WO2016125599A1 - Method for producing wheat gluten - Google Patents
Method for producing wheat gluten Download PDFInfo
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- WO2016125599A1 WO2016125599A1 PCT/JP2016/051767 JP2016051767W WO2016125599A1 WO 2016125599 A1 WO2016125599 A1 WO 2016125599A1 JP 2016051767 W JP2016051767 W JP 2016051767W WO 2016125599 A1 WO2016125599 A1 WO 2016125599A1
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- Prior art keywords
- acid
- wheat gluten
- calcium
- dough
- weight
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Classifications
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- A—HUMAN NECESSITIES
- A21—BAKING; EDIBLE DOUGHS
- A21D—TREATMENT OF FLOUR OR DOUGH FOR BAKING, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS
- A21D2/00—Treatment of flour or dough by adding materials thereto before or during baking
- A21D2/08—Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
- A21D2/36—Vegetable material
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/14—Vegetable proteins
- A23J3/18—Vegetable proteins from wheat
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L7/00—Cereal-derived products; Malt products; Preparation or treatment thereof
- A23L7/10—Cereal-derived products
Definitions
- the present invention relates to a method for producing wheat gluten having a high whiteness and a good color tone.
- the present invention also relates to wheat gluten obtained by the production method.
- Wheat gluten is abundant in supply as a by-product in the production of wheat starch, and is known to exhibit properties such as emulsification, cohesion, water absorption, viscoelasticity, etc., used in various processed foods Has been.
- the color tone of wheat gluten is affected by the variety of flour used as a raw material, and further contains tyrosinase, ash, etc., so there is a drawback that when heated, it causes a change in color tone (fading or discoloration). .
- wheat gluten is low in whiteness or causes a change in color tone by heating, when used in processed foods that require whiteness, it becomes a factor that reduces the commercial value of processed foods. Therefore, wheat gluten having high whiteness and capable of stably maintaining the color tone even by heating is demanded.
- An object of the present invention is to provide a technique for producing wheat gluten having a high whiteness and a good color tone.
- the present inventor conducted intensive studies to solve the above-mentioned problems.
- (i) flour, (ii) calcium salt, and (iii) a first step of kneading water to form a dough, and the dough It was found that wheat gluten having high whiteness and good color tone can be obtained by performing the second step of washing with water to wash away starch and recovering wheat gluten.
- the first step further, (iv) by mixing the organic acid, phosphoric acid, and / or their monovalent metal salt to form a dough, the whiteness is higher and wheat having a better color tone We have found that gluten can be obtained.
- the present invention has been completed by further studies based on this finding.
- Item 1 A method for producing wheat gluten, (i) wheat flour, (ii) calcium salt, and (iii) a first step of kneading water to form a dough, and a second step of washing the dough with water to wash away starch and recovering wheat gluten
- the manufacturing method characterized by including.
- Item 2. Item 2. The method according to Item 1, wherein the component (ii) is an inorganic salt of calcium and / or an organic acid salt of calcium.
- Item 3. Item 3.
- Item 4 The method according to Item 1 or 2, wherein the component (ii) is at least one selected from the group consisting of calcium chloride, calcium phosphate, calcium salt of hydroxy acid, and calcium salt of monocarboxylic acid.
- Item 4. The production method according to any one of Items 1 to 3, wherein the component (ii) is at least one selected from the group consisting of calcium chloride, tricalcium phosphate, calcium acetate, and calcium lactate.
- Item 5. The method according to any one of Items 1 to 4, wherein in the first step, (iv) at least one selected from the group consisting of an organic acid, phosphoric acid, and a monovalent metal salt thereof is mixed to form a dough. The manufacturing method as described.
- Item 6. Item 6.
- the component (iv) is an alkali metal citrate, ferulic acid, dibasic metal hydrogen phosphate, trialkali metal phosphate, or an alkali metal salt of polyphosphoric acid having 2 to 23 phosphoric acid residues.
- wheat gluten with high whiteness when producing wheat gluten, wheat gluten with high whiteness can be produced by a simple method of adding a specific additive to the flour dough. Further, in the present invention, even when low quality wheat flour having an ash content of 0.7% by weight or more is used as a raw material, wheat gluten having a high whiteness can be produced. Therefore, the variety of flour used as a raw material is restricted. The wheat gluten having an excellent color can be produced without any problems.
- the production method of the present invention is a method for producing wheat gluten, wherein (i) wheat flour, (ii) calcium salt, and (iii) a first step of kneading water to form a dough, and said dough to water It is characterized by including a second step of washing the starch to wash away starch and recovering wheat gluten.
- the manufacturing method of this invention is explained in full detail.
- flour hereinafter sometimes referred to as (i) component
- calcium salt hereinafter sometimes referred to as (ii) component
- (iii) water are mixed.
- the variety of flour used as the component (i) is not particularly limited, and any variety such as white wheat or red wheat may be used, but from the viewpoint of increasing the whiteness of wheat gluten, preferably White wheat.
- flour, medium strength, strong flour, etc. may be used as wheat flour, Preferably strong flour is mentioned.
- the calcium salt used as the component (ii) is not particularly limited as long as it is acceptable for food production, but preferably has a high solubility in water, specifically, purified water at 25 ° C.
- a calcium salt in which 0.001 g or more, preferably 0.01 g or more can be dissolved with respect to 100 mL is mentioned.
- Specific examples of the calcium salt used as the component (ii) include calcium inorganic salts and calcium organic acid salts.
- the kind of inorganic salt of calcium is not particularly limited as long as it is acceptable for food production, and specific examples include calcium chloride, calcium hydroxide, calcium phosphate and the like. These calcium inorganic salts may be used alone or in combination of two or more. Among these inorganic salts of calcium, calcium chloride, calcium phosphate, and more preferably calcium chloride are preferable from the viewpoint of producing wheat gluten having a higher whiteness and a better color tone.
- the type of organic acid salt of calcium is not particularly limited as long as it is acceptable for food production.
- hydroxy acid monocarboxylic acid, dicarboxylic acid
- An acid etc. are mentioned.
- examples of the hydroxy acid include hydroxy acids having 3 to 10 carbon atoms such as citric acid, lactic acid, malic acid, and ferulic acid.
- examples of the monocarboxylic acid include monocarboxylic acids having 2 to 6 carbon atoms such as acetic acid, propionic acid, butyric acid, valeric acid, and caproic acid.
- dicarboxylic acid examples include dicarboxylic acids having 2 to 6 carbon atoms such as oxalic acid, malonic acid, succinic acid, glutaric acid, and adipic acid.
- organic acid salts of calcium may be used alone or in combination of two or more.
- the organic acid salts of calcium from the viewpoint of producing wheat gluten with higher whiteness and better color tone, preferably calcium salt of hydroxy acid, calcium salt of monocarboxylic acid, more preferably calcium acetate, lactic acid Calcium is mentioned.
- one kind of calcium salt may be used alone, or two or more kinds of calcium salts may be used in combination.
- calcium from the viewpoint of producing wheat gluten having higher whiteness and a better color tone, calcium chloride, calcium phosphate, calcium salt of hydroxy acid, calcium salt of monocarboxylic acid; more preferably calcium chloride, Examples include calcium phosphate, calcium acetate, and calcium lactate.
- the amount of component (ii) added when forming the dough is, for example, 0.001 to 10 parts by weight, preferably 0, in total of component (ii) with respect to 100 parts by weight of flour.
- the amount is 0.001 to 5 parts by weight, more preferably 0.001 to 1.5 parts by weight.
- the amount of water to be added when forming the dough may be appropriately set within the range adopted in the production of general wheat gluten, for example, for 100 parts by weight of flour,
- the amount of water is 30 to 200 parts by weight, preferably 40 to 150 parts by weight, more preferably 50 to 100 parts by weight.
- the first step when forming the dough, in addition to the components (i) to (iii), at least one selected from the group consisting of organic acids, phosphoric acids, and monovalent metal salts thereof. (Hereinafter also referred to as component (iv)) may be added and mixed.
- component (iv) organic acids, phosphoric acids, and monovalent metal salts thereof.
- the type of organic acid used as component is not particularly limited as long as it is acceptable for food production, and examples thereof include hydroxy acid, monocarboxylic acid, dicarboxylic acid and the like. More specifically, examples of the hydroxy acid include hydroxy acids having 3 to 10 carbon atoms such as citric acid, lactic acid, malic acid, and ferulic acid. More specifically, examples of the monocarboxylic acid include monocarboxylic acids having 2 to 6 carbon atoms such as acetic acid, propionic acid, butyric acid, valeric acid, and caproic acid.
- dicarboxylic acid examples include dicarboxylic acids having 2 to 6 carbon atoms such as oxalic acid, malonic acid, succinic acid, glutaric acid, and adipic acid. These organic acids may be used individually by 1 type, and may be used in combination of 2 or more type. Among these organic acids, from the viewpoint of producing wheat gluten having a higher whiteness and a better color tone, hydroxy acids are preferable, hydroxy acids having 3 to 10 carbon atoms are more preferable, and citric acid is more preferable. Can be mentioned.
