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WO2018001752A1 - Material for a vibration filtering device, vibration filtering device, and wiper system comprising such a device - Google Patents

Material for a vibration filtering device, vibration filtering device, and wiper system comprising such a device Download PDF

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Publication number
WO2018001752A1
WO2018001752A1 PCT/EP2017/064739 EP2017064739W WO2018001752A1 WO 2018001752 A1 WO2018001752 A1 WO 2018001752A1 EP 2017064739 W EP2017064739 W EP 2017064739W WO 2018001752 A1 WO2018001752 A1 WO 2018001752A1
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Prior art keywords
material according
shore
epdm rubber
less
rubber
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PCT/EP2017/064739
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French (fr)
Inventor
Patrick ASSUID
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Valeo Systemes dEssuyage SAS
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Valeo Systemes dEssuyage SAS
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Publication of WO2018001752A1 publication Critical patent/WO2018001752A1/en
Anticipated expiration legal-status Critical
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16FSPRINGS; SHOCK-ABSORBERS; MEANS FOR DAMPING VIBRATION
    • F16F1/00Springs
    • F16F1/36Springs made of rubber or other material having high internal friction, e.g. thermoplastic elastomers
    • F16F1/3605Springs made of rubber or other material having high internal friction, e.g. thermoplastic elastomers characterised by their material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Ethene-propene or ethene-propene-diene copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/267Magnesium carbonate

