[go: up one dir, main page]

WO2019072061A1 - 包含噻苯隆和聚谷氨酸的农药组合物 - Google Patents

包含噻苯隆和聚谷氨酸的农药组合物 Download PDF

Info

Publication number
WO2019072061A1
WO2019072061A1 PCT/CN2018/104849 CN2018104849W WO2019072061A1 WO 2019072061 A1 WO2019072061 A1 WO 2019072061A1 CN 2018104849 W CN2018104849 W CN 2018104849W WO 2019072061 A1 WO2019072061 A1 WO 2019072061A1
Authority
WO
WIPO (PCT)
Prior art keywords
polyglutamic acid
active component
composition
composition according
thiabendazole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2018/104849
Other languages
English (en)
French (fr)
Inventor
仲汉根
季红进
张明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Huifeng Bio Agriculture Co Ltd
Original Assignee
Jiangsu Huifeng Bio Agriculture Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to AU2018347082A priority Critical patent/AU2018347082B2/en
Priority to EP18867220.8A priority patent/EP3695722B1/en
Priority to EA202090852A priority patent/EA039311B1/ru
Priority to UAA202002469A priority patent/UA124218C2/uk
Priority to MX2020003510A priority patent/MX2020003510A/es
Priority to US16/754,910 priority patent/US11576383B2/en
Application filed by Jiangsu Huifeng Bio Agriculture Co Ltd filed Critical Jiangsu Huifeng Bio Agriculture Co Ltd
Priority to PH1/2020/550232A priority patent/PH12020550232B1/en
Priority to BR112020007137-4A priority patent/BR112020007137A2/pt
Priority to CA3079653A priority patent/CA3079653C/en
Publication of WO2019072061A1 publication Critical patent/WO2019072061A1/zh
Anticipated expiration legal-status Critical
Priority to CONC2020/0005366A priority patent/CO2020005366A2/es
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture

