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WO2015130085A1 - Composition pour assouplissant pour textile - Google Patents

Composition pour assouplissant pour textile Download PDF

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Publication number
WO2015130085A1
WO2015130085A1 PCT/KR2015/001841 KR2015001841W WO2015130085A1 WO 2015130085 A1 WO2015130085 A1 WO 2015130085A1 KR 2015001841 W KR2015001841 W KR 2015001841W WO 2015130085 A1 WO2015130085 A1 WO 2015130085A1
Authority
WO
WIPO (PCT)
Prior art keywords
fabric softener
softener composition
weight
acid
cationic surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/KR2015/001841
Other languages
English (en)
Korean (ko)
Inventor
조윤진
차경온
김세훈
심연수
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG H&H Co Ltd
Original Assignee
LG Household and Health Care Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020140102212A external-priority patent/KR20150125518A/ko
Priority claimed from KR1020140102216A external-priority patent/KR20150125522A/ko
Priority claimed from KR1020140102209A external-priority patent/KR20150125515A/ko
Priority claimed from KR1020140102206A external-priority patent/KR20150100464A/ko
Priority claimed from KR1020140102208A external-priority patent/KR20150125514A/ko
Priority claimed from KR1020140102210A external-priority patent/KR20150125516A/ko
Priority claimed from KR1020140102207A external-priority patent/KR20150100465A/ko
Priority claimed from KR1020150025433A external-priority patent/KR20150100544A/ko
Priority claimed from KR1020150025436A external-priority patent/KR101809786B1/ko
Priority claimed from KR1020150025437A external-priority patent/KR102123613B1/ko
Priority claimed from KR1020150025435A external-priority patent/KR20150100546A/ko
Priority claimed from KR1020150025434A external-priority patent/KR101703138B1/ko
Priority to CN201580010356.6A priority Critical patent/CN106029857B/zh
Application filed by LG Household and Health Care Ltd filed Critical LG Household and Health Care Ltd
Priority to JP2016554203A priority patent/JP6817065B2/ja
Publication of WO2015130085A1 publication Critical patent/WO2015130085A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof

Definitions

  • the present invention relates to a fabric softener composition.
  • Fabric softeners are widely used in homes to prevent static electricity generated in clothing and to give the flexibility of the fiber, the amount of use is increasing gradually.
  • the desire for hygiene and cleanliness is increased, and the pursuit of a more comfortable medical life, there is a growing interest in preventing the growth of microorganisms that can occur in clothing and removing odors.
  • the altered odor that occurs in fibers is caused by the reaction of organic compounds, such as sweat odors, with volatile organic compounds such as unsaturated lower fatty acids and ammonia, which are produced by decomposition of skin flora, or with residual components of laundry detergents or fabric softeners.
  • organic compounds such as sweat odors
  • volatile organic compounds such as unsaturated lower fatty acids and ammonia, which are produced by decomposition of skin flora, or with residual components of laundry detergents or fabric softeners.
  • drying time is delayed when drying indoors, and it is known that the odor caused by Morxella asloensis is more likely to occur.
  • a conventional softening agent composition containing an antimicrobial agent was used, but the antimicrobial agent included in the conventional softening agent is harmful to the human body.
  • the use of such antimicrobial agents has been avoided due to the fact that the use of synthetic antimicrobial agents is reported to be harmful to the human body.
  • the fabric softener has been using a cationic surfactant as a flexible component for more than 60 years since it was commercialized worldwide in the 1950s [Korea Patent Publication No. 10-2007-0090861].
  • a cationic surfactant as a flexible component for more than 60 years since it was commercialized worldwide in the 1950s [Korea Patent Publication No. 10-2007-0090861].
  • the human hazard of such cationic surfactants has been revealed, and the desire to avoid them is increasing.
  • An object of the present invention is to provide a fabric softener composition having excellent dissolving and removing effects of calcium carbonate, which is a detergent insoluble component remaining in the fiber, without using a cationic surfactant, which is included as a flexible component in the conventional fabric softener composition.
