to 0, 10 P,
bis zu 0, 1 Nb, up to 0, 1 Nb,
bis zu 0,01 N, up to 0.01 N,
bis zu 0,05 S und up to 0.05 S and
bis zu 0, 1 B, up to 0, 1 B,
Rest Fe und unvermeidbare Verunreinigungen als Substrat, mit einem Überzug enthaltend (alle Angaben in Gew.-%) Residual Fe and unavoidable impurities as substrate, containing a coating (all data in% by weight)
3 bis 15 Si, 3 to 15 Si,
1 bis 3,5 Fe, 1 to 3.5 Fe,
bis zu 0,5 Alkali- und/oder Erdalkalimetalle, up to 0.5 alkali and / or alkaline earth metals,
Rest AI und unvermeidbare Verunreinigungen, wobei es nach dem Presshärten einen arithmetischen Mittenrauwert Ra nach DI N EN 10049:2014-03 von 1,30 bis 2,30 μιτι aufweist. Rest AI and unavoidable impurities, wherein it has an arithmetic average roughness R a according to DI N EN 10049: 2014-03 of 1.30 to 2.30 μιτι after press hardening.
Die vorliegende Erfindung betrifft auch die Verwendung eines erfindungsgemäßen beschichteten Stahlbauteils im Automobilsektor, insbesondere als Stoßstangenträger/-verstärkung, Türverstärkung, B-Säulen-Verstärkung, A-Säulen-Verstärkung, Dachrahmen oder Schweller. Bezüglich der einzelnen Merkmale der erfindungsgemäßen Verwendung und der bevorzugten Ausführungsformen gilt das bezüglich des erfindungsgemäßen Verfahrens Gesagte entsprechend . The present invention also relates to the use of a coated steel component according to the invention in the automotive sector, in particular as a bumper support / reinforcement, door reinforcement, B-pillar reinforcement, A-pillar reinforcement, roof frame or sill. With regard to the individual features of the use according to the invention and of the preferred embodiments, what has been said regarding the method according to the invention applies correspondingly.
Figuren characters
Figur 1 zeigt eine beispielhafte Topographiemessung in überhöhter Darstellung zur Veranschaulichung der Oberflächenrauheit. FIG. 1 shows an exemplary topography measurement in an exaggerated representation to illustrate the surface roughness.
Figur 2 zeigt eine beispielhafte Darstellung (Schliffbild) von zwei verschiedenen Topologien an der Oberfläche von erfindungsgemäßen Stahlbauteilen, darin bedeuten : FIG. 2 shows an exemplary illustration (micrograph) of two different topologies on the surface of steel components according to the invention, in which:
(1) Einbettmasse, welche zur Erzeugung des Schliffbildes erforderlich ist (1) investment, which is required to produce the microsection
(2) Oberflächenprofil, welches zur Messung des arithmetischen Mitten rauwertes abgetastet werden kann (2) Surface profile which can be scanned to measure the rough arithmetic mean
(3) AlSi-Überzug an der Oberfläche des beschichteten Stahlflachproduktes (3) AlSi coating on the surface of the coated flat steel product
Beispiele Examples
Die nachfolgenden Ausführungsbeispiele dienen der näheren Erläuterung der Erfindung . The following embodiments serve to illustrate the invention.
Es werden Stahlflachprodukte (Kaltband) der in Tabelle 1 genannten Analyse in Form von Platinen eingesetzt. Dabei wurde das Kaltband beschichtet und die Platinen herausgetrennt. Bei dem Überzug der exemplarisch eingesetzten Stahlflachprodukte handelt es sich um einen so genannte AlSi-Überzug der unter anderem durch Feuerbeschichten eingestellt werden kann, der aus 9 bis 10 Gew.-% Si, 2 bis 3,5 Gew.-% Eisen, Rest Aluminium besteht. Die so beschaffenen und beschichteten Stahlflachprodukte werden auf eine Temperatur Ti (siehe Tabelle) für eine Dauer ti (siehe Tabelle) erwärmt, anschließend in ein Pressformwerkzeug eingelegt, dort warm zu dem Stahlbauteil geformt und dabei so schnell wie möglich durch den Kontakt mit einem üblichen Warmumformwerkzeug innerhalb von ca . 15 Sekunden abgekühlt, dass ein Härtegefüge (mit einem Martensitanteil von mind . 80%, Rest: Bainit (0-20%), Restaustenit (0-5%), Ferrit (0-5%) im Stahlsubstrat des Stahlflachprodukts entsteht. Das Presshärten erfolgt bei folgenden Prozessparametern: Taupunkt < 278, 15 K, Transferzeit Ofen zu Werkzeug 6 s, Schließdauer des Werkzeugs 15 s. Steel flat products (cold strip) of the analysis mentioned in Table 1 are used in the form of blanks. The cold strip was coated and the boards were cut out. The coating of the flat steel products used by way of example is a so-called AlSi coating which can be adjusted, inter alia, by fire coating, consisting of 9 to 10 wt.% Si, 2 to 3.5 wt.% Iron, balance aluminum consists. The thus obtained and coated flat steel products are heated to a temperature Ti (see table) for a duration ti (see table), then placed in a press mold, where they are hot formed to the steel component and as quickly as possible by contact with a conventional hot forming tool within approx. Cooled for 15 seconds to produce a hardened structure (with a martensite content of at least 80%, balance: bainite (0-20%), retained austenite (0-5%), ferrite (0-5%) in the steel substrate of the flat steel product takes place at the following process parameters: dew point <278, 15 K, transfer time furnace to tool 6 s, closing time of the tool 15 s.
