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WO2014191071A1 - Chiffon de nettoyage - Google Patents

Chiffon de nettoyage Download PDF

Info

Publication number
WO2014191071A1
WO2014191071A1 PCT/EP2014/000972 EP2014000972W WO2014191071A1 WO 2014191071 A1 WO2014191071 A1 WO 2014191071A1 EP 2014000972 W EP2014000972 W EP 2014000972W WO 2014191071 A1 WO2014191071 A1 WO 2014191071A1
Authority
WO
WIPO (PCT)
Prior art keywords
cleaning cloth
pva
textile
pvf
cleaning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2014/000972
Other languages
German (de)
English (en)
Inventor
Volker RITTHALER
Jörg Dunkel
Jörg Hausdorf
Gerrius VROOM
Andreas Eisenhut
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Carl Freudenberg KG
Original Assignee
Carl Freudenberg KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carl Freudenberg KG filed Critical Carl Freudenberg KG
Priority to ES14726877T priority Critical patent/ES2717670T3/es
Priority to KR1020157036593A priority patent/KR101813152B1/ko
Priority to RU2015155558A priority patent/RU2635158C2/ru
Priority to CN201480029597.0A priority patent/CN105229222B/zh
Priority to EP14726877.5A priority patent/EP3004453B1/fr
Publication of WO2014191071A1 publication Critical patent/WO2014191071A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16—Cloths; Pads; Sponges
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/244—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons
    • D06M15/256—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of halogenated hydrocarbons containing fluorine
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/04—Processes in which the treating agent is applied in the form of a foam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/347—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated ethers, acetals, hemiacetals, ketones or aldehydes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/14—Processes for the fixation or treatment of textile materials in three-dimensional forms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material

