[go: up one dir, main page]

WO2017064352A1 - Pressure vessel - Google Patents

Pressure vessel Download PDF

Info

Publication number
WO2017064352A1
WO2017064352A1 PCT/FI2015/050679 FI2015050679W WO2017064352A1 WO 2017064352 A1 WO2017064352 A1 WO 2017064352A1 FI 2015050679 W FI2015050679 W FI 2015050679W WO 2017064352 A1 WO2017064352 A1 WO 2017064352A1
Authority
WO
WIPO (PCT)
Prior art keywords
pressure vessel
gas
vessel
lower half
upper half
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/FI2015/050679
Other languages
French (fr)
Inventor
Mikael BJÖRKLUND
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wartsila Finland Oy
Original Assignee
Wartsila Finland Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wartsila Finland Oy filed Critical Wartsila Finland Oy
Priority to PCT/FI2015/050679 priority Critical patent/WO2017064352A1/en
Publication of WO2017064352A1 publication Critical patent/WO2017064352A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10Working-up natural gas or synthetic natural gas
    • C10L3/101Removal of contaminants
    • C10L3/102Removal of contaminants of acid contaminants
    • C10L3/103Sulfur containing contaminants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D1/00Evaporating
    • B01D1/0011Heating features
    • B01D1/0058Use of waste energy from other processes or sources, e.g. combustion gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D5/00Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0057Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes
    • B01D5/006Condensation of vapours; Recovering volatile solvents by condensation in combination with other processes with evaporation or distillation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/04Pressure vessels, e.g. autoclaves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/0005Catalytic processes under superatmospheric pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08Production of synthetic natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02CGAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
    • F02C3/00Gas-turbine plants characterised by the use of combustion products as the working fluid
    • F02C3/20Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products
    • F02C3/22Gas-turbine plants characterised by the use of combustion products as the working fluid using a special fuel, oxidant, or dilution fluid to generate the combustion products the fuel or oxidant being gaseous at standard temperature and pressure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • F02M21/0203Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels characterised by the type of gaseous fuel
    • F02M21/0215Mixtures of gaseous fuels; Natural gas; Biogas; Mine gas; Landfill gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02MSUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • F02M21/0218Details on the gaseous fuel supply system, e.g. tanks, valves, pipes, pumps, rails, injectors or mixers
    • F02M21/0227Means to treat or clean gaseous fuels or fuel systems, e.g. removal of tar, cracking, reforming or enriching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • F17C2221/033Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • F17C2221/035Propane butane, e.g. LPG, GPL
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/04Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by other properties of handled fluid before transfer
    • F17C2223/042Localisation of the removal point
    • F17C2223/043Localisation of the removal point in the gas
    • F17C2223/045Localisation of the removal point in the gas with a dip tube
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/04Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by other properties of handled fluid after transfer
    • F17C2225/042Localisation of the filling point
    • F17C2225/043Localisation of the filling point in the gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2225/00Handled fluid after transfer, i.e. state of fluid after transfer from the vessel
    • F17C2225/04Handled fluid after transfer, i.e. state of fluid after transfer from the vessel characterised by other properties of handled fluid after transfer
    • F17C2225/042Localisation of the filling point
    • F17C2225/043Localisation of the filling point in the gas
    • F17C2225/045Localisation of the filling point in the gas with a dip tube
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2265/00Effects achieved by gas storage or gas handling
    • F17C2265/06Fluid distribution
    • F17C2265/066Fluid distribution for feeding engines for propulsion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/01Applications for fluid transport or storage
    • F17C2270/0102Applications for fluid transport or storage on or in the water
    • F17C2270/0105Ships
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/10Internal combustion engine [ICE] based vehicles
    • Y02T10/30Use of alternative fuels, e.g. biofuels