Definitions

  • the field of the present invention is that of filtering vibrations generated by the operation of small electric motors.
  • small electric motor of small size is meant in the context of the present invention a stepping motor, an actuator, a DC motor or an asynchronous motor, whose mass is less than 10 kg, in particular used for o operating equipment for vehicles, and more particularly equipment for wiping the windows of a vehicle.
  • the type of motor concerned by the invention thus constitutes an active solid source and has the main characteristic that the levels of vibrational acceleration that we will seek to filter are of the same order of magnitude.
  • This type of source can be qualified as a source of acceleration, compared to sources, rather larger size and mass, whose displacement levels would be of the same order of magnitude regardless of the frequency, for a band useful frequency
  • An example of such an active, non-limiting solid source of the invention is a windshield wiper system motor.
  • Motor vehicles are commonly equipped with a windshield wiper system to sweep and wash the windshield or rear window and prevent the driver's vision from being disturbed.
  • the wiper motor is
  • a mechanical system conventionally a crank system or an electronic function, so as to provide an angular back and forth movement of one or more output axes.
  • output axes On these output axes, are positioned elongated arms, themselves carrying scraper blades. These The blades rub against the windshield and drain the water away from the driver's field of vision.
  • the wiper system is generally mounted on the vehicle or more particularly on the chassis, in at least three attachment points provided for this purpose, by means of interface parts called damping pads.
  • the damping pads have the function of filtering the vibrations generated by the active ground substrate before their transmission via the points of fixation towards the interior of the vehicle where they are perceived by the vibratory sensory cues. and / or acoustic passengers.
  • the function of filtering damping studs for an acceleration source such as a wiping system depends on the order of magnitude of the dynamic transfer rate values of the stud. damping, in compression com ment ment.
  • the dynamic transfer stiffness (ISO-10846) is defined for a given filtration device, a level
  • the modulus of elasticity of a given material is a transfer stiffness related to the form factor of the test piece.
  • the wiping noises perceived in the passenger compartment originate in particular from the vibrations created by the electric motor by vibrating through the attachment points 25 towards the chassis to finally radiate inside the passenger compartment.
  • the rubber damping pads located at the interface between the wiper system and the fixing points have the function of filtering these vibrations, in other words to limit the transmission effect.
  • the current pads do not meet the expectations. Indeed, the perceived noise inside the cabin can have troublesome components up to 2000Hz and to fulfill the function of filtration, it is advisable to design rubber pads able to filter the vibrations on the widest possible range from 40-2000Hz.
  • the dynamic stiffness of transfer of the damping pad varies as a function of the frequency, the temperature, the level of precharge and the level of stress: for frequencies close to 1000 Hz the pads used in the prior art have values of dynamic stiffness of transfer too important for satisfactory filtration.
  • the object of the present invention is therefore to meet at least in part the needs described above.
  • the subject of the invention is a material adapted to active solid-state sources of the small electric motor vehicle type for which the vibratory excitation is of the "acceleration source” type in a frequency band of between 40.degree. and 2000Hz, characterized in that in that its hardness is less than 40 Shore A and its level of resistance to fracture is greater than 10MPa, its hardness is preferably less than or equal to 38 Shore A.
  • the level of resistance to rupture is, for example, greater than 12 MPa, or even greater than or equal to 14 MPa.
  • the material according to the invention has, in particular, viscoelastic characteristics such as the complex modulus of elasticity
  • corresponds substantially to the real part of the modulus of elasticity E '.
  • measured for a frequency of 200 Hz under excitation of 2.5 ⁇ peak / peak for an example of a cylindrical stud of height 14 mm and section 6 mm 2 made of a material according to the invention is example less than 4.5 MPa.
  • measured for a frequency of 50Hz under 40 ⁇ peak / peak, under 8% precharge, and at room temperature is less than 3.8 MPa.
  • the hardness of the material is, for example, between 20 and 40 Shore A, in particular between 30 and 40 Shore A, in particular between 35 and 40 Shore A, and even between 35 and 38 Shore A.
  • the hardness is measured at ambient temperature using a standard durometer.
  • the material includes several rubbers.
  • the material comprises at least one rubber of grades extended with oils, especially extended to 100 phr ("phr" in English).
  • rubber of grades extended to oils is meant a rubber containing a pre-integrated plasticizing oil during the polymerization phase.
  • the material comprises a mineral oil of petroleum origin composed of units with a paraffinic, naphthenic and aromatic structure, the content of paraffinic structure units is in particular greater than 60% and the content of units with an aromatic structure of less than 10%.
  • the material comprises SBR (styrene-butadiene) rubber and / or EPDM (ethylene-propylene-diene monomer) rubber
  • the material comprises at least one EPDM rubber with an ethylene content of greater than 60%, in particular an EPDM rubber extended with oils.
  • the material comprises at least one EPDM rubber with an ethylene content of between 45% and 50%,
  • the material comprises at least one EPDM rubber with a diene content greater than 5%, or even greater than 8%, -
  • the material has a Mooney viscosity of less than 40 Mooney points, especially between 34 and 40 points Mooney ML (1 +4) 100 ° C according to the current standard NFT43005.
  • the invention makes it possible to achieve a very low level of hardness of less than 40 Shore A or even of the order of 30 to 40 Shore A without resorting to a material having a high plasticizer content, which would prevent - during making the mixture - to generate sufficient friction between the elastomer and the other additives needed for formulation.
  • EPDM rubber of extended oil grades allows for better oxidation resistance, especially ozone resistance which is compatible with standards.
  • the material used in the invention thus has an ability not to generate cracking after exposure to 200 ppm of ozone concentration at 40 ° C for 72 hours under a deformation of 15%.
  • the diene content is especially chosen to allow a better vulcanization efficiency.
  • An ethylene content greater than 60% allows the EPDM grade thus selected to have a semicrystalline character which gives it a better mechanical strength than the conventional EPDM grades, amorphous at ethylene levels of the order of 50 to 50%. 60%.
  • the subject of the invention is a filtration device for a small electric motor, in particular a vehicle, made of a material as described above.
  • the device by virtue of the viscoelastic characteristics of the material chosen, the device provides better decoupling between the engine attachment means, in particular a wheelhouse, and the passenger compartment.
  • the device has in particular a dynamic transfer stiffness at ambient temperature between 0.1 N / m and 10 N / m in the frequency band between 40 and 2000 Hz, in particular between 50 and 1000 Hz.
  • the dynamic stiffness, expressed in N / m, is measured at room temperature using a DMA (Dynamic Mechanical Analysis).
  • the device comprises for example a pad or damper block.
  • the filtration device is used in particular for mounting a support of a wiper mechanism.
  • the stud comprises in particular a bore which is for example through.
  • the bore is located in particular at the longitudinal axis of the stud.
  • the damping device is for example as disclosed in the patent application EP 2 767 768.
  • the subject of the invention is a wiper system of a window of a vehicle comprising at least one filtration device as described above,
  • the system comprises, for example, three filtration devices.
  • the filtration devices are of identical shape or not.
  • FIG. 1 shows in perspective a wiper system of a window of a vehicle according to the invention
  • FIGS. 2 to 6 illustrate exemplary embodiments of filtration devices according to the invention
  • FIG. 1 shows a wiper system 20 for a window 150 of a vehicle which comprises a motor-driver 22, two drive shafts 24 for the wiping brushes 25 rotating about a 25 vertical axis, and a wheelhouse 26 which converts the continuous rotational movement u of the output of the motoréducteu r 22 in an alternating rotational movement of each drive shaft 24.
  • the wiper system 20 is mounted on a body structure element of the vehicle 100 at three points defined by mounting means 32 of the wiper system arranged to cooperate with complementary means 36 of the wiper system.
  • the wiper / wiper system 20 is an element which generates vibrations which are transmitted to the users of the vehicle when the wiper system 20 is specifically connected to the wiper system. the body structure element.
  • the mounting means 32 each comprise a filter device 10 which is interposed between the wheelhouse 26, in particular a support 1 4 of the wheelhouse lustred on the examples of Fig ures 7 to 1 1, and the structure checkout 1 00.
  • the filtration devices 10 of the wiper system 20 comprise a damping block 1 made of a material M having a hardness of less than 40 Shore A and a level of tensile strength greater than 10 MPa.
  • the hardness of the material M is in particular between 20 and 40 Shore A.
  • the material has a Mooney viscosity of less than 40 Mooney points, in particular between 34 and 40 Mooney points ML (1 +4) 100 ° C.
  • the constituent material of the damping devices 1 comprises several rubbers M1, M2. It comprises in particular at least one rubber of extended grades with oils, especially extended to 100pcc.
  • the material comprises in particular a first EPDM rubber with an ethylene content of greater than 60% and a second EPDM rubber, the latter having an ethylene content of between 45% and 50%.
  • the first and second EPDM rubber have a diene content greater than 5%, in particular greater than 8%.
  • the damping blocks 1 of the devices 10 illustrated in FIGS. 2 to 6 comprise, for example, a groove 30 between two flanges 12. They may have, according to the embodiments, a symmetry of revolution along their longitudinal axis X.
  • the damping devices 10 include in particular a through bore 16.
  • this formula is balanced according to a filler ratio of (carbon black + chalk) / plasticizer of 74/30 phr making it possible to produce a homogeneous mixture according to a process of industrial type, of rapid incorporation. (of the order of five minutes) and causing no phenomenon of sticking to the walls of the mixer.
  • the amount of oil already contained in the polymer makes it possible to give the mixture its flexibility.
  • the Mooney viscosity level of material equal to 33 pts Mooney is
  • the invention is not limited to the illustrated examples.
  • the above material examples include an EPDM rubber.
  • the invention also covers materials comprising an SBR rubber.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Vibration Prevention Devices (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Filtration Of Liquid (AREA)
  • Filtering Materials (AREA)

Abstract

The invention relates to a material (M) adapted to active structure-borne sources of the small electric motor type for a motor vehicle, for which sources vibration excitation is of the acceleration source type in a frequency band of between 40 and 2000Hz, characterised in that the hardness of the material is less than or equal to 40 Shore A and its tensile strength is greater than 10MPa.