Definitions

  • the invention relates to a cleaning cloth having a textile carrier material and a coating or impregnation thereon.
  • the cleaning cloths may have a simple structure, for example by being formed from a monolayer textile base body. It is important for the cleaning cloth that it absorbs the dirt from the surface to be cleaned well and returns as completely as possible during the wringing process. In addition, the water absorption and -abgäbe the cloth is important. On the one hand, water is used to dissolve adhering water
  • the cleaning cloth should slide rather easily to achieve a good ergonomics and low effort when wiping.
  • users prefer often wipes with a higher friction, so that adhering dirt can be better removed, or the cleaning process is also haptically detectable.
  • textile carrier materials can be provided with a coating or impregnation.
  • textile materials can be provided with a polyurethane (PU) coating or impregnation.
  • PU polyurethane
  • the application of the PU coating or impregnation mass is carried out according to common practice of the type that the substrate is immersed in a solution of PL) and dimethylformamide (DMF).
  • Another known method is the coating or impregnation of a textile carrier material consisting of PVA (polyvinyl alcohol) fibers with a PVF microfoam.
  • PVA polyvinyl alcohol
  • Coating material is achieved.
  • the object of the invention is based, a
  • Cleaning cloth should also be achieved a very good cleaning effect.
  • the cleaning cloth the dirt, especially loose dirt particles, when flushing again can easily and easily. This can be prevented, for example, that recorded sand (eg with quartz components) when cleaning chrome-plated / polished surfaces these are scratched or damaged.
  • the cleaning cloth should allow a gentle cleaning of objects or surfaces.
  • the coating, or impregnation should show sufficient adhesion to the textile substrate to a corresponding
  • Range of action AB a weight loss of the cleaning cloth of less than 5 wt.% Is present.
  • a cleaning cloth comprising a textile carrier material which is at least partially provided with a PVF microfoam in such an amount that the proportion of PVF microfoam on the total weight of the cleaning cloth less than 60 wt.%, Preferably less than 50 % By weight and which does not have PVA fibers or PVA fibers in an amount of less than 50% by weight.
  • the cleaning cloth according to the invention is characterized in that it has a non-PVA fibers textile substrate, which is provided with a PVF microfoam.
  • the PVF microfoam may be present as a coating and / or impregnation and have pore sizes below 00 pm.
  • the microfoam is both as
  • the cleaning cloth according to the invention has an excellent washing resistance. This is surprising insofar as it has always been assumed that it is necessary for a high resistance that a PVA fiber has to be coated or impregnated with a PVA solution.
  • Cleaning cloth according to the invention by a good mechanical stability during cleaning and in particular in the machine wash.
  • the proportion of PVA, in particular of PVA fibers may be less than 50% by weight or even less than 30% by weight, or even less than 10% by weight and in particular less than 5% by weight.
  • the cleaning cloth can not be PVA,
  • Micro foam structure has a significant share for the good connection of the non-PVA-like carrier with the PVF coating.
  • the textile carrier material is at least partially provided with a PVF microfoam in such an amount that the proportion of PVF microfoam in the total weight of the cleaning cloth is less than 50% by weight, preferably less than 30%.
  • a PVF microfoam in such an amount that the proportion of PVF microfoam in the total weight of the cleaning cloth is less than 50% by weight, preferably less than 30%.
  • Fleece fibers, or filaments can enclose on all sides.
  • Penetration of the substrate by the PVF microfoam can also be achieved by using a PVA solution that has a rather low viscosity.
  • the PVF (Pol vinylformal) microsphere as known to those skilled in the art, can be formed by reacting PVA with formaldehyde. This reduces the water solubility of the PVA.
  • the PVF microfoam preferably has a solubility in water at 100 ° C. of less than 5% by weight.
  • the textile carrier material consists at least proportionally of a microfiber material. This embodiment may be for some
  • Microfibre yarns may have a high water absorption capacity (e.g., in% relative to the dry weight of the fabric).
  • the cleaning cloth has hydrophobic materials in combination with hydrophilic materials (PVF microfoam) and is thus overall amphiphilic.
  • Cleaning cloth has a high cleaning effect for both oleophilic and hydrophilic dirt, which makes it suitable for a variety of applications.
  • PVF polyvinyl styrene
  • hydrophilicity of the PVF material is further enhanced by being used in the form of a microfoam. This material has due to the Feinporig maschine the
  • PVF microfoam structure on an even higher hydrophilicity.
  • the PVF microfoam may be the fibers and optionally yarns of the textile
  • Coating / impregnation can be achieved. This is particularly advantageous if hydrophobic materials are used as carrier material, since the PVF microfoam actually does not have good adhesion to such materials.
  • a preferred embodiment of the invention is a
  • Nonwoven backing material combined with a PVF microfoam. It is advantageous that nonwovens are simple and inexpensive to produce and the cleaning cloth yet by an excellent
  • Knitted a high washing stability is further facilitated by the fact that the knitted or knitted base material already in itself a high
  • Impregnation of PVF advantageously has a basis weight of 10 to 150 g / m 2 , preferably from 50 to 100 g / m 2 .
  • the textile substrate advantageously has a basis weight of 80 to 200 g / m 2 , preferably from 90 to 80 g / m 2 , in particular from 100 to 140 g / m 2 , on.
  • hydrophobic is understood according to the invention in the conventional sense.
  • materials are considered to be hydrophobic, in which water has a contact angle of greater than or equal to 90 ° on the surface of a compact body formed from them.