  • Another object of the present invention is to provide a fabric softener composition having excellent dissolution and removal effect of zeolite, which is a detergent-insoluble component remaining in the fiber, without using a cationic surfactant, which has been included as a flexible component in the conventional fabric softener composition. .
  • the present invention has a friction coefficient of 2 to 25 of the fibers after washing and rinsing according to the test method of the environmental mark EL306, without using a cationic surfactant that was included as a flexible component in the conventional fabric softener composition, the drying Another object of the present invention is to provide a fabric softener composition which can give a smooth feeling to a subject without being slippery.
  • Another object of the present invention is to provide a fabric softener composition having excellent water repellency / moisture permeability of Gore-Tex outdoor clothing, without using a cationic surfactant, which is included as a flexible component in the conventional fabric softener composition.
  • Another object of the present invention is to provide a fabric softener composition capable of removing odors changed after washing by adding an organic acid without using a cationic surfactant, which is included as a flexible component in a conventional fabric softener composition.
  • the present invention includes a pH adjusting agent, does not include a cationic surfactant, the content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 is 90 ppm or less It provides a fabric softener composition.
  • the present invention also provides a fabric softener composition containing a pH adjusting agent, no cationic surfactant, and a content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 is 20 ppm or less. .
  • the present invention also provides a fabric softener composition
  • a fabric softener composition comprising a pH adjuster, no cationic surfactant, and a coefficient of friction of 2 to 25 fibers after washing and rinsing according to the test method of environmental mark EL306.
  • the present invention also provides a fabric softener composition including a pH adjuster, no cationic surfactant, and having a water repellency degree of 4 or higher after rinsing / dehydrating 5 times with an amount according to the environmental mark EL306.
  • the present invention contains an organic acid, does not contain a cationic surfactant, and after the completion of washing according to the environmental mark EL306, the five-point scale sensory of the smell changed when left for 24 hours at a drying temperature of 30 °C, 80% relative humidity
  • the fabric softener composition which has an evaluation of 4 or more points is provided.
  • the fabric softener composition according to the present invention is excellent for dissolving and removing calcium carbonate, which is a detergent insoluble component remaining in fibers, and for dissolving and removing zeolite, a detergent insoluble component.
  • the fabric softener composition according to the present invention having a friction coefficient of 2 to 25 of the fibers after washing and rinsing according to the test method of environmental mark EL306, the dried subject is not slippery and smooth I can give a feeling.
  • the fabric softener composition according to the present invention instead of the cationic surfactant harmful to the human body, the water repellent / moisture permeability effect of Gore-Tex outdoor clothing than the fabric softener using the conventional cationic surfactant without using a pH adjuster to the human body Can improve.
  • the fabric softener composition according to the present invention can effectively remove the smell replaced after washing using an organic acid without using a cationic surfactant.
  • the present invention includes a pH adjusting agent, does not include a cationic surfactant,
  • the present invention relates to a fiber softener composition (hereinafter referred to as a first fabric softener composition) having a content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 of 90 ppm or less.
  • a fiber softener composition hereinafter referred to as a first fabric softener composition
  • the test method of the EL306 may be washed and rinsed according to the flexibility test method of the test method in the EL306.
  • the pH adjusting agent may serve to remove detergent residues.
  • the organic acid may play a role of the softener intrinsic (softens the cloth and improves the feel).
  • the pH adjusting agent may be an organic acid.
  • the kind of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
  • the content of the pH adjusting agent is not particularly limited and may be included in 1 to 30% by weight, 5 to 20% by weight, or 8 to 15% by weight based on 100% by weight of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even if the content of the pH regulator exceeds 30% by weight exhibits an excellent calcium carbonate removal effect, the higher the content of the pH regulator, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
  • the fabric softener composition according to the present invention is excellent in detergent debris removal effect even without including a cationic surfactant, and thus can be easily used as a fabric softener.
  • the content of calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 in the present invention is 90 ppm or less, 65 ppm or less, 50 ppm or less, 45 ppm or less, 40 ppm or less, Or less than 37 ppm or 0 ppm.
