[go: up one dir, main page]

WO2016125784A1 - Laminated separating container for high-viscosity substances - Google Patents

Laminated separating container for high-viscosity substances Download PDF

Info

Publication number
WO2016125784A1
WO2016125784A1 PCT/JP2016/053043 JP2016053043W WO2016125784A1 WO 2016125784 A1 WO2016125784 A1 WO 2016125784A1 JP 2016053043 W JP2016053043 W JP 2016053043W WO 2016125784 A1 WO2016125784 A1 WO 2016125784A1
Authority
WO
WIPO (PCT)
Prior art keywords
container body
container
viscosity
inner bag
discharge port
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2016/053043
Other languages
French (fr)
Japanese (ja)
Inventor
山内 由夫
有吾 奥田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nissho Jitsugyo Co ltd
Kyoraku Co Ltd
Original Assignee
Nissho Jitsugyo Co ltd
Kyoraku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissho Jitsugyo Co ltd, Kyoraku Co Ltd filed Critical Nissho Jitsugyo Co ltd
Publication of WO2016125784A1 publication Critical patent/WO2016125784A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Rigid or semi-rigid containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material or by deep-drawing operations performed on sheet material
    • B65D1/02Bottles or similar containers with necks or like restricted apertures, designed for pouring contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D1/00Rigid or semi-rigid containers having bodies formed in one piece, e.g. by casting metallic material, by moulding plastics, by blowing vitreous material, by throwing ceramic material, by moulding pulped fibrous material or by deep-drawing operations performed on sheet material
    • B65D1/32Containers adapted to be temporarily deformed by external pressure to expel contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D47/00Closures with filling and discharging, or with discharging, devices
    • B65D47/04Closures with discharging devices other than pumps
    • B65D47/20Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D47/00Closures with filling and discharging, or with discharging, devices
    • B65D47/04Closures with discharging devices other than pumps
    • B65D47/20Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge
    • B65D47/24Closures with discharging devices other than pumps comprising hand-operated members for controlling discharge with poppet valves or lift valves, i.e. valves opening or closing a passageway by a relative motion substantially perpendicular to the plane of the seat
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00Containers or packages with special means for dispensing contents

