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WO2019098608A2 - Composition de coloration capillaire oxydante - Google Patents

Composition de coloration capillaire oxydante Download PDF

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Publication number
WO2019098608A2
WO2019098608A2 PCT/KR2018/013605 KR2018013605W WO2019098608A2 WO 2019098608 A2 WO2019098608 A2 WO 2019098608A2 KR 2018013605 W KR2018013605 W KR 2018013605W WO 2019098608 A2 WO2019098608 A2 WO 2019098608A2
Authority
WO
WIPO (PCT)
Prior art keywords
agent
alcohol
ammonia
sorbitan
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2018/013605
Other languages
English (en)
Korean (ko)
Other versions
WO2019098608A3 (fr
Inventor
박재정
지제현
김종협
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Amorepacific Corp
Original Assignee
Amorepacific Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020180130995A external-priority patent/KR102371926B1/ko
Application filed by Amorepacific Corp filed Critical Amorepacific Corp
Priority to CN201880062426.6A priority Critical patent/CN111132655B/zh
Publication of WO2019098608A2 publication Critical patent/WO2019098608A2/fr
Publication of WO2019098608A3 publication Critical patent/WO2019098608A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/604—Alkylpolyglycosides; Derivatives thereof, e.g. esters

Definitions

  • the present invention relates to an oxidation type hair dye composition
  • an oxidation type hair dye composition comprising a mixture of a higher aliphatic alcohol, a sorbitan-based surfactant and a glucose-based surfactant as an active ingredient, Type hair dye composition.
  • hair decolorizing agents and hair dyeing agents are oxidants of peroxides such as hydrogene peroxide, urea peroxide, and melamine phehydrate, which act to discolor hair.
  • Ammonia is an effective activator that accelerates the action of these peroxides to discolor and dye hair, that is, the oxidative destruction of melanin, and increases the oxidation coupling ratio of the dye.
  • the pH must be adjusted to the alkaline side for the hydrogen peroxide water to work effectively with hair bleach. This pH control effect can be achieved with other alkalis, but ammonia is the most preferred alkaline agent because it acts effectively on both activator effect and pH control effect, and can be easily removed after swelling of hair and dyeing. Because of this effect, ammonia is the most commonly used hair bleaching agent or hair dye.
  • Ammonia which is a highly volatile alkaline agent, generates irritating odor peculiar to ammonia when mixed with the first agent and the second agent or applied to the hair, thereby causing eye irritation and skin irritation as well as a very unpleasant odor, .
  • ammonia is the most universally used Lt; / RTI > Therefore, it is very important to reduce ammonia irritation.
  • ammonia deodorization deodorizing
  • ammonia is chemically neutralized by mixing an appropriate acid-basic component to chemically neutralize the source of offensive odor
  • Eporion N7C is commercially available.
  • the content of ammonia itself is reduced, thereby deteriorating the original purpose of using ammonia in the hair dye.
  • An object of the present invention is to provide an oxidative hair dye composition which is remarkably improved in irritating and unpleasant odor derived from an ammonia component incorporated in an oxidative hair dye composition.
  • the inventors of the present invention have intensively investigated a substance having excellent stimulating and unpleasant odor-evoking effects derived from the ammonia component blended in the hair dye composition and a combination thereof.
  • the high aliphatic alcohol, sorbitan series surfactant It has been found that the addition of a mixture of glucose-based surfactants to a hair dye formulation containing ammonia (such as an aqueous ammonia solution) not only significantly improves the deodorizing effect of the ammonia odor but also maintains such deodorant effect for a prolonged period of time.
  • an oxidized hair dye composition comprising a first agent and a second agent
  • a material for generating ammonia as an alkaline agent in the first agent is a material for generating ammonia as an alkaline agent in the first agent
  • the present invention provides an oxidation type hair dye composition excellent in deodorization effect of ammonia odor, which comprises as an active ingredient, a mixture composed of a high-grade aliphatic alcohol, a sorbitan-based surfactant and a glucose-based surfactant.
  • the oxidation type hair dye composition according to the present invention is applicable to a hair dye cosmetic product having excellent deodorizing effect of ammonia odor and causing ammonia odor.
  • the term “about" used to describe length, area, volume, time (period), concentration, capacity (content etc.), temperature, etc. means that there is a maximum tolerance of 10% it means.
  • an oxidized hair dye composition comprising a first agent and a second agent
  • a material for generating ammonia as an alkaline agent in the first agent is a material for generating ammonia as an alkaline agent in the first agent
  • a high aliphatic alcohol, a sorbitan-based surfactant, and a glucose-based surfactant as an active ingredient.
  • the first agent may further contain a conventional oxidation dye precursor and a coupler, preferably two or more oxidation dye precursors and couplers, and may contain most of the oxidation dye precursors and couplers presently known have.
  • the type of the oxidation dye precursor is not particularly limited, and examples thereof include o-aminophenol, p-aminophenol, m-aminophenol, p-phenylenediamine, toluene-2,5-diamine hydrochloride, , Toluene-2,5-diamine, p-phenylenediamine sulfate, p-methylaminophenol sulfate, o-aminophenol sulfate, p-aminophenol sulfate, toluene-2,5-diamine sulfate, , And the oxidation dye precursor is used in an amount of 0.001 to 5.0% by weight based on the total weight of the first composition.