Definitions

  • the present invention relates to a pressure vessel in accordance with claim 1 . More particularly, the invention relates to a pressure vessel that can be used for processing gas that contains hydrocarbons for use as a fuel in an internal combustion engine.
  • the oil When crude oil is pumped from the ground, the oil is usually accompanied with gas.
  • the gas comprises methane, but often also significant amounts of other components, such as heavier hydrocarbons, water and hydrogen. Because of the varying composition of the associated gas that is separated from crude oil, the associated gas is conventionally flared. Flaring of the associated gas in offshore oil drilling facilities is a major environmental problem causing signifi- cant C0 2 emissions. In addition, valuable resources are wasted when the gas is not utilized as an energy source.
  • a solution to the problem of the varying composition and low quality of the associated gas is to use gas reformers, where heavier hydrocarbons of the gas are converted to synthesis gas (H 2 + CO) and finally to methane (CH 4 ).
  • the associated gas can thus be utilized in the oil production facilities for reliably, flexibly and efficiently producing electricity with dual fuel or gas engines. Dual fuel engines are often preferred due to their flexibility.
  • gas reformers also recovered volatile organic compounds (VOCs) that are generated when the crude oil is heated to improve its viscosity and stranded gas can be utilized in the oil production facilities for producing electricity.
  • VOCs volatile organic compounds
  • gas reformers With the gas reformers, the self-sufficiency of the oil production facilities can be improved and the need for fuel bunkering, which is costly in offshore locations, can be reduced. Gas reformers are also beneficial in onshore applications, for instance in remote locations lacking gas pipelines and electricity grid. However, in many applications the limited space complicates the use of gas reformers. Also the maintenance of the gas reformers can be problematic. Summary of the invention
  • the object of the present invention is to provide an improved pressure vessel for processing gas that contains hydrocarbons for use as a fuel in an internal combustion engine.
  • the characterizing features of the pressure vessel accord- ing to the invention are given in claim 1 .
  • a pressure vessel comprises a gas inlet that is located in an upper portion of the pressure vessel when the pressure vessel is in the intended operating position, and a gas outlet that is located in a lower portion of the pressure vessel when the pressure vessel is in the intended operat- ing position.
  • the pressure vessel comprises a lower half and an upper half, the upper half being removably attached to the lower half.
  • the gas inlet is arranged in the upper half of the pressure vessel, the gas outlet is arranged in the lower half of the pressure vessel, and the pressure vessel comprises a partition wall that is arranged between the lower half and the upper half. Because of the construction, the pressure vessel can replace two separate pressure vessels, which reduces the footprint of a pressure vessel arrangement where two vessels are needed. Also the amount of material needed for the equipment can be reduced and piping around the pressure vessel shortened.
  • the invention is advantageous especially in the case of pressure ves- sels that are filled with a catalyst material, since the construction allows easier filling of the pressure vessel.
  • the partition wall comprises a first wall element that is attached to the lower half of the pressure vessel and a second wall element that is attached to the upper half of the pressure vessel.
  • the partition wall comprises a plurality of openings for establishing fluid communication between the upper half and the lower half of the pressure vessel.
  • the two halves of the pressure vessel can thus be connected without external piping.
  • the upper end of the lower half of the pressure vessel is provided with a first flange and the lower end of the upper half of the pressure vessel is provided with a second flange that is configured to be attached to the first flange.
  • the flanges function as means for attaching the two halves of the pressure vessel to each other.
  • an upper portion of the upper half is provided with a first gas inlet
  • an upper portion of the lower half is provided with a second gas inlet
  • a lower portion of the upper half is provided with a first gas outlet
  • a lower portion of the lower half is provided with a second gas outlet.
  • This kind of pressure vessel can be used when a connection through the partition wall is not suitable.
  • a lower portion of the lower half of the pressure vessel is provided with a partition element that is horizontal in the intended operating position of the pressure vessel and separates a lower end portion from the rest of the pressure vessel, the partition element comprising a plurality of openings for establishing fluid communication between the lower end portion and the rest of the pressure vessel and the gas outlet opening to the lower end portion.
  • the partition element allows filling of the pressure vessel for instance with a catalyst material without a risk that the material blocks the outlet.
  • an upper portion of the upper half of the pressure vessel is provided with a partition element that is horizontal in the intended operating position of the pressure vessel and separates an upper end portion from the rest of the pressure vessel, the partition element comprising a plurality of openings for establishing fluid communication between the upper end portion and the rest of the pressure vessel and the gas inlet opening to the upper end portion.
  • the partition element allows filling of the pressure vessel for instance with a catalyst material without a risk that the material blocks the inlet.
  • one of the upper half and the lower half of the pressure vessel is configured to work as a reformer and the other is configured to work as a methanator.
  • each of the upper half and the lower half of the pressure vessel is configured to work as a desulphurization vessel.
  • Fig. 1 shows a pressure vessel according to an embodiment of the invention
  • Fig. 2 shows a cross-sectional view of the pressure vessel of figure 1 taken along line A-A
  • Fig. 3 shows a cross-sectional view of the pressure vessel of figure 1 taken along line B-B in figure 2,
  • Fig. 4 shows a pressure vessel according to another embodiment of the inven- tion
  • Fig. 5 shows a cross-sectional view of the pressure vessel of figure 4 taken along line A-A
  • Fig. 6 shows a cross-sectional view of the pressure vessel of figure 4 taken along line B-B in figure 5
  • Fig. 7 shows a cross-sectional view of a detail of the pressure vessel of figure 1
  • Fig. 8 shows a cross-sectional view of a detail of the pressure vessel of figure 4,
  • Fig. 9 shows a power generating system where the pressure vessel of figure 4 can be used.
  • Fig. 10 shows a power generating system where the pressure vessel of figure 1 can be used.
  • FIGS 9 and 10 show two examples of the use of gas reformers.
  • FIG 9 is shown schematically a power generating system that comprises an internal combustion engine 100 that is arranged to drive a generator 101 coupled to the engine 100.
  • the engine 100 is configured to be operable using gaseous fuel that has been processed in a gas reformer.
  • the engine 100 is a piston engine comprising a plurality of cylinders.
  • the engine 100 is a dual fuel engine that can be operated using either liquid fuel or a combination of gaseous fuel and liquid fuel. When gaseous fuel is used as a main fuel, the liquid fuel is used as a pilot fuel for igniting the gaseous fuel.
  • the liquid fuel is supplied to the engine 100 via a liquid fuel feed pipe 1 13.
  • Gas is supplied to the power generating system via a fuel supply line 1 14.
  • the gas contains hydrocarbons. At least part of the gas is heavier hydrocarbons than methane, for instance ethane or propane.
  • the gas can also comprise other components, such as nitrogen, water, carbon dioxide and sulfur compounds.
  • the gas can be, for instance, associated gas from oil drilling, stranded gas or volatile organic compounds (VOCs) recovered from oil/gas production process.
  • VOCs volatile organic compounds
  • the compressibility of a fuel gas can be expressed as a methane number.
  • a higher methane number means better compressibility.
  • the methane number of pure methane is 100. If the methane number of the fuel is low, the compres- sion ratio of the engine needs to be lower to prevent knocking, i.e. premature ignition of the fuel.
  • the heavier hydrocarbons have a low methane number. For instance, the methane number of ethane is 43 and the methane number of n- butane is only 10. Usually a methane number of at least 80 is needed for efficient operation of an engine.
  • the methane number is increased by converting the non-methane hydrocarbons to synthesis gas (H 2 + CO) and finally to methane (CH 4 ) in a reformer 104.
  • the hydrocarbons react with steam in the presence of a catalyst.
  • the temperature in the reformer 104 is 300 ⁇ 120 °C and pressure 7- 10 barg.
  • the design pressure of the reformer 104 is 1 1 barg.