Definitions

  • the present invention relates to a delamination container for high viscosity materials.
  • Patent Document 1 a laminated peeling container that suppresses air from entering the container by peeling and shrinking the inner bag from the outer shell as the contents are reduced.
  • Patent Document 1 is suitable for a liquid having a low viscosity.
  • the present inventors applied the configuration of Patent Document 1 to a high-viscosity product, the high-viscosity product obstructed the valve body 42. It has been found that there may be a problem that the return is hindered and the outside air enters the inner bag.
  • the present invention has been made in view of such circumstances, and even when a high-viscosity material is accommodated, the contents can be properly discharged, and after discharge, the outside air can be properly infiltrated into the inner bag.
  • the present invention provides a delamination container for high-viscosity products that can be suppressed to a low level.
  • the container body is provided with a container main body that contains a high-viscosity product having a viscosity at 20 ° C. of 100 mPa ⁇ s or more, and a cap that is attached to the mouth of the container main body.
  • a container main body that contains a high-viscosity product having a viscosity at 20 ° C. of 100 mPa ⁇ s or more
  • a cap that is attached to the mouth of the container main body.
  • an inner bag and the inner bag peels off from the outer shell and shrinks as the contents are reduced
  • the cap includes a cylindrical portion and a valve portion disposed in the cylindrical portion.
  • the valve portion includes a pedestal portion that protrudes toward the inside of the container body, and a connecting portion that connects the pedestal portion and the tubular portion, and the pedestal portion is provided with a cross slit-shaped discharge port.
  • the connecting portion includes a bent portion that protrudes toward the outside of the container body, and the pedestal portion is pushed by the high-viscosity material when pressure is applied to the container body. By pushing toward the outside of the container body.
  • the discharge port is opened and the pressure on the container body is removed, the state returns to the state of projecting toward the inside of the container body, the discharge port is closed, and the outside air into the inner bag.
  • the viscosity at 20 ° C. is 100 mPa ⁇ s or more. It has been found that even a high-viscosity product can be easily discharged, does not cause dripping after discharge, and can appropriately suppress the intrusion of outside air into the inner bag. Completed. In addition, it has been found that the valve portion configured as described above suppresses the intrusion of outside air when the content is a high-viscosity material, but does not exhibit such a function when the content is a low-viscosity material. .
  • FIG. 2 is a cross-sectional view illustrating a state in which a lid portion 60 is removed from FIG. 1 and a cap 51 is separated from a container body 3.
  • FIG. (A) is an enlarged view of the periphery of the cap 51 of the delamination container 1 with the lid 60 removed from FIG. 1 and turned upside down, and shows a state where no pressure is applied to the container body 3.
  • (B) is the figure which looked at the valve part 53 in (a) from the bottom.
  • FIGS. 4A and 4B correspond to FIGS. 4A and 4B and show a state in which pressure is applied to the container body 3.
  • the laminated release container 1 for a high viscosity material includes a container body 3, a valve member 5, and a cap 51.
  • the container body 3 includes a storage portion 7 that stores the contents, and a mouth portion 9 that discharges the contents from the storage portion 7.
  • the content is a high-viscosity product having a viscosity at 20 ° C. of 100 mPa ⁇ s or more.
  • the high viscosity material include ketchup, mayonnaise, and honey. The viscosity at 20 ° C.
  • the high viscosity product is preferably 500 mPa ⁇ s or more, more preferably 1000 mPa ⁇ s or more, and further preferably 5000 mPa ⁇ s or more.
  • the upper limit of the viscosity at 20 ° C. of the high-viscosity product is not particularly defined, but is, for example, 10,000, 50000, or 100,000 mPa ⁇ s.
  • the container body 3 includes an outer layer 11 and an inner layer 13 in the housing portion 7 and the mouth portion 9, an outer shell 12 is constituted by the outer layer 11, and an inner bag 14 is constituted by the inner layer 13. As the content decreases, the inner layer 13 peels from the outer layer 11, whereby the inner bag 14 peels from the outer shell 12 and contracts.
  • the cap 51 includes a cylindrical portion 52, a lid portion 60, a valve portion 53, and a valve fixing member 54.
  • the lid part 60 is connected to the cylinder part 52 at the hinge part 61, and the lid part 60 can be opened and closed by rotating the lid part 60 relative to the cylinder part 52 around the hinge part 61. Yes.
  • the valve portion 53 has an outer peripheral portion 53 a sandwiched between the valve fixing member 54 and the cylindrical portion 52, and the valve portion 53 is fixed to the cylindrical portion 52 by fixing the valve fixing member 54 to the cylindrical portion 52. Is done.
  • the mouth portion 9 is provided with a male screw portion 9d
  • the cylindrical portion 52 is provided with a female screw portion 52a.
  • the cap 51 can be attached to the container body 3 by screwing the female screw portion 52a and the male screw portion 9d.
  • the accommodating portion 7 is provided with a valve member 5 that adjusts the flow of air between the intermediate space 21 between the outer shell 12 and the inner bag 14 and the outer space S of the container body 3.
  • the outer shell 12 is provided with an outside air introduction hole 15 that communicates the intermediate space 21 and the outer space S in the housing portion 7.
  • the outside air introduction hole 15 is a through hole provided only in the outer shell 12 and does not reach the inner bag 14.
  • the valve member 5 is inserted in the outside air introduction hole 15 and is slidable with respect to the outside air introduction hole 15.
  • the valve member 5 is provided on the intermediate space 21 side of the shaft part 5a and has a larger sectional area than the shaft part 5a.
  • a seal portion 5c and a locking portion 5b provided on the outer space S side of the shaft portion 5a and preventing the valve member 5 from entering the intermediate space 21 are provided.
  • the seal portion 5c is configured to substantially close the outside air introduction hole 15 when the outer shell 12 is compressed, and has a shape in which a cross-sectional area decreases as the shaft portion 5a is approached. Moreover, the latching
  • the seal portion 5 c moves toward the outside air introduction hole 15, and the seal portion 5 c closes the outside air introduction hole 15. Since the cross-sectional area becomes smaller as the seal portion 5c approaches the shaft portion 5a, the seal portion 5c easily fits in the outside air introduction hole 15 and closes the outside air introduction hole 15.
  • the valve member 5 can be mounted on the container body 3 by inserting the seal portion 5c into the intermediate space 21 while the seal portion 5c expands the outside air introduction hole 15. Therefore, it is preferable that the tip of the seal portion 5c has a tapered shape. Since such a valve member 5 can be mounted simply by pushing the seal portion 5c into the intermediate space 21 from the outside of the container body 3, it is excellent in productivity.
  • the external air introduction hole 15 is closed when the pressure in the intermediate space 21 is equal to or higher than the external pressure, and the external air introduction hole is reduced when the pressure in the intermediate space 21 becomes lower than the external pressure.
  • middle space 21 from the outside may be sufficient.
  • the container body 3 includes an outer layer 11 and an inner layer 13.
  • the outer layer 11 is formed to be thicker than the inner layer 13 so that the restoring property is high.
  • the outer layer 11 is composed of, for example, low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, ethylene-propylene copolymer, and a mixture thereof.
  • the inner layer 13 is provided between the EVOH layer 13a provided on the outer surface side of the container, the inner surface layer 13b provided on the inner surface side of the EVOH layer 13a, and between the EVOH layer 13a and the inner surface layer 13b.
  • the adhesive layer 13c is provided.
  • the EVOH layer 13a is a layer made of an ethylene-vinyl alcohol copolymer (EVOH) resin, and is obtained by hydrolysis of ethylene and vinyl acetate copolymer.
  • the inner surface layer 13b is a layer that comes into contact with the contents of the delamination container 1, and is, for example, a polyolefin such as low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, ethylene-propylene copolymer, and a mixture thereof. It is preferably made of low-density polyethylene or linear low-density polyethylene.
  • the adhesive layer 13c is a layer having a function of adhering the EVOH layer 13a and the inner surface layer 13b.
  • an acid-modified polyolefin having a carboxyl group introduced into the above-described polyolefin eg, maleic anhydride-modified polyethylene
  • EVA ethylene vinyl acetate copolymer
  • An example of the adhesive layer 13c is a mixture of low-density polyethylene or linear low-density polyethylene and acid-modified polyethylene.
  • the valve portion 53 includes a pedestal portion 55 that protrudes toward the inside of the container main body 3 and a connecting portion 56 that connects the pedestal portion 55 and the cylindrical portion 52 in a state where the cap 51 is attached to the container main body 3.
  • the pedestal portion 55 includes a flat portion 55a in which the discharge port 57 is provided.
  • the connecting portion 56 includes a bent portion 56 a that protrudes toward the outside of the container body 3.
  • the valve portion 53 is formed of a flexible material such as silicone rubber.
  • the discharge port 57 is formed by slits 58a and 58b (cross slits) formed so as to intersect (preferably orthogonally) the flat portion 55a.
  • slits 58a and 58b cross slits formed so as to intersect (preferably orthogonally) the flat portion 55a.
  • flaps 57a to 57d are formed by the slits 58a and 58b.
  • FIG. 4 shows a state in which no pressure is applied to the container body 3.
  • the flaps 57a to 57d are in close contact with each other, and the contents in the container body 3 do not leak easily.
  • the flat portion 55 a is pushed by the contents in the container body 3, so that the pedestal portion 55 is outside the container body 3 as shown in FIG. 5.
  • the discharge port 57 is opened.
  • the flaps 57a to 57d are separated from each other by being bent toward the outside of the container body 3, and an opening 57e is formed at the center of the flaps 57a to 57d. And the contents in the container main body 3 are discharged through the opening 57e.
  • valve portion 53 When the pressure on the container body 3 is removed, the valve portion 53 returns to a state of projecting toward the inside of the container body 3 as shown in FIG. 4 due to its restoring force, and the flaps 57a to 57d are brought into close contact with each other again. Thus, the discharge port 57 is closed. At this time, since the discharge port 57 is closed while the position of the discharge port 57 moves toward the inside of the container body 3, liquid dripping hardly occurs.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
  • Containers Having Bodies Formed In One Piece (AREA)
  • Closures For Containers (AREA)

