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WO2018058394A1 - Plastic material and preparation method thereof - Google Patents

Plastic material and preparation method thereof Download PDF

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Publication number
WO2018058394A1
WO2018058394A1 PCT/CN2016/100702 CN2016100702W WO2018058394A1 WO 2018058394 A1 WO2018058394 A1 WO 2018058394A1 CN 2016100702 W CN2016100702 W CN 2016100702W WO 2018058394 A1 WO2018058394 A1 WO 2018058394A1
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parts
plastic material
flame retardant
paraffin
cellulose
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Chinese (zh)
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张睿
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride

Definitions

  • the invention relates to the field of cleaning articles, in particular to a plastic material and a preparation method thereof.
  • plastic mainly composed of carbon, oxygen, hydrogen and nitrogen and other organic or inorganic elements, the finished product is a solid, which is a molten liquid in the manufacturing process, so it can be melted by heating, The pressure is applied to flow, cool and solidify to form various shapes. This large and varied material group is called plastic.
  • the invention provides a plastic material and a preparation method thereof.
  • the invention has the advantages of good insulation performance, good flame retardant performance, good wear resistance, high strength and tensile strength, in particular, excellent high frequency insulation.
  • the present invention provides the following technical solutions:
  • a plastic material consisting of the following mass fraction of ingredients: 20-30 parts of polyvinyl chloride resin, 1-3 parts of flame retardant, 3-5 parts of cadmium stearate, 4-6 parts of quartz sand, cellulose 8- 10 parts, 3-5 parts of paraffin, 5-7 parts of white carbon, 7-9 parts of ABS plastic, 5-15 parts of calcium carbonate, and 1-3 parts of toughening agent.
  • a method for preparing a plastic material has the following steps:
  • Step 1 mixing polyvinyl chloride resin, cadmium stearate, quartz sand, cellulose, paraffin, silica, ABS plastic and calcium carbonate to prepare a mixture 1;
  • Step 2 Mixing the mixture with the flame retardant and the toughening agent at a temperature of 200-220 ° C, and cooling to obtain a plastic material.
  • the invention has the advantages that the invention has the advantages of good insulation performance, good flame retardant performance, good wear resistance, high strength and tensile strength, and particularly excellent high-frequency insulation.
  • Embodiment 1 is a diagrammatic representation of Embodiment 1:
  • a plastic material is composed of the following mass fraction formula components: 20-30 parts of polyvinyl chloride resin, 1-3 parts of flame retardant, 3-5 parts of cadmium stearate, 4-6 parts of quartz sand, cellulose 8-10 Parts, 3-5 parts of paraffin, 5-7 parts of white carbon, 7-9 parts of ABS plastic, 5-15 parts of calcium carbonate, 1-3 parts of toughening agent.
  • Embodiment 2 is a diagrammatic representation of Embodiment 1:
  • a plastic material consists of the following mass fraction formula: 20 parts of polyvinyl chloride resin, 1 part of flame retardant, 3 parts of cadmium stearate, 4 parts of quartz sand, 8 parts of cellulose, 3 parts of paraffin, white carbon black 5 Parts, 7 parts of ABS plastic, 5 parts of calcium carbonate, 1 part of toughening agent.
  • Embodiment 3 is a diagrammatic representation of Embodiment 3
  • a plastic material consists of the following mass fraction formula: 25 parts of polyvinyl chloride resin, 2 parts of flame retardant, 4 parts of cadmium stearate, 5 parts of quartz sand, 9 parts of cellulose, 4 parts of paraffin, white carbon black 6 8 parts of ABS plastic, 10 parts of calcium carbonate, and 2 parts of toughening agent.
  • Embodiment 4 is a diagrammatic representation of Embodiment 4:
  • a plastic material consists of the following mass fraction formula: 30 parts of polyvinyl chloride resin, 3 parts of flame retardant, 5 parts of cadmium stearate, 6 parts of quartz sand, 10 parts of cellulose, 5 parts of paraffin, white carbon black 7 Parts, 9 parts of ABS plastic, 15 parts of calcium carbonate, and 3 parts of toughening agent.
  • Embodiment 5 is a diagrammatic representation of Embodiment 5:
  • a method for preparing a plastic material has the following steps:
  • Step 1 mixing polyvinyl chloride resin, cadmium stearate, quartz sand, cellulose, paraffin, silica, ABS plastic and calcium carbonate to prepare a mixture 1;
  • Step 2 Mixing the mixture with the flame retardant and the toughening agent at a temperature of 200-220 ° C, and cooling to obtain a plastic material.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

