[go: up one dir, main page]

WO2014087679A1 - Procédé et dispositif de fabrication d'huile aqueuse transparente compatible - Google Patents

Procédé et dispositif de fabrication d'huile aqueuse transparente compatible Download PDF

Info

Publication number
WO2014087679A1
WO2014087679A1 PCT/JP2013/057719 JP2013057719W WO2014087679A1 WO 2014087679 A1 WO2014087679 A1 WO 2014087679A1 JP 2013057719 W JP2013057719 W JP 2013057719W WO 2014087679 A1 WO2014087679 A1 WO 2014087679A1
Authority
WO
WIPO (PCT)
Prior art keywords
oil
water
aeration
liquid
tank
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2013/057719
Other languages
English (en)
Japanese (ja)
Inventor
満治 服部
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP2013512918A priority Critical patent/JP5362138B1/ja
Publication of WO2014087679A1 publication Critical patent/WO2014087679A1/fr
Priority to PH12015501267A priority patent/PH12015501267A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/32—Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/328—Oil emulsions containing water or any other hydrophilic phase

Definitions

  • the present invention relates to a method for producing a compatible transparent hydrous oil and an apparatus for producing a compatible transparent hydrous oil. More specifically, the present invention relates to a compatible transparent hydrous oil production method capable of maintaining transparency while water and oil are mixed, and a compatible transparent hydrous oil production apparatus therefor.
  • Patent Document 1 water is mixed in an environment where a positive potential of 200 V or more is applied while air bubbles are generated by air injection in the fuel oil and stirred. An attempt is made to obtain a transparent oil-water mixture.
  • Patent Document 2 uses the eductor effect and the eddy current effect to appropriately adjust and add active water whose viscosity is increased by a plant-derived thickener and an oily combustion accelerator. By stirring and circulatingly mixing the base fuel oil, it is intended to obtain a uniform emulsion fuel oil in which oil and water are not separated stably for a long time.
  • Patent Document 1 provides a method for producing a transparent mixed oil without using harmful and costly emulsifiers and the like, but water that can be mixed in the oil.
  • the weight ratio remained at about 10% to 15%.
  • the present invention has been made in view of the above-described conventional technology, and provides a compatible transparent hydrous oil production method capable of maintaining transparency while water and oil are mixed, and a compatible transparent hydrous oil production apparatus therefor The purpose is to do.
  • the present invention is as follows.
  • an amine compound addition step of adding an amine compound as a clarifying agent to the liquid to be treated.
  • the method for producing a compatible transparent hydrated oil according to claim 2 is the method for producing a compatible transparent hydrated oil according to claim 1, wherein the aeration step is performed in an aeration tank, While performing the air diffusion, the liquid to be treated in the air diffusion tank is circulated so as to be taken out from the lower part of the air diffusion tank to the outside and re-injected into the tank from the upper part of the air diffusion tank.
  • the gist is that
  • the method for producing a compatible transparent hydrous oil according to claim 3 is the method for producing a compatible transparent hydrous oil according to claim 1 or 2, wherein the process water is prepared to obtain the process water before the aeration step.
  • the process water preparation step is a step of applying the negative oxidation-reduction potential by electrolysis of water before processing.
  • the method for producing a compatible transparent hydrated oil according to claim 4 is the method for producing a compatible transparent hydrated oil according to any one of claims 1 to 3, wherein the aeration step is applied to a negative electrode of a DC power source.
  • the gist of the present invention is the step of performing the aeration while bringing the connected conductor into contact with the liquid to be treated.
  • the method for producing a compatible transparent hydrated oil according to claim 5 is the method for producing a compatible transparent hydrated oil according to any one of claims 1 to 4, wherein the aerated gas used in the aeration step is:
  • the gist is to include air in contact with magnetite ore.
  • the method for producing a compatible transparent hydrated oil according to claim 6 is the method for producing a compatible transparent hydrated oil according to any one of claims 1 to 5, wherein the aeration step is performed in an aeration tank. Done, The gist is that the processed water is sprayed into the aeration tank.
  • the compatible transparent hydrous oil production apparatus is a compatible transparent hydrous oil production apparatus for the method according to claim 1, wherein the air diffusion means for performing the aeration and the filtration are performed.
  • the gist of the invention is to include a filtering means and an amine compound adding means for adding an amine compound.
  • the compatible transparent hydrous oil production device is the compatible transparent hydrous oil production device according to claim 7, wherein the aeration means comprises an air diffusion tank and a circulation function unit,
  • the circulatory function unit is a functional unit that can take out the liquid to be treated during the air diffusion process from the lower part of the air diffusion tank to the outside of the tank and re-inject the liquid into the tank from the upper part of the air diffusion tank. To do.
  • the compatible transparent hydrous oil production apparatus is the compatible transparent hydrous oil production apparatus according to claim 7 or 8, comprising processing water preparation means for obtaining the processed water,
  • the gist of the invention is that the processed water preparation means provides the negative oxidation-reduction potential by electrolysis of water before processing.
  • a compatible transparent hydrous oil production apparatus is the compatible transparent hydrous oil production apparatus according to any one of claims 7 to 9, comprising a conductor connected to a negative electrode of a DC power source,
  • the gist of the present invention is that the conductor is capable of contacting the liquid to be treated when the air is diffused.
  • the compatible transparent hydrous oil production apparatus is the compatible transparent hydrous oil production apparatus according to any one of claims 7 to 10, wherein a gas preparation means for preparing the aeration gas is provided.
  • a gas preparation means for preparing the aeration gas is provided.
  • the gist of the gas preparation means is a means for sending out the air passed through the gas preparation tank filled with magnetite ore as the aeration gas.
  • the compatible transparent hydrous oil production apparatus is the compatible transparent hydrous oil production apparatus according to any one of claims 7 to 11, wherein the air diffuser includes an air diffuser, and a spray injection.
  • a functional unit, The gist of the spray injection function unit is a function unit that sprays the processed water into the air diffusion tank.
  • the liquid to be treated during the air diffusion process is taken out from the lower part of the air diffusion tank to the outside of the tank, and from the upper part of the air diffusion tank to the inside of the tank.
  • a compatible transparent hydrous oil can be produced by consolidating the apparatus small.
  • the air diffusion step is a step of performing air diffusion while bringing the conductor connected to the negative electrode of the DC power source into contact with the liquid to be treated
  • the compatible transparent water-containing oil can be produced more efficiently.
  • the aerated gas used in the aeration process contains air in contact with magnetite ore
  • a compatible transparent hydrated oil can be produced more efficiently.
