WO2017072127A1 - Tissu biélastique et son procédé de fabrication - Google Patents
Tissu biélastique et son procédé de fabrication Download PDFInfo
- Publication number
- WO2017072127A1 WO2017072127A1 PCT/EP2016/075700 EP2016075700W WO2017072127A1 WO 2017072127 A1 WO2017072127 A1 WO 2017072127A1 EP 2016075700 W EP2016075700 W EP 2016075700W WO 2017072127 A1 WO2017072127 A1 WO 2017072127A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- yarn
- fabric
- elasticity
- biopolyamide
- minutes
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
- D04B1/14—Other fabrics or articles characterised primarily by the use of particular thread materials
- D04B1/18—Other fabrics or articles characterised primarily by the use of particular thread materials elastic threads
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/82—Textiles which contain different kinds of fibres
- D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/06—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyethers
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/08—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamino acids or polypeptides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/12—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyureas
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/06—Load-responsive characteristics
- D10B2401/061—Load-responsive characteristics elastic
Definitions
- the present invention relates to a bielastic fabric comprising biopolyamide yarn and elastane yarn, having excellent elastic properties and high dimensional stability, as well as to a cost-effective, efficient process for obtaining it.
- the present invention relates to a process for obtaining such a bielastic fabric.
- the present invention relates to a clothing or furniture item, at least partially made of such a bielastic fabric.
- FIG. 1 shows the pattern of jersey fabric (weave of stocking stitch) seen from the knit side on the left and from the purl side on the right;
- FIG. 3 shows the pattern of interlock fabric in which the front overlap of the front and back stitches is shown: the latter are represented by thinner lines solely to help understanding the figure itself, actually being all of the same length and width;
- Figure 4 shows the pattern of the same interlock fabric in Figure 1 in which the overlap of the front and back stitches is shown in perspective;
- the invention thus relates to a bielastic fabric comprising biopolyamide yarn and elastane yarn.
- the term “bielastic” means that the fabric is elastic in the warp and weft directions.
- biopolyamide means a polyamide entirely or partly of plant origin.
- the biomass from which the biopolyamide for the purposes of the present invention originates is the castor seed, referred to as Ricinus communis".
- the monomers used in the polymerization process are partly or totally derived from castor oil.
- Biopolyamides exhibit high resistance to chemical agents, in particular to hydrocarbons, dimensional stability, relatively low density and good processability.
- said biopolyamide is biopolyamide 6, biopolyamide 6.6, biopolyamide 6.10, biopolyamide 6.12, biopolyamide 11, biopolyamide 12, or a mixture thereof.
- said biopolyamide is biopolyamide 6.6.
- the biopolyamide yarn has a count of 10-200 dTex, preferably 20-150 dTex.
- elastane it is meant a synthetic fiber of polyurethane, also known as Spandex or Lycra.
- polyurethane is typically produced from raw materials.
- the reaction takes place in two steps, in the first step a polyol is placed to react with a diisocyanate to form an intermediate referred to as prepolymer, which will later be co-linked with amines or glycols.
- the polyol is characterized in that it has hydroxyl functional groups (-OH) at both ends and will form the elastic part of the molecule; it may be a polyester or a polyether or a mixture thereof.
- the diisocyanate instead, has isocyanate functional groups (-NCO) at its ends and will be the rigid part of the polyurethane.
- the isocyanate most used is diphenylmethane diisocyanate ("MDI", l-isocyanate-4-[(4- phenylisocyanate)methyl]benzene).
- the reaction takes place between -NCO and -OH groups to form the urea bond and since the molar ratio of isocyanate to polyol is 2: 1, the final product will be a macrodiisocyanate, that is, the prepolymer will be a macromolecule having -NCO groups at the ends.
- the chain extension is obtained by adding bifunctional amines (H2NR-NH2) to the prepolymer, which by reacting with the -NCO groups form a urethane bond.
- the exothermic reaction increases the molecular weight by hundreds of times and the viscosity therewith; in order to keep the product manageable, the reaction is conducted in a suitable solvent and small amounts of monofunctional amines regulate the final length thereof.