Description

MATERIAU POUR DISPOSITIF DE FILTRATION DES VIBRATIONS, DISPOSITIF DE FILTRATION DES VIBRATIONS ET SYSTEME D'ESSUYAGE  VIBRATION FILTRATION DEVICE MATERIAL, VIBRATION FILTRATION DEVICE, AND WIPING SYSTEM

COMPRENANT UN TEL DISPOSITIF  INCLUDING SUCH A DEVICE

5 Le domaine de la présente invention est celui de la filtration des vibrations générées par le fonctionnement de moteurs électriques de petite taille. Par petit moteur électrique de petite taille on entend dans le cadre de la présente invention un moteur pas à pas, un actuateur, un moteur à courant continu ou un moteur asynchrone, dont la masse est inférieure à 10 kg, en particulier utilisés pour î o actionner des équipements pour les véhicules, et plus particulièrement des équipements pour l'essuyage des vitres d'un véhicule. The field of the present invention is that of filtering vibrations generated by the operation of small electric motors. By small electric motor of small size is meant in the context of the present invention a stepping motor, an actuator, a DC motor or an asynchronous motor, whose mass is less than 10 kg, in particular used for o operating equipment for vehicles, and more particularly equipment for wiping the windows of a vehicle.

Le type de moteur concerné par l'invention constitue ainsi une source solidienne active et a pour caractéristique principale que les niveaux d'accélérations vibratoires que l'on va chercher à filtrer sont du même ordre de The type of motor concerned by the invention thus constitutes an active solid source and has the main characteristic that the levels of vibrational acceleration that we will seek to filter are of the same order of magnitude.

15 grandeur quelle que soit la fréquence, pour une bande de fréquence comprise entre 40 et 2000Hz. Ce type de source peut être qualifié de source d'accélération, par comparaison à des sources, plutôt d'encombrement et de masse beaucoup plus grandes, dont les niveaux de déplacement seraient du même ordre de grandeur quelle que soit la fréquence, pour une bande de fréquence utile15 magnitude regardless of the frequency, for a frequency band between 40 and 2000Hz. This type of source can be qualified as a source of acceleration, compared to sources, rather larger size and mass, whose displacement levels would be of the same order of magnitude regardless of the frequency, for a band useful frequency

20 comprise entre 10 et 300 Hz, typiquement. Between 10 and 300 Hz, typically.

Il existe ainsi un besoin de définir un matériau spécifique pour un dispositif de filtration, adapté à une source solidienne active pour laquelle l'excitation vibratoire est de type source d'accélération dans une bande de fréquence comprise entre 40 et 2000Hz.  There is thus a need to define a specific material for a filtration device adapted to an active solid source for which the vibratory excitation is of the acceleration source type in a frequency band of between 40 and 2000 Hz.

25 Un exemple d'une telle source solidienne active, non limitatif de l'invention, est un moteur de système d'essuie-glace. Les véhicules automobiles sont couramment équipés de système d'essuie-glace pour assurer un balayage et un lavage du pare-brise ou de la lunette arrière et éviter que la vision qu'a le conducteur de son environnement ne soit perturbée. Le moteur d'essuie-glace est An example of such an active, non-limiting solid source of the invention is a windshield wiper system motor. Motor vehicles are commonly equipped with a windshield wiper system to sweep and wash the windshield or rear window and prevent the driver's vision from being disturbed. The wiper motor is

30 associé soit à un système mécanique, classiquement un système de bielle manivelle, soit à une fonction électronique, de façon à assurer un mouvement de va-et-vient angulaire d'un ou plusieurs axes de sortie. Sur ces axes de sortie, sont positionnés des bras allongés, porteurs eux-mêmes de lames racleuses. Ces lames frottent contre le pare-brise et évacuent l'eau en l'amenant en dehors du champ de vision du conducteur. Associated with either a mechanical system, conventionally a crank system or an electronic function, so as to provide an angular back and forth movement of one or more output axes. On these output axes, are positioned elongated arms, themselves carrying scraper blades. These The blades rub against the windshield and drain the water away from the driver's field of vision.

Le système d'essuie-glace est généralement monté sur le véhicule ou plus particulièrement sur le châssis, en au moins trois points de fixation prévus à cet 5 effet, par l'intermédiaire de pièces d'interface appelées plots amortisseurs.  The wiper system is generally mounted on the vehicle or more particularly on the chassis, in at least three attachment points provided for this purpose, by means of interface parts called damping pads.

Les plots amortisseurs ont pou r vocation de filtrer l es vibrations générées par la sou rce sol id ienne active avant leu r transm ission via les points de fixation vers l' intérieur du véh icu le où i ls sont perçus par les capteu rs sensoriels vibratoires et/ou acoustiques des passagers . î o La fonction de filtration des plots amortisseu rs pou r une sou rces d'accélération tel le qu' un systèm e d'essuyage dépend de l'ordre de g randeu r des valeurs de ra ideu r dynam iq ue de transfert du plot amortisseu r, en compression com me en ment. La raideur dynamique de transfert (ISO-10846) est définie pour un dispositif de filtration donné, un niveau The damping pads have the function of filtering the vibrations generated by the active ground substrate before their transmission via the points of fixation towards the interior of the vehicle where they are perceived by the vibratory sensory cues. and / or acoustic passengers. The function of filtering damping studs for an acceleration source such as a wiping system depends on the order of magnitude of the dynamic transfer rate values of the stud. damping, in compression com ment ment. The dynamic transfer stiffness (ISO-10846) is defined for a given filtration device, a level

15 de fréquence donné, sous une pré-charge donnée, à une température donnée, et un niveau de sollicitation donné par un binôme en cisaillement (module et déphasage ou partie réelle et imaginaire) et en compression (module et déphasage ou partie réelle et imaginaire). Sa valeur, en N/m, est mesurée à l'aide d'un dispositif de mesure de raideur directe ou indirecte selon la norme ISO-Of given frequency, under a given pre-charge, at a given temperature, and a solicitation level given by a binomial in shear (modulus and phase shift or real and imaginary part) and in compression (module and phase shift or real and imaginary part) ). Its value, in N / m, is measured using a device for measuring direct or indirect stiffness according to the ISO-

20 10846. Le module d'élasticité d'un matériau donné est une raideur de transfert rapportée au facteur de forme de la pièce testée. 10846. The modulus of elasticity of a given material is a transfer stiffness related to the form factor of the test piece.

