[go: up one dir, main page]

WO2018101794A3 - Metallocene catalyst system comprising operationally stable composition, and method for producing polyolefin by means of metallocene catalyst system - Google Patents

Metallocene catalyst system comprising operationally stable composition, and method for producing polyolefin by means of metallocene catalyst system Download PDF

Info

Publication number
WO2018101794A3
WO2018101794A3 PCT/KR2017/014020 KR2017014020W WO2018101794A3 WO 2018101794 A3 WO2018101794 A3 WO 2018101794A3 KR 2017014020 W KR2017014020 W KR 2017014020W WO 2018101794 A3 WO2018101794 A3 WO 2018101794A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst system
metallocene catalyst
stable composition
producing polyolefin
operationally stable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2017/014020
Other languages
French (fr)
Korean (ko)
Other versions
WO2018101794A2 (en
WO2018101794A9 (en
Inventor
최혜선
김동옥
서준호
정동욱
허은정
정의갑
최승일
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hanwha Chemical Corp
Original Assignee
Hanwha Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hanwha Chemical Corp filed Critical Hanwha Chemical Corp
Publication of WO2018101794A2 publication Critical patent/WO2018101794A2/en
Publication of WO2018101794A3 publication Critical patent/WO2018101794A3/en
Publication of WO2018101794A9 publication Critical patent/WO2018101794A9/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647—Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6496—Catalysts containing a specific non-metal or metal-free compound organic containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

The present invention relates to a metallocene catalyst system comprising an operationally stable composition, and a method for producing polyolefin by means of the metallocene catalyst system. More specifically, by utilizing the metallocene catalyst system comprising: 90-99.9 wt% metallocene compound of one or more types; and 0.1-10 wt% operationally stable composition comprising one or more types of compounds selected from the group consisting of sulfate, sulfonate, phosphate, and carboxylate, and one or more types of white mineral oil, the unique activity of the catalyst is maintained and fouling and agglomeration phenomena are minimized during olefin polymerization to allow the process to be stably carried out, and thus by means of the present invention, a method for producing polyolefin can be provided, and produced polyolefin can be provided.
PCT/KR2017/014020 2016-12-01 2017-12-01 Metallocene catalyst system comprising operationally stable composition, and method for producing polyolefin by means of metallocene catalyst system Ceased WO2018101794A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2016-0162981 2016-12-01
KR1020160162981A KR101738827B1 (en) 2016-12-01 2016-12-01 Metallocene catalyst system comprising stabilizer composition for operation and method for preparing polyolefin using the same

Publications (3)

Publication Number Publication Date
WO2018101794A2 WO2018101794A2 (en) 2018-06-07
WO2018101794A3 true WO2018101794A3 (en) 2018-11-29
WO2018101794A9 WO2018101794A9 (en) 2018-12-20

Family

ID=59049917

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2017/014020 Ceased WO2018101794A2 (en) 2016-12-01 2017-12-01 Metallocene catalyst system comprising operationally stable composition, and method for producing polyolefin by means of metallocene catalyst system

Country Status (2)

Country Link
KR (1) KR101738827B1 (en)
WO (1) WO2018101794A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101738827B1 (en) * 2016-12-01 2017-05-22 한화케미칼 주식회사 Metallocene catalyst system comprising stabilizer composition for operation and method for preparing polyolefin using the same
US12318766B2 (en) 2019-05-17 2025-06-03 Lg Chem, Ltd. Method for preparing cocatalyst compound using anhydrous hydrocarbon solvent