  • the aeration process is performed in the aeration tank and the processed water is sprayed into the aeration tank, the compatible transparent hydrated oil can be produced more efficiently.
  • the compatible transparent hydrous oil production apparatus of the present invention can efficiently produce a compatible transparent hydrous oil that can maintain transparency while being mixed with water and oil.
  • the air diffuser includes an air diffuser and a circulation function unit, and the circulation function unit takes out the liquid to be treated during the air diffusion process from the lower part of the air diffuser to the outside of the tank and from the upper part of the diffuser
  • a compatible transparent hydrated oil can be produced by integrating the apparatus in a small size.
  • a compatible transparent hydrated oil can be produced more efficiently.
  • a gas preparation means for preparing the aeration gas is provided, and the gas preparation means is a means for sending out the air passed through the gas preparation tank filled with magnetite ore as the aeration gas, it is more efficient.
  • a compatible transparent hydrous oil can be produced.
  • the aeration means is provided with an aeration tank and a spray injection function section, and the spray injection function section is a function section for spraying processed water into the diffusion tank, the compatible transparent water content can be more efficiently Oil can be produced.
  • processed water that is water exhibiting a negative oxidation-reduction potential coexists with at least one oil selected from mineral oil and vegetable oil. This is a step of diffusing the liquid to be treated.
  • processed water is water having a negative oxidation-reduction potential.
  • This processed water may consist essentially of water, and the oxidation-reduction potential thereof may be a negative value, and the oxidation-reduction potential is set to a negative value by containing other water-soluble components. May be. In the latter case, the water is usually contained in an amount of 90% by volume or more based on the entire processed water.
  • Water used for the processed water can be any water without limitation. That is, for example, tap water, river lake water, ground water, ion exchange water, deionized water, purified water, pure water, and the like can be used. Although seawater can be used, it is usually necessary to remove the salt after preparing a compatible transparent hydrous oil.
  • presenting a negative oxidation-reduction potential means that the potential (mV) measured by an oxidation-reduction potentiometer (ORP meter) is a negative value. Specifically, it may be less than 0 mV, but is preferably less than 0 mV-1000 mV or more, more preferably less than 0 mV-500 mV or more.
  • this oxidation-reduction potential shall be a value at the time of using a saturated silver chloride electrode as a reference electrode of an ORP meter.
  • the negative redox potential may be obtained in any way. Examples thereof include a method for obtaining a negative redox potential by electrolysis, a method for obtaining a negative redox potential by adding other components, and a method for obtaining a negative redox potential by aeration. These methods may use only 1 type and may use 2 or more types together. Further, among the above methods, the method of obtaining a negative redox potential by adding other components includes, for example, a method of adding sodium metasilicate, a method of adding an aqueous solution of hypochlorous acid and / or a salt thereof, and the like.
  • a method of obtaining a negative oxidation-reduction potential by aeration there is a method of aeration using an aeration gas containing air in contact with magnetite ore, an aeration gas containing hydrogen, or the like.
  • the method by electrolysis is most preferred. This is because in the method using electrolysis, an oxidation-reduction potential of ⁇ 500 mV or less can be obtained in a short time, and high production efficiency can be obtained.
  • the “mineral oil” includes gasoline (regular gasoline, high-octane gasoline, etc.), light oil, kerosene, heavy oil (A heavy oil, C heavy oil, bunker C heavy oil, etc.). These may use only 1 type and may use 2 or more types together.
  • the above “vegetable oil” includes oil collected from various plants. That is, palm oil (oil palm), palm kernel oil (oil palm), palm oil (coconut palm), corn oil (corn), rice oil (rice), rice bran oil (rice), cottonseed oil (Aoiaceae cotton genus plant), olive oil (Olive), peanut oil (peanut), rapeseed oil (rapeseed), safflower oil (safflower), sesame oil (sesame), soybean oil (soybean), sunflower oil (sunflower), jatropha oil (nanyo oilseed), hemp oil (hemp) ), Oil extracted from various coniferous trees such as yellow lotus oil (yellow lotus tree) and pine oil (coniferous trees such as pine), and other oils collected from seeds of various plants used as nuts. That is, the vegetable oil contained in the category normally called biodiesel is contained.
  • mineral oil and / or vegetable oil may be included as the oil, but synthetic oil may also be included.
  • Synthetic oils include oils obtained by processing mineral oils, oils obtained by processing vegetable oils, and chemically synthetic oils that do not use mineral oils and vegetable oils as raw materials. That is, for example, various polyolefin synthetic oils, ether synthetic oils, ester synthetic oils and the like are included. Only one type of synthetic oil may be included, or two or more types may be included.
  • the oil used in the present method may be the above-described mineral oil, vegetable oil, or a mixture thereof. These oils may be new oils, but may be waste oils, or may be mixed oils of new oils and waste oils. Furthermore, the oil used in the air diffusion process can be used together with impurities other than oil.
  • the above “treated liquid” is a mixed liquid containing processing water and oil.
  • the ratio of the processing water and oil in this to-be-processed liquid is not specifically limited, Usually, the same quantity as the quantity of the processing water contained in the compatible transparent water-containing oil obtained is mix
  • gasoline When gasoline is used as the oil, it is preferably blended so that the processing water is 10 to 30% by volume with respect to 100% by volume of the liquid to be treated.
  • light oil When light oil is used, it is preferably blended so that the processing water is 10 to 30% by volume.
  • kerosene When used, it is preferably blended so that the processing water is 10 to 40% by volume.
  • heavy oil A it is preferable to blend so that the processed water is 10 to 40% by volume.
  • C heavy oil when used, it is preferably blended so that the processing water is 10 to 30% by volume.
  • bunker C heavy oil it is preferable to blend so that the processing water is 10 to 30% by volume.
  • palm oil including biodiesel fuel
  • silicate In addition to processed water and oil, other components can be added to the liquid to be treated.
  • Another component includes silicate.
  • a metasilicate is usually used, and further an alkali metal salt is used. Specifically, sodium metasilicate is preferable.
  • emulsification of oily water can be promoted.
  • the compounding quantity of this silicate is not specifically limited, Usually, 10 volume parts or less are preferable with respect to a total of 100 volume parts of processing water and oil.
  • the blending amount is more preferably 0.5 to 8 parts by volume, and particularly preferably 1 to 5 parts by volume.
  • Aeration in the aeration process may be performed in any way. That is, for example, the treatment may be performed continuously while the liquid to be treated is diffused, or the treatment may be performed discontinuously using an aeration tank.
  • the method of FIG. 5 is illustrated as a method performed continuously. In other words, this is a method that uses the flow pipe 29 and a diffuser that is disposed along the flow path of the flow pipe 29 and can diffuse into the flow pipe 29.