- the type of phosphoric acid used as the component is not particularly limited as long as it is acceptable for food production. Specifically, orthophosphoric acid; pyrophosphoric acid, tripolyphosphoric acid, tetrapolyphosphoric acid And polyphosphoric acid such as pentapolyphosphoric acid and hexapolyphosphoric acid. These phosphoric acids may be used individually by 1 type, and may be used in combination of 2 or more type. Among these phosphoric acids, from the viewpoint of producing wheat gluten with higher whiteness and better color tone, orthophosphoric acid, polyphosphoric acid having 2 to 23 constituents of phosphoric acid residues; more preferably Examples include orthophosphoric acid, pyrophosphoric acid, and tripolyphosphoric acid.
- the monovalent metal salt of organic acid and / or phosphoric acid used as component (iv) is not particularly limited as long as it is acceptable for food production.
- Examples include alkali metal salts such as sodium salt and potassium salt of acid and / or phosphoric acid. These monovalent metal salts may be used individually by 1 type, and may be used in combination of 2 or more type.
- one of organic acids, phosphoric acids, and monovalent metal salts thereof may be used alone, or two or more of these may be used in combination. May be.
- polyphosphoric acid having preferably 2 to 23 constituents of hydroxy acid, orthophosphoric acid, and phosphoric acid residue is preferable.
- monovalent metal salts thereof more preferably citric acid, ferulic acid, orthophosphoric acid, polyphosphoric acid having 2 to 23 constituents of phosphoric acid residues, and monovalent metal salts thereof; particularly preferably alkali citrate Examples thereof include metal salts, ferulic acid, hydrogen phosphate dialkali metal salts, phosphoric acid trialkali metal salts, and alkali metal salts of polyphosphoric acid having 2 to 23 constituents of phosphoric acid residues.
- the total amount of component (a) is 0.01 to 10 parts by weight, preferably 0.05 to 5 parts by weight per 100 parts by weight of flour. Parts, more preferably 0.1 to 1.5 parts by weight.
- the ingredients (i) to (iii) and, if necessary, the ingredient (iv) are mixed to form a dough called dough or batter.
- the kneading method at the time of forming the dough is not particularly limited.
- the method of kneading by simultaneously adding the components (i) to (iii) and, if necessary, the component (iv) A method in which the component (i) and the component (iii) are once mixed and then the component (ii) and the component (iv) used as necessary are added and mixed; the component (ii) and the component as necessary Examples thereof include a method in which a mixed liquid obtained by adding (iv) the component to the (iii) component is added to the (i) component and kneaded.
- the kneading conditions for forming the dough may be the same as the conditions used for forming the dough at the time of general gluten production.
- the kneading time (i ) To (iii) and, if necessary, the component (iv) is usually added for 1 to 120 minutes, preferably 1 to 60 minutes, more preferably 1 to 40 minutes.
- the temperature is usually 5 to 60 ° C., preferably 5 to 50 ° C., more preferably 5 to 40 ° C.
- a device used for forming the dough during general gluten production can be used as the kneading device used for forming the dough.
- the dough formed by kneading is preferably aged to sufficiently hydrate and swell the protein contained in the flour.
- a ripening method may be carried out under the conditions used for forming the dough at the time of general gluten production. Specifically, it is in the air at 5 to 60 ° C., preferably 5 to 40 ° C.
- a method of treatment by standing or the like in water for a aging time of 1 to 120 minutes, preferably 1 to 60 minutes can be mentioned.
- Second Step the dough obtained in the first step is washed with water to wash away starch, and wheat gluten is recovered.
- the method of washing the dough with water to wash away the starch may be carried out by a general washing method at the time of gluten production.
- the weight ratio is 1 to 100 times that of the dough.
- a method of washing with 2 to 50 times, more preferably 2 to 20 times, water is preferable.
- the wheat gluten thus obtained may be used as raw gluten as it is as a food material, but if necessary, by a drying method such as an air drying method, a spray drying method, a vacuum drying method or a freeze drying method. It may be dried to make active gluten.
- a drying method such as an air drying method, a spray drying method, a vacuum drying method or a freeze drying method. It may be dried to make active gluten.
- the wheat starch is suspended in the liquid obtained after washing the dough and collecting the gluten, so that the wheat starch can be collected and provided as a food material. .
- the wheat gluten obtained in the second step has emulsifiability, cohesiveness, water absorption, viscoelasticity, etc., as in the case of conventional wheat gluten, and is incorporated into various processed foods. Can be used.
- the type of processed food to which the wheat gluten obtained in the present invention is added is not particularly limited.
- fermented food such as wheat flour bread, rice flour bread, Chinese wharf; sponge cake, cookies, biscuits, caramel, pudding, jelly Processed foods such as margarine, mayonnaise, shortening, whipped cream, flower paste, dressing, etc .
- processed fishery and livestock products such as kamaboko, ham, sausage
- fried food such as tempura, fried food, fried food
- fried food ingredients Chinese buns, dumplings, grilled , Spring rolls, sandwiches and other internal ingredients
- processed milk fermented milk Dairy products
- various frozen food such as ice cream, frozen desserts such as ice sherbet and the like.
- the wheat gluten obtained in the present invention has high whiteness and can be stably maintained in color tone even when subjected to heat treatment, and thus is suitably used for processed foods that require whiteness.
- processed foods that require such whiteness include noodles such as udon and Chinese noodles, wheat bread, rice flour bread, gyoza skin, and yakin skin.
- Test example 1 Production of wheat gluten 75 parts by weight of water at 25 ° C. was added to 100 parts by weight of control flour and mixed for 6 minutes to prepare a dough. The obtained dough is allowed to stand for 30 minutes in water (25% by weight) of 3 times its weight (weight ratio), then the dough is kneaded in water, the starch is washed away, the massive residue is recovered, and viscoelastic raw gluten Got. These were dried with a freeze dryer to obtain activated wheat gluten. The protein content of the obtained active wheat gluten was 79% by weight.
- Comparative Examples 1-9 75 parts by weight of water at 25 ° C. and 100 parts by weight of wheat flour and a predetermined amount of an alkali metal salt of an organic acid shown in Table 1 were added and mixed for 6 minutes to prepare a dough. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
- Examples 1 to 5 75 parts by weight of water at 25 ° C. and a predetermined amount of calcium salt shown in Table 2 were added to 100 parts by weight of flour and mixed for 6 minutes to prepare a dough. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
- Examples 6-14 A dough was prepared by adding 75 parts by weight of water at 25 ° C. and a predetermined amount of calcium salt shown in Table 2 and an organic acid, phosphoric acid or a salt thereof to 100 parts by weight of flour and mixing for 6 minutes. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
- the L value is markedly before and after heating. It was high and had excellent whiteness.
- Test example 2 Production of wheat gluten 75 parts by weight of water at 25 ° C. was added to 100 parts by weight of control flour and mixed for 6 minutes to prepare a dough. The obtained dough is allowed to stand for 30 minutes in water (25% by weight) of 3 times its weight (weight ratio), then the dough is kneaded in water, the starch is washed away, the massive residue is recovered, and viscoelastic raw gluten Got. These were dried with a freeze dryer to obtain activated wheat gluten. The protein content of the obtained active wheat gluten was 79% by weight.
- Examples 15-20 100 parts by weight of flour, 75 parts by weight of water at 25 ° C., a predetermined amount of sodium polyphosphate (3 or more constituent phosphate residues) shown in Table 3 and calcium chloride are added and mixed for 6 minutes to prepare a dough did. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
- Examples 21-25 A dough was prepared by adding 75 parts by weight of water at 25 ° C. and predetermined amounts of trisodium citrate and calcium chloride shown in Table 3 to 100 parts by weight of flour and mixing for 6 minutes. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
- Table 3 shows the obtained results.
- required the difference ((DELTA) L value) with respect to L value of the active wheat gluten of control is shown.
- the activated wheat gluten produced by adding sodium polyphosphate or trisodium citrate and calcium chloride had an L value before and after heating as compared to the active wheat gluten as a control. A marked increase was observed. That is, from this result, the whiteness can be remarkably increased by setting the addition amount of sodium polyphosphate or trisodium citrate to 0.1 to 1 part by weight and using it together with calcium chloride with respect to 100 parts by weight of wheat flour. It became clear that highly active wheat gluten could be obtained.
- Test example 3 Production of wheat gluten 75 parts by weight of water at 25 ° C. was added to 100 parts by weight of control flour and mixed for 6 minutes to prepare a dough. The obtained dough is allowed to stand for 30 minutes in water (25% by weight) of 3 times its weight (weight ratio), then the dough is kneaded in water, the starch is washed away, the massive residue is recovered, and viscoelastic raw gluten Got. These were dried with a freeze dryer to obtain activated wheat gluten. The protein content in the obtained active wheat gluten was 79% by weight.
- Examples 26-32 A dough is prepared by adding 75 parts by weight of water at 25 ° C. to 100 parts by weight of wheat flour, adding a predetermined amount of sodium polyphosphate (having 3 or more constituent phosphate residues) and calcium chloride as shown in Table 4, and mixing for 6 minutes. did. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
- Examples 33-35 To 100 parts by weight of flour, 75 parts by weight of water at 25 ° C. and predetermined amounts of trisodium citrate and calcium chloride shown in Table 4 were added and mixed for 6 minutes to prepare a dough. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
- Table 4 shows the obtained results.
- required the difference ((DELTA) L value) with respect to L value of the active wheat gluten of control is shown.
