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WO2016017563A1 - Stator for rotary electric machine, and rotary electric machine provided with same - Google Patents

Stator for rotary electric machine, and rotary electric machine provided with same Download PDF

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Publication number
WO2016017563A1
WO2016017563A1 PCT/JP2015/071188 JP2015071188W WO2016017563A1 WO 2016017563 A1 WO2016017563 A1 WO 2016017563A1 JP 2015071188 W JP2015071188 W JP 2015071188W WO 2016017563 A1 WO2016017563 A1 WO 2016017563A1
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WO
WIPO (PCT)
Prior art keywords
stator
electric machine
resin
rotating electrical
conductor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2015/071188
Other languages
French (fr)
Japanese (ja)
Inventor
孝仁 村木
本間 雅彦
孝行 小泉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Astemo Ltd
Original Assignee
Hitachi Automotive Systems Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Automotive Systems Ltd filed Critical Hitachi Automotive Systems Ltd
Publication of WO2016017563A1 publication Critical patent/WO2016017563A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02KDYNAMO-ELECTRIC MACHINES
    • H02K3/00Details of windings
    • H02K3/32Windings characterised by the shape, form or construction of the insulation
    • H02K3/34Windings characterised by the shape, form or construction of the insulation between conductors or between conductor and core, e.g. slot insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02TCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00Road transport of goods or passengers
    • Y02T10/60Other road transportation technologies with climate change mitigation effect
    • Y02T10/64Electric machine technologies in electromobility

