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WO2018210629A1 - Dispositif d'insertion à écoulement radial pour prédéterminer au moins un trajet d'écoulement radial dans un réacteur à lit et procédé de montage et utilisation - Google Patents

Dispositif d'insertion à écoulement radial pour prédéterminer au moins un trajet d'écoulement radial dans un réacteur à lit et procédé de montage et utilisation Download PDF

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Publication number
WO2018210629A1
WO2018210629A1 PCT/EP2018/061853 EP2018061853W WO2018210629A1 WO 2018210629 A1 WO2018210629 A1 WO 2018210629A1 EP 2018061853 W EP2018061853 W EP 2018061853W WO 2018210629 A1 WO2018210629 A1 WO 2018210629A1
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WO
WIPO (PCT)
Prior art keywords
bed
container
radial
gas
radial flow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2018/061853
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German (de)
English (en)
Inventor
Daniela Dostal
Andreas Henke
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ThyssenKrupp AG
ThyssenKrupp Industrial Solutions AG
Original Assignee
ThyssenKrupp AG
ThyssenKrupp Industrial Solutions AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ThyssenKrupp AG, ThyssenKrupp Industrial Solutions AG filed Critical ThyssenKrupp AG
Publication of WO2018210629A1 publication Critical patent/WO2018210629A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0207—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal
    • B01J8/0214—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly horizontal in a cylindrical annular shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0278—Feeding reactive fluids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00884—Means for supporting the bed of particles, e.g. grids, bars, perforated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00893—Feeding means for the reactants
    • B01J2208/00911—Sparger-type feeding elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00893—Feeding means for the reactants
    • B01J2208/0092—Perforated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796—Details of the reactor or of the particulate material
    • B01J2208/00938—Flow distribution elements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00018—Construction aspects
    • B01J2219/0002—Plants assembled from modules joined together

Definitions

  • the invention relates to a radial flow apparatus for predetermining at least one radial flow path in a bed reactor and a mounting method for providing the radial flow apparatus.
  • the invention relates to an apparatus and a method according to the preamble of the respective claim.
  • Reactors with gas traversed beds are widely used and in many cases determine the boundary conditions of a process, e.g. the achievable throughput.
  • the corresponding sorption process must be fine-tuned, especially with regard to pressure loss and temperature profile or flow profile in the bed. This is especially true for ammonia plants, or quite generally for plants for synthesis gas treatment.
  • Optimization measures in particular also to increase the economic benefit, aim in many cases at increasing the capacity of the plants. Higher capacity requires larger volume / mass flow.
  • reactors with flow-through (fixed bed) beds the pressure losses occurring must be overcome. The pressure losses increase with increasing volume flow. Consequently, there is an effort to provide reactors with minimal pressure loss to have more degrees of freedom in capacity increases.
  • the bed in the reactor can be flowed through in the axial or radial direction. Radial bed reactors bring in most cases a lower pressure drop with it than axial bed reactors, which is particularly important for large systems or high flow rates.
  • a previous measure to reduce the pressure loss at the highest possible volume flow is therefore to convert existing axial bed reactors in radial bed reactors. This is usually done by introducing the required components and components through a manhole into the reactor. For a separation and re-welding of the reactor wall is for various reasons, not a viable approach to gain better access. In particular, one would be Stress relieving required. The reactors are also often pressure vessels, so that a renewed acceptance or approval with respect to the operating pressure would be required. There are a number of measures for influencing the pressure loss or the flow profile on the reactor inner wall known, as described for example in EP 3 037 165 AI or EP 0 446 592 Bl. However, these measures can not be applied without difficulty to a pure axial-bed reactor.
  • EP 0 372 453 A2 and EP 0 265 654 A1 each describe an annular insert with two concentrically arranged lateral surfaces for axial-bed reactors, by means of which a conversion to an at least partially radially through-flow radial-bed reactor can take place.
  • EP 1 432 507 B1 describes a basket-like annular cylindrical insert which can be positioned on a shoulder on the inner lateral surface of a reactor vessel.
  • the insert consists of a plurality of segments (cylinder sectors), each of which can be inserted through an access opening in the reactor vessel, so that the insert can be mounted in the container.
  • JP 03-131336 A describes an arrangement for increasing the contact time of a radial flow through a bed.
  • the bed is packed in a ring cylindrical container. Either the flow is introduced into a ring-cylindrical region radially outward from the bed or from the annular cylindrical container and then passed from there in the radial direction through the bed, or the flow is through a plurality of axial Tubes guided, which are arranged radially outwardly from the bed around the bed around.
  • the individual tubes are arranged between the inner wall of the reactor and the annular cylindrical container, in particular circumferentially.
  • the individual tubes are arranged separately from the bed, in particular also separately from the annular cylindrical container.
  • EP 2 374 531 A1 Again, there is a packed bed, around which radially outside either a ring-cylindrical cavity or individual tubes are arranged.
  • the object of the invention is to provide a device and a method which can be ensured in containers of bed reactors in a simple manner as homogeneous radial flow, especially at low pressure drop over the entire bed, especially in connection with newly configured or converted bulk reactors ,
  • a Radialstromdirvorraum for specifying at least one flow path in the radial direction inwardly through a bed of sorbent in a gas-flowed / gas-flowable container of a bed reactor, wherein the radial flow inserting modular through a plurality of axially in the direction of a center longitudinal axis of the container and longitudinally the bulk and arranged in the bulk gas distribution with radial passage structure is constructed, one / by the Radialstrombianvorraum defined flow path of the eccentrically arranged Gasverteilhowen radially inwardly directed to the central longitudinal axis or alignable, in particular each starting from a plurality of longitudinally in the axial direction the gas distribution units distributed height positions.