A plastic material and preparation method thereof, wherein the plastic material consists of the following ingredients by mass fraction: 20-30 parts of polyvinyl chloride resin, 1-3 parts of a flame retardant, 3-5 parts of cadmium stearate, 4-6 parts of quartz sand, 8-10 parts of cellulose, 3-5 parts of paraffin, 5-7 parts parts of white carbon black, 7-9 parts of an ABS plastic, 5-15 parts of calcium carbonate, and 1-3 parts of a toughener. The plastic material has advantages of good insulation, good flame retardance, good abrasion resistance, high strength and tension resistance, and in particular excellent high frequency insulation.

Description

[根据细则37.2由ISA制定的发明名称] 塑胶材料及其制备方法[Name of invention established by ISA according to Rule 37.2] Plastic material and preparation method thereof 技术领域Technical field

本发明涉及一种清洁用品领域,具体而言涉及一种塑胶材料及其制备方法。The invention relates to the field of cleaning articles, in particular to a plastic material and a preparation method thereof.

背景技术Background technique

塑胶的定义(美国塑料工业协会):主要由碳、氧、氢和氮及其他有机或无机元素所构成,成品为固体,在制造过程中是熔融状的液体,因此可以籍加热使其熔化、加压力使其流动、冷却使其固化,而形成各种形状,此庞大而变化多端的材料族群称为塑胶。The definition of plastic (American Plastics Industry Association): mainly composed of carbon, oxygen, hydrogen and nitrogen and other organic or inorganic elements, the finished product is a solid, which is a molten liquid in the manufacturing process, so it can be melted by heating, The pressure is applied to flow, cool and solidify to form various shapes. This large and varied material group is called plastic.

发明内容Summary of the invention

本发明提供了一种塑胶材料及其制备方法,本发明具有绝缘性能好、阻燃性能好、耐磨性能好、强度高、耐拉的优点,特别是具有优良的高频绝缘性。The invention provides a plastic material and a preparation method thereof. The invention has the advantages of good insulation performance, good flame retardant performance, good wear resistance, high strength and tensile strength, in particular, excellent high frequency insulation.

为实现上述目的,本发明提供如下技术方案:To achieve the above object, the present invention provides the following technical solutions:

一种塑胶材料,由以下质量分数配方成分组成:聚氯乙烯树脂20-30份、阻燃剂1-3份、硬脂酸镉3-5份、石英沙4-6份、纤维素8-10份、石蜡3-5份、白炭黑5-7份、ABS塑胶7-9份、碳酸钙5-15份、增韧剂1-3份。A plastic material consisting of the following mass fraction of ingredients: 20-30 parts of polyvinyl chloride resin, 1-3 parts of flame retardant, 3-5 parts of cadmium stearate, 4-6 parts of quartz sand, cellulose 8- 10 parts, 3-5 parts of paraffin, 5-7 parts of white carbon, 7-9 parts of ABS plastic, 5-15 parts of calcium carbonate, and 1-3 parts of toughening agent.

进一步:由以下质量分数配方成分组成:聚氯乙烯树脂20份、阻燃剂1 份、硬脂酸镉3份、石英沙4份、纤维素8份、石蜡3份、白炭黑5份、ABS塑胶7份、碳酸钙5份、增韧剂1份。Further: consists of the following mass fraction formula ingredients: 20 parts of polyvinyl chloride resin, flame retardant 1 Parts, 3 parts of cadmium stearate, 4 parts of quartz sand, 8 parts of cellulose, 3 parts of paraffin, 5 parts of white carbon, 7 parts of ABS plastic, 5 parts of calcium carbonate, and 1 part of toughening agent.