Definitions

  • the present invention relates to a stator of a rotating electrical machine and a rotating electrical machine including the same.
  • rotating electrical machines are required to have a small size and high output.
  • a rotating electrical machine for example, a large number of conductor segments having a square cross section are inserted into the slot, and then a pair of ends of each conductor segment are joined to form a stator winding, thereby reducing the space factor. What improved the output by improving the cooling performance is known.
  • the first resin member is thinly attached to the second coil end group in which a plurality of joint portions formed by joining the first coil end group in which the turn portion is formed and the tip portion are disposed.
  • the second resin member is thickly attached only in the vicinity of the joint of the second coil end group (see, for example, Patent Document 1).
  • Patent Document 1 it is necessary to use two types of resin members, and the second resin member is thickly attached only to the vicinity of the joint portion of the second coil end group.
  • the thickness of the resin member at the coil end may be substantially uniform, and there is no necessity to increase the thickness only in the vicinity of the joint.
  • Patent Document 2 is an alternative to the second resin member (powder epoxy varnish) used in Patent Document 1 and the like, and dust is prevented by using a liquid resin at the joint. .
  • the above-mentioned problem remains because it is intended only for the joint portion and uses two types of resin members.
  • the present application includes a plurality of means for solving the above-described problems.
  • the stator coil in a stator of a rotating electric machine in which a stator coil is disposed in a slot of a stator core, the stator coil includes a plurality of means.
  • the segment conductor includes an insulating coating portion covered with an insulating coating, and a conductor exposed portion where the conductor is exposed, and is joined to another segment conductor via the conductor exposed portion.
  • the stator coil is covered with a thermosetting resin composition containing a polymerizable monomer having a boiling point of less than 200 ° C. and a thermoplastic resin soluble in the polymerizable monomer. It is characterized by that.
  • Sectional drawing which shows the whole structure of the rotary electric machine apparatus containing the stator by the Example of this invention.
  • the perspective view which shows the structure of the stator to which this invention is applied.
  • the cross-sectional perspective view which shows the welding side coil end part of the stator coil in the rotary electric machine before varnish application
  • the cross-sectional perspective view which shows the non-welding side coil end part of the stator coil in the rotary electric machine before varnish application.
  • thermosetting resin comprises (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) (A) component. It has been found that a thermosetting resin composition containing a soluble thermoplastic resin is preferable.
  • thermosetting resin composition according to the present invention will be described in detail.
  • Component (A) A polymerizable monomer having a boiling point of less than 200 ° C.
  • the polymerizable monomer is not particularly limited as long as its boiling point is less than 200 ° C., and examples thereof include alkenes such as styrene, vinyl toluene, 1-hexene, 1-octene, and vinylcyclohexane, ) (Meth) acrylic esters such as methyl acrylate and ethyl (meth) acrylate, vinyl esters such as vinyl acetate and vinyl propionate, vinyl ethers such as vinyl ethyl ether and vinyl propyl ether, 1-hexene-3
  • Examples thereof include bifunctional polymerizable monomers such as hydroxyl-containing alkenes such as all, hydroxyethyl (meth) acrylate, and ethylene glucoglycol vinyl ether, (meth) acrylic acids, and divinylbenzene.
  • styrene and vinyltoluenes are preferable from the viewpoints of solubility of the thermoplastic resin and other components, heat resistance of the cured resin, and insulation.
  • thermoplastic resin soluble in component (A) is not particularly limited.
  • Polyalkenes such as polystyrene, polyvinyltoluene, polyvinylnaphthalene, polyhexene, poly (meth) acrylate, poly (meth) acrylic acid
  • Poly (meth) acrylates such as ethyl, poly (meth) acrylate hydroxyethyl, polyvinyl esters such as polyvinyl acetate and vinyl polypropionate
  • polyvinyl ethers such as polyvinyl ethyl ether and polyvinyl propyl ether
  • polyethylene examples include glycols and polyethylene glycols such as polyethylene glycol dimethyl ether and polyethylene oxide.
  • thermoplastic resins are not particularly limited, but the number average molecular weight is preferably in the range of 5,000 to 1,000,000 from the viewpoints of coatability and solubility. Furthermore, a number average molecular weight in the range of 10,000 to 500,000 is more preferable. When the number average molecular weight is less than 5,000, the covering property is lowered, and when the number average molecular weight is more than 1,000,000, the solubility in the thermosetting resin composition is lowered.
  • thermosetting resin The constituent components of the thermosetting resin are not particularly limited, but it is preferable that (C) a vinyl ester resin and (D) a radical polymerization initiator be included.
  • (C) component] (C) vinyl ester resin The vinyl ester resin is not particularly limited as long as it can be obtained, for example, by reacting an epoxy compound and an unsaturated monobasic acid using an esterification catalyst.
  • the epoxy compound used as a raw material for the vinyl ester resin is a compound having at least two epoxy groups in the molecule and is not particularly limited. Specifically, for example, bisphenol A, bisphenol F, and the like. Epibis-type glycidyl ether type epoxy resin obtained by condensation reaction of bisphenols such as bisphenol S and epihalohydrin; Novolac type glycidyl ether type epoxy resin obtained; tetrahydrophthalic acid, glycidyl ester type epoxy resin obtained by condensation reaction of hexahydrophthalic acid and epihalohydrin, 4,4'-biphenol Glycidyl ether type epoxy resin obtained by condensation reaction of 2,6-naphthalenediol, hydrogenated bisphenol or glycol and epihalohydrin; amine-containing glycidyl ether type epoxy resin obtained by condensation reaction of hydantoin or cyanuric acid and epihalohydrin, etc. Can be mentioned. Only one kind of these epoxy compounds may be used, or two or more
  • the unsaturated monobasic acid used as a raw material for the vinyl ester resin is not particularly limited, and specific examples include acrylic acid, methacrylic acid, and crotonic acid. Moreover, you may use half esters, such as maleic acid and itaconic acid. These unsaturated monobasic acids may be used alone or in a suitable mixture of two or more. Among these compounds, vinyl ester resins obtained by reacting an epibis type glycidyl ether type epoxy resin and methacrylic acid are preferable from the viewpoint of heat resistance and curability.
  • radical polymerization initiator is not particularly limited, and examples thereof include organic peroxides, organic azo compounds, and alkylboranes.
  • organic peroxides examples include benzoyl peroxide, lauroyl peroxide, t-butyl peroxide benzoate, t-amyl peroxide, t-amyl peroxyneodecanoate, and t-butyl peroxyneodecanoate.
  • T-amyl peroxyisobutyrate di-t-butyl peroxide, dicumyl peroxide, cumene hydroperoxide, 1,1-di (t-butylperoxy) cyclohexane, 2,2-di (t-butyl) Peroxy) butane, t-butyl hydroperoxide, di (s-butyl) peroxycarbonate, methyl ethyl ketone peroxide, etc., but are not particularly limited, and these may be used alone or in combination of two or more. May be.
  • organic azo compounds examples include 2,2′-azobis (isobutyronitrile), 1,1′-azobis (cyclohexanecarbonitrile), 4,4′-azobis (4-cyanovaleric acid), 2,2 'Azobis (2-methylpropionamidine) dihydrochloride and the like. These may be used alone or in combination of two or more.
  • alkylborane examples include triethylborane, tripropylborane, triisopropylborane, tri-n-butylborane, tri-n-amylborane, tri-n-hexylborane, tricyclohexylborane, and 9-borabicyclo [3.3.1] nonane.
  • Isopinocan phenylborane diethylmethylborane, diethylpropylborane, diethylbutylborane, ethylpropylbutylborane and the like.
  • examples of the boron compound oxide obtained by partially oxidizing these include diethylethoxyborane, dibutylbutoxyborane, diethylmethoxyborane, ethyldimethoxyborane, ethyldiethoxyborane, and ethylethoxymethoxyborane. These may be used alone or in combination of two or more.
  • organic peroxides organic azo compounds, and alkylboranes may be used alone or in combination of two or more.
  • thermosetting resin composition of this invention You may add another arbitrary component to the thermosetting resin composition of this invention as needed.
  • optional components include unsaturated polyester resins, curing accelerators, polymerization inhibitors, and adhesive strength improvers.
  • the unsaturated polyester resin is not particularly limited, and can be obtained, for example, by subjecting a dibasic acid and a polyhydric alcohol to a condensation reaction.
  • dibasic acid used as a raw material for the unsaturated polyester resin include ⁇ , ⁇ -unsaturated dibasic acids such as maleic acid, maleic anhydride, fumaric acid, itaconic acid, and itaconic anhydride.
  • polyhydric alcohol used as the raw material for the unsaturated polyester resin include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, and 2-methyl-1 , 3-propanediol, 1,3-butanediol, adducts of bisphenol A and propylene oxide or ethylene oxide, glycerin, trimethylolpropane, 1,3-propanediol, 1,2-cyclohexane glycol, 1,3-cyclohexane Glycol, 1,4-cyclohexane glycol, para-xylene glycol, bicyclohexyl-4,4′-diol, 2,6-decalin glycol, tris (2-hydroxyethyl) Le)
  • isocyanurate but is not particularly limited.
  • amino alcohols such as ethanolamine may be used. Only one kind of these polyhydric alcohols may be used,
  • curing accelerator examples include metal salts of naphthenic acid or octylic acid (metal salts of cobalt, zinc, zirconium, manganese, calcium, etc.). These may be used alone or in combination of two or more. May be.
  • polymerization inhibitor examples include quinones such as hydroquinone, paratertiary butyl catechol, and pyrogallol, and these may be used alone or in combination of two or more.
  • Examples of the adhesive strength improver include p-styryltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-methacryloxypropyltriethoxysilane, etc. These may be used alone or as appropriate. The above may be mixed.
  • thermoplastic resin composition of the present invention As a method for producing the thermoplastic resin composition of the present invention, first, (A) a polymerizable monomer having a boiling point of less than 200 ° C., (B) a thermoplastic resin soluble in component (A), (C) The vinyl ester resin, (D) radical polymerization initiator, and other optional components are uniformly stirred and mixed in the air to obtain a resin composition.
  • thermosetting resin composition of the present invention can be used for insulating and fixing the stator winding of a rotating electric machine.
  • axial direction refers to a direction along the rotation axis of the rotating electrical machine.
  • the circumferential direction refers to the direction along the rotational direction of the rotating electrical machine.
  • the “radial direction” refers to a radial direction (radial direction) when the rotational axis of the rotating electrical machine is the center.
  • Inner circumference side refers to the radially inner side (inner diameter side)
  • outer circumference side refers to the opposite direction, that is, the radially outer side (outer diameter side).
  • FIG. 1 is a cross-sectional view showing a rotating electrical machine having a stator according to the present invention.
  • the rotating electrical machine 10 includes a housing 50, a stator 20, a stator core 21, a stator coil 60, and a rotor 11.
  • the stator 20 is fixed to the inner peripheral side of the housing 50.
  • the rotor 11 is rotatably supported on the inner peripheral side of the stator 20.
  • the housing 50 constitutes an outer casing of an electric motor that is formed into a cylindrical shape by cutting an iron-based material such as carbon steel, casting of cast steel or aluminum alloy, or pressing.
  • the housing 50 is also referred to as a frame or a frame.
  • a liquid cooling jacket 130 is fixed to the outer peripheral side of the housing 50.
  • the inner peripheral wall of the liquid cooling jacket 130 and the outer peripheral wall of the housing 50 constitute a refrigerant passage 153 for a liquid refrigerant RF such as oil, and the refrigerant passage 153 is formed so as not to leak.
  • the liquid cooling jacket 130 houses the bearings 144 and 145 and is also called a bearing bracket.
  • the refrigerant RF flows through the refrigerant passage 153 and flows out of the refrigerant outlets 154 and 155 toward the stator 20 to cool the stator 20.
  • the stator 20 is composed of a stator core 21 and a stator coil 60.
  • the stator core 21 is made by laminating thin sheets of silicon steel plates.
  • the stator coil 60 is wound around a plurality of slots 15 provided in the inner peripheral portion of the stator core 21. Heat generated from the stator coil 60 is transferred to the liquid cooling jacket 130 via the stator core 21 and is radiated by the refrigerant RF flowing through the liquid cooling jacket 130.
  • the rotor 11 is composed of a rotor core 12 and a rotating shaft 13.
  • the rotor core 12 is made by laminating thin sheets of silicon steel plates.
  • the rotating shaft 13 is fixed to the center of the rotor core 12.
  • the rotating shaft 13 is rotatably held by bearings 144 and 145 attached to the liquid cooling jacket 130 and rotates at a predetermined position in the stator 20 at a position facing the stator 20.
  • the rotor 11 is provided with a permanent magnet 18 and an end ring (not shown).
  • the stator 20 is inserted into the housing 50 in advance and attached to the inner peripheral wall of the housing 50, and then the rotor 11 is inserted into the stator 20.
  • the rotating shaft 13 is assembled to the liquid cooling jacket 130 so that the bearings 144 and 145 are fitted.
  • the stator 20 includes a stator core 21 and a stator coil 60 wound around a plurality of slots 15 provided on the inner peripheral portion of the stator core.
  • the stator coil 60 uses a conductor (copper wire in this embodiment) having a substantially rectangular cross section to improve the space factor in the slot, thereby improving the efficiency of the rotating electrical machine.
  • a slot liner 302 is disposed in each slot 15 to ensure electrical insulation between the stator core 21 and the stator coil 60.
  • the slot liner 302 is formed into a B shape or an S shape so as to wrap a copper wire.
  • the stator 20 includes a stator core 21 and a stator coil 60 wound around a plurality of slots 15 provided on the inner peripheral portion of the stator core.
  • the stator coil 60 uses a coil having a substantially rectangular cross section, improves the space factor in the slot, and improves the efficiency of the rotating electrical machine.
  • Insulating paper 300 is annularly arranged for insulation between the coils.
  • Insulating paper 301 is annularly arranged for insulation between the welds.
  • the entire stator coil is composed of (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) a thermoplastic resin soluble in component (A). Cover substantially uniformly only with the cured product 601.
  • the stator 20 includes a stator core 21 and a stator coil 60 wound around a plurality of slots 15 provided on the inner peripheral portion of the stator core.
  • the stator coil 60 uses a coil having a substantially rectangular cross section, thereby improving the space factor in the slot and improving the efficiency of the rotating electrical machine.
  • Insulating paper 301 is annularly arranged for insulation between the coils.
  • the anti-welding side coil end 61 also covers the entire stator coil almost uniformly with only the cured product of the resin composition 601 after the insulating paper is disposed.
  • the resin composition 601 is the same material that covers the welding side coil end 62 ((A) a polymerizable monomer having a boiling point of less than 200 ° C., and (B) a thermoplastic resin that is soluble in the component (A). Resin composition).
  • FIG. 5 is an enlarged view of the vicinity of the conductor end portion 28E of the welding side coil end 62.
  • the segment conductor 28 is an exposed conductor in which the insulating coating 29A (the portion shown by shading in FIG. 7) covered with an insulating coating such as an enamel coating and the conductive coating (copper wire) are exposed by peeling off the insulating coating. Part 29B.
  • the conductor exposed portion 29B is provided at the conductor end portion 28E. This conductor portion is exposed for welding.
  • the entire segment conductor 28 including the insulating coating portion 29A and the exposed conductor portion 29B is composed of (A) a polymerizable monomer having a boiling point of less than 200 ° C., and (B) a thermoplastic that is soluble in the component (A). It is almost uniformly covered only with a cured product of the resin composition 601 made of resin. Since the second resin member used in the prior art is not used and the thickness is uniform, a double production facility is not required for adhesion and drying of the resin member, and the resin member necessary for insulation withstand voltage There is an effect that the above materials are unnecessary.
  • FIG. 6 is an enlarged view of the vicinity of the anti-welding side coil end apex 28 ⁇ / b> C of the anti-welding side coil end 61.
  • an insulation coating portion 29 ⁇ / b> A is formed over the entire circumference of the segment conductor 28.
  • the segment conductor 28 includes a resin 601 made of (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) a thermoplastic resin soluble in the component (A) so as to cover the insulating coating portion 29A. It is almost uniformly covered only with the cured product. Since the second resin member used in the prior art is not used and the thickness is uniform, a double production facility is not required for adhesion and drying of the resin member, and the resin member necessary for insulation withstand voltage There is an effect that the above materials are unnecessary.
  • the entire stator coil is substantially uniform only with the resin 601 made of (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) a thermoplastic resin soluble in the component (A). Further, by disposing the annular insulating resins 300 and 301 for reinforcing the insulation, it is possible to obtain a rotating electrical machine that satisfies the insulating properties required for electric vehicles and hybrid electric vehicles.
  • the resin used for forming the insulating coating was an unsaturated polyester resin from the viewpoints of cost and insulation, permeability and curability.
  • unsaturated polyester resin both a solvent type in which the resin is diluted with a solvent and a solventless type in which the resin is not diluted with a solvent can be used. Saturated polyester resins are more preferable, and non-styrene unsaturated polyester resins are more preferable in order to prevent deterioration of characteristics due to component volatilization during curing.
  • the resin composition 601 is desirably covered almost uniformly, the boundary surface with the insulating paper 300 and 301 and the complicated shape part of the coil may adhere unevenly.
  • substantially uniform as used herein means that the thickness is not intentionally increased as in the prior art (for example, Patent Document 1).
  • the rotor is not a permanent magnet type, but an induction type, synchronous reluctance, It can be applied to a claw magnetic pole type.
  • the winding method is a wave winding method, but any winding method having similar characteristics can be applied.
  • thermosetting resin composed of (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) a thermoplastic resin soluble in the component (A) will be described. It is not limited by these composition examples.
  • composition Example 1 50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 10 parts by weight of polystyrene having a number average molecular weight of 14,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butylperoxy) cyclohexane 1.5 parts by weight (manufactured by NOF) is added to obtain a thermosetting resin composition.
  • composition Example 2 50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polystyrene having a number average molecular weight of 48,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butylperoxy) cyclohexane 1.5 parts by weight (manufactured by NOF) is added to obtain a thermosetting resin composition.
  • thermosetting resin composition 50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polymethyl methacrylate having a number average molecular weight of 58,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butyl par Oxy) 1.5 parts by weight of cyclohexane (manufactured by NOF) is added to obtain a thermosetting resin composition.
  • thermosetting resin composition 50 parts by weight of methyl methacrylate (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polystyrene having a number average molecular weight of 48,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butylperoxy) ) 1.5 parts by weight of cyclohexane (manufactured by NOF) is added to obtain a thermosetting resin composition.
  • composition Example 5 50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polystyrene having a number average molecular weight of 48,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1.0 part by weight of diethylmethoxyborane (manufactured by Aldrich) In addition, a thermosetting resin composition is obtained.
  • composition Example 6 50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polystyrene having a number average molecular weight of 48,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butylperoxy) cyclohexane 1.5 parts by weight (manufactured by NOF), 0.05 parts by weight of manganese naphthenate (manufactured by Tokyo Chemical Industry), 5 parts by weight of unsaturated polyester resin consisting of isophthalic acid, maleic acid and ethylene glycol, 3-methacryloxypropyltrimethoxy 0.1 part by weight of silane (manufactured by Shin-Etsu Silicone) is added to obtain a thermosetting resin composition.
  • the resin composition 601 is impregnated in an electric device such as a motor coil by using this composition by dipping, dripping or the like.
  • the impregnation method is a conventional method and is not particularly limited.
  • the resin composition 601 applied to the stator 20 is completely cured by heating after drying at room temperature until the resin fluidity is no longer observed.
  • Room temperature drying is a conventional method such as standing or under ventilation, and is not particularly limited.
  • the main heating is performed by a conventional method such as a hot air heating furnace or an IH heating furnace, and there is no particular limitation.
  • this invention is not limited to the above-mentioned Example, Various modifications are included.
  • the above-described embodiments have been described in detail for easy understanding of the present invention, and are not necessarily limited to those having all the configurations described.