  • the calcium carbonate remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 may be removed from 5 to 300 ppm, 10 to 250 ppm, or 30 to 200 ppm.
  • the present invention includes a pH adjusting agent, does not include a cationic surfactant,
  • the present invention relates to a fabric softener composition (hereinafter referred to as a second fabric softener composition) having a content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 of 20 ppm or less.
  • a fabric softener composition hereinafter referred to as a second fabric softener composition
  • the test method of the EL306 may be washed and rinsed according to the flexibility test method of the test method in the EL306.
  • the pH adjusting agent may serve to remove detergent residues, specifically zeolite.
  • the organic acid may play a role of the softener intrinsic (softens the cloth and improves the feel).
  • the pH adjusting agent may be an organic acid.
  • the kind of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
  • the content of the pH adjusting agent is not particularly limited and may be included in 1 to 30% by weight, 5 to 20% by weight, or 8 to 15% by weight based on 100% by weight of the fabric softener composition. It is possible to exhibit an excellent zeolite removal effect within the above range. Although the zeolite removal effect is excellent even if the content of the pH regulator exceeds 30% by weight, the pH of the rinsing water is lower as the content of the pH regulator is higher, it is better to use less than 30% by weight.
  • the fabric softener composition according to the present invention is excellent in detergent debris removal effect even without including a cationic surfactant, and thus can be easily used as a fabric softener.
  • the content of zeolite remaining in the fiber after washing and rinsing according to the test method of environmental mark EL306 is 20 ppm or less, 10 ppm or less, 8 ppm or less, 7 ppm or less, 3 ppm or 0 ppm Can be.
  • the present invention includes a pH adjusting agent, does not include a cationic surfactant,
  • the present invention relates to a fabric softener composition (hereinafter referred to as a third fabric softener composition) having a friction coefficient of 2 to 25 after finishing washing and rinsing according to the test method of environmental mark EL306.
  • a fabric softener composition hereinafter referred to as a third fabric softener composition
  • the test method of the EL306 may be washed and rinsed according to the flexibility test method of the test method in the EL306.
  • the pH adjusting agent may serve to remove detergent residues.
  • the organic acid may play a role of the softener intrinsic (softens the cloth and improves the feel).
  • the pH adjusting agent may be an organic acid.
  • the kind of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
  • the content of the pH adjusting agent is not particularly limited and may be included in 1 to 30% by weight, 5 to 20% by weight, or 8 to 15% by weight based on 100% by weight of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even if the content of the pH regulator exceeds 30% by weight exhibits an excellent calcium carbonate removal effect, the higher the content of the pH regulator, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
  • the fabric softener composition according to the present invention is excellent in detergent debris removal effect even without including a cationic surfactant, and thus can be easily used as a fabric softener.
  • the coefficient of friction of the fibers after washing and rinsing according to the test method of environmental mark EL306 using the fabric softener composition according to the present invention may be 2 to 25, 10 to 25, or 20 to 23.
  • the subject dried in the friction coefficient range may give a smooth feeling without slipping.
  • the subject may be an object of a fabric softener such as clothing.
  • the present invention includes a fabric softener composition containing a pH adjuster, does not contain a cationic surfactant, water repellency degree 4 or more after repeated rinsing / dehydration five times with the amount according to the environmental mark EL306 (hereinafter, 4 fabric softener composition).
  • the fabric softener composition according to the present invention includes a pH adjusting agent.
  • the pH adjusting agent plays a role of water repellency / moisture permeability of Gore-Tex outdoor clothing.
  • the pH adjusting agent may be an organic acid.
  • the organic acid serves as a softener intrinsic (to soften the cloth and to feel good).
  • the type of such organic acid is not particularly limited, and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid, and lactic acid.
  • citric acid is suitable for use as an organic acid because the cost of raw materials is low.
