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WO2018124169A1 - Composition de résine, préimprégné, carte stratifiée, carte stratifiée plaquée de feuille métallique, carte de circuit imprimé et carte de circuit imprimé multicouche - Google Patents

Composition de résine, préimprégné, carte stratifiée, carte stratifiée plaquée de feuille métallique, carte de circuit imprimé et carte de circuit imprimé multicouche Download PDF

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Publication number
WO2018124169A1
WO2018124169A1 PCT/JP2017/046860 JP2017046860W WO2018124169A1 WO 2018124169 A1 WO2018124169 A1 WO 2018124169A1 JP 2017046860 W JP2017046860 W JP 2017046860W WO 2018124169 A1 WO2018124169 A1 WO 2018124169A1
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WO
WIPO (PCT)
Prior art keywords
group
resin composition
mass
parts
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2017/046860
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English (en)
Japanese (ja)
Inventor
翔平 山口
知樹 濱嶌
孝史 久保
環 伊藤
英祐 志賀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Gas Chemical Co Inc
Original Assignee
Mitsubishi Gas Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Co Inc filed Critical Mitsubishi Gas Chemical Co Inc
Priority to KR1020197004770A priority Critical patent/KR102058827B1/ko
Priority to CN201780081383.1A priority patent/CN110114407B/zh
Priority to JP2018530936A priority patent/JP6452083B2/ja
Publication of WO2018124169A1 publication Critical patent/WO2018124169A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/36—Amides or imides
    • C08F222/40—Imides, e.g. cyclic imides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00—Layered products comprising a layer of metal
    • B32B15/14—Layered products comprising a layer of metal next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • B32B17/04—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments bonded with or embedded in a plastic substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/061—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/067—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of fibres or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/28—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer impregnated with or embedded in a plastic substance
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014—Nitrogen containing compounds
    • C08G59/4042—Imines; Imides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3415—Five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00—Printed circuits
    • H05K1/02—Details
    • H05K1/03—Use of materials for the substrate
    • H05K1/0313—Organic insulating material
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00—Apparatus or processes for manufacturing printed circuits
    • H05K3/46—Manufacturing multilayer circuits
    • H05K3/4611—Manufacturing multilayer circuits by laminating two or more circuit boards
    • H05K3/4626—Manufacturing multilayer circuits by laminating two or more circuit boards characterised by the insulating layers or materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00—Condition, form or state of the layers or laminate
    • B32B2305/08—Reinforcements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00—Electrical equipment
    • B32B2457/08—PCBs, i.e. printed circuit boards
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2261/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G2261/10—Definition of the polymer structure
    • C08G2261/13—Morphological aspects
    • C08G2261/136—Comb-like structures

Definitions

  • the present invention relates to a resin composition, a prepreg, a laminate, a metal foil-clad laminate, a printed wiring board, and a multilayer printed wiring board.
  • One of the measures is to reduce the thermal expansion of the insulating layer used for the printed wiring board. This is a technique for suppressing warpage by bringing the thermal expansion coefficient of a printed wiring board close to the thermal expansion coefficient of a semiconductor element, and is currently being actively worked on (see, for example, Patent Documents 1 to 3).
  • methods for suppressing the warpage of the semiconductor plastic package include increasing the rigidity of the laminated board (higher rigidity) and increasing the glass transition temperature of the laminated board (high Tg). (For example, see Patent Documents 4 and 5).
  • JP 2013-216684 A Japanese Patent No. 3173332 JP 2009-035728 A JP 2013-001807 A JP2011-177892A
  • the present invention has a high glass transition temperature (high Tg) or no clear glass transition temperature (so-called Tg-less), and sufficiently reduces the warpage of a printed wiring board, particularly a multilayer coreless substrate. It is an object to provide a resin composition capable of achieving low warpage, and a prepreg, a laminate, a metal foil-clad laminate, a printed wiring board, and a multilayer printed wiring board using the resin composition. And
  • the present inventors have heretofore been concerned about the warping behavior of a printed wiring board for a semiconductor plastic package.
  • a resin composition capable of realizing a higher elastic modulus maintenance factor has been effective, it has been found that this is not always the case.
  • the present inventors solved the above problems by using a specific epoxy resin and / or comb-shaped graft polymer in a predetermined content in addition to the maleimide compound and the allyl group-containing compound. The present inventors have found that this can be done and have completed the present invention.
  • the content of the epoxy resin (C) composed of the bisphenol A type structural unit and the hydrocarbon-based structural unit or the comb-shaped graft polymer (D) in the resin composition is 3 to 25 parts by mass with respect to 100 parts by mass of the resin solid content.
  • the total content of the epoxy resin (C) composed of the bisphenol A-type structural unit and the hydrocarbon-based structural unit and the comb-shaped graft polymer (D) in the resin composition is 3 to 3 parts per 100 parts by mass of the resin solid content. 25 parts by mass [1]
  • the epoxy equivalent of the epoxy resin (C) composed of the bisphenol A-type structural unit and the hydrocarbon-based structural unit is 400 g / eq. That's it, The resin composition as described in [1] or [2].
  • the epoxy resin (C) composed of the bisphenol A structural unit and the hydrocarbon-based structural unit is represented by the following formula (1).
  • R 1 and R 2 each independently represent a hydrogen atom or a methyl group
  • R 3 to R 6 each independently represent a hydrogen atom, a methyl group, a chlorine atom, or bromine.
  • X represents an atom
  • X represents an ethyleneoxyethyl group, a di (ethyleneoxy) ethyl group, a tri (ethyleneoxy) ethyl group, a propyleneoxypropyl group, a di (propyleneoxy) propyl group, a tri (propyleneoxy) propyl group, or Represents an alkylene group having 2 to 15 carbon atoms, and n represents a natural number.
  • the epoxy resin (C) composed of the bisphenol A-type structural unit and the hydrocarbon-based structural unit is such that X in the formula (1) is an ethylene group.
  • the allyl group-containing compound (B) is an allylphenol derivative (E) and / or an alkenyl-substituted nadiimide compound (F).
  • E allylphenol derivative
  • F alkenyl-substituted nadiimide compound
  • the alkenyl-substituted nadiimide compound (F) includes a compound represented by the following formula (6).
  • each R 1 independently represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms
  • R 2 represents an alkylene group having 1 to 6 carbon atoms, a phenylene group, a biphenylene group, or a naphthylene.
  • R 3 represents a methylene group, an isopropylidene group, or a substituent represented by CO, O, S, or SO 2 .
  • each R 4 independently represents an alkylene group having 1 to 4 carbon atoms or a cycloalkylene group having 5 to 8 carbon atoms.
  • maleimide compound (A) examples include bis (4-maleimidophenyl) methane, 2,2-bis- ⁇ 4- (4-maleimidophenoxy) -phenyl ⁇ propane, and bis (3-ethyl-5methyl-4-maleimidophenyl).
  • maleimide compound (A) examples include bis (4-maleimidophenyl) methane, 2,2-bis- ⁇ 4- (4-maleimidophenoxy) -phenyl ⁇ propane, and bis (3-ethyl-5methyl-4-maleimidophenyl).
  • a maleimide compound represented by the following formula (3) [1] The resin composition as described in any one of [7].
  • R 5 each independently represents a hydrogen atom or a methyl group, and n 1 represents an integer of 1 or more.
  • the comb-shaped graft polymer (D) has a weight average molecular weight Mw of 1.0 ⁇ 10 5 to 3.5 ⁇ 10 5 .
  • the resin composition as described in any one of [8].
  • the cyanate ester compound (G) includes a compound represented by the following formula (4) and / or (5): [10] The resin composition according to [10].
  • R 6 each independently represents a hydrogen atom or a methyl group, and n 2 represents an integer of 1 or more.
  • R 7 each independently represents a hydrogen atom or a methyl group, and n 3 represents an integer of 1 or more.
  • the content of the filler (I) in the resin composition is 100 to 700 parts by mass with respect to 100 parts by mass of the resin solid content.
  • the resin composition according to [13] The resin composition according to [13].