Abstract

Provided is a laminated separating container for high-viscosity substances, with which it is possible to discharge the content thereof appropriately, and with which it is possible to appropriately suppress the intrusion of outside air into the inner bag after discharge, even if a high-viscosity substance is stored therein. According to the present invention, this laminated separating container comprises a container body for housing high-viscosity substances having a viscosity of at least 100mPa·s at 20°C, and a cap which is fitted to an opening of the container body, the container body comprising an outer shell and an inner bag, the inner bag separating from the outer shell and contracting in response to the reduction in content. The cap comprises a cylindrical portion and a valve part positioned inside the cylindrical portion, the valve part comprising a base portion which protrudes into the inside of the container body, and a connecting part that connects the base portion and the cylindrical part. The base portion is equipped with a flat part having provided thereto an intersecting slit-shaped discharge port, and the connecting part is equipped with a curved part which protrudes towards the outside of the container body. The base part is constituted in such a manner that when pressure is applied to the container body, the flat part is pressed by the high-viscosity substance so as to be pushed out towards the outside of the container body, and the discharge port is opened, and when the pressure on the container body is removed, the flat part returns to a state of protruding into the interior of the container, and the discharge port is closed, thereby preventing the intrusion of outside air into the interior of the inner bag.

Description

高粘度物用積層剥離容器Laminated peeling container for high viscosity materials

 本発明は、高粘度物用積層剥離容器に関する。 The present invention relates to a delamination container for high viscosity materials.

 従来、内容物の減少に伴って内袋が外殻から剥離し収縮することによって容器の内部に空気が入り込むことを抑制する積層剥離容器が知られている(例えば、特許文献1)。 Conventionally, there has been known a laminated peeling container that suppresses air from entering the container by peeling and shrinking the inner bag from the outer shell as the contents are reduced (for example, Patent Document 1).

 特許文献1の積層剥離容器では、醤油などの粘度が低い液体を収容することが想定されており、特許文献1の図2及び段落42に記載されているように、容器に圧力を加えて圧縮変形させたときに吐出口に設けた弁体部42を容器軸方向に沿って摺動させて連通凹部43を開放させることによって内容物の吐出を可能としている。また、容器への圧力が取り除かれたときに弁体部42を元の位置に復帰させて連通凹部43を閉じることによって、内袋への外気の侵入を抑制している。 In the delamination container of Patent Document 1, it is assumed that a liquid having a low viscosity such as soy sauce is accommodated. As described in FIG. 2 and Paragraph 42 of Patent Document 1, compression is performed by applying pressure to the container. When deformed, the valve body portion 42 provided at the discharge port is slid along the container axial direction to open the communication recess 43, thereby allowing the content to be discharged. In addition, when the pressure on the container is removed, the valve body 42 is returned to the original position and the communication recess 43 is closed, thereby preventing the outside air from entering the inner bag.

特開2013-147295号公報JP 2013-147295 A

 特許文献1の構成は、粘度が低い液体に適したものであり、本発明者らが特許文献1の構成を高粘度物に適用したところ、高粘度物が邪魔をして弁体部42の復帰が阻害されて内袋内に外気が侵入してしまうという問題が生じる場合があることが分かった。 The configuration of Patent Document 1 is suitable for a liquid having a low viscosity. When the present inventors applied the configuration of Patent Document 1 to a high-viscosity product, the high-viscosity product obstructed the valve body 42. It has been found that there may be a problem that the return is hindered and the outside air enters the inner bag.

 本発明はこのような事情に鑑みてなされたものであり、高粘度物を収容した場合でも、内容物を適切に吐出することができ、且つ吐出後は内袋内部への外気の侵入を適切に抑制することができる高粘度物用積層剥離容器を提供するものである。 The present invention has been made in view of such circumstances, and even when a high-viscosity material is accommodated, the contents can be properly discharged, and after discharge, the outside air can be properly infiltrated into the inner bag. The present invention provides a delamination container for high-viscosity products that can be suppressed to a low level.