Les bruits d'essuyage perçus dans l'habitacle proviennent notamment des vibrations créées par le moteur électrique en transitant par vibration par les points 25 de fixation, vers le châssis, pour finalement rayonner à l'intérieur de l'habitacle. The wiping noises perceived in the passenger compartment originate in particular from the vibrations created by the electric motor by vibrating through the attachment points 25 towards the chassis to finally radiate inside the passenger compartment.

Les plots amortisseu rs en caoutchouc localisés à l'interface entre le système d'essuyage et les points de fixation ont pour fonction de filtrer ces vibrations, autrement dit de limiter l'effet de transmission.  The rubber damping pads located at the interface between the wiper system and the fixing points have the function of filtering these vibrations, in other words to limit the transmission effect.

Cependant, les plots actuels ne permettent pas de répondre 30 aux attentes . En effet, le bruit perçu à l'intérieur de l'habitacle peut présenter des composantes gênantes jusqu'à 2000Hz et pour remplir la fonction de filtration, il convient de concevoir des plots en caoutchouc aptes à filtrer les vibrations sur la plus large gamme possible de 40-2000Hz. La raideur dynamique de transfert du plot amortisseur varie en fonction de la fréquence, de la température, du niveau de précharge et du niveau de sollicitation : pour des fréquences voisines de 1000Hz les plots utilisés dans l'art antérieur présentent des valeurs de raideur dynamique de transfert trop importantes pour une filtration satisfaisante. However, the current pads do not meet the expectations. Indeed, the perceived noise inside the cabin can have troublesome components up to 2000Hz and to fulfill the function of filtration, it is advisable to design rubber pads able to filter the vibrations on the widest possible range from 40-2000Hz. The dynamic stiffness of transfer of the damping pad varies as a function of the frequency, the temperature, the level of precharge and the level of stress: for frequencies close to 1000 Hz the pads used in the prior art have values of dynamic stiffness of transfer too important for satisfactory filtration.

Il existe un besoin pour réaliser des plots en caoutchouc de caractéristiques présentant une courbe de raideur dynamique de transfert qui dépend peu de la fréquence à température ambiante, sous condition de charge donnée et pour une source d'accélération.  There is a need to provide rubber pads with characteristics having a dynamic transfer stiffness curve that is low dependent on the frequency at ambient temperature, under given load condition and for an acceleration source.

En outre, mettre au point une matière de très basse dureté a pour inconvénient de dégrader les propriétés mécaniques de la matière, ainsi notamment, la caractéristique de Résistance à la Rupture, se retrouve à un niveau faible de l'ordre de 6 à 8 MPa. Il existe un besoin pour concevoir un matériau de très basse dureté tout en ayant des propriétés mécaniques satisfaisantes.  In addition, developing a material of very low hardness has the disadvantage of degrading the mechanical properties of the material, and in particular, the characteristic of resistance to rupture, is found at a low level of the order of 6 to 8 MPa . There is a need to design a material of very low hardness while having satisfactory mechanical properties.

Le but de la présente invention est donc de répondre au moins en partie aux besoins décrits ci-dessus.  The object of the present invention is therefore to meet at least in part the needs described above.

Selon un premier aspect, l'invention a pour objet un matériau adapté à des sources solidiennes actives de type petit moteur électrique pour véhicule automobile pour lesquels l'excitation vibratoire est de type « source d'accélération » dans une bande de fréquence comprise entre 40 et 2000Hz, caractérisé en ce que en ce que sa dureté est inférieure à 40 Shore A et son niveau de résistance à la rupture est supérieur à 10MPa, sa dureté est de préférence inférieure ou égale à 38 Shore A.  According to a first aspect, the subject of the invention is a material adapted to active solid-state sources of the small electric motor vehicle type for which the vibratory excitation is of the "acceleration source" type in a frequency band of between 40.degree. and 2000Hz, characterized in that in that its hardness is less than 40 Shore A and its level of resistance to fracture is greater than 10MPa, its hardness is preferably less than or equal to 38 Shore A.

Le niveau de résistance à la rupture est par exemple supérieur à 12MPa, voire supérieur ou égal à 14 MPa.  The level of resistance to rupture is, for example, greater than 12 MPa, or even greater than or equal to 14 MPa.

Le matériau selon l'invention présente en particulier des caractéristiques viscoélastiques telles que le module d'élasticité complexe | E*| , mesuré pour une fréquence de 1000Hz sous excitation de 0,1 m pic/pic, sous 8% de pré-charge, et à température ambiante, soit inférieur à 8,5 MPa. Le module d'élasticité complexe | E*| correspond sensiblement à la partie réelle du module d'élasticité E'. The material according to the invention has, in particular, viscoelastic characteristics such as the complex modulus of elasticity | E * | , measured for a frequency of 1000 Hz under excitation of 0.1 m peak / peak, under 8% pre-charge, and at room temperature, less than 8.5 MPa. The modulus of elasticity complex | E * | corresponds substantially to the real part of the modulus of elasticity E '.