  • the radial flow insert device for any bulk.
  • the comparatively narrow, lightweight gas distribution units can be flexibly moved past existing internals in the reactor.
  • asymmetrically shaped hollow elements with differently sized, outer sheath radii would require specially adapted shaped pieces. This would increase the implementation effort and the costs.
  • the radial flow device is set up for positive or positive and non-positive final assembly of gas-conducting components within the container, which allows a reversible arrangement in the container, without material connection. This simplifies the assembly, and also allows disassembly. Material bonding (in particular welding) in connection with the assembly is not required, either before or after the installation of the individual components in the container. Although some of the components may have welds. However, the (dis) assembly can be done entirely without material.
  • the radial flow insert device also provides the advantage that the bed can optionally be flowed through at least partially axially.
  • the extent of the axial flow component can be adjusted in a comparatively flexible manner, in particular via the flow resistance in the axial bypass guides (Gasverteilritten) within the bed.
  • an existing, in-service reactor can be converted or retrofitted in a simple manner, in particular by introducing all gas-conducting components through an inlet or through a manhole. Welds on the reactor vessel do not have to be carried out. A heat post-treatment is not required.
  • the container wall can remain untouched, that is without the need for cohesive measures such as welding are required.
  • the container wall can form an abutment or a coupling part for positive or positive and non-positive fastening means.
  • the avoidance of welding work inside the container not least also contributes to shortening the time required for the assembly.
  • the retrofitting of the radial flow insert device can be done either through an inlet or a manhole, in conjunction with a final assembly in the container, or in the final assembled state, namely a container with a jacket flange, whereby the entire container cross-section is accessible.
  • the radial flow charging device can be made of at least two gas-conducting components from the group: gas distribution units with radial passage structure, support unit, axially flowable and along the bed can be arranged gas collection unit with radial passage structure; be constructed, wherein the gas-conducting components comprise at least a plurality of Gasverteiltechniken and at least one support unit.
  • the respective support unit is not necessarily a gas-conducting component, but can optionally fulfill a gas-conducting function, in particular since the support unit can be arranged within the bed.
  • the support unit may be formed as a disc which at least partially seals the bed in the radial direction. If an axial component of the flow should be prevented as completely as possible, for example, at specific height positions of the bed, so may optionally be provided one or more support units which completely seal off the bed in the radial direction at the desired height position.
  • a support unit forms a partially gas-permeable bulkhead, or is arranged only in a narrow radial section, in particular annularly completely encircling, in order to ensure as homogeneous a flow as possible.
  • the gas collection unit may also be described as a gas discharge unit.
  • the gas passing through the bed is combined and then removed from the bed reactor.
  • the gas collection unit is not necessarily part of the radial flow insert device.
  • the gas collection unit may already be mounted or pre-installed on the container.
  • the gas collection unit may be permanently installed and connected to an outlet of the container.
  • the radial flow insert device can be provided without gas collection unit. Also, there may be cases where the gas collection unit is too bulky or bulky to replace, so it is advantageous to provide the radial flow apparatus without the gas collection unit and to introduce a possibly still to be retrofitted radial passage structure to the already installed gas collection unit in the vessel.
  • the Radial flow insert device is provided together with the gas collecting unit, it is even possible to exert greater influence on the flow path or on the flow profile forming in the bed.
  • the Radial mallass devis can be fine tuned to each other, for example, each as a perforation.
  • a radial passage structure which is tuned to those of the gas distribution units, can also be retrofitted into an already installed gas collection unit.
  • the radial flow insert device can also be described as a gas distribution tube basket according to an embodiment. Examples of applications for the radial flow apparatus include: low temperature reactors for the water gas conversion reaction, gas treatment of a hydrogen plant.
  • a bed is to be understood as meaning a statically arranged or at least partially dynamically displaceable entirety of sorbent pellets or tablets or other shaped bodies (eg also rings).
  • the bed can be a fixed bed. Usually, a bed of catalyst material in pellet form is used.
  • sorbents which are not intended to provide catalytic activity e.g. Moisture adsorbents such as zeolites.
  • the most advantageous packaging can be selected depending on the application, regardless of the radial flow insert device described here.
  • the radial flow apparatus described here also allows the use of loose beds, ie beds of pellets, which are not arranged by a separate container or individual segments, but are literally loosely arranged as bulk in the container as bulk material. The bed must therefore not be a packed bed. Not least, this broadens the spectrum of possible applications.
  • a gas-permeable separating bulkhead in particular a wire mesh, can be arranged on the inner and / or outer lateral surface of the respective wall with passages.
  • the radial flow insert device can furthermore be constructed from at least one support unit arranged for the eccentric arrangement of the gas distribution units and for aligning and supporting the gas distribution units on the container and / or relative to each other.
  • the respective support unit can be configured, for example, as a (basket) ring with retaining clips.
  • One or more support units may form a (basket) support structure, in particular with clamps or at least with attachment points therefor.
