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WO2014073004A4 - Carbon dioxide removal system and method - Google Patents

Carbon dioxide removal system and method Download PDF

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Publication number
WO2014073004A4
WO2014073004A4 PCT/IN2013/000689 IN2013000689W WO2014073004A4 WO 2014073004 A4 WO2014073004 A4 WO 2014073004A4 IN 2013000689 W IN2013000689 W IN 2013000689W WO 2014073004 A4 WO2014073004 A4 WO 2014073004A4
Authority
WO
WIPO (PCT)
Prior art keywords
sorbent
group
carbon dioxide
removal
beds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IN2013/000689
Other languages
French (fr)
Other versions
WO2014073004A2 (en
WO2014073004A3 (en
Inventor
Manish MONGA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AIREF ENGINEERS PVT Ltd
Original Assignee
AIREF ENGINEERS PVT Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by AIREF ENGINEERS PVT Ltd filed Critical AIREF ENGINEERS PVT Ltd
Publication of WO2014073004A2 publication Critical patent/WO2014073004A2/en
Publication of WO2014073004A3 publication Critical patent/WO2014073004A3/en
Publication of WO2014073004A4 publication Critical patent/WO2014073004A4/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047Pressure swing adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20Organic adsorbents
    • B01D2253/206Ion exchange resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/404Further details for adsorption processes and devices using four beds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/45Gas separation or purification devices adapted for specific applications
    • B01D2259/4566Gas separation or purification devices adapted for specific applications for use in transportation means
    • B01D2259/4575Gas separation or purification devices adapted for specific applications for use in transportation means in aeroplanes or space ships
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Treating Waste Gases (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The present invention relates to a system and method for removing carbon dioxide particles in a closed environment of high carbon dioxide concentration. The invention describes an improved method for removing carbon dioxide from a re-circulating gas stream by means of a carbon dioxide adsorbent resin in a closed habitat environment.

Claims

AMENDED CLAIMS received by the International Bureau on 04 May 2014 (04.05.2014) We claim:
1. An automatic regenerative system for carbon dioxide (C02) removal comprising:
a. a first and second group of at least two sorbent beds each and a third group of at least one sorbent bed;
b. a heat exchange system;
c. at least one blower for air movement;
d. at least one boiler for supplying steam to the said first and second group of
sorbent beds;
e. isolation valves for controlling the process;
f. a constant temperature bath for maintaining a desired temperature for C02 exhaust;
g. a vacuum pump for C02 exhaust; and
h. a direct digital control for sequential operation; wherein: the said heat exchange system comprises cooling coils for cooling down the air; the said first group of sorbent beds absorbs C02 and the second group of sorbent beds desorbs C02 in a span of 10 - 20 minutes, and alternately the said first group of sorbent beds desorbs C02 and the second group of sorbent beds absorbs C02; the said third group of the sorbent beds arrests the byproducts of the sorption process; the adsorption rate of the said system is commensurate to the emission rate of C02 by at least 200 persons; the said system maintains a predetermined level (ppm) of C02 conducive for a habitable environment in an enclosed space; the said system operates on continuous basis; the said direct digital control comprises of high end Programmed Logic Controller (PLC) and precision sensors; the said system is completely automatic with no human intervention required to function; and the said system is scalable for more than 200 occupants.
2. The system for C02 removal as claimed in claim 1 wherein, the said sorbent bed is made from material selected from the non-limiting group of metals like iron, Aluminium, Copper, or alike, or metal alloys like brass, stainless steel, or alike.
3. The system for C02 removal as claimed in claim 1 wherein, the said sorbent bed comprises a surface of spherical polystyrene based ion exchange resin covered by specially treated solid amine.
4. The system for C02 removal as claimed in claim 1 wherein, the said sorbent bed of first and second group comprise of a porous polymer structure coated with amine and the said sorbent bed of third group comprises of a porous structure coated with a chemical for arresting excessive amine in the air stream.
5. The system for C02 removal as claimed in claim 1 wherein, the said sorbent beds have shapes selected from the non limiting group of spherical, cylindrical, square, rhomboid, trapezoid or alike.
6. The system for C02 removal as claimed in claim 1 wherein, the steam generated from the said boiler is fed to resin beds for regeneration process.
7. The system for C02 removal as claimed in claim 1 wherein, the said isolation valves are installed at the air inlet and outlet of the individual bed to allow or disallow the air passage through it, as and when required, wherein the said valves remain in open position during the adsorption cycle of the bed while remain closed in the regeneration cycle.
8. A method for removing carbon dioxide from a gas stream, the method comprising: a. controllably supplying the gas stream to the first and second groups of sorbent beds containing solid amine sorbent allowing C02 absorption and removal from the process air stream;
b. altering the pressure of the sorbent beds by blower to facilitate step a. above; c. heating the sorbent bed that is desorbing C02 and cooling the sorbent bed that is absorbing C02;
d. removing C02 from the sorbent bed desorbing C02 as a C02 gas stream; and e. removing the byproducts of any of the above steps through sorbent bed comprising of a porous structure coated with a chemical for arresting excessive amine;
wherein: the said supply is controlled by isolation valves to allow absorption and regeneration process to complete in an effective manner; the said method operates on continuous basis;
the said method comprises direct digital control through high end Programmed Logic Controller (PLC) and precision sensors; the process of regeneration is by steam at a predefined temperature and pressure to suit the optimum regeneration process; and the said method enables maintaining a predetermined level (ppm) of C02 conducive for a habitable environment in an enclosed space.
9. The method of removing carbon dioxide as claimed in claim 8, wherein the said cycle of sorption of C02 at the said first and second group of sorbent beds ranges from 50 - 70 minutes.
10. The method of removing carbon dioxide as claimed in claim 8, wherein the said regeneration process ranges from 5 - 25 minutes.
25

