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WO2014164751A1 - Réacteur pour biomasse - Google Patents

Réacteur pour biomasse Download PDF

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Publication number
WO2014164751A1
WO2014164751A1 PCT/US2014/023390 US2014023390W WO2014164751A1 WO 2014164751 A1 WO2014164751 A1 WO 2014164751A1 US 2014023390 W US2014023390 W US 2014023390W WO 2014164751 A1 WO2014164751 A1 WO 2014164751A1
Authority
WO
WIPO (PCT)
Prior art keywords
biomass
ground
auger
conveying
auger reactor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2014/023390
Other languages
English (en)
Inventor
Michael C. Cheiky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cool Planet Energy Systems Inc
Original Assignee
Cool Planet Energy Systems Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/797,985 external-priority patent/US20130192971A1/en
Application filed by Cool Planet Energy Systems Inc filed Critical Cool Planet Energy Systems Inc
Priority to CN201480027260.6A priority Critical patent/CN105209577A/zh
Publication of WO2014164751A1 publication Critical patent/WO2014164751A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28—Other processes
    • C10B47/32—Other processes in ovens with mechanical conveying means
    • C10B47/44—Other processes in ovens with mechanical conveying means with conveyor-screws
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin

Definitions

  • the present invention is directed towards clean energy, and more particularly, some embodiments of the invention provide systems and methods for biomass fractioning.
  • pyro lysis Pyrolyzing wood and other forms of mixed biomass produces coke (which is sometimes called biochar) and a mixture of hydrogen, carbon monoxide and carbon dioxide, sometimes referred to as syngas.
  • Roasting fossil fuel hydrocarbons in an oxygen- free environment first causes a breakdown of longer chain hydrocarbons into shorter chain hydrocarbons, ultimately resulting in more elemental forms such as methane (CH 4 ), hydrogen, and elemental carbon.
  • pyrolysis is a fundamental mechanism of petrochemical cracking, which is the backbone of oil refinery processes. More extreme pyrolysis is used in the refinery process to produce hydrogen and high purity carbon.
  • biomass which is made up of cellulose, hemicelluloses, lignin, starches, and lipids
  • biomass proceeds through multiple steps of decomposition when subject to the pyrolysis process.
  • high temperatures e.g., 800°C
  • pyrolysis ultimately yields syngas.
  • an increasing amount of biochar residue remains.
  • increasingly complex hydrocarbons and oxygenated hydrocarbons are present in the gas stream from the pyrolyzed biomass.
  • simple everyday cooking typically drives off water and starts to dehydrolyze the biomass, causing the darkening and carmelization that we all associate with cooked foods.
  • Configurations include simple tube furnaces where the biomass is roasted in ceramic boats, ablative pyrolyzers where wood is rubbed against a hot surface, various forms of fluidized bed pyrolyzers where biomass is mixed with hot sand, and various simpler configurations that are based on earlier coking oven designs.
  • the fundamental problem with the resultant pyrolysis oil is that it is made up of hundreds to thousands of compounds, which are the result of subjecting the raw biomass to a wide range of temperature, time, and pressure profiles in bulk. When this process is complicated by the thousands of major bio-compounds in the original biofeedstock, the result is a nearly intractable array of resultant compounds all mixed together.
  • Pyrolysis oils from such processes are typically not thermodynamically stable. They contain active oxygenated free radicals that are catalyzed by organic acids and bases such that these oils typically evolve over a period of a few days from light colored liquids to dark mixtures with tar and resinous substances entrained in the mix.
  • Various embodiments of this invention provide systems and methods for biomass fractioning that addresses the major issues of biomass pyrolysis as detailed above while still utilizing the fundamental mechanism of heating biomass materials in a reduced oxygen, neutral or reducing environment. Certain embodiments of invention may be referred to as biomass fractionators.
  • An embodiment of the invention comprises a system for biomass fractioning, comprising: means for receiving ground biomass into the system; and a plurality of biomass processing stations including means for heating the biomass and subjecting the biomass to biofractioning, and means for collecting residual carbon and biochar.
  • the means for heating the biomass and subjecting the biomass to biofractioning comprises an auger reactor, wherein the auger reactor comprises means for extracting a process gas stream containing one or more volatile components.