  • the basket-like configuration can be formed by the plurality of gas distribution units. For example, 50 to 100 gas provided subunits, which in a final assembly arrangement a large part of the bed in the radial direction in a basket-like manner.
  • the final assembly (optionally outside of and / or in the container) can be carried out in particular by means of pipe clamps, ironing, screws, ie standardized standard parts, in particular reversible.
  • the gas distribution units can be fastened / mounted on the at least one support unit by means of such standard parts, in particular in the region of the openings.
  • the radial flow insert device makes it possible to adapt the gas distribution units to the respective application.
  • a diameter of the gas distribution units is for example 60 to 100 mm.
  • a distance of the center longitudinal axis of the respective gas distribution unit to the inner wall of the container is, for example, 40 to 70 mm, in particular 55 mm.
  • the number of distributor units is reduced, wherein the distributor units are shown with relatively larger diameters. It has been found that a large number of comparatively thin distribution units is particularly advantageous.
  • the optimum number of distribution units depends on the size of the container and the application, in particular also on the type of bed or the type of bulk material used.
  • the number of distributor units may be in the range of 50 to 100, in particular 80.
  • the number can also be over 100.
  • materials for the individual components of the radial flow apparatus in particular stainless steels can be used, optionally also other non-corrosive materials. This not least also allows a thin-walled and therefore lightweight construction with low mass.
  • the container can be filled to the bottom, so that also sets a partial axial flow, be it in the inlet or outflow.
  • the gas distribution units or gas inlet tubes or gas inlet hollow elements can thereby, apart from the upper gas inlet cross-sectional area (inlet), completely by catalyst material or be enclosed by a (fixed bed) bed, so that there is a largely symmetrical, radially aligned load profile on the respective gas distribution unit.
  • the gas first flows into the gas distribution units, then continues with a strong radial direction component to the gas collection unit (central tube) and from there to the outlet or outlet nozzle of the container.
  • the length of the gas collecting unit can be reduced starting from the upper end, so that the gas distribution units overlap the gas collecting unit axially. With this measure, it can also be avoided that undesired bypass flows form around the bed or only through partial areas of the bed.
  • the radially outflowable gas distribution units are each free-standing and spaced from each other within the bed can be arranged.
  • This arrangement has advantages both in terms of assembly (independence of the individual gas distribution units) and in terms of flow distribution.
  • a respective gas distribution unit can be designed in a particularly flexible manner for a particular application, e.g. be adjusted in diameter.
  • the gas distribution units may be formed as comparatively thin tubes, for example in the sum of more than 30 or more than 50 tubes, each free and radially spaced from the container wall and spaced from one another in the bed. This provides a comparatively homogeneous flow profile, and allows a high degree of flexibility in the design of the radial flow charging device or the type of flow.
  • the radial flow insert device can be designed as a tubular basket formed from a plurality of gas distribution units, in particular as a cylindrical tube basket with gas distribution units arranged concentrically about a central longitudinal axis.
  • the respective gas distribution unit may in particular have a ring-cylindrical geometry. This also provides advantages in terms of thinness and stability.
  • the annular cylindrical geometry allows a comparatively thin wall, and thus a comparatively low pressure loss.
  • the respective gas distribution unit can be provided in the form of a welded tube with longitudinal weld, in particular a tube made of a (preferably rolled) perforated sheet metal strip.
  • the respective gas distribution unit may, for example, also have a semi-cylindrical geometry, or a geometry in which the outside is adapted to the geometry of the container wall. This provides further variables with regard to arrangement and flow profile, in particular for containers with non-cylindrical inner circumferential surface.
  • the arrangement of the respective gas distribution unit in the container can be carried out in such a way, in particular with sufficient distance from the wall, that the gas distribution unit is completely enclosed by filling material or catalyst material. This ensures a uniform support effect and allows thermal expansion at comparatively homogeneous material stresses. In particular, upon complete enclosure with pellets or catalyst material, a largely uniform radial force effect on the respective gas distribution unit is realized.
  • the radial passage structure can be provided by individual (point-like) passages / holes and / or by a flat perforation. A perforation of the respective gas distribution unit and its length can optionally be adjusted individually for the purpose of adjusting the gas distribution or the flow path for each application. For example, holes are provided with a diameter of 2mm.
  • the diameter is chosen such that pellets or the bulk material can not pass through the holes.
  • the perforation can be punched, e.g. when perforated according to standard.
  • the introduction of holes or a perforation can be done by laser. Both individual holes and an entire perforation may be formed symmetrically with respect to the axial direction and / or the circumferential direction.
  • the gas distribution units can be varied in length, in particular to influence the flow path or the homogeneity of the flow.
  • the gas distribution units may, due to the design, depending on the container geometry, be straight (strictly axial), or at least partially curved, in particular to dodge existing installations can.
  • the radial flow insert device is set up for positive or positive and non-positive final assembly of the gas-conducting components within the container. This not only provides advantages when retrofitting existing plants. By the Modular design there are relief in many contexts, be it during retrofitting or retrofitting, either during operation of the radial flow apparatus or a bed reactor.
  • the positive or non-positive coupling to the bed reactor also provides a large degree of freedom in the design and dimensioning of the radial flow device.
  • the gas distribution units and / or a centrally arranged in the container gas collection unit of the radial flow inserting device each define an axially aligned cavity with a flow resistance smaller the flow resistance in the bed, in which cavity forms the flow path in the axial direction, in particular a hollow cavity.