  • the air diffuser can include a plurality of air diffusers 25 along the flow path of the flow pipe 29.
  • aeration can be performed while circulating the liquid to be treated from the upstream side to the downstream side of the flow pipe 29 (in the direction of the arrow in FIG. 5).
  • FIG. 4 is illustrated as an example of a non-continuous method. That is, it is a method of using the air diffusion tank 21 and performing air diffusion while circulating the liquid 27 to be processed in the air diffusion tank 21. Specifically, the liquid 27 to be processed is taken out of the air diffusion tank 21 from the lower side of the air diffusion tank 21 in which the liquid 27 to be processed is stored and air is diffused, and the taken out liquid 27 to be processed is diffused.
  • the circulation function unit 22 so that it can be re-introduced into the air diffusion tank 21 from above the air tank 21, it is possible to perform air diffusion for a required time while circulating the liquid 27 to be treated.
  • the process which makes the to-be-processed liquid 27 circulated contact a magnetic iron ore can further be provided.
  • this step the production of the emulsion can proceed more efficiently.
  • the method of performing discontinuously is preferable in the viewpoint which can make a compatible transparent water-containing oil manufacturing apparatus small.
  • the heating may be performed in any manner.
  • a heater jacket is wound around the circulation conduit 221 to heat the liquid 27 to be treated that has been circulated in the circulation conduit 221.
  • a heater jacket (95 in FIG. 3) is wound around the magnetite ore contact tank (223 in FIG. 3), and the inside of the magnetite ore contact tank 223 is circulated.
  • the treatment liquid 27 can be heated.
  • the liquid 27 to be treated distributed in the magnetite ore contact tank 223 can be heated.
  • the liquid 27 to be treated can be heated to a temperature of 40 to 60 ° C.
  • the aeration gas used in this aeration process is not particularly limited.
  • air can be used as it is, but it is preferable to use an aeration gas containing air in contact with magnetite ore.
  • the amount of air diffused in the air diffusion process is not particularly limited, but it is usually preferable to use 100 m 3 / min or more with respect to 100 L of the liquid to be treated in the entire air diffusion process.
  • the amount of air diffused is more preferably 200 to 1000 m 3 / min, more preferably 300 to 600 m 3 / min, with respect to 100 L of the liquid to be treated.
  • this aeration gas can be heated and used. By heating the diffused gas, the liquid 27 to be treated in the diffuser tank 21 can be heated. In this case, for example, the liquid 27 to be treated can be heated to a temperature of 40 to 60 ° C.
  • the conductor 92 in the air diffusion process, air can be diffused while the conductor 92 (see FIG. 3) connected to the negative electrode of the DC power supply 91 (see FIG. 3) is in contact with the liquid 27 to be treated.
  • the generation of the emulsion can be efficiently advanced.
  • the aeration time can be shortened to 1/2 to 1/4.
  • the material which comprises the conductor 92 is not specifically limited, A metal, carbon, etc. can be utilized.
  • the DC power supply 91 can be set to a voltage of 30 to 400 V, for example.
  • the conductor 92 is disposed so as not to contact the aeration tank 21. Further, the positive electrode of the DC power supply 91 can be grounded.
  • the “filtration step” in the present method is a step of filtering the liquid (liquid containing processing water and oil) that has undergone the air diffusion process. Normally, a slimy-like component is generated through an aeration process. By removing such slimy components, the liquid to be treated can be finally made transparent.
  • the transparency means that the liquid to be treated in a state where transparency is inferior is the same as the raw material oil (oil before mixing with processing water) and the obtained compatible transparent hydrous oil. Or a compatible transparent hydrous oil means higher transparency.
  • the filtration in the filtration step is usually performed using a filter. Moreover, only one stage of filtration may be performed, and multiple stages of filtration may be performed. When performing multi-stage filtration, filters can be included with different filtration accuracy.
  • the filtration accuracy of the filter in the filtration step is not particularly limited, but is preferably 1 to 10 ⁇ m. In this range, the above-mentioned slime can be removed without re-separating water dispersed in the oil in the air diffusion step. Further, the filtration accuracy is more preferably 2 to 9 ⁇ m, and further preferably 3 to 7 ⁇ m.
  • any filter medium may be used for each filter medium constituting the filter. That is, for example, filter paper may be used, a nonwoven fabric may be used, a stretched porous film may be used, and other filter media may be used. These filter media may use only 1 type and may use 2 or more types together. In these, it is preferable to use the filter medium which consists of a nonwoven fabric using a resin fiber, and what is called a synthetic fiber paper (For example, the nonwoven fabric of a dry-type manufacturing method) is preferable.
  • the type of resin used for the filter medium is not particularly limited, and olefin resins such as polypropylene, polyester resins such as PET, polyamide resins such as nylon, and cellulose resins such as rayon and acetate can be used. Among these, polypropylene is particularly preferable. That is, for example, polypropylene synthetic paper can be used.
  • the liquid to be processed may be passed through the filter in any way. That is, for example, the liquid to be treated may be passed through the filter by applying pressure from the upstream side, may be suctioned from the downstream side and passed through the filter, or may be passed using centrifugal force due to rotation. It may be allowed to flow down naturally. In these, it is preferable to flow down naturally and to filter without using pressurization and / or centrifugal force. This is because when pressurized and / or centrifugal force is used, it is feared that the oily water is separated.
  • the “amine compound addition step” in this method includes a liquid to be treated during the air diffusion step, a liquid to be treated after the air diffusion step and before the filtration step, a liquid to be treated during the filtration step, and a liquid to be treated after the filtration step.
  • steps of adding an amine compound as a clarifying agent to at least one of the liquids to be treated That is, this method comprises a step of adding an amine compound to the liquid to be treated after the air diffusion step.
  • this amine compound addition process may be performed simultaneously with an aeration process or a filtration process, and may be performed separately from these processes. Furthermore, it can also carry out continuously over both processes of an aeration process and a filtration process.
  • the amine compound addition step can be performed a plurality of times. That is, for example, after the amine compound is added to the liquid to be treated in the air diffusion process, it can be further added to the liquid to be treated in the filtration process. Thus, it can add with respect to 2 or more types of to-be-processed liquids of said each to-be-processed liquid.
  • the emulsion containing processed water and oil can be clarified by adding an amine compound.
  • the liquid to be treated emulsified by the aeration process can be made transparent like oil used as a raw material. The liquid to be treated thus made transparent and the compatible transparent water-containing oil as a finished product can stably maintain the transparent state.
  • the liquid to be treated in the air diffusion process is a liquid that contains processing water and oil and is in the process of becoming an emulsion by air diffusion. Usually, such a liquid to be treated is in a state where an aqueous layer is observed in the lower layer of the emulsion.
