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WO2018212399A1 - Composition d'eau de stérilisation à base d'acide hypochloreux - Google Patents

Composition d'eau de stérilisation à base d'acide hypochloreux Download PDF

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Publication number
WO2018212399A1
WO2018212399A1 PCT/KR2017/006618 KR2017006618W WO2018212399A1 WO 2018212399 A1 WO2018212399 A1 WO 2018212399A1 KR 2017006618 W KR2017006618 W KR 2017006618W WO 2018212399 A1 WO2018212399 A1 WO 2018212399A1
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WO
WIPO (PCT)
Prior art keywords
hypochlorous acid
water
acid
composition
sterilizing water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2017/006618
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English (en)
Korean (ko)
Inventor
송인환
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Individual
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Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to HU1900405A priority Critical patent/HUP1900405A1/hu
Publication of WO2018212399A1 publication Critical patent/WO2018212399A1/fr
Anticipated expiration legal-status Critical
Priority to PH12019502849A priority patent/PH12019502849A1/en
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/04—Disinfection

Definitions

  • the present invention relates to a hypochlorous acid sterilizing water composition, and more particularly, by mixing a certain amount of sodium hypochlorite in a mixture of citric acid and vinegar to prepare hypochlorous acid sterilizing water, the generation of chlorine gas from hypochlorous acid sterilizing water Hypochlorite sterilized water composition that can be produced at high concentration and stable at pH value, as well as space spraying during operation, is easy to comprehensive hygiene management and can be manufactured at low manufacturing cost. It is about.
  • sterilizing water that requires strong sterilizing power has various problems such as adversely affecting the human body and the environment at the same time as sterilization.
  • hypochlorous acid-based electrolytic water hydrochloric acid mixtures and the like have been developed.
  • hypochlorous acid is a chlorine-based disinfectant, which is a powerful oxidizing agent, and its present form varies depending on pH.
  • Strong acid hypochlorous acid pH 2.7 or less, effective chlorine concentration 20 ⁇ 60ppm
  • unacidic hypochlorous acid pH 5.0 ⁇ 6.5, effective chlorine concentration 10 ⁇ 30ppm
  • hypochlorite water has better sterilizing power and bleaching power than sodium hypochlorite at the same effective chlorine concentration.However, the method for producing hypochlorous water using the known manufacturing equipment requires a high cost, and further, such a method can be used with high concentration of hypochlorous acid. Water manufacture was economically and practically impossible and could not be widely used.
  • an electrolysis method in order to generate hypochlorous water, an electrolysis method, a hydrochloric acid mixing method, a carbon dioxide gas mixing method, and the like are mainly used.
  • the carbon dioxide gas mixing method is very difficult to store the hypochlorous acid water because the pH value rises as the carbon dioxide gas is opened after the generation of hypochlorous acid water, especially since the carbon dioxide gas is immediately converted to water when sterilized by sterilization. The effect is reduced, there is a problem that the sterilization power is significantly reduced when contacting the organic material.
  • a disinfectant disinfectant composition for obtaining a weakly acidic hypochlorous acid solution and a method for preparing sterilized water using the same (Korean Patent Publication No. 10-2013-0049031), and hypochlorous acid (CO2) using carbon dioxide gas Dilution chemical liquid mixing apparatus (Korean Patent Publication No. 10-2014-0127598) and the like are disclosed.
  • the present invention has been made by the above-described background, by mixing a certain amount of sodium hypochlorite in a mixture of citric acid and vinegar to produce hypochlorous acid sterilized water to exhibit a sterilizing effect for a certain time
  • Yet another object is to provide a hypochlorous acid sterilizing water composition that provides odorless sterilizing water without smell.
  • the present invention provides a hypochlorous acid sterilizing water composition that can be produced at a stable pH value at high concentrations while preventing the generation of chlorine gas from hypochlorous acid sterilizing water, as well as maintaining the sterilizing power for a long time in contact with organic matter. Its purpose is.
  • the present invention is manufactured by drinking citric acid and vinegar for drinking, as well as space spraying during operation, as well as comprehensive hygiene management, can be manufactured at a low manufacturing cost, hypochlorous acid sterilization that can be mass-produced The purpose is to provide an aqueous composition.
  • hypochlorous acid composition 87.0 to 97.0% by weight of a mixture of citric acid and acetic acid (acetic acid) in a certain amount by weight, sodium hypochlorite 3.0% to 13.0% by weight It is characterized in that the hypochlorous acid composition and water mixed at a ratio of the mixture to a certain volume (L).
  • the mixture is a certain amount of sodium hypochlorite (NaClO) in a weight ratio of the mixture of citric acid 70.0% to 97.0% by weight, acetic acid (acetic acid) 3.0 to 30.0% by weight It is characterized by consisting of a mixture.
  • NaClO sodium hypochlorite
  • the pH range of hypochlorous acid sterilized water prepared by adding 0.4 (ml) of the hypochlorous acid composition per 10 liters of water is characterized in that the range of 5 to 6.5.
  • the hypochlorous acid sterilizing water is adjusted to the concentration of the hypochlorous acid sterilizing water by adding 0.1 (ml) to 0.4 (ml) of the hypochlorous acid composition according to the intended use. Characterized in that.
  • hypochlorite sterilized water by mixing a certain amount of sodium hypochlorite in a mixture of citric acid and vinegar to prepare hypochlorite sterilized water to provide a sterilizing effect for a certain time while providing a odorless sterilized water without smell. It can work.
  • a mixture of citric acid and acetic acid in an amount of 87.0 to 97.0 wt%, sodium hypochlorite 3.0 wt% to 13.0 wt%, and a predetermined volume (l) It is characterized by providing a hypochlorous acid sterilized water composition which is mixed with.
  • the present invention provides a hypochlorous acid, characterized in that a mixture of citric acid and acetic acid in a certain weight ratio is mixed with sodium hypochlorite (NaClO) by a certain amount by weight to a certain amount of water. It relates to a sterile water composition.
  • Citric acid also called citric acid, is a metabolite of plants and animals that exists in nature. It is the most organic acid obtained from citrus fruits. Acidic, ph-modifying, antioxidant, detergent, astringent, etc. Organic acid, widely used as a chemical, is important in biochemistry as an intermediate step in the citric acid cycle in metabolism and as an environmentally friendly cleaning agent.
  • Acetic acid or acetic acid is one of the representative carboxylic acids, and the molecular formula is CH 3 COOH. It is also known as acetic acid because it contains about 3 to 5% of the main ingredient of vinegar and gives the sour taste of vinegar. Pure is known as glacial acetic acid because it has a high freezing point and easily becomes a solid in winter.
