WO2014013874A1 - ガス化炉のブリッジ解消制御装置 - Google Patents
ガス化炉のブリッジ解消制御装置 Download PDFInfo
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- WO2014013874A1 WO2014013874A1 PCT/JP2013/068247 JP2013068247W WO2014013874A1 WO 2014013874 A1 WO2014013874 A1 WO 2014013874A1 JP 2013068247 W JP2013068247 W JP 2013068247W WO 2014013874 A1 WO2014013874 A1 WO 2014013874A1
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- Prior art keywords
- gasification furnace
- inner cylinder
- stirring member
- bridge
- control device
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/22—Arrangements or dispositions of valves or flues
- C10J3/24—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed
- C10J3/26—Arrangements or dispositions of valves or flues to permit flow of gases or vapours other than upwardly through the fuel bed downwardly
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C10J3/32—Devices for distributing fuel evenly over the bed or for stirring up the fuel bed
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/723—Controlling or regulating the gasification process
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/158—Screws
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1643—Conversion of synthesis gas to energy
- C10J2300/165—Conversion of synthesis gas to energy integrated with a gas turbine or gas motor
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/024—Dust removal by filtration
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/026—Dust removal by centrifugal forces
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
- F02B43/08—Plants characterised by the engines using gaseous fuel generated in the plant from solid fuel, e.g. wood
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
Definitions
- the present invention relates to a bridge elimination control device for a gasification furnace employed in, for example, a biomass gasification system that gasifies biomass fuel.
- a biomass gasification system that gasifies biomass fuel includes a gasification furnace that gasifies fuel, a supply conveyor that supplies solid raw material (fuel) to the gasification furnace, and the gasification furnace
- a structure including an inner cylinder for introducing fuel, a scrubber, a filter, an engine generator, and the like is known (for example, see Patent Document 1).
- Patent Document 2 a biomass gasification system that can stably supply biomass fuel is known (see, for example, Patent Document 2).
- the biomass gasification system described in Patent Document 2 has a configuration that prevents a bridge from being generated in the hopper by providing a stirring blade in the hopper in the previous step of the gasification furnace.
- the gasification reaction in the gasification furnace becomes low temperature and tar is generated at a high concentration when the amount of air in the furnace is insufficient.
- the gas containing a large amount of tar condenses in each device downstream of the gasifier and causes malfunctions such as sticking. In particular, in an engine, a supercharger, an intake valve, and the like are stuck, causing a malfunction.
- crushing tips there are cutting tips and crushing tips (so-called pin tips) as fuel chips, and crushing tips have few uses and are inexpensive, so that it is desired to use them as gasification raw materials.
- the crushing chips are characterized in that the chips are entangled with each other, have poor fluidity and easily bridge, and have a high porosity.
- the angle of repose of the crushing tip increases (the slope of the ridgeline of the crushing tip becomes steep), and the air flow tends to drift.
- the inside of the fuel is gasified, so that a bridge state due to hollowing may occur.
- this bridge state occurs, the fuel in the upper part of the cavity collapses and collapses all at once.
- a large amount of fuel raw raw material that is not sufficiently heated
- the temperature balance is lost, the temperature in the gasification furnace is rapidly lowered, and a large amount of tar is generated due to the temperature drop.
- the stirring blade in the hopper can be rotated to prevent the biomass powder fluid from forming a bridge. If a bridge occurs, it cannot be resolved.
- an object of the present invention is to eliminate a bridge generated in the gasification furnace.
- the present invention has been made in order to solve the above problems, and in a gasification furnace having an inner cylinder for supplying a solid raw material at an upper part of an outer cylinder, the gasification furnace is inserted into the inner cylinder, and the vertical direction of the gasification furnace is changed.
- a stirring member having a longitudinal direction; a standby position in which the stirring member is separated from the solid raw material deposited in the inner cylinder; and a predetermined position in which the stirring member is positioned in the solid raw material inside the gasification furnace below the standby position.
- a lift drive unit that lifts and lowers between them, a rotation drive unit that rotates the stirring member around the axis of the stirring member, and a bridge of the solid material in the gasifier during a bridge elimination operation that lowers the stirring member
- a control device for controlling the elevating drive unit and the rotary drive unit based on a signal from the detection unit.
- the gasification furnace bridge elimination control device of the present invention controls the elevating drive unit and the rotation drive unit based on the signal of the detection means, and therefore detects the bridge in the gasification furnace and lowers the stirring member. Rotate to automatically eliminate the bridge. For example, it is possible to prevent a gas containing a large amount of tar from being supplied to the engine. As a result, it is possible to prevent the turbocharger, the intake valve, and the like of the engine from being stuck and cause a malfunction.
- the second stirring member is provided at the bottom of the outer cylinder, A throat part of the outer cylinder is provided above the bottom part and below the inner cylinder, and the pressure of the throat part does not increase with the operation of the second stirring member.
- the stirring member when a correlation between a pressure below the throat portion and the throat portion pressure is a predetermined relationship, or when the control device determines at least one condition where the throat portion temperature is equal to or higher than a predetermined value. However, the stirring member may be lowered to a position penetrating the throat portion.
- the gasification furnace bridge elimination control device of the present invention can eliminate the throat bridge.