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  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Insulation, Fastening Of Motor, Generator Windings (AREA)

Abstract

Provided are a stator for a rotary electric machine, said stator having excellent insulation properties, and a rotary electric machine provided with said stator. In order to solve this problem, the present invention provides a stator 20 for a rotary electric machine, said stator having a stator coil 60 that is disposed in a slot 15 of a stator iron core 21 and being configured such that: the stator coil is composed of a plurality of segment conductors; the segment conductors have an insulation-coated portion that is covered with an insulation coating, and an exposed conductor portion in which a conductor is exposed, and are joined to the other segment conductors via the exposed conductor portion; and the stator coil is covered with a thermosetting resin composition including a polymerizable monomer that has a boiling point of less than 200 °C, and a thermoplastic resin that is soluble in the polymerizable monomer.

Description

回転電機の固定子、およびこれを備えた回転電機Rotating electric machine stator and rotating electric machine equipped with the same

 本発明は、回転電機の固定子、およびこれを備えた回転電機に関する。 The present invention relates to a stator of a rotating electrical machine and a rotating electrical machine including the same.

 近年、回転電機は小型高出力が求められている。このような回転電機として、例えば断面角型の多数の導体セグメントをスロットに挿通してから、各導体セグメントの端部を一対ずつ接合して固定子巻線を形成することで、占積率を向上させて冷却性能を向上させることにより高出力化を図ったものが知られている。 In recent years, rotating electrical machines are required to have a small size and high output. As such a rotating electrical machine, for example, a large number of conductor segments having a square cross section are inserted into the slot, and then a pair of ends of each conductor segment are joined to form a stator winding, thereby reducing the space factor. What improved the output by improving the cooling performance is known.

 そして、絶縁性能向上のため、ターン部が形成された第1コイルエンド群と先端部を接合してなる複数の接合部が配置された第2のコイルエンド群に、薄く第1樹脂部材を付着させ、第2コイルエンド群の接合部近傍のみに厚く第2樹脂部材が付着された車輌用交流発電機の固定子がある(例えば、特許文献1参照)。 Then, in order to improve the insulation performance, the first resin member is thinly attached to the second coil end group in which a plurality of joint portions formed by joining the first coil end group in which the turn portion is formed and the tip portion are disposed. In addition, there is a vehicle alternator stator in which the second resin member is thickly attached only in the vicinity of the joint of the second coil end group (see, for example, Patent Document 1).

 また、接合部に用いる第2樹脂部材の材料を規定した電気機器もある(例えば、特許文献2参照)。 There is also an electrical device that defines the material of the second resin member used for the joint (see, for example, Patent Document 2).

特許第3770263号公報Japanese Patent No. 3770263 特開2012-90433号公報JP 2012-90433 A

 特許文献1の技術では、2種類の樹脂部材を用いる必要があり、また、第2コイルエンド群の接合部近傍のみに厚く第2樹脂部材を付着させている。絶縁設計上は、コイルエンドの樹脂部材の厚さはほぼ均一で良く、接合部近傍のみ厚くする必然性は無い。2種類の樹脂部材を用いることで、樹脂部材の付着、硬化のため2重の生産設備が必要となり、また、接合部のみ厚くする事により絶縁耐圧上必要な樹脂部材以上に材料が必要となるといった課題があった。 In the technique of Patent Document 1, it is necessary to use two types of resin members, and the second resin member is thickly attached only to the vicinity of the joint portion of the second coil end group. In the insulation design, the thickness of the resin member at the coil end may be substantially uniform, and there is no necessity to increase the thickness only in the vicinity of the joint. By using two types of resin members, double production facilities are required for adhesion and curing of the resin members, and more material is required than the resin members required for dielectric strength by increasing the thickness of only the joints. There was a problem.

 特許文献2の技術は、特許文献1などで用いられている第2の樹脂部材(粉体エポキシ系ワニス)の代替となるもので、接合部に液状樹脂を用いることで粉塵を防止している。しかし、接合部のみを対象としており、また、2種類の樹脂部材を用いることが前提となっていることから、上記の課題は残されている。 The technology of Patent Document 2 is an alternative to the second resin member (powder epoxy varnish) used in Patent Document 1 and the like, and dust is prevented by using a liquid resin at the joint. . However, the above-mentioned problem remains because it is intended only for the joint portion and uses two types of resin members.

 上記課題を解決するために、例えば請求の範囲に記載の構成を採用する。 
 本願は上記課題を解決する手段を複数含んでいるが、その一例を挙げるならば、固定子コイルが固定子鉄心のスロットに配置された回転電機の固定子において、前記固定子コイルは、複数のセグメント導体から構成され、前記セグメント導体は、絶縁被覆で覆われた絶縁被覆部と、導体が露出した導体露出部とを有し、かつ、他のセグメント導体と前記導体露出部を介して接合されており、前記固定子コイルが、沸点が200℃未満の重合性単量体と、前記重合性単量体に可溶な熱可塑性樹脂と、を含む熱硬化性樹脂組成物で覆われていることを特徴とする。
In order to solve the above problems, for example, the configuration described in the claims is adopted.
The present application includes a plurality of means for solving the above-described problems. For example, in a stator of a rotating electric machine in which a stator coil is disposed in a slot of a stator core, the stator coil includes a plurality of means. The segment conductor includes an insulating coating portion covered with an insulating coating, and a conductor exposed portion where the conductor is exposed, and is joined to another segment conductor via the conductor exposed portion. The stator coil is covered with a thermosetting resin composition containing a polymerizable monomer having a boiling point of less than 200 ° C. and a thermoplastic resin soluble in the polymerizable monomer. It is characterized by that.

 本発明によれば、絶縁性の優れた回転電機の固定子、およびこれを備えた回転電機を提供することができる。 According to the present invention, it is possible to provide a stator of a rotating electrical machine having excellent insulation and a rotating electrical machine including the stator.

 上記した以外の課題、構成及び効果は、以下の実施例の説明により明らかにされる。 Issues, configurations, and effects other than those described above will be clarified by the description of the following examples.

本発明の実施例による固定子を含む回転電機装置の全体構成を示す断面図。Sectional drawing which shows the whole structure of the rotary electric machine apparatus containing the stator by the Example of this invention. 本発明が適用される固定子の構成を示す斜視図。The perspective view which shows the structure of the stator to which this invention is applied. ワニス塗布前の回転電機における固定子コイルの溶接側コイルエンド部を示す断面斜視図。The cross-sectional perspective view which shows the welding side coil end part of the stator coil in the rotary electric machine before varnish application | coating. ワニス塗布前の回転電機における固定子コイルの反溶接側コイルエンド部を示す断面斜視図。The cross-sectional perspective view which shows the non-welding side coil end part of the stator coil in the rotary electric machine before varnish application. 固定子コイルの溶接側コイルエンド部の平面図。The top view of the welding side coil end part of a stator coil. 固定子コイルの反溶接側コイルエンド部の平面図。The top view of the non-welding side coil end part of a stator coil.

 本発明者らは、前述の課題を解決するため鋭意研究を重ねた結果、熱硬化性樹脂は、(A)沸点が200℃未満の重合性単量体と、(B)(A)成分に可溶な熱可塑性樹脂を含む熱硬化性樹脂組成物が好ましいことを見出した。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that the thermosetting resin comprises (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) (A) component. It has been found that a thermosetting resin composition containing a soluble thermoplastic resin is preferable.

 以下、本発明に係る熱硬化性樹脂組成物を詳細に説明する。 Hereinafter, the thermosetting resin composition according to the present invention will be described in detail.