- the activated wheat gluten produced by adding sodium polyphosphate or trisodium citrate and calcium chloride has an L value before and after heating as compared with the active wheat gluten as a control. A significant increase was observed.
- the addition amount of calcium chloride with respect to 100 parts by weight of flour, by setting the addition amount of calcium chloride to 0.2 parts by weight or more and using it together with sodium polyphosphate or trisodium citrate, It became clear that highly active wheat gluten was obtained.
- Test example 4 Production of wheat gluten 75 parts by weight of water at 25 ° C. was added to 100 parts by weight of control flour and mixed for 6 minutes to prepare a dough. The obtained dough is allowed to stand for 30 minutes in water (25% by weight) of 3 times its weight (weight ratio), then the dough is kneaded in water, the starch is washed away, the massive residue is recovered, and viscoelastic raw gluten Got. These were dried with a freeze dryer to obtain activated wheat gluten. The protein content of the obtained active wheat gluten was 79% by weight in terms of dry matter.
- Comparative Examples 12-15 Add 75 parts by weight of water at 25 ° C. to 100 parts by weight of wheat flour, add a predetermined amount of an alkali metal salt of an inorganic acid or an inorganic salt of an alkaline earth metal (other than calcium salt) as shown in Table 5 and mix for 6 minutes. Was made. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
- Comparative Examples 16-19 Add 75 parts by weight of water at 25 ° C. to 100 parts by weight of wheat flour, a predetermined amount of trisodium citrate shown in Table 1, and an inorganic salt of an alkali metal salt or an inorganic salt of an alkaline earth metal (other than calcium salt) For 6 minutes to prepare a dough. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
- Table 5 shows the obtained results.
- required the difference ((DELTA) L value) with respect to the L value of the active wheat gluten of control is shown.
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Abstract
Description
本発明は、白色度が高く、良好な色調を有する小麦グルテンを製造する方法に関する。また、本発明は、当該製造方法で得られる小麦グルテンに関する。 The present invention relates to a method for producing wheat gluten having a high whiteness and a good color tone. The present invention also relates to wheat gluten obtained by the production method.
小麦グルテンは、小麦デンプンの製造における副産物として供給量が豊富であり、乳化性、凝集性、吸水性、粘弾性等の物性を示すことも知られており、様々な加工食品に配合して使用されている。 Wheat gluten is abundant in supply as a by-product in the production of wheat starch, and is known to exhibit properties such as emulsification, cohesion, water absorption, viscoelasticity, etc., used in various processed foods Has been.
一方、小麦グルテンは、原料として使用される小麦粉の品種によってその色調が左右され、更に、チロシナーゼ、灰分等が含まれているため、加熱すると、色調変化(退色や変色)をきたすという欠点がある。小麦グルテンが、白色度が低かったり、加熱によって色調変化を生じさせたりする場合、白さが要求される加工食品に使用すると、加工食品の商品価値を低下させる要因になる。そのため、白色度が高く、加熱によっても色調を安定に維持できる小麦グルテンが求められている。 On the other hand, the color tone of wheat gluten is affected by the variety of flour used as a raw material, and further contains tyrosinase, ash, etc., so there is a drawback that when heated, it causes a change in color tone (fading or discoloration). . When wheat gluten is low in whiteness or causes a change in color tone by heating, when used in processed foods that require whiteness, it becomes a factor that reduces the commercial value of processed foods. Therefore, wheat gluten having high whiteness and capable of stably maintaining the color tone even by heating is demanded.
従来、白色度の高い白小麦品種が開発されており(特許文献1参照)、このような原料穀物として使用することによって、白色度が高い小麦グルテンを得ることが可能になる。また、原料として使用される小麦粉の精製度を高め、ふすまや胚芽の混入率や灰分の含有量を低減させることによっても、白色度が高い小麦グルテンを得ることが可能になる。しかしながら、小麦粉の品種を白色小麦に変更したり、小麦粉の精製度を高めたりすることは、コスト面、調達面から容易ではなく、更に副産物である小麦デンプンのコストも押し上げるという欠点がある。 Conventionally, white wheat varieties with high whiteness have been developed (see Patent Document 1), and wheat gluten with high whiteness can be obtained by using such raw material grains. It is also possible to obtain wheat gluten with high whiteness by increasing the degree of purification of wheat flour used as a raw material and reducing the mixing rate of bran and germ and the content of ash. However, changing the variety of wheat flour to white wheat or increasing the degree of purification of the wheat flour is not easy in terms of cost and procurement, and further has the disadvantage of increasing the cost of wheat starch as a by-product.
また、従来、フェルラ酸を小麦粉に添加することによって、小麦粉を原料とした生地の変色や退色を抑制できることが報告されている(特許文献2参照)。しかしながら、フェルラ酸は、水に0.1重量%程度しか溶解しないため、水を多く使うグルテンの製造現場では扱い難い欠点があり、また価格もグルテン価格に比べて高価であるためコストを大幅に押し上げるという欠点がある。更に、近年、加工食品の色調に対する要求レベルが高まっており、フェルラ酸を単独で使用して製造した場合に比べて、より高い白色度を示す小麦グルテンの開発も望まれている。 Also, conventionally, it has been reported that by adding ferulic acid to wheat flour, discoloration and fading of the dough made from wheat flour can be suppressed (see Patent Document 2). However, since ferulic acid dissolves only about 0.1% by weight in water, it has disadvantages that are difficult to handle in the production site of gluten that uses a lot of water. There is a drawback of pushing up. Furthermore, in recent years, the level of demand for the color tone of processed foods has increased, and it has also been desired to develop wheat gluten that exhibits higher whiteness than when manufactured using ferulic acid alone.
本発明は、白色度が高く、良好な色調を有する小麦グルテンを製造する技術を提供することを目的とする。 An object of the present invention is to provide a technique for producing wheat gluten having a high whiteness and a good color tone.
本発明者は、前記課題を解決すべく鋭意検討を行ったところ、(i)小麦粉、(ii)カルシウム塩、及び(iii)水を混捏して生地を形成する第1工程、並びに前記生地を水で洗滌して澱粉を洗い流し、小麦グルテンを回収する第2工程を行うことによって、白色度が高く、良好な色調を有する小麦グルテンが得られることを見出した。また、前記第1工程において、更に(iv)有機酸、リン酸、及び/又はそれらの1価金属塩を混捏して生地を形成することによって、白色度が一層高く、より良好な色調の小麦グルテンが得られることを見出した。本発明は、かかる知見に基づいて、更に検討を重ねることにより完成したものである。 The present inventor conducted intensive studies to solve the above-mentioned problems. As a result, (i) flour, (ii) calcium salt, and (iii) a first step of kneading water to form a dough, and the dough It was found that wheat gluten having high whiteness and good color tone can be obtained by performing the second step of washing with water to wash away starch and recovering wheat gluten. In the first step, further, (iv) by mixing the organic acid, phosphoric acid, and / or their monovalent metal salt to form a dough, the whiteness is higher and wheat having a better color tone We have found that gluten can be obtained. The present invention has been completed by further studies based on this finding.
即ち、本発明は、下記に掲げる態様の発明を提供する。
項1. 小麦グルテンを製造する方法であって、
(i)小麦粉、(ii)カルシウム塩、及び(iii)水を混捏して生地を形成する第1工程、並びに
前記生地を水で洗滌して澱粉を洗い流し、小麦グルテンを回収する第2工程
を含むことを特徴とする、製造方法。
項2. 前記(ii)成分が、カルシウムの無機塩及び/又はカルシウムの有機酸塩である、項1に記載の製造方法。
項3. 前記(ii)成分が、塩化カルシウム、リン酸カルシウム、ヒドロキシ酸のカルシウム塩、及びモノカルボン酸のカルシウム塩よりなる群から選択される少なくとも1種である、項1又は2に記載の製造方法。
項4. 前記(ii)成分が、塩化カルシウム、リン酸三カルシウム、酢酸カルシウム、及び乳酸カルシウムよりなる群から選択される少なくとも1種である、項1~3のいずれかに記載の製造方法。
項5. 前記第1工程において、更に(iv)有機酸、リン酸、及びそれらの1価金属塩よりなる群から選択される少なくとも1種を混捏して生地を形成する、項1~4のいずれかに記載の製造方法。
項6. 前記(iv)成分が、ヒドロキシ酸、モノカルボン酸、ジカルボン酸、オルトリン酸、ポリリン酸及びそれらの1価金属塩よりなる群から選択される少なくとも1種である、項5に記載の製造方法。
項7. 前記(iv)成分が、クエン酸アルカリ金属塩、フェルラ酸、リン酸水素2アルカリ金属塩、リン酸3アルカリ金属塩、及びリン酸残基の構成数が2~23のポリリン酸のアルカリ金属塩よりなる群から選択される少なくとも1種である、項5又は6に記載の製造方法。
項8. (i)成分100重量部当たり、前記(ii)成分を0.001~10重量部混捏する、項1~7のいずれかに記載の製造方法。
項9. (i)小麦粉100重量部当たり、前記(iv)成分を0.01~10重量部混捏する、項5~8のいずれかに記載の製造方法。
項10. 項1~9のいずれかに記載の製造方法によって得られる、小麦グルテン。
That is, this invention provides the invention of the aspect hung up below.