  • citric acid is used as a main raw material for preparing hypochlorous acid sterilized water, and a mixture of 70.0 wt% to 97.0 wt% of citric acid and 3.0 wt% to 30.0 wt% of acetic acid is prepared.
  • the citric acid when the citric acid and acetic acid are mixed, the citric acid is preferably mixed within the range of 70.0% by weight to 97.0% by weight.
  • the acetic acid (acetic acid) mixed with citric acid to prepare hypochlorous acid sterilized water is preferably mixed within the range of 3.0% by weight to 30.0% by weight.
  • the acetic acid is acidic and is a strong preservative and at the same time plays a role of a disinfectant
  • the mixed amount is less than 3.0% by weight, not only the sterilizing power for various bacteria is provided but also a sufficient role of the preservative. If you do not have a problem, and if it exceeds 30.0% by weight, there is a problem that the inherent aroma of acetic acid is too thick can affect the aroma of the prepared disinfectant.
  • acetic acid not only brewing vinegar, brown rice vinegar, onion vinegar, but also any one or more of fruit vinegar can be used to be mixed with citric acid.
  • the present invention is further prepared by mixing sodium hypochlorite (NaClO) in a certain weight ratio to the mixture of citric acid and acetic acid in a weight ratio to produce hypochlorous acid water.
  • NaClO sodium hypochlorite
  • sodium hypochlorite (NaClO) generates oxygen by reaction in water and uses cyanogen to make cyanic acid present in the wastewater. After that, the cyanic acid is decomposed again into nitrogen and carbon dioxide to be harmless. The lower the pH, the stronger the bactericidal power, and the lower the bactericidal power by protein, sugar, amino acid and the like. The sterilizing power is best adjusted to pH8-9 after dilution to 100ppm concentration.
  • Sodium hypochlorite is a pale greenish yellow or colorless liquid, smells of chlorine, and when stored for a long time, it is decomposed and converted into chlorine gas, which loses its effect as a disinfectant.
  • Such sodium hypochlorite is used as a disinfectant for removing rot or pathogens of food and is used as a disinfectant disinfectant, bleach and oxidant. This substance breaks down and releases oxygen. It dissolves well in water and decomposes as a disinfectant when stored for a long time because aqueous solution decomposes during storage to generate chlorine gas.
  • the mixture when the sodium hypochlorite is mixed, the mixture is composed of 87.0 to 97.0 wt% of the citric acid and acetic acid, and 3.0 wt% to 13.0 wt% of sodium hypochlorite.
  • the present invention is made by mixing a certain amount of sodium hypochlorite (NaClO) in a weight ratio to a mixture of citric acid 70.0% to 97.0% by weight, acetic acid (acetic acid) 3.0% to 30.0% by weight, The mixture is made by mixing at a ratio of 87.0 to 97.0% by weight, and 3.0% to 13.0% by weight of sodium hypochlorite.
  • NaClO sodium hypochlorite
  • the present invention is made by mixing a certain amount of water and the hypochlorous acid composition in which the citric acid, acetic acid and sodium hypochlorite are mixed so that the pH range of hypochlorous acid sterilized water is in the range of 5 to 6.5.
  • the present invention is preferably mixed by adding 0.4 (ml) of the hypochlorous acid composition per 10 liters (L) of water.
  • the present invention can be used in various ways, such as medical instruments and furniture, household furniture, bathroom sterilization, agriculture and livestock, fisheries and food sterilization, indoor sterilization, such as home or hotel, according to the needs of the user, use
  • the hypochlorous acid water may be mixed with a certain amount to adjust the concentration.
  • 0.1 (ml) to 0.4 (ml) of the hypochlorous acid composition is further added to the hypochlorous acid sterilized water prepared by adding 0.4 (ml) of the hypochlorous acid composition per 10 liters of water to adjust the concentration.
  • 0.1 (ml) to 0.4 (ml) of the hypochlorous acid composition is further added to the hypochlorous acid sterilized water prepared by adding 0.4 (ml) of the hypochlorous acid composition per 10 liters of water to adjust the concentration.
  • hypochlorous acid composition 87.0-97.0% by weight of a mixture of 10 liter (L) water, 70.0% to 97.0% citric acid, 3.0% to 30.0% acetic acid, and 3.0% by weight sodium hypochlorite 0.4 (ml) was added to the hypochlorous acid composition to be mixed at a ratio of ⁇ 13.0% by weight to prepare hypochlorous acid sterilized water.
  • the hypochlorous acid sterilizing water according to Example 1 has a concentration of 1 to 10 ppm with respect to the content of the hypochlorous acid composition, which is easily removed when used for cleaning a mop such as a bathroom, and has an excellent effect on removing mold. It was confirmed that there is.
  • hypochlorous acid sterilized water prepared in Example 1 was added 0.1 (ml) of the hypochlorous acid composition to prepare a hypochlorous acid sterilized water. That is, hypochlorous acid sterilized water prepared by adding 0.5 (ml) of the hypochlorous acid composition per 10 liters of water was prepared.
  • the hypochlorous acid sterilizing water according to Example 2 has a concentration of 50 to 80 ppm with respect to the content of the hypochlorous acid composition, which is not only an indoor room such as a hospital room, a waiting room, an agricultural house, or a livestock barn, but also surfaces of various furniture. It was confirmed that there is an excellent effect on the disinfection for sterilization.
  • hypochlorous acid sterilized water prepared in Example 1 was added 0.2 (ml) of the hypochlorous acid composition to prepare a hypochlorous acid sterilized water. That is, hypochlorous acid sterilized water prepared by adding 0.6 (ml) of the hypochlorous acid composition per 10 liters of water was prepared.
  • the hypochlorous acid sterilizing water according to Example 3 has a concentration of 50 to 100 ppm with respect to the content of the hypochlorous acid composition, and it is confirmed that the hypochlorous acid sterilizing water has excellent effects in various households, indoor and outdoor deodorization, and freshness of fish.
  • hypochlorous acid sterilized water prepared in Example 1 was added 0.3 (ml) of the hypochlorous acid composition to prepare a hypochlorous acid sterilized water. That is, hypochlorous acid sterilized water prepared by adding 0.7 (ml) of the hypochlorous acid composition per 10 liters of water was prepared.
  • the hypochlorous acid sterilizing water according to Example 4 has a concentration of 100 to 150 ppm with respect to the content of the hypochlorous acid composition, and it was confirmed that the effect was excellent when the sterilization was performed on the walls of the room.
  • hypochlorous acid sterilized water prepared in Example 1 was added 0.4 (ml) of the hypochlorous acid composition to prepare a hypochlorous acid sterilized water. That is, hypochlorous acid sterilized water prepared by adding 0.8 (ml) of the hypochlorous acid composition per 10 liters of water was prepared.
  • the hypochlorous acid sterilizing water according to Example 5 has a concentration of 100 to 200 ppm with respect to the content of the hypochlorous acid composition, which has been confirmed to have an excellent sterilizing effect on pets, food waste, freshness maintenance of bodies, etc. It was confirmed that there is an effect of suppressing reproduction.