  • a kind of axial bridge or axial bypass can be provided within the bed.
  • Individual axial sections of the bed can be short-circuited or bypassed without the gas coming into contact with the bed. This allows, so far not governed, fresh gas, for example, to lead to a central height position of the bed and initiate it there in the bed, with the result that the bed is applied in the axial direction at any height positions in a similar manner with foreign matter.
  • the bed is used particularly well.
  • the cavity is cylindrical.
  • the cavities are hollow and without filling, in particular to be able to ensure minimal pressure loss in the axial direction.
  • measures can be taken to adjust the pressure loss within the cavities, for example, depending on the nature (packing density, porosity) and the volume of the bed in the container. Such measures can be particularly effective when the bed is covered by a bulkhead in the inflow, so that the flow must be made at least by the Gasverteilticianen.
  • the cavities can also be filled with inert shaped bodies in order to reduce the difference in the flow resistance and thereby cause an even stronger radial orientation of the flow or a greater charge of the head of the bed.
  • This measure can also sections along the respective Gasverteilech / Gassammeimaschine be made.
  • the radial flow insert device can define a plurality of axial flow path sections free of sorbent by means of the gas distribution units.
  • the axial flow path sections may extend along the entire length of the respective gas distribution unit. This provides good gas distribution and introduction into the entire bed.
  • the radial flow insert device defines circumferentially distributed radial inflow points, which are arranged in the axial direction in different height positions at the same radial position. This provides, viewed in the axial direction, at least approximately the same flow conditions at each height position of the reactor, ie a fairly homogeneous flow profile even in the case of elongate containers.
  • the respective radial passage structure of the gas distribution units and / or the gas collection unit has a plurality of passages, in particular in the manner of a homogeneously distributed perforation, in particular homogeneously distributed both in the circumferential direction and in the axial direction. The plurality of passages in the gas distribution units allows a homogeneous gas distribution in the bed.
  • the gas outlet openings are performed differently in sections, in order to improve the uniformity of the flow.
  • the passages can be punched or cut, for example, depending on diameter and wall thickness.
  • the passages can define the respective height positions.
  • a homogeneous distribution in the circumferential direction is also a distribution to understand that is interrupted at one or more circumferential positions in a narrow area segment, for example, due to a longitudinally extending in the axial direction weld.
  • the gas distribution units and / or the gas collection unit are ring-cylindrical. This can be ensured in a simple manner the most symmetrical or homogeneous flow distribution. Also, forces exerted on the gas distribution units can be intercepted in a comparatively homogeneous manner.
  • the (respective) support unit has openings arranged for receiving the gas distribution units and their relative arrangement to each other, wherein the Openings preferably define both the radial and the circumferential position of the respective gas distribution unit in the container.
  • the openings may be formed in particular as through holes.
  • the openings can in particular be provided by means of brackets or clamps (standardized standard parts), in particular standard parts, which can be fastened directly to the container wall.
  • the (respective) support unit has an opening for receiving a gas collection unit and for arranging relative to the gas distribution units. This allows alignment and support by means of the support unit in a simple manner. The assembly can be facilitated.
  • the gas distribution units and optionally also one / the gas collection unit of the radial flow apparatus or the bulk reactor can be held by the or by means of a plurality of support units independent of the container and aligned relative to each other. This allows the arrangement and orientation of the components regardless of the container geometry.
  • the gas distribution units can be arranged in a predefined / predefinable radial distance to a wall of the container (to the pressure vessel wall), in particular by means of one or more support units.
  • This makes it possible to use the radial flow from the gas distribution units over the entire circumference of the gas distribution units, and thus to provide a large gas exchange area at a comparatively low pressure loss. Last but not least, this can also stabilize the entire arrangement (full external pressure on the gas distribution units). Since the gas distribution units can be arranged freely in the bed, ie directly in the bed material or in the pellets, the design of the radial flow insert device for a specific application can be carried out in a particularly flexible manner, in particular each with freely selectable radial distance.
  • the radial flow apparatus can be set up to arrange the gas distribution units in radial support and at a predefined radial distance from a wall of the container, in particular by means of the (respective) support unit in concentric arrangement around a gas-removing gas collection unit with radial passage structure.
  • the radial spacing can be ensured in particular by means of the support unit (s).
  • the respective support unit is preferably formed from a plurality of segments or ring segments, in particular at least three ring segments.
  • the respective segment can be dimensioned such that it can also be introduced through the inlet into the container.
  • a support unit is formed by a plurality of steel construction profiles, which are annular shaped and segmented.
  • the radial flow insert device is modular from at least three and at most four gas-conducting components from the group: plurality of gas distribution units, support unit, bulkhead, centrally arranged gas collection unit; built up.
  • the support unit can assume at least insofar a gas-conducting function, as at least in a radial section in the axial direction more or less gas-tight bulkhead is formed by the support unit.
  • the support unit can not only extend fully (ring-like), but also from a wall of the container, e.g.
  • the support unit extends radially outward to the wall, whereby (especially due to lower pressure loss) there forming edge currents avoided or at least can be slowed down.
  • the respective support unit fulfills exclusively a supporting function.