 本発明によれば、20℃での粘度が100mPa・s以上である高粘度物を収容する容器本体と、前記容器本体の口部に装着されるキャップとを備え、前記容器本体は、外殻と内袋とを備え且つ内容物の減少に伴って前記内袋が前記外殻から剥離し収縮する積層剥離容器であり、前記キャップは、筒部と、前記筒部内に配置された弁部を備え、前記弁部は、前記容器本体内部に向かって突出する台座部と、前記台座部と前記筒部を連結する連結部とを備え、前記台座部は、交差スリット状の吐出口が設けられる平坦部を備え、前記連結部は、前記容器本体の外側に向かって突出する屈曲部を備え、前記台座部は、前記容器本体に圧力が加えられると前記平坦部が前記高粘度物によって押されることによって前記容器本体の外側に向かって押し出されると共に前記吐出口が開かれ、且つ前記容器本体への圧力が除かれると前記容器本体の内部に向かって突出する状態に復帰して前記吐出口が閉じられて前記内袋内部への外気の侵入が抑制されるように構成される、高粘度物用積層剥離容器が提供される。 According to the present invention, the container body is provided with a container main body that contains a high-viscosity product having a viscosity at 20 ° C. of 100 mPa · s or more, and a cap that is attached to the mouth of the container main body. And an inner bag, and the inner bag peels off from the outer shell and shrinks as the contents are reduced, and the cap includes a cylindrical portion and a valve portion disposed in the cylindrical portion. The valve portion includes a pedestal portion that protrudes toward the inside of the container body, and a connecting portion that connects the pedestal portion and the tubular portion, and the pedestal portion is provided with a cross slit-shaped discharge port. The connecting portion includes a bent portion that protrudes toward the outside of the container body, and the pedestal portion is pushed by the high-viscosity material when pressure is applied to the container body. By pushing toward the outside of the container body. When the discharge port is opened and the pressure on the container body is removed, the state returns to the state of projecting toward the inside of the container body, the discharge port is closed, and the outside air into the inner bag There is provided a delamination container for high-viscosity materials, which is configured to suppress intrusion of water.

 本発明者らが実験を行ったところ、キャップに設ける弁部として、上記の特定の構造を有する台座部及び連結部を有するものを採用したところ、20℃での粘度が100mPa・s以上である高粘度物であっても、容易に吐出することができ、吐出後に液ダレを起こすことがなく、しかも、内袋内部への外気の侵入を適切に抑制することができることを見出し、本発明の完成に到った。また、上記構成の弁部は、内容物が高粘度物である場合には外気の侵入を抑制するが、内容物が低粘度物である場合にはそのような機能が発揮されないことも分かった。 As a result of experiments by the present inventors, when a valve portion provided on the cap having a pedestal portion and a connecting portion having the specific structure described above is employed, the viscosity at 20 ° C. is 100 mPa · s or more. It has been found that even a high-viscosity product can be easily discharged, does not cause dripping after discharge, and can appropriately suppress the intrusion of outside air into the inner bag. Completed. In addition, it has been found that the valve portion configured as described above suppresses the intrusion of outside air when the content is a high-viscosity material, but does not exhibit such a function when the content is a low-viscosity material. .

本発明の一実施形態の積層剥離容器1の構成を示す断面図である。It is sectional drawing which shows the structure of the lamination peeling container 1 of one Embodiment of this invention. 図1から蓋部60を除き、且つキャップ51を容器本体3から分離した状態を示す断面図である。FIG. 2 is a cross-sectional view illustrating a state in which a lid portion 60 is removed from FIG. 1 and a cap 51 is separated from a container body 3. 図2中の内層13の構成を示す断面図である。It is sectional drawing which shows the structure of the inner layer 13 in FIG. (a)は、図1から蓋部60を除き且つ上下反転させた、積層剥離容器1のキャップ51周辺の拡大図であり、容器本体3に圧力を加えていない状態を示す。(b)は、(a)中の弁部53を下から見た図である。(A) is an enlarged view of the periphery of the cap 51 of the delamination container 1 with the lid 60 removed from FIG. 1 and turned upside down, and shows a state where no pressure is applied to the container body 3. (B) is the figure which looked at the valve part 53 in (a) from the bottom. (a)~(b)は、図4(a)~(b)に対応し、容器本体3に圧力を加えた状態を示す。FIGS. 4A and 4B correspond to FIGS. 4A and 4B and show a state in which pressure is applied to the container body 3.

 以下、本発明の実施形態について説明する。以下に示す実施形態中で示した各種特徴事項は、互いに組み合わせ可能である。また、各特徴について独立して発明が成立する。 Hereinafter, embodiments of the present invention will be described. Various characteristic items shown in the following embodiments can be combined with each other. The invention is established independently for each feature.

 図1~図2に示すように、本発明の一実施形態の高粘度物用積層剥離容器1は、容器本体3と、弁部材5と、キャップ51を備える。
 容器本体3は、内容物を収容する収容部7と、収容部7から内容物を吐出する口部9を備える。本実施形態では、内容物は、20℃での粘度が100mPa・s以上である高粘度物である。高粘度物としては、ケチャップ、マヨネーズ、ハチミツが例示される。高粘度物の20℃での粘度は、好ましくは500mPa・s以上であり、さらに好ましくは1000mPa・s以上であり、さらに好ましくは5000mPa・s以上である。高粘度物の20℃での粘度の上限は、特に規定されないが、例えば、10000、50000、又は100000mPa・sである。
As shown in FIGS. 1 and 2, the laminated release container 1 for a high viscosity material according to an embodiment of the present invention includes a container body 3, a valve member 5, and a cap 51.
The container body 3 includes a storage portion 7 that stores the contents, and a mouth portion 9 that discharges the contents from the storage portion 7. In the present embodiment, the content is a high-viscosity product having a viscosity at 20 ° C. of 100 mPa · s or more. Examples of the high viscosity material include ketchup, mayonnaise, and honey. The viscosity at 20 ° C. of the high viscosity product is preferably 500 mPa · s or more, more preferably 1000 mPa · s or more, and further preferably 5000 mPa · s or more. The upper limit of the viscosity at 20 ° C. of the high-viscosity product is not particularly defined, but is, for example, 10,000, 50000, or 100,000 mPa · s.

