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WO2013165321A1 - Fluorescent materials - Google Patents

Fluorescent materials Download PDF

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Publication number
WO2013165321A1
WO2013165321A1 PCT/SK2013/000005 SK2013000005W WO2013165321A1 WO 2013165321 A1 WO2013165321 A1 WO 2013165321A1 SK 2013000005 W SK2013000005 W SK 2013000005W WO 2013165321 A1 WO2013165321 A1 WO 2013165321A1
Authority
WO
WIPO (PCT)
Prior art keywords
materials
fluorescent
fluorescent materials
fact
phosphorogenic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/SK2013/000005
Other languages
French (fr)
Inventor
Ladislav KOZMÉR
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO2013165321A1 publication Critical patent/WO2013165321A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/56—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing sulfur
    • C09K11/562—Chalcogenides
    • C09K11/565—Chalcogenides with zinc cadmium
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/22—Luminous paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/58—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing copper, silver or gold
    • C09K11/582—Chalcogenides
    • C09K11/584—Chalcogenides with zinc or cadmium
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
    • C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
    • C09K11/64—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing aluminium
    • C09K11/641—Chalcogenides
    • C09K11/643—Chalcogenides with alkaline earth metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/54—Pigments; Dyes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/80—Optical properties, e.g. transparency or reflexibility
    • C04B2111/807—Luminescent or fluorescent materials

Definitions

  • nail polishes such as nail polish by Acmellight
  • fluorescent puzzles or fluorescent home accesories there are nail polishes which shine after they are illuminated by UV light
  • fluorescent puzzles or fluorescent home accesories there are nail polishes (such as nail polish by Acmellight) which shine after they are illuminated by UV light
  • fluorescent puzzles or fluorescent home accesories there are nail polishes (such as nail polish by Acmellight) which shine after they are illuminated by UV light, and there are fluorescent puzzles or fluorescent home accesories.
  • the solution is based on materials which themselves are fluorescent and can be used as material base or as surface applications.
  • Fluorescence of the materials is achieved by absorption of daylight and consequently the light is emmited during dark. Intensity and the time period of illumination depends on the ratio of components which create the material, time of illumination is between 2 and 24 hours in dark and it is possible to select from various colors and color shades of light. ... . . . _
  • Base of technical solution are fluorescent materials which consists of base material mixture which stands for 50% to 90% of total material weight and phosphorogenic pigment which stands for 10% to 50% of material weight.
  • the fluorescent material can be in a form of compact mass or in a form of surface coating.
  • a base mixture can be used materials used in building industry, such as gypsum, mosaic wall coating, joint substances based on anorganic materials or organic sealants or polyurethane (PUR) plasticized or nonplasticized, epoxide resins, transparent lackquers based on synthetic materials, synthetic and non-.synthetic cover color.
  • Phosphorogenic pigment can be zinc sulphide and coper, or strontium aluminate.
  • Material is prepared as a mixture of 75% of cement substance used for joints Ceresit (which can be used for setting of tiles) and 25% of phosphorogenic pigment which is zinc sulphide and coper.
  • Material is prepared as a mixture of 50% of gypsum and 25% of phosphorogenic pigment which is strontium aluminate.
  • the final material can be used for production various garden architecture accesories, such as sculptures, garden lights, garden benches, etc.
  • the mixture consists of 70% of synthetic acryl color and 30% of phosphorogenic pigment strontium aluminate.
  • PUR nonplasticized polyurethane
  • phosphorogenic pigment which is zinc sulphide and coper.
  • the final mixture can be used in production of different products, such as orientation boards, street identification boards, billboards, advertising and promotional boards, etc.
  • Mixture consisting of 84% of epoxide lackquer and 16% of phosphorogenic pigment strontium aluminate can be used as a transparent lapkquer for surface finishing of various products, such as direction pillarets, edge lines used for traffic roads and pavements, etc.
  • base material which can be PVC and 10% of phosphorogenic pigment strontium aluminate can be used as organic coating, which are materials used, for surface finishings of decorative items, for instance for Christmas tree decorations.
  • Industial application of fluorescent materials prepared according to this invention is in various types of industries, in individual or mass production.
  • Main advantage of the solution is based on the fact, that there is no need for additional source of light, the solution operates solely on the daylight energy.
  • Invention can be applied in traffic for zebra crossings, for road marking, for street identification boards used in urban areas, but also for orientation boards for frying purposes.
  • Another field of application is garden architecture for production of various products (such as ballustrades, sculptures, pavements) with main advantage being better orientation at lower visibility conditions or after dark.
  • Very important field of application is advertising, billboards and promotional boards made from fluorescent materials alow for more creativity and stronger impact.
  • fluorescent materials which is used in production of banisters, direction pillarets, edge lines used for traffic roads and pavements, etc.
  • these materials can be used as joint substance and mosaic wall coating.
  • Material can also be used as paint coating in production of decorative items, such as Christmas decorations and printed decoration of textiles.
  • the material can be successfully used as cover finishing for vehicles, e.g. frame of bicycle wheels, etc.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Luminescent Compositions (AREA)
  • Road Signs Or Road Markings (AREA)