  • the liquid to be treated after the air diffusion process and before the filtration process is a liquid containing processing water and oil, and the whole is an emulsion by the air diffusion.
  • the liquid to be treated in the filtration step is a liquid to be treated in the process of containing processing water and oil, the whole being an emulsion, and removing the slimy components and foreign matters by filtration. is there.
  • the liquid to be treated after the filtration step is a treatment in a state where the slimy-like components, foreign matters, and the like are removed by the filtration step.
  • the “amine compound as a clarifying agent” is a component for maintaining the transparency of the obtained compatible transparent hydrous oil.
  • R 1 to R 3 are each independently a hydrogen atom, a halogen atom or a monovalent organic group. That is, the amine compound may be a primary amine, a secondary amine, or a tertiary amine.
  • R 1 to R 3 constituting the amine compound are organic groups
  • examples of these organic groups include alkyl groups, hydroxyalkyl groups, and aryl groups.
  • the alkyl group include a linear or branched alkyl group having 1 to 5 carbon atoms and a cyclic alkyl group having 5 to 8 carbon atoms.
  • Specific examples include a linear or branched alkyl group such as a methyl group, an ethyl group, a propyl group, and a butyl group, and a cycloalkyl group such as a cyclohexyl group.
  • hydroxyalkyl group examples include linear and branched hydroxyalkyl groups having 1 to 5 carbon atoms and hydroxycycloalkyl groups having 6 to 8 carbon atoms. Specific examples include hydroxyalkyl groups such as hydroxymethyl group, hydroxyethyl group, hydroxypropyl group, and hydroxybutyl group, and hydroxycyclohexyl group. Furthermore, examples of the aryl group include a phenyl group, a methylphenyl group, an ethylphenyl group, and a hydroxyphenyl group.
  • the amine compound is preferably a water-soluble amine compound.
  • Examples of such amine compounds include cyclohexylamine, monoethanolamine, diethanolamine, n-butylamine, sec-butylamine, tert-butylamine, isobutylamine, triethanolamine, trishydroxymethylaminomethane, aminophenol, aminocyclohexanol, cyclohexane.
  • Examples include diamine, cyclohexylhydroxylamine, and aminobenzyl alcohol.
  • cyclohexylamine, monoethanolamine, diethanolamine, n-butylamine, sec-butylamine, tert-butylamine, isobutylamine, triethanolamine, and trishydroxymethylaminomethane are particularly preferable. This is because these preferable amine compounds have particularly high solubility in water.
  • These amine compounds may use only 1 type and may use 2 or more types together.
  • an amine compound including at least cyclohexylamine when oil other than heavy oil is used, cyclohexylamine can be used, and triethanolamine can be used without using cyclohexylamine.
  • the compounding amount of the amine compound is not particularly limited, and it is preferably blended to such an extent that a sufficient effect can be obtained according to the type. 1 to 10 parts by volume is preferable. In this range, the compatible transparent hydrous oil can be more effectively transparentized and the transparency can be easily maintained. Moreover, although it may mix
  • the blending ratio is further preferably 0.5 to 8 parts by volume, more preferably 1 to 6 parts by volume, and particularly preferably 1.5 to 4 parts by volume.
  • the amine compound when only cyclohexylamine is used as the clarifying agent, is preferably 0.1 to 5 parts by volume with respect to 100 parts by volume of the liquid to be treated. In this range, the compatible transparent hydrous oil can be more effectively transparentized and the transparency can be easily maintained. Although it may mix
  • the blending ratio is more preferably 0.2 to 3.5 parts by volume, and particularly preferably 0.5 to 2.5 parts by volume.
  • the volume ratio of cyclohexylamine and triethanolamine is 1: 9 to 3: 7 (particularly 1.5: 8.5 to 2. It is preferred to use an amine mixture mixed in 5: 7.5).
  • the amine compound (amine mixture) is preferably used at a ratio of 0.1 to 5 parts by volume with respect to 100 parts by volume of the liquid to be treated. In this range, the compatible transparent hydrous oil can be more effectively transparentized and the transparency can be easily maintained. Although it may mix
  • the blending ratio is more preferably 0.2 to 3.5 parts by volume, and particularly preferably 0.5 to 2.5 parts by volume.
  • the amine compound may be blended in the liquid to be treated only with the amine compound, but can be blended in the liquid to be treated together with other components.
  • other components include alcohols.
  • alcohols methanol, ethanol and propanol are preferable, and methanol and / or ethanol are particularly preferable.
  • the amine compound: alcohol is 10% by volume: 90% by volume to 90% by volume: 10 when the total of the amine compound and the alcohol is 100% by volume. They can be mixed and used in a volume% range. This ratio (amine compound: alcohol) is preferably in the range of 10% by volume: 90% by volume to 50% by volume: 50% by volume.
  • a compatible transparent water-containing oil having a high water content of 30 to 50% by volume can be obtained. Since the unit price of water is smaller than that of oil, the fuel cost per unit volume can be reduced by mixing 30 to 50% by volume of water (processed water) with oil. Moreover, the compatible transparent hydrous oil obtained by this method can maintain transparency, without oil-water being isolate
  • the transparency of the raw material oil (oil before mixing with processed water) and the obtained compatible transparent hydrous oil are compared, they are the same or compatible transparent hydrous oil It is possible to maintain a state of higher transparency at room temperature (temperature 25 ° C.) for 24 hours or more.
  • the compatible transparent water-containing oil obtained by this method can improve the calorific value in the place of combustion.
  • vegetable oil can also be used as fuel oil, the ratio of dependence on conventional fossil fuels can be reduced.
  • the compatible transparent hydrous oil obtained by this method can reduce the generation amount of CO 2 , NOx, SOx, etc. by the water content at the time of combustion, thereby suppressing global warming and preserving the global environment. Can also contribute greatly. Furthermore, since the hydrated oil produced by the method for producing a compatible transparent hydrated oil of the present invention is made transparent, the commercial value of the product can be increased.
  • the compatible transparent hydrous oil production apparatus of the present invention is a compatible transparent hydrous oil production apparatus 1 for the above production method, and performs aeration means 2 for performing aeration and filtration.
  • a filtering means 3 and an amine compound addition means 7 for adding an amine compound are provided.
  • the “aeration means (2)” usually includes an aeration tank 21.
  • the air diffusion tank 21 is a tank that can store the liquid 27 to be processed and can diffuse the liquid 27 to be processed. Moreover, normally, aeration is performed by discharging gas from the diffusion gas 25 accommodated in the bottom part in the diffusion tank 21. Oil is usually supplied from the oil supply means 5 to the aeration tank 21, and the processing water is supplied from the processing water supply means (processing water preparation means) 4.
  • the oil supply means 5 can include an oil storage tank 51 for storing the oil 55. The oil stored in the oil storage tank 51 can be supplied to the aeration tank 21 via the oil supply conduit 52.
  • the oil supply line 52 can further include a flow meter 53 and a pump 54.
  • the processing water supply means (processing water preparation means) 4 has a function of storing the processed water 49 processed in advance and supplying the stored processed water 49 to the aeration tank 21. However, it may have a function of preparing processed water. That is, the processed water preparation means 4 can be obtained.
  • Processed water preparation means 4 is a means for obtaining processed water.