  • the contact angle may be known e.g. be determined with a contact angle measuring device from Krüss.
  • fibers made of a hydrophilic material have also proven to be suitable.
  • Fibers made of the following materials have proven to be particularly suitable: polyamide or polyester, viscose, hydrophobized viscose, hydrophilized viscose, modified polyester, polyacrylonitrile, triacetate, acetate, polyolefins such as polyethylene and polypropylene, polyvinyl chloride and / or mixtures thereof.
  • polyamide in particular polyamide 6 or 66, polyethylene and / or polyester,
  • Fibers made of polyester, viscose, polyethylene and in particular mixtures thereof have proved to be particularly suitable according to the invention.
  • such a textile carrier material contains polyester, in particular PET and / or modified polyester. This can be used either as an exclusive raw material or blended with other fibers (e.g., viscose).
  • the used fiber titer can range between 0.05 and 3 dtex. For some applications, it is useful when in the
  • Range of a microfiber that is between 0.1 and 1 dtex.
  • the advantage of using the microfibers is that they show good cleaning results, are very soft and thus provide a pleasant feel.
  • microfibers with a titre of 0.05 to 1.0 dtex, in particular 0.1 to 0.7 dtex, can be used.
  • Microfoam cleaning wipes can be obtained in which the textile and soft feel of the substrate is maintained although the PVF microfoam basically loses its softness in the dry state and. thus leading to a largely flexible cleaning cloth.
  • the cleaning cloth has a total basis weight of from 90 to 350 g / m 2 , more preferably from 200 to 300 g / m 2 . It can do that
  • Cleaning cloth fibers preferably in an amount of 60 to 200 g / m 2 , more preferably from 100 to 120 g / m 2 included.
  • the fibers used for the production of the textile fabric can be inexpensively in a wide variety of Finishes and colors are provided and the PVA coating, or impregnation can be applied in a simple manner by conventional methods.
  • the fabric is preferably provided with a full-surface coating or impregnation.
  • Embodiment is that the full-surface coating, or impregnation solidifies the sheet and thus increases its stability.
  • the high proportion of hydrophilic PVF on the one hand the
  • both consolidated and unconsolidated textile base materials can be used as the textile fabric.
  • the textile substrate is at least partially mechanically, thermally and / or chemically solidified.
  • the consolidation of the randomly arranged or partially aligned fibers can be effected mechanically by needling and / or thermally and / or chemically.
  • the fabric is preferably in the form of a nonwoven fabric, a knitted fabric, a knitted fabric, a fabric, fabric,
  • Braid a knitted fabric, a felt, fleece, a tufted fabric, a fabric, combinations of the like and other planar structures.
  • Particularly preferred according to the invention is the use of nonwovens.
  • Nonwovens offer the advantage that they can be produced easily and inexpensively.
  • the basis weight of the cleaning cloth can vary depending on the desired application. As suitable for most purposes have basis weights of 90 to 350 g / m 2 , preferably 180 to 230 g / m 2 proved.
  • the textile substrate can be easy to clean and / or flameproof.
  • the fibers may be composed of polymers containing additives, such as color pigments, permanently acting
  • the textile substrate may further comprise fibers (staple fibers or
  • the textile fabric Due to the advantageous properties of the textile fabric, its use as a cleaning textile is recommended. So it can be made of it, for example, wiping or cleaning cloths.
  • Sheet a print pattern of abrasives, for example
  • polishing particles applied.
  • the polishing particles could be formed for example by silica. These particles result in a cleaning cloth with a slightly abrasive effect.
  • the abrasive can be applied in a simple printing process in a variety of variants on the textile substrate.
  • pretreat the textile substrate e.g. a printing, calendering or partial embossing in question.
  • a colorless PVF microfoam in particular the printing can remain visible even after the coating or impregnation still durable and wash stable.
  • the cleaning cloth For professional cleaning, it is advantageous to design the cleaning cloth in different colors so as to mark the use of a cloth in only one cleaning area (e.g., sanitary area).
  • the dyeing of the cloth can be done, for example, in the following ways:
  • the textile substrate is already used partially or fully colored. In combination with a colorless PVF order remains the
  • the PVA solution used to make the PVF microfoam may also be mixed with a colored pigment.
  • a colorless, and thus cheaper carrier material can be selected and the color of the cleaning cloth can be omitted entirely or only in the later step of the PVF coating, or
  • Impregnation can be selected and adjusted. This has particular logistic advantages. Again, the dye can be chosen so that it can be permanently wash stable and in particular without bleeding introduced into the PVF material.
  • a further subject of the present invention comprises a process for producing the cleaning cloth according to the invention, comprising the following steps:
  • a fabric having no PVA or PVA in an amount of less than 50% by weight is prepared or provided as a base fabric.
  • This is then mixed with a PVA-containing aqueous solution by conventional application methods, for example the padding method, a doctor blade method, a
  • the aqueous PVA solution and / or suspension contains further addition substances, such as color pigments or other additives or particles, such as the abovementioned abrasive.
  • the PVA solution preferably contains a solids content of PVA between 1 and 10% by weight, preferably between 3 and 7% by weight.
  • a textile structure can be produced in a simple and highly productive manner, which has a PVF-containing coating or impregnation.
  • the PVF-containing coating or impregnation can penetrate into the textile base material, whereby it is firmly anchored in the textile base material.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)