  • a substrate The resin composition according to any one of [1] to [14], impregnated or coated on the substrate; Prepreg with
  • the substrate is one or more selected from the group consisting of E glass fiber, D glass fiber, S glass fiber, T glass fiber, Q glass fiber, L glass fiber, NE glass fiber, HME glass fiber, and organic fiber. Made up of fibers, [15] The prepreg according to [15].
  • An insulating layer A conductor layer formed on the surface of the insulating layer; Have The insulating layer includes the resin composition according to any one of [1] to [14]; Printed wiring board.
  • a multilayer printed wiring board having:
  • the present invention has a high glass transition temperature (high Tg) or no clear glass transition temperature (Tg-less), and sufficiently reduces the warpage of a printed wiring board, particularly a multilayer coreless substrate ( A resin composition capable of achieving low warpage), and a prepreg, a laminate, a metal foil-clad laminate, a printed wiring board, and a multilayer printed wiring board using the resin composition can be provided.
  • high Tg glass transition temperature
  • Tg-less no clear glass transition temperature
  • resin solid content means a component in the resin composition excluding the solvent and filler, unless otherwise specified, and “resin solid content 100 parts by mass” means resin The total of the components excluding the solvent and the filler in the composition is 100 parts by mass.
  • the resin composition of the present embodiment comprises a maleimide compound (A), an allyl group-containing compound (B), an epoxy resin (C) comprising a bisphenol A-type structural unit and a hydrocarbon-based structural unit and / or a comb-shaped graft polymer ( D), and the content of the epoxy resin (C) or the comb-shaped graft polymer (D) composed of a bisphenol A structural unit and a hydrocarbon-based structural unit in the resin composition is 100 parts by mass of resin solid content 5 to 25 parts by mass.
  • the resin composition contains such a composition, for example, in a cured product obtained by curing a prepreg, the resin composition has a high glass transition temperature (high Tg) or no clear glass transition temperature (Tg-less). ), And the warpage of the printed wiring board, particularly the multilayer coreless substrate, can be sufficiently reduced (low warpage can be achieved).
  • high Tg glass transition temperature
  • Tg-less clear glass transition temperature
  • the maleimide compound (A) is not particularly limited as long as it has one or more maleimide groups in the molecule.
  • maleimide compounds represented by the following formula (3) At least one selected from the group consisting of maleimide compounds represented by the following formula (3) is preferred, and maleimide compounds represented by the following formula (3) are particularly preferred.
  • a maleimide compound (A) By containing such a maleimide compound (A), the thermal expansion coefficient of the obtained cured product is further lowered, and the heat resistance and the glass transition temperature (Tg) tend to be further improved.
  • the maleimide compound (A) may be used alone or in combination of two or more.
  • R 5 each independently represents a hydrogen atom or a methyl group, preferably a hydrogen atom.
  • n1 represents an integer greater than or equal to 1 , Preferably it is an integer of 10 or less, More preferably, it is an integer of 7 or less.
  • the content of the maleimide compound (A) is preferably 10 to 70 parts by mass, more preferably 20 to 60 parts by mass, and more preferably 25 to 55 parts by mass with respect to 100 parts by mass of the resin solid content. More preferably 35 to 55 parts by mass, particularly preferably 35 to 45 parts by mass.
  • content of a maleimide compound (A) exists in the said range, it exists in the tendency for the thermal expansion coefficient of the hardened
  • the allyl group-containing compound (B) is not particularly limited as long as it is a compound having one or more allyl groups in the molecule, but may further have a reactive functional group other than the allyl group.
  • the reactive functional group other than the allyl group is not particularly limited, and examples thereof include a cyanate group (cyanate ester group), a hydroxyl group, an epoxy group, an amine group, an isocyanate group, a glycidyl group, and a phosphate group.
  • cyanate group cyanate group
  • a hydroxyl group a hydroxyl group
  • an epoxy group cyanate group
  • cyanate group cyanate group
  • the allyl group-containing compound (B) one type may be used alone, or two or more types may be used in combination.
  • the reactive functional groups other than the allyl group may be the same or different.
  • the allyl group-containing compound (B) includes an allyl group-containing compound whose reactive functional group is a cyanate group (cyanate group) and an allyl group-containing compound whose reactive functional group is an epoxy group. It is preferable.
  • an allyl group-containing compound having a reactive functional group other than an allyl group and / or an alkenyl-substituted nadiimide compound (F) described later as the allyl group-containing compound (B).
  • the glass transition temperature (Tg) the thermal expansion coefficient, and the thermal conductivity tend to be improved.
  • allyl group-containing compound (B) it is particularly preferable to use an allylphenol derivative (E) and / or an alkenyl-substituted nadiimide compound (F) described later.
  • Tg glass transition temperature
  • Tg thermal expansion coefficient
  • T conductivity tend to be further improved.
  • the content of the allyl group-containing compound (B) is preferably 1 to 90 parts by mass, more preferably 10 to 80 parts by mass, and more preferably 20 to 75 parts by mass with respect to 100 parts by mass of the resin solid content. Part, more preferably 25 to 40 parts by weight, and particularly preferably 25 to 35 parts by weight.
  • the content of the allyl group-containing compound (B) is within the above range, the flexibility, bending strength, bending elastic modulus, glass transition temperature (Tg), thermal expansion coefficient, thermal conductivity, and There exists a tendency for copper foil peel strength to improve more.
  • the allylphenol derivative (E) is not particularly limited as long as it is a compound in which an allyl group and a phenolic hydroxyl group are directly bonded to an aromatic ring, and a derivative thereof.
  • bisphenol in which an aromatic ring hydrogen atom is substituted with an allyl group A modified bisphenol compound in which the hydrogen atom of the aromatic ring is substituted with an allyl group, and the phenolic hydroxyl group is modified with a reactive functional group other than the hydroxyl group in the reactive functional group other than the above-mentioned allyl group,
  • Specific examples include compounds represented by the following formula (2), and more specifically, diallyl bisphenol A, a cyanate ester compound of diallyl bisphenol A, and diallyl bisphenol A type epoxy.
  • each Ra independently represents a reactive substituent other than an allyl group.
  • the compound represented by the formula (2) is not particularly limited, and examples thereof include a compound represented by the following formula (2a) and / or a compound represented by the following formula (2b).
  • a compound represented by the following formula (2a) and / or a compound represented by the following formula (2b) By using such an allylphenol derivative (E), bending strength, bending elastic modulus, glass transition temperature (Tg), thermal expansion coefficient, thermal conductivity, and copper foil peel strength tend to be further improved.
  • bisphenol A bisphenol A
  • bisphenol AP bisphenol AF
  • bisphenol B bisphenol BP
  • bisphenol C bisphenol C
  • bisphenol E bisphenol F
  • bisphenol G bisphenol M
  • bisphenol S bisphenol P Bisphenol PH
  • bisphenol TMC bisphenol TMC
  • bisphenol Z bisphenol Z.
  • bisphenol A is preferred.
  • the number of allyl groups in one molecule of the allylphenol derivative (E) is preferably 1 to 5, more preferably 2 to 4, and still more preferably 2.
  • the bending strength, bending elastic modulus, copper foil peel strength, glass transition temperature (Tg) are further improved, and the thermal expansion coefficient is increased. It tends to be low and excellent in thermal conductivity.
  • the number of reactive functional groups other than the allyl group in one molecule of the allylphenol derivative (E) is preferably 1 to 5, more preferably 2 to 4, and still more preferably 2.
  • the bending strength, bending elastic modulus, copper foil peel strength, glass transition temperature (Tg) are further improved, and the thermal expansion coefficient is increased. It tends to be low and excellent in thermal conductivity.
  • the preferable range of the content of the allylphenol derivative (E) conforms to the content of the allyl group-containing compound (B) described above.
  • alkenyl-substituted nadiimide compound (F) is not particularly limited as long as it is a compound having one or more alkenyl-substituted nadiimide groups in the molecule. Among these, the compound represented by the following formula (6) is preferable.
  • each R 1 independently represents a hydrogen atom or an alkyl group having 1 to 6 carbon atoms
  • R 2 represents an alkylene group having 1 to 6 carbon atoms, a phenylene group, a biphenylene group, or a naphthylene.