  • the content of the pH adjusting agent is not particularly limited, and may be included in an amount of 0.01 to 30% by weight, 0.1 to 20% by weight or 1 to 15% by weight based on 100% by weight of the fabric softener composition. Within the above range can exhibit excellent water repellent / moisture permeability of Gore-Tex outdoor clothing. Even if the content of the organic acid is more than 30% by weight of the excellent Gore-Tex outdoor clothing exhibits a water-repellent / moisture-permeable effect, the higher the content of the organic acid, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
  • the Gore-Tex outdoor clothing can be easily used as a fabric softener because of excellent water / moisture permeability.
  • the fabric softener composition according to the present invention has a water repellency of 4 or more after repeated rinsing / dehydrating 5 times with the amount according to the environmental mark EL306.
  • the present invention contains an organic acid, does not contain a cationic surfactant, and after the completion of washing according to the environmental mark EL306, the five-point scale sensory of the smell changed when left for 24 hours at a drying temperature of 30 °C, 80% relative humidity
  • the evaluation relates to a fibrous softener composition (hereinafter referred to as a fifth fibrous softener composition) having four or more points.
  • the fabric softener composition of the present invention is characterized in that an organic acid is used instead of the cationic surfactant to remove the smell after washing.
  • the organic acid serves to remove detergent residues, specifically calcium carbonate.
  • the organic acid serves as a softener intrinsic (to soften the cloth and to feel good).
  • the organic acid may be, for example, citric acid, acetic acid, tartaric acid, succinic acid, malic acid or lactic acid or the like, but is not particularly limited thereto.
  • the organic acid may be citric acid. Since citric acid has a low unit cost of raw material costs, it is possible to reduce the production cost of the fabric softener composition.
  • the content of the organic acid is not particularly limited and may be included in an amount of 1 to 30% by weight, more specifically, 2 to 25% by weight, based on 100% by weight of the fabric softener composition. It can exhibit an excellent calcium carbonate removal effect within the above range. Even when the content of the organic acid exceeds 30% by weight exhibits excellent calcium carbonate removal effect, the higher the content of the organic acid, the lower the pH of the rinsing water, it is better to use less than 30% by weight.
  • the fabric softener composition of the present invention uses an organic acid instead of a cationic surfactant, and then, after washing for 24 hours at a drying temperature of 30 ° C. and a relative humidity of 80%, a five-point scale sensory evaluation of 4 Shown above the dots can effectively remove the odor. Therefore, it can be used easily as a fabric softener.
  • the fabric softener composition according to the present invention may further include a thickening polymer for viscosity control in addition to the aforementioned organic acid.
  • the thickening polymers include calcium-carboxymethyl cellulose, methyl cellulose / hydroxypropylmethylcellulose, hydroxy ethyl cellulose, carbopol 934, carbopol 934, carbopol 941, xanthan gum, sodium alginate, guar gum. , Carrageenan, pectin, acrylic polymer and the like can be used.
  • at least one acrylic polymer selected from the group consisting of acrylic acid polymers, acrylic copolymers, and acrylic acrylates is preferable.
  • the content of the thickening polymer is not particularly limited and may be included as 0.01 to 1.2% by weight, more specifically, 0.05 to 1% by weight based on 100% by weight of the fabric softener composition.
  • Vinegar may further be used in the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) of the present invention.
  • Vinegar is a sour and slightly sweet seasoning that contains acetic acid as its main ingredient, and contains dozens of organic acids such as acetic acid, citric acid and various amino acids, which helps to increase metabolism and remove body wastes, and is a powerful preservative. It serves as a powerful fungicide. In addition, vinegar may serve to remove detergent residues.
  • the content of the vinegar is not particularly limited and may be included in 0.1 to 10% by weight, 0.5 to 5% by weight or 1 to 3% by weight relative to 100% by weight of the fabric softener composition. It has a bactericidal effect and an effect of removing detergent residues within the above range.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include a flower fermentation vinegar that plays a role of strong deodorization in addition to the above-mentioned composition.
  • the flower fermentation vinegar may be obtained by washing the petals with water, dried and mixed with excess vinegar and sugar fermentation for 3 to 7 days.