进一步:由以下质量分数配方成分组成:聚氯乙烯树脂25份、阻燃剂2份、硬脂酸镉4份、石英沙5份、纤维素9份、石蜡4份、白炭黑6份、ABS塑胶8份、碳酸钙10份、增韧剂2份。Further: consisting of the following mass fraction formula ingredients: 25 parts of polyvinyl chloride resin, 2 parts of flame retardant, 4 parts of cadmium stearate, 5 parts of quartz sand, 9 parts of cellulose, 4 parts of paraffin, 6 parts of white carbon black, 8 parts of ABS plastic, 10 parts of calcium carbonate, and 2 parts of toughening agent.

进一步:由以下质量分数配方成分组成:聚氯乙烯树脂30份、阻燃剂3份、硬脂酸镉5份、石英沙6份、纤维素10份、石蜡5份、白炭黑7份、ABS塑胶9份、碳酸钙15份、增韧剂3份。Further: consisting of the following mass fraction formula ingredients: 30 parts of polyvinyl chloride resin, 3 parts of flame retardant, 5 parts of cadmium stearate, 6 parts of quartz sand, 10 parts of cellulose, 5 parts of paraffin, 7 parts of white carbon black, 9 parts of ABS plastic, 15 parts of calcium carbonate, and 3 parts of toughening agent.

进一步:一种塑胶材料的制备方法具有以下几个步骤:Further: a method for preparing a plastic material has the following steps:

步骤一:将聚氯乙烯树脂、硬脂酸镉、石英沙、纤维素、石蜡、白炭黑、ABS塑胶和碳酸钙混合制得混合物一;Step 1: mixing polyvinyl chloride resin, cadmium stearate, quartz sand, cellulose, paraffin, silica, ABS plastic and calcium carbonate to prepare a mixture 1;

步骤二:将混合物一与阻燃剂和增韧剂在温度为200-220℃情况下进行混合,冷却后既得一种塑胶材料。Step 2: Mixing the mixture with the flame retardant and the toughening agent at a temperature of 200-220 ° C, and cooling to obtain a plastic material.

本发明的有益效果是:本发明具有绝缘性能好、阻燃性能好、耐磨性能好、强度高、耐拉的优点,特别是具有优良的高频绝缘性。The invention has the advantages that the invention has the advantages of good insulation performance, good flame retardant performance, good wear resistance, high strength and tensile strength, and particularly excellent high-frequency insulation.

具体实施方式detailed description

下面将结合本发明实施例,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部 的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。The technical solutions in the embodiments of the present invention are clearly and completely described in the following with reference to the embodiments of the present invention. It is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all An embodiment. All other embodiments obtained by those skilled in the art based on the embodiments of the present invention without creative efforts are within the scope of the present invention.

实施例一:Embodiment 1:

一种塑胶材料由以下质量分数配方成分组成:聚氯乙烯树脂20-30份、阻燃剂1-3份、硬脂酸镉3-5份、石英沙4-6份、纤维素8-10份、石蜡3-5份、白炭黑5-7份、ABS塑胶7-9份、碳酸钙5-15份、增韧剂1-3份。A plastic material is composed of the following mass fraction formula components: 20-30 parts of polyvinyl chloride resin, 1-3 parts of flame retardant, 3-5 parts of cadmium stearate, 4-6 parts of quartz sand, cellulose 8-10 Parts, 3-5 parts of paraffin, 5-7 parts of white carbon, 7-9 parts of ABS plastic, 5-15 parts of calcium carbonate, 1-3 parts of toughening agent.

实施例二:Embodiment 2:

一种塑胶材料由以下质量分数配方成分组成:聚氯乙烯树脂20份、阻燃剂1份、硬脂酸镉3份、石英沙4份、纤维素8份、石蜡3份、白炭黑5份、ABS塑胶7份、碳酸钙5份、增韧剂1份。A plastic material consists of the following mass fraction formula: 20 parts of polyvinyl chloride resin, 1 part of flame retardant, 3 parts of cadmium stearate, 4 parts of quartz sand, 8 parts of cellulose, 3 parts of paraffin, white carbon black 5 Parts, 7 parts of ABS plastic, 5 parts of calcium carbonate, 1 part of toughening agent.