  • the processing water preparation method in the processing water preparation means 4 is not limited as described above, but in the present apparatus 1, the processing water preparation means 4 includes means for giving a negative oxidation-reduction potential by electrolysis of water before processing. can do. Specifically, it can be a means capable of electrolyzing water (water before processing) supplied to the processed water preparation tank 41 via the water supply pipe line 42.
  • the processed water 49 to which a negative oxidation-reduction potential is applied by electrolysis is supplied to the aeration tank 21 through the processed water supply pipe 45.
  • a pump 46 and a flow meter 47 can be provided in the processing water supply line 45 to adjust and monitor the supply amount to the aeration tank 21.
  • a spray injection function unit 48 can be provided at the end of the processing water supply pipe 45 on the side of the diffuser tank 21. That is, the spray head 48 can be provided. As a result, the processed water 49 can be sprayed into the aeration tank 21. By supplying the spray, the efficiency of air diffusion in the air diffusion tank 21 can be improved, and the time for generating the emulsion can be shortened.
  • a gas preparation means 6 can be provided.
  • the aeration gas 8 is not limited, it can be set as the aeration gas 8 containing the air contacted with the magnetite ore 61 as mentioned above.
  • the gas preparation means 6 includes a gas preparation tank 62 filled with magnetite ore 61 and can send out the air that has passed through the gas preparation tank 62 as the diffused gas 8.
  • the gas preparation means 6 is connected to the air diffusion tank 21 and is connected to the air diffusion gas 25 accommodated in the bottom of the air diffusion tank 21.
  • a valve 63 and a flow meter 64 can be provided in the diffused gas supply conduit 26 connecting the gas preparation means 6 and the diffuser tank 21. Thereby, adjustment and monitoring of the supply amount of the diffused gas 8 to the diffuser tank 21 can be performed.
  • the gas preparation means 6 can comprise means for heating the diffused gas 8.
  • the liquid 27 to be processed in the diffuser tank 21 can be heated.
  • the liquid 27 to be treated can be heated to a temperature of 40 to 60 ° C.
  • means for heating the diffused gas 8 include a diffused gas supply pipe 26 that is a path through which the diffused gas 8 is circulated, and a heater jacket that can be wound around the gas preparation tank 62. By providing such a heater jacket around the diffused gas supply pipe 26 or the gas preparation tank 62, the diffused gas 8 flowing through the inside can be heated.
  • the air diffusion means 2 includes a circulation function unit 22.
  • the circulation function part 22 is a function part that can take out the liquid 27 to be treated from the lower part of the air diffusion tank 21 to the outside of the tank and re-inject it into the tank from the upper part of the air diffusion tank 21.
  • a circulation conduit 221 is connected to the lower portion of the air diffusion tank 21, and the liquid 27 to be treated is taken out from the air diffusion tank 21 to diffuse the air diffusion tank 21.
  • the structure which can be sent to the upper part of this and can circulate the liquid 27 to be processed is preferable.
  • a pump 225 can be disposed in the circulation pipe 221.
  • a flow meter (not shown) can be provided in the circulation conduit 221.
  • a part of the pipe line for sending the liquid 27 to be processed to the filters for performing the filtration step and a part of the circulation pipe line 221 can be used.
  • a magnetite ore contact tank 223 for bringing the liquid to be circulated into contact with the magnetite ore can be provided in the circulation function unit 22.
  • the magnetite ore contact tank 223 can be provided by being connected to the circulation conduit 221.
  • the apparatus 1 of the present invention can include a heating unit that heats the liquid 27 to be processed.
  • the heating means is provided, the liquid 27 to be treated can be heated, and the generation of the emulsion can be promoted more efficiently.
  • the heating means is preferably disposed in the circulation function unit 22.
  • a heating means can be provided as a heater jacket wound around the circulation conduit 221 (see FIG. 1-3).
  • circulated in the circulation pipe line 221 can be heated.
  • a heating means can be provided as the heater jacket 95 wound around the magnetite ore contact tank 223.
  • circulated in the magnetite ore contact tank 223 can be heated.
  • a heating means can be provided as a means for heating the magnetite ore in the magnetite ore contact tank (see FIG. 1-3).
  • circulated in the magnetite ore contact tank 223 can be heated.
  • the liquid 27 to be processed can be heated to a temperature of 40 to 60 ° C.
  • the device 1 of the present invention can include a conductor 92 connected to the negative electrode of the DC power supply 91.
  • the conductor 92 is disposed so as to be in contact with the liquid 27 to be treated when air is diffused, so that the generation of the emulsion can be promoted more efficiently.
  • the material constituting the conductor 92 is not particularly limited, and metal, carbon, and the like can be used.
  • the DC power supply 91 can be set to a voltage of 30 to 400 V, for example.
  • the conductor 92 is disposed so as not to contact the aeration tank 21.
  • the positive electrode of the DC power supply 91 can be grounded.
  • the “filtering means (3)” is not particularly limited as long as it can perform filtration.
  • the first filter 31 and the second filter 34 can be provided. .
  • each filter can be used properly depending on the type of oil. That is, the first filter can be used for filtering compatible transparent hydrous oil using light oil as a raw material, and the second filter can be used for filtering compatible transparent hydrous oil using heavy oil as a raw material.
  • the valves 32 and 35 etc. can be provided in the pipe line which leads to each filter. Further, usually, at the lower part of each filter, extraction pipes 33 and 36 for taking out the obtained compatible transparent water-containing oil are provided.
  • each filter is not shown in FIG. 1 and FIG. 2, but, for example, filtration accuracy using polypropylene synthetic paper, a particle size that provides a filtration efficiency of 90% in a liquid in which seven types of dust of JIS Z8901 are mixed. ) Can accommodate a filter member of approximately 5 ⁇ m.
  • the “amine compound addition means (7)” is a means for adding an amine compound to the liquid to be treated.
  • the amine compound is added to the liquid to be processed during the air diffusion process, the liquid to be processed after the air diffusion process and before the filtration process, the liquid to be processed during the filtration process, and the liquid to be processed after the filtration process. Are performed on the liquid to be treated. Therefore, the amine compound addition means 7 may be any means that can add an amine compound to at least one of the liquids to be treated at the addition time.
  • the addition to the liquid to be treated during the aeration process can be performed by connecting the amine compound addition means 7 to the aeration tank 21.
  • the addition to the liquid to be treated during the air diffusion process can be performed by connecting the amine compound addition means 7 to the circulation function unit 22 (see FIGS. 1 and 2).
  • the addition to the liquid to be treated after the air diffusion process and before the filtration process is performed by connecting the amine compound adding means 7 downstream of the valve 222 and upstream of the first filter 31 and the second filter 34 in FIGS. It can be performed by connecting to a road or the like.
  • the addition to the liquid to be treated during the filtration step can be performed by connecting the amine compound addition means 7 to the first filter 31 and the second filter 34.