  • the coupler there may be mentioned 2-methyl-5-hydroxyethylaminophenol, p-amino-ocresol, m-aminophenol, 2,4-diaminophenoxyethanol hydrochloride, m- m-phenylenediamine,? -naphthol, resorcinol, 2-methylresorcinol, etc., and the coupler is used in an amount of 0.001 to 5.0% by weight based on the total weight of the first composition, And can be used in combination with the oxidation dye precursor to exhibit various hues on the hair.
  • the direct dye may be added to the oxidative dye composition of the present invention to the extent that it does not impair the object of the present invention.
  • Examples of such direct dyes include Arianol dye, p- Nitro-phenylenediamine, nitro-p-phenylenediamine, 2-amino-4-nitrophenol, 2-amino-5-nitrophenol, nitro-p-phenylenediamine hydrochloride, Henna and the like can be used.
  • the oxidizing type hair dye composition of the present invention can be used within a range that does not impair the effect of the present invention.
  • antioxidants, metal sequestrants, solvents, surfactants, thickeners, perfumes, and conditioning agents are used, but they are not particularly limited as they can be commonly used in hair dyeing agents.
  • the metal blockade agent may not contain the metal salt in the composition of the present invention or may contain a very small amount because the metal salt is deteriorated in reactivity.
  • the metal sequestering agent include EDTA, disodium iodide, tetrasodium-idtite, pentasodium pentitate, etidronic acid, and salts thereof.
  • antioxidant examples include ascorbic acid, erythorbic acid, cysteine hydrochloride, sodium sulfite and thioglycolic acid.
  • solvent examples include ethanol, propyl alcohol, isopropyl alcohol, propylene glycol, hexylene glycol, diethylene glycol
  • a cationic surfactant an anionic surfactant or a nonionic surfactant can be used.
  • thickener a higher alcohol having 14 to 22 carbon atoms can be used singly or as a mixture.
  • Nonionic Polymer and anionic polymer, paraffin, light flowing isoparaffin and the like can be used.
  • conditioning agent a cationic polymer, quaternary ammonium salt, silicon or the like can be used.
  • the second agent contains an oxidizing agent.
  • an oxidizing agent at least one selected from the group consisting of hydrogen peroxide, peroxide element, alkali metal bromate, pericyanide, perborate and persulfate commonly used in the oxidizing type hair dye composition , And it is particularly preferable to contain hydrogen peroxide.
  • the oxidizing agent may be used in an amount of usually 0.1 to 10.0% by weight based on the total weight of the second composition.
  • the second component of the present invention can also be used within the range that does not impair the effect of the present invention.
  • emulsions such as paraffin, hard flowing isoparaffin, higher fatty alcohol and higher fatty acid ester, cationic or nonionic surfactants, stabilizers such as phenacetin, and pH adjusters such as phosphoric acid.
  • the first agent and the second agent of the oxidative salt hair dye composition according to the present invention usually contain water in addition to the above-mentioned components.
  • water it is preferable to use purified water such as ion-exchanged water and distilled water, and the content thereof is not particularly limited, and it may be any amount that sufficiently dissolves or disperses each component used in the hair dye composition.
  • the oxidative hair dye composition according to the present invention is used by mixing a first agent and a second agent immediately before applying to the hair.
  • the first agent and the second agent are mixed in a weight ratio of usually 1: 1 to 1: 2, more preferably in a range of 1: 1 Can be mixed and used.
  • the ratio of the first agent When the ratio of the first agent is lowered when the ratio of the first agent and the second agent is decreased, the amount of the dye is decreased, the amount of dye penetrated into the hair is decreased and the coloring power is decreased.
  • the ratio of the second agent When the ratio of the second agent is increased, The addition reaction takes place, and the lower the ratio, the slower the reaction rate becomes.
  • a method of hair dyeing using the oxidative hair dye composition according to the present invention there is a method of preparing an oxidized hair dye by mixing the first and second agents, applying the oxidized hair dye to the hair, and washing the hair after a predetermined time And a conventional hair dyeing method.
  • the higher aliphatic alcohol may be at least one selected from the group consisting of Cetyl Alcohol, Stearyl Alcohol, Cetearyl Alcohol and Behenyl Alcohol, And is preferably a cetearyl alcohol.
  • the sorbitan-based surfactant may be at least one selected from the group consisting of cetearyl olivate / sorbitan olivate, sorbitan sesquioleate and sorbitan stearate / sorbityl laurate, May be characterized by being a mixture of cetearyl olivate / sorbitan olivate.
  • the glucose-based surfactant is selected from the group consisting of C12-20 alkyl glucoside, C14-22 alcohol / C12-20 alkyl glucoside, cetearyl alcohol / cetearyl glucoside and arachidyl alcohol / behenyl alcohol / arachidyl glucoside , Preferably at least one selected from the group consisting of C12-20 alkyl glucoside.
  • the mixture is preferably present in an amount of from 10: 0.1 to 4.8: 1, preferably from 10: 1 to 4: 1, most preferably from 10: 1 to 4: 1 by weight, based on the weight of the higher aliphatic alcohol, the sorbitan surfactant and the glucose surfactant. By weight, and a mixing ratio of 10: 1.5 to 3: 1.