- the stirring member may be lowered until a predetermined time elapses after the stirring member returns to the standby position.
- the gasification furnace bridge elimination control device of the present invention can prevent hunting in which the agitating member moves up and down carelessly.
- the first predetermined position from the lower end of the inner cylinder is a first predetermined height
- the predetermined position higher than the first predetermined height is a second predetermined height. More than the height, the solid raw material is more than the first predetermined height and the pressure of the outer cylinder facing the inner cylinder is not less than atmospheric pressure, the temperature between the outer cylinders facing the inner cylinder is not less than a predetermined value,
- the control device determines that the absolute value of the temperature difference between the separated positions of the outer cylinder facing the inner cylinder is equal to or greater than a predetermined value, or at least one condition after the elapse of a predetermined time from the standby position return of the stirring member
- the stirring member may be lowered to a position where the lower end of the stirring member reaches the lower end of the inner cylinder.
- the gasification furnace bridge elimination control device of the present invention can eliminate the bridge of the inner cylinder. It is also possible to level the solid raw material deposited in the inner cylinder.
- the stirring member may be lowered until a second predetermined time shorter than a predetermined time from the standby position return of the stirring member elapses.
- the gasification furnace bridge elimination control device of the present invention can prevent hunting in which the agitating member moves up and down carelessly.
- the elevating drive unit and the rotary drive unit are controlled based on the signal from the detecting means, the agitating member is lowered and rotated to detect the bridge in the gasifier and automatically eliminate the bridge. it can.
- FIG. 1 is a schematic diagram in which a gasification furnace according to an embodiment of the present invention is employed in a gasification system.
- FIG. 2 is a front sectional view of the gasification furnace showing the standby position of the stirring blades.
- FIG. 3 is a front sectional view of the gasification furnace showing an intermediate position of the stirring blades.
- FIG. 4 is a front sectional view of the gasification furnace showing the lower end position of the stirring blade.
- FIG. 5 is a perspective view showing a lower portion of the stirring blade.
- FIG. 6 is a schematic plan view showing a cross section of the gasification furnace.
- FIG. 7 is a block diagram showing control of the gasifier.
- FIG. 8 is a schematic view showing intermediate position control of the stirring blades.
- FIG. 9 is a flow showing intermediate position control of the stirring blades.
- FIG. 10 is a schematic view showing the lower end position control of the stirring blade.
- FIG. 11 is a flow showing lower end position control of the stirring blade.
- FIG. 1 is a schematic diagram in which a gasification furnace according to an embodiment of the present invention is employed in a gasification system for gasifying biomass fuel.
- the gasification system 1 is, for example, a woody biomass power plant that uses woody material as a fuel as a solid material.
- the gasification system 1 includes a fuel supply device 10, a gasification furnace 20, an elevating and stirring device 30, a cyclone 45, a gas cooling device (heat exchanger) 40, a scrubber 50, a water tank 60, a cooling tower 70, a filter 80, and an attraction A blower 90, an engine generator 100, a surplus gas combustion device 200, and the like are included.
- the fuel supply device 10 supplies fuel to the gasification furnace 20, and includes a hopper 11, a motor 12, and a screw 13 for fuel discharge. Then, by controlling the frequency of the motor 12 by inverter, the rotational speed of the screw 13 is controlled and the amount of fuel input to the gasification furnace 20 is adjusted.
- the gasification furnace 20 gasifies the fuel from the fuel supply device 10.
- a gasifying agent (air) is supplied into the gasification furnace 20 in order to promote gasification of fuel.
- the dotted line arrow shown in FIG. 1 shows the path
- the cyclone 45 removes large dust contained in the gas from the gasification furnace 20 by centrifugation.
- the solid line arrow shown in FIG. 1 shows the path
- a gas path 101 is connected between the gasification furnace 20 and the cyclone 45.
- the heat exchanger 40 is a gas cooling device that cools the gas from the cyclone 45.
- a watering nozzle 41 for cleaning gas is provided in the heat exchanger 40.
- a gas path 102 is connected between the cyclone 45 and the heat exchanger 40.
- the scrubber 50 cleans and cools the gas from the heat exchanger 40 with water.
- the water storage tank 60 stores water supplied to the scrubber 50 and the heat exchanger 40.
- the water storage tank 60 is provided with a heat exchanger 61.
- a gas path 103 is connected between the heat exchanger 40 and the scrubber 50.
- Water in the water storage tank 60 is pumped to the watering nozzle 41 and the scrubber 50 by the pump 62.
- the water in the water storage tank 60 returns from the heat exchanger 40 and the scrubber 50 to the water storage tank 60. That is, the water in the water storage tank 60 includes soot, tar, and the like contained in the gas.
- the water in the water storage tank 60 is referred to as “circulated water”.
- the dashed-two dotted line arrow shown in FIG. 1 shows the path
- the cooling tower 70 stores water supplied to the heat exchanger 40 and the heat exchanger 61. Water in the cooling tower 70 is pumped to the heat exchanger 40 and the heat exchanger 61 by a pump 71.
- Water in the cooling tower 70 returns from the heat exchanger 40 and the heat exchanger 61 to the cooling tower 70.
- the water in the cooling tower 70 cools the circulating water in the water storage tank 60 indirectly by the heat exchanger 61 (so that the circulating water in the water storage tank 60 and the water in the cooling tower 70 are not mixed) and heat exchange.