Definitions

  • the invention belongs to the field of agricultural plant protection, in particular to a pesticide composition with improved properties, in particular to a composition comprising a thidiazuron and a polyglutamic acid pesticide.
  • Pyraclostrobin is a new type of high-efficiency plant growth regulator. When it is absorbed by plants, it can promote the separation of petioles and stems and form natural shedding. It can be widely used in pesticides and fertilizers. It has strong biological activity, and its ability to induce plant cell division and callus formation is many times higher than that of general cytokinins. Improve crop absorptive capacity and increase photosynthesis, so as to increase production and enhance the purpose. It can be used in various kinds of melons, fruits, vegetables, seedlings, flowers, food, tobacco and other crops, and can also be used for tissue culture, genetic engineering, etc. In production, it can significantly improve crop yield, improve quality and use less, has no pollution to the ecological environment, and is non-toxic to humans, animals, birds, bees and natural enemies.
  • Polyglutamic acid also known as natto gum or polyglutamic acid, is a water-soluble, biodegradable, non-toxic, biopolymer produced by microbial fermentation.
  • Polyglutamic acid is a kind of homo-amino acid formed by glutamic acid monomer polymerization through amide bond. It has excellent biodegradability, super-adsorption, non-toxicity, etc. It is reduced by adding it to compound fertilizer. Fertilizer nutrient loss, improve fertilizer utilization, regulate plant growth and other multiple effects. It has significant application effects on rice, wheat, corn, vegetables, fruit trees, flowers and other plants, which can significantly increase crop yield.
  • the inventors have found that there is a significant synergistic effect between thidiazuron and polyglutamic acid in regulating or promoting plant growth.
  • Another object of the present invention is to provide a process for the preparation of a composition comprising two active ingredients A and B plant growth regulators and for regulating and promoting the growth of crops in the agricultural field.
  • the object of the invention can be achieved by the following measures:
  • a synergistic pesticidal composition comprising two active components A and B, wherein active component A is thiabendazole and active component B is polyglutamic acid, between the two components
  • the weight ratio is a weight ratio of the active component A to the active component B of 1:0.01 to 200.
  • the weight ratio of the active component A to the active component B is 1:0.011 to 180, and the weight ratio of the two components may be more preferably 1:0.0125 to 180 or 1:0.012. 170.
  • the weight ratio between the two components of A and B can be arbitrarily adjusted within the range of the following ratios: 100:1, 95:1, 90:1, 85:1, 80: 1, 75:1, 70:1, 65:1, 60:1, 55:1, 50:1, 45:1, 40:1, 35:1, 30:1, 29:1, 28:1 27:1, 26:1, 25:1, 24:1, 23:1, 22:1, 21:1, 20:1, 19:1, 18:1, 17:1, 16:1, 15 : 1, 14: 1, 13: 1, 12: 1, 11: 1, 10: 1, 9: 1, 8: 1, 7: 1, 6: 1, 5: 1, 4: 1, 3: 1 , 2:1, 1:1, 1:2, 1:3, 1:4, 1:5, 1:6, 1:7, 1:8, 1:9, 1:10, 1:15, 1 :20, 1:25, 1:30, 1:31, 1:32, 1:33, 1:34, 1:35, 1:36, 1:37, 1:38, 1:39, 1:40 1, 1:41, 1:42, 1:
  • Polyglutamic acid is mainly composed of D-glutamic acid and L-glutamic acid by amide bond polymerization. Due to different polymerization methods, polyglutamic acid mainly contains two configurations: ⁇ -polyglutamic acid. (by ⁇ -amide bond polymerization, ⁇ -PGA) and ⁇ -polyglutamic acid (polymerization by ⁇ -amide bond, ⁇ -PGA), the polyglutamic acid form of the present invention is ⁇ -polyglutamic acid, In the present invention, it is simply referred to as "polyglutamic acid" (the structural formula is as follows).
  • composition of the present invention is useful for better regulating the growth of crops, promoting the health effects of crops, and increasing crop yield.
  • the present invention provides a use of a composition comprising component A (thiabendazole) and component B (polyglutamic acid) to regulate crop growth in the agricultural field, in particular to regulate crop growth in rice, wheat or fruit trees to improve disease resistance Uses such as effects.
  • component A thiabendazole
  • component B polyglutamic acid
  • composition of the present invention can also be used in combination with other pesticides (such as fungicides, insecticides, herbicides, plant growth regulators), fertilizers, etc., and these are mixed with Commonly used pesticides or fertilizers disclosed in the art.
  • pesticides such as fungicides, insecticides, herbicides, plant growth regulators
  • fertilizers etc.
  • composition of the present invention can be made into a pesticide-acceptable dosage form from the active ingredient and the pesticide adjuvant.
  • composition may specifically comprise an agrochemical auxiliary, such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, etc., during the application process.
  • an agrochemical auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, etc.
  • an agrochemical auxiliary such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, etc.
  • Suitable auxiliaries may be solid or liquid, they are usually materials commonly used in the processing of dosage forms, such as natural or regenerated minerals, solvents, dispersants, wetting agents, adhesives, thickeners, binders or fertilizers. .
  • the method of application of the compositions of the invention comprises the use of the compositions of the invention for aerial parts of plants, in particular leaves or foliage. You can choose to soak or apply to the surface of the control object.
  • the plant growth site such as rice fields, may be wetted with a liquid formulation of the composition, or the composition may be applied to the soil in solid form, such as in the form of granules (soil application), the composition may be passed from the soil to the plant through the roots of the plant. In vivo (systemic action).
  • compositions may be applied only with the active ingredient or may be mixed with an additive (agrochemical adjuvant).
  • composition of the present invention can be prepared into a pesticide-acceptable dosage form such as a liquid, a suspension, a soluble liquid, an oil suspension, a water-dispersible granule, a microemulsion, a wettable powder and the like.
  • a pesticide-acceptable dosage form such as a liquid, a suspension, a soluble liquid, an oil suspension, a water-dispersible granule, a microemulsion, a wettable powder and the like.
  • the compositions may be applied by spraying, misting, dusting, spreading or pouring, and the like.
  • composition of the present invention can be prepared into various dosage forms by a known method, and the active ingredient and the auxiliary agent, such as a solvent, a solid carrier, and, if necessary, can be uniformly mixed and ground together with the surfactant to prepare a desired preparation. Dosage form.
  • the above solvent may be selected from aromatic hydrocarbons, preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • aromatic hydrocarbons preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • Alkenes or paraffins, alcohols and glycols and their ethers and esters such as ethanol, ethylene glycol, ethylene glycol monomethyl
  • ketones such as cyclohexanone
  • highly polar solvents such as N-methyl-2 Pyrrolidone, dimethyl sulfoxide or dimethylformamide
  • vegetable or vegetable oils such as soybean oil.
  • the above solid carriers are typically natural mineral fillers such as talc, kaolin, montmorillonite or activated clay.