 [(A)成分]沸点が200℃未満の重合性単量体 
 上記重合性単量体は、その沸点が200℃未満であれば、特に限定されるものではなく、例えば、スチレン、ビニルトルエン、1-ヘキセン、1-オクテン、ビニルシクロヘキサン等のアルケン類、(メタ)アクリル酸メチル、(メタ)アクリル酸エチル等の(メタ)アクリル酸エステル類、酢酸ビニル、プロピオン酸ビニル等のビニルエステル類、ビニルエチルエーテル、ビニルプロピルエーテル等のビニルエーテル類、1-ヘキセン-3オール、(メタ)アクリル酸ヒドロキシエチル、エチレングルコグリコールビニルエーテル等の、水酸基含有アルケンや(メタ)アクリル酸類、ジビニルベンゼン等の、二官能重合性単量体などがある。これら化合物は、一種類のみを用いてもよく、適宜二種類以上を混合して用いてもよい。これら化合物の中でも、熱可塑性樹脂やその他成分の溶解性、硬化樹脂の耐熱性、絶縁性の観点から、スチレンやビニルトルエン類が好ましい。
[Component (A)] A polymerizable monomer having a boiling point of less than 200 ° C.
The polymerizable monomer is not particularly limited as long as its boiling point is less than 200 ° C., and examples thereof include alkenes such as styrene, vinyl toluene, 1-hexene, 1-octene, and vinylcyclohexane, ) (Meth) acrylic esters such as methyl acrylate and ethyl (meth) acrylate, vinyl esters such as vinyl acetate and vinyl propionate, vinyl ethers such as vinyl ethyl ether and vinyl propyl ether, 1-hexene-3 Examples thereof include bifunctional polymerizable monomers such as hydroxyl-containing alkenes such as all, hydroxyethyl (meth) acrylate, and ethylene glucoglycol vinyl ether, (meth) acrylic acids, and divinylbenzene. Only one kind of these compounds may be used, or two or more kinds may be appropriately mixed and used. Among these compounds, styrene and vinyltoluenes are preferable from the viewpoints of solubility of the thermoplastic resin and other components, heat resistance of the cured resin, and insulation.

 [(B)成分](A)成分に可溶な熱可塑性樹脂を含む熱硬化性樹脂組成物 
 上記(A)成分に可溶な熱可塑性樹脂は、特に限定されるものではなく、ポリスチレン、ポリビニルトルエン、ポリビニルナフタレン、ポリヘキセン等のポリアルケン類、ポリ(メタ)アクリル酸メチル、ポリ(メタ)アクリル酸エチル、ポリ(メタ)アクリル酸ヒドロキシエチル、等のポリ(メタ)アクリル酸エステル類、ポリ酢酸ビニル、ポリプロピオン酸ビニル等のポリビニルエステル類、ポリビニルエチルエーテル、ポリビニルプロピルエーテル等のポリビニルエーテル類、ポリエチレングリコールや、ポリエチレングリコールジメチルエーテル、ポリエチレンオキシド等のポリエチレングリコール類等がある。これら化合物は、一種類のみを用いてもよく、適宜二種類以上を混合して用いてもよい。これら化合物の中でも(A)成分への溶解性や耐熱性、絶縁性の観点から、ポリスチレン、ポリビニルトルエン類やポリ(メタ)アクリル酸メチルなどのポリ(メタ)アクリル酸エステル類が好ましい。また、これら熱可塑性樹脂の分子量は、特に制限されるものではないが、被覆性および溶解性の観点から、数平均分子量5,000から1,000,000の範囲が好ましい。更に、数平均分子量10,000から500,000の範囲がより好ましい。数平均分子量が、5,000より小さいと被覆性が低下し、数平均分子量が1,000,000より大きいと、熱硬化性樹脂組成物への溶解性が低下する。
[Component (B)] Thermosetting resin composition containing thermoplastic resin soluble in component (A)
The thermoplastic resin soluble in the component (A) is not particularly limited. Polyalkenes such as polystyrene, polyvinyltoluene, polyvinylnaphthalene, polyhexene, poly (meth) acrylate, poly (meth) acrylic acid Poly (meth) acrylates such as ethyl, poly (meth) acrylate hydroxyethyl, polyvinyl esters such as polyvinyl acetate and vinyl polypropionate, polyvinyl ethers such as polyvinyl ethyl ether and polyvinyl propyl ether, polyethylene Examples include glycols and polyethylene glycols such as polyethylene glycol dimethyl ether and polyethylene oxide. Only one kind of these compounds may be used, or two or more kinds may be appropriately mixed and used. Among these compounds, from the viewpoints of solubility in the component (A), heat resistance, and insulation, poly (meth) acrylates such as polystyrene, polyvinyltoluenes and poly (meth) methyl acrylate are preferable. Further, the molecular weight of these thermoplastic resins is not particularly limited, but the number average molecular weight is preferably in the range of 5,000 to 1,000,000 from the viewpoints of coatability and solubility. Furthermore, a number average molecular weight in the range of 10,000 to 500,000 is more preferable. When the number average molecular weight is less than 5,000, the covering property is lowered, and when the number average molecular weight is more than 1,000,000, the solubility in the thermosetting resin composition is lowered.

 また、熱硬化性樹脂の構成成分は、特に限定されるものではないが、(C)ビニルエステル樹脂、(D)ラジカル重合開始剤を含むことが好ましい。 The constituent components of the thermosetting resin are not particularly limited, but it is preferable that (C) a vinyl ester resin and (D) a radical polymerization initiator be included.

 [(C)成分](C)ビニルエステル樹脂 
 ビニルエステル樹脂については、特に限定されるものではなく、例えば、エポキシ化合物と不飽和一塩基酸とをエステル化触媒を用いて反応させることによって得ることができるものであればよい。
[(C) component] (C) vinyl ester resin
The vinyl ester resin is not particularly limited as long as it can be obtained, for example, by reacting an epoxy compound and an unsaturated monobasic acid using an esterification catalyst.

 上記ビニルエステル樹脂の原料として用いられるエポキシ化合物としては、分子中に、少なくとも2個のエポキシ基を有する化合物で、特に限定されるものではないが、具体的には、例えば、ビスフェノールA、ビスフェノールF、ビスフェノールS等のビスフェノール類とエピハロヒドリンとの縮合反応により得られるエピビスタイプグリシジルエーテル型エポキシ樹脂;フェノール、クレゾール、ビスフェノール等のフェノール類とホルマリンとの縮合物であるノボラックとエピハロヒドリンとの縮合反応により得られるノボラックタイプグリシジルエーテル型エポキシ樹脂;テトラヒドロフタル酸、ヘキサヒドロフタル酸とエピハロヒドリンとの縮合反応により得られるグリシジルエステル型エポキシ樹脂、4,4´-ビフェノール、2,6-ナフタレンジオール、水添ビスフェノールやグリコール類とエピハロヒドリンとの縮合反応により得られるグリシジルエーテル型エポキシ樹脂;ヒダントインやシアヌール酸とエピハロヒドリンとの縮合反応により得られる含アミングリシジルエーテル型エポキシ樹脂等が挙げられる。これらエポキシ化合物は、一種類のみを用いてもよく、適宜二種類以上を混合して用いてもよい。 The epoxy compound used as a raw material for the vinyl ester resin is a compound having at least two epoxy groups in the molecule and is not particularly limited. Specifically, for example, bisphenol A, bisphenol F, and the like. Epibis-type glycidyl ether type epoxy resin obtained by condensation reaction of bisphenols such as bisphenol S and epihalohydrin; Novolac type glycidyl ether type epoxy resin obtained; tetrahydrophthalic acid, glycidyl ester type epoxy resin obtained by condensation reaction of hexahydrophthalic acid and epihalohydrin, 4,4'-biphenol Glycidyl ether type epoxy resin obtained by condensation reaction of 2,6-naphthalenediol, hydrogenated bisphenol or glycol and epihalohydrin; amine-containing glycidyl ether type epoxy resin obtained by condensation reaction of hydantoin or cyanuric acid and epihalohydrin, etc. Can be mentioned. Only one kind of these epoxy compounds may be used, or two or more kinds may be appropriately mixed and used.

 上記ビニルエステル樹脂の原料として用いられる不飽和一塩基酸としては、特に限定されるものではないが、具体的には、例えば、アクリル酸、メタアクリル酸、クロトン酸等が挙げられる。また、マレイン酸、イタコン酸等のハーフエステル等を用いてもよい。これら不飽和一塩基酸は、一種類のみを用いてもよく、適宜二種類以上を混合して用いてもよい。これら化合物の中でも、耐熱性や硬化性の観点から、エピビスタイプグリシジルエーテル型エポキシ樹脂とメタクリル酸を反応させて得られるビニルエステル樹脂が好ましい。 The unsaturated monobasic acid used as a raw material for the vinyl ester resin is not particularly limited, and specific examples include acrylic acid, methacrylic acid, and crotonic acid. Moreover, you may use half esters, such as maleic acid and itaconic acid. These unsaturated monobasic acids may be used alone or in a suitable mixture of two or more. Among these compounds, vinyl ester resins obtained by reacting an epibis type glycidyl ether type epoxy resin and methacrylic acid are preferable from the viewpoint of heat resistance and curability.

 [(D)成分]ラジカル重合開始剤 
 ラジカル重合開始剤については、特に限定されるものではなく、例えば、有機過酸化物や、有機アゾ化合物、アルキルボラン等があげられる。
[Component (D)] Radical polymerization initiator
The radical polymerization initiator is not particularly limited, and examples thereof include organic peroxides, organic azo compounds, and alkylboranes.

 有機過酸化物としては、過酸化ベンゾイル,過酸化ラウロイル,過酸化安息香酸 t-ブチル、過酸化安息香酸 t-アミル,t-アミル パーオキシネオデカノエート,t-ブチル パーオキシネオデカノエート,t-アミル パーオキシイソブチレート,ジt-ブチルパーオキシド,ジクミルパーオキシド,クメンヒドロパーオキシド,1,1-ジ(t-ブチルパーオキシ)シクロヘキサン,2,2-ジ(t-ブチルパーオキシ)ブタン,t-ブチルハイドロパーオキシド、ジ(s-ブチル)パーオキシカーボネート、メチルエチルケトンパーオキシドなどが挙げられるが、特に制限されるものではなく、これらを1種単独もしくは2種以上を混合してもよい。 Examples of organic peroxides include benzoyl peroxide, lauroyl peroxide, t-butyl peroxide benzoate, t-amyl peroxide, t-amyl peroxyneodecanoate, and t-butyl peroxyneodecanoate. , T-amyl peroxyisobutyrate, di-t-butyl peroxide, dicumyl peroxide, cumene hydroperoxide, 1,1-di (t-butylperoxy) cyclohexane, 2,2-di (t-butyl) Peroxy) butane, t-butyl hydroperoxide, di (s-butyl) peroxycarbonate, methyl ethyl ketone peroxide, etc., but are not particularly limited, and these may be used alone or in combination of two or more. May be.