- the gas is cooled indirectly by the vessel 40 (so that the gas and the water in the cooling tower 70 are not mixed). That is, the water in the cooling tower 70 does not contain soot, tar, and the like contained in the gas.
- the water in the cooling tower 70 is referred to as “cooling water”.
- the dashed-dotted arrow shown in FIG. 1 shows the path
- the filter 80 filters small dust contained in the gas.
- a gas path 104 is connected between the scrubber 50 and the filter 80.
- the attracting blower 90 attracts the gas from the gasification furnace 20 to the engine generator 100 side by a negative pressure action.
- the filter 80 is connected to the engine generator 100 and the surplus gas combustion device 200 via the gas path 106. In the middle of the gas path 106, the attracting blower 90 is connected.
- Engine generator 100 drives a generator with a gas engine.
- the surplus gas combustion apparatus 200 performs a combustion process on surplus gas.
- FIG. 2 is a front sectional view of the gasification furnace showing the standby position of the stirring blade
- FIG. 3 is a front sectional view of the gasification furnace showing an intermediate position of the stirring blade
- FIG. 4 is a gas showing the lower end position of the stirring blade. It is front sectional drawing of a chemical reactor.
- the gasification furnace 20 includes a gasification furnace main body 21 composed of an outer cylinder and an inner cylinder 23.
- a gas outlet 22 is provided below the gasifier main body 21.
- a bottom stirring blade 29 for stirring the fuel is provided at the bottom of the gasification furnace 20. Residues (such as ash after gasification) in the gasification furnace 20 are discharged out of the gasification furnace 20 by a discharge conveyor (not shown).
- the inner cylinder 23 protrudes upward from the upper end of the gasifier main body 21.
- the inner cylinder 23 is a cylindrical member that introduces fuel into the inner cylinder 23.
- the inner cylinder 23 is erected in the vertical direction so that the axial centers of the gasifier main body 21 coincide with each other.
- the upper and lower ends of the inner cylinder 23 are opened. Note that the upper end opening of the inner cylinder 23 can be closed by the lid 24.
- the lower part of the inner cylinder 23 is inserted into the gasifier main body 21 from above and faces the gasifier main body 21 in the vertical direction, and the lower end opening 235 is located in the middle of the gasifier main body 21.
- the upper part of the inner cylinder 23 protrudes upward from the upper end part of the gasification furnace main body 21, and a gasifying agent (air) is introduced from the upper end part (one place) of the inner cylinder 23.
- An inlet 231 into which fuel from the fuel supply device 10 is introduced is opened on the outer peripheral side of the upper part of the inner cylinder 23.
- One end of the input pipe 232 communicates with the input port 231.
- the input pipe 232 is provided so that the other end extends obliquely upward, and the fuel 5 from the fuel supply device 10 is supplied from the other end of the input pipe 232.
- the gasification furnace main body 21 is provided with a constricted portion 210 at a position below the lower end opening 235 of the inner cylinder 23.
- the constricted portion 210 is composed of an annular convex portion projecting toward the center direction of the gasification furnace main body 21.
- the constricted portion 210 extends downward from a reduced opening 211 having an inclined surface 211a in which the opening area of the inner peripheral surface 21a of the gasification furnace main body 21 gradually decreases downward, and the lower end of the reduced opening 211.
- the throat portion 212 has an opening 212a, and an enlarged opening 213 having an inclined surface 213a in which the opening area gradually increases from the throat portion 212.
- the opening area of the upper end of the reduced opening 211 is set to be equal to the opening area formed by the inner peripheral surface 21a of the gasification furnace main body 21.
- the opening area at the lower end of the reduced opening 211 is set to be equal to the opening area of the throat 212 and to the opening area of the inner cylinder 23.
- the upper opening area of the enlarged opening 213 is equivalent to the opening area of the throat portion 212, and the lower opening area of the enlarged opening 213 is equivalent to the opening area formed by the inner peripheral surface 21a of the gasifier main body 21. Is set.
- An elevating stirrer 30 is provided at the top of the gasification furnace 20.
- the elevating type stirring device 30 is inserted into the inner cylinder 23 from above, and the stirring blade 31 as a stirring member whose longitudinal direction is the vertical direction of the gasification furnace 20 and the stirring blade 31 are raised and lowered stepwise to an arbitrary height.
- a drive unit 32 is provided at the top of the gasification furnace 20.
- FIG. 5 is a perspective view showing the lower part of the stirring blade
- FIG. 6 is a schematic plan view showing a cross section of the gasification furnace.
- the stirring blade 31 includes a vertical axis (stirring member shaft) 33 whose upper part is connected to the drive unit 32 and hangs downward, and a pair of blade parts 34 provided below the vertical axis 33.
- the blade portion 34 is formed of a flat plate and protrudes in the diameter direction of the vertical axis 33.
- the blade portion 34 is configured by a plate member having a sharp top and bottom side along the vertical axis 33.
- the lower edge 34 a of the blade portion 34 is gradually inclined upward toward the radially outward direction of the vertical axis 33.
- the blade portion 34 can be easily inserted into the fuel when the blade portion 34 is lowered.