STATEMENT UNDER ARTICLE 19 (1 )

After reviewing the citations of ISR, the applicant has amended the claims and the same are enclosed herewith.

The present invention relates to an improved system and method for removing carbon dioxide from a re-circulating gas stream by means of a carbon dioxide adsorbent resin, wherein the said gas stream is derived from a breathable atmosphere in a closed habitat environment. The main aspect of the invention is to provide a system for removing carbon dioxide (CO?) particles in a closed environment of high carbon dioxide concentration in a manner such that the CC is removed from the air at a higher pace and the sorbent beds are regenerated in lesser time- Further, the system incorporates additional provisions for removal of byproducts of the system and thus providing recycling of fresh breathable air.

The cited arts either relate to C02 scrubbers for manufacturing premises or system for C02 removal using sorbent beds without removing the byproducts of the process itself. The cited art further lacks the pace and regenerative efficiency as indicated in the present invention.

The claims are amended so as to differentiate the invention from the cited arts. The independent claimsl and 8 have been amended to further characterize the present invention.

The following table describes wherein the changes made in the claims along with the basis of such amendments are mentioned:

Figure imgf000005_0001

26

PCT/IN2013/000689 2012-11-08 2013-11-08 Carbondioxide removal system Ceased WO2014073004A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN3472DE2012 2012-11-08
IN3472/DEL/2012 2012-11-08

Publications (3)

Publication Number Publication Date
WO2014073004A2 WO2014073004A2 (en) 2014-05-15
WO2014073004A3 WO2014073004A3 (en) 2014-06-12
WO2014073004A4 true WO2014073004A4 (en) 2014-07-31

Family

ID=50685279

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IN2013/000689 Ceased WO2014073004A2 (en) 2012-11-08 2013-11-08 Carbondioxide removal system

Country Status (1)

Country Link
WO (1) WO2014073004A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106377971A (en) * 2016-11-07 2017-02-08 河南科技学院 Tail gas carbon collecting and compressing system of nuclear power plant