  • the means for heating the biomass and subjecting the biomass to biofractioning comprises: means for feeding the biomass into a feeder of an auger reactor; means for conveying biomass through the auger reactor; and means for heating the biomass as it is conveyed through the auger reactor.
  • the means for conveying the biomass can comprises a transfer screw powered by an external motor.
  • the means for receiving ground biomass may comprise: means for storing and funneling ground biomass; means for dispensing ground biomass from the hopper; means for receiving ground biomass from the dispenser; and means for moving ground biomass within the biomass load dump station.
  • the plurality of biomass processing stations further might comprise means for compressing ground biomass such as a heated pulverizing processing station.
  • the plurality of biomass processing stations is implemented as one or more discs.
  • the plurality of biomass processing stations is implemented as a series of interconnected plates configured in an oval configuration.
  • a further embodiment of the invention comprises a method for biomass fractioning, comprising: receiving ground biomass; heating the biomass and subjecting the biomass to bio fractioning within a plurality of biomass processing stations; and collecting residual carbon and biochar.
  • the step of heating the biomass and subjecting the biomass to biofractioning may comprise conveying the biomass through an auger reactor.
  • the method may further comprise extracting a process gas stream containing one or more volatile components.
  • the step of heating the biomass and subjecting the biomass to biofractioning may comprise: feeding the biomass into a feeder of an auger reactor; conveying biomass through the auger reactor; and heating the biomass as it is conveyed through the auger reactor.
  • conveying the biomass can comprise conveying the biomass using a rotating a transfer screw powered by an external motor.
  • the step of receiving ground biomass may comprise: storing and funneling ground biomass; dispensing ground biomass from the hopper; receiving ground biomass from the dispenser; and moving ground biomass within the biomass load dump station.
  • the method further comprises compressing the ground biomass in a heated pulverizing processing station.
  • Some embodiments of the invention involve dispensing ground biomass into thin sheets for further processing. In doing so, an environment similar to laboratory scale tests is produced; however, the environment is scalable in that it can be expanded in two dimensions to any practical working throughput while retaining a constant thickness for heat treatment of incoming materials.
  • biomass pyro lysis products are effectively fractionated into various working streams, much like a crude oil cracking tower separates incoming fossil crude into various working streams.
  • modular mechanical constructs are used to facilitate multiple fractionating stations, all within a pressure vessel, which can operate below atmospheric pressure, in open air, and at elevated pressures up to and including temperatures and pressures required for supercritical water as a working medium.
  • Such embodiments incorporate multiple stage input and output airlocks to facilitate inputting biomass in bulk and discharging biochar and various fractionation streams from a potentially very high temperature and pressure internal environment, on an efficient basis.
  • Some embodiments further accommodate variable thermal isolation and gas flow isolation between the various modular pyrolysis processing stations described herein. This allows for improved fractionator yield by way of substantial changes in temperature, pressure and local gas composition at various processing stations.
  • Various embodiments of the invention are specifically designed to operate in a supercritical environment.
  • supercritical fluid environments provide both a substantial improvement in heat transfer as compared to gaseous environments and a substantial increase in chemical reaction rates, as compared to liquid environments due to their much, much higher rate of diffusion.
  • embodiments are designed to operate with supercritical carbon dioxide, supercritical water, methane, methanol and other small hydrocarbons, their oxygenates, and mixtures of the above such as 60% C02, 30% water, 10% methane and other organics.
  • the following table lists the supercritical parameters for some key constituents.
  • Figure 1 is a diagram of example biomass reaction compartments m
  • FIG. 2 is a diagram of an example load and dump station for ground biomass in accordance with one embodiment of the invention.
  • FIG. 3 is a diagram of an example heating and pulverizing processing station in accordance with one embodiment of the invention.
  • FIG. 4 is a diagram of an example biochar processing station in accordance with one embodiment of the invention.
  • FIG. 5 is a diagram of an example biomass fractionator system of six stations in accordance with one embodiment of the invention.
  • Figure 6 is a flow diagram illustrating a method of making negative carbon fuel in accordance with an embodiment of the invention.
  • Figure 7 is a flow diagram illustrating a method in which biomass is the carbon-containing input in accordance with an embodiment of the invention.