  • the vinegar may be commercially available vinegar, it is preferable to use 5 to 30 parts by weight based on 1 part by weight of the petals.
  • the sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup.
  • the sugar serves to alcohol ferment the flower extract, it is preferred to use 5 to 30 parts by weight based on 1 part by weight of the petals.
  • the flower fermentation vinegar is sterilized with the original flower, hot water extracted for 10 to 30 minutes at 100 to 150 °C and then mixed with the hot water extract and vinegar and sugar and fermentation process at 20 to 40 °C for 72 to 96 hours Can be obtained through
  • the vinegar refers to fermented by propagating wild vinegar isolated from vinegar, odorless ( ⁇ ) produced in the traditional manner, the seed vinegar by the acetic acid bacteria Acetobacter sp. Anything that can be produced can be used.
  • the amount of the seed may be added in 5 to 30% by weight based on 100% by weight of the hydrothermal extract flowers.
  • the added amount of the vinegar is less than 5% by weight, it is difficult to induce vinegar fermentation of the aged hydrothermal extract, and when it exceeds 30% by weight, the efficiency of vinegar fermentation does not increase any more.
  • the sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup.
  • the sugar serves to ferment the flower hydrothermal extract alcohol, and may be added in an amount of 5 to 30% by weight based on 100% by weight of the hydrothermal extract flower.
  • Flower fermentation vinegar prepared by the above method may have a pH of 2.70 to 3.30, the acidity of 3 to 7.
  • Types of flowers used for the flower fermentation vinegar can be used without limitation.
  • a peach blossom, an apricot blossom, an acacia blossom, a chamomile blossom, a jasmine blossom or a lotus blossom can be used.
  • the content of the flower fermentation vinegar is not particularly limited and may be included in 0.001 to 10% by weight, 0.05 to 5% by weight or 0.1 to 2% by weight relative to 100% by weight of the fabric softener composition. It has an effect of removing bactericidal action and odor within the above range.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include ethanol for phase stability of the contents.
  • the content of the ethanol is not particularly limited, and may be included in 0.1 to 10% by weight, 0.5 to 8% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition. It has a phase stability effect of excellent contents within the above range.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further use a fragrance.
  • the fragrance may include, for example, a floral fragrance, a citrus fragrance, or the like, but may be used without limitation within a range that does not impair the effects of the present invention if it can be used as a fabric softener.
  • the amount of the perfume is not particularly limited and may be included in 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further use a fragrance solubilizer
  • the fragrance solubilizer is vinegar odor by fermentation vinegar, etc. It alleviates the fragrance satisfaction of the fabric softener. Its content is not particularly limited and may be included in 0.1 to 10% by weight or 1 to 7% by weight relative to 100% by weight of the fabric softener composition.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include a plant extract to improve the odor removal effect such as vinegar odor.
  • the plant extract may include one or more selected from the group consisting of persimmon leaves, green tea and dermis.
  • the fabric softener composition (first, second, third, fourth or fifth fabric softener composition) according to the present invention may further include a small amount of additives within the scope of the present invention.
  • the additive may be an antimicrobial component for further improving the antimicrobial effect.
  • the additive may be a pigment, a preservative, an antioxidant, an antifoaming agent, and the like.
  • the content of the additive is not particularly limited, and may be included in an amount of 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fabric softener composition.
  • compositions of the present invention are generally formulated with fibrous softeners in addition to the components described above in their respective formulations, water, surfactants, A moisturizer, a lower alcohol, a thickener, a chelating agent, a pigment
  • the content thereof is not particularly limited, and may be included in an amount of 55 to 90 wt% or 60 to 85 wt% based on 100 wt% of the fabric softener composition.
  • composition first, second, third, fourth or fifth fabric softener composition
  • the composition may be used by powder, granulation using a method known in the art, may be prepared in a liquid state have.
  • citric acid As pH adjusting agent, citric acid, acetic acid, malic acid, tartaric acid, succinic acid or lactic acid among organic acids were used.
  • Vinegar was used brewed vinegar (natural food).
  • the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.
  • An indicator fiber softener was used instead of the fabric softener composition.