- the upper edge 34b of the blade portion 34 is gradually inclined downward toward the radially outward direction of the vertical axis 33.
- the blade portion 34 in the fuel can be easily removed when the blade portion 34 is raised.
- the vertical axis 33 is provided with a pair of linear reinforcing members 33 a along the vertical axis 33.
- the reinforcing member 33a reinforces the bending rigidity of the vertical axis 33.
- the drive unit 32 includes an elevating drive unit 35 that moves the stirring blade 31 up and down, and a rotation drive unit 36 that rotates the stirring blade 31 around the vertical axis 33.
- the raising / lowering drive part 35 raises / lowers the stirring blade 31 by a cylinder mechanism, a motor mechanism, or the like.
- the rotation driving unit 36 is a motor mechanism or the like that rotates the stirring blade 31 by a predetermined angle when the stirring blade 31 descends.
- the agitating blade 31 is configured to stop the lifting operation at a predetermined height position in a plurality of stages.
- the stirring blade 31 has an uppermost standby position X (see FIG. 2), an intermediate position Y (see FIG. 3) as a first position, and a lower end position Z (see FIG. 4) as a second position. ) And the position can be changed at three stages.
- the standby position X is a position above the fuel 5 by a predetermined height so as to be separated from the fuel 5 deposited in the inner cylinder 23.
- the intermediate position Y is a bridge elimination position where the bridge of the fuel 5 in the inner cylinder is eliminated, and the position where the lowest end of the stirring blade 31 (the tip of the vertical axis 33) substantially reaches the lower end opening 235 of the inner cylinder 23. Or the position where the lowest end of the stirring blade 31 slightly protrudes from the lower end opening 235 of the inner cylinder 23 is said.
- the lower end position Z is a bridge elimination position where the bridge of the fuel 5 in the gasifier main body 21 is eliminated, and a position where the blade portion 34 of the stirring blade 31 penetrates the constricted portion 210.
- the blade portion 34 of the stirring blade 31 is stopped at a rotational angle position that is parallel to the direction in which the fuel 5 is introduced (the direction indicated by the arrow in FIG. 6).
- the stirring blade 31 is positioned by a plurality of (three in this embodiment) limit switches LSH, LSM, and LSL as detection means fixed to the drive unit 32 side. That is, the upper limit switch LSH stops the stirring blade 31 at the standby position X. The middle limit switch LSM stops the stirring blade 31 at the intermediate position Y. The lower limit switch LSL stops the stirring blade 31 at the lower end position Z.
- the limit switches LSL, LSM, and LSH are provided above the inner cylinder 23. In this way, by placing the limit switches LSL, LSM, LSH above the inner cylinder 23, the reliability of the limit switch can be improved so as not to be affected by heat at the time of fuel combustion as much as possible. It can be maintained over a long period of time.
- a level sensor 25 for detecting the height position of the fuel 5 accumulated in the inner cylinder 23 (fuel accumulation height) is provided on the upper part of the inner cylinder 23.
- the level sensor 25 has a chain 252 that hangs down in the inner axial direction (vertical direction) of the inner cylinder 23 and has a weight 251 at the lower end, and a drive unit that winds up and rewinds the chain 252 to raise and lower the weight 251. And a measurement unit (not shown).
- the level sensor 25 measures the upper surface position of the fuel 5 accumulated in the inner cylinder 23, the weight 251 is lowered by the extension of the chain 252, and when the weight 251 contacts the fuel 5, The height of the fuel 5 can be obtained by detecting the weight change of the weight 251 (change in the weight balance of the weight). Such level detection of the fuel 5 is performed regularly and continuously (for example, at intervals of 1 minute).
- a plurality of pressure sensors 26 a, 26 b, and 26 c are attached in the gasifier main body 21.
- the pressure sensors 26a, 26b, and 26c detect the pressure in the gasification furnace main body 21 (hereinafter referred to as “internal pressure”).
- the mounting position of the pressure sensor 26a is the upper part (preferably the upper end part) in the gasification furnace main body 21. That is, the pressure sensor 26 a is attached at a position separated from the fuel 5 deposited in the gasification furnace 20.
- the pressure sensor 26a is used for detection when the inner cylinder level control in the furnace is not appropriate.
- the pressure sensor 26b is attached to the throat portion 212.
- the pressure sensor 26c is attached to the lower side (the bottom of the gasification furnace main body 21 or the vicinity thereof) than the throat portion 212.
- the pressure sensors 26 b and 26 c are used for bridge detection at the throat portion 212.
- a plurality of temperature sensors 27 a, 27 b, 27 c are attached in the gasifier main body 21.
- the temperature sensors 27a, 27b, and 27c detect the temperature in the gasification furnace main body 21.
- the attachment positions of the pair of temperature sensors 27 a and 27 b are the inner peripheral surface 21 a of the gasification furnace main body 21 and the upper part of the constricted portion 210. That is, the temperature sensors 27 a and 27 b are attached at positions separated from the fuel 5 deposited in the gasification furnace main body 21.
- the temperature sensors 27a and 27b are provided to be separated from each other in the diametrical direction with respect to the center of the gasification furnace main body 21.
- the temperature sensors 27a and 27b are used for detection when the inner cylinder level control in the furnace is not appropriate.