  • the content of the higher aliphatic alcohol is 0.1 to 15% by weight, preferably 5 to 15% by weight, and most preferably 8 to 12% by weight, based on the total weight of the first agent. If the content of the higher aliphatic alcohol is less than 0.1% by weight based on the total weight of the first agent, the deodorizing effect of the ammonia odor is insignificant. When the content of the higher aliphatic alcohol is higher than 15% by weight, And may lower the stability of the formulation and the feeling of use.
  • the content of the sorbitan-based surfactant is 0.1 to 15% by weight, preferably 0.8 to 5.0% by weight, and most preferably 1.0 to 4.0% by weight, based on the total weight of the first agent If the content of the surfactant of the sorbitan series is less than 0.1% by weight based on the total weight of the first agent, the deodorizing effect of the ammonia odor is insignificant. When the content of the surfactant exceeds 15% by weight, The increase of the effect is not so large, and the stability and feeling of use of the composition may be lowered.
  • the content of the glucose-based surfactant is 0.1 to 15% by weight, preferably 0.1 to 5% by weight, and most preferably 0.5 to 1.5% by weight, based on the total weight of the first agent If the amount of the glucose-based surfactant is less than 0.1% by weight based on the total weight of the first agent, the deodorizing effect of the ammonia odor is insignificant. When the content of the surfactant exceeds 15% by weight, The stability of the formulation and feeling of use can be reduced.
  • the ammonia content of the ammonia-generating material may be 0.1 to 10% by weight, preferably 2 to 8% by weight based on the total weight of the first agent, If the ammonia content of the material is less than 0.1% by weight based on the total weight of the first agent, the hair dyeing / bleaching effect of the hair is insignificant. If the ammonia content exceeds 10% by weight, The feeling of use may be lowered.
  • the substance generating ammonia may be aqueous ammonia solution, preferably 28% w / w ammonia water, but is not limited thereto.
  • the composition may be characterized by containing conventional carriers and additives known in the art.
  • conventional cosmetic ingredients may be contained according to cosmetic formulation.
  • the composition may be characterized by reducing the feeling of scalp stimulation and hair damage.
  • the first hair dye preparation agents of Examples 1 to 6 and Comparative Examples 1 to 9 and the second hair dye preparation agent were prepared in the compositions of Tables 1 to 3 and Table 4, respectively.
  • Tables 1 to 3 below show the hair dye first agent (unit: wt%).
  • the water phase can be purified water, an antioxidant (erythorbic acid), a reducing agent (sodium pyrosulfite), PPD (p-phenylene diamine) Sorcinol) was added and dissolved by heating to about 75 ° C.
  • an antioxidant erythorbic acid
  • a reducing agent sodium pyrosulfite
  • PPD p-phenylene diamine
  • Sorcinol a reducing agent
  • cetyl alcohol, stearyl alcohol or cetearyl alcohol, polyoxyethylene stearyl ether, cetearyl olivate / sorbitan olivate were added and dissolved by heating to about 75 ° C.
  • the oil phase and water phase were mixed and emulsified, and after cooling to about 55 ° C, the final concentration of C12-20 alkyl glucoside and ammonia (ammonia was 8.0 wt% or 12.0 wt% based on the total weight of the hair dye preparation 1 Ammonia water (28% w / w) was added thereto to prepare a hair dye preparation.
  • Table 4 shows the hair dye second agent (unit: wt%).
  • the hair dye second agent (oxidizing agent) was prepared by dissolving cetearyl alcohol, polyoxyethylene stearyl ether and polyoxyethylene sarcoyl ether in an oil state at about 75 ° C according to the composition ratios shown in Table 4, Dithia and purified water were dissolved by heating to about 75 ° C to emulsify the water phase and the oil phase at the same temperature and cooled to about 55 ° C to obtain a final concentration of phosphoric acid and hydrogen peroxide (35% w / w) was used so as to have a concentration of 5.9% by weight), and the mixture was uniformly mixed and stirred to prepare a hair dye-forming agent.
  • the oxidative hair dye composition prepared by mixing 30 g of the hair dye preparation 1 prepared in Preparation Example 1 and 30 g of the hair dye formulation 2 was placed in a 500 ml flask and left at room temperature for about 30 minutes. Then, a detector tube for detecting ammonia (GASTEC No. 3HM Ammonia, GASTEC) was connected to the flask and a pump was operated to suck ammonia generated from the oxidative hair dyeing composition. The scale of the changed color was read and the amount of ammonia generated from the oxidation type hair dye composition was measured.
  • GASTEC No. 3HM Ammonia GASTEC
  • Tables 5 to 7 show the amounts of ammonia generated by NH 3 detection tube measurement.
  • the evaluation of the deodorizing effect on the ammonia odor of the oxidative dyeing composition prepared by mixing 30 g of the hair dyeing agent 1 prepared in Preparation Example 1 and 30 g of the hair dyeing agent 2 was carried out through 15 sensory evaluation specialists Next, the average score was calculated by the 10 point scaling method.
  • Table 8 below shows the sensory evaluation criteria.
  • Formulation Example 1 Formulation Example 2
  • Formulation Example 3 Formulation Example 4
  • Stimulus intensity evaluation 5.0 5.0 5.0 5.0 5.5 Improvement of feeling (comfort) by reduction of irritant odor Great Great Great Great usually
  • Comparative Formulation Example 5 Comparative Formulation Example 6 Comparative Formulation Example 7 Comparative Formulation Example 8 Comparative Formulation Example 9 Stimulus intensity evaluation 8.8 6.5 6.5 10 10 Improvement of feeling (comfort) by reduction of irritant odor Very low lowness lowness Very low Very low