Item 1. A method for producing wheat gluten,
(i) wheat flour, (ii) calcium salt, and (iii) a first step of kneading water to form a dough, and a second step of washing the dough with water to wash away starch and recovering wheat gluten The manufacturing method characterized by including.
Item 2. Item 2. The method according to Item 1, wherein the component (ii) is an inorganic salt of calcium and / or an organic acid salt of calcium.
Item 3. Item 3. The method according to Item 1 or 2, wherein the component (ii) is at least one selected from the group consisting of calcium chloride, calcium phosphate, calcium salt of hydroxy acid, and calcium salt of monocarboxylic acid.
Item 4. Item 4. The production method according to any one of Items 1 to 3, wherein the component (ii) is at least one selected from the group consisting of calcium chloride, tricalcium phosphate, calcium acetate, and calcium lactate.
Item 5. Item 4. The method according to any one of Items 1 to 4, wherein in the first step, (iv) at least one selected from the group consisting of an organic acid, phosphoric acid, and a monovalent metal salt thereof is mixed to form a dough. The manufacturing method as described.
Item 6. Item 6. The method according to Item 5, wherein the component (iv) is at least one selected from the group consisting of hydroxy acids, monocarboxylic acids, dicarboxylic acids, orthophosphoric acids, polyphosphoric acids, and monovalent metal salts thereof.
Item 7. The component (iv) is an alkali metal citrate, ferulic acid, dibasic metal hydrogen phosphate, trialkali metal phosphate, or an alkali metal salt of polyphosphoric acid having 2 to 23 phosphoric acid residues. Item 7. The production method according to Item 5 or 6, which is at least one selected from the group consisting of:
Item 8. Item 8. The production method according to any one of Items 1 to 7, wherein 0.001 to 10 parts by weight of the component (ii) is mixed per 100 parts by weight of the component (i).
Item 9. Item 9. The method according to any one of Items 5 to 8, wherein 0.01 to 10 parts by weight of the component (iv) is mixed per 100 parts by weight of flour.
Item 10. Item 10. Wheat gluten obtained by the production method according to any one of Items 1 to 9.
本発明によれば、小麦グルテンを製造する際に、小麦粉生地に対して、特定の添加剤を添加するとう簡便な手法によって、白色度が高い小麦グルテンを製造することが可能になる。また、本発明では、灰分が0.7重量%以上という低品質の小麦粉を原料として使用しても、白色度が高い小麦グルテンを製造できるので、原料として使用する小麦粉の品種等に制約を受けることなく、優れた色調の小麦グルテンを製造することができる。 According to the present invention, when producing wheat gluten, wheat gluten with high whiteness can be produced by a simple method of adding a specific additive to the flour dough. Further, in the present invention, even when low quality wheat flour having an ash content of 0.7% by weight or more is used as a raw material, wheat gluten having a high whiteness can be produced. Therefore, the variety of flour used as a raw material is restricted. The wheat gluten having an excellent color can be produced without any problems.
本発明の製造方法は、小麦グルテンを製造する方法であって、(i)小麦粉、(ii)カルシウム塩、及び(iii)水を混捏して生地を形成する第1工程、並びに前記生地を水で洗滌して澱粉を洗い流し、小麦グルテンを回収する第2工程を含むことを特徴とする。以下、本発明の製造方法について詳述する。 The production method of the present invention is a method for producing wheat gluten, wherein (i) wheat flour, (ii) calcium salt, and (iii) a first step of kneading water to form a dough, and said dough to water It is characterized by including a second step of washing the starch to wash away starch and recovering wheat gluten. Hereafter, the manufacturing method of this invention is explained in full detail.
第1工程
第1工程では、小麦粉(以下、(i)成分と表記することもある)、カルシウム塩(以下、(ii)成分と表記することもある)、及び(iii)水を混捏して生地を形成する。このように(i)~(iii)成分を組み合わせて小麦グルテンの製造に用いられる生地を調製することによって、白色度が高く、良好な色調の小麦グルテンを得ることが可能になる。
First Step In the first step, flour (hereinafter sometimes referred to as (i) component), calcium salt (hereinafter sometimes referred to as (ii) component), and (iii) water are mixed. Form the dough. Thus, by preparing the dough used for the production of wheat gluten by combining the components (i) to (iii), it is possible to obtain wheat gluten with high whiteness and good color.
(i)成分として使用される小麦粉の品種については、特に制限されず、白小麦、赤小麦等のいずれの品種を使用してもよいが、小麦グルテンの白色度を高めるという観点から、好ましくは白小麦が挙げられる。また、本発明では、小麦粉として、薄力粉、中力粉、強力粉等のいずれを使用してもよいが、好ましくは強力粉が挙げられる。 The variety of flour used as the component (i) is not particularly limited, and any variety such as white wheat or red wheat may be used, but from the viewpoint of increasing the whiteness of wheat gluten, preferably White wheat. Moreover, in this invention, although flour, medium strength, strong flour, etc. may be used as wheat flour, Preferably strong flour is mentioned.
(ii)成分として使用されるカルシウム塩については、食品製造に許容されるものであることを限度として特に制限されないが、水に対する溶解度か高いものが好ましく、具体的には、25℃の精製水100mLに対して、0.001g以上、好ましくは0.01g以上が溶解可能なカルシウム塩が挙げられる。 The calcium salt used as the component (ii) is not particularly limited as long as it is acceptable for food production, but preferably has a high solubility in water, specifically, purified water at 25 ° C. A calcium salt in which 0.001 g or more, preferably 0.01 g or more can be dissolved with respect to 100 mL is mentioned.
(ii)成分として使用されるカルシウム塩については、具体的には、カルシウムの無機塩、カルシウムの有機酸塩等が挙げられる。 Specific examples of the calcium salt used as the component (ii) include calcium inorganic salts and calcium organic acid salts.
カルシウムの無機塩の種類については、食品製造に許容されるものであることを限度として特に制限されないが、具体的には、塩化カルシウム、水酸化カルシウム、リン酸カルシウム等が挙げられる。これらのカルシウムの無機塩は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。これらのカルシウムの無機塩の中でも、白色度が一層高く、より良好な色調の小麦グルテンを製造するという観点から、好ましくは塩化カルシウム、リン酸カルシウム、更に好ましくは塩化カルシウムが挙げられる。 The kind of inorganic salt of calcium is not particularly limited as long as it is acceptable for food production, and specific examples include calcium chloride, calcium hydroxide, calcium phosphate and the like. These calcium inorganic salts may be used alone or in combination of two or more. Among these inorganic salts of calcium, calcium chloride, calcium phosphate, and more preferably calcium chloride are preferable from the viewpoint of producing wheat gluten having a higher whiteness and a better color tone.
カルシウムの有機酸塩の種類については、食品製造に許容されるものであることを限度として特に制限されないが、例えば、カルシウムの有機酸塩を構成する有機酸として、ヒドロキシ酸、モノカルボン酸、ジカルボン酸等が挙げられる。前記ヒドロキシ酸として、より具体的には、クエン酸、乳酸、リンゴ酸、フェルラ酸等の炭素数3~10のヒドロキシ酸が挙げられる。前記モノカルボン酸として、より具体的には、酢酸、プロピオン酸、酪酸、吉草酸、カプロン酸等の炭素数2~6のモノカルボン酸が挙げられる。また、前記ジカルボン酸として、より具体的には、シュウ酸、マロン酸、コハク酸、グルタル酸、アジピン酸等の炭素数2~6のジカルボン酸が挙げられる。これらのカルシウムの有機酸塩は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。カルシウムの有機酸塩の中でも、白色度が一層高く、より良好な色調の小麦グルテンを製造するという観点から、好ましくはヒドロキシ酸のカルシウム塩、モノカルボン酸のカルシウム塩、更に好ましくは酢酸カルシウム、乳酸カルシウムが挙げられる。 The type of organic acid salt of calcium is not particularly limited as long as it is acceptable for food production. For example, as an organic acid constituting the organic acid salt of calcium, hydroxy acid, monocarboxylic acid, dicarboxylic acid can be used. An acid etc. are mentioned. More specifically, examples of the hydroxy acid include hydroxy acids having 3 to 10 carbon atoms such as citric acid, lactic acid, malic acid, and ferulic acid. More specifically, examples of the monocarboxylic acid include monocarboxylic acids having 2 to 6 carbon atoms such as acetic acid, propionic acid, butyric acid, valeric acid, and caproic acid. More specific examples of the dicarboxylic acid include dicarboxylic acids having 2 to 6 carbon atoms such as oxalic acid, malonic acid, succinic acid, glutaric acid, and adipic acid. These organic acid salts of calcium may be used alone or in combination of two or more. Among the organic acid salts of calcium, from the viewpoint of producing wheat gluten with higher whiteness and better color tone, preferably calcium salt of hydroxy acid, calcium salt of monocarboxylic acid, more preferably calcium acetate, lactic acid Calcium is mentioned.