  • the reformer 104 is thus configured to withstand a pressure difference of at least 1 1 bar.
  • the reformer 104 is filled with a material comprising a Ni-based catalyst. Also some other catalysts could be used in the process instead of or in addition to the Ni-based catalyst.
  • the Ni-based catalyst is sensitive to sulfur compounds, and therefore the sulfur compounds need to be re- moved from the gas before the gas is processed in the reformer 104.
  • the power generating system is provided with a first desulfurization vessel 102 and a second desulfurization vessel 103.
  • the desulfurization vessels 102, 103 are filled with a desulfurization absorbent, which absorbs sulfur compounds from the gas.
  • the absorbent is ZnO and the chemical reaction taking place in the desulfurization vessels 102, 103 is ZnO + H 2 S -> ZnS + H 2 O.
  • the reaction takes place mainly in the first desulfurization vessel 102 and the second desulfurization vessel 103 acts as guard.
  • the gas is fed into the reformer 104. Temperature in the desulfurization vessels 102, 103 is 250-350 °C.
  • the desulfurization vessels 102, 103 are configured to withstand a pressure difference of at least 1 1 bar.
  • the power generating system is provided with a first heat exchanger 106 and a second heat exchanger 107.
  • the first heat exchanger 106 receives processed gas from the reformer 104.
  • the second heat exchanger 107 receives processed gas from the first heat exchanger 106.
  • the second heat exchanger 107 also receives unprocessed gas upstream from the first desulfurization vessel 102.
  • the first heat exchanger 106 receives desulfurized gas from the second desulfurization vessel 103.
  • the heat exchangers 106, 107 are thus configured to lower the temperature of the processed gas.
  • the second heat exchanger 107 is configured to increase the temperature of the unprocessed gas and the first heat exchanger 106 is configured to increase the temperature of the desulfurized gas.
  • the desulfurized gas is introduced into an electric heater 105, where the temperature of the gas is further increased before the gas is supplied into the reformer 104.
  • the electric heater 105 some other means could naturally be used for increasing the temperature of the gas before the reformer 104.
  • the processed gas is introduced into a condenser/separator 108.
  • water is removed from the processed gas.
  • the temperature of the processed gas is further lowered.
  • the condenser/separator 108 receives cooling water from a cooling water inlet duct 1 1 1 of the engine 100.
  • the condensed water is supplied into a fresh water line 1 15.
  • the amount of fresh water needed in the processing of the gas can be decreased by recirculating the water.
  • the cooling water from the condenser/separator 108 is returned to a cooling water outlet duct 1 12 of the engine 100.
  • the processed gas is introduced from the condenser/separator 108 into a gas valve unit 109, which controls the gas flow to the engine 100.
  • the temperature of the gas in the gas valve unit 109 is approximately 50 °C.
  • FIG. 10 shows a power generating system for a hydrocarbon mixture having low methane content.
  • the system comprises an engine 100 that is arranged to drive a generator 101 .
  • the system of figure 9 is suitable for gases having a methane number of at least 40 and a total amount of non-methane hydrocarbons below 80 mol-%.
  • the system of figure 10 is suitable even for gases con- taining no methane at all and having a methane number around 20.
  • gases can be, for instance, natural gas liquids or liquefied VOCs recovered from tankers and carriers during venting and uploading of cargo.
  • the system of figure 10 is similar to the system of figure 9. The main difference is that the heavier hydrocarbons are converted to methane in two separate phases.
  • the sys- tem comprises a reformer 104, which operates at higher temperature and converts the heavier hydrocarbons to synthesis gas.
  • the system further comprises a methanator 1 17, which operates at lower temperatures and converts the synthesis gas to methane-rich gas.
  • a fuel supply line 1 14 supplies the hydrocarbon mixture, which may be at least partly liquid, to an evaporator 1 18.
  • the fuel is evaporated and supplied to an electric heater 105, where the temperature of the gas is increased.
  • the gas is then introduced into a desulfurization vessel 102, where sulfur compounds are removed from the gas. Only one desulfurization vessel 102 is shown, but the system could also comprise two or more desulfurization vessels arranged in series.
  • the desulfurization vessel 102 works in the same manner as in the system of figure 9. From the desulfurization vessel 102 the gas is supplied into the reformer 104, where the non-methane hydrocarbons are converted to synthesis gas. Temperature in the reformer 104 is 360 ⁇ 150 °C.
  • a heat exchanger 106 is arranged between the desulfurization vessel 102 and the reformer 104. In the heat exchanger 106, heat is transferred from the synthesis gas to the desulfurized gas.
  • the synthesis gas is fed from the heat exchanger 106 into the methanator 1 17, where the synthesis gas is converted to methane-rich gas. Temperature in the methanator 1 17 is 300-350 °C.
  • the gas from the methanator 1 17 is supplied to the evaporator 1 18, where the heat of the gas is used for evaporating the unprocessed fuel and the temperature of the processed gas is decreased.
  • the gas is further fed to a condenser 108, which removes water from the gas.
  • the condenser 108 receives cooling water from a cooling water inlet duct of the engine 100 and returns it into a cooling water outlet duct of the engine 100.
  • the gas is supplied from the condenser 108 to a gas valve unit 109 and further to the engine 100.
  • the steam needed in the reformer 104 is produced in a boiler 1 19.
  • the boiler 1 19 is a multi-fuel boiler, which uses the fuel to be processed as an energy source together with a surplus gas that is fed into the boiler via a gas supply line 120.
  • the boiler 1 19 may be additionally connected to a back-up fuel source.
  • an exhaust gas boiler can be used for generating the steam.
  • the steam is supplied from the boiler 1 19 into the gas stream between the desulfurization vessel 102 and the heat exchanger 106.
  • FIG 1 a pressure vessel 1 according to an embodiment of the invention.
  • Figure 2 shows a cross-sectional view of the pressure vessel 1 taken along line A-A of figure 1 .
  • Figure 3 shows a cross-sectional view of the pressure vessel 1 taken along line B-B of figure 2.
  • the pressure vessel 1 of figure 1 can be used as a reformer-methanator unit in the power generating system of figure 10.
  • the pressure vessel 1 comprises a lower half 1 a and an upper half 1 b.
  • the expressions "lower” and "upper” refer to the intended operation position of the pressure vessel 1 .
  • the upper half 1 b is arranged on top of the lower half 1 a.
  • the pressure vessel 1 is configured to be used in a vertical position, in which the longitudinal axis 2 of the pressure vessel 1 is vertical.
  • the volume of the upper half 1 b is the same as the volume of the lower half 1 a of the pressure vessel 1 .
  • the height of the upper half 1 b could differ from the height of the lower half 1 a.
  • the upper half 1 b of the pressure vessel 1 can thus have a different volume than the lower half 1 a.
  • the diameters of the upper half 1 a and the lower half 1 b needs to be equal at least in those ends of the two halves 1 a, 1 b that are arranged against each other.
  • the lower half 1 a of the pressure vessel 1 is provided with a first flange 3, which is arranged at the upper end of the lower half 1 a.
  • the upper half 1 b of the pressure vessel 1 is provided with a second flange 4, which is arranged at the lower end of the upper half 1 b.
  • Each of the flanges 3, 4 is provided with holes 5, 6, which can receive bolts 8 for attaching the upper half 1 b to the lower half 1 a.
  • the upper half 1 b of the pressure vessel 1 is thus removably attached to the lower half 1 a of the pressure vessel 1 .
  • the pressure vessel 1 comprises a partition wall 7, which is arranged between the lower half 1 a and the upper half 1 b.
  • the partition wall 7 is horizontal when the pressure vessel 1 is in the operating position and divides the pressure vessel 1 into a lower compartment and an upper compartment.
  • the partition wall 7 comprises a first wall element 7a and a second wall element 7b.
  • the first wall element 7a is attached to the lower half 1 a of the pressure vessel 1 and the second wall element 7b is attached to the upper half 1 b of the pressure vessel 1 .
  • the attachment of the wall elements 7a, 7b can be seen in more detail in figure 7.
  • the wall elements 7a, 7b are provided with holes 10, 1 1 for allowing attachment of the wall elements 7a, 7b to the pressure vessel 1 .
  • the flanges 3, 4 of the lower half 1 a and the upper half 1 b of the pressure vessel 1 are provided with holes 12, 13, and the wall elements 7a, 7b can be attached to the flanges 3, 4 by means of bolts 14, 15.
  • the first wall element 7a closes the upper end of the lower half 1 a of the pressure vessel 1 and the second wall element 7b closes the lower end of the upper half 1 b of the pressure vessel 1 .