  • a highly dispersible silicic acid or a highly dispersible adsorbent polymer carrier such as a particulate adsorbent carrier or a non-adsorbing carrier, and a suitable particulate adsorbent carrier is porous, such as pumice, bentonite or Bentonite; a suitable non-adsorbing carrier such as calcite or sand.
  • a large amount of pre-granulated materials of inorganic or organic nature can be used as a carrier, in particular dolomite.
  • Suitable surfactants are lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, alkaline earth metal or amine salts, alkylarylsulfonates, alkyl groups Sulfates, alkyl sulfonates, fatty alcohol sulphates, fatty acids and sulfated fatty alcohol glycol ethers, as well as condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, naphthalene or naphthalene sulfonic acid with phenol and formaldehyde Condensate, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octyl phenol, nonyl phenol, alkyl aryl polyglycol ether, tributyl benzene poly
  • Plants of the invention include, but are not limited to, indica, corn, and the like.
  • the two active ingredients in the compositions of the present invention exhibit synergistic effects, the activity of which is more pronounced than the expected sum of activity using a single compound, and the individual activity of a single compound.
  • Other characteristics exhibited by the composition of the present invention are mainly as follows: 1.
  • the composition of the present invention has a significant synergistic effect; 2. Due to the large difference in the chemical structure of the two single agents of the composition, the effect The mechanism is completely different, there is no cross-resistance, which can delay the resistance problem caused by the two single agents alone; 3.
  • the composition of the invention can well regulate crop growth, improve disease resistance and stress resistance, and promote crop health effects. To increase crop yields.
  • the components such as dispersing agent, wetting agent, thickener and water are uniformly mixed according to the formula, and the emulsifier, dispersing agent, wetting agent, stabilizer and dispersion medium are first added to the reaction kettle, and mixed and dispersed uniformly; Antifreeze and thickener were added under high shear condition, and the active ingredient polyglutamic acid and thidiazepine were sanded under the zirconia grinding medium to obtain a dispersible oil suspension containing polyglutamic acid and thidiazuron. Agent.
  • Example 1 2.025% thienol-polyglutamic acid dispersible oil suspension agent
  • Example 2 6.6% thiabendazole ⁇ polyglutamic acid dispersible oil suspension agent
  • Thiabendron 6% polyglutamic acid 0.6%, castor oil polyoxyethylene ether 5%, alkylphenol polyoxyethylene ether phosphate 3%, polyoxyethylene polyoxypropylene block copolymer 15%, dodecane Calcium benzenesulfonate 4%, attapulgite 10%, organic bentonite 5%, 2,6-di-tert-butyl-p-cresol 5%, corn oil to 100%.
  • Example 3 10.2% thiabendazole ⁇ polyglutamic acid dispersible oil suspension agent
  • Thiabendazole 0.2% polyglutamic acid 10%, polyoxyethylene polyoxypropylene block copolymer (EO-PO block copolymer) 15%, calcium dodecylbenzenesulfonate 3%, castor oil polyoxygen Vinyl ether 3%, polyvinyl alcohol 2%, magnesium aluminum silicate 4%, 2,6-di-tert-butyl-p-cresol 2%, mineral oil to 100%.
  • polyglutamic acid 10% polyoxyethylene polyoxypropylene block copolymer (EO-PO block copolymer) 15%
  • calcium dodecylbenzenesulfonate 3% calcium dodecylbenzenesulfonate 3%
  • castor oil polyoxygen Vinyl ether 3% polyvinyl alcohol 2%
  • magnesium aluminum silicate 4% 2,6-di-tert-butyl-p-cresol 2%, mineral oil to 100%.
  • Example 4 20.25% thiabendazole ⁇ polyglutamic acid dispersible suspending agent
  • the active ingredient active group A and the active component B, and the auxiliary agent and the filler are uniformly mixed according to the formula, and are pulverized into a wettable powder by a jet stream, and then added with a certain amount of water to be mixed and extruded, granulated, and dried and sieved.
  • a water dispersible granule product A water dispersible granule product.
  • Example 5 3.06% thiabendazole-polyglutamic acid water-dispersible granules
  • Example 6 24% thiabendazole-polyglutamic acid water-dispersible granules
  • Example 7 13% thiabendazole-polyglutamic acid water-dispersible granules
  • the active ingredient thiablon and the polyglutamic acid active ingredient are mixed with various auxiliary agents and fillers in proportion, and pulverized by an ultrafine pulverizer to obtain a wettable powder.
  • Example 8 1.01% thilbone polyglutamic acid wettable powder
  • Example 9 5.2% thilbone polyglutamic acid wettable powder
  • Example 10 11% thibenzo-polyglutamic acid wettable powder
  • Example 11 25.25% thiabendazole-polyglutamic acid wettable powder
  • the active ingredient active group A and the active ingredient B are mixed with the auxiliary agent and the filler in a ratio of the formula, and then mixed with water to obtain a liquid product.
  • Example 12 12.1% thiabendazole-polyglutamic acid aqueous solution
  • Example 13 14.1% thiabendazole-polyglutamic acid aqueous solution
  • Example 14 16.1% thiabendazole-polyglutamic acid aqueous solution
  • Example 15 18.1% thiabendazole-polyglutamic acid aqueous solution
  • Example 16 20.1% thiabendazole-polyglutamic acid aqueous solution
  • Example 17 22.1% thiabendazole-polyglutamic acid aqueous solution
  • the thidiazepine and polyglutamic acid were diluted with acetone at a certain concentration, and the crops were sprayed with stems and leaves.
  • the effects of various concentrations on the growth of the crops were determined in the field, including the plant height, panicle number, seed setting rate and disease resistance of the crops. And comprehensive evaluation of the production situation.
  • Plant height control rate (clear water control plant height - treated plant height) / clear water control plant height * 100%
  • Increase rate of panicle (number of panicles after treatment - number of spikes of clear water control plants) / number of spikes of clear water control plants * 100%
  • Seed setting rate number of grains per panicle / total number of kernels per pan * 100%
  • thio is the abbreviation of “thiablon” and “poly” is the abbreviation of “polyglutamic acid”.
  • Application period during the flowering stage, the rice plants in this stage did not occur or began to develop sheath blight. The number of application times: 2 times, the application interval is 8 days; the application method: stem and leaf spray; the investigation period: the late stage of indica rice filling. In this test, the indicators such as plant height, panicle number, disease index, and fruiting number were the average values of each treatment.
  • thiabendazole can promote cell division and promote plant growth, and in this process, rice needs to absorb more from the outside.
  • Nutrients such as fertilizers, amino acids, humic acids, and other nutrient organic matter required for growth
  • polyglutamic acid as a metabolite of beneficial bacteria can be used as a fertilizer to satisfy the growth of thiabendazole in rice.
  • Sorghum variety Su Yu 23.
  • the corn horn period the corn flowering period is prone to small spot disease and other diseases.
  • the number of applications 2 times, each interval of 6 days. Spraying was carried out using the formulation examples of the present invention, three replicates, and the results were averaged.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