  • R 3 represents a methylene group, an isopropylidene group, or a substituent represented by CO, O, S, or SO 2 .
  • each R 4 independently represents an alkylene group having 1 to 4 carbon atoms or a cycloalkylene group having 5 to 8 carbon atoms.
  • the alkenyl-substituted nadiimide compound (F) is more preferably a compound represented by the following formula (9) and / or (10).
  • a commercially available alkenyl-substituted nadiimide compound (F) can also be used.
  • examples of commercially available products include, but are not limited to, for example, BANI-M (manufactured by Maruzen Petrochemical Co., Ltd., compound represented by formula (9)), BANI-X (manufactured by Maruzen Petrochemical Co., Ltd.) A compound represented by the formula (10)) and the like. These may be used alone or in combination of two or more.
  • the content of the alkenyl-substituted nadiimide compound (F) is preferably 20 to 50 parts by weight, more preferably 20 to 40 parts by weight, and particularly preferably 25 to 35 parts by weight with respect to 100 parts by weight of the resin solid content. Part. More preferably, the total content of the allylphenol derivative (E) and the alkenyl-substituted nadiimide compound (F) is preferably 25 to 45 parts by mass with respect to 100 parts by mass of the resin solid content, and more preferably Is 30 to 45 parts by mass. When the content of the alkenyl-substituted nadiimide compound (F) is within the above range, the thermal expansion coefficient of the obtained cured product is further decreased, and the heat resistance tends to be further improved.
  • Epoxy resin consisting of bisphenol A structural unit and hydrocarbon-based structural unit (C) The epoxy resin (C) composed of a bisphenol A structural unit and a hydrocarbon structural unit is a compound having one or more bisphenol A structural units and one or more hydrocarbon structural units in the molecule. There is no particular limitation. Among these, the compound represented by the following formula (1) is preferable.
  • an epoxy resin (C) composed of such a bisphenol A structural unit and a hydrocarbon-based structural unit the storage elastic modulus E ′ during heating of the resulting cured product tends to be a value suitable for warpage suppression. is there.
  • R 1 and R 2 each independently represent a hydrogen atom or a methyl group
  • R 3 to R 6 each independently represent a hydrogen atom, a methyl group, or a chlorine atom.
  • X represents an ethyleneoxyethyl group, a di (ethyleneoxy) ethyl group, a tri (ethyleneoxy) ethyl group, a propyleneoxypropyl group, a di (propyleneoxy) propyl group, or a tri (propyleneoxy) propyl group.
  • Group represents an alkylene group having 2 to 15 carbon atoms
  • n represents a natural number.
  • epoxy resin (C) comprising the above-described bisphenol A structural unit and hydrocarbon structural unit can be used.
  • Commercially available products are not particularly limited.
  • EPICLON EXA-4850-150 (a compound having a structure represented by the formula (1) manufactured by DIC Corporation), EPICLON EXA-4816 (DIC Corporation) And a compound in which X in formula (1) is an ethylene group). These may be used alone or in combination of two or more.
  • the content of the epoxy resin (C) composed of the bisphenol A type structural unit and the hydrocarbon-based structural unit is 3 to 25 parts by mass, preferably 5 to 25 parts per 100 parts by mass of the resin solid content. Parts by mass, more preferably 5 to 20 parts by mass, and even more preferably 10 to 20 parts by mass.
  • the storage elastic modulus E ′ during heating of the obtained cured product is a value suitable for warpage suppression. It tends to be.
  • the epoxy equivalent of the epoxy resin (C) composed of a bisphenol A-type structural unit and a hydrocarbon-based structural unit is preferably 400 g / eq. Or more, more preferably 400 to 800 g / eq. And more preferably 400 to 500 g / eq. It is.
  • the storage elastic modulus E ′ during heating of the resulting cured product is a value suitable for warpage suppression. It tends to be.
  • Comb-shaped graft polymer (D) As the comb-shaped graft polymer (D), one or more polymer side chains (branched parts) are present on a polymer main chain (trunk portion; ie, (meth) acryl main chain) having a structural unit derived from a (meth) acrylic monomer.
  • the constitutional unit derived from the silicone monomer is not particularly limited as long as it is a graft-polymerized (silicone-modified (meth) acrylic resin compound), and may have a functional group in the (meth) acrylic main chain.
  • This functional group is not particularly limited, and examples thereof include an OH group and a carboxyl group, and among these, a carboxyl group is preferable.
  • the (meth) acrylic monomer is not particularly limited, and examples thereof include acrylic acid, methacrylic acid, and derivatives thereof. Furthermore, although it does not specifically limit as said silicone monomer, For example, the monomer etc. which have a reactive functional group in the one terminal of the siloxane frame
  • skeleton of polydimethylsiloxane are mentioned.
  • the storage elastic modulus E 'at the time of heating of the obtained cured product tends to be a value suitable for warpage suppression.
  • the weight average molecular weight Mw of the comb-shaped graft polymer (D) is preferably 1.0 ⁇ 10 5 to 3.5 ⁇ 10 5 , more preferably 1.0 ⁇ 10 5 to 2.0 ⁇ 10 5 , More preferably, it is 1.0 ⁇ 10 5 to 1.5 ⁇ 10 5 .
  • the measuring method of the weight average molecular weight Mw is not particularly limited, but can be measured by, for example, the method described in the examples of the present specification.
  • the method for producing the comb-shaped graft polymer (D) is not particularly limited.
  • a method of grafting an acrylic resin and one-end silicone oil by radical polymerization in the presence of a polymerization initiator in an organic solvent Is mentioned.
  • commercially available products can be used as the comb-shaped graft polymer (D). Examples of commercially available products include US-350 and US-380 of the Saimak (registered trademark) series of Toa Gosei Co., Ltd. Product name). These may be used alone or in combination of two or more.
  • the content of the comb-shaped graft polymer (D) is 3 to 25 parts by weight, preferably 5 to 25 parts by weight, more preferably 5 to 20 parts by weight with respect to 100 parts by weight of the resin solid content. Part, particularly preferably 10 to 20 parts by weight.
  • the storage elastic modulus E ′ during heating of the resulting cured product tends to be a value suitable for warpage suppression.
  • the total content of the epoxy resin (C) composed of a bisphenol A type structural unit and a hydrocarbon-based structural unit and the comb-shaped graft polymer (D) in the resin composition is 100 parts by mass of resin solid content. Is preferably 3 to 25 parts by mass, more preferably 5 to 25 parts by mass, more preferably 5 to 20 parts by mass, and still more preferably 10 to 20 parts by mass. Heating of the cured product obtained when the total content of the resin composition of the epoxy resin (C) composed of the bisphenol A type structural unit and the hydrocarbon-based structural unit and the comb-shaped graft polymer (D) is within the above range.
  • the storage elastic modulus E ′ at the time tends to be a suitable value due to warpage suppression.
  • the resin composition of this embodiment may further contain a cyanate ester compound (G).
  • the cyanate ester compound (G) is not particularly limited as long as it is a cyanate ester compound other than the above-mentioned allylphenol derivative (E).
  • each R 6 independently represents a hydrogen atom or a methyl group, and among them, a hydrogen atom is preferable.
  • n 2 represents an integer of 1 or more. The upper limit value of n 2 is usually 10, and preferably 6.
  • each R 7 independently represents a hydrogen atom or a methyl group, and among them, a hydrogen atom is preferable.
  • n 3 represents an integer of 1 or more. upper limit of n 3 is usually a 10, preferably a 7.
  • the cyanate ester compound (G) is composed of a naphthol aralkyl cyanate ester represented by the formula (4), a novolac cyanate ester represented by the formula (5), and a biphenylaralkyl cyanate ester. It is preferable to include one or more selected from the group, and one or more selected from the group consisting of the naphthol aralkyl cyanate represented by the formula (4) and the novolak cyanate ester represented by the formula (5) It is more preferable to contain.
  • a cyanate ester compound (G) By using such a cyanate ester compound (G), a cured product that is superior in flame retardancy, higher curability, and lower thermal expansion coefficient tends to be obtained.