  • the axially arranged gas distribution units in the final assembled state can define a ring of radial inflow points distributed over the circumference, in particular concentrically with a gas collection unit or an outlet of the container. This promotes a homogeneous distribution of the gas flow.
  • the gas distribution units each have a downstream, the cavity delimiting end. This improves the efficiency in distributing the flow in the radial direction. A bypass can be avoided.
  • the end can have individual passages or be perforated in order to be able to realize a partial axial flow as a function of the height position of the end.
  • the radial flow charging device comprises a bulkhead bulkhead which at least partially seals off the bulk material in the axial direction, in particular a bulkhead bulkhead arranged above the bulk material.
  • the radial portion of the flow can be amplified. A flow in the axial direction is at least partially blocked or impeded.
  • the flow path can be defined more accurately, and the pressure loss can be reduced.
  • the gas can first be forced into the distribution units. The flow in the axial direction then takes place more or less exclusively in the distributor units. The fill can only be flowed in from the radial direction.
  • the bulkhead can be completely gas impermeable.
  • a partially gas-permeable bulkhead can be used, especially in conjunction with ceramic balls or at least one grid.
  • the radial flow insert device can be provided with and without upper bulkhead (or cover plate). This can be used to influence the flow path.
  • the functionality can be modified from a radially radially flowed through radial bed to an axial axial flow at least partially through Axialradialbett. In particular in the upper region of the bed, this makes it possible to influence the inflow of the gas in a simple manner.
  • an upper cylinder jacket region of the gas collection unit has no perforation or passages, or the gas collection unit is shortened from above.
  • an essay in the nature of a blind pipe socket for the central manifold can be provided, which can be placed from the top of the central manifold or slipped over to shorten the effective length of the central manifold.
  • an uppermost height position of the radial passage structure of the gas collecting unit is arranged lower than an upper end of the bed or as a closed end of the gas collecting unit, in particular 5 to 25% lower. This makes possible an influence on the flow profile, in particular if no bulkhead is provided, in particular even if the length of the gas collection unit is to remain unchanged. In an upper region of the gas collection unit, no radial passage structure is then formed.
  • an axial-radial flow with a more or less pronounced axial component is formed in the lower region of the container. This can be adjusted depending on the application.
  • a radial flow inserting device for a bed reactor for specifying at least one flow path in the radial direction inwardly by a bed starting from a plurality of different height positions axially along the bed, in particular a previously described Radialstromplastvorraum, prepared by arranging and aligning a Variety of axially flowed through and radially outflow gas distribution in the bed and eccentrically to the bed and to a central gas collection unit, in particular by modular final assembly in a container of the bed reactor.
  • the arranging and aligning can be effected in particular by means of at least one annular support unit, in particular a support unit which can be subdivided into several segments.
  • a bed reactor in particular for or in an ammonia plant, comprising a previously described, modular radial flow insert device with a plurality of axially flowed gas distribution, wherein the radial flow inserting device is formed from gas-conducting components, which is smaller than a or outlet of the bed reactor and can be introduced through the inlet or outlet in a container of the bed reactor.
  • the bed reactor may be formed, for example, as a fixed bed reactor.
  • the bed reactor may also be provided, for example, for or in a water gas conversion reaction reactor (LT shift reactor) for producing synthesis gas.
  • LT shift reactor water gas conversion reaction reactor
  • the radial flow insert device can be supported on / on one or more consoles, in particular centrally arranged in the container at half height brackets.
  • a corresponding support structure of the radial flow insert device can be arranged in a corresponding height position.
  • the attachment to one or more consoles can be combined with or replaced by attachment to a container support arranged or retrofitted in the foot support ring.
  • a respective console can for example have a T-profile or configured as a T-carrier.
  • the gas distribution units are radially spaced from the inner surface of the container inwardly offset / disposed within the bed directly in the bulk material, in particular at a distance of at least 1/36 or 1/25 of the radius of the container, for example at a distance of a maximum 1/4 or 1/3 of the radius of the container.
  • the gas distribution units extend axially along at least 50%, in particular at least 75% or completely along the bed. This provides the advantage that gas can be provided at all height positions of the bed for radial flow. Not only the head of the bed is charged, but also the middle and downstream lower part of the bed. The bed is used more efficiently. The whole arrangement is more efficient. This not least saves installation space and plant or process costs.
  • the radial flow charging device has a multiplicity of external, axially alignable gas distribution units which can be arranged / arranged around a centrally arranged gas collecting unit, in particular at a uniform predefinable radial distance.
  • the gas collection unit is connected to an outlet of the container, in particular integrally.
  • the gas collection unit may be pre-assembled in the container and may have a diameter smaller than the inlet (upper access port).
  • the gas collection unit may have a larger diameter than the upper access port, wherein the gas collection unit may be provided segmented and partially pre-assembled for final assembly.
  • the above object is also achieved by a method for assembling a radial flow inserting device for predetermining at least one flow path in the radial direction inwardly through a bed of a bed reactor, in particular a previously described radial flow insert device, wherein the radial flow inserting device is formed by a plurality of Gasverteilhowen, which or arranged eccentrically about a gas collection unit by means of at least one support unit and aligned and supported relative to each other, in particular within the bed or within a provided for receiving the bulk material volume.
  • This embodiment allows a particularly simple assembly, as well as a radial flow through the bed of a plurality of height positions.