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne une composition d'eau de stérilisation à base d'acide hypochloreux, et fournit une composition d'eau de stérilisation à base d'acide hypochloreux formée par mélange d'une composition d'acide hypochloreux et d'eau dans un volume prédéfini (L), la composition d'acide hypochloreux comprenant : de 87,0 à 97,0 % en poids d'un mélange comprenant de l'acide citrique et de l'acide acétique selon un rapport pondéral prédéfini ; et de 3,0 à 13,0 % en poids d'hypochlorite de sodium. Selon un mode de réalisation de la présente invention, de l'eau de stérilisation à base d'acide hypochloreux est préparée par mélange d'une quantité prédéfinie d'hypochlorite de sodium dans un mélange comprenant de l'acide citrique et du vinaigre, et par conséquent de l'eau de stérilisation inodore, qui n'a pas d'odeur tout en présentant un effet de stérilisation pendant une durée prédéfinie, peut être fournie, et la présente invention peut générer une valeur de pH stable à une concentration élevée tout en empêchant la génération de chlore gazeux à partir d'eau de stérilisation à base d'acide hypochloreux, et peut également maintenir un pouvoir stérilisant pendant une longue période même lors d'un contact avec de la matière organique.
PCT/KR2017/006618 2017-05-17 2017-06-23 Composition d'eau de stérilisation à base d'acide hypochloreux Ceased WO2018212399A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
HU1900405A HUP1900405A1 (hu) 2017-05-17 2017-06-23 Hipoklórossavas sterilizáló vizes összetétel
PH12019502849A PH12019502849A1 (en) 2017-05-17 2019-12-17 Hypochlorous acid sterilizing water composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2017-0060921 2017-05-17
KR1020170060921A KR20180126208A (ko) 2017-05-17 2017-05-17 차아염소산 살균수 조성물