(ii)成分として、1種のカルシウム塩を単独で使用してもよく、また2種以上のカルシウム塩を組み合わせて使用してもよい。カルシウムの中でも、白色度が一層高く、より良好な色調の小麦グルテンを製造するという観点から、好ましくは塩化カルシウム、リン酸カルシウム、ヒドロキシ酸のカルシウム塩、モノカルボン酸のカルシウム塩;更に好ましくは塩化カルシウム、リン酸カルシウム、酢酸カルシウム、乳酸カルシウムが挙げられる。 (Ii) As the component, one kind of calcium salt may be used alone, or two or more kinds of calcium salts may be used in combination. Among calcium, from the viewpoint of producing wheat gluten having higher whiteness and a better color tone, calcium chloride, calcium phosphate, calcium salt of hydroxy acid, calcium salt of monocarboxylic acid; more preferably calcium chloride, Examples include calcium phosphate, calcium acetate, and calcium lactate.
第1工程において、生地を形成する際に添加する(ii)成分の量については、例えば、小麦粉100重量部に対して、(ii)成分が総量で0.001~10重量部、好ましくは0.001~5重量部、更に好ましくは0.001~1.5重量部となる量が挙げられる。 In the first step, the amount of component (ii) added when forming the dough is, for example, 0.001 to 10 parts by weight, preferably 0, in total of component (ii) with respect to 100 parts by weight of flour. The amount is 0.001 to 5 parts by weight, more preferably 0.001 to 1.5 parts by weight.
第1工程において、生地を形成する際に添加する水の量については、一般的な小麦グルテンの製造において採用されている範囲で適宜設定すればよいが、例えば、小麦粉100重量部に対して、水が30~200重量部、好ましくは40~150重量部、更に好ましくは50~100重量部となる量が挙げられる。 In the first step, the amount of water to be added when forming the dough may be appropriately set within the range adopted in the production of general wheat gluten, for example, for 100 parts by weight of flour, The amount of water is 30 to 200 parts by weight, preferably 40 to 150 parts by weight, more preferably 50 to 100 parts by weight.
また、第1工程において、生地を形成する際に、前記(i)~(iii)成分に加えて、有機酸、リン酸、及びそれらの1価金属塩よりなる群から選択される少なくとも1種(以下、(iv)成分と表記することもある)を添加して混捏してもよい。このように、(iv)成分を更に添加することによって、より一層白色度が高く、格段に良好な色調の小麦グルテンを製造することが可能になる。特に、前記(ii)成分として、カルシウムの無機塩を使用する場合には、(iv)成分の添加によって、得られる小麦グルテンにおいて、白色度のより効果的な向上を図り、格段に良好な色調を備えさせることが可能になる。 In the first step, when forming the dough, in addition to the components (i) to (iii), at least one selected from the group consisting of organic acids, phosphoric acids, and monovalent metal salts thereof. (Hereinafter also referred to as component (iv)) may be added and mixed. Thus, by further adding the component (iv), it becomes possible to produce wheat gluten with a much higher whiteness and a much better color tone. In particular, when an inorganic salt of calcium is used as the component (ii), the addition of the component (iv) improves the whiteness more effectively in the resulting wheat gluten, and has a much better color tone. Can be provided.
(iv)成分として使用される有機酸の種類については、食品製造に許容されるものであることを限度として特に制限されないが、例えば、ヒドロキシ酸、モノカルボン酸、ジカルボン酸等が挙げられる。ヒドロキシ酸として、より具体的には、クエン酸、乳酸、リンゴ酸、フェルラ酸等の炭素数3~10のヒドロキシ酸が挙げられる。モノカルボン酸として、より具体的には、酢酸、プロピオン酸、酪酸、吉草酸、カプロン酸等の炭素数2~6のモノカルボン酸が挙げられる。また、ジカルボン酸として、より具体的には、シュウ酸、マロン酸、コハク酸、グルタル酸、アジピン酸等の炭素数数2~6のジカルボン酸が挙げられる。これらの有機酸は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。これらの有機酸の中でも、白色度が一層高く、より良好な色調の小麦グルテンを製造するという観点から、好ましくはヒドロキシ酸、更に好ましくは炭素数3~10のヒドロキシ酸、更に好ましくはクエン酸が挙げられる。 (Iv) The type of organic acid used as component is not particularly limited as long as it is acceptable for food production, and examples thereof include hydroxy acid, monocarboxylic acid, dicarboxylic acid and the like. More specifically, examples of the hydroxy acid include hydroxy acids having 3 to 10 carbon atoms such as citric acid, lactic acid, malic acid, and ferulic acid. More specifically, examples of the monocarboxylic acid include monocarboxylic acids having 2 to 6 carbon atoms such as acetic acid, propionic acid, butyric acid, valeric acid, and caproic acid. More specific examples of the dicarboxylic acid include dicarboxylic acids having 2 to 6 carbon atoms such as oxalic acid, malonic acid, succinic acid, glutaric acid, and adipic acid. These organic acids may be used individually by 1 type, and may be used in combination of 2 or more type. Among these organic acids, from the viewpoint of producing wheat gluten having a higher whiteness and a better color tone, hydroxy acids are preferable, hydroxy acids having 3 to 10 carbon atoms are more preferable, and citric acid is more preferable. Can be mentioned.
(iv)成分として使用されるリン酸の種類については、食品製造に許容されるものであることを限度として特に制限されないが、具体的には、オルトリン酸;ピロリン酸、トリポリリン酸、テトラポリリン酸、ペンタポリリン酸、ヘキサポリリン酸等のポリリン酸等が挙げられる。これらのリン酸は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。これらのリン酸の中でも、白色度が一層高く、より良好な色調の小麦グルテンを製造するという観点から、好ましくはオルトリン酸、リン酸残基の構成数が2~23のポリリン酸;更に好ましくはオルトリン酸、ピロリン酸、トリポリリン酸が挙げられる。 (iv) The type of phosphoric acid used as the component is not particularly limited as long as it is acceptable for food production. Specifically, orthophosphoric acid; pyrophosphoric acid, tripolyphosphoric acid, tetrapolyphosphoric acid And polyphosphoric acid such as pentapolyphosphoric acid and hexapolyphosphoric acid. These phosphoric acids may be used individually by 1 type, and may be used in combination of 2 or more type. Among these phosphoric acids, from the viewpoint of producing wheat gluten with higher whiteness and better color tone, orthophosphoric acid, polyphosphoric acid having 2 to 23 constituents of phosphoric acid residues; more preferably Examples include orthophosphoric acid, pyrophosphoric acid, and tripolyphosphoric acid.
また(iv)成分として使用される有機酸及び/又はリン酸の1価金属塩としては、食品製造に許容されるものであることを限度として特に制限されないが、具体的には、前述する有機酸及び/又はリン酸のナトリウム塩、カリウム塩等のアルカリ金属塩が挙げられる。これらの1価金属塩は、1種単独で使用してもよく、また2種以上を組み合わせて使用してもよい。 The monovalent metal salt of organic acid and / or phosphoric acid used as component (iv) is not particularly limited as long as it is acceptable for food production. Examples include alkali metal salts such as sodium salt and potassium salt of acid and / or phosphoric acid. These monovalent metal salts may be used individually by 1 type, and may be used in combination of 2 or more type.
本発明では、(iv)成分として、有機酸、リン酸、及びそれらの1価金属塩の中から1種を単独で使用してもよく、またこれらの中から2種以上を組わせて使用してもよい。(iv)成分の中でも、白色度が一層高く、より良好な色調の小麦グルテンを製造するという観点から、好ましくは、ヒドロキシ酸、オルトリン酸、リン酸残基の構成数が2~23のポリリン酸、及びこれらの1価金属塩;更に好ましくはクエン酸、フェルラ酸、オルトリン酸、リン酸残基の構成数が2~23のポリリン酸、及びこれらの1価金属塩;特に好ましくはクエン酸アルカリ金属塩、フェルラ酸、リン酸水素2アルカリ金属塩、リン酸3アルカリ金属塩、リン酸残基の構成数が2~23ポリリン酸のアルカリ金属塩が挙げられる。 In the present invention, as the component (iv), one of organic acids, phosphoric acids, and monovalent metal salts thereof may be used alone, or two or more of these may be used in combination. May be. Among the components (iv), from the viewpoint of producing wheat gluten having a higher whiteness and a better color tone, polyphosphoric acid having preferably 2 to 23 constituents of hydroxy acid, orthophosphoric acid, and phosphoric acid residue is preferable. And monovalent metal salts thereof; more preferably citric acid, ferulic acid, orthophosphoric acid, polyphosphoric acid having 2 to 23 constituents of phosphoric acid residues, and monovalent metal salts thereof; particularly preferably alkali citrate Examples thereof include metal salts, ferulic acid, hydrogen phosphate dialkali metal salts, phosphoric acid trialkali metal salts, and alkali metal salts of polyphosphoric acid having 2 to 23 constituents of phosphoric acid residues.
生地を形成する際に添加する(iv)成分の量については、例えば、小麦粉100重量部に対して、(a)成分の総量で0.01~10重量部、好ましくは0.05~5重量部、更に好ましくは0.1~1.5重量部となる量が挙げられる。 Regarding the amount of component (iv) to be added when forming the dough, for example, the total amount of component (a) is 0.01 to 10 parts by weight, preferably 0.05 to 5 parts by weight per 100 parts by weight of flour. Parts, more preferably 0.1 to 1.5 parts by weight.