  • the gas distribution units can be arranged in the axial direction in such a way that a bed to be flowed through is radially inflowable or chargeable via an axial section of at least 50% or at least 75% of the bed by means of the gas distribution units.
  • the gas distribution units can be mounted individually modularly with the support unit.
  • the gas distribution units are arranged with an eccentricity smaller than the radius of the container at a distance from a wall of the container, in particular by means of one / of the support unit.
  • This also provides a favorable flow profile.
  • the distance has not least the advantage that bedding material (pellets) can be easily inserted and removed from the container.
  • All required (gas-conducting) components can be introduced for assembly through an existing opening in the container (in particular inlet, gas inlet nozzle or manhole), in particular in a prefabricated outside the reactor state. All components can also be arranged within the bed. The packing need not be packed.
  • the filling of the container with bulk material can take place.
  • at least one bulkhead in / on the bed can be provided during or after this.
  • hold-down grids or at least one layer of ceramic balls can be provided on / in the bed.
  • an automation can take place with regard to individual steps of this type.
  • the provision of the individual components of the radial flow insert device can be carried out in an automated manner, be it as separate components in the form of a mounting kit, be it already at least partially preassembled.
  • the final assembly in the container can also comprise a coupling of the respective gas distribution unit with a magazine, a feed device and / or a loading unit. Furthermore, adjustment units and fixing units can be provided. Depending on the accessibility of the container and this assembly process can be carried out at least partially automated or motorized by robot support.
  • the assembly can be carried out in the following order:
  • the support structure may be formed at least partially by already provided in the container consoles.
  • consoles for example, steel construction profiles in ring form can be fastened with lugs. Clamps can be attached to the tabs.
  • the support structure may also be at least partially formed by at least one support ring, in particular in the region of a bottom of the container.
  • the radial flow inserter can be positioned and supported on the support ring.
  • the support ring can optionally be arranged in a central portion of the container.
  • the support ring can be segmented.
  • the method may further comprise providing the gas collection unit and attaching the gas collection unit to the container or to the support unit.
  • the gas distribution units by means of positive or positive and non-positive fastening means, in particular with standardized standard parts from the group: clamps, brackets, fittings; attached to the (respective) support unit.
  • the pipes can be additionally aligned and stabilized in their positioning.
  • the gas distribution units by means of and / or the support unit by means of positive or positive and non-positive fastening means, in particular with standardized standard parts from the group: (steel) profile segments (in particular Profilsegmenteringe), clamps, brackets, fittings; attached in a container of the bed reactor.
  • the gas distribution units are secured by means of brackets, at least one support ring with tabs and clamps in the container.
  • a radial flow apparatus in particular a previously described radial flow apparatus, for specifying at least one flow path in a container of a bed reactor in the radial direction inwardly by a bed starting from a plurality of different height positions axially along the bed, in particular starting from height positions with the same eccentricity smaller than the radius of the container.
  • the aforementioned object is also achieved according to the invention by using a plurality of perforated sheet-metal strips for forming a plurality of gas distribution units for providing a radial flow apparatus, in particular a previously described radial flow apparatus.
  • a particularly stable arrangement which can be realized in a cost-effective manner.
  • the use can be made to predetermine at least one flow path in a container of a bed reactor in the radial direction inwardly by a bed, wherein the gas distribution units are aligned in the axial direction and positioned within the bed each surrounded by bed material. This results in many of the aforementioned advantages.
  • FIG. 1 is a sectional perspective view of a radial flow inserting device according to an embodiment
  • FIG. 2 is a sectional perspective view of a radial flow apparatus according to another embodiment
  • Fig. 3 is a perspective view of an arrangement and embodiment of a
  • Fig. 4A, 4B, 4C, 4D, 4E, 4F are sectional side and sectional views, respectively
  • Fig. 5A, 5B respectively in a sectional side view and a sectional top view and in sectional detail views of support units on a container for accommodating a radial flow apparatus according to one of the exemplary embodiments;
  • Fig. 6A, 6B respectively in a sectional side view and a sectional plan view of an axially flow-through container compared to a radially flow-through container with a radial flow inserting device positioned therein according to one of the embodiments.
  • Fig. 1 shows a container 1, in particular a pressure vessel with a wall 1.1 and an inner circumferential surface 1.11.
  • the container extends along a central longitudinal axis M.
  • a bed 7 can be arranged, in particular after a radial flow insert device 10 has been mounted therein, so that a bed reactor 20 is formed, which can be used for example in an ammonia plant.
  • an inlet 3.1 is arranged in the form of an inlet nozzle, in particular centrally.
  • an outlet 5.1 in the form of an outlet nozzle is arranged on a hemispherical bottom 5.
  • a gas collection unit 13 is coupled in the manner of an axially and centrally oriented tube or integral with it. Both the head 3 and the bottom 5 may also have an elliptical geometry.
  • the radial flow insert device 10 comprises a plurality of gas distribution units 11 in the form of axially and eccentrically aligned tubes, wherein twelve tubes are shown here by way of example. Preferably, the number is even greater, in particular in the range of 50 to 100 pieces.
  • the Gasverteilrittritt 11 direct the gas within the bed at least over a certain height section past the bed, and thereby form a partial axial bypass of the bed. Within the bed so a plurality of Axialbypass- units 11 are provided.