  • the addition to the liquid to be treated after the filtration step can be performed by connecting the amine compound addition means 7 to a pipe line downstream of the first filter 31 and the second filter 34 or the like.
  • the amine compound addition means 7 for performing these additions can include an amine compound storage tank 71 for storing the amine compound 75 as shown in FIGS. 1 and 2, for example.
  • an amine compound supply line 72 (connected to the circulation line 221 in FIGS. 1 and 2) for supplying the amine compound to a predetermined supply point can be provided.
  • a pump 74 for delivering the amine compound from the storage tank 71 can be provided.
  • the flowmeter 73 for measuring the flow volume of an amine compound can be provided.
  • a valve 76 for selecting whether or not to supply the amine compound to the circulation pipe 221 can be provided.
  • the amine compound addition means 7 can be set as the structure different from the above. Specifically, an amine compound is supported on a filter for performing a filtration step, and the amine compound is added to the liquid to be processed at the same time as the liquid to be processed passes through the filter. That is, in this case, it can be said that the filtering means 3 also serves as the amine compound adding means 7.
  • the aeration tank 21 can be provided with a liquid cover 28 to be treated in order to suppress scattering of liquid to be processed due to air diffusion and excessive foaming.
  • the liquid cover to be processed can be used by floating on the surface of the liquid 27 to be processed. Specifically, a non-woven fabric having air permeability can be used.
  • the upper limit of the mixing ratio (volume%) of the processing water to the raw material oil of the compatible transparent hydrous oil that can be produced by the present method and apparatus is usually as follows. Gasoline 30% Light oil 30% Kerosene 40% A heavy oil 40% C heavy oil 30% Bunker C heavy oil 30% Palm oil (including biodiesel fuel) 30%
  • vegetable oils such as palm oil generally have a high melting point, unlike mineral oils, and were originally unsuitable for use in winter and cold regions, but the hydrous oil obtained by the method of the present invention has a melting point. Can be lowered to ⁇ 20 ° C., and the practical value as a fuel oil is increased.
  • the processed water 49 has a redox potential of deionized water (an oxidation-reduction potential of 300 to 500 mV) is set to ⁇ 700 mV (value measured by an ORP meter at a temperature of 20 ° C.) by electrolysis in the processed water preparation means 4. It is liquid.
  • the diffused gas prepared by the gas preparation means 6 is diffused while adjusting the flow rate within a range of 400 m 3 / min. Do care.
  • 30 L of the processed water (49) prepared in the processed water preparation tank 41 is discharged from the spray charging function unit 48 and charged into the aeration tank 21.
  • valve 222 When the processing water is completely charged, with the valves 32 and 35 closed, the valve 222 is opened so that the liquid 27 to be processed flows to the circulation function unit 22, and the liquid 27 is circulated while circulating the liquid 27 to be processed.
  • a magnetite ore contact tank 223 filled with magnetite ore 224 is connected to the circulation function unit 22 downstream of a valve 222 provided in the middle of the circulation conduit 221.
  • the to-be-processed liquid 27 taken out from the diffuser tank 21 contacts with the magnetite ore 224 in the magnetite ore contact tank 223 until it is returned to the diffuser tank 21 again through the circulation conduit 221. Is done.
  • the amine compound addition means 7 is further connected to the circulation pipe 221.
  • the amine compound addition means 7 includes an amine compound storage tank 71, an amine compound supply pipe 72, a pump 74, and a flow meter 73. Then, the amine compound 75 is added to the liquid 27 to be processed while the liquid 27 is being circulated in the circulation function unit 22.
  • a liquid in which cyclohexylamine: methyl alcohol is mixed at a ratio of 20% by volume: 80% by volume is used.
  • the total addition amount of an amine compound is 2 volume parts with respect to 100 volume parts of to-be-processed liquids (27).
  • the liquid to be treated in the air diffusing tank 21 is sampled, and the aeration is terminated with reference to the fact that the whole is in an emulsion state without water separating and staying below the sampled liquid to be treated. Then, the liquid 27 to be treated is sent to the filter 31.
  • a filter medium using polypropylene synthetic fiber with a filtration accuracy of 5 ⁇ m (manufactured by Azumi Filter Paper Co., Ltd., a polypropylene synthetic fiber with a filtration accuracy specified by the company of 5 ⁇ m) is accommodated.
  • the liquid 27 is permeated by natural flow without applying pressure, and the slime component is removed and transparentized.
  • Example 2 Manufacture of compatible transparent hydrous oil (80% by volume of light oil / 20% by volume of processed water) In the same manner as in Example 1, when the total amount of light oil and processed water was 100% by volume, A compatible transparent hydrous oil containing 80% by volume and 20% by volume of processed water is obtained.
  • Example 3 Production of compatible transparent hydrous oil (60% by volume of heavy oil / 40% by volume of processed water) In the same manner as in Example 1, when the total of heavy oil and processed water was 100% by volume, heavy oil A compatible transparent hydrous oil containing 60% by volume and 40% by volume of processed water is obtained.
  • Example 4 Production of compatible transparent hydrous oil (70% by volume of light oil / 30% by volume of processed water) Using the compatible transparent hydrous oil production apparatus 1 shown in FIG. % Compatible transparent hydrous oil is produced.
  • the compatible transparent hydrous oil production apparatus 1 in FIG. 3 differs from the compatible transparent hydrous oil production apparatus 1 in FIG. 2 in the following three points. That is, (1) the gas preparation means 6 is not provided, (2) the conductor 92 connected to the DC power supply 91 is provided, and (3) the heater jacket 95 is provided.
  • the conductor 92 in the above (2) is a copper conductor 92 connected to a DC power supply 91 of 30V.
  • the conductor 92 is fixed to the air diffusion tank 21 so as not to contact the air diffusion tank 21. Further, a part of the conductor 92 is immersed in the liquid 27 to be processed in the diffusion tank 21 and is brought into contact with the liquid 27 to be processed.
  • the heater jacket 95 (3) is wound around the outer periphery of the magnetite ore contact layer 223 so that the magnetite ore 224 can be indirectly heated. And the to-be-processed liquid 27 distribute
  • Example 4 Using the compatible transparent hydrous oil production apparatus 1 of FIG. 3, as in Example 1, when the total of light oil and processed water is 100% by volume, 70% by weight of light oil and 30% by volume of processed water are A compatible transparent hydrous oil is obtained. According to Example 4, the preparation time of the compatible transparent hydrous oil is shortened to 1/3 compared to Example 1.
  • the compatible transparent hydrous oil of Example 3 has a density (15 ° C.), kinematic viscosity (50 ° C.), pour point, ash content, cetane index, sulfur content, flash point, moisture (KF method), moisture (distillation). Method), total acid number, 10% distillation temperature, 50% distillation temperature, 90% distillation temperature, and residual carbon content, contained in heavy oil as defined in JIS K 2205.
  • the method for producing a compatible transparent hydrous oil according to the present invention comprises a hydrous oil made from mineral oils (fossil fuels such as petroleum-derived A heavy oil, C heavy oil, bunker C heavy oil, light oil, kerosene, gasoline, etc.) and palm oil. It can be widely used as an oil production method.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physical Water Treatments (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