一种具有增效作用的农药组合物，其有效成分包含A和B，其中活性组分A为噻苯隆，活性组分B为聚谷氨酸，其重量比为1：0.01～200。同时，还提供了该组合物的制备方法及用途。

Description

包含噻苯隆和聚谷氨酸的农药组合物 技术领域
本发明属于农业植物保护领域，特别是涉及一种具有改进性能的农药组合物，具体地说是涉及一种包含噻苯隆和聚谷氨酸农药的组合物。
背景技术
噻苯隆(pyraclostrobin)是新型高效植物生长调节剂，噻苯隆被植物吸收后，可促进叶柄与茎之间的分离组织，形成自然脱落，在农药、肥料中可被广泛应用。它具有极强的生物活性，其诱导植物细胞分裂、愈伤组织形成的能力比一般细胞分裂素高许多倍。提高作物吸收能力，增加光合作用，从而达到增产、增优目的。可用于各类瓜、果、蔬菜、苗木、花卉、粮食、烟草等作物，还可用于组织培养、基因工程等。在生产上能显著提高作物产量、改善品质且有用量少、对生态环境无污染，对人、畜、鸟、蜜蜂、天敌无毒等特点。
聚谷氨酸又称纳豆胶、多聚谷氨酸，它是一种水溶性，生物降解，不含毒性，使用微生物发酵法制得的生物高分子。聚谷氨酸是由谷氨酸单体通过酰胺键聚合而成的一类均聚氨基酸，具有极佳的生物可降解性、超强吸附、无毒等优点，将其加入复合肥中具有减少肥料养分流失，提高肥料利用率、调节植物生长等多重功效。在水稻、小麦、玉米、蔬菜、果树、花卉等植物上均具有显著应用效果，可以显著提高作物产量。
实际的农药经验已经表明，重复且专一施用一种活性化合物来防治有害真菌在很多情况下将导致真菌菌株的快速选择性，为降低抗性真菌菌株选择性的危险性，目前通常使用不同活性化合物的混合物来防治有害真菌。通过将具有不同作用机理的活性化合物进行组合，可延缓抗性产生，降低施用量，减少防治成本。
发明内容
本发明的目的是提供一种具有增效作用的农药组合物，以促进作物生长，提高作物的抗病和作物产量。发明人发现，噻苯隆与聚谷氨酸两者之间在调节或促进植物生长方面具有显著的协同增效作用。
本发明的另一个目的是提供包含两种有效成分A和B植物生长调节剂组合物的制备方 法及在农业领域调节和促进农作物生长中的应用。
本发明的目的可以通过以下措施达到：
一种具有增效作用的农药组合物，该组合物包含A和B两种活性组分，其中活性组分A为噻苯隆，活性组分B为聚谷氨酸，两组分之间的重量比为活性组分A和活性组分B的重量比为1:0.01～200。在一种优选方案中，活性组分A和活性组分B的重量比为1：0.011～180，为使作用效果更明显两者重量比可进一步优选为1：0.0125～180或1：0.012～170。
在一种优选的方案中，A和B两组分之间的重量比可以任意地在下述配比的范围内进行调整：100:1、95:1、90:1、85:1、80:1、75:1、70:1、65:1、60:1、55：1、50:1、45:1、40:1、35：1、30:1、29:1、28:1、27:1、26:1、25:1、24:1、23:1、22:1、21:1、、20:1、19:1、18:1、17:1、16:1、15:1、14:1、13:1、12:1、11:1、10:1、9:1、8:1、7:1、6:1、5:1、4:1、3:1、2:1、1：1、1：2、1：3、1：4、1：5、1：6、1：7、1：8、1：9、1：10、1：15、1：20、1：25、1：30、1:31、1:32、1:33、1:34、1:35、1:36、1:37、1:38、1:39、1:40、1:41、1:42、1:43、1:44、1:45、1:46、1:47、1:48、1:49、1:50、1:51、1:52、1:53、1:54、1:55、1:56、1:57、1:58、159:、1:60、1:61、1:62、1:63、1:64、1:65、1:66、1:67、1:68、1:69、1:70、1:71、1:72、1:73、1:74、1:75、1:76、1:77、1:78、1:79、1:80、1:81、1:82、1:83、1:84、1:85、1:86、1:87、1:88、1:89、1:90、1:91、1:92、1:93、1:94、1:95、1:96、1:97、1:98、1:99、1:100、1：102、1：103、1：104、1：105、1：106、1：107、1：108、1：109、1：110、1：111、1：112、1：113、1：114、1：115、1：116、1：117、1：118、1：119、1：120、1：121、1：122、1：123、1：124、1：125、1：126、1：127、1：128、1：129、1：130、1:131、1:132、1:133、1:134、1:135、1:136、1:137、1:138、1:139、1:140、1:141、1:142、1:143、1:144、1:145、1:146、1:147、1:148、1:149、1:150、1:151、1:152、1:153、1:154、1:155、1:156、1:157、1:158、1：159:、1:160、1:161、1:162、1:163、1:164、1:165、1:166、1:167、1:168、1:169、1:170、1:171、1:172、1:173、1:174、1:175、1:176、1:177、1:178、1:179、1:180、1:181、1:182、1:183、1:184、1:185、1:186、1:187、1:188、1:189、1:190、1:191、1:192、1:193、1:194、1:195、1:196、1:197、1:198、1:199、1:200，也可以在以上任意两个配比所组成的范围内进行选择，这些比例可以理解为重量比，也可以包括摩尔比。
聚谷氨酸(PGA)主要是由D-谷氨酸和L-谷氨酸通过酰胺键聚合而成，由于聚合方式不同，聚谷氨酸主要包含两种构型：α-聚谷氨酸(通过α-酰胺键聚合，α-PGA)和γ- 聚谷氨酸(通过γ-酰胺键聚合，γ-PGA)，本发明中的聚谷氨酸形式为γ-聚谷氨酸，在本发明中简称为“聚谷氨酸”(其结构式如下)。
Figure PCTCN2018104849-appb-000001