  • the compartment formed inside the upper half 1 b of the pressure vessel 1 is used as a reformer 104.
  • the compartment formed inside the lower half 1 a of the pressure vessel 1 is used as a methanator 1 17.
  • the pressure vessel 1 thus forms an integrated reformer-methanator unit.
  • the gas to be processed is fed into the reformer 104 via a first gas inlet 20.
  • the side wall of the upper half 1 b of the pressure vessel 1 is provided with a first inlet opening 18, through which a first inlet pipe 16 is inserted.
  • the first inlet opening 18 is arranged in an upper portion of the upper half 1 b of the pressure vessel 1 , i.e. close to the upper end of the upper half 1 b.
  • the first inlet pipe 16 protrudes into the pressure vessel 1 .
  • the first gas inlet 20 is arranged at the end of the first inlet pipe 16.
  • a first outlet opening 24 is arranged in the side wall of a lower portion of the upper half 1 b of the pressure vessel 1 .
  • a first outlet pipe 22 is inserted through the first outlet opening 24 and protrudes into the pressure vessel 1 .
  • a first gas outlet 26 is arranged at the end of the first outlet pipe 22. Through the first gas inlet 20 the gas to be processed can be fed into the reformer part 104 of the pressure vessel 1 . Through the first outlet 26, the synthesis gas can flow out of the reformer 104.
  • the side wall of the lower half 1 a of the pressure vessel 1 is provided with a second inlet opening 19, through which a second inlet pipe 17 is inserted.
  • the second inlet opening 19 is arranged in an upper portion of the lower half 1 a of the pressure vessel 1 , i.e. close to the upper end of the lower half 1 a.
  • the second inlet pipe 17 protrudes into the pressure vessel 1 .
  • a second gas inlet 21 is arranged at the end of the second inlet pipe 17.
  • a second outlet opening 25 is arranged in the side wall of a lower portion of the lower half 1 a of the pressure vessel 1 .
  • a second outlet pipe 23 is inserted through the second outlet opening 25 and protrudes into the pressure vessel 1 .
  • a second gas outlet 27 is arranged at the end of the first outlet pipe 25.
  • An upper portion of the upper half 1 b of the pressure vessel 1 is provided with a partition element 29, which separates an upper end portion 30 from the rest of the pressure vessel 1 .
  • the partition element 29 is provided with openings for establishing fluid communication between the upper end portion 30 and the rest of the upper half 1 b of the pressure vessel 1 .
  • the partition element 29 is a net.
  • a lower portion of the upper half 1 b of the pressure vessel 1 is provided with a similar partition element 31 , which separates a lower end portion 32 from the rest of the pressure vessel 1 .
  • the upper half 1 b of the pressure vessel 1 between the nets 29, 31 is filled with the catalyst material.
  • the end portions 30, 32 are filled with alumina balls.
  • the nets 29, 31 hold the alumina balls in the end portions 30, 32.
  • the first gas inlet 20 opens to the upper end portion 30 and the first gas outlet 26 opens to the lower end portion 32.
  • the construction of the lower half 1 a of the pressure vessel 1 is similar.
  • An up- per portion of the lower half 1 a is provided with a partition element 35, which separates an upper end portion 36 from the rest of the lower half 1 a of the pressure vessel 1 .
  • a lower portion of the lower half 1 a is provided with a partition element 33, which separates a lower end portion 34 from the rest of the lower half 1 a of the pressure vessel 1 .
  • the lower half 1 a of the pressure vessel 1 is filled with the catalyst material between the partition elements 33, 35 and the end portions 34, 36 are filled with alumina balls.
  • the second gas inlet 21 opens to the upper end portion 36 and the second gas outlet 27 opens to the lower end portion 34 of the lower half 1 a of the pressure vessel 1 .
  • the footprint of the reformer 104 and the methanator 1 17 can be reduced. Since the reformer 104 and the methanator 1 17 work at the substantially same pressure, the partition wall 7 does not need to withstand a great pressure difference. Consequently, it can be a relatively light part, and material is saved compared to two separate pressure vessels, where both ends of the pressure vessels have to carry significant forces.
  • Be- cause the partition wall 7 comprises separate wall elements 7a, 7b for the upper half 1 b and the lower half 1 a of the pressure vessel 1 , the pressure vessel 1 is easy to divide into two parts and the parts can be transported for instance from an offshore location to service facilities, where the catalyst material is exchanged.
  • the pressure vessel 1 is also easy to fill through the open ends of the upper half 1 b and the lower half 1 a.
  • Figure 4 shows a pressure vessel 1 according to another embodiment of the invention.
  • Figure 5 shows a cross-sectional view of the pressure vessel 1 taken along line A-A of figure 4.
  • Figure 6 shows a cross-sectional view of the pressure vessel 1 taken along line B-B of figure 5.
  • the pressure vessel 1 of figure 4 can be used as a desulfurization unit in the power generating system of figure 9.
  • Both the first desulfurization vessel 102 and the second desulfurization vessel 103 can be integrated in the pressure vessel 1 of figure 4.
  • the construction of the pressure vessel of figures 4 to 6 is similar to the construction of the pressure vessel of figures 1 to 3.
  • the pres- sure vessel 1 of figures 4 to 6 is provided with only one gas inlet and one gas outlet and that the compartments 102, 103 inside the upper half 1 b and the lower half 1 a of the pressure vessel 1 are in fluid communication with each other through the partition wall 7.
  • the pressure vessel 1 of figures 4 to 6 is configured to withstand a pressure difference of at least 1 1 bar.
  • the tempera- ture inside the pressure vessel 1 is 200 ⁇ 100 °C.
  • the pressure vessel 1 comprises an inlet opening 18 that is arranged in an upper portion of the upper half 1 b of the pressure vessel 1 .
  • An inlet pipe 16 is inserted through the inlet opening 18 and protrudes into the pressure vessel 1 .
  • a gas inlet 20 is arranged at the end of the inlet pipe 16.
  • the pressure vessel 1 further comprises an outlet opening 25 that is arranged in a lower portion of the lower half 1 a of the pressure vessel 1 .
  • An outlet pipe 23 is inserted through the outlet opening 25 and protrudes into the pressure vessel 1 .
  • a gas outlet 27 is arranged at the end of the outlet pipe 23.
  • the partition wall 7 is provided with open- ings 28, which can be best seen in figure 8.
  • the openings 28 establish fluid communication between the upper half 1 b and the lower half 1 a of the pressure vessel 1 .
  • the gas can thus flow from the first desulfurization vessel 102 into the second desulfurization vessel 103 inside the pressure vessel 1 , which reduces the external piping needed for the desulfurization arrangement.
  • the pressure inside the upper half 1 b and the lower half 1 a of the pressure vessel 1 is substantially the same, and the partition wall 7 does therefore not need to carry significant forces.
  • the partition wall 7 comprises a first wall element 7a covering the upper end of the lower half 1 a of the pressure vessel 1 and a second wall element 7b covering the lower end of the upper half 1 b of the pressure vessel 1 .
  • the first wall element 7a is attached to the lower half 1 a of the pressure vessel 1 and the second wall element 7b is attached to the upper half 1 b of the pressure vessel 1 .
  • the wall elements 7a, 7b can be attached to the flanges 3, 4 of the lower half 1 a and the upper half 1 b of the pressure vessel 1 in a similar way as in the embodi- ment of figures 1 to 3.
  • An upper portion of the upper half 1 b of the pressure vessel 1 is provided with a partition element 29, which separates an upper end portion 30 from the rest of the pressure vessel 1 .
  • the partition element 29 is provided with openings for establishing fluid communication between the upper end portion 30 and the rest of the upper half 1 b of the pressure vessel 1 .
  • the partition element 29 is a net.
  • the upper end portion 30 is filled with alumina balls.
  • the gas inlet 20 opens to the upper end portion 30.
  • the rest of the upper half 1 b of the pressure vessel is filled with an absorbent that removes sulfur compounds from the gas that is introduced into the pressure vessel 1 .
  • the construction of the lower half 1 a of the pressure vessel 1 is similar.
  • a lower portion of the lower half 1 a is provided with a partition element 33, which separates a lower end portion 34 from the rest of the lower half 1 a of the pressure vessel 1 .
  • the lower end portion 34 is filled with alumina balls.
  • the rest of the lower half 1 a of the pressure vessel 1 is filled with the absorbent.
  • the gas outlet 27 opens to the lower end portion 34.
  • the pressure vessel 1 of figures 4 to 6 provides the same benefits as the pressure vessel 1 of figures 1 to 3.
  • the footprint of the pressure vessel 1 is smaller than the footprint of two separate pressure vessels, the pressure vessel 1 is easy to fill and it can be transported in two parts for servicing and exchange of the absorbent material.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