L'invention a pour objectif de fournir un procédé de fabrication d'huile aqueuse transparente compatible permettant de maintenir des propriétés de transparence tout en mélangeant de l'eau et de l'huile, et également de fournir un dispositif de fabrication d'huile aqueuse transparente compatible associé à ce procédé. Le procédé de l'invention comporte : une étape de diffusion d'air au cours de laquelle une diffusion d'air est exécutée sur un liquide à traiter (27) dans lequel sont combinées une eau conditionnée (49) qui consiste en une eau présentant un potentiel d'oxydo-réduction négatif, et au moins une huile (55) choisie parmi des huiles minérales et des huiles végétales ; une étape de filtrage au cours de laquelle le liquide à traiter (27) est filtré après l'étape de diffusion d'air ; et une étape d'adjonction au cours de laquelle un composé amine est ajouté au liquide à traiter pendant l'étape de diffusion d'air, ou au liquide à traiter après l'étape de diffusion d'air et avant l'étape de filtrage, ou au liquide à traiter pendant l'étape de filtrage, ou au liquide à traiter après l'étape de filtrage. Le dispositif de l'invention consiste en un dispositif de fabrication d'huile aqueuse transparente compatible (1) associé à ce procédé, et est équipé d'un moyen de diffusion d'air (2) effectuant la diffusion d'air, d'un moyen de filtrage (3) effectuant le filtrage et d'un moyen d'adjonction de composé amine (7) ajoutant un composé amine.
PCT/JP2013/057719 2012-12-06 2013-03-18 Procédé et dispositif de fabrication d'huile aqueuse transparente compatible Ceased WO2014087679A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2013512918A JP5362138B1 (ja) 2012-12-06 2013-03-18 相溶性透明含水油の製造方法及び相溶性透明含水油製造装置
PH12015501267A PH12015501267A1 (en) 2012-12-06 2015-06-04 Method for producing compatible, transparent water-containing oil, and device for producing compatible, transparent water-containing oil