 また、有機アゾ化合物としては、2,2´-アゾビス(イソブチロニトリル)、1,1´-アゾビス(シクロヘキサンカルボニトリル)、4,4´-アゾビス(4-シアノ吉草酸)、2,2´アゾビス(2-メチルプロピオンアミジン)二塩酸塩等があげられる。これらを1種単独もしくは2種以上を混合してもよい。 Examples of organic azo compounds include 2,2′-azobis (isobutyronitrile), 1,1′-azobis (cyclohexanecarbonitrile), 4,4′-azobis (4-cyanovaleric acid), 2,2 'Azobis (2-methylpropionamidine) dihydrochloride and the like. These may be used alone or in combination of two or more.

 アルキルボランとしては、トリエチルボラン、トリプロピルボラン,トリイソプロピルボラン、トリ-n-ブチルボラン、トリ-n-アミルボラン、トリ-n-ヘキシルボラン、トリシクロヘキシルボラン、9-ボラビシクロ[3.3.1]ノナン,イソピノカンフェニルボラン、ジエチルメチルボラン、ジエチルプロピルボラン、ジエチルブチルボラン、エチルプロピルブチルボラン等がある。またはこれらの一部が酸化されたホウ素化合物酸化物として、ジエチルエトキシボラン、ジブチルブトキシボラン、ジエチルメトキシボラン、エチルジメトキシボラン、エチルジエトキシボラン、エチルエトキシメトキシボラン等が挙げられる。これらを1種単独もしくは2種以上を混合してもよい。 Examples of the alkylborane include triethylborane, tripropylborane, triisopropylborane, tri-n-butylborane, tri-n-amylborane, tri-n-hexylborane, tricyclohexylborane, and 9-borabicyclo [3.3.1] nonane. , Isopinocan phenylborane, diethylmethylborane, diethylpropylborane, diethylbutylborane, ethylpropylbutylborane and the like. Alternatively, examples of the boron compound oxide obtained by partially oxidizing these include diethylethoxyborane, dibutylbutoxyborane, diethylmethoxyborane, ethyldimethoxyborane, ethyldiethoxyborane, and ethylethoxymethoxyborane. These may be used alone or in combination of two or more.

 また、有機過酸化物、有機アゾ化合物、アルキルボランは、1種単独もしくは2種以上を併用してもよい。 Further, organic peroxides, organic azo compounds, and alkylboranes may be used alone or in combination of two or more.

 [その他任意成分] 
 本発明の熱硬化性樹脂組成物には、必要に応じて、その他任意成分を添加してもよい。任意成分としては、不飽和ポリエステル樹脂や硬化促進剤、重合禁止剤、接着力向上剤等があげられる。
[Other optional ingredients]
You may add another arbitrary component to the thermosetting resin composition of this invention as needed. Examples of optional components include unsaturated polyester resins, curing accelerators, polymerization inhibitors, and adhesive strength improvers.

 不飽和ポリエステル樹脂は、特に限定されるものではなく、例えば、二塩基酸と多価アルコール類とを縮合反応させることによって得ることができる。 The unsaturated polyester resin is not particularly limited, and can be obtained, for example, by subjecting a dibasic acid and a polyhydric alcohol to a condensation reaction.

 上記不飽和ポリエステル樹脂の原料として用いられる二塩基酸としては、具体的には、例えば、マレイン酸、無水マレイン酸、フマル酸、イタコン酸、無水イタコン酸等のα,β-不飽和二塩基酸;フタル酸、無水フタル酸、ハロゲン化無水フタル酸、イソフタル酸、テレフタル酸、テトラヒドロフタル酸、テトラヒドロ無水フタル酸、ヘキサヒドロフタル酸、ヘキサヒドロイソフタル酸、ヘキサヒドロテレフタル酸、コハク酸、マロン酸、グルタル酸、アジピン酸、セバシン酸、1,10-デカンジカルボン酸、2,6-ナフタレンジカルボン酸、2,7-ナフタレンジカルボン酸、2,3-ナフタレンジカルボン酸、2,3-ナフタレンジカルボン酸無水物、4,4´-ビフェニルジカルボン酸、および、これらのジアルキルエステル等の飽和二塩基酸等が挙げられるが、特に限定されるものではない。これら二塩基酸は、一種類のみを用いてもよいし、適宜、二種類以上を混合して用いてもよい。 Specific examples of the dibasic acid used as a raw material for the unsaturated polyester resin include α, β-unsaturated dibasic acids such as maleic acid, maleic anhydride, fumaric acid, itaconic acid, and itaconic anhydride. Phthalic acid, phthalic anhydride, halogenated phthalic anhydride, isophthalic acid, terephthalic acid, tetrahydrophthalic acid, tetrahydrophthalic anhydride, hexahydrophthalic acid, hexahydroisophthalic acid, hexahydroterephthalic acid, succinic acid, malonic acid, Glutaric acid, adipic acid, sebacic acid, 1,10-decanedicarboxylic acid, 2,6-naphthalenedicarboxylic acid, 2,7-naphthalenedicarboxylic acid, 2,3-naphthalenedicarboxylic acid, 2,3-naphthalenedicarboxylic acid anhydride 4,4'-biphenyldicarboxylic acid, and dialkyl esters thereof Such a saturated dibasic acid, and the like, but not particularly limited. Only one kind of these dibasic acids may be used, or two or more kinds may be appropriately mixed and used.

 上記不飽和ポリエステル樹脂の原料として用いられる多価アルコール類としては、具体的には、例えばエチレングリコール、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、ポリプロピレングリコール、2-メチル-1,3-プロパンジオール、1,3-ブタンジオール、ビスフェノールAとプロピレンオキシドまたはエチレンオキシドとの付加物、グリセリン、トリメチロールプロパン、1,3-プロパンジオール、1,2-シクロヘキサングリコール、1,3-シクロヘキサングリコール、1,4-シクロヘキサングリコール、パラキシレングリコール、ビシクロヘキシル-4,4´-ジオール、2,6-デカリングリコール、トリス(2-ヒドロキシエチル)イソシアヌレート等が挙げられるが、特に限定されるものではない。また、エタノールアミン等のアミノアルコール類を用いてもよい。これら多価アルコール類は、一種類のみを用いてもよいし、適宜、二種類以上を混合してもよい。また必要によりジシクロペンタジエン系化合物を樹脂骨格中に組み入れてもよい。 Specific examples of the polyhydric alcohol used as the raw material for the unsaturated polyester resin include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, and 2-methyl-1 , 3-propanediol, 1,3-butanediol, adducts of bisphenol A and propylene oxide or ethylene oxide, glycerin, trimethylolpropane, 1,3-propanediol, 1,2-cyclohexane glycol, 1,3-cyclohexane Glycol, 1,4-cyclohexane glycol, para-xylene glycol, bicyclohexyl-4,4′-diol, 2,6-decalin glycol, tris (2-hydroxyethyl) Le) Although isocyanurate, but is not particularly limited. In addition, amino alcohols such as ethanolamine may be used. Only one kind of these polyhydric alcohols may be used, or two or more kinds may be appropriately mixed. If necessary, a dicyclopentadiene compound may be incorporated into the resin skeleton.

 硬化促進剤としては、ナフテン酸又はオクチル酸の金属塩(コバルト,亜鉛,ジルコニウム,マンガン,カルシウム等の金属塩)があげられ、これらは一種類のみを用いてもよく、適宜二種類以上を混合してもよい。 Examples of the curing accelerator include metal salts of naphthenic acid or octylic acid (metal salts of cobalt, zinc, zirconium, manganese, calcium, etc.). These may be used alone or in combination of two or more. May be.

 重合禁止剤としては、ハイドロキノン,パラターシャリーブチルカテコール,ピロガロール等のキノン類があげられ、これらは一種類のみを用いてもよく、適宜二種類以上を混合してもよい。 Examples of the polymerization inhibitor include quinones such as hydroquinone, paratertiary butyl catechol, and pyrogallol, and these may be used alone or in combination of two or more.

 接着力向上剤としては、p-スチリルトリメトキシシラン、3-メタクリロキシプロピルトリメトキシシラン、3-メタクリロキシプロピルトリエトキシシラン等があげられ、これらは一種類のみを用いてもよく、適宜二種類以上を混合してもよい。 Examples of the adhesive strength improver include p-styryltrimethoxysilane, 3-methacryloxypropyltrimethoxysilane, 3-methacryloxypropyltriethoxysilane, etc. These may be used alone or as appropriate. The above may be mixed.

 [本組成物の製造方法] 
 本発明の熱可塑性樹脂組成物の製造方法としては、まず、(A)沸点が200℃未満の重合性単量体と、(B)(A)成分に可溶な熱可塑性樹脂、(C)ビニルエステル樹脂、(D)ラジカル重合開始剤と、その他任意成分とを、空気中にて均一に攪拌、混合し、樹脂組成物とする。
[Production method of the present composition]
As a method for producing the thermoplastic resin composition of the present invention, first, (A) a polymerizable monomer having a boiling point of less than 200 ° C., (B) a thermoplastic resin soluble in component (A), (C) The vinyl ester resin, (D) radical polymerization initiator, and other optional components are uniformly stirred and mixed in the air to obtain a resin composition.

 本発明の熱硬化性樹脂組成物は、回転電機の固定子巻線の絶縁および固着用途に用いることができる。 The thermosetting resin composition of the present invention can be used for insulating and fixing the stator winding of a rotating electric machine.