第1工程では、前記(i)~(iii)成分、及び必要に応じて(iv)成分を混捏することにより、ドウやバッター等と称される生地を形成する。第1工程において、生地を形成する際の混捏方法については、特に制限されず、例えば、前記(i)~(iii)成分、及び必要に応じて(iv)成分を同時に添加して混捏する方法;(i)成分と(iii)成分を一旦混捏した後に、(ii)成分及び必要に応じて使用される(iv)成分を添加して混捏する方法;前記(ii)成分と必要に応じて(iv)成分を(iii)成分に添加混合した混合液を(i)成分に添加して混捏する方法等が挙げられる。 In the first step, the ingredients (i) to (iii) and, if necessary, the ingredient (iv) are mixed to form a dough called dough or batter. In the first step, the kneading method at the time of forming the dough is not particularly limited. For example, the method of kneading by simultaneously adding the components (i) to (iii) and, if necessary, the component (iv) A method in which the component (i) and the component (iii) are once mixed and then the component (ii) and the component (iv) used as necessary are added and mixed; the component (ii) and the component as necessary Examples thereof include a method in which a mixed liquid obtained by adding (iv) the component to the (iii) component is added to the (i) component and kneaded.
また、第1工程において、生地を形成する際の混捏条件については、一般的なグルテン製造時の生地の形成に使用されている条件を採用すればよく、例えば、混捏時間としては、前記(i)~(iii)成分、及び必要に応じて(iv)成分が添加された状態で通常1~120分間、好ましくは1~60分間、更に好ましくは1~40分間が挙げられ、混捏温度としては、通常5~60℃、好ましくは5~50℃、更に好ましくは5~40℃が挙げられる。 In the first step, the kneading conditions for forming the dough may be the same as the conditions used for forming the dough at the time of general gluten production. For example, as the kneading time, (i ) To (iii) and, if necessary, the component (iv) is usually added for 1 to 120 minutes, preferably 1 to 60 minutes, more preferably 1 to 40 minutes. The temperature is usually 5 to 60 ° C., preferably 5 to 50 ° C., more preferably 5 to 40 ° C.
また、第1工程において、生地の形成に使用される混捏装置については、一般的なグルテン製造時の生地の形成に使用されている装置を使用することができる。 In the first step, as the kneading device used for forming the dough, a device used for forming the dough during general gluten production can be used.
混捏によって形成された生地は、小麦粉中に含まれる蛋白質を十分に水和膨潤させるために熟成させることが好ましい。このような熟成の方法については、一般的なグルテン製造時の生地の形成に使用されている条件で行えばよいが、具体的には、5~60℃、好ましくは5~40℃の空気中又は水中で、1~120分間、好ましくは1~60分間の熟成時間で、静置等により処理する方法が挙げられる。 The dough formed by kneading is preferably aged to sufficiently hydrate and swell the protein contained in the flour. Such a ripening method may be carried out under the conditions used for forming the dough at the time of general gluten production. Specifically, it is in the air at 5 to 60 ° C., preferably 5 to 40 ° C. Alternatively, a method of treatment by standing or the like in water for a aging time of 1 to 120 minutes, preferably 1 to 60 minutes can be mentioned.
第2工程
第2工程では、前記第1工程で得られた生地を水で洗滌して澱粉を洗い流し、小麦グルテンを回収する。
Second Step In the second step, the dough obtained in the first step is washed with water to wash away starch, and wheat gluten is recovered.
第2工程において、生地を水で洗滌して澱粉を洗い流す方法については、一般的なグルテン製造時の洗滌方法で行えばよいが、具体的には、生地に対して重量比で1~100倍、好ましくは2~50倍、更に好ましくは2~20倍の水を使用して洗滌する方法が挙げられる。 In the second step, the method of washing the dough with water to wash away the starch may be carried out by a general washing method at the time of gluten production. Specifically, the weight ratio is 1 to 100 times that of the dough. A method of washing with 2 to 50 times, more preferably 2 to 20 times, water is preferable.
生地を水で洗滌することにより、小麦グルテンは塊状の残留物として残るので、これを回収することによって、小麦グルテンが得られる。斯して得られた小麦グルテンは、生グルテンとして、そのまま食品素材として使用してもよいが、必要に応じて、気流乾燥法、噴霧乾燥法、真空乾燥法、凍結乾燥法等の乾燥方法によって乾燥させて活性グルテンにしてもよい。 By washing the dough with water, the wheat gluten remains as a lump residue. By collecting this, the wheat gluten can be obtained. The wheat gluten thus obtained may be used as raw gluten as it is as a food material, but if necessary, by a drying method such as an air drying method, a spray drying method, a vacuum drying method or a freeze drying method. It may be dried to make active gluten.
また、第2工程において、生地を洗滌してグルテンを回収した後に得られる液体分には、小麦デンプンが懸濁しているので、当該小麦デンプンを回収し、これを食品素材として提供することもできる。 In the second step, the wheat starch is suspended in the liquid obtained after washing the dough and collecting the gluten, so that the wheat starch can be collected and provided as a food material. .
第2工程で得られる小麦グルテン
斯して得られた小麦グルテンは、従来の小麦グルテンと同様に、乳化性、凝集性、吸水性、粘弾性等を備えており、様々な加工食品に配合して使用することができる。
Wheat gluten obtained in the second step The wheat gluten thus obtained has emulsifiability, cohesiveness, water absorption, viscoelasticity, etc., as in the case of conventional wheat gluten, and is incorporated into various processed foods. Can be used.
本発明で得られる小麦グルテンが添加される加工食品の種類については、特に制限されないが、例えば、小麦粉パン、米粉パン、中華饅頭等の発酵食品;スポンジケーキ、クッキー、ビスケット、キャラメル、プディング、ゼリー等の菓子類;マーガリン、マヨネーズ、ショートニング、ホイップクリーム、フラワーペースト、ドレッシング等の油脂加工食品;かまぼこ、ハム、ソーセージ等の水産・畜産加工食品;天ぷら、から揚げ、フライ食品等の揚げ物の衣;うどん、中華麺、餃子の皮、焼売の皮、春巻きの皮、焼き麩、生麩、麩饅頭等の小麦粉を主体とする生地から調製される加工食品;揚げ物の具材、中華饅頭、餃子、焼売、春巻き、サンドウィッチ等に充填される内部具材;ソース、たれ、ジャム等の調味料;加工乳、発酵乳等の乳製品;各種冷凍食品;アイスクリーム、アイスシャーベット等の冷菓等が挙げられる。本発明で得られる小麦グルテンは、白色度が高く、加熱処理に供しても色調を安定に維持できるので、白さが要求される加工食品に対して好適に使用される。このような白さが要求される加工食品としては、具体的には、うどん、中華麺などの麺類全般、小麦粉パン、米粉パン、餃子の皮、焼売の皮等が挙げられる。 The type of processed food to which the wheat gluten obtained in the present invention is added is not particularly limited. For example, fermented food such as wheat flour bread, rice flour bread, Chinese wharf; sponge cake, cookies, biscuits, caramel, pudding, jelly Processed foods such as margarine, mayonnaise, shortening, whipped cream, flower paste, dressing, etc .; processed fishery and livestock products such as kamaboko, ham, sausage; fried food such as tempura, fried food, fried food; Udon, Chinese noodles, dumpling skin, grilled skin, spring roll skin, grilled salmon, ginger, buns and other processed foods prepared from flour-based ingredients; fried food ingredients, Chinese buns, dumplings, grilled , Spring rolls, sandwiches and other internal ingredients; sauces, sauces, jams and other seasonings; processed milk, fermented milk Dairy products; various frozen food; ice cream, frozen desserts such as ice sherbet and the like. The wheat gluten obtained in the present invention has high whiteness and can be stably maintained in color tone even when subjected to heat treatment, and thus is suitably used for processed foods that require whiteness. Specific examples of processed foods that require such whiteness include noodles such as udon and Chinese noodles, wheat bread, rice flour bread, gyoza skin, and yakin skin.
以下に、実施例等を挙げて、本発明を具体的に説明するが、本発明はこれらによって何ら限定されるものではない。 Hereinafter, the present invention will be specifically described with reference to examples and the like, but the present invention is not limited thereto.
試験例1
1.小麦グルテンの製造
コントロール
小麦粉100重量部に対して25℃の水75重量部を加えて6分間ミキシングし、生地を作製した。得られた生地を、その3倍量(重量比)の25℃の水中で30分間静置後、水中で生地を練って澱粉を洗い流し、塊状の残留物を回収し、粘弾質の生グルテンを得た。これらをフリーズドライヤーで乾燥し、活性小麦グルテンを得た。得られた活性小麦グルテンにおける蛋白質含量は79重量%であった。
Test example 1
1. Production of wheat gluten
75 parts by weight of water at 25 ° C. was added to 100 parts by weight of control flour and mixed for 6 minutes to prepare a dough. The obtained dough is allowed to stand for 30 minutes in water (25% by weight) of 3 times its weight (weight ratio), then the dough is kneaded in water, the starch is washed away, the massive residue is recovered, and viscoelastic raw gluten Got. These were dried with a freeze dryer to obtain activated wheat gluten. The protein content of the obtained active wheat gluten was 79% by weight.