Für die Versuche werden Ofentemperatur T Ofenverweildauer ti, Blechdicke und Auflagegewicht variiert und dementsprechend Proben für den Biegeversuch hergestellt. Die Messung erfolgt an jeweils 5 Proben mit gleichen Verarbeitungseigenschaften im Biegeversuch nach VDA238-100 (Probenlage„Längs" , d.h . Biegeachse quer zur Walzrichtung). Aus den 5 Proben wird das arithmetische Mittel gebildet. Der arithmetische Mittenrauwert Ra wird in μιτι als Durchschnittswert aus 40 Messungen, 20 auf Ober- und Unterseite der Proben, jeweils quer zur Walzrichtung der Probe bestimmt. Die Bestimmung erfolgt nach DIN EN 10049:2014-03 (Ac = 2,5 mm, Tastnadel R = 5 μιη). For the experiments oven temperature T oven residence time ti, plate thickness and coating weight are varied and accordingly samples are prepared for the bending test. The measurement is carried out on 5 samples each The arithmetic mean is formed from the 5 samples, the average arithmetic mean R a being calculated in μιτι from 40 measurements, 20 to upper and underside of the samples, each transverse to the direction of rolling of the sample, determined in accordance with DIN EN 10049: 2014-03 (A c = 2.5 mm, stylus R = 5 μm).
Tabelle 1 : Zusammensetzung der eingesetzten Schmelze, aller Angaben in Gew.-%, Rest Fe Table 1: Composition of the melt used, all data in wt .-%, balance Fe
In Tabelle 2 werden die Prozessparameter und die erhaltenen Biegewinkel angegeben. Tabelle 2: Prozessparameter und erhaltene Biegewinkel Table 2 shows the process parameters and the resulting bending angles. Table 2: Process parameters and obtained bending angles
V9 1233 0, 1667 33,3 1,66 50,3 V9 1233 0, 1667 33.3 1.66 50.3
V Vergleichsversuch V comparative experiment
Ti Ofentemperatur Ti oven temperature
tl Ofenverweildauer tl oven residence time
Pi skalarer Produktionsparameter Pi scalar production parameter
a arithmetischer Mittenrauwert a arithmetic mean roughness
α Biegewinkel nach VDA238-100 (Probenlage längs, d .h. Biegeachse quer zur Walzrichtung) α Bending angle according to VDA238-100 (longitudinal sample location, ie bending axis transverse to rolling direction)
Gewerbliche Anwendbarkeit Industrial Applicability
Das erfindungsgemäß hergestellte Stahlbauteil weist ein verbessertes Crashverhalten auf und kann daher vorteilhaft im Automobilsektor verwendet werden. The steel component produced according to the invention has an improved crash behavior and can therefore be used advantageously in the automotive sector.
Claims
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| ATE468417T1 (en) * | 1999-03-19 | 2010-06-15 | Nippon Steel Corp | SURFACE TREATED STEEL PRODUCT PROVIDED WITH TIN OR ALUMINUM BASED PLATING |
| DE102007061489A1 (en) * | 2007-12-20 | 2009-06-25 | Voestalpine Stahl Gmbh | Process for producing hardened hardenable steel components and hardenable steel strip therefor |
| DE102009007909A1 (en) * | 2009-02-06 | 2010-08-12 | Thyssenkrupp Steel Europe Ag | A method of producing a steel component by thermoforming and by hot working steel component |
| ES2813870T3 (en) * | 2014-09-05 | 2021-03-25 | Thyssenkrupp Steel Europe Ag | Flat steel product with an Al coating, procedure for its manufacture and procedure for the manufacture of a hot-formed constructive element |
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2017
- 2017-07-10 DE DE102017211753.2A patent/DE102017211753A1/en not_active Withdrawn
- 2017-10-20 CN CN201710983637.0A patent/CN109234641A/en active Pending
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2018
- 2018-06-26 EP EP18745498.8A patent/EP3652351A1/en not_active Withdrawn
- 2018-06-26 WO PCT/EP2018/067051 patent/WO2019011644A1/en not_active Ceased
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Also Published As
| Publication number | Publication date |
|---|---|
| DE102017211753A1 (en) | 2019-01-10 |
| CN109234641A (en) | 2019-01-18 |
| EP3652351A1 (en) | 2020-05-20 |
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