  • Figure 8A is a flow diagram illustrating a method in which biomass is the carbon-containing input and biofractionation is the process which produces negative carbon fuel.
  • Figure 8B is a diagram illustrating an auger reactor and associated method of use in accordance with an embodiment of the invention.
  • biomass includes any material derived or readily obtained from plant sources. Such material can include without limitation: (i) plant products such as bark, leaves, tree branches, tree stumps, hardwood chips, softwood chips, grape pumice, sugarcane bagasse, switchgrass; and (ii) pellet material such as grass, wood and hay pellets, crop products such as corn, wheat and kenaf. This term may also include seeds such as vegetable seeds, sunflower seeds, fruit seeds, and legume seeds.
  • biomass can also include: (i) waste products including animal manure such as poultry derived waste; (ii) commercial or recycled material including plastic, paper, paper pulp, cardboard, sawdust, timber residue, wood shavings and cloth; (iii) municipal waste including sewage waste; (iv) agricultural waste such as coconut shells, pecan shells, almond shells, coffee grounds; and (v) agricultural feed products such as rice straw, wheat straw, rice hulls, corn stover, corn straw, and corn cobs.
  • waste products including animal manure such as poultry derived waste
  • commercial or recycled material including plastic, paper, paper pulp, cardboard, sawdust, timber residue, wood shavings and cloth
  • municipal waste including sewage waste
  • agricultural waste such as coconut shells, pecan shells, almond shells, coffee grounds
  • agricultural feed products such as rice straw, wheat straw, rice hulls, corn stover, corn straw, and corn cobs.
  • Figure 1 is a diagram of example biomass reaction compartments in
  • biomass reaction compartments can be machined or cast into solid discs (1, 2, 3). These discs may rotate via any of a number of common drive mechanisms such as gear drives, chain drives, ratcheting sprockets, etc..
  • the disc can rotate continuously. However, to simplify operation of individual processing stations, it may be desirable to step the disc, typically with the same number of indexes per rotation as there are biomass chambers.
  • embodiments of the invention can have one or more chambers in a disc, preferably there are 4 to N chambers in a disc.
  • the biomass chamber is much wider and longer than it is thick.
  • a preferred thickness for the chamber for uncompressed biomass is approximately 3 ⁇ 4" in thickness.
  • the emerging biochar quickly condenses to a layer about 1/10" thick.
  • these biomass chambers can be sized in width and length along with the diameter of their corresponding drive disc to any such size as appropriate for the desired throughput for the biomass fractionator.
  • a 34" diameter disc of 1" thick 316 stainless steel can have six chambers ( 4" wide X 10" long X 3 ⁇ 4" deep) indexed to the perimeter of the disc.
  • Such a disc can efficiently process about 130 grams of dry biomass per chamber. When operating at 20 rotations per minute, 20 hours per day for 250 days per year, the disc can produce over 500,000 gallons per year of useful bio-intermediary chemicals and biofuels.
  • drive discs can be made of inexpensive base materials such as cast iron that is coated, plated, or clad with corrosion resistant metals and/or ceramics.
  • the plates can feature various thermal isolation structures between the chambers such as honeycombs, voids, simple slots, insulation filled cavities, etc., to facilitate large temperature extremes between adjacent processing stations. Such structures may be positioned on the disc planar surface opposite the chamber cavities.
  • the top surface of the disc could be smoothed or coated with an appropriate solid-state lubricant to accommodate various types of gas seals between adjacent processing stations such as gas turbine style labyrinth seals, roller seals, sliding seals, or expandable/retractable seals.
  • the main disc is subdivided into a large series of interconnected plates that move around a designated race track in an oval configuration 4 with interconnection hinges 8.
  • processing stations can be located anywhere along the track, it may be preferable to arrange the processing stations in a linear manner along the straight portions of the oval track (at 5, 5 A, 6, 6A, 7, 7 A), rather than at positions along the circular part of the oval track.
  • only one side of the track contains processing stations.
  • Other embodiments feature a geometry adapted for very high throughput, wherein both sides of the track contain processing stations, such that the matching station on each side corresponds to its number and its alphabetic suffix.
  • FIG. 2 illustrates an example load and dump station for ground biomass comprising a hopper, a dispenser, an airlock, and a transfer mechanism in accordance with one embodiment of the invention.