  • Gas flows from a respective inlet 11.3 through a cavity defined by the tube 11.4 in the axial direction downwards, and depending on the pressure conditions in the radial direction through a Radial screenlass Weg 11.5, in particular perforation in the wall of the tube.
  • the tubes each have an enclosed end 11.7, which can cause the gas to flow in any case in the radial direction.
  • the gas collecting unit 13 has an upper closed end 13.3 and defines a particularly cylindrical cavity 13.4, through which the gas can flow in the axial direction through an outlet 13.7, after it has passed in the radial direction a Radial facilitator Quilt 13.5, in particular perforation of the gas collection unit 13.
  • the gas distribution units 11 define a plurality of radial inflow points zrl l radially inwardly into the bed (view A-A). Strictly axially in the axial direction z, the flow, after passing through the gas distribution units 11, only in this outlet 13.7 aligned.
  • the gas distribution units 11 and optionally also the gas collection unit 13 are aligned relative to one another by means of a plurality of support units 15, in particular support rings, and positioned in the container 1.
  • the support units 15 have corresponding openings 15.11 or holes for the Gas distribution units, in particular according to the outer contour of the gas distribution units. Furthermore, an opening 15.13 may optionally be provided for the gas collection unit.
  • a bulkhead 17 is positioned, in particular a separating bulkhead or a gas-tight cover plate.
  • the height position zl7 of the bulkhead 17 in this example corresponds to the upper (closed) end 13.3 of the gas collection unit, but may optionally be arranged above or below, depending on the configuration of the end 13.3 or depending on the design and arrangement of passages 13.51 in the gas collection unit.
  • openings 17.11 may be formed for the gas distribution unit and an opening 17.13 for the gas collection unit.
  • the gas distribution units 11 are arranged in the circumferential direction t at a distance dtl to each other, which results in dependence on the number and diameter of the gas distribution 11, and which also depends on the size of the pellets of the bed 7.
  • the distance dtl is approximately in the range of 1.5 times the diameter of the gas distribution units 11.
  • the outer walls of the gas distribution units 11 are arranged at a distance corresponding to their radius from each other. In the event that particularly many or particularly narrow Gasverteilhowen 11 are provided, the distance may also be larger or smaller.
  • a wall 11.1 and a lateral surface 11.11 and individual passages 11.51 of the respective gas distribution units 11 are shown.
  • the gas collection unit 13 has a wall 13.1, a lateral surface 13.11 and individual passages 13.51.
  • Fig. 2 shows a radial flow apparatus 110 according to a further embodiment.
  • a bulkhead is not provided here.
  • An uppermost height position z5 of the radial passage structure 13.5 of the gas collecting unit 13 is approx. 20% lower than an upper open end or as the respective inlet 11.3 of the gas distribution units 11.
  • the flow path SP of the gas is schematically indicated by the arrows with the arrowed end made.
  • the bed height zl can thereby at least approximately correspond to the height position zl3 of the closed end of the gas collecting unit.
  • Fig. 3 shows the eccentric arrangement of the gas distribution units 11 in detail.
  • a radial distance dr 1 measured in the radial direction r between the respective gas distribution unit 11 and the inner lateral surface 1.11 of the container 1 is in this example significantly smaller than the radius of the gas distribution unit 11, in particular approx. half the size. Depending on the size of the pellets of the bed 7, the distance may also be larger or smaller.
  • the plurality of height positions z51 of the individual passages are shown, starting from which the radial profile can form in the respective height position.
  • Fig. 4A, 4B, 4C, 4D, 4E, 4F assembly steps are shown.
  • Fig. 4A a container 1 without a fill is shown. The bed was removed.
  • Fig. 4A a container 1 without a fill is shown. The bed was removed.
  • FIG. 4B a centrally mounted in the container on brackets 9.1 support ring 9.3 is shown.
  • the radial flow service device 10 can thus be mounted on a support unit 9, in particular comprising at least one bracket 9.1 (bearing wall projection) and at least one support ring 9.3 in the container 1.
  • Fig. 4C Gasverteilizien 11 are shown, which are positively and optionally also frictionally supported on the support ring 9.3.
  • Fig. 4D support units 15 are additionally mounted.
  • the central gas collection unit 13 is mounted.
  • a bulkhead 17 is provided for placement on top of the bed. The bulkhead 17 is preferably mounted after introduction of the bed (not shown).
  • the radial flow insert device 10 can be mounted in the container 1 as follows: After mounting at least one support ring 9.3, the gas distribution units 11 are fixed with suitable clamps or clamps (not shown). Support rings 15 above and below serve the additional positioning and alignment, so that a radial flow inserting device 10 can be realized in the manner of a gas distribution pipe rack with a defined distance from the wall. Finally, provided for the gas outlet central tube 13 is mounted. After filling with catalyst, a cover 17 is mounted depending on the type of reactor. Instead of a cover, ceramic balls or a hold-down grid (not shown) may be provided become. Installation for a container with foot support ring (Fig. 5B) is possible with modifications in a similar manner.
  • FIG. 5A shows a container 1 with brackets 9.1 centered therein in the circumferential direction at several positions on the wall 1.1. On these consoles, a support ring or a support unit can be attached.
  • a bottom / foot support ring 9.3 is shown on which a radial flow device (not shown) can be positioned and supported.