- the most common solvents are dimethylformamide (DMF) and dimethylacetamide (DM Ac).
- a suitable elastane yarn for the purposes of the present invention is the yarn described in the international patent application WO0181443.
- said elastane yarn is the reaction product between (A) poly(tetramethylene-ether-co-2methyltetramethylene-ether)glycol, (B) a mixture of 1- isocyanate-4-[(4'- isocyanatephenyl)methyl]benzene (abbreviated "4,4'-MDI") and 23- 55 mol% of l-isocyanate-2-[(4'-isocyanatephenyl)methyl]benzene (abbreviated "2,4'- MDI”) over the total diisocyanate, and (C) at least one chain extender.
- A poly(tetramethylene-ether-co-2methyltetramethylene-ether)glycol
- B a mixture of 1- isocyanate-4-[(4'- isocyanatephenyl)methyl]benzene
- 2,4'- MDI 23- 55 mol% of l-isocyanate-2-[(4'-isocyanatephenyl)methyl]benzene
- said elastane yarn is the reaction product between (A) poly(tetramethylene-ether-co-2methyltetramethylene-ether)glycol, (B) a mixture of 1- isocyanate-4-[(4'- isocyanatephenyl)methyl]benzene and 28-55 mol% of 1-isocyanate- 2-[(4'-isocyanatephenyl)methyl]benzene over the total diisocyanate, and (C) at least one chain extender.
- the chain extender is ethylenediamine, 1,4-butanediamine, 1,6- hexanediamine, 1,2-propanediamine, 1,3-propanediamine, 2-methyl-l,5-pentane- diamine, 1,4-cyclohexanediamine, 1,3-cyclohexanediamine, 1,3-diaminopentane, or a mixture thereof.
- the chain extender is ethylenediamine.
- the elastane yarn is preferably obtained by dry spinning.
- the bielastic fabric comprises at least 60% of biopolyamide yarn, more preferably at least 70% of biopolyamide yarn.
- the bielastic fabric comprises at least 5% of elastane yarn, more preferably at least 15% of elastane yarn.
- the elastane yarn has a count of 10-200 dTex, preferably 15-100 dTex.
- commercially available elastane yarns may be used, such as the Easy Set LYCRA® yarns marketed by Invista.
- the bielastic fabric has a basis weight of 50-270 g/sqm (grams/square meter).
- the basis weight is the weight of a fabric per unit area, expressed in grams per square meter, and is an indication of the total amount of fiber in the fabric.
- the basis weight indicated is a nominal basis weight, which corresponds to the actual basis weight +5 g/sqm.
- the measurement of the basis weight is obtained by taking a fabric round having a diameter of 11 cm and weighed with a precision balance.
- the bielastic fabric comprises at least 60% of biopolyamide yarn and at least 5% of elastane yarn.
- the bielastic fabric comprises at least 70% of biopolyamide yarn and at least 15% of elastane yarn.
- the bielastic fabric comprises 75-90% of biopolyamide yarn and 10- 25% of elastane yarn.
- the bielastic fabric has jersey stitch or interlock stitch.
- “Jersey” is a fabric made of stocking stitch; the name refers to most of the products of the knitwear industry. Produced with knitting machines, it is elastic both in length and in width and if made in warp, it has ladder-proof properties. An example of jersey fabric pattern is shown in Figure 1.
- Interlock is a crossed knitted fabric; it is a variant of jersey but easier to cut; it is one of the fundamental weaving of weft knitting, made on double knit machines, i.e. with two series of needles working in opposite positions.
- the cylinder needles are coincident with the dial needles, so they cannot stitch together; so, one yarn is worked by the odd needles of the cylinder needles and the even ones by the dial needles, thus forming a first row of rib stitch.
- the subsequent yarn is worked by the needles, which have not worked the first one: a second rib row is thus obtained, "crossed" with the first one. This results in a thickness and volume similar to those of the rib stitch but with a much more reduced extensibility.
- An example of interlock fabric pattern is shown in Figures 3 and 4.
- the bielastic fabric has a basis weight of 100-250 g/sqm.