  • the indicator fabric softener was produced by the test method in EL306 (fiber softener) of the environmental label certification standard of Korea Environmental Industry and Technology Institute as TEA Ester Quaternary of LG H & H.
  • the cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).
  • the content of calcium carbonate remaining in the garment after washing and rinsing was measured using the fabric softener composition prepared by the above-described examples and comparative examples.
  • the garments used three white standard cotton cloths (10 X 10 cm) as specified in KS K 0905, and the laundry detergents were powdered detergent (LG Health, Tech) containing calcium carbonate, which is readily available on the market.
  • Washing was based on the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute, and the amount of the fabric softener composition was 0.67 mL / L at the last rinsing.
  • Example 2 Example 3
  • Example 4 Example 5
  • Example 6 Example 7
  • Example 8 Example 9 Calcium Carbonate Content 0 37 65 45 40 56 50 25 30
  • the fiber softener composition using citric acid in the organic acid was excellent in the ability to remove calcium carbonate, and in Comparative Example 3 using the same amount of cationic surfactant as the organic acid, it was confirmed that there was no effect of removing calcium carbonate.
  • the amount of zeolite remaining in the garment after washing and rinsing was measured using the fabric softener compositions prepared by the above-described examples and comparative examples.
  • the garments used three white standard cotton cloths (10 ⁇ 10 cm) as specified in KS K 0905, and the laundry detergent was a powdered detergent (LG Health, Tech) containing zeolite, which is readily available on the market.
  • LG Health, Tech powdered detergent
  • Washing was based on the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute, and the amount of the fabric softener composition was 0.67 mL / L at the last rinsing.
  • the analysis of zeolite residue in the garment after washing rinsing was analyzed by using ICP (high frequency inductively coupled plasma) after extracting 0.5 g of the cotton rinsing-washed cotton, acid-treated with a mixture of hydrochloric acid, hydrofluoric acid, nitric acid and boric acid, and extracting for 24 hours. .
  • Example 4 Example 5
  • Example 6 Example 7
  • Example 8 Zeolite content 0 3 10 7 7 8 8 2 2
  • Citric acid in organic acid was used as a pH adjuster.
  • Vinegar was used brewed vinegar (natural food).
  • the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.
  • a cationic surfactant was added to purified water at 60 ° C. and stirred for 20 minutes to prepare a fabric softener composition.
  • the cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).
  • Example 11 Example 12
  • Example 13 Example 14
  • Cationic surfactant 5 - - - - - - - Citric acid - 20 10
  • One 10 Flower Fermented Vinegar - - - - - - One One vinegar - - - - - - One Spices 0.5 ethanol 5 Fragrance Solubilizer 5 Antifoam 0.05 Purified water Up to 100% by weight
  • the coefficient of friction of the garment was measured after washing and rinsing using the fabric softener composition prepared according to the above-described examples and comparative examples.
  • Washing was based on the test method in EL306 (Fiber Softener) among the environmental label certification standards of Korea Environmental Industry and Technology Institute, and the amount of the fabric softener composition was 0.67 mL / L at the last rinsing.
  • the conditions of measurement of the coefficient of friction of the garment were measured using a moving speed of 25 cm / min, weight of 160 g, and NBR (Nitrile Butadiene Rubber). The measurement was carried out to measure the load that occurs when the weight is moved at a constant speed after placing the treated standard cotton cloth on the test plate and placing the weight.
  • the slipperiness index was measured by sensory evaluation of 10 professional monitors, and 5 points were considered as slippery.
  • Comparative Example 1 which was rinsed only with water, showed an increased friction coefficient and the surface was too rough
  • Comparative Example 2 which was rinsed with the indicator fiber softener
  • Comparative Example 3 which was rinsed with the fabric softener containing a cationic surfactant, showed severe slipperiness.
  • a pH adjuster i.e., an organic acid
  • citric acid, vinegar, and flower fermentation vinegar were added to purified water and stirred for 30 minutes. Then, a solution in which ethanol, a solubilizing agent, and an antifoam were dissolved was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition.