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition de coloration capillaire oxydante et, plus particulièrement, une composition de coloration capillaire oxydante comprenant un mélange d'un alcool aliphatique supérieur, d'un tensioactif à base de sorbitane et d'un tensioactif à base de glucose en tant que principes actifs. La composition de coloration capillaire oxydante a considérablement amélioré l'odeur piquante et déplaisante de l'ammoniac.
PCT/KR2018/013605 2017-11-17 2018-11-09 Composition de coloration capillaire oxydante Ceased WO2019098608A2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201880062426.6A CN111132655B (zh) 2017-11-17 2018-11-09 氧化型染发剂组合物

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2017-0154141 2017-11-17
KR20170154141 2017-11-17
KR1020180130995A KR102371926B1 (ko) 2017-11-17 2018-10-30 산화형 염모제 조성물
KR10-2018-0130995 2018-10-30

Publications (2)

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WO2019098608A2 true WO2019098608A2 (fr) 2019-05-23
WO2019098608A3 WO2019098608A3 (fr) 2019-07-11

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PCT/KR2018/013605 Ceased WO2019098608A2 (fr) 2017-11-17 2018-11-09 Composition de coloration capillaire oxydante

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Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100850223B1 (ko) * 2002-07-31 2008-08-04 가부시키가이샤 아리미노 모발 탈색 또는 염모제용 유화 조성물, 이 유화 조성물을사용한 탈색 또는 염모방법
JP5629063B2 (ja) * 2009-06-01 2014-11-19 ホーユー株式会社 毛髪化粧料組成物
JP5792926B2 (ja) * 2009-06-12 2015-10-14 ホーユー株式会社 毛髪処理方法
EP2343037B1 (fr) * 2010-01-08 2012-05-09 The Procter & Gamble Company Composition épaissie de coloration et décoloration capillaire
JP5737932B2 (ja) * 2010-12-27 2015-06-17 ホーユー株式会社 毛髪処理剤

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