Description

Fluorescent materials
Field of the invention
Technical solution deals with fluorescent materials based on commonly used materials or products with traditional features which are transfered to materials or products with fluorescent attributes in low visibility conditions or in the dark.
State of the art
There is requirement for higher visibility of various important information in many cases, such as road traffic signs, or making visible information in advertising industry, signmaking of various objects, institutions, buildings. The visibility is especially important in low visibility conditions or in the dark.
The problem of visibility is currently often solved by reflex items, but in such case it is necessary to have contact to the source of light or the item needs to be illuminated by the source of light.
For instance there are nail polishes (such as nail polish by Acmellight) which shine after they are illuminated by UV light, and there are fluorescent puzzles or fluorescent home accesories.
The main disadvantage of known solutions is inevitable condition that there have to be the source of light.
Summary of the invention
The described solution overcomes limitations of existing materials.
The solution is based on materials which themselves are fluorescent and can be used as material base or as surface applications.
Fluorescence of the materials is achieved by absorption of daylight and consequently the light is emmited during dark. Intensity and the time period of illumination depends on the ratio of components which create the material, time of illumination is between 2 and 24 hours in dark and it is possible to select from various colors and color shades of light. ... . . . _
Base of technical solution are fluorescent materials which consists of base material mixture which stands for 50% to 90% of total material weight and phosphorogenic pigment which stands for 10% to 50% of material weight. The fluorescent material can be in a form of compact mass or in a form of surface coating. As a base mixture can be used materials used in building industry, such as gypsum, mosaic wall coating, joint substances based on anorganic materials or organic sealants or polyurethane (PUR) plasticized or nonplasticized, epoxide resins, transparent lackquers based on synthetic materials, synthetic and non-.synthetic cover color. Phosphorogenic pigment can be zinc sulphide and coper, or strontium aluminate.
Examples of realization of the invention
The examples illustrate how the technical solution can be used in practice, but they do not constrict the application area of the solution.
Example Nol
Material is prepared as a mixture of 75% of cement substance used for joints Ceresit (which can be used for setting of tiles) and 25% of phosphorogenic pigment which is zinc sulphide and coper.
Example No2
Material is prepared as a mixture of 50% of gypsum and 25% of phosphorogenic pigment which is strontium aluminate. The final material can be used for production various garden architecture accesories, such as sculptures, garden lights, garden benches, etc.
Example No3
For mosaic wall coat it is necessary to prepare mixture consisting of 75% of wall coat and 25% of phosphorogenic pigment which is zinc sulphide and copper.
Example No 4
To prepare colors which can be used as cover layer for finishing of banisters, direction pillarets, edge lines used for traffic roads and pavements, etc. the mixture consists of 70% of synthetic acryl color and 30% of phosphorogenic pigment strontium aluminate.
Example No5
Mixture consisting of 85% of nonplasticized polyurethane (PUR) (the material can be in form of boards) and 15% of phosphorogenic pigment which is zinc sulphide and coper. The final mixture can be used in production of different products, such as orientation boards, street identification boards, billboards, advertising and promotional boards, etc.
Example No6
Mixture consisting of 84% of epoxide lackquer and 16% of phosphorogenic pigment strontium aluminate can be used as a transparent lapkquer for surface finishing of various products, such as direction pillarets, edge lines used for traffic roads and pavements, etc.
Example No7
Mixture consisiting of 90% of base material which can be PVC and 10% of phosphorogenic pigment strontium aluminate can be used as organic coating, which are materials used, for surface finishings of decorative items, for instance for Christmas tree decorations.
Industrial applicability
Industial application of fluorescent materials prepared according to this invention is in various types of industries, in individual or mass production. Main advantage of the solution is based on the fact, that there is no need for additional source of light, the solution operates solely on the daylight energy.
Invention can be applied in traffic for zebra crossings, for road marking, for street identification boards used in urban areas, but also for orientation boards for turism purposes. Another field of application is garden architecture for production of various products (such as ballustrades, sculptures, pavements) with main advantage being better orientation at lower visibility conditions or after dark. Very important field of application is advertising, billboards and promotional boards made from fluorescent materials alow for more creativity and stronger impact.
Interesting field of application is surface finishing made from fluorescent materials, which is used in production of banisters, direction pillarets, edge lines used for traffic roads and pavements, etc. In building industry these materials can be used as joint substance and mosaic wall coating.
Material can also be used as paint coating in production of decorative items, such as Christmas decorations and printed decoration of textiles.
In transport, the material can be successfully used as cover finishing for vehicles, e.g. frame of bicycle wheels, etc.