 容器本体3は、収容部7及び口部9において、外層11と内層13を備えており、外層11によって外殻12が構成され、内層13によって内袋14が構成される。内容物の減少に伴って内層13が外層11から剥離することによって、内袋14が外殻12から剥離して収縮する。 The container body 3 includes an outer layer 11 and an inner layer 13 in the housing portion 7 and the mouth portion 9, an outer shell 12 is constituted by the outer layer 11, and an inner bag 14 is constituted by the inner layer 13. As the content decreases, the inner layer 13 peels from the outer layer 11, whereby the inner bag 14 peels from the outer shell 12 and contracts.

 キャップ51は、筒部52と、蓋部60と、弁部53と、弁固定部材54とを備える。蓋部60は、ヒンジ部61において筒部52に連結されており、ヒンジ部61を中心にして筒部52に対して蓋部60を相対回転させることによって蓋部60の開閉が可能になっている。弁部53は、その外周部53aが弁固定部材54と筒部52の間に挟まれており、弁固定部材54を筒部52に固定することによって弁部53が筒部52に対して固定される。 The cap 51 includes a cylindrical portion 52, a lid portion 60, a valve portion 53, and a valve fixing member 54. The lid part 60 is connected to the cylinder part 52 at the hinge part 61, and the lid part 60 can be opened and closed by rotating the lid part 60 relative to the cylinder part 52 around the hinge part 61. Yes. The valve portion 53 has an outer peripheral portion 53 a sandwiched between the valve fixing member 54 and the cylindrical portion 52, and the valve portion 53 is fixed to the cylindrical portion 52 by fixing the valve fixing member 54 to the cylindrical portion 52. Is done.

 図3に示すように、口部9には、雄ネジ部9dが設けられており、筒部52の内面には雌ねじ部52aが設けられている。雌ねじ部52aと雄ネジ部9dを螺合させることによってキャップ51を容器本体3に取り付けることができる。 As shown in FIG. 3, the mouth portion 9 is provided with a male screw portion 9d, and the cylindrical portion 52 is provided with a female screw portion 52a. The cap 51 can be attached to the container body 3 by screwing the female screw portion 52a and the male screw portion 9d.

 収容部7には、外殻12と内袋14の間の中間空間21と、容器本体3の外部空間Sとの間の空気の出入りを調節する弁部材5が設けられている。外殻12には、収容部7において中間空間21と外部空間Sを連通する外気導入孔15が設けられている。外気導入孔15は、外殻12にのみ設けられた貫通孔であり、内袋14には到達していない。弁部材5は、外気導入孔15に挿通され且つ外気導入孔15に対してスライド移動可能な軸部5aと、軸部5aの中間空間21側に設けられ且つ軸部5aよりも断面積が大きいシール部5cと、軸部5aの外部空間S側に設けられ且つ弁部材5が中間空間21に入り込むことを防ぐ係止部5bを備える。 The accommodating portion 7 is provided with a valve member 5 that adjusts the flow of air between the intermediate space 21 between the outer shell 12 and the inner bag 14 and the outer space S of the container body 3. The outer shell 12 is provided with an outside air introduction hole 15 that communicates the intermediate space 21 and the outer space S in the housing portion 7. The outside air introduction hole 15 is a through hole provided only in the outer shell 12 and does not reach the inner bag 14. The valve member 5 is inserted in the outside air introduction hole 15 and is slidable with respect to the outside air introduction hole 15. The valve member 5 is provided on the intermediate space 21 side of the shaft part 5a and has a larger sectional area than the shaft part 5a. A seal portion 5c and a locking portion 5b provided on the outer space S side of the shaft portion 5a and preventing the valve member 5 from entering the intermediate space 21 are provided.

 シール部5cは、外殻12を圧縮した際に外気導入孔15を実質的に閉塞させるように構成され、軸部5aに近づくにつれて断面積が小さくなる形状になっている。また、係止部5bは、外殻12が圧縮された後に復元する際に中間空間21に空気が導入可能なように構成される。外殻12を圧縮すると、中間空間21内の圧力が外圧よりも高くなって、中間空間21内の空気が外気導入孔15から外部に漏れ出す。この圧力差と空気の流れによってシール部5cが外気導入孔15に向かって移動し、シール部5cが外気導入孔15を閉塞する。シール部5cが軸部5aに近づくにつれて断面積が小さくなる形状であるので、シール部5cが容易に外気導入孔15に嵌って外気導入孔15を閉塞する。 The seal portion 5c is configured to substantially close the outside air introduction hole 15 when the outer shell 12 is compressed, and has a shape in which a cross-sectional area decreases as the shaft portion 5a is approached. Moreover, the latching | locking part 5b is comprised so that air can be introduce | transduced into the intermediate | middle space 21 when decompress | restoring after the outer shell 12 is compressed. When the outer shell 12 is compressed, the pressure in the intermediate space 21 becomes higher than the external pressure, and the air in the intermediate space 21 leaks out from the outside air introduction hole 15. Due to the pressure difference and the air flow, the seal portion 5 c moves toward the outside air introduction hole 15, and the seal portion 5 c closes the outside air introduction hole 15. Since the cross-sectional area becomes smaller as the seal portion 5c approaches the shaft portion 5a, the seal portion 5c easily fits in the outside air introduction hole 15 and closes the outside air introduction hole 15.

 この状態で外殻12をさらに圧縮すると、中間空間21内の圧力が高まり、その結果、内袋14が圧縮されて、内袋14内の内容物が吐出される。また、外殻12への圧縮力を解除すると、外殻12が自身の弾性によって復元しようとする。この際、シール部5cが外気導入孔15から離れて、外気導入孔15の閉塞が解除されて、中間空間21内に外気が導入される。また、係止部5bが外気導入孔15を塞いでしまわないように、係止部5bには外殻12に当接する面に溝5dが設けられている。 When the outer shell 12 is further compressed in this state, the pressure in the intermediate space 21 is increased. As a result, the inner bag 14 is compressed and the contents in the inner bag 14 are discharged. Further, when the compressive force applied to the outer shell 12 is released, the outer shell 12 tries to recover by its own elasticity. At this time, the seal portion 5 c moves away from the outside air introduction hole 15, the block of the outside air introduction hole 15 is released, and outside air is introduced into the intermediate space 21. Further, a groove 5 d is provided on the surface of the locking portion 5 b that contacts the outer shell 12 so that the locking portion 5 b does not block the outside air introduction hole 15.