  • the production method of these cyanate ester compounds (G) is not particularly limited, and a known method can be used as a synthesis method of the cyanate ester compounds.
  • the known method is not particularly limited.
  • a method of reacting a phenol resin and cyanogen halide in an inert organic solvent in the presence of a basic compound, a salt of the phenol resin and the basic compound, water examples thereof include a method of forming in a solution to be contained, and then causing the obtained salt and cyanogen halide to undergo a two-phase interface reaction.
  • the phenol resin used as a raw material for these cyanate ester compounds (G) is not particularly limited, and examples thereof include naphthol aralkyl type phenol resins, novolak type phenol resins, and biphenyl aralkyl type phenol resins represented by the following formula (11). Can be mentioned.
  • R 8 each independently represents a hydrogen atom or a methyl group, and among these, a hydrogen atom is preferable.
  • n 4 represents an integer of 1 or more. The upper limit value of n 4 is usually 10 and preferably 6.
  • the naphthol aralkyl type phenol resin represented by the formula (11) can be obtained by condensing a naphthol aralkyl resin and cyanic acid.
  • the naphthol aralkyl type phenol resin is not particularly limited, and examples thereof include naphthols such as ⁇ -naphthol and ⁇ -naphthol, p-xylylene glycol, ⁇ , ⁇ '-dimethoxy-p-xylene, and 1,4- Examples thereof include those obtained by reaction with benzenes such as di (2-hydroxy-2-propyl) benzene.
  • the naphthol aralkyl cyanate ester can be selected from those obtained by condensing the naphthol aralkyl resin obtained as described above and cyanic acid.
  • the content of the cyanate ester compound (G) is preferably 0 to 10 parts by mass, more preferably 0 to 5 parts by mass with respect to 100 parts by mass of the resin solid content.
  • the content of the cyanate ester compound is within the above range, the heat resistance and chemical resistance of the obtained cured product tend to be further improved.
  • the resin composition of this embodiment may further contain an epoxy compound (H) other than the epoxy resin (C) composed of the above-described bisphenol A-type structural unit and hydrocarbon-based structural unit.
  • the epoxy compound (H) is not particularly limited as long as it is a compound having two or more epoxy groups in one molecule.
  • bisphenol A type epoxy resin bisphenol E type epoxy resin, bisphenol F type epoxy resin, Bisphenol S type epoxy resin, phenol novolac type epoxy resin, bisphenol A novolak type epoxy resin, cresol novolac type epoxy resin, biphenyl type epoxy resin, naphthalene type epoxy resin, anthracene type epoxy resin, trifunctional phenol type epoxy resin, tetrafunctional phenol Type epoxy resin, glycidyl ester type epoxy resin, phenol aralkyl type epoxy resin, biphenyl aralkyl type epoxy resin, aralkyl novolak type epoxy resin, naphthol aralkyl type Epoxy resins, dicyclopentadiene type epoxy resin, a polyol type epoxy resin, isocyanurate ring-containing epoxy resin, or their halides.
  • the epoxy compound (H) is other than the allyl group-containing compound (B) having an epoxy group.
  • the content of the epoxy compound (H) is preferably 0 to 30 parts by mass, and more preferably 0 to 10 parts by mass with respect to 100 parts by mass of the resin solid content.
  • content of an epoxy compound (H) exists in the said range, it exists in the tendency for the softness
  • the resin composition of this embodiment may further contain a filler (I).
  • a filler I
  • filler I
  • an inorganic filler and an organic filler are mentioned, It is preferable that both contain an inorganic filler, and an organic filler is used with an inorganic filler. It is preferable.
  • the inorganic filler examples include, but are not limited to, silicas such as natural silica, fused silica, synthetic silica, amorphous silica, aerosil, and hollow silica; silicon compounds such as white carbon; titanium white, zinc oxide, magnesium oxide, Metal oxides such as zirconium oxide; metal nitrides such as boron nitride, agglomerated boron nitride, silicon nitride, and aluminum nitride; metal sulfates such as barium sulfate; aluminum hydroxide, aluminum hydroxide heat-treated products (heating aluminum hydroxide) Treated and reduced in part of crystal water), metal hydrates such as boehmite and magnesium hydroxide; molybdenum compounds such as molybdenum oxide and zinc molybdate; zinc compounds such as zinc borate and zinc stannate; alumina Clay, kaolin, talc, calcined clay, calcined kaolin,
  • the organic filler is not particularly limited, and examples thereof include rubber powders such as styrene type powder, butadiene type powder, and acrylic type powder; core shell type rubber powder; silicone resin powder; silicone rubber powder; It is done.
  • the filler (I) may be used alone or in combination of two or more.
  • the inorganic filler may contain at least one selected from the group consisting of silica, alumina, magnesium oxide, aluminum hydroxide, boehmite, boron nitride, aggregated boron nitride, silicon nitride, and aluminum nitride.
  • it contains at least one selected from the group consisting of silica, alumina, and boehmite.
  • the content of the filler (I) (particularly inorganic filler) is preferably 100 to 700 parts by mass, more preferably 100 to 450 parts by mass, and still more preferably 100 parts by mass of the resin solid content. 120 to 250 parts by mass.
  • the content of the filler (I) is within the above range, the obtained cured product tends to have higher rigidity and lower warpage.
  • the resin composition of this embodiment may further contain a silane coupling agent and a wetting and dispersing agent.
  • a silane coupling agent and a wetting and dispersing agent By including a silane coupling agent and a wetting and dispersing agent, the dispersibility of the filler (I), the resin component, the filler (I), and the adhesive strength of the substrate described later tend to be further improved.
  • the silane coupling agent is not particularly limited as long as it is a silane coupling agent generally used for surface treatment of inorganic substances.
  • ⁇ -aminopropyltriethoxysilane, N- ⁇ - (aminoethyl) - ⁇ Aminosilane compounds such as aminopropyltrimethoxysilane; epoxysilane compounds such as ⁇ -glycidoxypropyltrimethoxysilane; acrylic silane compounds such as ⁇ -acryloxypropyltrimethoxysilane; N- ⁇ - (N— Cationic silane compounds such as vinylbenzylaminoethyl) - ⁇ -aminopropyltrimethoxysilane hydrochloride; phenylsilane compounds and the like.
  • a silane coupling agent may be used individually by 1 type, or may use 2 or more types together.
  • the wetting dispersant is not particularly limited as long as it is a dispersion stabilizer used for paints.
  • the resin composition of this embodiment may be an allyl group-containing compound (hereinafter also referred to as “other allyl group-containing compound”), phenol resin, oxetane resin, other than the above-described allyl group-containing compound (B).
  • other allyl group-containing compound phenol resin, oxetane resin, other than the above-described allyl group-containing compound (B).
  • You may further contain 1 type, or 2 or more types selected from the group which consists of a benzoxazine compound and the compound which has a polymerizable unsaturated group.
  • the copper foil peel strength, bending strength, bending elastic modulus and the like of the obtained cured product tend to be further improved.
  • allyl group-containing compounds examples include, but are not limited to, allyl chloride, allyl acetate, allyl ether, propylene, triallyl cyanurate, triallyl isocyanurate, diallyl phthalate, diallyl isophthalate, diallyl maleate, and the like. Can be mentioned.
  • the content of the other allyl group-containing compound is preferably 0 to 50 parts by mass, more preferably 10 to 45 parts by mass, and more preferably 15 to 45 parts by mass with respect to 100 parts by mass of the resin solid content. More preferably, it is 20 to 35 parts by mass.
  • the content of the other allyl group-containing compound is within the above range, the bending strength, bending elastic modulus, heat resistance, and chemical resistance of the obtained cured product tend to be further improved.
  • phenol resin generally known resins can be used as long as they are phenol resins having two or more hydroxy groups in one molecule, and the kind thereof is not particularly limited. Specific examples thereof include bisphenol A type phenol resin, bisphenol E type phenol resin, bisphenol F type phenol resin, bisphenol S type phenol resin, phenol novolac resin, bisphenol A novolac type phenol resin, glycidyl ester type phenol resin, aralkyl novolac type.