Le module d'élasticité complexe | E*| , mesuré pour une fréquence de 200Hz sous excitation de 2,5 μιτι pic/pic pour un exemple de plot cylindrique de hauteur 14mm et section 6mm2 réalisé dans un matériau selon l'invention est par exemple inférieur à 4,5 MPa. Selon un autre exemple, de le module d'élasticité complexe | E*| , mesuré pour une fréquence de 50Hz sous 40 μιτι pic/pic, sous 8% de précharge, et à température ambiante est inférieur à 3.8 MPa. The modulus of elasticity complex | E * | , measured for a frequency of 200 Hz under excitation of 2.5 μιτι peak / peak for an example of a cylindrical stud of height 14 mm and section 6 mm 2 made of a material according to the invention is example less than 4.5 MPa. According to another example, the complex modulus of elasticity | E * | , measured for a frequency of 50Hz under 40 μιτι peak / peak, under 8% precharge, and at room temperature is less than 3.8 MPa.

5 5

Matériau  Material

La dureté du matériau est par exemple comprise entre 20 et 40 Shore A , notamment entre 30 et 40 Shore A, en particulier entre 35 et 40 Shore A, voire entre 35 et 38 Shore A .  The hardness of the material is, for example, between 20 and 40 Shore A, in particular between 30 and 40 Shore A, in particular between 35 and 40 Shore A, and even between 35 and 38 Shore A.

î o De façon connue de l'homme du métier, la dureté est mesurée à température ambiante à l'aide d'un Duromètre normalisé. In a manner known to those skilled in the art, the hardness is measured at ambient temperature using a standard durometer.

Selon d'autres caractéristiques de l'invention , indépendam ment ou en combinaison :  According to other features of the invention, independently or in combination:

- Le matériau comprend plusieurs caoutchoucs.  - The material includes several rubbers.

15 - Le matériau comprend au moins un caoutchouc de grades étendus aux huiles, notamment étendu à 100pcc (« phr » en anglais). On entend par caoutchouc de grades étendus aux huiles un caoutchouc contenant une huile plastifiante pré-intégrée lors de la phase de polymérisation. Ces élastomères de très hauts poids moléculaires sont capables de par leur structure interne, de The material comprises at least one rubber of grades extended with oils, especially extended to 100 phr ("phr" in English). By rubber of grades extended to oils is meant a rubber containing a pre-integrated plasticizing oil during the polymerization phase. These elastomers of very high molecular weight are capable by their internal structure, of

20 retenir à cœur l'huile plastifiante. Remember the plasticizing oil.

- Le matériau comprend une huile minérale d'origine pétrolière composé de motifs à structure paraffinique, naphténique et aromatique, le taux de motifs à structure paraffinique est en particulier supérieur à 60% et le taux de motifs à structure aromatique inférieur à 10%.  The material comprises a mineral oil of petroleum origin composed of units with a paraffinic, naphthenic and aromatic structure, the content of paraffinic structure units is in particular greater than 60% and the content of units with an aromatic structure of less than 10%.

25 - Le matériau comprend un caoutchouc de SBR (styrène-butadiène) et/ou un caoutchouc d'EPDM (éthylène-propylène-diène monomère)  The material comprises SBR (styrene-butadiene) rubber and / or EPDM (ethylene-propylene-diene monomer) rubber

- Le matériau comprend au moins un caoutchouc d'EPDM à taux d'éthylène supérieur à 60%, notamment un caoutchouc d'EPDM étendu aux huiles.  The material comprises at least one EPDM rubber with an ethylene content of greater than 60%, in particular an EPDM rubber extended with oils.

30 - le matériau comprend au moins un caoutchouc d'EPDM à taux d'éthylène compris entre 45% et 50%,  The material comprises at least one EPDM rubber with an ethylene content of between 45% and 50%,

- le matériau comprend au moins un caoutchouc d'EPDM à taux de diène supérieur à 5%, voire supérieur à 8%, - le matériau présente une viscosité Mooney inférieure à 40 points Mooney, notamment comprise entre 34 et 40 points Mooney ML(1 +4)100°C selon la norme en vigueur NFT43005. the material comprises at least one EPDM rubber with a diene content greater than 5%, or even greater than 8%, - The material has a Mooney viscosity of less than 40 Mooney points, especially between 34 and 40 points Mooney ML (1 +4) 100 ° C according to the current standard NFT43005.

L'invention permet d'atteindre un niveau de dureté très faible inférieure à 40 5 Shore A, voire de l'ordre de 30 à 40 Shore A sans avoir recours à un matériau présentant un taux de plastifiant élevé, ce qui empêcherait - lors de la confection du mélange - de générer suffisamment de frottement entre l'élastomère et les autres additifs nécessaire à la formulation.  The invention makes it possible to achieve a very low level of hardness of less than 40 Shore A or even of the order of 30 to 40 Shore A without resorting to a material having a high plasticizer content, which would prevent - during making the mixture - to generate sufficient friction between the elastomer and the other additives needed for formulation.

Le choix d'un caoutchouc d'EPDM de grades étendus aux huiles permet une î o meilleure résistance à l'oxydation, en particulier une tenue ozone compatible avec les standards. Le matériau utilisé dans l'invention présente ainsi une aptitude à ne pas générer de craquelure après une exposition à 200pphm de concentration ozone, à 40°C pendant 72h sous une déformation de 15%.  The choice of EPDM rubber of extended oil grades allows for better oxidation resistance, especially ozone resistance which is compatible with standards. The material used in the invention thus has an ability not to generate cracking after exposure to 200 ppm of ozone concentration at 40 ° C for 72 hours under a deformation of 15%.

Le taux de diène est notamment choisi pour permettre une meilleure 15 efficacité de vulcanisation.  The diene content is especially chosen to allow a better vulcanization efficiency.

Un taux d'éthylène supérieur à 60% permet au grade d'EPDM ainsi sélectionné de revêtir un caractère semi-cristallin qui lui confère une meilleure tenue mécanique que les grades EPDM classiques, amorphes aux taux d'éthylène de l'ordre de 50 à 60%.  An ethylene content greater than 60% allows the EPDM grade thus selected to have a semicrystalline character which gives it a better mechanical strength than the conventional EPDM grades, amorphous at ethylene levels of the order of 50 to 50%. 60%.