Abstract

L'invention concerne un chiffon de nettoyage comprenant un matériau de support textile, lequel est pourvu au moins en partie d'une micro-mousse de polyfluorure de vinyle dans une quantité telle que la proportion de micro-mousse de polyfluorure de vinyle sur le poids total du chiffon de nettoyage est inférieure à 60 % en poids, de préférence inférieure à 40 % en poids. Le matériau de support textile ne présente pas d'alcool polyvinylique ou de l'alcool polyvinylique à raison de moins de 50 % en poids.
PCT/EP2014/000972 2013-05-28 2014-04-11 Chiffon de nettoyage Ceased WO2014191071A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
ES14726877T ES2717670T3 (es) 2013-05-28 2014-04-11 Paño de limpieza
KR1020157036593A KR101813152B1 (ko) 2013-05-28 2014-04-11 세척천
RU2015155558A RU2635158C2 (ru) 2013-05-28 2014-04-11 Чистящий материал
CN201480029597.0A CN105229222B (zh) 2013-05-28 2014-04-11 清洁布
EP14726877.5A EP3004453B1 (fr) 2013-05-28 2014-04-11 Chiffon de nettoyage

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013008985.9A DE102013008985A1 (de) 2013-05-28 2013-05-28 Reinigungstuch
DE102013008985.9 2013-05-28

Publications (1)

Publication Number Publication Date
WO2014191071A1 true WO2014191071A1 (fr) 2014-12-04

Family

ID=50841731

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2014/000972 Ceased WO2014191071A1 (fr) 2013-05-28 2014-04-11 Chiffon de nettoyage

Country Status (7)

Country Link
EP (1) EP3004453B1 (fr)
KR (1) KR101813152B1 (fr)
CN (1) CN105229222B (fr)
DE (1) DE102013008985A1 (fr)
ES (1) ES2717670T3 (fr)
RU (1) RU2635158C2 (fr)
WO (1) WO2014191071A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018162328A1 (fr) * 2017-03-08 2018-09-13 Carl Freudenberg Kg Article de nettoyage

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102017003028A1 (de) * 2017-03-29 2018-10-04 Delu Ako Minky GmbH Reinigungstuch mit Appretur
RU2710756C1 (ru) * 2019-05-14 2020-01-13 Общество С Ограниченной Ответственностью "Юрьев-Польская Ткацко-Отделочная Фабрика "Авангард" Способ получения текстильного материала для чистящих изделий
DE102019123275A1 (de) 2019-08-30 2021-03-04 Carl Freudenberg Kg Reinigungsartikel mit schmutzabweisenden Eigenschaften
DE102019123274A1 (de) * 2019-08-30 2021-03-04 Carl Freudenberg Kg Reinigungsartikel, der Mikrokapseln enthält

Citations (7)