 弁部材5は、シール部5cが外気導入孔15を押し広げながら、シール部5cに中間空間21内に挿入することによって容器本体3に装着することができる。そのため、シール部5cの先端は、先細り形状になっていることが好ましい。このような弁部材5は、容器本体3の外側からシール部5cを中間空間21内に押し込むだけで装着可能なので、生産性に優れている。尚、弁部材5を備える場合に限らず、中間空間21内の圧力が外部の圧力以上のときには外気導入孔15を閉塞し、中間空間21内の圧力が外部の圧力よりも低くなると外気導入孔15を開放して中間空間21に外部から空気を導入する逆止弁を備える構成であってもよい。 The valve member 5 can be mounted on the container body 3 by inserting the seal portion 5c into the intermediate space 21 while the seal portion 5c expands the outside air introduction hole 15. Therefore, it is preferable that the tip of the seal portion 5c has a tapered shape. Since such a valve member 5 can be mounted simply by pushing the seal portion 5c into the intermediate space 21 from the outside of the container body 3, it is excellent in productivity. The external air introduction hole 15 is closed when the pressure in the intermediate space 21 is equal to or higher than the external pressure, and the external air introduction hole is reduced when the pressure in the intermediate space 21 becomes lower than the external pressure. The structure provided with the non-return valve which open | releases 15 and introduces air into the intermediate | middle space 21 from the outside may be sufficient.

 次に、容器本体3の層構成についてさらに詳細に説明する。容器本体3は、外層11と内層13を備える。外層11は、復元性が高くなるように、内層13よりも肉厚に形成される。 Next, the layer structure of the container body 3 will be described in more detail. The container body 3 includes an outer layer 11 and an inner layer 13. The outer layer 11 is formed to be thicker than the inner layer 13 so that the restoring property is high.

 外層11は、例えば、低密度ポリエチレン、直鎖状低密度ポリエチレン、高密度ポリエチレン、ポリプロピレン、エチレン-プロピレン共重合体及びその混合物などで構成される。 The outer layer 11 is composed of, for example, low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, ethylene-propylene copolymer, and a mixture thereof.

 図3に示すように、内層13は、容器外面側に設けられたEVOH層13aと、EVOH層13aの容器内面側に設けられた内面層13bと、EVOH層13aと内面層13bの間に設けられた接着層13cを備える。EVOH層13aを設けることでガスバリア性、及び外層11からの剥離性を向上させることができる。EVOH層13aは、エチレン-ビニルアルコール共重合体(EVOH)樹脂からなる層であり、エチレンと酢酸ビニル共重合物の加水分解により得られる。 As shown in FIG. 3, the inner layer 13 is provided between the EVOH layer 13a provided on the outer surface side of the container, the inner surface layer 13b provided on the inner surface side of the EVOH layer 13a, and between the EVOH layer 13a and the inner surface layer 13b. The adhesive layer 13c is provided. By providing the EVOH layer 13a, the gas barrier property and the peelability from the outer layer 11 can be improved. The EVOH layer 13a is a layer made of an ethylene-vinyl alcohol copolymer (EVOH) resin, and is obtained by hydrolysis of ethylene and vinyl acetate copolymer.

 内面層13bは、積層剥離容器1の内容物に接触する層であり、例えば、低密度ポリエチレン、直鎖状低密度ポリエチレン、高密度ポリエチレン、ポリプロピレン、エチレン-プロピレン共重合体及びその混合物などのポリオレフィンからなり、低密度ポリエチレン又は直鎖状低密度ポリエチレンからなることが好ましい。 The inner surface layer 13b is a layer that comes into contact with the contents of the delamination container 1, and is, for example, a polyolefin such as low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, ethylene-propylene copolymer, and a mixture thereof. It is preferably made of low-density polyethylene or linear low-density polyethylene.

 接着層13cは、EVOH層13aと内面層13bとを接着する機能を有する層であり、例えば上述したポリオレフィンにカルボキシル基を導入した酸変性ポリオレフィン(例:無水マレイン酸変性ポリエチレン)を添加したものや、エチレン酢酸ビニル共重合体(EVA)である。接着層13cの一例は、低密度ポリエチレン又は直鎖状低密度ポリエチレンと、酸変性ポリエチレンの混合物である。 The adhesive layer 13c is a layer having a function of adhering the EVOH layer 13a and the inner surface layer 13b. For example, an acid-modified polyolefin having a carboxyl group introduced into the above-described polyolefin (eg, maleic anhydride-modified polyethylene) is added. And ethylene vinyl acetate copolymer (EVA). An example of the adhesive layer 13c is a mixture of low-density polyethylene or linear low-density polyethylene and acid-modified polyethylene.

 次に、弁部53の構成についてさらに詳細に説明する。弁部53は、キャップ51が容器本体3に取り付けられた状態で、容器本体3内部に向かって突出する台座部55と、台座部55と筒部52を連結する連結部56を備える。台座部55は、吐出口57が設けられる平坦部55aを備える。連結部56は、容器本体3の外側に向かって突出する屈曲部56aを備える。弁部53は、シリコーンゴムなどの可撓性材料で形成される。 Next, the configuration of the valve unit 53 will be described in more detail. The valve portion 53 includes a pedestal portion 55 that protrudes toward the inside of the container main body 3 and a connecting portion 56 that connects the pedestal portion 55 and the cylindrical portion 52 in a state where the cap 51 is attached to the container main body 3. The pedestal portion 55 includes a flat portion 55a in which the discharge port 57 is provided. The connecting portion 56 includes a bent portion 56 a that protrudes toward the outside of the container body 3. The valve portion 53 is formed of a flexible material such as silicone rubber.