20 Dispositif de filtration 20 Filtration device

Selon un autre de ses aspects l'invention a pour objet un dispositif de filtration pour petit moteur électrique, notamment de véhicule, réalisé en un matériau tel que décrit précédemment.  According to another of its aspects, the subject of the invention is a filtration device for a small electric motor, in particular a vehicle, made of a material as described above.

Grâce à l'invention, de par les caractéristiques visco-élastiques du matériau 25 choisi, le dispositif assure un meilleur découplage entre les moyens de fixation du moteur, notamment une timonerie, et l'habitacle.  Thanks to the invention, by virtue of the viscoelastic characteristics of the material chosen, the device provides better decoupling between the engine attachment means, in particular a wheelhouse, and the passenger compartment.

Le dispositif présente en particulier une raideur dynamique de transfert à température ambiante comprise entre 0.1 N/m et 10 N/m sur la bande de 30 fréquence comprise entre 40 et 2000Hz, notamment entre 50 et 1000Hz.. La raideur dynamique, exprimée en N/m, est mesurée à température ambiante à l'aide d'une DMA (Dynamic Mechanical Analysis). The device has in particular a dynamic transfer stiffness at ambient temperature between 0.1 N / m and 10 N / m in the frequency band between 40 and 2000 Hz, in particular between 50 and 1000 Hz. The dynamic stiffness, expressed in N / m, is measured at room temperature using a DMA (Dynamic Mechanical Analysis).

Le dispositif comporte par exemple un plot ou bloc amortisseur. Le dispositif de filtration sert notamment au montage d'un support d'un mécanisme d'essuie-glace. The device comprises for example a pad or damper block. The filtration device is used in particular for mounting a support of a wiper mechanism.

Le plot comporte en particulier un alésage qui est par exemple traversant. L'alésage est situé notamment au niveau de l'axe longitudinal du plot.  The stud comprises in particular a bore which is for example through. The bore is located in particular at the longitudinal axis of the stud.

5 Le dispositif d'amortissement est par exemple tel que divulgué dans la demande de brevet EP 2 767 768.  The damping device is for example as disclosed in the patent application EP 2 767 768.

Selon encore un autre de ses aspects l'invention a pour objet un système d'essuyage d'une vitre d'un véhicule comprenant au moins un dispositif de filtration tel que décrit précédemment,  According to yet another of its aspects the subject of the invention is a wiper system of a window of a vehicle comprising at least one filtration device as described above,

î o Le système comporte par exemple trois dispositifs de filtration. Les dispositifs de filtration sont de forme identique ou non. The system comprises, for example, three filtration devices. The filtration devices are of identical shape or not.

D'autres caractéristiques, détails et avantages de l'invention ressortiront plus clairement à la lecture de la description donnée ci-après à titre indicatif en relation 15 avec des dessins dans lesquels : Other characteristics, details and advantages of the invention will emerge more clearly on reading the description given below as an indication in relation to drawings in which:

- la fig ure 1 il lustre en perspective un système d'essuyage d'une vitre d'un véhicule conforme à l'invention ,  FIG. 1 shows in perspective a wiper system of a window of a vehicle according to the invention,

les figures 2 à 6 illustrent des exemples de réalisation de dispositifs de filtration selon l'invention, et  FIGS. 2 to 6 illustrate exemplary embodiments of filtration devices according to the invention, and

20 - les figures 7 à 12 illustrent en coupe axiale d'autres exemples de réalisation de dispositifs de filtration. - Figures 7 to 12 illustrate in axial section other embodiments of filtration devices.

On a représenté à la fig ure 1 un système d'essuyage 20 d'une vitre 150 d'un véhicule q u i com porte un motoréducteu r 22, deux arbres d'entraînement 24 des balais d'essuyage 25 en rotation autour d'un 25 axe vertical , et u ne timonerie 26 q u i transforme le mouvement de rotation contin u de la sortie d u motoréducteu r 22 en u n mouvement de rotation alternée de chaq ue arbre d'entraînement 24.  FIG. 1 shows a wiper system 20 for a window 150 of a vehicle which comprises a motor-driver 22, two drive shafts 24 for the wiping brushes 25 rotating about a 25 vertical axis, and a wheelhouse 26 which converts the continuous rotational movement u of the output of the motoréducteu r 22 in an alternating rotational movement of each drive shaft 24.

Le système d'essuyage 20 est monté sur u n élément de structure de caisse du véh icule 1 00 en trois points défin is par des moyens de 30 montage 32 du système d'essuyage agencés pou r coopérer avec des moyens com plémenta ire 36 de l'élément de structu re de ca isse 1 00. Le mécan isme d'essu ie-glace/ système d'essuyage 20 est un élément q u i génère des vibrations q u i sont transm ises j usqu'aux util isateu rs du véh icule lorsq ue le système d'essuyage 20 est d irectement rel ié à l'élément de structu re de caisse . The wiper system 20 is mounted on a body structure element of the vehicle 100 at three points defined by mounting means 32 of the wiper system arranged to cooperate with complementary means 36 of the wiper system. structural element of ca isse 1 00. The wiper / wiper system 20 is an element which generates vibrations which are transmitted to the users of the vehicle when the wiper system 20 is specifically connected to the wiper system. the body structure element.