  • FIG. 6A an axially flow-through container 1 is shown, in which two bedding levels are provided, so with two catalyst beds above the other, the upper bed is delimited by a support ring 9.3 and a bulkhead or support grid with steel support from the lower bed.
  • the bulkhead and / or the support ring can be supported on, for example, eight pieces of brackets.
  • the brackets can be welded to the container wall.
  • Fig. 6B shows the same container 1, but now converted with a radial flow insert device 10 positioned therein.
  • console especially supporting wall projection

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

L'invention concerne un dispositif d'insertion à écoulement radial (10 ; 110) destiné à prédéterminer au moins un trajet d'écoulement (SP) dans une direction radiale vers l'intérieur à travers un lit (7) de sorbant situé dans un récipient (1) traversé par un gaz d'un réacteur à lit (20). Le dispositif d'insertion à écoulement radial a une structure modulaire constituée d'une pluralité d'unités de distribution de gaz (11) pouvant être traversées axialement et pouvant être disposées longitudinalement et excentriquement dans le lit et ayant une structure de traversée radiale (11.5). Un/le trajet d'écoulement (SP), défini par le dispositif d'insertion à écoulement radial, peut être aligné par les unités de distribution de gaz radialement vers l'intérieur sur un axe longitudinal central (M) du récipient, en particulier à chaque fois à partir d'une pluralité de positions en hauteur (z51) réparties dans une direction axiale le long des unités de distribution de gaz. En outre, l'invention concerne un procédé de montage d'un dispositif d'insertion à écoulement radial dans un tel récipient.
PCT/EP2018/061853 2017-05-17 2018-05-08 Dispositif d'insertion à écoulement radial pour prédéterminer au moins un trajet d'écoulement radial dans un réacteur à lit et procédé de montage et utilisation Ceased WO2018210629A1 (fr)

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DE102017208319.0 2017-05-17
DE102017208319.0A DE102017208319A1 (de) 2017-05-17 2017-05-17 Radialstromeinsatzvorrichtung zum Vorgeben wenigstens eines radialen Strömungspfades in einem Schüttungsreaktor sowie Montageverfahren und Verwendung

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CN111992146B (zh) * 2020-08-27 2022-08-09 江苏正丹化学工业股份有限公司 一种乙烯基甲苯轴径向脱氢反应器

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EP0265654A1 (fr) 1986-09-25 1988-05-04 Ammonia Casale S.A. Procédé et appareillage pour la fabrication de parois de paniers remplis de catalyseurs destinées aux réacteurs de synthèse hétérogène
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EP0372453A2 (fr) 1988-12-09 1990-06-13 Ammonia Casale S.A. Methode de rajustement in-situ d'un réacteur de conversion de monoxide de carbone du type flux axial.
JPH03131336A (ja) 1989-10-17 1991-06-04 Chiyoda Corp ガス反応器
EP0446592B1 (fr) 1990-02-27 1994-05-18 Ammonia Casale S.A. Structure de paroi pour la distribution de gaz dans des lits catalytiques et pour un support à dimensions minimales de catalyseur dans des réactions de synthèse hétérogène
EP1432507B1 (fr) 2001-10-04 2010-08-04 Methanol Casale S.A. Reacteur catalytique heterogene avec cartouche catalytique modulaire
EP2374531A1 (fr) 2010-03-29 2011-10-12 Toyo Engineering Corporation Réacteur
EP3037165A1 (fr) 2014-12-23 2016-06-29 Casale SA Procéde de réalisation de parois interieures d'un réacteur catalytique
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DE3318098A1 (de) 1983-05-18 1984-11-22 Linde Ag, 6200 Wiesbaden Verfahren und reaktor zur durchfuehrung einer endo- oder exothermen reaktion
EP0265654A1 (fr) 1986-09-25 1988-05-04 Ammonia Casale S.A. Procédé et appareillage pour la fabrication de parois de paniers remplis de catalyseurs destinées aux réacteurs de synthèse hétérogène
DE3817303A1 (de) * 1987-05-20 1988-12-15 Haldor Topsoe As Modulare rohrverzweigungseinrichtung zur verteilung eines gasflusses in einem reaktor
EP0372453A2 (fr) 1988-12-09 1990-06-13 Ammonia Casale S.A. Methode de rajustement in-situ d'un réacteur de conversion de monoxide de carbone du type flux axial.
JPH03131336A (ja) 1989-10-17 1991-06-04 Chiyoda Corp ガス反応器
EP0446592B1 (fr) 1990-02-27 1994-05-18 Ammonia Casale S.A. Structure de paroi pour la distribution de gaz dans des lits catalytiques et pour un support à dimensions minimales de catalyseur dans des réactions de synthèse hétérogène
EP1432507B1 (fr) 2001-10-04 2010-08-04 Methanol Casale S.A. Reacteur catalytique heterogene avec cartouche catalytique modulaire
EP2374531A1 (fr) 2010-03-29 2011-10-12 Toyo Engineering Corporation Réacteur
EP3037165A1 (fr) 2014-12-23 2016-06-29 Casale SA Procéde de réalisation de parois interieures d'un réacteur catalytique
WO2016209790A1 (fr) * 2015-06-25 2016-12-29 Uop Llc Conduits coniques pour réacteurs
EP3219384A1 (fr) * 2016-03-16 2017-09-20 Casale SA Parois pour lits catalytiques de réacteurs à écoulement axial ou radial

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