  • the content of the phenol resin is preferably 0 to 99 parts by mass, more preferably 1 to 90 parts by mass, and further preferably 3 to 80 parts by mass with respect to 100 parts by mass of the resin solid content.
  • the content of the phenol resin is within the above range, the obtained cured product tends to be more excellent in adhesiveness, flexibility, and the like.
  • oxetane resin As the oxetane resin, generally known oxetane resins can be used, and the kind thereof is not particularly limited. Specific examples thereof include alkyloxetanes such as oxetane, 2-methyloxetane, 2,2-dimethyloxetane, 3-methyloxetane, and 3,3-dimethyloxetane, 3-methyl-3-methoxymethyloxetane, 3,3 ′ -Di (trifluoromethyl) perfluoxetane, 2-chloromethyloxetane, 3,3-bis (chloromethyl) oxetane, biphenyl type oxetane, OXT-101 (trade name, manufactured by Toagosei), OXT-121 (produced by Toagosei) Product name). These oxetane resins can be used alone or in combination of two or more. By including such an o
  • the content of the oxetane resin is preferably 0 to 99 parts by mass, more preferably 1 to 90 parts by mass, and further preferably 3 to 80 parts by mass with respect to 100 parts by mass of the resin solid content.
  • the content of the oxetane resin is within the above range, the obtained cured product tends to be more excellent in adhesion and flexibility.
  • benzoxazine compound As the benzoxazine compound, generally known compounds can be used as long as they have two or more dihydrobenzoxazine rings in one molecule, and the kind thereof is not particularly limited. Specific examples include bisphenol A type benzoxazine BA-BXZ (trade name, manufactured by Konishi Chemical) bisphenol F type benzoxazine BF-BXZ (trade name, manufactured by Konishi Chemical), bisphenol S type benzoxazine BS-BXZ (product manufactured by Konishi Chemical). Name). These benzoxazine compounds can be used alone or in combination. By including such a benzoxazine compound, the obtained cured product tends to be more excellent in flame retardancy, heat resistance, low water absorption, low dielectric constant, and the like.
  • the content of the benzoxazine compound is preferably 0 to 99 parts by mass, more preferably 1 to 90 parts by mass, and further preferably 3 to 80 parts by mass with respect to 100 parts by mass of the resin solid content.
  • the content of the benzoxazine compound is within the above range, the resulting cured product tends to be more excellent in heat resistance and the like.
  • Compound having a polymerizable unsaturated group As the compound having a polymerizable unsaturated group, generally known compounds can be used, and the kind thereof is not particularly limited. Specific examples thereof include vinyl compounds such as ethylene, propylene, styrene, divinylbenzene and divinylbiphenyl; methyl (meth) acrylate, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, polypropylene glycol di ( Mono- or polyhydric alcohol (meth) such as (meth) acrylate, trimethylolpropane di (meth) acrylate, trimethylolpropane tri (meth) acrylate, pentaerythritol tetra (meth) acrylate, dipentaerythritol hexa (meth) acrylate Acrylates; Epoxy (meth) acrylates such as bisphenol A type epoxy (meth) acrylate and bisphenol F type
  • the content of the compound having a polymerizable unsaturated group is preferably 0 to 99 parts by mass, more preferably 1 to 90 parts by mass, and still more preferably 3 to 100 parts by mass with respect to 100 parts by mass of the resin solid content. 80 parts by mass.
  • the content of the polymerizable unsaturated group-containing compound is within the above range, the cured product obtained tends to be more excellent in heat resistance, toughness, and the like.
  • the resin composition of this embodiment may further contain a curing accelerator.
  • the curing accelerator is not particularly limited, and examples thereof include imidazoles such as triphenylimidazole; benzoyl peroxide, lauroyl peroxide, acetyl peroxide, parachlorobenzoyl peroxide, di-tert-butyl-diperphthalate, and the like.
  • Organic peroxides azo compounds such as azobisnitrile; N, N-dimethylbenzylamine, N, N-dimethylaniline, N, N-dimethyltoluidine, N, N-dimethylpyridine, 2-N-ethylanilino Tertiary amines such as ethanol, tri-n-butylamine, pyridine, quinoline, N-methylmorpholine, triethanolamine, triethylenediamine, tetramethylbutanediamine, N-methylpiperidine; phenol, xylenol, cresol, resorcin, cateco Phenols such as lead; organic metal salts such as lead naphthenate, lead stearate, zinc naphthenate, zinc octylate, tin oleate, dibutyltin malate, manganese naphthenate, cobalt naphthenate, iron acetylacetone; these organic metal salts Inorganic metal salts
  • the resin composition of this embodiment may further contain a solvent.
  • a solvent By including the solvent, the viscosity at the time of preparing the resin composition is lowered, the handling property is further improved, and the impregnation property to the substrate described later tends to be further improved.
  • the solvent is not particularly limited as long as it can dissolve a part or all of the resin component in the resin composition.
  • ketones such as acetone, methyl ethyl ketone, and methyl cellosolve
  • aromatics such as toluene and xylene Group hydrocarbons
  • amides such as dimethylformamide
  • a solvent may be used individually by 1 type, or may use 2 or more types together.
  • the manufacturing method of the resin composition of this embodiment is not specifically limited, For example, the method of mix
  • known processes such as stirring, mixing, and kneading can be performed.
  • the dispersibility of the filler (I) with respect to the resin composition can be improved by performing the stirring and dispersing treatment using a stirring tank provided with a stirrer having an appropriate stirring ability.
  • the above stirring, mixing, and kneading treatment can be appropriately performed using, for example, a known device such as a ball mill or a bead mill for mixing, or a revolving or rotating mixing device.
  • an organic solvent can be used as necessary.
  • the kind of the organic solvent is not particularly limited as long as it can dissolve the resin in the resin composition. Specific examples thereof are as described above.
  • a cured product obtained by thermally curing a prepreg containing the base material and a substrate at 230 ° C. for 100 minutes is represented by the following formulas (12) to (16): It is preferable that the numerical value range of the physical property parameter related to the characteristic is satisfied, and it is more preferable that the numerical value range of the physical property parameter related to the mechanical characteristic represented by the following formulas (12A) to (16A) is satisfied.
  • E ′ represents the storage elastic modulus of the cured product at the temperature indicated in parentheses
  • E ′′ max is the maximum value of the loss elastic modulus of the cured product in the temperature range of 30 ° C. to 330 ° C
  • E ′′ min indicates the minimum loss elastic modulus of the cured product in a temperature range of 30 ° C. to 330 ° C. (E ′′ indicates the loss elastic modulus of the cured product).
  • the warping behavior of a printed wiring board, in a cured product of a prepreg it has been considered that a resin composition capable of realizing a larger storage modulus during heat and a higher elastic modulus retention rate is effective.
  • the numerical values of the physical property parameters relating to the mechanical properties of the cured product obtained by thermally curing the prepreg at 230 ° C. for 100 minutes are not necessarily limited to the above formulas (12) to (16), preferably the formula (12A) to By being within the range of (16A), the glass transition temperature (Tg) can be sufficiently increased, and the amount of warpage of the laminate, metal foil-clad laminate, printed wiring board, particularly the multilayer coreless substrate itself is sufficient. It becomes possible to reduce it.
  • the numerical values of the physical property parameters relating to the mechanical properties of the cured product obtained by thermosetting the prepreg at 230 ° C. for 100 minutes are the above formulas (12) to (16), preferably the formulas (12A) to (16A).
  • it has a high glass transition temperature (high Tg) or does not have a clear glass transition temperature (Tg-less), and is a printed wiring board (particularly a multilayer coreless substrate). It is possible to sufficiently reduce the warp (achieve low warpage). That is, satisfying formulas (15) and (16), preferably formulas (15A) and (16A) relating to the loss modulus has a high glass transition temperature (high Tg) or a clear glass transition temperature.
  • the cured product satisfies the formulas (15) and (16), preferably the formulas (15A) and (16A), and the formulas (12) to (14), preferably the formula (12A).
  • the printed circuit board is used as a printed wiring board, it is difficult to achieve low warpage, although the loss elastic modulus itself is small and hardly stretched when it does not satisfy () to (14A).