- the temperature sensor 27c is attached to the throat portion 212.
- the temperature sensor 27 c is used for bridge detection at the throat unit 212.
- the level sensor 25, the pressure sensors 26a, 26b, 26c and the temperature sensors 27a, 27b, 27c are connected to the control device 28 as shown in FIGS.
- the control device 28 controls the elevating type stirring device 30 based on the detection signals of the level sensor 25, the pressure sensors 26a, 26b, 26c and the temperature sensors 27a, 27b, 27c. For example, when there is a drift in the inner cylinder 23 and when a bridge occurs in which a space (edge breakage) occurs between the combustion portion in the inner cylinder 23 and the fuel, stirring is performed by the elevating stirrer 30 at the intermediate position Y. When the bridge of the constricted portion 210 is generated, the destruction operation is executed at the lower end position Z.
- the level sensor 25, the pressure sensors 26a, 26b, and 26c, and the temperature sensors 27a, 27b, and 27c correspond to detection means for monitoring the furnace atmosphere state.
- the control device 28 is connected to an elevating type stirring device 30.
- the control device 28 includes a processing unit 281 and a storage unit 282.
- the processing unit 281 includes a CPU (Central Processing Unit) and the like.
- the storage unit 282 includes a ROM (Read (Only Memory), a RAM (Random Access Memory), and the like.
- the fuel 5 is put into the hopper 11 of the fuel supply device 10.
- the motor 12 rotates the screw 13 at a predetermined rotational speed.
- the fuel 5 is supplied to the inner cylinder 23 of the gasification furnace 20 through the screw 13.
- the fuel 5 introduced into the inner cylinder 23 is supplied into the gasification furnace main body 21 and accumulated upward from the lower end opening 235 of the inner cylinder 23 to a predetermined height (in-furnace level target value). And this fuel 5 starts combustion and gasifies.
- the fuel 5 deposited in the inner cylinder 23 is formed with a dry layer / carbonized layer A, an oxidized layer B, and a reduced layer C from above. Further, since the stirring blade 31 of the elevating type stirring device 30 is in the standby position X, the stirring blade 31 does not hinder when the fuel 5 is charged.
- the gas generated in the gasification furnace 20 is sucked from the gas outlet 22 and supplied to the cyclone 45 via the gas path 101.
- the cyclone 45 removes large dust and the like contained in the gas from the gasification furnace 20 by centrifugation.
- the gas from which large dust or the like has been removed by the cyclone 45 is supplied to the heat exchanger 40 via the gas path 102 and is cooled by the heat exchanger 40.
- the gas cooled by the heat exchanger 40 is supplied to the scrubber 50 through the gas path 103, and is cleaned and cooled by water in the scrubber 50.
- the gas cleaned and cooled by the scrubber 50 is supplied to the filter 80 via the gas path 104.
- the filter 80 filters small dust contained in the gas.
- the attraction blower 90 attracts the gas from the gasification furnace 20 to the engine generator 100 side by a negative pressure action.
- the gas that has passed through the induction blower 90 is supplied to the engine generator 100.
- the engine generator 100 drives a generator by a gas engine.
- the surplus gas is supplied to the surplus gas combustion device 200.
- the surplus gas combustion apparatus 200 performs a combustion process on surplus gas.
- ⁇ ⁇ ⁇ Tar is generated when the furnace level inside the inner cylinder is not within the proper range, or when a bridge is generated at the throat portion 212 and the bridge collapses. Therefore, when the inner cylinder level in the furnace is not appropriate or when the bridge at the throat section 212 is detected and the bridge is eliminated early, the influence of tar on the equipment is prevented by the fuel bridge elimination control. is there.
- intermediate position control for stirring the fuel in the inner cylinder 23 and lower end position control for breaking the bridge at the lower end position are performed.
- the lower end position control is preferentially performed.
- FIG. 8 is a schematic diagram showing the intermediate position control of the stirring blade
- FIG. 9 is a flow showing the intermediate position control of the stirring blade.
- the level in the inner cylinder 23 of the fuel 5 is measured by the level sensor 25, which is a detecting means for monitoring the atmospheric state inside the gasification furnace 20, and the in-furnace level H of the fuel 5 is detected (S1). Then, it is confirmed whether the in-furnace level H and the in-furnace level limit position Hhh are exceeded (S2). If the in-furnace level limit position Hhh is not exceeded, the in-furnace level H is compared with the preset in-furnace level upper limit position Hh (S3).
- the in-furnace level limit position Hhh is a height from the position of the lower end opening 235 of the inner cylinder 23 and means a height at which combustion is impossible.
- the in-furnace level limit position Hhh when the in-furnace level limit position Hhh has been reached, it is determined that the intermediate position bridge cancellation operation condition is satisfied (S12).
- the in-furnace level upper limit position Hh corresponds to the first height
- the in-furnace level upper limit position Hhh corresponds to the second height.
- the pressure sensor 26a measures the furnace pressure (internal pressure) P1 (S4), and the internal pressure P1 is preset.
- the reference pressure (predetermined value) Pa is compared (S5).
- the reference pressure Pa refers to, for example, atmospheric pressure.