  • vinegar used brewed vinegar (natural food).
  • the flower fermented vinegar was washed with jasmine petals and dried, and then 15 parts by weight of vinegar and 15 parts by weight of sugar and 1 part by weight of the dried petals were mixed with the dried petals were obtained through a natural fermentation process for about 7 days.
  • a cationic surfactant was added to purified water and stirred for 30 minutes. Then, a solution in which ethanol, a solubilizing agent and an antifoam were dissolved was added thereto, followed by stirring for 30 minutes to prepare a fabric softener composition.
  • the cationic surfactant was TEA Ester Quaternary (INCI Name: dihydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).
  • Example 21 Comparative Example 5 Flower Fermented Vinegar - - - - 0.5 0.5 - Cationic surfactant - - - - - 5 Citric acid 0.1 One 10 20 10 10 - vinegar - - - - - One - Spices 0.5 ethanol 5 Fragrance Solubilizer 5 Antifoam 0.05 Purified water Up to 100% by weight
  • the water repellency of Gore-Tex outdoor clothing was measured using the fabric softener compositions of Examples and Comparative Examples.
  • the Gore-Tex used in the test was purchased directly from the commercial Gore-Tex garment [ISUKA's GORE-TEX cover], and the laundry detergent was used by LG H & H.
  • the water repellency criterion is based on the AATCC (American Textile Chemical Dyeing Association), and it is classified as 5th grade (without surface adhesion or wetting), 4th grade (with slight adhesion or wetting on the surface), Grades 3 (wetting where the water dropped), 2nd (partial wetting over the entire surface), and 1st level (wetting the surface completely).
  • Vinegar was used brewed vinegar (natural food).
  • the fabrication process of the fabric softener composition was performed in the same manner as in the above embodiment except that a cationic surfactant was added instead of citric acid.
  • the cationic surfactant was Polymer LR30M manufactured by DOW Chemical.
  • Example 26 Cationic surfactant 5 - - - - - - Citric acid - 2 5 20 20 20 Thickening Polymer 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Spices 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 ethanol 5 5 5 5 5 5 5 Fragrance Solubilizer 5 5 5 5 5 5 5 Antifoam 0.05 0.05 0.05 0.05 0.05 vinegar - - - - - 1.0 Flower Fermented Vinegar - - - - 0.5 0.5 Purified water Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight Up to 100% by weight
  • Washing test conditions were based on the test method in EL306 (Fiber Softener) among the environmental label certification criteria of the Korea Environmental Industry and Technology Institute.
  • the amount of the composition was 0.67 mL / L at the last rinsing.
  • the sensory evaluation of the replaced odor removal ability was not good, but was lower than 4 points of citric acid and / or flower fermentation.
  • the replaced odor removal ability was excellent with a sensory evaluation of 4 or more points.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

La présente invention concerne une composition pour un assouplissant pour textile qui contient un régulateur de pH, ne contient pas de tensioactif cationique, et ne produit pas plus de 90 ppm de carbonate de calcium restant dans un textile qui a subi un lavage et un rinçage selon un procédé d'essai de l'écolabel EL306 ; la composition pour l'assouplissant pour textile dissout et élimine très efficacement du textile le carbonate de calcium, qui est insoluble dans un détergent. La présente invention concerne une composition pour un assouplissant pour textile qui contient un régulateur de pH, ne contient pas de tensioactif cationique, et ne produit pas plus de 20 ppm de zéolite restant dans un textile qui a subi un lavage et un rinçage selon un procédé d'essai de l'écolabel EL306 ; la composition pour l'assouplissant pour textile dissout et élimine très efficacement du textile la zéolite, qui est insoluble dans un détergent. La présente invention concerne une composition pour un assouplissant pour textile qui contient un régulateur de pH, ne contient pas de tensioactif cationique, et permet d'obtenir un coefficient de frottement de 2 à 25 dans un textile qui a subi un lavage et un rinçage selon un procédé d'essai de l'écolabel EL306, ce qui permet d'obtenir une sensation sèche et duveteuse après utilisation, au lieu d'une sensation glissante, de l'article séché. En outre, la composition pour l'assouplissant pour textile, selon la présente invention, utilise le régulateur de pH au lieu du tensioactif cationique, qui est nocif pour le corps, ayant ainsi d'excellents effets hydrofuges/perméables à l'humidité dans un vêtement d'extérieur de type Gore-Tex. En outre, la présente invention permet d'éliminer efficacement l'odeur d'humidité après lavage grâce à l'utilisation d'un acide organique au lieu du tensioactif cationique.