比較例1~9
小麦粉100重量部に対して25℃の水75重量部、表1に示す所定量の有機酸のアルカリ金属塩を加えて6分間ミキシングし、生地を作製した。得られた生地を用いて、前記コントロールと同条件で活性小麦グルテンを得た。
Comparative Examples 1-9
75 parts by weight of water at 25 ° C. and 100 parts by weight of wheat flour and a predetermined amount of an alkali metal salt of an organic acid shown in Table 1 were added and mixed for 6 minutes to prepare a dough. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
実施例1~5
小麦粉100重量部に対して25℃の水75重量部、表2に示す所定量のカルシウム塩を加えて6分間ミキシングし、生地を作製した。得られた生地を用いて、前記コントロールと同条件で活性小麦グルテンを得た。
Examples 1 to 5
75 parts by weight of water at 25 ° C. and a predetermined amount of calcium salt shown in Table 2 were added to 100 parts by weight of flour and mixed for 6 minutes to prepare a dough. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
実施例6~14
小麦粉100重量部に対して25℃の水75重量部、表2に示す所定量のカルシウム塩と、有機酸、リン酸又はその塩とを加えて6分間ミキシングし、生地を作製した。得られた生地を用いて、前記コントロールと同条件で活性小麦グルテンを得た。
Examples 6-14
A dough was prepared by adding 75 parts by weight of water at 25 ° C. and a predetermined amount of calcium salt shown in Table 2 and an organic acid, phosphoric acid or a salt thereof to 100 parts by weight of flour and mixing for 6 minutes. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
2.小麦グルテンの特性評価
得られた各活性小麦グルテンのタンパク質含量を測定した。
2. Characterization of wheat gluten The protein content of each active wheat gluten obtained was measured.
また、各活性小麦グルテン10gに対して、精製水15.5mlを添加して十分に混合して小麦グルテンドウを得た。これをナイロン製の袋(商品名「彊美人」、クリロン化成社製、80μm×150mm×250mm)に入れて、真空パックして密封し、長方形(13cm×6cm)に引き伸ばして、色差計(日本電色社製 Spectro Color Meter SE2000)にてL値(明度)(加熱前)を測定した。更に、その後、ナイロン製の袋に収容した活性小麦グルテンを90℃で50分間ボイルし、放冷後、再度、同様の方法でL値(加熱後)の測定を行った。 Further, 15.5 ml of purified water was added to 10 g of each active wheat gluten and mixed well to obtain wheat gluten dough. This is put into a nylon bag (trade name “Aoi Bijin”, manufactured by Krillon Kasei Co., Ltd., 80 μm × 150 mm × 250 mm), vacuum-packed and sealed, stretched into a rectangle (13 cm × 6 cm), and color difference meter L value (brightness) (before heating) was measured with Denki Color Spectrometer Color SE2000. Further, the activated wheat gluten contained in a nylon bag was then boiled at 90 ° C. for 50 minutes, allowed to cool, and then the L value (after heating) was measured again in the same manner.
得られた結果を表1及び2に示す。なお、L値については、コントロールの活性小麦グルテンのL値に対する差(ΔL値)を求めた値を示す。L値は、高い値を示す程、白色度が高いことを示す指標である。 The results obtained are shown in Tables 1 and 2. In addition, about the L value, the value which calculated | required the difference ((DELTA) L value) with respect to L value of the active wheat gluten of control is shown. The L value is an index indicating that the higher the value, the higher the whiteness.
表1及び2に示すように、有機酸のアルカリ金属塩を単独で添加して製造した活性小麦グルテン(比較例1~9)では、加熱後に変色が認められ、更にコントロールの活性小麦グルテンと比べて、加熱前後においてL値が殆ど変らないか、L値の低下が認められた。これに対して、カルシウム塩添加して製造した活性小麦グルテン(実施例1~14)では、加熱前後で白色度が高く、コントロール、及び有機酸のアルカリ金属塩を単独で添加して製造した場合に比べて、加熱前及び加熱後の双方においてL値が大幅に上昇していた。特に、カルシウム塩と、有機酸、ポリリン酸又はこれらのアルカリ金属塩とを組み合わせて添加して製造した小麦グルテン(実施例6~14)では、加熱前及び加熱後の双方においてL値が格段に高く、顕著に優れた白色度を備えていた。 As shown in Tables 1 and 2, in the active wheat gluten produced by adding an alkali metal salt of an organic acid alone (Comparative Examples 1 to 9), discoloration was observed after heating, and compared with the control active wheat gluten. Thus, the L value hardly changed before and after heating, or a decrease in the L value was observed. In contrast, the activated wheat gluten produced by adding calcium salt (Examples 1 to 14) has high whiteness before and after heating, and is produced by adding an alkali metal salt of organic acid and control alone. In comparison with, the L value was significantly increased both before and after heating. In particular, in wheat gluten (Examples 6 to 14) produced by adding a calcium salt and a combination of an organic acid, polyphosphoric acid or an alkali metal salt thereof, the L value is markedly before and after heating. It was high and had excellent whiteness.
試験例2
1.小麦グルテンの製造
コントロール
小麦粉100重量部に対して25℃の水75重量部を加えて6分間ミキシングし、生地を作製した。得られた生地を、その3倍量(重量比)の25℃の水中で30分間静置後、水中で生地を練って澱粉を洗い流し、塊状の残留物を回収し、粘弾質の生グルテンを得た。これらをフリーズドライヤーで乾燥し、活性小麦グルテンを得た。得られた活性小麦グルテンにおける蛋白質含量は79重量%であった。
Test example 2
1. Production of wheat gluten
75 parts by weight of water at 25 ° C. was added to 100 parts by weight of control flour and mixed for 6 minutes to prepare a dough. The obtained dough is allowed to stand for 30 minutes in water (25% by weight) of 3 times its weight (weight ratio), then the dough is kneaded in water, the starch is washed away, the massive residue is recovered, and viscoelastic raw gluten Got. These were dried with a freeze dryer to obtain activated wheat gluten. The protein content of the obtained active wheat gluten was 79% by weight.
実施例15~20
小麦粉100重量部に対して25℃の水75重量部、表3に示す所定量のポリリン酸ナトリウム(構成リン酸残基数3以上)と塩化カルシウムとを加えて6分間ミキシングし、生地を作製した。得られた生地を用いて、前記コントロールと同条件で活性小麦グルテンを得た。
Examples 15-20
100 parts by weight of flour, 75 parts by weight of water at 25 ° C., a predetermined amount of sodium polyphosphate (3 or more constituent phosphate residues) shown in Table 3 and calcium chloride are added and mixed for 6 minutes to prepare a dough did. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
実施例21~25
小麦粉100重量部に対して25℃の水75重量部、表3に示す所定量のクエン酸3ナトリウムと塩化カルシウムを加えて6分間ミキシングし、生地を作製した。得られた生地を用いて、前記コントロールと同条件で活性小麦グルテンを得た。
Examples 21-25
A dough was prepared by adding 75 parts by weight of water at 25 ° C. and predetermined amounts of trisodium citrate and calcium chloride shown in Table 3 to 100 parts by weight of flour and mixing for 6 minutes. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
2.小麦グルテンの特性評価
得られた各活性小麦グルテンについて、前記試験例1と同様の方法で、タンパク質含量、加熱前後のL値を測定した。
2. Evaluation of Wheat Gluten Characteristics Each active wheat gluten obtained was measured for protein content and L value before and after heating in the same manner as in Test Example 1.
得られた結果を表3に示す。なお、L値については、コントロールの活性小麦グルテンのL値に対する差(ΔL値)を求めた値を示す。 Table 3 shows the obtained results. In addition, about the L value, the value which calculated | required the difference ((DELTA) L value) with respect to L value of the active wheat gluten of control is shown.
表3に示すように、ポリリン酸ナトリウム又はクエン酸3ナトリウムと塩化カルシウムを添加して製造した活性小麦グルテン(実施例15~25)では、コントロールの活性小麦グルテンと比べて、加熱前後においてL値の顕著な上昇が認められた。即ち、この結果から、小麦粉100重量部に対して、ポリリン酸ナトリウム又はクエン酸3ナトリウムの添加量を0.1~1重量部に設定して、塩化カルシウムと併用することによって、格段に白色度の高い活性小麦グルテンが得られることが明らかとなった。 As shown in Table 3, the activated wheat gluten produced by adding sodium polyphosphate or trisodium citrate and calcium chloride (Examples 15 to 25) had an L value before and after heating as compared to the active wheat gluten as a control. A marked increase was observed. That is, from this result, the whiteness can be remarkably increased by setting the addition amount of sodium polyphosphate or trisodium citrate to 0.1 to 1 part by weight and using it together with calcium chloride with respect to 100 parts by weight of wheat flour. It became clear that highly active wheat gluten could be obtained.
試験例3
1.小麦グルテンの製造
コントロール
小麦粉100重量部に対して25℃の水75重量部を加えて6分間ミキシングし、生地を作製した。得られた生地を、その3倍量(重量比)の25℃の水中で30分間静置後、水中で生地を練って澱粉を洗い流し、塊状の残留物を回収し、粘弾質の生グルテンを得た。これらをフリーズドライヤーで乾燥し、活性小麦グルテンを得た。得られた活性小麦グルテンにける蛋白質含量は79重量%であった。
Test example 3
1. Production of wheat gluten
75 parts by weight of water at 25 ° C. was added to 100 parts by weight of control flour and mixed for 6 minutes to prepare a dough. The obtained dough is allowed to stand for 30 minutes in water (25% by weight) of 3 times its weight (weight ratio), then the dough is kneaded in water, the starch is washed away, the massive residue is recovered, and viscoelastic raw gluten Got. These were dried with a freeze dryer to obtain activated wheat gluten. The protein content in the obtained active wheat gluten was 79% by weight.