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007186718A (en) * 2000-12-19 2007-07-26 Sunallomer Ltd Olefin polymerization catalyst, olefin polymerization catalyst component and storage method thereof, and process for producing olefin polymer
WO2011138211A1 (en) * 2010-05-07 2011-11-10 Borealis Ag Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins
KR101161887B1 (en) * 2003-12-09 2012-07-02 다우 글로벌 테크놀로지스 엘엘씨 Thermoplastic olefinic compositions
JP5941476B2 (en) * 2010-11-30 2016-06-29 ユニベーション・テクノロジーズ・エルエルシー Process for the polymerization of olefins using extracted metal carboxylate salts
KR101738827B1 (en) * 2016-12-01 2017-05-22 한화케미칼 주식회사 Metallocene catalyst system comprising stabilizer composition for operation and method for preparing polyolefin using the same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6482903B1 (en) 1999-12-15 2002-11-19 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2007186718A (en) * 2000-12-19 2007-07-26 Sunallomer Ltd Olefin polymerization catalyst, olefin polymerization catalyst component and storage method thereof, and process for producing olefin polymer
KR101161887B1 (en) * 2003-12-09 2012-07-02 다우 글로벌 테크놀로지스 엘엘씨 Thermoplastic olefinic compositions
WO2011138211A1 (en) * 2010-05-07 2011-11-10 Borealis Ag Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins
JP5941476B2 (en) * 2010-11-30 2016-06-29 ユニベーション・テクノロジーズ・エルエルシー Process for the polymerization of olefins using extracted metal carboxylate salts
KR101738827B1 (en) * 2016-12-01 2017-05-22 한화케미칼 주식회사 Metallocene catalyst system comprising stabilizer composition for operation and method for preparing polyolefin using the same

Also Published As

Publication number Publication date
WO2018101794A2 (en) 2018-06-07
WO2018101794A9 (en) 2018-12-20
KR101738827B1 (en) 2017-05-22

Similar Documents

Publication Publication Date Title
PH12016501559A1 (en) Producing polyolefin products
SA517382086B1 (en) Systems and Processes for Polymer Production
EA033278B1 (en) METHOD FOR PRODUCING SOLID MgClSUPPORTED CATALYST COMPONENT
EP4488302A3 (en) Methods of preparing a catalyst utilizing hydrated reagents
WO2015105750A3 (en) Processes for preparing metallocene-based catalyst systems
CA2985519C (en) Environmentally-friendly high potassium-content liquid fertilizer and uses for the fertilizer
EA201200117A1 (en) METHOD OF OBTAINING WATER SUSPENSION OF ORGANIC PESTICIDE COMPOUND
SA518391122B1 (en) Synthesis of Methacrylic Acid from Methacrolein-Based Alkyl Methacrylate
MX394953B (en) Process for preparing optically active 2,3-dihydrothiazolo[3,2-a]pyrimidin-4-ium compounds
BR112018013476B8 (en) PHTHALATE-FREE CATALYST SYSTEM, AND PROCESS FOR PREPARING A POLYOLEFIN
EA201990186A1 (en) METHOD FOR OLIGOMERIZING OLEFINS
EA201990152A1 (en) SOLID CATALYST FOR PRODUCING NUCLEOUS POLYOLEFINS
AU2017324520B2 (en) Solid detergent compositions and methods of adjusting the dispense rate of solid detergents using solid anionic surfactants
EA201490953A1 (en) COMPOSITIONS OF LUBE OILS
BR112017022154A2 (en) method for synthesis of zirconium and hafnium monocyclopentadienyl complexes
WO2018101794A3 (en) Metallocene catalyst system comprising operationally stable composition, and method for producing polyolefin by means of metallocene catalyst system
SG11201906688VA (en) Novel ester compounds, method for the production thereof and use thereof
WO2013150114A3 (en) Process to prepare residual base oil
MX369759B (en) Combined preparation of butene and octene from ethene.
ZA202105432B (en) Process for preparation of copper compounds
WO2018237291A3 (en) Signaling centers of erythroid differentiation
WO2011087634A3 (en) Isomerized alpha olefin sulfonate and method of making the same
PL3708596T3 (en) Novel metallocene catalyst compound for production of polyolefin resin or method of preparing same
SA116370842B1 (en) Composition of Catalyst for Cracking of Heavy Hydrocarbon Feed Stocks and Process for Preparing the Same
PH12018501748B1 (en) Surface-coated acetylacetone metal salt and method for producing same

Legal Events

Date Code Title Description
NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17876562

Country of ref document: EP

Kind code of ref document: A2