发明人通过试验发现，本发明的组合物是用于可以更好的调节作物的生长，促进作物的健康作用，提高作物的产量。
本发明提供了包含组分A(噻苯隆)和组分B(聚谷氨酸)的组合物在农业领域调节农作物生长的用途，特别是在水稻、小麦或果树方面调节作物生长提高抗病效果等方面的用途。
为充分发挥本发明的优势效果，本发明的组合物还可以与其他农药(如杀菌剂、杀虫剂、除草剂、植物生长调节剂)、肥料等混合使用，这些与之混用的均为现有技术公开的常用的农药或肥料。
本发明的组合物可以由活性成分和农药助剂制成农药上允许的剂型。
上述组合物具体可包含农药助剂，例如载体、溶剂、分散剂、润湿剂、胶粘剂、增稠剂、粘合剂、表面活性剂等中的一种或几种，在施用的过程中可以混合常用的助剂。
合适的助剂可以是固体或液体，它们通常是剂型加工过程中常用的物质，例如天然的或再生的矿物质，溶剂、分散剂、润湿剂、胶粘剂、增稠剂、粘合剂或肥料。
本发明组合物的施用方法包括将本发明的组合物用于植物生长的地上部分，特别是叶部或叶面。可以选择浸种或涂抹于防治对象表面。可以将植物的生长场所，如稻田，用组合物的液体制剂浸湿，或者将组合物以固体形式施用于土壤中，如以颗粒形式(土壤施用)，组合物可以由土壤经植物根部进入植物体内(内吸作用)。
这些组合物可以仅仅包含活性成分进行施用，也可以与添加剂(农药助剂)一起混合使用。
本发明的组合物可以制备成农药上可接受的剂型，例如水剂、悬浮剂、可溶性液剂、油悬浮剂、水分散粒剂、微乳剂、可湿性粉剂等。根据这些组合物的性质以及施用组合物所要达到的目的和环境情况，可以选择将组合物以喷雾、弥雾、喷粉、撒播或泼浇等之类的方法施用。
可用已知的方法可以将本发明的组合物制备成各种剂型，可以将有效成分与助剂，如 溶剂、固体载体，需要时可以与表面活性剂一起均匀混合、研磨，制备成所需要的剂型。
上述的溶剂可选自芳香烃，优选含8-12个碳原子，如二甲苯混合物或取代的苯，酞酸酯类，如酞酸二丁酯或酞酸二辛酸，脂肪烃类，如环已烷或石蜡，醇和乙二醇和它们的醚和酯，如乙醇，乙二醇，乙二醇单甲基；酮类，如环已酮，强极性的溶剂，如N-甲基-2-吡咯烷酮，二甲基亚砜或二甲基甲酰胺，和植物油或植物油，如大豆油。
上述的固体载体，如用于可湿性粉剂和可分散剂的通常是天然矿物填料，例如滑石、高岭土，蒙脱石或活性白土。为了管理组合物的物理性能，也可以加入高分散性硅酸或高分散性吸附聚合物载体，例如粒状吸附载体或非吸附载体，合适的粒状吸附载体是多孔型的，如浮石、皂土或膨润土；合适的非吸附载体如方解石或砂。另外，可以使用大量的无机性质或有机性质的预制成粒状的材料作为载体，特别是白云石。
根据本发明的组合物中的有效成分的化学性质，合适的表面活性剂为木质素磺酸、萘磺酸、苯酚磺酸、碱土金属盐或胺盐，烷基芳基磺酸盐，烷基硫酸盐，烷基磺酸盐，脂肪醇硫酸盐，脂肪酸和硫酸化脂肪醇乙二醇醚，还有磺化萘和萘衍生物与甲醛的缩合物，萘或萘磺酸与苯酚和甲醛的缩合物，聚氧乙烯辛基苯基醚，乙氧基化异辛基酚，辛基酚，壬基酚，烷基芳基聚乙二醇醚，三丁基苯聚乙二醇醚，三硬脂基苯基聚乙二醇醚，烷基芳基聚醚醇，乙氧基化蓖麻油，聚氧乙烯烷基醚，氧化乙烯缩合物、乙氧基化聚氧丙烯，月桂酸聚乙二醇醚缩醛，山梨醇酯，木质素亚硫酸盐废液和甲基纤维素。
本发明中的植物包括但不限于籼稻、玉米等。
本发明的组合物中两种有效成分表现为增效效果，该组合物的活性比使用单个化合物的活性预期总和，以及单个化合物的单独活性更为显著。本发明的组合物的表现出的其它特点主要表现为：1、本发明的组合物混配具有明显的协同增效作用；2、由于本组合物的两个单剂化学结构差异很大，作用机理完全不同，不存在交互抗性，可延缓两单剂单独使用所产生的抗性问题；3、本发明的组合物可很好的调节作物生长，提高抗病抗逆性，促进作物健康作用，提高作物产量。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅用以解释本发明，并不用于限定本发明，凡在本发明的精神和原则之内所做的任何修改、等同替换和改进等，均应包含在本发明的保护范围之内。
以下实施例所有配方中百分比均为重量百分比(折百)。本发明组合物各种制剂的加工工艺均为现有技术，根据不同情况可以有所变化。
一、剂型制备实施例
(一)可分散油悬浮剂的加工及实施例
将分散剂、润湿剂、增稠剂和水等各组分按配方的比例混合均匀，先将乳化剂、分散剂、润湿剂、稳定剂、分散介质加入反应釜，混合、分散均匀；高速剪切状态下加入防冻剂和增稠剂，将活性成分聚谷氨酸与噻苯隆在锆珠研磨介质下进行砂磨，制得含有聚谷氨酸与噻苯隆的可分散油悬浮剂。
实施例1：2.025％噻苯隆·聚谷氨酸可分散油悬浮剂
噻苯隆2％，聚谷氨酸0.025％，二苯基酚聚氧乙烯聚甲醛缩合物6％，异丙醇2％，硫酸铵1％，烷基苯萘磺酸盐15％，油酸甲酯补足至100％。
实施例2：6.6％噻苯隆·聚谷氨酸可分散油悬浮剂
噻苯隆6％，聚谷氨酸0.6％，蓖麻油聚氧乙烯醚5％，烷基酚聚氧乙烯醚磷酸酯3％，聚氧乙烯聚氧丙烯嵌段共聚物15％，十二烷基苯磺酸钙4％，凹凸棒土10％，有机膨润土5％，2,6-二叔丁基对甲酚5％，玉米油补足至100％。
实施例3：10.2％噻苯隆·聚谷氨酸可分散油悬浮剂
噻苯隆0.2％，聚谷氨酸10％，聚氧乙烯聚氧丙烯嵌段共聚物(EO-PO嵌段共聚物)15％，十二烷基苯磺酸钙3％，蓖麻油聚氧乙烯醚3％，聚乙烯醇2％，硅酸镁铝4％，2,6-二叔丁基对甲酚2％，矿物油补足至100％。
实施例4：20.25％噻苯隆·聚谷氨酸可分散悬浮剂
噻苯隆0.25％，聚谷氨酸20％，烷基酚聚氧乙烯醚磷酸酯3％，聚氧乙烯聚氧丙烯嵌段共聚物(EO-PO嵌段共聚物)5％，十二烷基苯磺酸钙3％，白炭黑2％，有机膨润土4％，2,6-二叔丁基对甲酚4％，甘油2％，蓖麻油补足至100％。
(二)水分散粒剂的加工及实施例
将活性成分活性分组A与活性组分B，与助剂和填料按配方的比例混合均匀，经气流粉碎成可湿性粉剂，再加入一定量的水混合挤压造粒，经干燥筛分后制得水分散粒剂产品。
实施例5：3.06％噻苯隆·聚谷氨酸水分散粒剂
噻苯隆3％，聚谷氨酸0.06％，十二烷基硫酸钠5％，白炭黑3％，烷基磺酸盐3％，膨润土2％，2-溴-2-硝基-丙基-1，3-二醇3％，高岭土补足至100％。