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WO2018212399A1 true WO2018212399A1 (fr) 2018-11-22

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KR (1) KR20180126208A (fr)
HU (1) HUP1900405A1 (fr)
PH (1) PH12019502849A1 (fr)
WO (1) WO2018212399A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114916558A (zh) * 2021-07-29 2022-08-19 江苏豪凡医疗科技有限公司 一种生产次氯酸稳定的方法

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102475055B1 (ko) * 2020-07-29 2022-12-06 연세대학교 원주산학협력단 차아염소산 음용 조성물
KR102560481B1 (ko) * 2020-10-12 2023-07-27 한국생산기술연구원 부유 세균 또는 부유 바이러스 제거방법 및 제거장치

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11228316A (ja) * 1998-02-19 1999-08-24 Clean Chemical Kk 殺菌消毒用製剤
JP2003170171A (ja) * 2001-12-06 2003-06-17 Tadashi Inoue 循環水および貯水の殺菌および抗菌方法。
JP2009219984A (ja) * 2008-03-14 2009-10-01 Hanada:Kk 殺菌水の製造方法
JP2010167375A (ja) * 2009-01-23 2010-08-05 Shinmeiwa:Kk 殺菌用の残留有効塩素含有水の製造方法およびその製造装置
JP2010253463A (ja) * 2009-03-31 2010-11-11 Shinmeiwa:Kk 殺菌用の残留有効塩素含有水の製造装置及びその方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11228316A (ja) * 1998-02-19 1999-08-24 Clean Chemical Kk 殺菌消毒用製剤
JP2003170171A (ja) * 2001-12-06 2003-06-17 Tadashi Inoue 循環水および貯水の殺菌および抗菌方法。
JP2009219984A (ja) * 2008-03-14 2009-10-01 Hanada:Kk 殺菌水の製造方法
JP2010167375A (ja) * 2009-01-23 2010-08-05 Shinmeiwa:Kk 殺菌用の残留有効塩素含有水の製造方法およびその製造装置
JP2010253463A (ja) * 2009-03-31 2010-11-11 Shinmeiwa:Kk 殺菌用の残留有効塩素含有水の製造装置及びその方法

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114916558A (zh) * 2021-07-29 2022-08-19 江苏豪凡医疗科技有限公司 一种生产次氯酸稳定的方法
CN114916558B (zh) * 2021-07-29 2024-04-26 江苏豪凡医疗科技有限公司 一种生产次氯酸稳定的方法

Also Published As

Publication number Publication date
HUP1900405A1 (hu) 2020-03-30
KR20180126208A (ko) 2018-11-27
PH12019502849A1 (en) 2020-09-14

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