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10279306B2 (en) * 2014-07-10 2019-05-07 Climeworks Ag Steam assisted vacuum desorption process for carbon dioxide capture
CN104368221B (en) * 2014-11-14 2016-05-11 杰瑞石油天然气工程有限公司 The device of the de-hydrocarbon of a kind of high methane gas dehydration
BR112018070204B1 (en) 2016-03-31 2023-01-31 Inventys Thermal Technologies Inc ADSORTIVE GAS SEPARATION PROCESS THAT USES STEAM FOR REGENERATION
CN107042050A (en) * 2017-01-10 2017-08-15 江苏净领环保科技有限公司 One kind automatically controls emission-control equipment
CA3098613A1 (en) 2018-06-14 2019-12-19 Climeworks Ag Efficient method and device for adsorption/desorption of carbon dioxide from gas streams
US11161076B1 (en) 2020-08-26 2021-11-02 Next Carbon Solutions, Llc Devices, systems, facilities, and processes of liquid natural gas processing for power generation
CN112742167B (en) * 2021-01-08 2022-12-02 李长松 Device for improving ecological environment of cave and preparation method thereof
US11865494B2 (en) 2021-11-22 2024-01-09 Next Carbon Solutions, Llc Devices, systems, facilities and processes for bio fermentation based facilities
US11484825B1 (en) 2021-12-20 2022-11-01 Next Carbon Solutions, Llc Devices, systems, facilities and processes for carbon capture optimization in industrial facilities
WO2023177668A1 (en) 2022-03-15 2023-09-21 Next Carbon Solutions, Llc Devices, systems, facilities and processes for co2 capture/sequestration and direct air capture
WO2023177792A1 (en) * 2022-03-17 2023-09-21 Next Carbon Solutions, Llc Devices, systems, facilities and processes for co 2 direct air capture using direct mounted adsorption beds
US11959637B2 (en) 2022-04-06 2024-04-16 Next Carbon Solutions, Llc Devices, systems, facilities and processes for CO2 post combustion capture incorporated at a data center
US12025307B2 (en) 2022-07-26 2024-07-02 Next Carbon Solutions Methods, systems, and devices for flue gas cooling
US12491467B1 (en) 2025-05-12 2025-12-09 Provocative Science Holdings, Inc. Carbon capture systems and methods of use

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CA934939A (en) * 1969-08-12 1973-10-09 Mine Safety Appliances Company Method for separating carbon dioxide from other gases
CA1261813A (en) * 1985-04-22 1989-09-26 Hidefumi Hirai Adsorbent for use in selective gas adsorption- separation and a process for producing the same
US4822383A (en) * 1987-04-30 1989-04-18 United Technologies Corporation Method and apparatus for removing carbon dioxide from air
US5876488A (en) * 1996-10-22 1999-03-02 United Technologies Corporation Regenerable solid amine sorbent
US6755892B2 (en) * 2000-08-17 2004-06-29 Hamilton Sundstrand Carbon dioxide scrubber for fuel and gas emissions
CN102160957A (en) * 2005-07-28 2011-08-24 乞力马扎罗能量公司 Removal of carbon dioxide from air
RU2010123008A (en) * 2007-11-05 2011-12-20 ГЛОБАЛ РИСЕРЧ ТЕКНОЛОДЖИЗ, ЭлЭлСи (US) REMOVING CARBON GAS FROM AIR
EP3653282A1 (en) * 2010-04-30 2020-05-20 Peter Eisenberger System and method for carbon dioxide capture and sequestration

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106377971A (en) * 2016-11-07 2017-02-08 河南科技学院 Tail gas carbon collecting and compressing system of nuclear power plant

Also Published As

Publication number Publication date
WO2014073004A2 (en) 2014-05-15
WO2014073004A3 (en) 2014-06-12

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