実施例26~32
小麦粉100重量部に対して25℃の水75重量部、表4に示す所定量のポリリン酸ナトリウム(構成リン酸残基数3以上)と塩化カルシウムとを加えて6分間ミキシングし、生地を作製した。得られた生地を用いて、前記コントロールと同条件で活性小麦グルテンを得た。
Examples 26-32
A dough is prepared by adding 75 parts by weight of water at 25 ° C. to 100 parts by weight of wheat flour, adding a predetermined amount of sodium polyphosphate (having 3 or more constituent phosphate residues) and calcium chloride as shown in Table 4, and mixing for 6 minutes. did. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
実施例33~35
小麦粉100重量部に対して25℃の水75重量部、表4に示す所定量のクエン酸3ナトリウムと塩化カルシウムを加えて6分間ミキシングし、生地を作製した。得られた生地を用いて、前記コントロールと同条件で活性小麦グルテンを得た。
Examples 33-35
To 100 parts by weight of flour, 75 parts by weight of water at 25 ° C. and predetermined amounts of trisodium citrate and calcium chloride shown in Table 4 were added and mixed for 6 minutes to prepare a dough. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
2.小麦グルテンの特性評価
得られた各活性小麦グルテンについて、前記試験例1と同様の方法で、タンパク質含量、加熱前後のL値を測定した。
2. Evaluation of Wheat Gluten Characteristics Each active wheat gluten obtained was measured for protein content and L value before and after heating in the same manner as in Test Example 1.
得られた結果を表4に示す。なお、L値については、コントロールの活性小麦グルテンのL値に対する差(ΔL値)を求めた値を示す。 Table 4 shows the obtained results. In addition, about the L value, the value which calculated | required the difference ((DELTA) L value) with respect to L value of the active wheat gluten of control is shown.
本試験結果からも、ポリリン酸ナトリウム又はクエン酸3ナトリウムと塩化カルシウムを添加して製造した活性小麦グルテン(実施例26~35)では、コントロールの活性小麦グルテンと比べて、加熱前後においてL値の顕著な上昇が認められた。また、この結果から、小麦粉100重量部に対して、塩化カルシウムの添加量を0.2重量部以上に設定して、ポリリン酸ナトリウム又はクエン酸3ナトリウムと併用することによって、格段に白色度の高い活性小麦グルテンが得られることが明らかとなった。 From the results of this test, the activated wheat gluten produced by adding sodium polyphosphate or trisodium citrate and calcium chloride (Examples 26 to 35) has an L value before and after heating as compared with the active wheat gluten as a control. A significant increase was observed. In addition, from this result, with respect to 100 parts by weight of flour, by setting the addition amount of calcium chloride to 0.2 parts by weight or more and using it together with sodium polyphosphate or trisodium citrate, It became clear that highly active wheat gluten was obtained.
試験例4
1.小麦グルテンの製造
コントロール
小麦粉100重量部に対して25℃の水75重量部を加えて6分間ミキシングし、生地を作製した。得られた生地を、その3倍量(重量比)の25℃の水中で30分間静置後、水中で生地を練って澱粉を洗い流し、塊状の残留物を回収し、粘弾質の生グルテンを得た。これらをフリーズドライヤーで乾燥し、活性小麦グルテンを得た。得られた活性小麦グルテンにける蛋白質含量は乾物重量換算で79重量%であった。
Test example 4
1. Production of wheat gluten
75 parts by weight of water at 25 ° C. was added to 100 parts by weight of control flour and mixed for 6 minutes to prepare a dough. The obtained dough is allowed to stand for 30 minutes in water (25% by weight) of 3 times its weight (weight ratio), then the dough is kneaded in water, the starch is washed away, the massive residue is recovered, and viscoelastic raw gluten Got. These were dried with a freeze dryer to obtain activated wheat gluten. The protein content of the obtained active wheat gluten was 79% by weight in terms of dry matter.
比較例12~15
小麦粉100重量部に対して25℃の水75重量部、表5に示す所定量の無機酸のアルカリ金属塩又はアルカリ土類金属の無機塩(カルシウム塩以外)を加えて6分間ミキシングし、生地を作製した。得られた生地を用いて、前記コントロールと同条件で活性小麦グルテンを得た。
Comparative Examples 12-15
Add 75 parts by weight of water at 25 ° C. to 100 parts by weight of wheat flour, add a predetermined amount of an alkali metal salt of an inorganic acid or an inorganic salt of an alkaline earth metal (other than calcium salt) as shown in Table 5 and mix for 6 minutes. Was made. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
比較例16~19
小麦粉100重量部に対して25℃の水75重量部、表1に示す所定量のクエン酸3ナトリウムと、アルカリ金属塩の無機塩又はアルカリ土類金属の無機塩(カルシウム塩以外)とを加えて6分間ミキシングし、生地を作製した。得られた生地を用いて、前記コントロールと同条件で活性小麦グルテンを得た。
Comparative Examples 16-19
Add 75 parts by weight of water at 25 ° C. to 100 parts by weight of wheat flour, a predetermined amount of trisodium citrate shown in Table 1, and an inorganic salt of an alkali metal salt or an inorganic salt of an alkaline earth metal (other than calcium salt) For 6 minutes to prepare a dough. Using the obtained dough, active wheat gluten was obtained under the same conditions as in the control.
2.小麦グルテンの特性評価
得られた各活性小麦グルテンについて、前記試験例1と同様の方法で、タンパク質含量、加熱前後のL値を測定した。
2. Evaluation of Wheat Gluten Characteristics Each active wheat gluten obtained was measured for protein content and L value before and after heating in the same manner as in Test Example 1.
得られた結果を表5に示す。なお、L値については、コントロールの活性小麦グルテンのL値に対する差(ΔL値)を求めた値を示す。 Table 5 shows the obtained results. In addition, about the L value, the value which calculated | required the difference ((DELTA) L value) with respect to the L value of the active wheat gluten of control is shown.
本試験結果から、アルカリ金属塩の無機塩又はアルカリ土類金属の無機塩(カルシウム塩以外)を単独で添加した場合(比較例10~13)、並びにクエン酸3ナトリウムとアルカリ金属塩の無機塩又はアルカリ土類金属の無機塩(カルシウム塩以外)を組み合わせて添加した場合(比較例14~17)では、加熱前後のL値が、コントロールと同等又はそれ以下になっていた。即ち、この結果から、白色度が高い小麦グルテンを製造する場合には、生地の形成において、2価金属塩の中でもカルシウム塩を選択し、これを添加することが必要になることが明らかとなった。 From this test result, when an inorganic salt of an alkali metal salt or an inorganic salt of an alkaline earth metal (other than calcium salt) is added alone (Comparative Examples 10 to 13), and an inorganic salt of trisodium citrate and an alkali metal salt Alternatively, when alkaline earth metal inorganic salts (other than calcium salts) were added in combination (Comparative Examples 14 to 17), the L value before and after heating was equal to or less than that of the control. That is, from this result, when producing wheat gluten with high whiteness, it is clear that it is necessary to select and add a calcium salt among divalent metal salts in the formation of dough. It was.
Claims (10)
(i)小麦粉、(ii)カルシウム塩、及び(iii)水を混捏して生地を形成する第1工程、並びに
前記生地を水で洗滌して澱粉を洗い流し、小麦グルテンを回収する第2工程
を含むことを特徴とする、製造方法。 A method for producing wheat gluten,
(i) wheat flour, (ii) calcium salt, and (iii) a first step of kneading water to form a dough, and a second step of washing the dough with water to wash away starch and recovering wheat gluten The manufacturing method characterized by including.
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| JP6420689B2 (en) * | 2015-02-26 | 2018-11-07 | 株式会社日清製粉グループ本社 | Method for producing cooked noodles |
| CN112244142B (en) * | 2020-10-23 | 2023-04-21 | 河南飞天生物科技股份有限公司 | Production method of nutritional gluten |
| CN115553375B (en) * | 2022-10-17 | 2024-03-01 | 江南大学 | Method for modifying wheat gluten protein by lactic acid |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018143189A (en) * | 2017-03-07 | 2018-09-20 | グリコ栄養食品株式会社 | Powdery wheat protein and method for producing the same |
| CN110325050A (en) * | 2017-03-07 | 2019-10-11 | 格力高营养食品株式会社 | Powdered wheat gluten and preparation method thereof |
| EP3593644A4 (en) * | 2017-03-07 | 2020-08-12 | Glico Nutrition Co., Ltd. | POWDERED WHEAT PROTEIN AND METHOD FOR MANUFACTURING THEREOF |
| JP7102100B2 (en) | 2017-03-07 | 2022-07-19 | グリコ栄養食品株式会社 | Powdered wheat protein and its manufacturing method |
| CN110325050B (en) * | 2017-03-07 | 2023-10-27 | 格力高营养食品株式会社 | Powdered wheat protein and preparation method thereof |
| US11952403B2 (en) | 2017-03-07 | 2024-04-09 | Glico Nutrition Co., Ltd. | Powdered wheat protein and method for producing same |
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| JP2016140331A (en) | 2016-08-08 |
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