实施例三:Embodiment 3:

一种塑胶材料由以下质量分数配方成分组成:聚氯乙烯树脂25份、阻燃剂2份、硬脂酸镉4份、石英沙5份、纤维素9份、石蜡4份、白炭黑6份、ABS塑胶8份、碳酸钙10份、增韧剂2份。A plastic material consists of the following mass fraction formula: 25 parts of polyvinyl chloride resin, 2 parts of flame retardant, 4 parts of cadmium stearate, 5 parts of quartz sand, 9 parts of cellulose, 4 parts of paraffin, white carbon black 6 8 parts of ABS plastic, 10 parts of calcium carbonate, and 2 parts of toughening agent.

实施例四:Embodiment 4:

一种塑胶材料由以下质量分数配方成分组成:聚氯乙烯树脂30份、阻燃剂3份、硬脂酸镉5份、石英沙6份、纤维素10份、石蜡5份、白炭黑7份、ABS塑胶9份、碳酸钙15份、增韧剂3份。 A plastic material consists of the following mass fraction formula: 30 parts of polyvinyl chloride resin, 3 parts of flame retardant, 5 parts of cadmium stearate, 6 parts of quartz sand, 10 parts of cellulose, 5 parts of paraffin, white carbon black 7 Parts, 9 parts of ABS plastic, 15 parts of calcium carbonate, and 3 parts of toughening agent.

实施例五:Embodiment 5:

一种塑胶材料的制备方法具有以下几个步骤:A method for preparing a plastic material has the following steps:

步骤一:将聚氯乙烯树脂、硬脂酸镉、石英沙、纤维素、石蜡、白炭黑、ABS塑胶和碳酸钙混合制得混合物一;Step 1: mixing polyvinyl chloride resin, cadmium stearate, quartz sand, cellulose, paraffin, silica, ABS plastic and calcium carbonate to prepare a mixture 1;

步骤二:将混合物一与阻燃剂和增韧剂在温度为200-220℃情况下进行混合,冷却后既得一种塑胶材料。Step 2: Mixing the mixture with the flame retardant and the toughening agent at a temperature of 200-220 ° C, and cooling to obtain a plastic material.

此外,应当理解,虽然本说明书按照实施方式加以描述,但并非每个实施方式仅包含一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可以理解的其他实施方式。 In addition, it should be understood that although the description is described in terms of embodiments, not every embodiment includes only one independent technical solution. The description of the specification is merely for the sake of clarity, and those skilled in the art should regard the specification as a whole. The technical solutions in the respective embodiments may also be combined as appropriate to form other embodiments that can be understood by those skilled in the art.

Claims (5)