 吐出口57は、図4(b)に示すように、平坦部55aに互いに交差(好ましくは直交)するように形成されたスリット58a,58b(交差スリット)によって形成される。スリット58a,58bによって4つのフラップ57a~57dが形成される。 As shown in FIG. 4B, the discharge port 57 is formed by slits 58a and 58b (cross slits) formed so as to intersect (preferably orthogonally) the flat portion 55a. Four flaps 57a to 57d are formed by the slits 58a and 58b.

 図4は、容器本体3に対して圧力が加わっていない状態であり、この状態では、フラップ57a~57dは互いに密着しており、容器本体3内の内容物が容易には漏れ出さない。一方、容器本体3に圧力を加えて容器本体3を圧縮すると、平坦部55aが容器本体3内の内容物によって押されることによって、図5に示すように、台座部55が容器本体3の外側に向かって押し出されると共に吐出口57が開かれる。具体的には、図5に示すように、フラップ57a~57dが容器本体3の外側に向かって湾曲することによって互いに離間されて、フラップ57a~57dの中心に開口57eが形成される。そして、開口57eを通じて、容器本体3内の内容物が吐出される。 FIG. 4 shows a state in which no pressure is applied to the container body 3. In this state, the flaps 57a to 57d are in close contact with each other, and the contents in the container body 3 do not leak easily. On the other hand, when the container body 3 is compressed by applying pressure to the container body 3, the flat portion 55 a is pushed by the contents in the container body 3, so that the pedestal portion 55 is outside the container body 3 as shown in FIG. 5. And the discharge port 57 is opened. Specifically, as shown in FIG. 5, the flaps 57a to 57d are separated from each other by being bent toward the outside of the container body 3, and an opening 57e is formed at the center of the flaps 57a to 57d. And the contents in the container main body 3 are discharged through the opening 57e.

 容器本体3への圧力が除かれると、弁部53は、自身の復元力によって図4に示すように容器本体3の内部に向かって突出する状態に復帰すると共にフラップ57a~57dが再度互いに密着して吐出口57が閉じられる。この際、吐出口57の位置が容器本体3の内部に向かって移動しながら吐出口57が閉じられるので、液ダレが起こりにくい。 When the pressure on the container body 3 is removed, the valve portion 53 returns to a state of projecting toward the inside of the container body 3 as shown in FIG. 4 due to its restoring force, and the flaps 57a to 57d are brought into close contact with each other again. Thus, the discharge port 57 is closed. At this time, since the discharge port 57 is closed while the position of the discharge port 57 moves toward the inside of the container body 3, liquid dripping hardly occurs.

 容器本体3の内容物の吐出後に吐出口57が閉じられた後に、吐出口57を通じて外気が内袋14内に侵入するかどうかについて実験を行ったところ、内容物が水のような低粘度物(粘度が20℃で1mPa・s)である場合には、内袋14内に外気が侵入した。一方、内容物がケチャップ(粘度が20℃で約1000mPa・s)である場合や、ハチミツ(粘度が20℃で約8000mPa・s)である場合には、内袋14内に外気が侵入しなかった。このように本発明の積層剥離容器は、高粘度物を収容した場合に限って、内容物の吐出後に外気の侵入を効果的に抑制することができることが分かった。 After the discharge port 57 was closed after the contents of the container body 3 were discharged, an experiment was conducted to determine whether outside air would enter the inner bag 14 through the discharge port 57. When the viscosity was 1 mPa · s at 20 ° C., outside air entered the inner bag 14. On the other hand, when the contents are ketchup (viscosity is about 1000 mPa · s at 20 ° C.) or honey (viscosity is about 8000 mPa · s at 20 ° C.), outside air does not enter the inner bag 14. It was. Thus, it has been found that the delamination container of the present invention can effectively suppress the intrusion of outside air after the contents are discharged only when a highly viscous material is accommodated.

1:高粘度物用積層剥離容器、3:容器本体、5:弁部材、7:収容部、9:口部、11:外層、12:外殻、13:内層、14:内袋、15:外気導入孔、51:キャップ、53:弁部 1: Laminated peeling container for high viscosity material, 3: Container body, 5: Valve member, 7: Storage part, 9: Mouth part, 11: Outer layer, 12: Outer shell, 13: Inner layer, 14: Inner bag, 15: Outside air introduction hole, 51: cap, 53: valve part

Claims (1)