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Publication number Priority date Publication date Assignee Title
DE2536440A1 (de) * 1975-08-16 1977-02-24 Freudenberg Carl Fa Saugfaehiges textiles flaechengebilde
DE3000806A1 (de) * 1980-01-11 1981-07-16 Christian Heinrich Sandler GmbH & Co KG, 8676 Schwarzenbach Tuch, insbesondere fuer reinigungszwecke
JPH02125725A (ja) * 1988-11-04 1990-05-14 Kuraray Co Ltd 高抱水性複合体およびその製造方法
JPH02200232A (ja) * 1989-01-30 1990-08-08 Kuraray Co Ltd 高抱水性拭浄材の製造方法
EP0987098A1 (fr) * 1998-09-16 2000-03-22 Financiere Elysees Balzac Produit essuyant, sa préparation, têtes de balais à franges et combinés de nettoyage l'incorporant
DE10345086A1 (de) * 2003-07-16 2005-02-03 Fleissner Gmbh Vollsynthetisches Wischtuch, Verfahren und Anlage zur Herstellung des Wischtuchs
WO2009098725A2 (fr) * 2008-02-06 2009-08-13 Toscana Non Tessuti S.R.L. Chiffon de nettoyage

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NL7308406A (fr) * 1973-06-18 1974-12-20
DE19845784C1 (de) * 1998-09-21 2000-02-17 Ufz Leipzighalle Gmbh Bakterienstamm Comamonas testosteroni MC1 und Verfahren zur mikrobiellen Dekontamination von mit Phenoxy-Herbiziden belasteten Materialien
DE10109474C1 (de) * 2001-02-28 2002-06-20 Sandler Helmut Helsa Werke Filtermaterialien mit bipolarer Beschichtung
JP2003164404A (ja) 2001-11-29 2003-06-10 Yuichiro Niizaki 洗浄処理具
DE102006052662A1 (de) * 2006-11-07 2008-05-08 Henkel Kgaa Schaumstoffschwamm mit Depotpartikeln
JP2009153687A (ja) 2007-12-26 2009-07-16 Lion Corp 床用清掃シート

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2536440A1 (de) * 1975-08-16 1977-02-24 Freudenberg Carl Fa Saugfaehiges textiles flaechengebilde
DE3000806A1 (de) * 1980-01-11 1981-07-16 Christian Heinrich Sandler GmbH & Co KG, 8676 Schwarzenbach Tuch, insbesondere fuer reinigungszwecke
JPH02125725A (ja) * 1988-11-04 1990-05-14 Kuraray Co Ltd 高抱水性複合体およびその製造方法
JPH02200232A (ja) * 1989-01-30 1990-08-08 Kuraray Co Ltd 高抱水性拭浄材の製造方法
EP0987098A1 (fr) * 1998-09-16 2000-03-22 Financiere Elysees Balzac Produit essuyant, sa préparation, têtes de balais à franges et combinés de nettoyage l'incorporant
DE10345086A1 (de) * 2003-07-16 2005-02-03 Fleissner Gmbh Vollsynthetisches Wischtuch, Verfahren und Anlage zur Herstellung des Wischtuchs
WO2009098725A2 (fr) * 2008-02-06 2009-08-13 Toscana Non Tessuti S.R.L. Chiffon de nettoyage

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Title
DATABASE WPI Week 199025, Derwent World Patents Index; AN 1990-190126, XP002727442 *
DATABASE WPI Week 199038, Derwent World Patents Index; AN 1990-285873, XP002727441 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018162328A1 (fr) * 2017-03-08 2018-09-13 Carl Freudenberg Kg Article de nettoyage

Also Published As

Publication number Publication date
EP3004453B1 (fr) 2019-01-16
RU2635158C2 (ru) 2017-11-09
RU2015155558A (ru) 2017-06-29
EP3004453A1 (fr) 2016-04-13
CN105229222A (zh) 2016-01-06
DE102013008985A1 (de) 2014-12-04
KR20160012218A (ko) 2016-02-02
ES2717670T3 (es) 2019-06-24
KR101813152B1 (ko) 2017-12-28
CN105229222B (zh) 2018-03-23

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