 [実施例] 
 次に、図面を用いて本発明の実施例を説明する。 
 なお、以下の説明では、回転電機の一例として、ハイブリット自動車に用いられる電動機を用いる。また、以下の説明において、「軸方向」は回転電機の回転軸に沿った方向を指す。周方向は回転電機の回転方向に沿った方向を指す。「径方向」は回転電機の回転軸を中心としたときの動径方向(半径方向)を指す。「内周側」は径方向内側(内径側)を指し、「外周側」はその逆方向、すなわち径方向外側(外径側)を指す。
[Example]
Next, embodiments of the present invention will be described with reference to the drawings.
In the following description, an electric motor used in a hybrid vehicle is used as an example of a rotating electric machine. In the following description, “axial direction” refers to a direction along the rotation axis of the rotating electrical machine. The circumferential direction refers to the direction along the rotational direction of the rotating electrical machine. The “radial direction” refers to a radial direction (radial direction) when the rotational axis of the rotating electrical machine is the center. “Inner circumference side” refers to the radially inner side (inner diameter side), and “outer circumference side” refers to the opposite direction, that is, the radially outer side (outer diameter side).

 図1は本発明による固定子を備える回転電機を示す断面図である。回転電機10は、ハウジング50、固定子20、固定子鉄心21と、固定子コイル60と、回転子11とから構成される。 FIG. 1 is a cross-sectional view showing a rotating electrical machine having a stator according to the present invention. The rotating electrical machine 10 includes a housing 50, a stator 20, a stator core 21, a stator coil 60, and a rotor 11.

 ハウジング50の内周側には、固定子20が固定されている。固定子20の内周側には、回転子11が回転可能に支持されている。ハウジング50は、炭素鋼など鉄系材料の切削により、または、鋳鋼やアルミニウム合金の鋳造により、または、プレス加工によって円筒状に成形した、電動機の外被を構成している。ハウジング50は、枠体或いはフレームとも称されている。 The stator 20 is fixed to the inner peripheral side of the housing 50. The rotor 11 is rotatably supported on the inner peripheral side of the stator 20. The housing 50 constitutes an outer casing of an electric motor that is formed into a cylindrical shape by cutting an iron-based material such as carbon steel, casting of cast steel or aluminum alloy, or pressing. The housing 50 is also referred to as a frame or a frame.

 ハウジング50の外周側には、液冷ジャケット130が固定されている。液冷ジャケット130の内周壁とハウジング50の外周壁とで、油などの液状の冷媒RFの冷媒通路153が構成され、この冷媒通路153は液漏れしないように形成されている。液冷ジャケット130は、軸受144,145を収納しており、軸受ブラケットとも称されている。 A liquid cooling jacket 130 is fixed to the outer peripheral side of the housing 50. The inner peripheral wall of the liquid cooling jacket 130 and the outer peripheral wall of the housing 50 constitute a refrigerant passage 153 for a liquid refrigerant RF such as oil, and the refrigerant passage 153 is formed so as not to leak. The liquid cooling jacket 130 houses the bearings 144 and 145 and is also called a bearing bracket.

 直接液体冷却の場合、冷媒RFは、冷媒通路153を通り、冷媒出口154,155から固定子20へ向けて流出し、固定子20を冷却する。 In the case of direct liquid cooling, the refrigerant RF flows through the refrigerant passage 153 and flows out of the refrigerant outlets 154 and 155 toward the stator 20 to cool the stator 20.

 固定子20は、固定子鉄心21と、固定子コイル60とによって構成されている。固定子鉄心21は、珪素鋼板の薄板が積層されて作られている。固定子コイル60は、固定子鉄心21の内周部に多数個設けられているスロット15に巻回されている。固定子コイル60からの発熱は、固定子鉄心21を介して、液冷ジャケット130に伝熱され、液冷ジャケット130内を流通する冷媒RFにより、放熱される。 The stator 20 is composed of a stator core 21 and a stator coil 60. The stator core 21 is made by laminating thin sheets of silicon steel plates. The stator coil 60 is wound around a plurality of slots 15 provided in the inner peripheral portion of the stator core 21. Heat generated from the stator coil 60 is transferred to the liquid cooling jacket 130 via the stator core 21 and is radiated by the refrigerant RF flowing through the liquid cooling jacket 130.

 回転子11は、回転子鉄心12と、回転軸13とから構成されている。回転子鉄心12は、珪素鋼板の薄板が積層されて作られている。回転軸13は、回転子鉄心12の中心に固定されている。回転軸13は、液冷ジャケット130に取り付けられた軸受144,145により回転自在に保持されており、固定子20内の所定の位置で、固定子20に対向した位置で回転する。また、回転子11には、永久磁石18と、エンドリング(図示せず)が設けられている。 The rotor 11 is composed of a rotor core 12 and a rotating shaft 13. The rotor core 12 is made by laminating thin sheets of silicon steel plates. The rotating shaft 13 is fixed to the center of the rotor core 12. The rotating shaft 13 is rotatably held by bearings 144 and 145 attached to the liquid cooling jacket 130 and rotates at a predetermined position in the stator 20 at a position facing the stator 20. The rotor 11 is provided with a permanent magnet 18 and an end ring (not shown).

 回転電機の組立は、予め、固定子20をハウジング50の内側に挿入してハウジング50の内周壁に取付けておき、その後、固定子20内に回転子11を挿入する。次に、回転軸13に軸受144,145が嵌合するようにして液冷ジャケット130に組み付ける。 In assembling the rotating electrical machine, the stator 20 is inserted into the housing 50 in advance and attached to the inner peripheral wall of the housing 50, and then the rotor 11 is inserted into the stator 20. Next, the rotating shaft 13 is assembled to the liquid cooling jacket 130 so that the bearings 144 and 145 are fitted.

 図2を用いて、本実施例による回転電機10に用いる固定子20の要部の詳細構成について説明する。固定子20は、固定子鉄心21と、前記固定子鉄心の内周部に多数個設けられているスロット15に巻回された固定子コイル60とから構成されている。固定子コイル60は、断面が略矩形形状の導体(本実施例では銅線)を使用しスロット内の占積率を向上させ、回転電機の効率が向上する。 The detailed configuration of the main part of the stator 20 used in the rotating electrical machine 10 according to the present embodiment will be described with reference to FIG. The stator 20 includes a stator core 21 and a stator coil 60 wound around a plurality of slots 15 provided on the inner peripheral portion of the stator core. The stator coil 60 uses a conductor (copper wire in this embodiment) having a substantially rectangular cross section to improve the space factor in the slot, thereby improving the efficiency of the rotating electrical machine.

 また、スロットライナー302が各スロット15に配設され、固定子鉄心21と固定子コイル60との電気的絶縁を確実にしている。 Further, a slot liner 302 is disposed in each slot 15 to ensure electrical insulation between the stator core 21 and the stator coil 60.

 前記スロットライナー302は、銅線を包装するようにB字形状や、S字形状に成形されている。 The slot liner 302 is formed into a B shape or an S shape so as to wrap a copper wire.

 図3を用いて、回転電機10に用いる固定子20の溶接部(溶接側コイルエンド62)の詳細構成について説明する。固定子20は、固定子鉄心21と、前記固定子鉄心の内周部に多数個設けられているスロット15に巻回された固定子コイル60とから構成されている。固定子コイル60は、断面が略矩形形状のコイルを使用しスロット内の占積率を向上させ、回転電機の効率が向上する。コイル間の絶縁のため、絶縁紙300が環状に配置される。溶接部間の絶縁のため、絶縁紙301が環状に配置される。 The detailed configuration of the welded portion (welding side coil end 62) of the stator 20 used in the rotating electrical machine 10 will be described with reference to FIG. The stator 20 includes a stator core 21 and a stator coil 60 wound around a plurality of slots 15 provided on the inner peripheral portion of the stator core. The stator coil 60 uses a coil having a substantially rectangular cross section, improves the space factor in the slot, and improves the efficiency of the rotating electrical machine. Insulating paper 300 is annularly arranged for insulation between the coils. Insulating paper 301 is annularly arranged for insulation between the welds.

 絶縁紙が配置された後、前記固定子コイルの全体を、(A)沸点が200℃未満の重合性単量体と、(B)(A)成分に可溶な熱可塑性樹脂からなる樹脂組成物601の硬化物のみでほぼ均一に覆う。 After the insulating paper is disposed, the entire stator coil is composed of (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) a thermoplastic resin soluble in component (A). Cover substantially uniformly only with the cured product 601.

 図4を用いて、固定子20の反溶接部(反溶接側コイルエンド61)の詳細構成について説明する。固定子20は、固定子鉄心21と、前記固定子鉄心の内周部に多数個設けられているスロット15に巻回された固定子コイル60とから構成されている。固定子コイル60は、断面が略矩形形状のコイルを使用することでスロット内の占積率を向上させ、回転電機の効率が向上させている。コイル間の絶縁のため、絶縁紙301が環状に配置される。 The detailed configuration of the anti-welded part (anti-weld side coil end 61) of the stator 20 will be described with reference to FIG. The stator 20 includes a stator core 21 and a stator coil 60 wound around a plurality of slots 15 provided on the inner peripheral portion of the stator core. The stator coil 60 uses a coil having a substantially rectangular cross section, thereby improving the space factor in the slot and improving the efficiency of the rotating electrical machine. Insulating paper 301 is annularly arranged for insulation between the coils.

 溶接側コイルエンド62と同様に、反溶接側コイルエンド61においても、絶縁紙が配置された後、前記固定子コイルの全体を樹脂組成物601の硬化物のみでほぼ均一に覆う。ここで、樹脂組成物601は溶接側コイルエンド62を覆うものと同じ材質((A)沸点が200℃未満の重合性単量体と、(B)(A)成分に可溶な熱可塑性樹脂からなる樹脂組成物)である。 Similarly to the welding side coil end 62, the anti-welding side coil end 61 also covers the entire stator coil almost uniformly with only the cured product of the resin composition 601 after the insulating paper is disposed. Here, the resin composition 601 is the same material that covers the welding side coil end 62 ((A) a polymerizable monomer having a boiling point of less than 200 ° C., and (B) a thermoplastic resin that is soluble in the component (A). Resin composition).