  • this load and dump station comprises the first station at the lowest operating temperature of an embodiment.
  • Ground biomass e.g., 1/8" or smaller
  • a transfer plate (11, 11A) is retracted to the fill position by control bar (12, 12A) via conventional control schemes such as an air cylinder.
  • the slider bar and hopper are depicted in side view 13 and top view 14. While the transfer plate is in the left or fill position, airlock door 15 is pushed down to the closed position, contacting pressure bulkhead 16 through guide slots 17.
  • the airlock 15 is actuated by a common control scheme such as an air cylinder.
  • transfer fill slots 18 are located in the hopper fill zone 19.
  • the hopper sliding gate valve 10 is quickly retracted, filling the transfer fill slots 18 with ground biomass.
  • the sliding gate valve 10 is then quickly closed.
  • the transfer plate (11, 11A) is moved to the right, the biomass remains in the transfer slots ( 18, 18 A) due to the action of the pressure bulkhead 16 on the bottom and a slightly sloping compression plate 20 on top.
  • the transfer plate (11, 11A) approaches the airlock door 15, it is retracted, allowing the transfer plate (11, 11A) to proceed to the dump position as depicted in Figure 2.
  • air door 21 closes behind the transfer plate (11, 11A) and around the actuator bar (12, 12A) contacting the pressure bulkhead 16 through guide slots 22.
  • the chamber volume can be pressure equalized through port 23.
  • the transfer plate (11, 11A) can operate with both air doors (15, 21) open simultaneously during transfer and retract operations in a compact design suitable for relatively low-pressure operation up to a few atmospheres.
  • the airlock spacing 24 between air doors (15, 21) should be wide enough to allow one door to close before the next door opens. In this manner, airlock spacing 24 is wide enough to accommodate the full length of the transfer plate (11, 11A). Under such a scenario, pressurization equalization via port 23 is important for efficient operation.
  • biomass With the transfer plate (11, 11A) in the dump position as depicted in Figure 2, biomass is entrained in the transfer slots (18, 18 A) and is free to fall through transfer opening 25 on to a biomass compartment of disc (1, 2, 3) or hinged plate set 4.
  • the entrained biomass is constrained from above by fixed guide plates 26 and movable plungers 27.
  • the movable plungers 27 are then pushed down through the transfer slots (18, 18 A) to ensure essentially complete biomass transfer from the biomass transfer plate (11, 11A) to the disc (1, 2, 3) via drive mechanism 28, which can be operated by any conventional means such as an air cylinder.
  • the transferred biomass then rotates out of position under the pressure bulkhead (16, 20) at the same time the transfer plate (11, 11A) is retracted through the reversal of the air door sequence to the fill position where the process is repeated.
  • slot width to chamber height may be employed, e.g., l'h" width for a transfer plate thickness of 3 ⁇ 4".
  • Configuration adjustments for slots (18, 18A) and corresponding structures (26, 27, 28) may be appropriate with different biomass feedstock, varying water content, and varying working media conditions such as supercritical water based operation.
  • Figure 3 depicts an example of one or more heated pulverizing processing stations in accordance with one embodiment of the invention. Specifically, Figure 3 shows the top view 29 of a rotating disc (1, 2, 3) with a corresponding biomass processing chamber 30 operated on by two or more sets of compressing structures 31 shown in side view 32.
  • the compressing structures 31 are operated by matching sets of actuators (33, 34) through force distribution plates (35, 36).
  • Each compressing structure 31 can be equipped with gas vent slots 37, which become exposed and functional as each compressing block 31 A is pushed down into the biomass.
  • the disc (1, 2, 3) moves the incoming biomass from a load and dump station, such as depicted in Figure 2, to a heating and pulverizing station, such as depicted in Figure 3.
  • the biomass is held in place during this rotational movement by the floor of the disc (1, 2, 3), the sidewall and the top of the pressure vessel until it arrives at the first heating and pulverizing station (e.g. Figure 2), where the compressing blocks 31 A are at a rest position flush with the top of the chamber.
  • This position can be heated by electrical heating elements, direct flame combustion, or by directed jets of heated working gas or supercritical fluid.
  • the objective of the first working station is to drive off entrapped water and to perform first stage dehydration of the biomass while compacting it for more effective heat transfer at later stages.