5 Dans le but de filtrer les vibrations prod u ites par le mécan isme d'essu ie-glace 20, et pou r empêcher q ue cel les-ci ne soient transm ises à l'élément de structure de caisse d u vé h icu le, les moyens de montage 32 comportent chacun un d ispositif de filtration 1 0 q u i est interposé entre la timonerie 26 , notam ment u n support 1 4 de la î o timonerie il lustré sur les exemples des fig ures 7 à 1 1 , et la structure de caisse 1 00.  For the purpose of filtering the vibrations produced by the windshield wiper mechanism 20, and to prevent them from being transmitted to the body structure element of the vehicle. , the mounting means 32 each comprise a filter device 10 which is interposed between the wheelhouse 26, in particular a support 1 4 of the wheelhouse lustred on the examples of Fig ures 7 to 1 1, and the structure checkout 1 00.

Les dispositifs de filtration 10 du système d'essuyage 20 comportent un bloc amortisseur 1 réalisé en un matériau M présentant une dureté inférieure à 40 Shore A et un niveau de résistance à la rupture supérieur à 10MPa.  The filtration devices 10 of the wiper system 20 comprise a damping block 1 made of a material M having a hardness of less than 40 Shore A and a level of tensile strength greater than 10 MPa.

15 Dans l'exemple illustré la dureté du matériau M est notamment comprise entre 20 et 40 Shore A. In the example illustrated, the hardness of the material M is in particular between 20 and 40 Shore A.

Le matériau présente en particulier une viscosité Mooney inférieure à 40 points Mooney , en particulier comprise entre 34 et 40 points Mooney ML(1 +4)100°C  In particular, the material has a Mooney viscosity of less than 40 Mooney points, in particular between 34 and 40 Mooney points ML (1 +4) 100 ° C.

20 Dans l'exemple illustré le matériau constitutif des dispositifs d'amortissement 1 comprend plusieurs caoutchoucs M1 , M2. Il comprend en particulier au moins un caoutchouc de grades étendus aux huiles, notamment étendu à 100pcc.  In the illustrated example, the constituent material of the damping devices 1 comprises several rubbers M1, M2. It comprises in particular at least one rubber of extended grades with oils, especially extended to 100pcc.

Le matériau comprend en particulier un premier caoutchouc d'EPDM à 25 taux d'éthylène supérieur à 60% et un deuxième caoutchouc d'EPDM, ce dernier présentant un taux d'éthylène compris entre 45% et 50%.  The material comprises in particular a first EPDM rubber with an ethylene content of greater than 60% and a second EPDM rubber, the latter having an ethylene content of between 45% and 50%.

Le premier et le deuxième caoutchouc d'EPDM présentent un taux de diène supérieur à 5% en particulier supérieur à 8%. Les blocs amortisseur 1 des dispositifs 10 illustrés aux figures 2 à 6 comportent par exemple une gorge 15 30 entre deux collerettes 12. Ils peuvent présenter selon les modes de réalisation une symétrie de révolution selon leur axe longitudinal X.  The first and second EPDM rubber have a diene content greater than 5%, in particular greater than 8%. The damping blocks 1 of the devices 10 illustrated in FIGS. 2 to 6 comprise, for example, a groove 30 between two flanges 12. They may have, according to the embodiments, a symmetry of revolution along their longitudinal axis X.

Les dispositifs d'amortissement 10 comportent notamment un alésage traversant 16. Exemple de réalisation : The damping devices 10 include in particular a through bore 16. Example of realization:

Figure imgf000009_0001
Figure imgf000009_0001

Du point de vue procédé de mélange, cette formule est équilibrée selon un ratio de charge de (noir de carbone + craie) / plastifiant de 74 / 30 pce permettant de 5 réaliser un mélange homogène selon un process de type industriel, d'incorporation rapide (de l'ordre de cinq minutes) et n'occasionnant aucun phénomène de collage aux parois du mélangeur. From the point of view of the mixing process, this formula is balanced according to a filler ratio of (carbon black + chalk) / plasticizer of 74/30 phr making it possible to produce a homogeneous mixture according to a process of industrial type, of rapid incorporation. (of the order of five minutes) and causing no phenomenon of sticking to the walls of the mixer.

La quantité d'huile déjà contenue dans le polymère permet de conférer au î o mélange sa souplesse. The amount of oil already contained in the polymer makes it possible to give the mixture its flexibility.

Le niveau de viscosité Mooney du matériau égal à 33 pts Mooney est The Mooney viscosity level of material equal to 33 pts Mooney is

suffisamment bas et permet d'envisager un procédé de moulage par compression, ou compression tranfert, ou même par moulage injection.  low enough and allows to consider a compression molding process, or tranfert compression, or even by injection molding.

15 Le mélange ainsi confectionné puis vulcanisé 10 minutes à 190°C par moulage compression. The mixture thus made and then vulcanized for 10 minutes at 190 ° C. by compression molding.

Il présente les propriétés mécaniques suivantes :  It has the following mechanical properties:

dureté(Shore A) (pts) 38  hardness (Shore A) (pts) 38

Module 100% (MPa) 0.9  Module 100% (MPa) 0.9

Module 300% (MPa) 2.4  Module 300% (MPa) 2.4

résistance à la rupture (MPa) 14  breaking strength (MPa) 14

allongement à la rupture (%) 980  elongation at break (%) 980

dureté(Shore A) (pts) 38 Lors des tests effectués, pour une plage de fréquence entre 40 et 1000Hz, le module de la raideur dynamique de transfert mesurée varie entre 0.1 N/m et 10 N/m. hardness (Shore A) (pts) 38 During the tests carried out, for a frequency range between 40 and 1000 Hz, the modulus of the dynamic transfer stiffness measured varies between 0.1 N / m and 10 N / m.

L'invention n'est pas limitée aux exemples illustrés. Les exemples de matériau ci-dessus comportent un caoutchouc d'EPDM. L'invention couvre également des matériaux comprenant un caoutchouc de SBR.  The invention is not limited to the illustrated examples. The above material examples include an EPDM rubber. The invention also covers materials comprising an SBR rubber.