The pressure vessel (1) for processing gas that con- tains hydrocarbons for use as a fuel in an internal combustion engine (100) comprises a gas inlet (20) that is located in an upper portion of the pressure ves- sel (1) when the pressure vessel (1) is in the intended operating position, a gas outlet (27) that is located in a lower portion of the pressure vessel (1), a lower half (1a) and an upper half (1b), the upper half (1b) being removably attached to the lower half (1a), the gas inlet (20) being arranged in the upper half (1b) of the pres- sure vessel (1), and the gas outlet (27) being arranged in the lower half (1a) of the pressure vessel (1). The pressure vessel (1) further comprises a partition wall (7) that is arranged between the lower half (1a) and the upper half (1b).

Description

Pressure vessel
Technical field of the invention
The present invention relates to a pressure vessel in accordance with claim 1 . More particularly, the invention relates to a pressure vessel that can be used for processing gas that contains hydrocarbons for use as a fuel in an internal combustion engine.
Background of the invention
When crude oil is pumped from the ground, the oil is usually accompanied with gas. The gas comprises methane, but often also significant amounts of other components, such as heavier hydrocarbons, water and hydrogen. Because of the varying composition of the associated gas that is separated from crude oil, the associated gas is conventionally flared. Flaring of the associated gas in offshore oil drilling facilities is a major environmental problem causing signifi- cant C02 emissions. In addition, valuable resources are wasted when the gas is not utilized as an energy source.
A solution to the problem of the varying composition and low quality of the associated gas is to use gas reformers, where heavier hydrocarbons of the gas are converted to synthesis gas (H2 + CO) and finally to methane (CH4). The associated gas can thus be utilized in the oil production facilities for reliably, flexibly and efficiently producing electricity with dual fuel or gas engines. Dual fuel engines are often preferred due to their flexibility. With the help of gas reformers, also recovered volatile organic compounds (VOCs) that are generated when the crude oil is heated to improve its viscosity and stranded gas can be utilized in the oil production facilities for producing electricity.
With the gas reformers, the self-sufficiency of the oil production facilities can be improved and the need for fuel bunkering, which is costly in offshore locations, can be reduced. Gas reformers are also beneficial in onshore applications, for instance in remote locations lacking gas pipelines and electricity grid. However, in many applications the limited space complicates the use of gas reformers. Also the maintenance of the gas reformers can be problematic. Summary of the invention
The object of the present invention is to provide an improved pressure vessel for processing gas that contains hydrocarbons for use as a fuel in an internal combustion engine. The characterizing features of the pressure vessel accord- ing to the invention are given in claim 1 .
A pressure vessel according to the invention comprises a gas inlet that is located in an upper portion of the pressure vessel when the pressure vessel is in the intended operating position, and a gas outlet that is located in a lower portion of the pressure vessel when the pressure vessel is in the intended operat- ing position. The pressure vessel comprises a lower half and an upper half, the upper half being removably attached to the lower half. The gas inlet is arranged in the upper half of the pressure vessel, the gas outlet is arranged in the lower half of the pressure vessel, and the pressure vessel comprises a partition wall that is arranged between the lower half and the upper half. Because of the construction, the pressure vessel can replace two separate pressure vessels, which reduces the footprint of a pressure vessel arrangement where two vessels are needed. Also the amount of material needed for the equipment can be reduced and piping around the pressure vessel shortened. The invention is advantageous especially in the case of pressure ves- sels that are filled with a catalyst material, since the construction allows easier filling of the pressure vessel.
According to an embodiment of the invention, the partition wall comprises a first wall element that is attached to the lower half of the pressure vessel and a second wall element that is attached to the upper half of the pressure vessel. This allows the filling of both halves of the pressure vessel for instance with a catalyst material and transportation of the pressure vessel in two parts without a risk of losing the filling material.
According to an embodiment of the invention, the partition wall comprises a plurality of openings for establishing fluid communication between the upper half and the lower half of the pressure vessel. In certain applications, the two halves of the pressure vessel can thus be connected without external piping.
According to an embodiment of the invention, the upper end of the lower half of the pressure vessel is provided with a first flange and the lower end of the upper half of the pressure vessel is provided with a second flange that is configured to be attached to the first flange. The flanges function as means for attaching the two halves of the pressure vessel to each other.
According to an embodiment of the invention, an upper portion of the upper half is provided with a first gas inlet, an upper portion of the lower half is provided with a second gas inlet, a lower portion of the upper half is provided with a first gas outlet, and a lower portion of the lower half is provided with a second gas outlet. This kind of pressure vessel can be used when a connection through the partition wall is not suitable. According to an embodiment of the invention, a lower portion of the lower half of the pressure vessel is provided with a partition element that is horizontal in the intended operating position of the pressure vessel and separates a lower end portion from the rest of the pressure vessel, the partition element comprising a plurality of openings for establishing fluid communication between the lower end portion and the rest of the pressure vessel and the gas outlet opening to the lower end portion. The partition element allows filling of the pressure vessel for instance with a catalyst material without a risk that the material blocks the outlet.
According to an embodiment of the invention, an upper portion of the upper half of the pressure vessel is provided with a partition element that is horizontal in the intended operating position of the pressure vessel and separates an upper end portion from the rest of the pressure vessel, the partition element comprising a plurality of openings for establishing fluid communication between the upper end portion and the rest of the pressure vessel and the gas inlet opening to the upper end portion. The partition element allows filling of the pressure vessel for instance with a catalyst material without a risk that the material blocks the inlet.
According to an embodiment of the invention, one of the upper half and the lower half of the pressure vessel is configured to work as a reformer and the other is configured to work as a methanator. According to another embodiment of the invention, each of the upper half and the lower half of the pressure vessel is configured to work as a desulphurization vessel. Brief description of the drawings
Embodiments of the invention are described below in more detail with reference to the accompanying drawings, in which
Fig. 1 shows a pressure vessel according to an embodiment of the invention, Fig. 2 shows a cross-sectional view of the pressure vessel of figure 1 taken along line A-A,
Fig. 3 shows a cross-sectional view of the pressure vessel of figure 1 taken along line B-B in figure 2,
Fig. 4 shows a pressure vessel according to another embodiment of the inven- tion,
Fig. 5 shows a cross-sectional view of the pressure vessel of figure 4 taken along line A-A,
Fig. 6 shows a cross-sectional view of the pressure vessel of figure 4 taken along line B-B in figure 5, Fig. 7 shows a cross-sectional view of a detail of the pressure vessel of figure 1 ,
Fig. 8 shows a cross-sectional view of a detail of the pressure vessel of figure 4,
Fig. 9 shows a power generating system where the pressure vessel of figure 4 can be used, and
Fig. 10 shows a power generating system where the pressure vessel of figure 1 can be used.
Description of embodiments of the invention
Figures 9 and 10 show two examples of the use of gas reformers.
In figure 9 is shown schematically a power generating system that comprises an internal combustion engine 100 that is arranged to drive a generator 101 coupled to the engine 100. The engine 100 is configured to be operable using gaseous fuel that has been processed in a gas reformer. The engine 100 is a piston engine comprising a plurality of cylinders. In figure 9, the engine 100 is a dual fuel engine that can be operated using either liquid fuel or a combination of gaseous fuel and liquid fuel. When gaseous fuel is used as a main fuel, the liquid fuel is used as a pilot fuel for igniting the gaseous fuel. The liquid fuel is supplied to the engine 100 via a liquid fuel feed pipe 1 13.
Gas is supplied to the power generating system via a fuel supply line 1 14. The gas contains hydrocarbons. At least part of the gas is heavier hydrocarbons than methane, for instance ethane or propane. The gas can also comprise other components, such as nitrogen, water, carbon dioxide and sulfur compounds. The gas can be, for instance, associated gas from oil drilling, stranded gas or volatile organic compounds (VOCs) recovered from oil/gas production process. Before being used as a fuel in the internal combustion engine 100, the gas is processed to improve its quality and to enhance the efficiency of the engine 100 and the power production.