Claims

Fluorescent materials characterized by the fact that they are created by the mixture of base material which amounts from 50% to 90% of the total weight and phosphorogenic pigment which amounts from 10% to 50% of the total weight, and the fluorescent material is in form of compact mass or in a form of surface coating material.
Fluorescent materials according to claim 1, characterized by the fact that the base material are materials used in building industry, such as gypsum, mosaic wall coating or sealant substance while all materials are based on anorganic raw materials and organic sealant.
Fluorescent materials according to claim 1, characterized by the fact that the base material is nonplasticized or plasticized polyurethane (PUR), epoxide resin, transparent lackquers based on synthetic substances, synthetic and non-synthetic cover coating.
Fluorescent materials characterized by the fact that the phosphorogenic pigment is zinc sulphide and coper or strontium alumiriate.
PCT/SK2013/000005 2012-04-30 2013-04-15 Fluorescent materials Ceased WO2013165321A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SKPUV61-2012 2012-04-30
SK61-2012U SK6395Y1 (en) 2012-04-30 2012-04-30 A luminiscent materials

Publications (1)

Publication Number Publication Date
WO2013165321A1 true WO2013165321A1 (en) 2013-11-07

Family

ID=46888808

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/SK2013/000005 Ceased WO2013165321A1 (en) 2012-04-30 2013-04-15 Fluorescent materials

Country Status (2)

Country Link
SK (1) SK6395Y1 (en)
WO (1) WO2013165321A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016128667A1 (en) * 2015-02-12 2016-08-18 By Flavie Phosphorescent ceramic material
EP3342763A1 (en) 2016-12-29 2018-07-04 TPA sp. z o.o. A method for producing a luminescent pavement, a luminescent pavement obtained by said method, a combination and use of the combination

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001060943A1 (en) * 2000-02-18 2001-08-23 Orion 21 A.D. Pty Limited Luminescent gel coats and moldable resins
WO2009106342A1 (en) * 2008-02-27 2009-09-03 Lufthansa Technik Ag Escape route marking for an aircraft and method for producing an escape route marking
US20100291409A1 (en) * 2009-05-18 2010-11-18 Natglow Usa, Inc. Method for making a photoluminescent article
WO2011015604A2 (en) * 2009-08-07 2011-02-10 Nightec Gmbh & Co. Kg Photoluminescent granulate and method for the production thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001060943A1 (en) * 2000-02-18 2001-08-23 Orion 21 A.D. Pty Limited Luminescent gel coats and moldable resins
WO2009106342A1 (en) * 2008-02-27 2009-09-03 Lufthansa Technik Ag Escape route marking for an aircraft and method for producing an escape route marking
US20100291409A1 (en) * 2009-05-18 2010-11-18 Natglow Usa, Inc. Method for making a photoluminescent article
WO2011015604A2 (en) * 2009-08-07 2011-02-10 Nightec Gmbh & Co. Kg Photoluminescent granulate and method for the production thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2016128667A1 (en) * 2015-02-12 2016-08-18 By Flavie Phosphorescent ceramic material
FR3032703A1 (en) * 2015-02-12 2016-08-19 By Flavie PHOSPHORESCENT CERAMIC MATERIAL.
EP3342763A1 (en) 2016-12-29 2018-07-04 TPA sp. z o.o. A method for producing a luminescent pavement, a luminescent pavement obtained by said method, a combination and use of the combination
WO2018122079A1 (en) 2016-12-29 2018-07-05 Strabag Sp. Z O.O. A method for producing a luminescent pavement, a luminescent pavement obtained by said method, a combination and use of the combination

Also Published As

Publication number Publication date
SK6395Y1 (en) 2013-03-01
SK612012U1 (en) 2012-10-02

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