实施例6:24％噻苯隆·聚谷氨酸水分散粒剂
噻苯隆12％，聚谷氨酸12％，硫酸铵6％，硅藻土5％，膨润土补足至100％。
实施例7:13％噻苯隆·聚谷氨酸水分散粒剂
噻苯隆0.5％，聚谷氨酸12.5％，烷基苯磺酸钠4％，十二烷基硫酸钙4％，白炭黑5％，碳氢酸钙5％，轻质碳酸钙补足至100％。
(三)可湿性粉剂的加工及实施例
将活性成分噻苯隆与聚谷氨酸活性成分与各种助剂及填料等按比例充分混合，经超细粉碎机粉碎后制得可湿性粉剂。
实施例8:1.01％噻苯隆·聚谷氨酸可湿性粉剂
噻苯隆1％，聚谷氨酸0.01％，木质素磺酸盐5％，拉开粉6％，膨润土4％，白炭黑补足至100％。
实施例9:5.2％噻苯隆·聚谷氨酸可湿性粉剂
噻苯隆5％，聚谷氨酸0.2％，拉开粉4％，皂角粉2％，十二烷基硫酸钠3％，分子筛2％，高岭土补足至100％。
实施例10:11％噻苯隆·聚谷氨酸可湿性粉剂
噻苯隆1％，聚谷氨酸10％，木质素磺酸钠6％，十二烷基磺酸钙4％，硅藻土2％，白炭黑补足至100％。
实施例11:25.25％噻苯隆·聚谷氨酸可湿性粉剂
噻苯隆0.25％，聚谷氨酸25％，硅酸镁铝4％，十二烷基硫酸钠3％，烷基苯磺酸钠7％，膨润土％，轻质碳酸钠补足至100％。
(四)水剂的加工及实施例
将活性成分活性分组A与活性组分B，与助剂和填料按配方的比例混合均匀后与水在搅拌混合即得水剂产品。
实施例12:12.1％噻苯隆·聚谷氨酸水剂
噻苯隆0.1％，聚谷氨酸12％，烷基芳基聚氧乙烯醚磷酸酯3％，有机硅2％，尿素8％，十二烷基苯磺酸钠4％，丙二醇2.5％，水补足至100％。
实施例13:14.1％噻苯隆·聚谷氨酸水剂
噻苯隆0.1％，聚谷氨酸14％，十二烷基苯磺酸9％份，醋酸钠2％，高岭土15％，氢氧化铵3％，水补足至100％。
实施例14:16.1％噻苯隆·聚谷氨酸水剂
噻苯隆0.1％，聚谷氨酸16％，单硬脂酸酯3％，聚烷基硅环氧乙烷6％，壬基酚聚氧乙烯醚4％， 蓖麻油聚氧乙烯醚3％，水补足至100％。
实施例15:18.1％噻苯隆·聚谷氨酸水剂
噻苯隆0.1％，聚谷氨酸18％，聚烷基硅环氧乙烷5％，丙三醇2％，羟丙基纤维素1％，苯甲酸钠2％，聚异丁二酸酐-聚乙二醇共聚物1.5％，水补足至100％。
实施例16:20.1％噻苯隆·聚谷氨酸水剂
噻苯隆0.1％，聚谷氨酸20％，邻苯二甲酸二甲酯2％，碳酸丙烯基5％，N-正辛基吡咯烷酮0.5％，单棕榈酸酯4％，乙二醇3％，羟乙基纤维素2％，水补足至100％。
实施例17:22.1％噻苯隆·聚谷氨酸水剂
噻苯隆0.1％，聚谷氨酸22％，羟丙基纤维素1％，壬基酚聚氧乙烯醚4％，异丙二醇3％，聚异丁二酸酐-聚乙二醇共聚物1.8％，水补足至100％。
二、药效验证试验
(一)生物测定实施例
1、噻苯隆与聚谷氨酸复配对籼稻生长调节综合测定试验
将噻苯隆与聚谷氨酸用丙酮按照一定浓度稀释，对作物进行茎叶喷雾，在田间测定各个浓度对作物生长的影响，包括对作物的株高、穗数、结实率、抗病情况以及产量情况等进行综合评价。
株高控制率＝(清水对照株高-处理后的株高)/清水对照株高*100％
穗数提高率＝(处理后的植株穗数-清水对照植株穗数)/清水对照植株穗数*100％
结实率＝每穗实粒数/穗总粒数*100％
预防效果＝(清水对照的发病指数-处理后的发病指数)/清水对照的发病指数*100％
亩产提高率＝(处理后的亩产量-清水对照的亩产量)/清水对照的亩产量*100％
表1.噻苯隆与聚谷氨酸复配对籼稻生长调节综合测定汇总表
Figure PCTCN2018104849-appb-000002
Figure PCTCN2018104849-appb-000003
注：表格中“噻”为“噻苯隆”的缩写,“聚”为“聚谷氨酸”缩写。施药时期：扬花期，该阶段籼稻植株未发生或开始发生纹枯病。施药次数：2次，施药间隔期8天；施药方式：茎叶喷雾；调查时期：籼稻灌浆后期期。本试验中，株高、穗数、发病指数、结实数等指标均为各处理的平均值。
通过实验发明人发现，噻苯隆与聚谷氨酸之间具有很好的协同提升作用，噻苯隆与聚谷氨酸混配在不同配比下，相对噻苯隆、聚谷氨酸单剂，以及清水对照，对籼稻的生长调节作用明显，主要表现在：1、噻苯隆作为植物生长调节剂可以促进植株细胞分裂，促进植株生长，而在这过程中需要水稻从外界吸收更多的养分(如生长所需的肥料、氨基酸、腐殖酸，以及其他营养有机质)来满足其生长，而聚谷氨酸作为有益菌的代谢产物，可作为肥料来满足噻苯隆促进水稻生长过程中所需的养分，两者之间的协同作用，促进了水稻植株的营养传导、抗病抗逆，在水稻成熟期，对单位亩产有显著的提升作用，亩产提高率最高达到17.1％；2、试验中发现，聚谷氨酸本省也具备调节植物生长的功能，可与噻苯隆之间起到相辅相成的作用，可有效减少水稻的株高，提升植株上下营养传导能力，而且通过减少株高，可以提高水稻生长的抗倒伏性能；3、噻苯隆在作为单剂使用时对植物生长具有一定的抗病抗逆作用，而聚谷氨酸对作物病害具有一定免疫力，聚谷氨酸与噻苯隆之间共同施用具有良好的协同作用，从上表分析可以看出，噻苯隆与聚谷氨酸之间协同作用对籼稻纹枯病的预防效果相对于单剂及清水对照，具有很好的预防效果。
(二)田间药效验证试验
1、噻苯隆与聚谷氨酸混配对玉米作物调节生长及抗病增产的田间综合试验
高粱品种：苏玉23。
施药时期：玉米大喇叭期，玉米扬花期易发生小斑病等病害。
施药次数：2次，每次间隔6天。利用本发明的制剂实施例进行喷施，三个重复，结果取平均值。
表2 噻苯隆与聚谷氨酸混配对玉米调节生长的田间综合实验
Figure PCTCN2018104849-appb-000004
Figure PCTCN2018104849-appb-000005
从表2实验数据显示，噻苯隆与聚谷氨酸之间具有显著的协同作用，具体表现在：1、促进玉米植株长势齐整，弱苗促壮，大苗矮化，叶片宽厚浓绿，叶绿素增加、叶片功能期延长，光合作用增强，有效控制玉米控旺徒长，提高玉米茎径促进营养传导，防止玉米倒伏；2、诱导玉米植株抗病、抗逆，提高植株的健康作用；3、促进玉米籽粒饱满，提高玉米籽粒千粒重，显著提升玉米单位产量，单位亩产量提高率最高可达18.3％。