- the inside of the gasifier 20 is at atmospheric pressure or lower, but when the internal pressure P1 is higher than the reference value Pa, air drift occurs in the gasifier main body 21 (inside the inner cylinder 23). it is conceivable that. Such uneven flow forms a portion in which the air hardly flows in the fuel 5 accumulated in the inner cylinder 23 and a portion inadvertently flowing.
- the space temperature T1 of the outer peripheral portion of the inner cylinder 23 is measured by the temperature sensor 27a (S6), and the furnace temperature T1 is compared with a preset reference temperature (predetermined value) Tb (S7).
- the reference temperature Tb refers to a temperature at which fuel can be normally gasified in the gasification furnace 20.
- the space temperature T2 of the outer peripheral portion of the inner cylinder 23 is measured by the temperature sensor 27b (S8), and the furnace temperature T2 is compared with the reference temperature Tb (S9).
- the furnace temperature T2 is equal to or higher than the reference temperature Tb, it is similarly determined that the intermediate position bridge canceling operation condition is satisfied (S12).
- the measurement by the temperature sensors 27a and 27b is performed for a predetermined time (for example, 5 seconds).
- any one of the intermediate position bridge elimination operation conditions of Step 2, Step 5, Step 7, Step 9, Step 10, and Step 11 is satisfied, and further, the previous operation is performed by the timer after the previous operation. It is confirmed that a predetermined time (for example, 1 minute) has passed (S13), and an intermediate position bridge canceling operation is executed on the condition that the lower end position canceling condition is not satisfied (S14) (S15). .
- a predetermined time for example, 1 minute
- the drive unit 32 of the elevating type stirring device 30 is activated.
- the elevating drive unit 35 lowers the stirring blade 31 in the standby position to the intermediate position (see FIG. 3).
- the rotation drive unit 36 rotates the descending stirring blade 31.
- the blade portion 34 enters the fuel while rotating, and the fuel can be leveled substantially evenly.
- the bridge can be eliminated at an early stage.
- the stirring blade 31 that has reached the intermediate position Y rises while being fixed at a predetermined rotational position. For this reason, the blade
- FIG. 10 is a schematic diagram showing the lower end position control of the stirring blade
- FIG. 11 is a flow showing the lower end position control of the stirring blade.
- the opening area is small in the constricted part 210 part, it is easy to raise
- the lower stirring condition is established (S21), and after the internal pressure is measured by the pressure sensor 26b (S22), the bottom stirring blade 29 is used to stir the lower part of the furnace (S23). After this stirring operation is performed for a predetermined time (S24), the internal pressure is again measured by the pressure sensor 26b (S25). Then, it is determined whether the previously measured internal pressure P (2-0) is equal to or higher than the internal pressure P (2-1) measured later (S26). If it is equal to or higher than the internal pressure P (2-1) measured later, it is determined that there is no recovery of P2 due to stirring, and it is determined that the lower-end position bridge cancellation operation condition is satisfied (S33).
- the internal pressure P3 of the pressure sensor 26c is measured (S29). If the value of the correlation between P2 and P3 is greater than the predetermined value A, it is determined that a bridge has occurred (S30), and the lower end position bridge is detected. It is determined that the canceling operation condition is satisfied (S33).
- the correlation between P2 and P3 is, for example, P2 / (P3-P2)> A.
- the temperature T3 measured by the temperature sensor 27c is compared with the predetermined temperature TC.
- the temperature T3 is equal to or higher than the predetermined temperature TC (S31) and (S32), cavitation occurs below the throat portion 212 and char is present. Therefore, it is determined that a bridge is generated in the throat portion 212, and it is determined that the lower-end position bridge cancellation operation condition is satisfied (S33).
- the previous operation time t2 (for example, 1 minute) has elapsed.
- the lower-end position bridge elimination operation is executed (S35).
- the previous operation time t2 (for example, 1 minute) corresponds to the time from when the stirring member returns to the standby position until a predetermined time elapses.
- the drive unit 32 of the elevating type stirring device 30 is activated.
- the elevating drive unit 35 lowers the stirring blade 31 in the standby position to the lower end position Z (see FIG. 4).
- the rotation driving unit 36 rotates the descending stirring blade 31 around the vertical axis 33.
- the blade portion 34 enters the fuel while rotating, and the bridge can be destroyed.
- the bridge can be reliably broken by rotating the stirring blade 31, but the bridge can be broken by lowering the stirring blade 31 without rotating.
- the stirring blade 31 that has reached the lower end position Z rises while being fixed at a predetermined rotational position.
- the gasification furnace 20 of the present embodiment is configured to enter the fuel while rotating the stirring blade 31 around the vertical axis 33, thereby preventing the formation of a rathole in the fuel. be able to. That is, a mere pusher function that does not rotate the stirring blade 31 forms a rat hole in the fuel and affects gasification, but by adding a stirring operation, the hole is filled to make the fuel accumulation level uniform. Can do.
- the stirring blade 31 since the stirring blade 31 is in a standby position (a position where it does not come into contact with fuel) X when not in operation, it is not in a high-temperature atmosphere and the durability of the stirring blade 31 is improved.
- the longitudinal axis 33 of the stirring blade 31 is provided with a pair of linear reinforcing members 33a along the longitudinal axis 33, so that the rigidity at the time of insertion is increased by the stirring blade and the advantage of being strong against bending. There is.