  • biomass While biomass is being heated at this station, it is compressed and pulverized by the up/down action of two or more sets of compressing blocks 31 A. Water vapor is extracted primarily through the slots 37 and some parasitic leakage around the structure (31, 35, and 36).
  • the downward motion of the force bars (35, 36) can be limited to compact the dehydrating biomass to a designated thickness such as, for example, 3" thick.
  • processing time per station is .5 seconds less indexing time of about .1 seconds, or, .4 seconds. This will practically allow up to 10 pulverizing cycles at this relatively high disc rotating speed.
  • the high transfer rate also implies a high temperature -heating source to bring the biomass in biomass processing chamber 30 up to de-watering and first stage dehydration in the 150°C region.
  • At least one additional pulverizing station as depicted in Figure 3 is utilized as a third station in the fractioning sequence, after the biomass input station and the dewatering station.
  • this second heated pulverizing station in the sequence, the biomass is further heated and compacted to outgas commercially viable bio-intermediary compounds.
  • multiple such stations can be added in series around increasingly large discs (1, 2, 3), or, even longer processing chains via oval track 4.
  • Various combinations of temperature profile, pressure and working gas phase or supercritical media can be utilized to extract various compounds such as (i) long chain dehydrated sugars; (ii) lignin derived aromatics; (iii) lipid based oils; (iv) carbohydrate based furans; (v) shorter hydrocarbons; (vi) oxygenates such as butane, butanol, acetone, acetylaldehyde, aldehyde, methane, methanol, etc.; and (vii) ultimate syngas components (hydrogen, carbon monoxide, and carbon dioxide).
  • the station is heated to a higher temperature via the various heating schemes detailed above, and the material is compacted to a thinner layer with an increasing level of elemental carbon in the remaining biomass.
  • some embodiments later perform one or more stages of thermal processing that can eliminate the compaction mechanism (31, 33, 34, 35, 36) and simply substitute a gas or supercritical fluid pick off. Such a station can maximize the production of high purity carbon.
  • FIG. 4 depicts an example of a last processing station in accordance with one embodiment of the invention.
  • the processing station is positioned before the disc returns to the biomass fill hopper.
  • This unheated station empties the biomass chamber of residual carbon or biochar into an air-locked hopper for collection. Since this biochar has a propensity to fuse to the chamber floor and walls, a scraping knife action is used to transfer this remaining carbon to an output chute.
  • a vertical overview of this mechanism is depicted in view 51, and is depicted with horizontal cross section in view 52.
  • the main drive disc (1, 2, 3) is shown as elements (53, 53A) with the biomass chamber (54, 54A) surrounded by pressure vessel (55, 55A) and dump chute 38.
  • Scraping knife (39, 39A) is depicted in the rest position with scraper blade (40, 40A). It is pushed down by rollers or sliders (41, 41 A) and press bar 42 via any conventional means such as an air cylinder, and is retracted by any conventional means such as another air cylinder to dotted line position 43 in order to transfer the remaining carbon or biochar into the dump chute 38 to gate valve 44.
  • a simple gate valve can be used to discharge the biochar out of the system.
  • a dual gate valve 45 including pressure equalization port 46 should be utilized for efficient operation.
  • Figure 5 depicts an example of a complete system of six stations in accordance with one embodiment of the invention.
  • the illustrated system uses a 34" diameter disc (2, 53) at up to 20 rpm utilizing a supercritical working medium comprised mostly of carbon dioxide to produce up to 500,000 gallons per year of useful biointermediaries and biofuels.
  • the main disc (2, 53) is driven on its center axis by an indexing stepping motor 47. It is housed in a pressure vessel 48. Chopped biomass is dispensed into an input hopper 49 via the transfer plate mechanism 50 of Figure 2. The plate then indexes to position 57 where a heated pulverizing processing station as depicted in Figure 3 dehydrates the biomass.
  • the hopper and biomass transfer station (49, 50) loads the next sequential biomass reaction compartment.
  • the disc indexes to station 58 where the initial load of biomass is further heated and pulverized to release low boiling point bio-compounds and pyro lysis fragments.
  • the second load of biomass is moved from station #1 (57) to station #2 (58) where it is dehydrated and a third load of biomass is transferred from the hopper to a corresponding biomass reaction chamber.