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2012-267691 2012-12-06
JP2012267691 2012-12-06

Publications (1)

Publication Number Publication Date
WO2014087679A1 true WO2014087679A1 (fr) 2014-06-12

Family

ID=50883117

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2013/057719 Ceased WO2014087679A1 (fr) 2012-12-06 2013-03-18 Procédé et dispositif de fabrication d'huile aqueuse transparente compatible

Country Status (2)

Country Link
PH (1) PH12015501267A1 (fr)
WO (1) WO2014087679A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019088006A1 (fr) 2017-11-01 2019-05-09 株式会社Ｆｕｓｉｏｎ Ｇｒｏｕｐ Ｈｏｌｄｉｎｇｓ Procédé de fabrication d'huile de combustion
JP6976016B1 (ja) * 2021-05-11 2021-12-01 ガルファ株式会社 化石資源増量装置

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008045022A (ja) * 2006-08-15 2008-02-28 Nobuaki Ando エマルジョン燃料
WO2008072391A1 (fr) * 2006-12-14 2008-06-19 Ait Corporation Carburant émulsionné, et procédé et appareil destinés à sa production
JP2008255208A (ja) * 2007-04-04 2008-10-23 Masayuki Furuno 水可溶化油用添加剤、該添加剤の製造方法、及び該添加剤を用いた水可溶化油の製造方法
JP2009079149A (ja) * 2007-09-26 2009-04-16 Meg:Kk エマルション燃料製造装置及びエマルション燃料の製造方法
JP2010100751A (ja) * 2008-10-24 2010-05-06 Suzuya Denki Service:Kk 水成燃料及びその生成方法と生成装置
JP2012021105A (ja) * 2010-07-16 2012-02-02 Takeshi Wakasugi 化石油水可溶化用添加剤、該添加剤の製造方法及び、該添加剤を用いた化石油水可溶化の製造方法

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008045022A (ja) * 2006-08-15 2008-02-28 Nobuaki Ando エマルジョン燃料
WO2008072391A1 (fr) * 2006-12-14 2008-06-19 Ait Corporation Carburant émulsionné, et procédé et appareil destinés à sa production
JP2008255208A (ja) * 2007-04-04 2008-10-23 Masayuki Furuno 水可溶化油用添加剤、該添加剤の製造方法、及び該添加剤を用いた水可溶化油の製造方法
JP2009079149A (ja) * 2007-09-26 2009-04-16 Meg:Kk エマルション燃料製造装置及びエマルション燃料の製造方法
JP2010100751A (ja) * 2008-10-24 2010-05-06 Suzuya Denki Service:Kk 水成燃料及びその生成方法と生成装置
JP2012021105A (ja) * 2010-07-16 2012-02-02 Takeshi Wakasugi 化石油水可溶化用添加剤、該添加剤の製造方法及び、該添加剤を用いた化石油水可溶化の製造方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019088006A1 (fr) 2017-11-01 2019-05-09 株式会社Ｆｕｓｉｏｎ Ｇｒｏｕｐ Ｈｏｌｄｉｎｇｓ Procédé de fabrication d'huile de combustion
AU2018358373B2 (en) * 2017-11-01 2020-07-02 Fusion Group Holdings Co., Ltd. Method of Preparing Combustible Oil
US10982160B2 (en) 2017-11-01 2021-04-20 Fusion Group Holdings Co., Ltd. Method of preparing combustible oil
JP6976016B1 (ja) * 2021-05-11 2021-12-01 ガルファ株式会社 化石資源増量装置
WO2022239258A1 (fr) * 2021-05-11 2022-11-17 ガルファ株式会社 Dispositif pour augmenter les ressources fossiles
JP2022174538A (ja) * 2021-05-11 2022-11-24 ガルファ株式会社 化石資源増量装置

Also Published As

Publication number Publication date
PH12015501267A1 (en) 2015-08-17

Similar Documents

Publication Publication Date Title
Saleh et al. Glycerol removal from biodiesel using membrane separation technology
EP3218452B1 (fr) Micro-emulsions de l'eau dans fioul lourd
JP5255162B1 (ja) 相溶性透明含水油の製造方法
JPWO2009075317A1 (ja) 含油水を用いて乳化燃料を製造する方法
JP5362138B1 (ja) 相溶性透明含水油の製造方法及び相溶性透明含水油製造装置
WO2015037678A1 (fr) Procédé et dispositif de fabrication d'huile aqueuse transparente compatible
WO2014087679A1 (fr) Procédé et dispositif de fabrication d'huile aqueuse transparente compatible
WO2015037109A1 (fr) Procédé et dispositif de fabrication d'huile aqueuse transparente compatible
CN211562889U (zh) 一种基于石油炼化的高效反应装置
JP2016169270A (ja) 相溶性透明含水油の製造方法及び相溶性透明含水油製造装置
RU55938U1 (ru) Гидродинамический кавитационный преобразователь жидкости
JP2010149089A (ja) エマルジョンオイルの連続生成方法およびエマルジョンオイルの連続生成装置
JP4491526B2 (ja) 簡易廃油改質・燃料化装置及び燃焼装置と組み合わせた前記装置
RU2519466C1 (ru) Установка для приготовления топливных смесей
Saleh A membrane separation process for biodiesel purification
WO2020159350A2 (fr) Procédé pour la production d'un carburant diesel amélioré
CN206069611U (zh) 一种水处理低温等离子装置
CN202289946U (zh) 液体燃料在线乳化装置
CN206051973U (zh) 一种废乳化液处理设备
CN101861376A (zh) 燃料组合物
Naksomboonchai et al. Water removal from crude biodiesel using microbubbles
CN205803193U (zh) 一种用于化工环境保护中的含油污水过滤器
RU1806179C (ru) Способ переработки отработанных нефт ных масел и устройство дл его осуществлени
RU121010U1 (ru) Установка для производства дизельного топлива с низкотемпературными свойствами
CN103289732A (zh) 一种离心分离重油处理系统

Legal Events

Date Code Title Description
ENP Entry into the national phase

Ref document number: 2013512918

Country of ref document: JP

Kind code of ref document: A

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 13861337

Country of ref document: EP

Kind code of ref document: A1

WWE Wipo information: entry into national phase

Ref document number: 12015501267

Country of ref document: PH

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 13861337

Country of ref document: EP

Kind code of ref document: A1