- the bielastic fabric has a basis weight of 180-210 g/sqm, more preferably 190-200 g/sqm.
- the bielastic fabric has a basis weight of 100-140 g/sqm, more preferably 110-130 g/sqm.
- the bielastic fabric has a basis weight of 160-200 g/sqm, more preferably 170-190 g/sqm.
- the bielastic fabric has 40-200% of elasticity in the weft.
- the bielastic fabric has 45-90% of elasticity in the weft, more preferably 50- 80%.
- the bielastic fabric has 120-200% of elasticity in the weft, more preferably 140-180%.
- the bielastic fabric has 110-190% of elasticity in the weft, more preferably 130-180%.
- the bielastic fabric has 30-200% of elasticity in the warp.
- the bielastic fabric has 35-80% of elasticity in the warp, more preferably 45- 70%.
- the bielastic fabric has 120-200% of elasticity in the warp, more preferably 140-180%.
- the bielastic fabric has 50-100% of elasticity in the warp, more preferably 60-90%.
- the bielastic fabric has a basis weight of 100-250 g/sqm, 40-200% of elasticity in the weft and 30-200% of elasticity in the warp.
- the elasticity is measured by taking 10x5 cm 2 strips of fabric and placing them in a dynamometer (e.g. dynamometer Zwick/Roell Z0,5).
- a dynamometer e.g. dynamometer Zwick/Roell Z0,5
- elasticity in the weft it is meant the measure of the elasticity taken in the weft direction
- elasticity in the warp means the measure of the elasticity taken in the warp direction.
- the bielastic fabric comprises 75-90% of biopolyamide yarn and 10-25% of elastane yarn, and has jersey stitch, a basis weight of 180-210 g/sqm, 45- 90% of elasticity in the weft and 35-80% of elasticity in the warp.
- the bielastic fabric comprises 80-90% of biopolyamide yarn and 10-20% of elastane yarn, and has jersey stitch, a basis weight of 190-200 g/sqm, 50-80% of elasticity in the weft and 45-70% of elasticity in the warp.
- the bielastic fabric comprises 75-90% of biopolyamide yarn and 10-25% of elastane yarn, and has jersey stitch, a basis weight of 100-140 g/sqm, 120- 200% of elasticity in the weft and 120-200% of elasticity in the warp.
- the bielastic fabric comprises 70-80% of biopolyamide yarn and 20-30% of elastane yarn, and has jersey stitch, a basis weight of 110-130 g/sqm, 140-180% of elasticity in the weft and 140-180% of elasticity in the warp.
- the bielastic fabric comprises 75-90% of biopolyamide yarn and 10-25% of elastane yarn, and has interlock stitch, a basis weight of 160-200 g/sqm, 110-190% of elasticity in the weft and 50-100% of elasticity in the warp.
- the bielastic fabric comprises 70-80% of biopolyamide yarn and 20-30% of elastane yarn, and has interlock stitch, a basis weight of 170-190 g/sqm, 130-180% of elasticity in the weft and 60-90% of elasticity in the warp.
- the bielastic fabric may further comprise at least one yarn of natural fiber selected from wool, cotton, silk, and flax.
- the bielastic fabric may further comprise at least one yarn of synthetic fiber selected from polyester, polyamide, acetate, acrylic, rayon, and polyolefin, such as polyethylene or polypropylene.
- the bielastic fabric consists essentially of biopolyamide yarn and elastane yarn.
- the expression "essentially consists of indicates that the fabric may further comprise other types of yarns which, however, do not alter the technical features of the final bielastic fabric.
- the bielastic fabric consists of biopolyamide yarn and elastane yarn.
- the present invention relates to a manufacturing process of the bielastic fabric as described above, said process comprising the steps of:
- a fabric is obtained according to procedures known in the field.
- the fabric is obtained by circular knitting with stitching of the two yarns. More preferably, the fabric has jersey stitch or interlock stitch.
- the knitting looms are selected on the basis of the gauge of the stitches they produce; preferably, gauge E (expressed as "number of needles per English inch”) ranges from E20 to E50.