  • This process continues around the circle until all stations are full, and then runs continuously until the last stations are emptied during the turn off process. As such, the description of this continuous stepping process will not be repeated in conjunction with the stations to follow, but is implied in their operation.
  • the first loaded biomass chamber then proceeds to station 59 where an even hotter pulverizing station as depicted in Figure 2 drives off heavier biomass fragments such as sugar derived furans and lignin derived aromatics.
  • the first biomass load moves to station 60, comprising a heater system and a gas venting system 61, to complete the pyro lysis process by driving the residual hydrocarbons off the biochar, typically in the form of syngas.
  • the disc then increments to station 62, comprising the biochar dumping station as depicted in Figure 4, which scrapes the biochar into an exit hopper 63.
  • the emptied biomass chamber then indexes back to the initial fill station and is sequenced around the disc as described herein throughout the normal operation of the biomass fractionator.
  • An optional cooling station 64 may be incorporated, as necessary, to reduce the wall temperature of the biomass reaction chamber prior to the next filling in order to ensure a consistent increasing temperature profile for incoming biomass.
  • the hopper is shut off or allowed to run out of material, and the remaining biomass processing stations are emptied through the biochar chute.
  • the biochar clearing knife station can readily clean out any partially processed or unprocessed stations. Such improperly processed materials will simply be dumped in an alternate collector at the bottom of the biochar collection chute 38.
  • FIG. 6 is a flow diagram illustrating a method of making negative carbon fuel in accordance with an embodiment of the invention.
  • the process may be performed by a system including any of the biomass reaction compartments and/or or stations described with respect to Figures 1-5. Additionally, one or more of the biomass reaction compartments and/or stations may comprise a biomass reactor such as biomass reactor 325 of Figure 8B.
  • a carbon-containing input 200 is processed in process 250 to produce concurrently combustible fuels and chemicals 290 and
  • sequesterable carbon 270 in a substantially uncontaminated and separate form.
  • Combustible fuels and chemicals 290 can be negative carbon, while carbon-containing input 200 can include, but is not limited to, biomass, biomass-containing material, hydrocarbons, oxygenates such as alcohols, aldehydes, ketones and ethers.
  • Process 250 refers to any sequence of steps that convert the carbon-containing input 200 into outputs 290 and 270 as separate entities in a substantially uncontaminated form. These processes can include, but are not limited to, a biofractionation process which thermo-chemically converts the input at increasing temperatures under pressure.
  • Sequesterable carbon 270 refers to any carbon that is stored for long periods of time, including carbon that is stored underground or used as a soil amendment.
  • Combustible fuels and chemicals 290 can include, but are not limited to, gasoline, gasoline-components, jet fuel, diesel, naphtha, oxygenate fuels such as methanol and dimethyl ether, hydrogen, methane, light gas oil, and vacuum gas oil.
  • FIG. 7 is a flow diagram illustrating an embodiment of the invention in which the carbon-containing input comprises biomass.
  • Biomass 300 is fed as input into process 350, which concurrently outputs combustible fuel and chemicals 390 and sequesterable carbon 370 as substantially uncontaminated and separate entities.
  • FIG. 8A is a flow diagram illustrating a method in which biomass is the carbon-containing input and biofractionation is the process which produces negative carbon fuel. This process subjects the biomass to decomposition by way of a heat source. In some embodiments, the biomass is subjected to temperature ramps under pressure. It is described in detail in co-owned US Patent Application Nos. 13/103,905 and 13/019,236, the contents of which are incorporated herein by reference in their entireties. As illustrated in Figure 8A, biomass 405 is inputted into biofractionation process 420 to concurrently produce combustible fuels and chemicals 500 and sequesterable carbon 425.
  • FIG 8B illustrates an auger reactor 325 that may comprise one of the stations or compartments used to carry out biomass fractioning process 250 of Figure 6, biomass fractioning process 350 of figure 7, or biofractionation process 420 of Figure 8A.
  • auger reactor 325 comprises a feeder 330 for receiving biomass 405, auger 335 for receiving the biomass 405 from feeder and including a transfer screw 340 for conveying the biomass, a motor 345 for driving the transfer screw 340, an exit port 355, and a condenser 360.