一种塑胶材料,其特征在于:由以下质量分数配方成分组成:A plastic material characterized by: consisting of the following mass fraction formula ingredients: 聚氯乙烯树脂20-30份、阻燃剂1-3份、硬脂酸镉3-5份、石英沙4-6份、纤维素8-10份、石蜡3-5份、白炭黑5-7份、ABS塑胶7-9份、碳酸钙5-15份、增韧剂1-3份。20-30 parts of polyvinyl chloride resin, 1-3 parts of flame retardant, 3-5 parts of cadmium stearate, 4-6 parts of quartz sand, 8-10 parts of cellulose, 3-5 parts of paraffin, white carbon black 5 -7 parts, 7-9 parts of ABS plastic, 5-15 parts of calcium carbonate, and 1-3 parts of toughening agent. 根据权利要求1所述的一种塑胶材料,其特征在于:由以下质量分数配方成分组成:A plastic material according to claim 1, which is composed of the following mass fraction formula components: 聚氯乙烯树脂20份、阻燃剂1份、硬脂酸镉3份、石英沙4份、纤维素8份、石蜡3份、白炭黑5份、ABS塑胶7份、碳酸钙5份、增韧剂1份。20 parts of polyvinyl chloride resin, 1 part of flame retardant, 3 parts of cadmium stearate, 4 parts of quartz sand, 8 parts of cellulose, 3 parts of paraffin, 5 parts of white carbon, 7 parts of ABS plastic, 5 parts of calcium carbonate, 1 part of toughening agent. 根据权利要求1所述的一种塑胶材料,其特征在于:由以下质量分数配方成分组成:A plastic material according to claim 1, which is composed of the following mass fraction formula components: 聚氯乙烯树脂25份、阻燃剂2份、硬脂酸镉4份、石英沙5份、纤维素9份、石蜡4份、白炭黑6份、ABS塑胶8份、碳酸钙10份、增韧剂2份。25 parts of polyvinyl chloride resin, 2 parts of flame retardant, 4 parts of cadmium stearate, 5 parts of quartz sand, 9 parts of cellulose, 4 parts of paraffin, 6 parts of white carbon black, 8 parts of ABS plastic, 10 parts of calcium carbonate, 2 parts of toughening agent. 根据权利要求1所述的一种塑胶材料,其特征在于:由以下质量分数配方成分组成:A plastic material according to claim 1, which is composed of the following mass fraction formula components: 聚氯乙烯树脂30份、阻燃剂3份、硬脂酸镉5份、石英沙6份、纤维素10份、石蜡5份、白炭黑7份、ABS塑胶9份、碳酸钙15份、增韧剂3份。30 parts of polyvinyl chloride resin, 3 parts of flame retardant, 5 parts of cadmium stearate, 6 parts of quartz sand, 10 parts of cellulose, 5 parts of paraffin, 7 parts of white carbon black, 9 parts of ABS plastic, 15 parts of calcium carbonate, 3 parts of toughening agent. 一种根据权利要求1所述的一种塑胶材料的制备方法,其特征在于:具有以下几个步骤: A method for preparing a plastic material according to claim 1, characterized by the following steps: 步骤一:将聚氯乙烯树脂、硬脂酸镉、石英沙、纤维素、石蜡、白炭黑、ABS塑胶和碳酸钙混合制得混合物一;Step 1: mixing polyvinyl chloride resin, cadmium stearate, quartz sand, cellulose, paraffin, silica, ABS plastic and calcium carbonate to prepare a mixture 1; 步骤二:将混合物一与阻燃剂和增韧剂在温度为200-220℃情况下进行混合,冷却后既得一种塑胶材料。 Step 2: Mixing the mixture with the flame retardant and the toughening agent at a temperature of 200-220 ° C, and cooling to obtain a plastic material.
PCT/CN2016/100702 2016-09-29 2016-09-29 Plastic material and preparation method thereof Ceased WO2018058394A1 (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4764539A (en) * 1987-11-24 1988-08-16 Norton Company Flame resistant polymers
CN102131863A (en) * 2008-08-13 2011-07-20 路博润高级材料公司 Filled poly vinyl chloride composition
WO2011130780A1 (en) * 2010-04-23 2011-10-27 Peter Walker Edwards Cellulose fibre-polymer composite material
CN103059466A (en) * 2012-12-25 2013-04-24 东莞市祺龙电业有限公司 A kind of anti-ultraviolet environment-friendly PVC modified material and preparation method thereof
CN104059314A (en) * 2014-06-26 2014-09-24 青岛博洋生物技术有限公司 Environmental protection material for home decoration
CN104086920A (en) * 2014-07-18 2014-10-08 东北林业大学 Flame-retardant smoke-suppression type PVC-based wood-plastic composite material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4764539A (en) * 1987-11-24 1988-08-16 Norton Company Flame resistant polymers
CN102131863A (en) * 2008-08-13 2011-07-20 路博润高级材料公司 Filled poly vinyl chloride composition
WO2011130780A1 (en) * 2010-04-23 2011-10-27 Peter Walker Edwards Cellulose fibre-polymer composite material
CN103059466A (en) * 2012-12-25 2013-04-24 东莞市祺龙电业有限公司 A kind of anti-ultraviolet environment-friendly PVC modified material and preparation method thereof
CN104059314A (en) * 2014-06-26 2014-09-24 青岛博洋生物技术有限公司 Environmental protection material for home decoration
CN104086920A (en) * 2014-07-18 2014-10-08 东北林业大学 Flame-retardant smoke-suppression type PVC-based wood-plastic composite material and preparation method thereof

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