The compressibility of a fuel gas can be expressed as a methane number. A higher methane number means better compressibility. The methane number of pure methane is 100. If the methane number of the fuel is low, the compres- sion ratio of the engine needs to be lower to prevent knocking, i.e. premature ignition of the fuel. The heavier hydrocarbons have a low methane number. For instance, the methane number of ethane is 43 and the methane number of n- butane is only 10. Usually a methane number of at least 80 is needed for efficient operation of an engine. The methane number is increased by converting the non-methane hydrocarbons to synthesis gas (H2 + CO) and finally to methane (CH4) in a reformer 104.
In the reformer 104, the hydrocarbons react with steam in the presence of a catalyst. The temperature in the reformer 104 is 300^120 °C and pressure 7- 10 barg. The design pressure of the reformer 104 is 1 1 barg. The reformer 104 is thus configured to withstand a pressure difference of at least 1 1 bar. In the embodiment of figure 9, the reformer 104 is filled with a material comprising a Ni-based catalyst. Also some other catalysts could be used in the process instead of or in addition to the Ni-based catalyst. The Ni-based catalyst is sensitive to sulfur compounds, and therefore the sulfur compounds need to be re- moved from the gas before the gas is processed in the reformer 104. The power generating system is provided with a first desulfurization vessel 102 and a second desulfurization vessel 103. The desulfurization vessels 102, 103 are filled with a desulfurization absorbent, which absorbs sulfur compounds from the gas. The absorbent is ZnO and the chemical reaction taking place in the desulfurization vessels 102, 103 is ZnO + H2S -> ZnS + H2O. The reaction takes place mainly in the first desulfurization vessel 102 and the second desulfurization vessel 103 acts as guard. From the second desulfurization vessel 103, the gas is fed into the reformer 104. Temperature in the desulfurization vessels 102, 103 is 250-350 °C. Also the desulfurization vessels 102, 103 are configured to withstand a pressure difference of at least 1 1 bar. The power generating system is provided with a first heat exchanger 106 and a second heat exchanger 107. The first heat exchanger 106 receives processed gas from the reformer 104. The second heat exchanger 107 receives processed gas from the first heat exchanger 106. The second heat exchanger 107 also receives unprocessed gas upstream from the first desulfurization vessel 102. The first heat exchanger 106 receives desulfurized gas from the second desulfurization vessel 103. The heat exchangers 106, 107 are thus configured to lower the temperature of the processed gas. In addition the second heat exchanger 107 is configured to increase the temperature of the unprocessed gas and the first heat exchanger 106 is configured to increase the temperature of the desulfurized gas.
From the first heat exchanger 106 the desulfurized gas is introduced into an electric heater 105, where the temperature of the gas is further increased before the gas is supplied into the reformer 104. Instead of the electric heater 105, some other means could naturally be used for increasing the temperature of the gas before the reformer 104.
From the second heat exchanger 107, the processed gas is introduced into a condenser/separator 108. In the condenser/separator 108, water is removed from the processed gas. Also the temperature of the processed gas is further lowered. The condenser/separator 108 receives cooling water from a cooling water inlet duct 1 1 1 of the engine 100. The condensed water is supplied into a fresh water line 1 15. The amount of fresh water needed in the processing of the gas can be decreased by recirculating the water. The cooling water from the condenser/separator 108 is returned to a cooling water outlet duct 1 12 of the engine 100. The processed gas is introduced from the condenser/separator 108 into a gas valve unit 109, which controls the gas flow to the engine 100. The temperature of the gas in the gas valve unit 109 is approximately 50 °C.
The fresh water that is needed for generating the steam used in the process is introduced into the process via the fresh water line 1 15. The water is heated in an exhaust gas boiler 1 10. The heat for generating the steam is taken from the exhaust gases of the engine 100. The exhaust gases are fed into the exhaust gas boiler 1 10 via an exhaust duct 1 16. The steam is introduced into the gas stream between the second desulfurization vessel 103 and the first heat exchanger 106. Figure 10 shows a power generating system for a hydrocarbon mixture having low methane content. The system comprises an engine 100 that is arranged to drive a generator 101 . The system of figure 9 is suitable for gases having a methane number of at least 40 and a total amount of non-methane hydrocarbons below 80 mol-%. The system of figure 10 is suitable even for gases con- taining no methane at all and having a methane number around 20. Such gases can be, for instance, natural gas liquids or liquefied VOCs recovered from tankers and carriers during venting and uploading of cargo. The system of figure 10 is similar to the system of figure 9. The main difference is that the heavier hydrocarbons are converted to methane in two separate phases. The sys- tem comprises a reformer 104, which operates at higher temperature and converts the heavier hydrocarbons to synthesis gas. The system further comprises a methanator 1 17, which operates at lower temperatures and converts the synthesis gas to methane-rich gas.
A fuel supply line 1 14 supplies the hydrocarbon mixture, which may be at least partly liquid, to an evaporator 1 18. The fuel is evaporated and supplied to an electric heater 105, where the temperature of the gas is increased. The gas is then introduced into a desulfurization vessel 102, where sulfur compounds are removed from the gas. Only one desulfurization vessel 102 is shown, but the system could also comprise two or more desulfurization vessels arranged in series. The desulfurization vessel 102 works in the same manner as in the system of figure 9. From the desulfurization vessel 102 the gas is supplied into the reformer 104, where the non-methane hydrocarbons are converted to synthesis gas. Temperature in the reformer 104 is 360^150 °C. A heat exchanger 106 is arranged between the desulfurization vessel 102 and the reformer 104. In the heat exchanger 106, heat is transferred from the synthesis gas to the desulfurized gas. The synthesis gas is fed from the heat exchanger 106 into the methanator 1 17, where the synthesis gas is converted to methane-rich gas. Temperature in the methanator 1 17 is 300-350 °C. The gas from the methanator 1 17 is supplied to the evaporator 1 18, where the heat of the gas is used for evaporating the unprocessed fuel and the temperature of the processed gas is decreased. The gas is further fed to a condenser 108, which removes water from the gas. The condenser 108 receives cooling water from a cooling water inlet duct of the engine 100 and returns it into a cooling water outlet duct of the engine 100. The gas is supplied from the condenser 108 to a gas valve unit 109 and further to the engine 100.
The steam needed in the reformer 104 is produced in a boiler 1 19. In the embodiment of figure 10, the boiler 1 19 is a multi-fuel boiler, which uses the fuel to be processed as an energy source together with a surplus gas that is fed into the boiler via a gas supply line 120. The boiler 1 19 may be additionally connected to a back-up fuel source. Instead of the multi-fuel boiler, an exhaust gas boiler can be used for generating the steam. The steam is supplied from the boiler 1 19 into the gas stream between the desulfurization vessel 102 and the heat exchanger 106.
In figure 1 is shown a pressure vessel 1 according to an embodiment of the invention. Figure 2 shows a cross-sectional view of the pressure vessel 1 taken along line A-A of figure 1 . Figure 3 shows a cross-sectional view of the pressure vessel 1 taken along line B-B of figure 2. The pressure vessel 1 of figure 1 can be used as a reformer-methanator unit in the power generating system of figure 10. The pressure vessel 1 comprises a lower half 1 a and an upper half 1 b. The expressions "lower" and "upper" refer to the intended operation position of the pressure vessel 1 . Thus, when the pressure vessel 1 is in use, the upper half 1 b is arranged on top of the lower half 1 a. The pressure vessel 1 is configured to be used in a vertical position, in which the longitudinal axis 2 of the pressure vessel 1 is vertical. In the embodiment of figure 1 , the volume of the upper half 1 b is the same as the volume of the lower half 1 a of the pressure vessel 1 . However, the height of the upper half 1 b could differ from the height of the lower half 1 a. The upper half 1 b of the pressure vessel 1 can thus have a different volume than the lower half 1 a. The diameters of the upper half 1 a and the lower half 1 b needs to be equal at least in those ends of the two halves 1 a, 1 b that are arranged against each other.