  • Auger reactor 325 can includes a heater 375 for heating the biomass 405 as it is conveyed through auger 335.
  • the heater 375 can include one or more heating components for delivering temperature ramps under pressure.
  • auger reactor 325 can heat the biomass by way of hot transfer fluid passing through the auger 335.
  • the transfer screw 340 can itself be heated.
  • hot sand is passed through the auger during operation, thereby heating the biomass.
  • transfer screw 340 is mounted to rotate inside the auger 335, and is driven by associated external motor 345.
  • the auger 335 has an inlet 365 connected to feeder 330.
  • biomass 405 is loaded into the feeder 330, which feeds the biomass 405 into auger 335 by way of inlet 365.
  • Transfer screw 340 conveys the biomass 405 at a constant and regulated speed through the auger 335.
  • the biomass is subjected to heat resulting in its decomposition during transport through the auger. This decomposition creates both BMF char 425 and a pyrolysis gas stream.
  • Condenser 360 may comprise a vertical condenser having its inlet connected to auger outlet 380.
  • the condenser 360 is configured to condense fractions of a portion of the pyrolysis gas stream. Gas stream extraction of one or more volatile components can be performed while maintaining the temperature of the gas until it reaches the vertical condenser 360. Sequesterable carbon 425 (sometimes referred to herein as BMF char 425) is recovered from exit port 355.
  • a group of items linked with the conjunction "and” should not be read as requiring that each and every one of those items be present in the grouping, but rather should be read as “and/or” unless expressly stated otherwise.
  • a group of items linked with the conjunction "or” should not be read as requiring mutual exclusivity among that group, but rather should also be read as “and/or” unless expressly stated otherwise.
  • items, elements or components of the invention may be described or claimed in the singular, the plural is contemplated to be within the scope thereof unless limitation to the singular is explicitly stated.
  • module does not imply that the components or functionality described or claimed as part of the module are all configured in a common package. Indeed, any or all of the various components of a module, whether control logic or other components, can be combined in a single package or separately maintained and can further be distributed in multiple groupings or packages or across multiple locations.

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  • Combustion & Propulsion (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

La présente invention concerne une colonne de fractionnement de la biomasse et un procédé associé qui consiste à introduire dans ladite colonne de la biomasse broyée pour obtenir, à la sortie de la colonne, plusieurs flux de vapeur à base de composés de type bio-intermédiaires, ainsi que du gaz de synthèse et du biochar. Une telle colonne de fractionnement comprend un moyen de réception de la biomasse broyée introduite dans le système ; et une pluralité de postes de traitement de la biomasse comprenant un moyen de chauffage de la biomasse, un moyen permettant de soumettre la biomasse à un bio-fractionnement et un moyen de recueil du carbone résiduel et du biochar.
PCT/US2014/023390 2013-03-12 2014-03-11 Réacteur pour biomasse Ceased WO2014164751A1 (fr)

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US13/797,985 US20130192971A1 (en) 2009-01-21 2013-03-12 Biomass reactor
US13/797,985 2013-03-12

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WO2017062793A1 (fr) * 2015-10-09 2017-04-13 Cool Planet Energy Systems, Inc. Conception de système de pyrolyse pour le traitement de biomasse
KR101788575B1 (ko) * 2016-07-15 2017-10-23 한국과학기술연구원 해조류 바이오매스로부터 바이오-오일 및 바이오-촤를 제조하는 장치 및 방법
WO2019186216A1 (fr) 2018-03-29 2019-10-03 Agricarbon Kft. Procédé et appareil pour le traitement de biomasse

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CN106010602B (zh) * 2016-06-13 2019-01-01 浙江大学 一种生物质炭化装置的运作方法
CN107159686A (zh) * 2017-07-05 2017-09-15 成都世远科技有限公司 一种车载可移动式秸秆和废塑料地膜同时连续处理系统

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KR101788575B1 (ko) * 2016-07-15 2017-10-23 한국과학기술연구원 해조류 바이오매스로부터 바이오-오일 및 바이오-촤를 제조하는 장치 및 방법
WO2019186216A1 (fr) 2018-03-29 2019-10-03 Agricarbon Kft. Procédé et appareil pour le traitement de biomasse

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