  • the cured product satisfies not only formulas (15) and (16), preferably formulas (15A) and (16A), but also formulas (12) to (14), preferably formulas (12A) to (16A).
  • Those having a high glass transition temperature (high Tg) or not having a clear glass transition temperature (Tg-less) tend to be difficult to stretch and tend to achieve low warpage of the printed wiring board.
  • the method for measuring the mechanical properties (storage elastic modulus E ′ and loss elastic modulus E ′′) of the cured prepreg is not particularly limited, and can be measured, for example, by the following method. That is, copper foil (3EC-VLP, manufactured by Mitsui Mining & Smelting Co., Ltd., thickness 12 ⁇ m) is arranged on both upper and lower surfaces of one prepreg, and laminated molding (thermosetting) at a pressure of 30 kgf / cm 2 and a temperature of 230 ° C. for 100 minutes. ) To obtain a copper foil-clad laminate having a predetermined insulating layer thickness.
  • the obtained copper foil-clad laminate is cut into a size of 5.0 mm ⁇ 20 mm with a dicing saw, and then the copper foil on the surface is removed by etching to obtain a measurement sample.
  • the resin composition of the present embodiment can be suitably used as a prepreg, an insulating layer, a laminate, a metal foil-clad laminate, a printed wiring board, or a multilayer printed wiring board.
  • a prepreg, a laminate, a metal foil-clad laminate, and a printed wiring board (including a multilayer printed wiring board) will be described.
  • the prepreg of this embodiment has a base material and the resin composition impregnated or coated on the base material.
  • the manufacturing method of a prepreg can be performed according to a conventional method, and is not specifically limited.
  • the substrate is semi-cured (B stage) by heating in a dryer at 100 to 200 ° C. for 1 to 30 minutes.
  • the prepreg of this embodiment can be produced.
  • the content of the resin composition (including the filler (I)) in the prepreg of this embodiment is preferably 30 to 90% by volume, more preferably 35 to 85% by volume, based on the total amount of the prepreg. More preferably, it is 40 to 80% by volume. When the content of the resin composition is within the above range, the moldability tends to be further improved.
  • the substrate is not particularly limited, and known materials used for various printed wiring board materials can be appropriately selected and used depending on the intended use and performance.
  • the substrate include a glass substrate, an inorganic substrate other than glass, an organic substrate, and the like.
  • a glass substrate is particularly preferable from the viewpoint of high rigidity and heat dimensional stability.
  • Specific examples of the fibers constituting these base materials are not particularly limited.
  • glass base materials for example, from E glass, D glass, S glass, T glass, Q glass, L glass, NE glass, and HME glass.
  • inorganic base materials other than glass inorganic fibers other than glass, such as quartz, are mentioned.
  • polyparaphenylene terephthalamide (Kevlar (registered trademark), manufactured by DuPont), copolyparaphenylene 3,4'oxydiphenylene terephthalamide (Technola (registered trademark), Teijin Techno Products Ltd.
  • Wholly aromatic polyamides polyesters such as 2,6-hydroxynaphthoic acid and parahydroxybenzoic acid (Vectran (registered trademark), manufactured by Kuraray Co., Ltd.), Zexion (registered trademark, manufactured by KB Seiren);
  • organic fibers such as phenylene benzoxazole (Zylon (registered trademark), manufactured by Toyobo Co., Ltd.) and polyimide.
  • These base materials may be used individually by 1 type, or may use 2 or more types together.
  • a shape of a base material For example, a woven fabric, a nonwoven fabric, roving, a chopped strand mat, a surfacing mat, etc. are mentioned.
  • the weaving method of the woven fabric is not particularly limited, and for example, plain weave, Nanako weave, twill weave and the like are known, and can be appropriately selected from these known ones depending on the intended use and performance. .
  • the thing which spread-processed these, and the glass woven fabric surface-treated with the silane coupling agent etc. are used suitably.
  • the thickness and mass of the base material are not particularly limited, but usually about 0.01 to 0.3 mm is preferably used.
  • the base material is preferably a glass woven fabric having a thickness of 200 ⁇ m or less and a mass of 250 g / m 2 or less, and a glass woven fabric made of glass fibers of E glass, S glass, and T glass. More preferred.
  • the laminated board of this embodiment has the prepreg of this embodiment laminated at least one or more.
  • the metal foil-clad laminate of the present embodiment includes the laminate of the embodiment (that is, the prepreg of the embodiment laminated at least one sheet) and the metal foil disposed on one or both sides of the laminate. (Conductor layer).
  • the conductor layer can be a metal foil such as copper or aluminum.
  • the metal foil used here will not be specifically limited if it is used for printed wiring board material, Well-known copper foils, such as a rolled copper foil and an electrolytic copper foil, are preferable.
  • the thickness of the conductor layer is not particularly limited, but is preferably 1 to 70 ⁇ m, more preferably 1.5 to 35 ⁇ m.
  • the molding method and molding conditions of the laminate or metal foil-clad laminate are not particularly limited, and general techniques and conditions of a laminate for a printed wiring board and a multilayer board can be applied.
  • a multistage press, a multistage vacuum press, a continuous molding machine, an autoclave molding machine, etc. can be used at the time of shaping
  • the temperature is generally 100 to 300 ° C.
  • the pressure is 2 to 100 kgf / cm 2
  • the heating time is generally 0.05 to 5 hours. It is.
  • post-curing can be performed at a temperature of 150 to 300 ° C., if necessary.
  • a temperature of 200 ° C. to 250 ° C., a pressure of 10 to 40 kgf / cm 2 , a heating time of 80 minutes to 130 minutes is preferable, and a temperature of 215 ° C. to More preferably, the temperature is 235 ° C., the pressure is 25 to 35 kgf / cm 2 , and the heating time is 90 to 120 minutes.
  • a multilayer board can be formed by laminating and combining the above-described prepreg and a separately prepared wiring board for an inner layer.
  • the printed wiring board of this embodiment is a printed wiring board having an insulating layer and a conductor layer formed on the surface of the insulating layer, and the insulating layer contains the resin composition.
  • the resin composition of the present embodiment has a high glass transition temperature (high Tg) or does not have a clear glass transition temperature (Tg-less), and has sufficient warpage Therefore, it can be used particularly effectively as a printed wiring board that requires such performance.
  • the printed wiring board of the present embodiment can be manufactured by the following method, for example.
  • the metal foil-clad laminate such as a copper-clad laminate
  • An inner layer circuit is formed by etching the surface of the metal foil-clad laminate to produce an inner layer substrate.
  • the inner layer circuit surface of the inner layer substrate is subjected to a surface treatment to increase the adhesive strength as necessary, then the required number of the above-mentioned prepregs are stacked on the inner layer circuit surface, and a metal foil for the outer layer circuit is further formed outside thereof.
  • a multilayer laminate is produced in which an insulating layer made of a cured material of the base material and the thermosetting resin composition is formed between the inner layer circuit and the metal foil for the outer layer circuit.
  • the method of lamination molding and the molding conditions thereof are the same as those of the above-described laminate or metal foil-clad laminate.
  • desmear treatment is performed to remove smears, which are resin residues derived from the resin component contained in the cured product layer. .
  • a plated metal film is formed on the wall surface of this hole to connect the inner layer circuit and the metal foil for the outer layer circuit, and the outer layer circuit is formed by etching the metal foil for the outer layer circuit to produce a printed wiring board. Is done.
  • the above-described prepreg (the base material and the above-described resin composition attached thereto) and the metal foil-clad laminate resin composition layer (the layer made of the above-described resin composition) include the above-described resin composition.
  • An insulating layer is formed.
  • a printed wiring board may be produced by forming a conductor layer serving as a circuit on the prepreg or the resin composition. At this time, a method of electroless plating can be used for forming the conductor layer.
  • the printed wiring board of the present embodiment includes a first insulating layer (1) formed of the above-described prepreg that is laminated at least one sheet, and the first insulating layer (1 ) And a plurality of insulating layers (1, 2) formed of the second insulating layer (2) formed of the above-mentioned prepreg laminated in at least one sheet in the one-side direction (the lower surface direction in the figure).