 図5は溶接側コイルエンド62の、導体端部28E付近を拡大した図である。セグメント導体28は、エナメル被膜などの絶縁被膜で覆われた絶縁被覆部29A(図7中で網掛けで示した部分)と、絶縁被膜が剥離され、導体部分(銅線)が露出した導体露出部29Bとを有する。導体露出部29Bは導体端部28Eに設けられる。この導体部分の露出は溶接のために行われる。さらに、絶縁被覆部29Aと導体露出部29Bとを含むセグメント導体28の全体が、(A)沸点が200℃未満の重合性単量体と、(B)(A)成分に可溶な熱可塑性樹脂からなる樹脂組成物601の硬化物のみでほぼ均一に覆われている。従来技術で用いられている第2の樹脂部材を用いておらず、また厚さも均一なので、樹脂部材の付着、乾燥のため2重の生産設備が不要となり、また、絶縁耐圧上必要な樹脂部材以上の材料が不要となる効果がある。 FIG. 5 is an enlarged view of the vicinity of the conductor end portion 28E of the welding side coil end 62. FIG. The segment conductor 28 is an exposed conductor in which the insulating coating 29A (the portion shown by shading in FIG. 7) covered with an insulating coating such as an enamel coating and the conductive coating (copper wire) are exposed by peeling off the insulating coating. Part 29B. The conductor exposed portion 29B is provided at the conductor end portion 28E. This conductor portion is exposed for welding. Further, the entire segment conductor 28 including the insulating coating portion 29A and the exposed conductor portion 29B is composed of (A) a polymerizable monomer having a boiling point of less than 200 ° C., and (B) a thermoplastic that is soluble in the component (A). It is almost uniformly covered only with a cured product of the resin composition 601 made of resin. Since the second resin member used in the prior art is not used and the thickness is uniform, a double production facility is not required for adhesion and drying of the resin member, and the resin member necessary for insulation withstand voltage There is an effect that the above materials are unnecessary.

 図6は反溶接側コイルエンド61の、反溶接側コイルエンド頂点28C付近を拡大した図である。反溶接側コイルエンド61では、セグメント導体28の全周に渡って絶縁被覆部29Aが形成されている。さらに、絶縁被覆部29Aを覆うように、セグメント導体28は、(A)沸点が200℃未満の重合性単量体と、(B)(A)成分に可溶な熱可塑性樹脂からなる樹脂601の硬化物のみでほぼ均一に覆われている。従来技術で用いられている第2の樹脂部材を用いておらず、また厚さも均一なので、樹脂部材の付着、乾燥のため2重の生産設備が不要となり、また、絶縁耐圧上必要な樹脂部材以上の材料が不要となる効果がある。 FIG. 6 is an enlarged view of the vicinity of the anti-welding side coil end apex 28 </ b> C of the anti-welding side coil end 61. In the non-welding side coil end 61, an insulation coating portion 29 </ b> A is formed over the entire circumference of the segment conductor 28. Further, the segment conductor 28 includes a resin 601 made of (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) a thermoplastic resin soluble in the component (A) so as to cover the insulating coating portion 29A. It is almost uniformly covered only with the cured product. Since the second resin member used in the prior art is not used and the thickness is uniform, a double production facility is not required for adhesion and drying of the resin member, and the resin member necessary for insulation withstand voltage There is an effect that the above materials are unnecessary.

 本構成により、前記固定子コイルの全体を、(A)沸点が200℃未満の重合性単量体と、(B)(A)成分に可溶な熱可塑性樹脂からなる樹脂601のみでほぼ均一に覆い、かつ、絶縁強化のための環状絶縁樹脂300、301を配置する事により、電気自動車やハイブリッド電気自動車に求められる絶縁性を満足した回転電機を得られるものとなる。 With this configuration, the entire stator coil is substantially uniform only with the resin 601 made of (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) a thermoplastic resin soluble in the component (A). Further, by disposing the annular insulating resins 300 and 301 for reinforcing the insulation, it is possible to obtain a rotating electrical machine that satisfies the insulating properties required for electric vehicles and hybrid electric vehicles.

 上記において、絶縁被膜を形成するために用いる樹脂は、コストおよび絶縁性、浸透性、硬化性の観点から、不飽和ポリエステル樹脂とした。不飽和ポリエステル樹脂は、樹脂を溶剤に希釈した溶剤型、及び溶剤による希釈を行っていない無溶剤型のいずれも使用可能であるが、硬化時に、溶剤の揮発による膨れが生じない無溶剤型不飽和ポリエステル樹脂がより好ましく、硬化時の成分揮発による特性の低下を防ぐために、非スチレン系不飽和ポリエステル樹脂が更に好ましい。 In the above, the resin used for forming the insulating coating was an unsaturated polyester resin from the viewpoints of cost and insulation, permeability and curability. As the unsaturated polyester resin, both a solvent type in which the resin is diluted with a solvent and a solventless type in which the resin is not diluted with a solvent can be used. Saturated polyester resins are more preferable, and non-styrene unsaturated polyester resins are more preferable in order to prevent deterioration of characteristics due to component volatilization during curing.

 なお、樹脂組成物601はほぼ均一に覆われることが望ましいが、絶縁紙300、301との境界面やコイルの複雑な形状部位は不均一に付着する場合もある。ここで言うほぼ均一とは、従来技術(例えば特許文献1など)の様に意図的に厚くするものでは無いとの意味で用いている。 Although the resin composition 601 is desirably covered almost uniformly, the boundary surface with the insulating paper 300 and 301 and the complicated shape part of the coil may adhere unevenly. The term “substantially uniform” as used herein means that the thickness is not intentionally increased as in the prior art (for example, Patent Document 1).

 また、樹脂組成物601のみでほぼ均一に覆われているとの説明における「のみ」は、エナメル被膜などの予め導体に形成されている絶縁被膜の存在を除外するものではない。ここで言う「のみ」とは、セグメント導体28の成形後の絶縁強化のために付与される絶縁樹脂が樹脂組成物601だけであり、従来技術における第2の樹脂部材を用いないという意味で用いている。 In addition, “only” in the description that the resin composition 601 is almost uniformly covered does not exclude the presence of an insulating coating formed on a conductor in advance, such as an enamel coating. The term “only” used herein means that the insulating resin applied for reinforcing the insulation after the segment conductor 28 is molded is only the resin composition 601 and does not use the second resin member in the prior art. ing.

 以上においては、永久磁石式の回転電機において説明を行ったが、本発明の特徴は固定子のコイル絶縁に関するものであるため、回転子は永久磁石式でなく、インダクション式や、シンクロナスリラクタンス、爪磁極式等にも適用可能である。また、巻線方式においては波巻方式であるが、同様の特徴を持つ巻線方式であれば、適用可能である。次に、内転型で説明を行っているが、外転型でも同様に適用可能である。 In the above, a permanent magnet type rotating electrical machine has been described, but since the feature of the present invention relates to the coil insulation of the stator, the rotor is not a permanent magnet type, but an induction type, synchronous reluctance, It can be applied to a claw magnetic pole type. In addition, the winding method is a wave winding method, but any winding method having similar characteristics can be applied. Next, the explanation is made with the inner rotation type, but the same applies to the outer rotation type.

 次に、(A)沸点が200℃未満の重合性単量体と、(B)(A)成分に可溶な熱可塑性樹脂からなる熱硬化性樹脂の組成例について記すが、本発明は、これらの組成例によって限定されるものではない。 Next, a composition example of a thermosetting resin composed of (A) a polymerizable monomer having a boiling point of less than 200 ° C. and (B) a thermoplastic resin soluble in the component (A) will be described. It is not limited by these composition examples.

 [組成例1] 
 スチレン50重量部(和光純薬製)、数平均分子量14,000のポリスチレン10重量部、ビスフェノールAグリセロレートジメタクリレート50重量部(アルドリッチ製)、1,1-ジ(t-ブチルパーオキシ)シクロヘキサン1.5重量部(日油製)を加え、熱硬化性樹脂組成物とする。
[Composition Example 1]
50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 10 parts by weight of polystyrene having a number average molecular weight of 14,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butylperoxy) cyclohexane 1.5 parts by weight (manufactured by NOF) is added to obtain a thermosetting resin composition.

 [組成例2] 
 スチレン50重量部(和光純薬製)、数平均分子量48,000のポリスチレン5重量部、ビスフェノールAグリセロレートジメタクリレート50重量部(アルドリッチ製)、1,1-ジ(t-ブチルパーオキシ)シクロヘキサン1.5重量部(日油製)を加え、熱硬化性樹脂組成物とする。
[Composition Example 2]
50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polystyrene having a number average molecular weight of 48,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butylperoxy) cyclohexane 1.5 parts by weight (manufactured by NOF) is added to obtain a thermosetting resin composition.

 [組成例3] 
 スチレン50重量部(和光純薬製)、数平均分子量58,000のポリメタクリル酸メチル5重量部、ビスフェノールAグリセロレートジメタクリレート50重量部(アルドリッチ製)、1,1-ジ(t-ブチルパーオキシ)シクロヘキサン1.5重量部(日油製)を加え、熱硬化性樹脂組成物とする。
[Composition Example 3]
50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polymethyl methacrylate having a number average molecular weight of 58,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butyl par Oxy) 1.5 parts by weight of cyclohexane (manufactured by NOF) is added to obtain a thermosetting resin composition.

 [組成例4] 
 メタクリル酸メチル50重量部(和光純薬製)、数平均分子量48,000のポリスチレン5重量部、ビスフェノールAグリセロレートジメタクリレート50重量部(アルドリッチ製)、1,1-ジ(t-ブチルパーオキシ)シクロヘキサン1.5重量部(日油製)を加え、熱硬化性樹脂組成物とする。
[Composition Example 4]
50 parts by weight of methyl methacrylate (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polystyrene having a number average molecular weight of 48,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butylperoxy) ) 1.5 parts by weight of cyclohexane (manufactured by NOF) is added to obtain a thermosetting resin composition.

 [組成例5] 
 スチレン50重量部(和光純薬製)、数平均分子量48,000のポリスチレン5重量部、ビスフェノールAグリセロレートジメタクリレート50重量部(アルドリッチ製)、ジエチルメトキシボラン1.0重量部(アルドリッチ製)を加え、熱硬化性樹脂組成物とする。
[Composition Example 5]
50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polystyrene having a number average molecular weight of 48,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1.0 part by weight of diethylmethoxyborane (manufactured by Aldrich) In addition, a thermosetting resin composition is obtained.