- the jersey fabric is obtained with a single knit machine, while the interlock fabric is obtained with a double knit machine.
- step b) of the process the step of heat- setting of the fabric obtained in step a) is performed.
- Heat- setting is a thermal treatment for setting the fibers, imparting dimensional stability to the fabric and constancy of mass per unit area of the finished fabric.
- the thermal treatment may be carried out with various heat sources:
- the typical temperatures at which heat-setting is carried out are 190-195°C.
- the biopolyamides allow the heat- setting temperature to bet lowered down to about 165°C.
- the typical temperatures at which heat-setting is carried out are 190-195°C.
- the heat-setting step b) is carried out over a time period of 30-70 seconds, more preferably 40-45 seconds.
- the heat-setting step b) is carried out at a temperature of 100-160°C, more preferably of 120- 160°C.
- the process also comprises a step c) of dyeing the heat-set fabric.
- Said step may be carried out according to techniques known in the field, however, dyeing is preferably carried out in overflow machines at atmospheric pressure.
- the fabric moves at variable speeds within the bath which consists of water, auxiliary products and dyes.
- the maximum temperature achievable is lower than 100°C.
- the dyeing step c) comprises the following substeps:
- dyeing with dye dosage for 15-30 minutes at 90-110°C with permanence for 20- 40 minutes, preferably for 24 minutes at 98°C with permanence for 30 minutes, iv) stripping at 30-50°C for 5-20 minutes, preferably at 40°C for 10 minutes, v) treating with a fixer at 50-90°C for 10-30 minutes, preferably at 70°C for 20 minutes, and
- the dyed fabric is discharged from the machines and opened, using a specific machinery.
- the fabric is dried.
- drying is carried out in a tentering machine at a speed of about 20 meters per minute at a temperature of 90°C.
- the present invention relates to a bielastic fabric obtainable by the process described above, said bielastic fabric comprising biopolyamide yarn and elastane yarn.
- the present invention also relates to a clothing item or a furniture item, at least partially made of the bielastic fabric of the invention.
- clothing item it is meant any article of clothing for men, women or children, such as shirt, pant, skirt, jacket, dress, shirt, blouse, sweater, as well as accessories such as handbags, briefcases, wallets, purses, key cases, cases for phones and tablets.
- clothing items suitable as sea garments such as swimwear, underwear and sportswear.
- “Furniture item” is meant to include any home linen article, such as bedspreads, curtains, tablecloths and linen for pillows, benches, armchairs, sofas, chairs, beds and ottomans.
- the Jersey fabric thus obtained was subjected to heat-setting in a tentering machine at a temperature of 160°C over a time period of 40-45 seconds.
- the dyed fabric is discharged from the machines and opened, using a specific machinery.
- the fabric is dried in a tentering machine at a speed of about 20 meters per minute at a temperature of 90°C.
- the bielastic fabric thus obtained is shown in Figure 2 and has a basis weight of 195 g/sqm, 60% elasticity in the weft and 50% elasticity in the warp.
- the measurement of the basis weight was obtained by taking a fabric round having a diameter of 11 cm and weighing with a precision balance. Instead, the elasticity was measured by taking 12 cm long fabric strips and placing them in a dynamometer Zwick/Roell Z0,5.
- the Jersey fabric thus obtained was subjected to heat-setting in a tentering machine at a temperature of 160°C over a time period of 40-45 seconds.
- the dyed fabric is discharged from the machines and opened, using a specific machinery.
- the fabric is dried in a tentering machine at a speed of about 20 meters per minute at a temperature of 90°C.
- the bielastic fabric thus obtained has a basis weight of 115 g/sqm, 160% elasticity in the weft and 160% elasticity in the warp.
- the measurement of the basis weight was obtained by taking a fabric round having a diameter of 11 cm and weighing with a precision balance. Instead, the elasticity was measured by taking 12 cm long fabric strips and placing them in a dynamometer Zwick/Roell Z0,5.
- the Interlock fabric thus obtained was subjected to heat-setting in a tentering machine at a temperature of 160°C over a time period of 40-45 seconds.