20℃での粘度が100mPa・s以上である高粘度物を収容する容器本体と、前記容器本体の口部に装着されるキャップとを備え、
前記容器本体は、外殻と内袋とを備え且つ内容物の減少に伴って前記内袋が前記外殻から剥離し収縮する積層剥離容器であり、
前記キャップは、筒部と、前記筒部内に配置された弁部を備え、
前記弁部は、前記容器本体内部に向かって突出する台座部と、前記台座部と前記筒部を連結する連結部とを備え、
前記台座部は、交差スリット状の吐出口が設けられる平坦部を備え、
前記連結部は、前記容器本体の外側に向かって突出する屈曲部を備え、
前記台座部は、前記容器本体に圧力が加えられると前記平坦部が前記高粘度物によって押されることによって前記容器本体の外側に向かって押し出されると共に前記吐出口が開かれ、且つ前記容器本体への圧力が除かれると前記容器本体の内部に向かって突出する状態に復帰して前記吐出口が閉じられて前記内袋内部への外気の侵入が抑制されるように構成される、高粘度物用積層剥離容器。
A container body containing a highly viscous material having a viscosity at 20 ° C. of 100 mPa · s or more, and a cap attached to the mouth of the container body,
The container body is a laminated peeling container including an outer shell and an inner bag, and the inner bag is peeled off and contracted from the outer shell as the content decreases.
The cap includes a tubular portion and a valve portion disposed in the tubular portion,
The valve portion includes a pedestal portion that protrudes toward the inside of the container body, and a connecting portion that connects the pedestal portion and the cylindrical portion,
The pedestal part includes a flat part provided with a cross-slit discharge port,
The connecting portion includes a bent portion that protrudes toward the outside of the container body,
When the pressure is applied to the container main body, the pedestal is pushed toward the outside of the container main body by being pushed by the high-viscosity material, the discharge port is opened, and the container main body is opened. A high-viscosity product configured to return to a state of projecting toward the inside of the container main body when the pressure is removed and the discharge port is closed to prevent intrusion of outside air into the inner bag Laminated peeling container.
PCT/JP2016/053043 2015-02-02 2016-02-02 Laminated separating container for high-viscosity substances Ceased WO2016125784A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2015018130A JP6496154B2 (en) 2015-02-02 2015-02-02 Laminated peeling container for high viscosity materials
JP2015-018130 2015-02-02

Publications (1)

Publication Number Publication Date
WO2016125784A1 true WO2016125784A1 (en) 2016-08-11

Family

ID=56564125

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2016/053043 Ceased WO2016125784A1 (en) 2015-02-02 2016-02-02 Laminated separating container for high-viscosity substances

Country Status (2)

Country Link
JP (1) JP6496154B2 (en)
WO (1) WO2016125784A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2556898A (en) * 2016-11-22 2018-06-13 Nerudia Ltd Dispense tip and dispenser apparatus
JP2019085175A (en) * 2017-11-01 2019-06-06 シロウマサイエンス株式会社 Cap and packaged food

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6859777B2 (en) * 2017-03-17 2021-04-14 東洋製罐株式会社 Cap with slit valve
JP6859778B2 (en) * 2017-03-17 2021-04-14 東洋製罐株式会社 Cap sealing structure
JP2018177350A (en) * 2017-04-20 2018-11-15 東洋製罐グループホールディングス株式会社 Packaging material
JP6987526B2 (en) * 2017-04-28 2022-01-05 株式会社吉野工業所 Squeeze former container
JP7089156B2 (en) * 2018-02-26 2022-06-22 キョーラク株式会社 Laminated peeling container
WO2024014071A1 (en) * 2022-07-11 2024-01-18 東京ライト工業株式会社 Discharge cap
JP7398722B1 (en) * 2022-07-11 2023-12-15 東京ライト工業株式会社 discharge cap

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08506307A (en) * 1992-09-10 1996-07-09 ザ、プロクター、エンド、ギャンブル、カンパニー Upright liquid container with self-sealing valve
JP2002531346A (en) * 1998-12-09 2002-09-24 シークイスト クロージャーズ フォーリン、 インコーポレイテッド Non-venting valve for fluid and dispensing packaging container
JP2013095455A (en) * 2011-10-31 2013-05-20 Yoshino Kogyosho Co Ltd Capped container

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6780911B2 (en) * 2013-11-27 2020-11-04 キョーラク株式会社 Laminate peeling container

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08506307A (en) * 1992-09-10 1996-07-09 ザ、プロクター、エンド、ギャンブル、カンパニー Upright liquid container with self-sealing valve
JP2002531346A (en) * 1998-12-09 2002-09-24 シークイスト クロージャーズ フォーリン、 インコーポレイテッド Non-venting valve for fluid and dispensing packaging container
JP2013095455A (en) * 2011-10-31 2013-05-20 Yoshino Kogyosho Co Ltd Capped container

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2556898A (en) * 2016-11-22 2018-06-13 Nerudia Ltd Dispense tip and dispenser apparatus
GB2556898B (en) * 2016-11-22 2021-12-15 Nerudia Ltd Dispense tip and dispenser apparatus
JP2019085175A (en) * 2017-11-01 2019-06-06 シロウマサイエンス株式会社 Cap and packaged food
JP7199050B2 (en) 2017-11-01 2023-01-05 シロウマサイエンス株式会社 caps and packaged food

Also Published As

Publication number Publication date
JP2016141437A (en) 2016-08-08
JP6496154B2 (en) 2019-04-03

Similar Documents

Publication Publication Date Title
JP6496154B2 (en) Laminated peeling container for high viscosity materials
TWI552927B (en) Eject the container
CN109641686B (en) discharge container
JP5295460B2 (en) Discharge container
WO2018062436A1 (en) Discharge container
WO2013065599A1 (en) Discharge container
WO2016117668A1 (en) Delamination container
JP6993554B2 (en) Laminated peeling container
JP2017132508A (en) Discharge container
JP5793807B2 (en) Container with cap
JP2018122860A (en) Delamination container
JP2017165452A (en) Double container
JP2016179822A (en) Delamination container
JP5041486B2 (en) Pill container
JP6710468B2 (en) Discharge container
JP2019116308A (en) Delamination container
JP2018012511A (en) Delamination container
JP2017081628A (en) Discharge container
JP6366518B2 (en) Squeeze foamer container
JP2016159930A (en) Discharge container
JP2018090282A (en) Double container
JP6961210B2 (en) Cap and discharge container
WO2016080030A1 (en) Double-walled container for highly viscous liquid
JP2019081591A (en) Double container cap
JP6896342B2 (en) Double container cap

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 16746615

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 16746615

Country of ref document: EP

Kind code of ref document: A1