  • a normal laminated board for example, it is performed to form a multilayer printed wiring board by laminating another prepreg on both sides of a prepreg that is one core substrate.
  • the prepreg of the embodiment is a coreless type manufactured by stacking another prepreg that forms the second insulating layer (2) only in one direction of one prepreg that forms the first insulating layer (1). It was confirmed that the present invention is particularly effective for multilayer printed wiring boards (multilayer coreless substrates).
  • the prepreg and the resin composition of the present embodiment can effectively reduce the amount of warping when used in a printed wiring board, and are not particularly limited. This is particularly effective for a coreless substrate. That is, a normal printed wiring board generally has a symmetrical structure on both sides, and thus tends to be warped. On the other hand, a multilayer coreless board tends to have a double-sided asymmetric structure, and thus is more likely to warp than a normal printed wiring board. There is a tendency. Therefore, by using the prepreg and the resin composition of the present embodiment, it is possible to particularly effectively reduce the amount of warping of the multilayer coreless substrate that has been prone to warping.
  • FIG. 9 a configuration in which two second insulating layers (2) are stacked on one first insulating layer (1) (that is, a configuration in which a plurality of insulating layers are three layers) is provided.
  • the number of the second insulating layer (2) may be one or two or more. Therefore, the first conductor layer (3) may be one layer or two or more layers.
  • the above-described resin composition of the present embodiment is, for example, a cured product obtained by curing a prepreg, such as a hot storage elastic modulus and a loss elastic modulus.
  • the mechanical properties can be controlled to a specific range suitable for low warpage, so that it has a high glass transition temperature (high Tg) or no clear glass transition temperature (Tg-less), and printing Since the warpage of the wiring board, particularly, the multilayer coreless substrate is sufficiently reduced (low warpage is achieved), it can be used particularly effectively as a printed wiring board for a semiconductor package and a multilayer coreless substrate.
  • Example 1 Maleimide compound (A) (BMI-2300, manufactured by Daiwa Kasei Kogyo Co., Ltd., maleimide equivalent 186 g / eq.) 46 parts by mass, allyl group-containing compound (B) and alkenyl-substituted nadiimide compound (F) (BANI-M, Maruzen Petrochemical Co., Ltd., allyl equivalent: 286 g / eq.) 33 parts by mass, epoxy resin (C) (EPICLON EXA-4850-150, made of bisphenol A structural unit and hydrocarbon-based structural unit, manufactured by DIC Corporation) , Epoxy equivalent: 450 g / eq.) 10 parts by mass, 1 part by mass of ⁇ -naphthol aralkyl cyanate ester compound (SN495VCN, cyanate equivalent: 261 g / eq.) Of Synthesis Example 1 which is a cyanate ester compound (G),
  • Example 2 From 52 parts by mass of maleimide compound (A) (BMI-2300), 38 parts by mass of allyl group-containing compound (B) and alkenyl-substituted nadiimide compound (F) (BANI-M), bisphenol A structural unit and hydrocarbon-based structural unit ⁇ -naphthol aralkyl type cyanic acid of Synthesis Example 1 which is 5 parts by mass of epoxy resin (C) (EPICLON EXA-4816, manufactured by DIC Corporation, epoxy equivalent: 403 g / eq.), And cyanate compound (G) 5 parts by mass of an ester compound (SN495VCN), 100 parts by mass of slurry silica (SC-2050MB) as filler (I), 100 parts by mass of the same slurry silica (SC-5050MOB, manufactured by Admatex Co., Ltd.), and the silicone composite 20 parts by mass of powder (KMP-600), silane coupling agent (Z-60 0) 5 parts
  • Example 3 From 43 parts by mass of maleimide compound (A) (BMI-2300), 32 parts by mass of allyl group-containing compound (B) and alkenyl-substituted nadiimide compound (F) (BANI-M), bisphenol A structural unit and hydrocarbon-based structural unit 10 parts by mass of epoxy resin (C) (EPICLON EXA-4816), 5 parts by mass of ⁇ -naphthol aralkyl-type cyanate ester compound (SN495VCN) of Synthesis Example 1 which is a cyanate ester compound (G), epoxy compound (H) (NC-3000FH) 10 parts by mass, filler (I) 100 parts by mass of slurry silica (SC-2050MB), 100 parts by mass of slurry silica (SC-5050MOB), and the same silicone composite powder (KMP-600) 20 Parts by mass, 5 parts by mass of a silane coupling agent (Z-6040), 2 parts by mass of a dispersant (DIS
  • the varnish was obtained by dilution with methyl ethyl ketone. This varnish was impregnated and applied to an E glass woven fabric and dried by heating at 160 ° C. for 3 minutes to obtain a prepreg having a resin composition content of 57 vol%.
  • Example 4 10 parts by mass of the same epoxy resin (C) (EPICLON EXA-4850-150) is used instead of 10 parts by mass of the epoxy resin (C) (EPICLON EXA-4816) composed of a bisphenol A type structural unit and a hydrocarbon-based structural unit.
  • a prepreg having a resin composition content of 57% by volume was obtained in the same manner as in Example 3, except that the amount of the wet dispersant (DISPERBYK-111) was 1 part by mass.
  • Example 5 Instead of 10 parts by mass of epoxy resin (C) (EPICLON EXA-4850-150) consisting of a bisphenol A type structural unit and a hydrocarbon-based structural unit, 20 parts by mass of the same epoxy resin (C) (EPICLON EXA-4816) is used. A prepreg having a resin composition content of 57 vol% was obtained in the same manner as in Example 4 except that the epoxy compound (H) (NC-3000FH) was not used.
  • C epoxy resin
  • H N-000FH
  • Example 6 Maleimide compound (A) (BMI-2300, manufactured by Daiwa Kasei Kogyo Co., Ltd., maleimide equivalent 186 g / eq.) 46 parts by mass, allyl group-containing compound (B) and alkenyl-substituted nadiimide compound (F) (BANI-M, Maruzen Petrochemical Co., Ltd., allyl equivalent: 286 g / eq.) 34 parts by mass, comb-shaped graft polymer (D) (Symac (registered trademark) US-350, manufactured by Toagosei Co., Ltd.), 5 parts by mass, cyanate ester compound (G) 5 parts by mass of ⁇ -naphthol aralkyl-type cyanate ester compound (SN495VCN, cyanate equivalent: 261 g / eq.) Of Synthesis Example 1 and epoxy compound (H) (NC-3000FH, manufactured by Nippon Kayaku Co
  • This varnish was impregnated and applied to an E glass woven fabric and dried by heating at 160 ° C. for 3 minutes to obtain a prepreg having a resin composition content of 73 vol%.
  • Example 7 43 parts by mass of maleimide compound (A) (BMI-2300, manufactured by Daiwa Kasei Kogyo Co., Ltd., maleimide equivalent 186 g / eq.), Allyl group-containing compound (B) and alkenyl-substituted nadiimide compound (F) (BANI -M, manufactured by Maruzen Petrochemical Co., Ltd., allyl equivalent: 286 g / eq.) was 32 parts by mass, and comb-shaped graft polymer (D) (Symac (registered trademark) US-350, Toa Gosei Co., Ltd.) A prepreg having a resin composition content of 73% by volume was obtained in the same manner as in Example 6 except that the amount of the product was 10 parts by mass.
  • A maleimide compound (A) (BMI-2300, manufactured by Daiwa Kasei Kogyo Co., Ltd., maleimide equivalent 186 g / eq.
  • Example 8 Comb-shaped graft polymer (D) (Symac (registered trademark) US-380, Toa Gosei Co., Ltd.) instead of 5 parts by mass of comb-shaped graft polymer (D) (Symac (registered trademark) US-350, manufactured by Toa Gosei Co., Ltd.) ))
  • D Synchronization-based graft polymer
  • the weight average molecular weight Mw of the comb-shaped graft polymer (D) (Symac (registered trademark) US-380, manufactured by Toagosei Co., Ltd.) was measured by the “method for measuring the weight average molecular weight Mw” described later. Met.