The lower half 1 a of the pressure vessel 1 is provided with a first flange 3, which is arranged at the upper end of the lower half 1 a. The upper half 1 b of the pressure vessel 1 is provided with a second flange 4, which is arranged at the lower end of the upper half 1 b. Each of the flanges 3, 4 is provided with holes 5, 6, which can receive bolts 8 for attaching the upper half 1 b to the lower half 1 a. The upper half 1 b of the pressure vessel 1 is thus removably attached to the lower half 1 a of the pressure vessel 1 . The pressure vessel 1 comprises a partition wall 7, which is arranged between the lower half 1 a and the upper half 1 b. The partition wall 7 is horizontal when the pressure vessel 1 is in the operating position and divides the pressure vessel 1 into a lower compartment and an upper compartment. The partition wall 7 comprises a first wall element 7a and a second wall element 7b. The first wall element 7a is attached to the lower half 1 a of the pressure vessel 1 and the second wall element 7b is attached to the upper half 1 b of the pressure vessel 1 . The attachment of the wall elements 7a, 7b can be seen in more detail in figure 7. The wall elements 7a, 7b are provided with holes 10, 1 1 for allowing attachment of the wall elements 7a, 7b to the pressure vessel 1 . Also the flanges 3, 4 of the lower half 1 a and the upper half 1 b of the pressure vessel 1 are provided with holes 12, 13, and the wall elements 7a, 7b can be attached to the flanges 3, 4 by means of bolts 14, 15. The first wall element 7a closes the upper end of the lower half 1 a of the pressure vessel 1 and the second wall element 7b closes the lower end of the upper half 1 b of the pressure vessel 1 . The compartment formed inside the upper half 1 b of the pressure vessel 1 is used as a reformer 104. The compartment formed inside the lower half 1 a of the pressure vessel 1 is used as a methanator 1 17. The pressure vessel 1 thus forms an integrated reformer-methanator unit. The gas to be processed is fed into the reformer 104 via a first gas inlet 20. The side wall of the upper half 1 b of the pressure vessel 1 is provided with a first inlet opening 18, through which a first inlet pipe 16 is inserted. The first inlet opening 18 is arranged in an upper portion of the upper half 1 b of the pressure vessel 1 , i.e. close to the upper end of the upper half 1 b. The first inlet pipe 16 protrudes into the pressure vessel 1 . The first gas inlet 20 is arranged at the end of the first inlet pipe 16. A first outlet opening 24 is arranged in the side wall of a lower portion of the upper half 1 b of the pressure vessel 1 . A first outlet pipe 22 is inserted through the first outlet opening 24 and protrudes into the pressure vessel 1 . A first gas outlet 26 is arranged at the end of the first outlet pipe 22. Through the first gas inlet 20 the gas to be processed can be fed into the reformer part 104 of the pressure vessel 1 . Through the first outlet 26, the synthesis gas can flow out of the reformer 104.
The side wall of the lower half 1 a of the pressure vessel 1 is provided with a second inlet opening 19, through which a second inlet pipe 17 is inserted. The second inlet opening 19 is arranged in an upper portion of the lower half 1 a of the pressure vessel 1 , i.e. close to the upper end of the lower half 1 a. The second inlet pipe 17 protrudes into the pressure vessel 1 . A second gas inlet 21 is arranged at the end of the second inlet pipe 17. A second outlet opening 25 is arranged in the side wall of a lower portion of the lower half 1 a of the pressure vessel 1 . A second outlet pipe 23 is inserted through the second outlet opening 25 and protrudes into the pressure vessel 1 . A second gas outlet 27 is arranged at the end of the first outlet pipe 25. Through the second inlet 21 , the synthesis gas can be introduced into the methanator part 1 17 of the pressure vessel and through the second outlet 27 the methane-rich gas can flow out of the methanator 1 17.
An upper portion of the upper half 1 b of the pressure vessel 1 is provided with a partition element 29, which separates an upper end portion 30 from the rest of the pressure vessel 1 . The partition element 29 is provided with openings for establishing fluid communication between the upper end portion 30 and the rest of the upper half 1 b of the pressure vessel 1 . In the embodiment of the figures, the partition element 29 is a net. A lower portion of the upper half 1 b of the pressure vessel 1 is provided with a similar partition element 31 , which separates a lower end portion 32 from the rest of the pressure vessel 1 . The upper half 1 b of the pressure vessel 1 between the nets 29, 31 is filled with the catalyst material. The end portions 30, 32 are filled with alumina balls. The nets 29, 31 hold the alumina balls in the end portions 30, 32. The first gas inlet 20 opens to the upper end portion 30 and the first gas outlet 26 opens to the lower end portion 32.
The construction of the lower half 1 a of the pressure vessel 1 is similar. An up- per portion of the lower half 1 a is provided with a partition element 35, which separates an upper end portion 36 from the rest of the lower half 1 a of the pressure vessel 1 . A lower portion of the lower half 1 a is provided with a partition element 33, which separates a lower end portion 34 from the rest of the lower half 1 a of the pressure vessel 1 . Also the lower half 1 a of the pressure vessel 1 is filled with the catalyst material between the partition elements 33, 35 and the end portions 34, 36 are filled with alumina balls. The second gas inlet 21 opens to the upper end portion 36 and the second gas outlet 27 opens to the lower end portion 34 of the lower half 1 a of the pressure vessel 1 .
With the pressure vessel of figure 1 , the footprint of the reformer 104 and the methanator 1 17 can be reduced. Since the reformer 104 and the methanator 1 17 work at the substantially same pressure, the partition wall 7 does not need to withstand a great pressure difference. Consequently, it can be a relatively light part, and material is saved compared to two separate pressure vessels, where both ends of the pressure vessels have to carry significant forces. Be- cause the partition wall 7 comprises separate wall elements 7a, 7b for the upper half 1 b and the lower half 1 a of the pressure vessel 1 , the pressure vessel 1 is easy to divide into two parts and the parts can be transported for instance from an offshore location to service facilities, where the catalyst material is exchanged. The pressure vessel 1 is also easy to fill through the open ends of the upper half 1 b and the lower half 1 a.
Figure 4 shows a pressure vessel 1 according to another embodiment of the invention. Figure 5 shows a cross-sectional view of the pressure vessel 1 taken along line A-A of figure 4. Figure 6 shows a cross-sectional view of the pressure vessel 1 taken along line B-B of figure 5. The pressure vessel 1 of figure 4 can be used as a desulfurization unit in the power generating system of figure 9. Both the first desulfurization vessel 102 and the second desulfurization vessel 103 can be integrated in the pressure vessel 1 of figure 4. The construction of the pressure vessel of figures 4 to 6 is similar to the construction of the pressure vessel of figures 1 to 3. The main differences are that the pres- sure vessel 1 of figures 4 to 6 is provided with only one gas inlet and one gas outlet and that the compartments 102, 103 inside the upper half 1 b and the lower half 1 a of the pressure vessel 1 are in fluid communication with each other through the partition wall 7. Also the pressure vessel 1 of figures 4 to 6 is configured to withstand a pressure difference of at least 1 1 bar. The tempera- ture inside the pressure vessel 1 is 200^100 °C. In the embodiment of figures 4 to 6, the pressure vessel 1 comprises an inlet opening 18 that is arranged in an upper portion of the upper half 1 b of the pressure vessel 1 . An inlet pipe 16 is inserted through the inlet opening 18 and protrudes into the pressure vessel 1 . A gas inlet 20 is arranged at the end of the inlet pipe 16. The pressure vessel 1 further comprises an outlet opening 25 that is arranged in a lower portion of the lower half 1 a of the pressure vessel 1 . An outlet pipe 23 is inserted through the outlet opening 25 and protrudes into the pressure vessel 1 . A gas outlet 27 is arranged at the end of the outlet pipe 23. Through the gas inlet 20 the gas to be desulfurized is introduced into the upper half 1 b of the pressure vessel 1 , which functions as a first desulfurization vessel 102. Through the gas outlet 27, the processed gas can flow out of the lower half 1 a of the pressure vessel 1 , which functions as a second desulfurization vessel 103.
In the embodiment of figures 4 to 6, the partition wall 7 is provided with open- ings 28, which can be best seen in figure 8. The openings 28 establish fluid communication between the upper half 1 b and the lower half 1 a of the pressure vessel 1 . The gas can thus flow from the first desulfurization vessel 102 into the second desulfurization vessel 103 inside the pressure vessel 1 , which reduces the external piping needed for the desulfurization arrangement. The pressure inside the upper half 1 b and the lower half 1 a of the pressure vessel 1 is substantially the same, and the partition wall 7 does therefore not need to carry significant forces. As in the embodiment of figures 1 to 3, the partition wall 7 comprises a first wall element 7a covering the upper end of the lower half 1 a of the pressure vessel 1 and a second wall element 7b covering the lower end of the upper half 1 b of the pressure vessel 1 . The first wall element 7a is attached to the lower half 1 a of the pressure vessel 1 and the second wall element 7b is attached to the upper half 1 b of the pressure vessel 1 . The wall elements 7a, 7b can be attached to the flanges 3, 4 of the lower half 1 a and the upper half 1 b of the pressure vessel 1 in a similar way as in the embodi- ment of figures 1 to 3.
An upper portion of the upper half 1 b of the pressure vessel 1 is provided with a partition element 29, which separates an upper end portion 30 from the rest of the pressure vessel 1 . The partition element 29 is provided with openings for establishing fluid communication between the upper end portion 30 and the rest of the upper half 1 b of the pressure vessel 1 . In the embodiment of the figures, the partition element 29 is a net. The upper end portion 30 is filled with alumina balls. The gas inlet 20 opens to the upper end portion 30. The rest of the upper half 1 b of the pressure vessel is filled with an absorbent that removes sulfur compounds from the gas that is introduced into the pressure vessel 1 . The construction of the lower half 1 a of the pressure vessel 1 is similar. A lower portion of the lower half 1 a is provided with a partition element 33, which separates a lower end portion 34 from the rest of the lower half 1 a of the pressure vessel 1 . The lower end portion 34 is filled with alumina balls. The rest of the lower half 1 a of the pressure vessel 1 is filled with the absorbent. The gas outlet 27 opens to the lower end portion 34.
The pressure vessel 1 of figures 4 to 6 provides the same benefits as the pressure vessel 1 of figures 1 to 3. The footprint of the pressure vessel 1 is smaller than the footprint of two separate pressure vessels, the pressure vessel 1 is easy to fill and it can be transported in two parts for servicing and exchange of the absorbent material.
It will be appreciated by a person skilled in the art that the invention is not limited to the embodiments described above, but may vary within the scope of the appended claims.