- the dyed fabric is discharged from the machines and opened, using a specific machinery.
- the fabric is dried in a tentering machine at a speed of about 20 meters per minute at a temperature of 90°C.
- the bielastic fabric thus obtained is shown in Figure 5 and has a basis weight of 175 g/sqm, 150% elasticity in the weft and 70% elasticity in the warp.
- the measurement of the basis weight was obtained by taking a fabric round having a diameter of 11 cm and weighing with a precision balance. Instead, the elasticity was measured by taking 12 cm long fabric strips and placing them in a dynamometer Zwick/Roell Z0,5.
- the Jersey fabric thus obtained was subjected to heat-setting in a tentering machine at a temperature of 150°C over a time period of 50-55 seconds.
- the dyed fabric is discharged from the machines and opened, using a specific machinery.
- the fabric is dried in a tentering machine at a speed of about 20 meters per minute at a temperature of 90°C.
- the bielastic fabric thus obtained has a basis weight of 195 g/sqm, 60% elasticity in the weft and 50% elasticity in the warp.
- the measurement of the basis weight was obtained by taking a fabric round having a diameter of 11 cm and weighing with a precision balance. Instead, the elasticity was measured by taking 12 cm long fabric strips and placing them in a dynamometer Zwick/Roell Z0,5.
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Knitting Of Fabric (AREA)
- Woven Fabrics (AREA)
- Artificial Filaments (AREA)
Abstract
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| RU2018113719A RU2741020C2 (ru) | 2015-10-28 | 2016-10-25 | Биэластичное полотно и способ его получения |
| CN201680063201.3A CN108368652B (zh) | 2015-10-28 | 2016-10-25 | 双弹性织物及其制造工艺 |
| CA3002488A CA3002488A1 (fr) | 2015-10-28 | 2016-10-25 | Tissu bielastique et son procede de fabrication |
| US15/769,988 US20180313008A1 (en) | 2015-10-28 | 2016-10-25 | Bielastic fabric and its manufacturing process |
| KR1020187014748A KR102639632B1 (ko) | 2015-10-28 | 2016-10-25 | 이중탄성(bielastic) 직물 및 이의 제조방법 |
| US18/090,752 US20230151515A1 (en) | 2015-10-28 | 2022-12-29 | Bielastic fabric and its manufacturing process |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15191811.7 | 2015-10-28 | ||
| EP15191811.7A EP3162937B1 (fr) | 2015-10-28 | 2015-10-28 | Tissu biélastique et son procédé de fabrication |
Related Child Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US15/769,988 A-371-Of-International US20180313008A1 (en) | 2015-10-28 | 2016-10-25 | Bielastic fabric and its manufacturing process |
| US18/090,752 Division US20230151515A1 (en) | 2015-10-28 | 2022-12-29 | Bielastic fabric and its manufacturing process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2017072127A1 true WO2017072127A1 (fr) | 2017-05-04 |
Family
ID=55023840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/EP2016/075700 Ceased WO2017072127A1 (fr) | 2015-10-28 | 2016-10-25 | Tissu biélastique et son procédé de fabrication |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20180313008A1 (fr) |
| EP (1) | EP3162937B1 (fr) |
| KR (1) | KR102639632B1 (fr) |
| CN (1) | CN108368652B (fr) |
| CA (1) | CA3002488A1 (fr) |
| ES (1) | ES2692813T3 (fr) |
| PT (1) | PT3162937T (fr) |
| RU (1) | RU2741020C2 (fr) |
| TR (1) | TR201815564T4 (fr) |