- the elevating type stirring device 30 since the elevating type stirring device 30 is provided, the gasification performance can be improved. That is, by reducing the input amount fluctuation and improving the contact ratio between the fuel and the gas, the heat generation of the gas is improved and the fluctuation rate can be reduced.
- the present invention is not limited to the above embodiment.
- the constriction part 210 does not necessarily need to provide. Even in a gasification furnace that does not have the constricted portion 210, a bridge may occur. Therefore, it is possible to lower the stirring blade 31 to a predetermined position and eliminate the bridge.
- the predetermined position where the stirring blade 31 descends can be stopped at a plurality of three or more positions. For example, it is possible to set a plurality of predetermined positions at which the stirring blades 31 descend in each of the inner cylinder 23 and the gasification furnace main body 21.
- any shapes such as a circular shape and a rectangular shape can be adopted.
- the present invention can be applied to applications where it is indispensable to eliminate the bridge of fuel generated inside the gasifier.
- it is useful for a gasification furnace that uses a solid material that is easy to bridge, such as a crushing chip, as a fuel.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Processing Of Solid Wastes (AREA)
- Gasification And Melting Of Waste (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
Description
(1)ガス発熱量の低下
炉内偏流により、全体としては空気過多となりやすく、燃料が燃焼傾向となり、燃焼ガスとチャーの接触率も悪くなる。また、燃料のブリッジにより原料の供給が断続的となり、発熱量が低下する。
(2)タールの発生
炉内偏流となるため、全体として空気過多となる一方で、炉内に空気が不足する領域が発生する。空気が不足する領域では低温となるため、タールが発生する。
前記ガス化炉のブリッジ解消制御装置において、前記外筒底部に第2攪拌部材を設け、前記底部よりも上方で前記内筒より下方に前記外筒のスロート部を設け、前記第2攪拌部材の作動に伴って前記スロート部の圧力が上昇しない、前記スロート部の圧力が所定値以下、前記スロート部の下方側の圧力と前記スロート部圧力との相関が所定の関係である、または、前記スロート部温度が所定値以上の少なくとも一つの条件を前記制御装置が判定したときに、前記攪拌部材が前記スロート部を貫通する位置まで前記攪拌部材を下降させてもよい。
矢印で示す方向)に対して平行となる回転角度位置で停止している。このように羽根部34の回転角度位置を設定することにより、投入される燃料5が羽根部34に当接して反射するのを防止でき、燃料5が片寄って内筒23内に堆積するのを防止することが可能となる。
5 燃料(固体原料)
10 燃料供給装置
20 ガス化炉
21 ガス化炉本体
23 内筒
25 レベルセンサ(検出手段)
26a 圧力センサ(検出手段)
26b 圧力センサ(検出手段)
26c 圧力センサ(検出手段)
27a 温度センサ(検出手段)
27b 温度センサ(検出手段)
27c 温度センサ(検出手段)
28 制御装置
29 底部攪拌羽根
30 昇降式攪拌装置
31 攪拌羽根(攪拌部材)
32 駆動部
33 縦軸(攪拌部材軸)
34 羽根部
35 昇降駆動部
36 回転駆動部
210 くびれ部
211 縮小開口部
211a 傾斜面
212 スロート部
213 拡大開口部
235 下端開口
X 待機位置
Y 中間位置
Z 下端位置
LSL リミットスイッチ
LSM リミットスイッチ
LSH リミットスイッチ
Claims (5)
- 固体原料を供給する内筒を外筒の上部に有するガス化炉において、
前記内筒内に挿入され、ガス化炉の上下方向を長手方向とする攪拌部材と、
前記攪拌部材を、前記内筒内に堆積する固体原料から離間させる待機位置と前記待機位置よりも下方のガス化炉内部の固体原料内に位置させる所定位置との間で昇降させる昇降駆動部と、
前記攪拌部材を下降させるブリッジ解消動作時に、前記攪拌部材を攪拌部材軸回りに回転させる回転駆動部と、
前記ガス化炉内の前記固体原料のブリッジを検出するための検出手段と、
前記検出手段の信号に基づいて前記昇降駆動部および回転駆動部を制御する制御装置とを備えたことを特徴とするガス化炉のブリッジ解消制御装置。 - 請求項1に記載のガス化炉のブリッジ解消制御装置において、
前記外筒底部に第2攪拌部材を設け、前記底部よりも上方で前記内筒より下方に前記外筒のスロート部を設け、
前記第2攪拌部材の作動に伴って前記スロート部の圧力が上昇しない、前記スロート部の圧力が所定値以下、前記スロート部の下方側の圧力と前記スロート部圧力との相関が所定の関係である、または、前記スロート部温度が所定値以上の少なくとも一つの条件を前記制御装置が判定したときに、前記攪拌部材が前記スロート部を貫通する位置まで前記攪拌部材を下降させることを特徴とするガス化炉のブリッジ解消制御装置。 - 請求項2に記載のガス化炉のブリッジ解消制御装置において、前記攪拌部材の待機位置復帰から所定時間経過するまでは前記攪拌部材の下降を待機させることを特徴とするガス化炉のブリッジ解消制御装置。
- 請求項1に記載のガス化炉のブリッジ解消制御装置において、前記内筒下端から第1所定位置を第1所定高さとし、前記第1所定高さより高い所定位置を第2所定高さとして前記固体原料が第2所定高さ以上、前記固体原料が前記第1所定高さ以上であって前記内筒と対向する外筒の圧力が大気圧以上、前記内筒と対向する前記外筒間の温度が所定値以上、前記内筒と対向する前記外筒の離間した位置の温度差の絶対値が所定値以上、または、前記攪拌部材の待機位置復帰から所定時間経過の少なくとも一つの条件を前記制御装置が判定したときに、前記攪拌部材の下端が、前記内筒の下端に達する位置まで、前記攪拌部材を下降させることを特徴とするガス化炉のブリッジ解消制御装置。