Claims

Claims
1 . A pressure vessel (1 ) for processing gas that contains hydrocarbons for use as a fuel in an internal combustion engine (100), the pressure vessel (1 ) comprising a gas inlet (20) that is located in an upper portion of the pressure vessel (1 ) when the pressure vessel (1 ) is in the intended operating position, and a gas outlet (27) that is located in a lower portion of the pressure vessel (1 ) when the pressure vessel (1 ) is in the intended operating position, wherein the pressure vessel (1 ) comprises a lower half (1 a) and an upper half (1 b), the upper half (1 b) being removably attached to the lower half (1 a), the gas inlet (20) is arranged in the upper half (1 b) of the pressure vessel (1 ), the gas outlet (27) is arranged in the lower half (1 a) of the pressure vessel (1 ), and the pressure vessel (1 ) comprises a partition wall (7) that is arranged between the lower half (1 a) and the upper half (1 b).
2. A pressure vessel (1 ) according to claim 1 , wherein the partition wall (7) comprises a first wall element (7a) that is attached to the lower half (1 a) of the pressure vessel (1 ) and a second wall element (7b) that is attached to the upper half (1 b) of the pressure vessel (1 ).
3. A pressure vessel (1 ) according to claim 1 or 2, wherein the partition wall (7) comprises a plurality of openings (28) for establishing fluid communication between the upper half (1 b) and the lower half (1 a) of the pressure vessel (1 ).
4. A pressure vessel (1 ) according to any of claims 1 to 3, wherein the upper end of the lower half (1 a) of the pressure vessel (1 ) is provided with a first flange (3) and the lower end of the upper half (1 b) of the pressure vessel (1 ) is provided with a second flange (4) that is configured to be attached to the first flange (3).
5. A pressure vessel (1 ) according to any of the preceding claims, wherein an upper portion of the upper half (1 b) is provided with a first gas inlet (20), an upper portion of the lower half (1 a) is provided with a second gas inlet (21 ), a lower portion of the upper half (1 b) is provided with a first gas outlet (26), and a lower portion of the lower half (1 a) is provided with a second gas outlet (27).
6. A pressure vessel (1 ) according to any of the preceding claims, wherein a lower portion of the lower half (1 a) of the pressure vessel (1 ) is provided with a partition element (33) that is horizontal in the intended operating position of the pressure vessel (1 ) and separates a lower end portion (34) from the rest of the pressure vessel (1 ), the partition element (33) comprising a plurality of openings for establishing fluid communication between the lower end portion (34) and the rest of the pressure vessel (1 ) and the gas outlet (27) opening to the lower end portion (34).
7. A pressure vessel (1 ) according to any of the preceding claims, wherein an upper portion of the upper half (1 b) of the pressure vessel (1 ) is provided with a partition element (29) that is horizontal in the intended operating position of the pressure vessel (1 ) and separates an upper end portion (30) from the rest of the pressure vessel (1 ), the partition element (29) comprising a plurality of openings for establishing fluid communication between the upper end portion (30) and the rest of the pressure vessel (1 ) and the gas inlet (20) opening to the upper end portion (30).
8. A pressure vessel (1 ) according to any of the preceding claims, wherein one of the upper half (1 b) and the lower half (1 a) of the pressure vessel (1 ) is configured to work as a reformer (104) and the other is configured to work as a methanator (1 17).
9. A pressure vessel (1 ) according to any of claims 1 to 8, wherein each of the upper half (1 b) and the lower half (1 a) of the pressure vessel (1 ) is config- ured to work as a desulphurization vessel (102, 103).
10. A power generating system comprising an internal combustion engine (100) that can be operated using a gaseous fuel and a first vessel (102, 104) and a second vessel (103, 1 17) for processing the gas to be used in the internal combustion engine (100), wherein the first vessel (102, 104) and the sec- ond vessel (103, 1 17) are integrated into a pressure vessel (1 ) according to any of the preceding claims.
1 1 . A power generating system according to claim 10, wherein the first vessel is a reformer (104) and the second vessel is a methanator (1 17).
12. A power generating system according to claim 10, wherein the first vessel and the second vessel are desulfurization vessels (102, 103).
PCT/FI2015/050679 2015-10-12 2015-10-12 Pressure vessel Ceased WO2017064352A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PCT/FI2015/050679 WO2017064352A1 (en) 2015-10-12 2015-10-12 Pressure vessel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/FI2015/050679 WO2017064352A1 (en) 2015-10-12 2015-10-12 Pressure vessel

Publications (1)

Publication Number Publication Date
WO2017064352A1 true WO2017064352A1 (en) 2017-04-20

Family

ID=54477001

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI2015/050679 Ceased WO2017064352A1 (en) 2015-10-12 2015-10-12 Pressure vessel

Country Status (1)

Country Link
WO (1) WO2017064352A1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100121126A1 (en) * 2007-06-14 2010-05-13 Northrop Paul S Process For Purification of Hydrocarbons
CN101982448A (en) * 2010-10-19 2011-03-02 北京低碳清洁能源研究所 Production of enriched CH4System for gas and production of CH-enriched gas using the same4Method for producing gas
US8173082B1 (en) * 2007-05-14 2012-05-08 Gas Technology Institute JP-8 fuel processor system
WO2014181079A1 (en) * 2013-05-10 2014-11-13 Johnson Matthey Public Limited Company Reactor

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8173082B1 (en) * 2007-05-14 2012-05-08 Gas Technology Institute JP-8 fuel processor system
US20100121126A1 (en) * 2007-06-14 2010-05-13 Northrop Paul S Process For Purification of Hydrocarbons
CN101982448A (en) * 2010-10-19 2011-03-02 北京低碳清洁能源研究所 Production of enriched CH4System for gas and production of CH-enriched gas using the same4Method for producing gas
WO2014181079A1 (en) * 2013-05-10 2014-11-13 Johnson Matthey Public Limited Company Reactor

Similar Documents

Publication Publication Date Title
US11280451B2 (en) Methods for storage and transportation of natural gas in liquid solvents
KR102473954B1 (en) Floating Power Plant and Employment Method therefor
CN113195961A (en) For transporting liquid hydrocarbons and CO2To pass through CO2Process and method for capture production of hydrogen
CN104265512A (en) High-pressure/low-pressure gas supply system of ship power plant
KR20210145031A (en) Fuel supply system for vessel
SG191687A1 (en) A comprehensive system for the storage and transportation of natural gas in a light hydrocarbon liquid medium
KR20180077098A (en) Method of manufacturing a solid liquefied hydrocarbon gas plant
Fernández et al. H2 production by the steam reforming of excess boil off gas on LNG vessels
KR20160058882A (en) Expandable LNG processing plant
WO2000023689A1 (en) Gas disposal system
US20130256093A1 (en) LPG Fractionation Recovery System
KR20180092403A (en) VOC Recovery System and Method
CN102428311A (en) Regasification plant for lng and lpg combined with production of electric energy
KR20180085518A (en) VOC Recovery System and Method
KR101707512B1 (en) Drillship of Dual Fuel Engine Type
WO2017064352A1 (en) Pressure vessel
KR101707513B1 (en) Drillship of Dual Fuel Engine Type
WO2007143776A1 (en) Improvements in the utilisation of methane
KR101839643B1 (en) Supercritical Carbon Dioxide Power Generation System having Steam Supplying Function and Ship having the same
KR102160341B1 (en) Heat exchanger for LNG fuel supply bunkering
US20080011219A1 (en) Enhanced cargo venting system
KR101671477B1 (en) Oil Producing System and Method of Offshore Floating Structure having GTL Producing Module
KR101940263B1 (en) carrier Propelling system
US11952870B2 (en) Method for constructing and exploiting a hydrocarbons production facility, notably on an expanse of water, and associated exploitation facility
KR20250164075A (en) Offshore facilities

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 15791001

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 15791001

Country of ref document: EP

Kind code of ref document: A1