Claims (8)

  1. 一种具有增效作用的农药组合物，其特征在于该组合物包含A和B两种活性组分，其中活性组分A为噻苯隆，活性组分B为聚谷氨酸。
  2. 根据权利要求1所述的组合物，其特征在于活性组分A和活性组分B的重量比为1:0.01～200。
  3. 根据权利要求2所述的组合物，其特征在于活性组分A和活性组分B的重量比为1：0.011～180。
  4. 根据权利要求3所述的组合物，其特征在于活性组分A和活性组分B的重量比为1：0.0125～180。
  5. 根据权利要求1所述的组合物，其特征在于该组合物由活性成分和助剂制成农药上允许的剂型。
  6. 根据权利要求5所述的组合物，其特征在于所述剂型为可分散油悬浮剂、可湿性粉剂、水分散粒剂或水剂。
  7. 根据权利要求5所述的组合物，其特征在于所述农药助剂选自载体、溶剂、分散剂、润湿剂、胶粘剂、增稠剂、粘合剂、表面活性剂和肥料中的一种或几种。
  8. 权利要求1～6中任意一项所述的农药组合物在农业领域促进或调节植物生长中的用途。
PCT/CN2018/104849 2017-10-09 2018-09-10 包含噻苯隆和聚谷氨酸的农药组合物 Ceased WO2019072061A1 (zh)

Priority Applications (10)

Application Number Priority Date Filing Date Title
PH1/2020/550232A PH12020550232B1 (en) 2017-10-09 2018-09-10 Pesticide composition containing thidiazuron and polyglutamic acid
EP18867220.8A EP3695722B1 (en) 2017-10-09 2018-09-10 Pesticide composition containing thidiazuron and polyglutamic acid
EA202090852A EA039311B1 (ru) 2017-10-09 2018-09-10 Пестицидная композиция, содержащая тидиазурон и полиглутаминовую кислоту
UAA202002469A UA124218C2 (uk) 2017-10-09 2018-09-10 Пестицидна композиція, що містить тидіазурон і поліглютамінову кислоту
MX2020003510A MX2020003510A (es) 2017-10-09 2018-09-10 Composicion plaguicida que contiene tidiazuron y acido poliglutamico.
AU2018347082A AU2018347082B2 (en) 2017-10-09 2018-09-10 Pesticide composition containing thidiazuron and polyglutamic acid
CA3079653A CA3079653C (en) 2017-10-09 2018-09-10 Pesticide composition containing thidiazuron and polyglutamic acid
US16/754,910 US11576383B2 (en) 2017-10-09 2018-09-10 Pesticide composition containing thidiazuron and polyglutamic acid
BR112020007137-4A BR112020007137A2 (pt) 2017-10-09 2018-09-10 composição pesticida, contendo thidiazuron e ácido poliglutâmico
CONC2020/0005366A CO2020005366A2 (es) 2017-10-09 2020-04-29 Composición plaguicida que contiene tidiazurón y ácido poliglutámico

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710929416.5A CN107616184B (zh) 2017-10-09 2017-10-09 包含噻苯隆和聚谷氨酸的农药组合物
CN201710929416.5 2017-10-09

Publications (1)

Publication Number Publication Date
WO2019072061A1 true WO2019072061A1 (zh) 2019-04-18

Family

ID=61091500

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2018/104849 Ceased WO2019072061A1 (zh) 2017-10-09 2018-09-10 包含噻苯隆和聚谷氨酸的农药组合物

Country Status (12)

Country Link
US (1) US11576383B2 (zh)
EP (1) EP3695722B1 (zh)
CN (1) CN107616184B (zh)
AU (1) AU2018347082B2 (zh)
BR (1) BR112020007137A2 (zh)
CA (1) CA3079653C (zh)
CO (1) CO2020005366A2 (zh)
EA (1) EA039311B1 (zh)
MX (1) MX2020003510A (zh)
PH (1) PH12020550232B1 (zh)
UA (1) UA124218C2 (zh)
WO (1) WO2019072061A1 (zh)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107616184B (zh) 2017-10-09 2019-12-31 江苏辉丰生物技术有限公司 包含噻苯隆和聚谷氨酸的农药组合物
CN108477203A (zh) * 2018-04-20 2018-09-04 江苏辉丰生物农业股份有限公司 含有亚磷酸胆碱和噻苯隆的组合物
CN109730091A (zh) * 2019-02-02 2019-05-10 江苏辉丰生物技术有限公司 含有超敏蛋白和聚谷氨酸的组合物
CN109997866A (zh) * 2019-03-14 2019-07-12 江苏辉丰生物农业股份有限公司 含有噻苯隆和尿囊素的组合物
CN111248217A (zh) * 2020-03-29 2020-06-09 邢宇俊 一种含二氢卟吩铁和噻苯隆的植物生长调节剂组合物