 [組成例6] 
 スチレン50重量部(和光純薬製)、数平均分子量48,000のポリスチレン5重量部、ビスフェノールAグリセロレートジメタクリレート50重量部(アルドリッチ製)、1,1-ジ(t-ブチルパーオキシ)シクロヘキサン1.5重量部(日油製)、ナフテン酸マンガン0.05重量部(東京化成製)、イソフタル酸、マレイン酸、エチレングリコールからなる不飽和ポリエステル樹脂5重量部、3-メタクリロキシプロピルトリメトキシシラン0.1重量部(信越シリコーン製)を加え、熱硬化性樹脂組成物とする。
[Composition Example 6]
50 parts by weight of styrene (manufactured by Wako Pure Chemical Industries), 5 parts by weight of polystyrene having a number average molecular weight of 48,000, 50 parts by weight of bisphenol A glycerolate dimethacrylate (manufactured by Aldrich), 1,1-di (t-butylperoxy) cyclohexane 1.5 parts by weight (manufactured by NOF), 0.05 parts by weight of manganese naphthenate (manufactured by Tokyo Chemical Industry), 5 parts by weight of unsaturated polyester resin consisting of isophthalic acid, maleic acid and ethylene glycol, 3-methacryloxypropyltrimethoxy 0.1 part by weight of silane (manufactured by Shin-Etsu Silicone) is added to obtain a thermosetting resin composition.

 続いて、上記組成の樹脂による、固定子20のコイル部分の被覆法について述べる。上記樹脂組成物601を、この組成物を浸漬法,滴下含浸法等を用いて、モーターコイル等の電気機器に含浸させる。含浸方法については常法によるもので、特に制限は無い。固定子20に塗布した樹脂組成物601は、樹脂の流動性が見られなくなるまで室温乾燥した後、加熱により完全に硬化する。室温乾燥は、静置や通風下など、常法によるもので、特に制限はない。本加熱は、温風式加熱炉やIH加熱炉など常法によるもので、特に制限はない。 Subsequently, a method of coating the coil portion of the stator 20 with the resin having the above composition will be described. The resin composition 601 is impregnated in an electric device such as a motor coil by using this composition by dipping, dripping or the like. The impregnation method is a conventional method and is not particularly limited. The resin composition 601 applied to the stator 20 is completely cured by heating after drying at room temperature until the resin fluidity is no longer observed. Room temperature drying is a conventional method such as standing or under ventilation, and is not particularly limited. The main heating is performed by a conventional method such as a hot air heating furnace or an IH heating furnace, and there is no particular limitation.

 以上で説明したように、本発明によれば、絶縁性に優れ、かつ、小型高出力であるにも関わらず、冷却性が優れた回転電機の固定子を提供することができる。 As described above, according to the present invention, it is possible to provide a stator for a rotating electrical machine that has excellent insulating properties and excellent cooling performance despite its small size and high output.

 なお、本発明は上記した実施例に限定されるものではなく、様々な変形例が含まれる。例えば、上記した実施例は本発明を分かりやすく説明するために詳細に説明したものであり、必ずしも説明した全ての構成を備えるものに限定されるものではない。また、実施例の構成の一部について、他の構成の追加・削除・置換をすることが可能である。 In addition, this invention is not limited to the above-mentioned Example, Various modifications are included. For example, the above-described embodiments have been described in detail for easy understanding of the present invention, and are not necessarily limited to those having all the configurations described. In addition, it is possible to add, delete, and replace other configurations for a part of the configuration of the embodiment.

  10  回転電機
  11  回転子
  12  回転子鉄心
  13  回転軸
  15  スロット
  18  永久磁石
  20  固定子
  21  固定子鉄心
  28C 反溶接側コイルエンド頂点
  28D 導体斜行部
  28E 導体端部
  28F 導体斜行部
  50  ハウジング
  60  固定子コイル
  61  反溶接側コイルエンド
  62  溶接側コイルエンド
  130 液冷ジャケット
  144 軸受
  145 軸受
  150 冷媒(油)貯蔵空間
  153 冷媒通路
  154 冷媒出口
  155 冷媒出口
  300 環状絶縁紙
  301 環状絶縁紙
  302 スロットライナー
  601 樹脂部材
  RF  冷媒
DESCRIPTION OF SYMBOLS 10 Rotating electrical machine 11 Rotor 12 Rotor core 13 Rotating shaft 15 Slot 18 Permanent magnet 20 Stator 21 Stator core 28C Non-welding side coil end apex 28D Conductor skew part 28E Conductor end part 28F Conductor skew part 50 Housing 60 Fixed Child coil 61 Anti-welding side coil end 62 Welding side coil end 130 Liquid cooling jacket 144 Bearing 145 Bearing 150 Refrigerant (oil) storage space 153 Refrigerant passage 154 Refrigerant outlet 155 Refrigerant outlet 300 Annular insulating paper 301 Annular insulating paper 302 Slot liner 601 Resin Components RF refrigerant

Claims (4)

 固定子コイルが固定子鉄心のスロットに配置された回転電機の固定子において、
 前記固定子コイルは、複数のセグメント導体から構成され、
 前記セグメント導体は、絶縁被覆で覆われた絶縁被覆部と、導体が露出した導体露出部とを有し、かつ、他のセグメント導体と前記導体露出部を介して接合されており、
 前記固定子コイルが、
  沸点が200℃未満の重合性単量体と、
  前記重合性単量体に可溶な熱可塑性樹脂と、
 を含む熱硬化性樹脂組成物で覆われている回転電機の固定子。
In a stator of a rotating electric machine in which a stator coil is disposed in a slot of a stator core,
The stator coil is composed of a plurality of segment conductors,
The segment conductor has an insulation coating portion covered with an insulation coating, a conductor exposure portion where the conductor is exposed, and is joined to another segment conductor via the conductor exposure portion,
The stator coil is
A polymerizable monomer having a boiling point of less than 200 ° C .;
A thermoplastic resin soluble in the polymerizable monomer;
The stator of the rotary electric machine covered with the thermosetting resin composition containing this.
 請求項1に記載の回転電機の固定子であって、
 前記熱硬化性樹脂組成物が、
  ビニルエステル樹脂と、
  ラジカル重合開始剤と、
 を含む回転電機の固定子。
A stator for a rotating electrical machine according to claim 1,
The thermosetting resin composition is
Vinyl ester resin,
A radical polymerization initiator;
Rotating electric machine stator including
 請求項1又は2に記載の回転電機の固定子であって、
 前記重合性単量体が、スチレン又はスチレンの誘導体である回転電機の固定子。
A stator for a rotating electrical machine according to claim 1 or 2,
A stator for a rotating electrical machine, wherein the polymerizable monomer is styrene or a derivative of styrene.
 請求項1乃至3のいずれかに記載の回転電機の固定子と、
 回転子と、を備えた回転電機。
A stator for a rotating electrical machine according to any one of claims 1 to 3,
A rotating electrical machine including a rotor.
PCT/JP2015/071188 2014-08-01 2015-07-27 Stator for rotary electric machine, and rotary electric machine provided with same Ceased WO2016017563A1 (en)

Applications Claiming Priority (2)

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JP2014-157292 2014-08-01
JP2014157292A JP2016036192A (en) 2014-08-01 2014-08-01 Rotating electric machine stator and rotating electric machine equipped with the same

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JPS6248236A (en) * 1985-08-26 1987-03-02 Toshiba Corp Electromagnetic device
JP2004229460A (en) * 2003-01-27 2004-08-12 Mitsubishi Electric Corp Rotating electric machine stator
JP2009102586A (en) * 2007-10-25 2009-05-14 Kyocera Chemical Corp Thermosetting resin composition, cured material, and high thermal conduction coil
JP2009191105A (en) * 2008-02-12 2009-08-27 Honda Motor Co Ltd CURABLE COMPOSITION AND ELECTRIC / ELECTRONIC PARTS FOR VEHICLE USING THE SAME
JP2012007081A (en) * 2010-06-25 2012-01-12 Hitachi Ltd Unsaturated polyester resin composition for fixing coil
WO2012017646A1 (en) * 2010-08-03 2012-02-09 パナソニック株式会社 Molded structure and motor comprising same
JP2012090433A (en) * 2010-10-20 2012-05-10 Hitachi Industrial Equipment Systems Co Ltd Electric appliance having joint part insulation structure
WO2013089196A1 (en) * 2011-12-14 2013-06-20 昭和電工株式会社 Unsaturated polyester resin composition and encapsulated motor

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003189523A (en) * 2001-12-21 2003-07-04 Aisin Aw Co Ltd Varnish dripping impregnation method
JP2012231638A (en) * 2011-04-27 2012-11-22 Toyota Motor Corp Rotary electric machine stator

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6248236A (en) * 1985-08-26 1987-03-02 Toshiba Corp Electromagnetic device
JP2004229460A (en) * 2003-01-27 2004-08-12 Mitsubishi Electric Corp Rotating electric machine stator
JP2009102586A (en) * 2007-10-25 2009-05-14 Kyocera Chemical Corp Thermosetting resin composition, cured material, and high thermal conduction coil
JP2009191105A (en) * 2008-02-12 2009-08-27 Honda Motor Co Ltd CURABLE COMPOSITION AND ELECTRIC / ELECTRONIC PARTS FOR VEHICLE USING THE SAME
JP2012007081A (en) * 2010-06-25 2012-01-12 Hitachi Ltd Unsaturated polyester resin composition for fixing coil
WO2012017646A1 (en) * 2010-08-03 2012-02-09 パナソニック株式会社 Molded structure and motor comprising same
JP2012090433A (en) * 2010-10-20 2012-05-10 Hitachi Industrial Equipment Systems Co Ltd Electric appliance having joint part insulation structure
WO2013089196A1 (en) * 2011-12-14 2013-06-20 昭和電工株式会社 Unsaturated polyester resin composition and encapsulated motor

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