- 請求項4に記載のガス化炉のブリッジ解消制御装置において、前記攪拌部材の待機位置復帰からの所定時間よりも短い第2所定時間が経過するまでは前記攪拌部材の下降を待機させることを特徴とするガス化炉のブリッジ解消制御装置。
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13819195.2A EP2876148A4 (en) | 2012-07-19 | 2013-07-03 | BRIDGE DISPOSAL CONTROL DEVICE FOR A GAS OVEN |
| PH12015500118A PH12015500118B1 (en) | 2012-07-19 | 2015-01-20 | Bridge elimination control apparatus for gasification furnace |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012160651A JP5798091B2 (ja) | 2012-07-19 | 2012-07-19 | ガス化炉のブリッジ解消制御装置 |
| JP2012-160651 | 2012-07-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2014013874A1 true WO2014013874A1 (ja) | 2014-01-23 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2013/068247 Ceased WO2014013874A1 (ja) | 2012-07-19 | 2013-07-03 | ガス化炉のブリッジ解消制御装置 |
Country Status (4)
| Country | Link |
|---|---|
| EP (1) | EP2876148A4 (ja) |
| JP (1) | JP5798091B2 (ja) |
| PH (1) | PH12015500118B1 (ja) |
| WO (1) | WO2014013874A1 (ja) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AT520818B1 (de) * | 2018-03-26 | 2019-08-15 | Hargassner Gmbh | Verfahren zum Betreiben eines Festbettvergasers |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003336079A (ja) * | 2002-05-20 | 2003-11-28 | Kyuchiku Ind Co Ltd | 熱分解ガスの改質方法 |
| JP2005146188A (ja) * | 2003-11-19 | 2005-06-09 | Satake Corp | バイオマスガス発生炉 |
| JP2006082963A (ja) | 2004-09-17 | 2006-03-30 | Mitsubishi Heavy Ind Ltd | ホッパ及び該ホッパを有するガス化システム |
| JP2008280411A (ja) * | 2007-05-09 | 2008-11-20 | Yanmar Co Ltd | ガス化装置 |
| JP2010215810A (ja) | 2009-03-17 | 2010-09-30 | Yanmar Co Ltd | ガス化装置 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1524511A (en) * | 1918-10-12 | 1925-01-27 | Henry A Dreffein | Fuel agitator for gas producers |
| GB212311A (en) * | 1922-12-08 | 1924-03-10 | Arthur Henry Lymn | Process of and apparatus for utilising caking fuel in gas producers |
| GB573944A (en) * | 1943-08-18 | 1945-12-13 | Albert Leet Galusha | Improvements in or relating to gas producers |
| US2502141A (en) * | 1943-08-18 | 1950-03-28 | Albert L Galusha | Agitator for gas producers |
| US4011059A (en) * | 1976-01-30 | 1977-03-08 | General Electric Company | Self-centering traversing stirrer shaft for fixed bed gasifier |
| US4134738A (en) * | 1978-04-10 | 1979-01-16 | Foster Wheeler Energy Corporation | Automated poking system for coal gasifier |
-
2012
- 2012-07-19 JP JP2012160651A patent/JP5798091B2/ja active Active
-
2013
- 2013-07-03 EP EP13819195.2A patent/EP2876148A4/en not_active Withdrawn
- 2013-07-03 WO PCT/JP2013/068247 patent/WO2014013874A1/ja not_active Ceased
-
2015
- 2015-01-20 PH PH12015500118A patent/PH12015500118B1/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003336079A (ja) * | 2002-05-20 | 2003-11-28 | Kyuchiku Ind Co Ltd | 熱分解ガスの改質方法 |
| JP2005146188A (ja) * | 2003-11-19 | 2005-06-09 | Satake Corp | バイオマスガス発生炉 |
| JP2006082963A (ja) | 2004-09-17 | 2006-03-30 | Mitsubishi Heavy Ind Ltd | ホッパ及び該ホッパを有するガス化システム |
| JP2008280411A (ja) * | 2007-05-09 | 2008-11-20 | Yanmar Co Ltd | ガス化装置 |
| JP2010215810A (ja) | 2009-03-17 | 2010-09-30 | Yanmar Co Ltd | ガス化装置 |
Non-Patent Citations (1)
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2014019809A (ja) | 2014-02-03 |
| EP2876148A4 (en) | 2015-07-08 |
| EP2876148A1 (en) | 2015-05-27 |
| PH12015500118B1 (en) | 2017-10-06 |
| PH12015500118A1 (en) | 2015-03-16 |
| JP5798091B2 (ja) | 2015-10-21 |
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