Claims

REVENDICATIONS 1. Matériau (M) adapté à des sources solidiennes actives de type petit moteur électrique pour véhicule automobile pour lesquels l'excitation vibratoire est de type source d'accélération dans une bande de fréquence comprise entre 40 et 2000Hz, caractérisé en ce que sa dureté est inférieure à 40 Shore A et son niveau de résistance à la rupture est supérieur à 10MPa.  1. Material (M) adapted to active solid-state sources of small electric motor type for a motor vehicle for which the vibratory excitation is of the acceleration source type in a frequency band of between 40 and 2000 Hz, characterized in that its hardness is less than 40 Shore A and its level of tensile strength is greater than 10 MPa. 2. Matériau selon la revendication 1 , pour lequel la dureté est comprise entre 20 et 40 Shore A, voire entre 30 et 38 Shore A. 2. Material according to claim 1, wherein the hardness is between 20 and 40 Shore A, or even between 30 and 38 Shore A. 3. Matériau selon l'une quelconque des revendications précédentes, comprenant plusieurs caoutchoucs (M1 , M2). 3. Material according to any one of the preceding claims, comprising several rubbers (M1, M2). 4. Matériau selon l'une quelconque des revendications précédentes, comprenant au moins un caoutchouc de grades étendus aux huiles, notamment étendu à 100pcc 4. Material according to any one of the preceding claims, comprising at least one rubber of extended grades with oils, in particular extended to 100pcc 5. Matériau selon l'une quelconque des revendications précédentes, comprenant une huile minérale d'origine pétrolière composé de motifs à structure paraffinique, naphténique et aromatique, les taux de motifs à structure paraffinique et à structure aromatique étant en particulier respectivement supérieur à 60% et inférieur à 10%. 5. Material according to any one of the preceding claims, comprising a mineral oil of petroleum origin composed of units with paraffinic, naphthenic and aromatic structure, the paraffinic structure and aromatic structure units being in particular respectively greater than 60%. and less than 10%. 6. Matériau selon l'une quelconque des revendications précédentes, comprenant un caoutchouc d'EPDM. The material of any of the preceding claims comprising an EPDM rubber. 7. Matériau selon l'une quelconque des revendications précédentes, comprenant au moins un caoutchouc d'EPDM à taux d'éthylène supérieur à 60%, notamment un caoutchouc d'EPDM étendu aux huiles. 7. Material according to any one of the preceding claims, comprising at least one EPDM rubber having an ethylene content of greater than 60%, in particular an EPDM rubber extended with oils. 8. Matériau selon l'une quelconque des revendications précédentes, comprenant au moins un caoutchouc d'EPDM à taux d'éthylène compris entre 45% et 50%. 8. Material according to any one of the preceding claims, comprising at least one EPDM rubber with an ethylene content of between 45% and 50%. 9. Matériau selon l'une quelconque des revendications précédentes, comprenant au moins un caoutchouc d'EPDM à taux de diène supérieur à 5%, voire supérieur à 8%. 9. Material according to any one of the preceding claims, comprising at least one EPDM rubber with a diene content greater than 5%, or even greater than 8%. 10. Matériau selon l'une quelconque des revendications précédentes, 5 présentant une viscosité Mooney inférieure à 40 points Mooney, notamment comprise entre 34 et 40 points Mooney. 10. Material according to any one of the preceding claims, having a Mooney viscosity of less than 40 Mooney points, especially between 34 and 40 Mooney points. 11. Dispositif de filtration des vibrations(10) pour petit moteur électrique, notamment de véhicule, comportant un bloc amortisseur (1 ) réalisé en un î o matériau (M) selon l'une quelconque des revendications précédentes. 11. A vibration filtering device (10) for a small electric motor, particularly a vehicle, comprising a damping block (1) made of a material (M) according to any one of the preceding claims. 12. Système d'essuyage (20) d'une vitre d'un véhicule comprenant au moins un dispositif de filtration (10) selon la revendication précédente. 12. System for wiping (20) a window of a vehicle comprising at least one filtration device (10) according to the preceding claim. 15 15
PCT/EP2017/064739 2016-06-29 2017-06-16 Material for a vibration filtering device, vibration filtering device, and wiper system comprising such a device Ceased WO2018001752A1 (en)

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FR1656127A FR3053423B1 (en) 2016-06-29 2016-06-29 VIBRATION FILTRATION DEVICE MATERIAL, VIBRATION FILTRATION DEVICE, AND WIPING SYSTEM COMPRISING SUCH A DEVICE

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290036A (en) * 1993-04-12 1994-03-01 Frank Fenton Cavity back iron with vibration dampening material in rear cavity
EP1860006A1 (en) * 2005-03-09 2007-11-28 Mitsuba Corporation Motor fixing structure
US20090239014A1 (en) * 2007-12-05 2009-09-24 Mitsui Chemicals, Inc. Rubber composition, crosslinked product and foam thereof, molded product therefrom, and use thereof
US20110118404A1 (en) * 2009-11-18 2011-05-19 Hyun-Dae Jung Blend Partner with Natural Rubber for Elastomeric Compounds
EP2767768A1 (en) 2013-02-18 2014-08-20 Franco Palmucci Cover for outdoor unit

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290036A (en) * 1993-04-12 1994-03-01 Frank Fenton Cavity back iron with vibration dampening material in rear cavity
EP1860006A1 (en) * 2005-03-09 2007-11-28 Mitsuba Corporation Motor fixing structure
US20090239014A1 (en) * 2007-12-05 2009-09-24 Mitsui Chemicals, Inc. Rubber composition, crosslinked product and foam thereof, molded product therefrom, and use thereof
US20110118404A1 (en) * 2009-11-18 2011-05-19 Hyun-Dae Jung Blend Partner with Natural Rubber for Elastomeric Compounds
EP2767768A1 (en) 2013-02-18 2014-08-20 Franco Palmucci Cover for outdoor unit

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