| WO (1) | WO2017072127A1 (fr) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060021387A1 (en) * | 2004-06-01 | 2006-02-02 | Invista North America S. A R.L. | Method to make circular knit elastic fabric comprising spandex and hard yarns |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3412547A (en) * | 1966-06-27 | 1968-11-26 | Du Pont | Elastic composite yarn and preparation thereof |
| GB9225302D0 (en) * | 1992-12-03 | 1993-01-27 | Cv Apparel Ltd | Knitting |
| TW589421B (en) | 2000-04-26 | 2004-06-01 | Du Pont | Spandex with high heat-set efficiency |
| GB0214866D0 (en) * | 2002-06-27 | 2002-08-07 | Courtaulds Textiles Holdings | Elasticated fabric |
| KR101165244B1 (ko) * | 2002-12-12 | 2012-07-17 | 닛신보 홀딩스 가부시키 가이샤 | 폴리우레탄 탄성섬유 혼용 직편물 및 그 제조방법 |
| US6776014B1 (en) * | 2003-06-02 | 2004-08-17 | Invista North America S.A.R.L. | Method to make circular-knit elastic fabric comprising spandex and hard yarns |
| CN101084332B (zh) * | 2004-12-21 | 2013-10-30 | 因维斯塔技术有限公司 | 圆型针织弹力织物及其制作方法 |
| BRPI0914021B1 (pt) * | 2008-10-13 | 2019-06-18 | Invista Technologies S.À.R.L. | Artigo e método para preparar um tecido |
| JP5454191B2 (ja) * | 2010-02-09 | 2014-03-26 | 東レ株式会社 | 捲縮糸および繊維構造体 |
| US8845934B2 (en) * | 2011-09-12 | 2014-09-30 | Sabic Global Technologies B.V. | Compatibilized biopolyamide-poly(arylene ether) thermoplastic resin |
| CN103014903B (zh) * | 2012-12-26 | 2014-12-31 | 北京服装学院 | 一种生物基聚酰胺纤维的制备方法 |
| CN103147152B (zh) * | 2013-02-26 | 2015-01-21 | 上海凯赛生物技术研发中心有限公司 | 一种尼龙纤维 |
| JP6063569B2 (ja) * | 2013-07-12 | 2017-01-18 | 旭化成株式会社 | 弾性丸編地 |
| CN203451743U (zh) * | 2013-07-31 | 2014-02-26 | 吴江市巨诚喷织有限公司 | 一种锦纶纤维面料 |
| US12018133B1 (en) * | 2021-05-07 | 2024-06-25 | K Joy Nunn | System and method of elastane removal for repurposing textiles |
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2015
- 2015-10-28 TR TR2018/15564T patent/TR201815564T4/tr unknown
- 2015-10-28 EP EP15191811.7A patent/EP3162937B1/fr active Active
- 2015-10-28 PT PT15191811T patent/PT3162937T/pt unknown
- 2015-10-28 ES ES15191811.7T patent/ES2692813T3/es active Active
-
2016
- 2016-10-25 CA CA3002488A patent/CA3002488A1/fr active Pending
- 2016-10-25 US US15/769,988 patent/US20180313008A1/en not_active Abandoned
- 2016-10-25 RU RU2018113719A patent/RU2741020C2/ru active
- 2016-10-25 KR KR1020187014748A patent/KR102639632B1/ko active Active
- 2016-10-25 CN CN201680063201.3A patent/CN108368652B/zh active Active
- 2016-10-25 WO PCT/EP2016/075700 patent/WO2017072127A1/fr not_active Ceased
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2022
- 2022-12-29 US US18/090,752 patent/US20230151515A1/en active Pending
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Also Published As
| Publication number | Publication date |
|---|---|
| KR102639632B1 (ko) | 2024-02-23 |
| TR201815564T4 (tr) | 2018-11-21 |
| CA3002488A1 (fr) | 2017-05-04 |
| RU2741020C2 (ru) | 2021-01-25 |
| CN108368652A (zh) | 2018-08-03 |
| EP3162937A1 (fr) | 2017-05-03 |
| ES2692813T3 (es) | 2018-12-05 |
| US20180313008A1 (en) | 2018-11-01 |
| KR20180083867A (ko) | 2018-07-23 |
| US20230151515A1 (en) | 2023-05-18 |
| EP3162937B1 (fr) | 2018-10-10 |
| PT3162937T (pt) | 2018-11-06 |
| RU2018113719A (ru) | 2019-11-28 |
| RU2018113719A3 (fr) | 2020-02-03 |
| CN108368652B (zh) | 2021-03-30 |
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