PCT/KR2015/001841 2014-02-25 2015-02-25 Composition pour assouplissant pour textile Ceased WO2015130085A1 (fr)

Priority Applications (2)

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CN201580010356.6A CN106029857B (zh) 2014-02-25 2015-02-25 纤维柔顺剂组合物
JP2016554203A JP6817065B2 (ja) 2014-02-25 2015-02-25 繊維柔軟剤組成物

Applications Claiming Priority (38)

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KR10-2014-0021927 2014-02-25
KR20140021927 2014-02-25
KR20140021928 2014-02-25
KR10-2014-0021928 2014-02-25
KR20140052638 2014-04-30
KR10-2014-0052635 2014-04-30
KR10-2014-0052638 2014-04-30
KR20140052634 2014-04-30
KR10-2014-0052636 2014-04-30
KR20140052635 2014-04-30
KR10-2014-0052634 2014-04-30
KR10-2014-0052642 2014-04-30
KR20140052642 2014-04-30
KR20140052636 2014-04-30
KR10-2014-0102206 2014-08-08
KR1020140102208A KR20150125514A (ko) 2014-04-30 2014-08-08 섬유유연제 조성물
KR1020140102210A KR20150125516A (ko) 2014-04-30 2014-08-08 섬유유연제 조성물
KR10-2014-0102207 2014-08-08
KR10-2014-0102212 2014-08-08
KR1020140102207A KR20150100465A (ko) 2014-02-25 2014-08-08 섬유유연제 조성물
KR1020140102206A KR20150100464A (ko) 2014-02-25 2014-08-08 섬유유연제 조성물
KR10-2014-0102216 2014-08-08
KR10-2014-0102210 2014-08-08
KR1020140102212A KR20150125518A (ko) 2014-04-30 2014-08-08 섬유유연제 조성물
KR10-2014-0102209 2014-08-08
KR10-2014-0102208 2014-08-08
KR1020140102209A KR20150125515A (ko) 2014-04-30 2014-08-08 섬유유연제 조성물
KR1020140102216A KR20150125522A (ko) 2014-04-30 2014-08-08 섬유유연제 조성물
KR1020150025433A KR20150100544A (ko) 2014-02-25 2015-02-23 섬유유연제 조성물
KR10-2015-0025437 2015-02-23
KR1020150025436A KR101809786B1 (ko) 2014-02-25 2015-02-23 섬유유연제 조성물
KR1020150025437A KR102123613B1 (ko) 2014-02-25 2015-02-23 섬유유연제 조성물
KR10-2015-0025433 2015-02-23
KR10-2015-0025434 2015-02-23
KR1020150025435A KR20150100546A (ko) 2014-02-25 2015-02-23 섬유유연제 조성물
KR1020150025434A KR101703138B1 (ko) 2014-02-25 2015-02-23 섬유유연제 조성물
KR10-2015-0025435 2015-02-23
KR10-2015-0025436 2015-02-23

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US11072768B2 (en) 2018-11-07 2021-07-27 The Procter & Gamble Company Low pH fabric care compositions
US11781093B2 (en) 2018-11-07 2023-10-10 The Procter & Gamble Company Process for treating a fabric and related compositions

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11072768B2 (en) 2018-11-07 2021-07-27 The Procter & Gamble Company Low pH fabric care compositions
US11781093B2 (en) 2018-11-07 2023-10-10 The Procter & Gamble Company Process for treating a fabric and related compositions

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