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584496A (zh) * 2012-02-17 2012-07-18 南京工业大学 一种高效缓释尿素及其制备方法
CN105916376A (zh) * 2014-01-14 2016-08-31 农作物智力有限公司 农业化学组合物
CN107616184A (zh) * 2017-10-09 2018-01-23 江苏辉丰农化股份有限公司 包含噻苯隆和聚谷氨酸的农药组合物

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080009414A1 (en) * 2006-07-07 2008-01-10 Tung Hai Biotechnology Corporation Method for enhancing the growth of crops, plants, or seeds, and soil renovation
CN101103727A (zh) * 2007-08-17 2008-01-16 咸阳德丰有限责任公司 以噻苯隆作为活性物用于植物提质增产产品的制备方法及其应用
AU2014101391B4 (en) * 2014-09-01 2015-09-03 Suunil Sudhakar Chaudhry Multifunctional organic agricultural fertilizer composition and process for preparation thereof
CN106212492A (zh) * 2016-04-02 2016-12-14 江苏辉丰农化股份有限公司 具有增效作用的植物生长调节剂组合物
CN106212491A (zh) * 2016-04-02 2016-12-14 江苏辉丰农化股份有限公司 一种植物生长调节组合物
CN106259464A (zh) * 2016-04-29 2017-01-04 江苏辉丰农化股份有限公司 含有噻苯隆和超敏蛋白的植物生长调节剂组合物
CN106962406B (zh) * 2016-11-10 2019-10-25 江苏辉丰生物技术有限公司 包含噻苯隆和极细链格孢激活蛋白的组合物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102584496A (zh) * 2012-02-17 2012-07-18 南京工业大学 一种高效缓释尿素及其制备方法
CN105916376A (zh) * 2014-01-14 2016-08-31 农作物智力有限公司 农业化学组合物
CN107616184A (zh) * 2017-10-09 2018-01-23 江苏辉丰农化股份有限公司 包含噻苯隆和聚谷氨酸的农药组合物

Also Published As

Publication number Publication date
EA039311B1 (ru) 2022-01-12
MX2020003510A (es) 2020-07-22
CA3079653C (en) 2022-06-07
EP3695722A4 (en) 2021-07-14
UA124218C2 (uk) 2021-08-04
CN107616184B (zh) 2019-12-31
EA202090852A1 (ru) 2020-08-17
CA3079653A1 (en) 2019-04-18
US11576383B2 (en) 2023-02-14
PH12020550232A1 (en) 2021-02-15
PH12020550232B1 (en) 2023-10-25
EP3695722B1 (en) 2022-11-02
EP3695722A1 (en) 2020-08-19
BR112020007137A2 (pt) 2020-09-24
CO2020005366A2 (es) 2020-06-19
AU2018347082A1 (en) 2020-05-07
US20200260731A1 (en) 2020-08-20
CN107616184A (zh) 2018-01-23
AU2018347082B2 (en) 2024-06-13

Similar Documents

Publication Publication Date Title
CN106259403B (zh) 具有增效作用的植物生长调节剂组合物
CN105660659B (zh) 一种杀菌剂组合物
WO2019072061A1 (zh) 包含噻苯隆和聚谷氨酸的农药组合物
WO2018086634A1 (zh) 包含噻苯隆和极细链格孢激活蛋白的组合物
WO2017166565A1 (zh) 具有增效作用的植物生长调节剂组合物
WO2018059605A2 (zh) 一种植物生长调节剂
WO2017166566A1 (zh) 一种植物生长调节组合物
WO2017166567A1 (zh) 具有增效作用的植物生长调节剂组合物
WO2018086633A1 (zh) 一种包含苯并异噻唑啉酮类和乙蒜素的杀菌剂组合物
WO2015196951A1 (zh) 具有增效作用的杀虫杀螨剂组合物
WO2017166564A1 (zh) 一种植物生长调节剂组合物
WO2020147277A1 (zh) 一种植物生长调节剂组合物
WO2017206825A1 (zh) 具有增效作用的除草组合物
WO2018036294A1 (zh) 一种农药组合物
WO2017185559A1 (zh) 一种杀菌剂组合物
WO2017185558A1 (zh) 含有噻苯隆和超敏蛋白的植物生长调节剂组合物
WO2018068773A2 (zh) 含苯并异噻唑啉酮类和极细链格孢激活蛋白的杀菌组合物
WO2017166563A1 (zh) 具有增效作用的植物生长调节剂组合物
WO2018028324A1 (zh) 具有增效作用的除草组合物
CN106035338A (zh) 一种包含吡氟酰草胺和丁草胺的除草组合物
CN104970022A (zh) 一种含嘧霉胺和春雷霉素的杀菌组合物
WO2018036288A1 (zh) 一种农药组合物
CN105211080B (zh) 一种除草组合物
WO2016070632A1 (zh) 具有增效作用的杀虫杀螨剂组合物
CN102084865B (zh) 粉唑醇·丙森锌杀菌组合物

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18867220

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 3079653

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: NC2020/0005366

Country of ref document: CO

ENP Entry into the national phase

Ref document number: 2018347082

Country of ref document: AU

Date of ref document: 20180910

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 2018867220

Country of ref document: EP

Effective date: 20200511

WWP Wipo information: published in national office

Ref document number: NC2020/0005366

Country of ref document: CO

REG Reference to national code

Ref country code: BR

Ref legal event code: B01A

Ref document number: 112020007137

Country of ref document: BR

ENP Entry into the national phase

Ref document number: 112020007137

Country of ref document: BR

Kind code of ref document: A2

Effective date: 20200409

WWG Wipo information: grant in national office

Ref document number: NC2020/0005366

Country of ref document: CO

WWW Wipo information: withdrawn in national office

Ref document number: NC2020/0005366

Country of ref document: CO

Ref document number: 763818

Country of ref document: NZ