  • Example 9 Comb graft polymer (D) (Saimak (registered trademark) US-350, manufactured by Toa Gosei Co., Ltd.) Instead of 10 parts by mass, comb graft polymer (D) (Symac (registered trademark) US-380, Toa Gosei Co., Ltd.) )) A prepreg having a resin composition content of 73% by volume was obtained in the same manner as in Example 7 except that 10 parts by mass were used.
  • Example 10 Maleimide compound (A) (BMI-2300, manufactured by Daiwa Kasei Kogyo Co., Ltd., maleimide equivalent 186 g / eq.) Was 38 parts by mass, allyl group-containing compound (B) and alkenyl-substituted nadiimide compound (F) (BANI -M, manufactured by Maruzen Petrochemical Co., Ltd., allyl equivalent: 286 g / eq.) Was 30 parts by mass, comb-shaped graft polymer (D) (Symac (registered trademark) US-350, manufactured by Toa Gosei Co., Ltd.) Instead of 5 parts by mass, 20 parts by mass of comb-shaped graft polymer (D) (Symac (registered trademark) US-380, manufactured by Toa Gosei Co., Ltd.) was used, and Synthesis Example 1 which is a cyanate ester compound (G) ⁇ -naphthol aral
  • A maleimide compound (A) (BMI-2300, manufactured by Daiwa Kasei Kogyo Co., Ltd., maleimide equivalent 186 g / eq
  • carrier copper foil surfaces of an ultrathin copper foil with carrier (b1) (MT18Ex, manufactured by Mitsui Mining & Smelting Co., Ltd., thickness 5 ⁇ m) are provided on both sides of the prepreg to be the support (a).
  • the prepreg (c1) obtained in Examples 1 to 10 and Comparative Examples 1 to 6 is further arranged on the copper foil (d) (3EC-VLP, Mitsui Mining & Mining).
  • a copper foil-clad laminate shown in FIG. 2 was obtained by performing laminate molding at a pressure of 30 kgf / cm 2 and a temperature of 220 ° C. for 120 minutes.
  • the copper foil (d) of the obtained copper foil-clad laminate shown in FIG. 2 was etched into a predetermined wiring pattern as shown in FIG. 3, for example, to form a conductor layer (d ′).
  • the prepregs (c2) obtained in Examples 1 to 10 and Comparative Examples 1 to 6 are placed on the laminate shown in FIG. 3 on which the conductor layer (d ′) is formed.
  • an ultrathin copper foil with carrier (b2) (MT18Ex, manufactured by Mitsui Mining & Smelting Co., Ltd., thickness 5 ⁇ m) is further placed thereon, and laminated molding is performed at a pressure of 30 kgf / cm 2 and a temperature of 230 ° C. for 120 minutes.
  • a copper foil clad laminate shown in FIG. 5 was obtained.
  • the carrier copper foil and the ultrathin copper foil of the carrier-attached ultrathin copper foil (b1) placed on the support (a) (cured support prepreg) are peeled off.
  • the two laminated plates were peeled from the support (a), and the carrier copper foil was further peeled from the ultrathin copper foil with carrier (b2) on the upper portion of each laminated plate.
  • processing by a laser processing machine was performed on the upper and lower ultrathin copper foils of each obtained laminate, and a predetermined via (v) was formed by chemical copper plating as shown in FIG. Then, for example, as shown in FIG.
  • a conductor layer was formed by etching into a predetermined wiring pattern to obtain a panel of a multilayer coreless substrate. Then, the amount of warpage at a total of eight locations of the four corners and the center of the four sides of the obtained panel was measured with a metal ruler, and the average value was defined as the “warpage amount” of the panel of the multilayer coreless substrate.
  • Copper foil (3EC-VLP, manufactured by Mitsui Mining & Smelting Co., Ltd., thickness 12 ⁇ m) was placed on the upper and lower surfaces of one prepreg obtained in Examples 1 to 10 and Comparative Examples 1 to 6, and the pressure was 30 kgf / cm 2. Then, lamination molding was performed at a temperature of 220 ° C. for 120 minutes to obtain a copper foil-clad laminate. Next, the obtained copper foil-clad laminate was drilled at nine points uniformly in a grid pattern with a drill, and then the copper foil was removed.
  • the distance between the holes in the laminate from which the copper foil was removed was measured (distance A).
  • the laminate was subjected to a reflow treatment at a maximum temperature of 260 ° C. using a salamander reflow apparatus. Thereafter, the distance between the holes in the laminate was measured again (distance b).
  • the measured distance A and distance B were substituted into the following formula (I) to determine the dimensional change rate of the substrate in the reflow process, and the value was used as the substrate shrinkage rate before and after the reflow process. ((Distance A)-(Distance B)) / Distance A x 100 ...
  • Formula (I) ((Distance A)-(Distance B)) / Distance A x 100 ...
  • the resin composition of this embodiment has industrial applicability as a material for a prepreg, a laminate, a metal foil-clad laminate, a printed wiring board, or a multilayer printed wiring board.
  • This application is based on Japanese Patent Application No. 2016-255207 filed on Dec. 28, 2016 and Japanese Patent Application No. 2017-035200 filed on Feb. 27, 2017. The contents of those descriptions are incorporated by reference.

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Abstract

La présente invention concerne une composition de résine ayant une température de transition vitreuse élevée (Tg élevée) ou n'ayant pas une température de transition vitreuse distincte (sans Tg), et étant susceptible de supprimer suffisamment le gauchissement (obtention d'un gauchissement faible) d'une carte de circuit imprimé, en particulier, d'un substrat sans noyau multicouche ; un préimprégné ; une carte stratifiée ; une carte stratifiée plaquée de feuille métallique ; une carte de circuit imprimé ; et une carte de circuit imprimé multicouche, la composition de résine selon la présente invention comprenant un composé maléimide (A), un composé contenant un groupe allyle (B), une résine époxy (C) comprenant des motifs structuraux de type bisphénol A et des motifs structuraux à base d'hydrocarbure, et/ou un polymère greffé en forme de peigne (D). La teneur en résine époxy (C) comprenant les motifs structuraux de type bisphénol A et les motifs structuraux à base d'hydrocarbure ou le polymère greffé en forme de peigne (D) dans la composition de résine est de 3 à 25 parties en masse par rapport à 100 parties en masse de la teneur en matières solides de la résine.
PCT/JP2017/046860 2016-12-28 2017-12-27 Composition de résine, préimprégné, carte stratifiée, carte stratifiée plaquée de feuille métallique, carte de circuit imprimé et carte de circuit imprimé multicouche Ceased WO2018124169A1 (fr)

Priority Applications (3)

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KR1020197004770A KR102058827B1 (ko) 2016-12-28 2017-12-27 수지 조성물, 프리프레그, 적층판, 금속박 피복 적층판, 프린트 배선판, 및 다층 프린트 배선판
CN201780081383.1A CN110114407B (zh) 2016-12-28 2017-12-27 树脂组合物、预浸料、层叠板、覆金属箔层叠板、印刷电路板、及多层印刷电路板
JP2018530936A JP6452083B2 (ja) 2016-12-28 2017-12-27 樹脂組成物、プリプレグ、積層板、金属箔張積層板、プリント配線板、及び多層プリント配線板

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JP2016-255207 2016-12-28
JP2016255207 2016-12-28
JP2017-035200 2017-02-27
JP2017035200 2017-02-27

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EP3900921A4 (fr) * 2018-12-18 2022-01-26 Showa Denko Materials Co., Ltd. Stratifié, carte de circuit imprimé, boîtier de semi-conducteur et procédé de fabrication de stratifié
WO2022024839A1 (fr) * 2020-07-27 2022-02-03 積水化学工業株式会社 Produit d'étanchéité pour élément d'affichage électroluminescent organique
WO2023280681A1 (fr) * 2021-07-05 2023-01-12 Lisa Dräxlmaier GmbH Carte de circuit imprimé pour un calculateur d'un véhicule et procédé de fabrication d'une telle carte de circuit imprimé
WO2024075245A1 (fr) * 2022-10-06 2024-04-11 株式会社レゾナック Préimprégné, plaque stratifiée, carte de circuit imprimé et boîtier de semi-conducteur

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CN110114407B (zh) 2021-10-22
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