[go: up one dir, main page]

WO2013033590A3 - Upgrading hydrocarbon pyrolysis products by hydroprocessing - Google Patents

Upgrading hydrocarbon pyrolysis products by hydroprocessing Download PDF

Info

Publication number
WO2013033590A3
WO2013033590A3 PCT/US2012/053433 US2012053433W WO2013033590A3 WO 2013033590 A3 WO2013033590 A3 WO 2013033590A3 US 2012053433 W US2012053433 W US 2012053433W WO 2013033590 A3 WO2013033590 A3 WO 2013033590A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydroprocessing
pyrolysis products
hydrocarbon pyrolysis
upgrading hydrocarbon
pyrolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2012/053433
Other languages
French (fr)
Other versions
WO2013033590A2 (en
Inventor
Stephen H. Brown
Stephen M. Davis
John S. Buchanan
David T. Ferrughelli
Keith G. REED
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Priority to PCT/US2012/053433 priority Critical patent/WO2013033590A2/en
Priority to CA2843517A priority patent/CA2843517A1/en
Priority to CN201280041820.4A priority patent/CN103764799B/en
Priority to EP12762465.8A priority patent/EP2751234B1/en
Publication of WO2013033590A2 publication Critical patent/WO2013033590A2/en
Publication of WO2013033590A3 publication Critical patent/WO2013033590A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one step of thermal cracking in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/18—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen-generating compounds, e.g. ammonia, water, hydrogen sulfide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention relates to processes for upgrading products obtained from hydrocarbon pyrolysis, equipment useful for such processes, and the use of upgraded pyrolysis products. A tar-containing stream recovered from the pyrolysis effluent is mixed with a utility fluid and subsequently hydroprocessed.
PCT/US2012/053433 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing Ceased WO2013033590A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
PCT/US2012/053433 WO2013033590A2 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing
CA2843517A CA2843517A1 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing
CN201280041820.4A CN103764799B (en) 2011-08-31 2012-08-31 Upgrading Hydrocarbon Pyrolysis Products by Hydrotreating
EP12762465.8A EP2751234B1 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201161529588P 2011-08-31 2011-08-31
US201161529565P 2011-08-31 2011-08-31
US61/529,588 2011-08-31
US61/529,565 2011-08-31
US201261657299P 2012-06-08 2012-06-08
US61/657,299 2012-06-08
PCT/US2012/053433 WO2013033590A2 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing

Publications (2)

Publication Number Publication Date
WO2013033590A2 WO2013033590A2 (en) 2013-03-07
WO2013033590A3 true WO2013033590A3 (en) 2013-04-25

Family

ID=51862040

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/053433 Ceased WO2013033590A2 (en) 2011-08-31 2012-08-31 Upgrading hydrocarbon pyrolysis products by hydroprocessing

Country Status (4)

Country Link
EP (1) EP2751234B1 (en)
CN (1) CN103764799B (en)
CA (1) CA2843517A1 (en)
WO (1) WO2013033590A2 (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9243193B2 (en) * 2013-03-14 2016-01-26 Exxonmobil Research And Engineering Company Fixed bed hydrovisbreaking of heavy hydrocarbon oils
US9777227B2 (en) 2014-04-30 2017-10-03 Exxonmobil Chemical Patents Inc. Upgrading hydrocarbon pyrolysis products
WO2015191148A1 (en) 2014-06-13 2015-12-17 Exxonmobil Chemical Patents Inc. Method and apparatus for improving a hydrocarbon feed
WO2015191236A1 (en) 2014-06-13 2015-12-17 Exxonmobil Chemical Patents Inc. Hydrocarbon upgrading
US9657239B2 (en) 2014-06-20 2017-05-23 Exxonmobil Chemical Patents Inc. Pyrolysis tar upgrading using recycled product
US9637694B2 (en) 2014-10-29 2017-05-02 Exxonmobil Chemical Patents Inc. Upgrading hydrocarbon pyrolysis products
WO2016099787A1 (en) 2014-12-17 2016-06-23 Exxonmobil Chemical Patents Inc. Methods and systems for treating a hydrocarbon feed
US10597592B2 (en) 2016-08-29 2020-03-24 Exxonmobil Chemical Patents Inc. Upgrading hydrocarbon pyrolysis tar
WO2018111572A1 (en) 2016-12-16 2018-06-21 Exxonmobil Chemical Patents Inc. Pyrolysis tar conversion
CN110072976B (en) 2016-12-16 2021-11-30 埃克森美孚化学专利公司 Upgrading of pyrolysis tar
US11162037B2 (en) 2016-12-16 2021-11-02 Exxonmobil Chemical Patents Inc. Pyrolysis tar conversion
CN110072974B (en) 2016-12-16 2021-11-30 埃克森美孚化学专利公司 Pyrolysis tar pretreatment
WO2018213025A1 (en) 2017-05-17 2018-11-22 Exxonmobil Chemical Patents Inc. Upgrading hydrocarbon pyrolysis products
WO2019014008A1 (en) 2017-07-14 2019-01-17 Exxonmobil Research And Engineering Company Multi-stage upgrading pyrolysis tar products
US11401473B2 (en) 2018-08-30 2022-08-02 Exxonmobil Chemical Patents Inc. Process to maintain high solvency of recycle solvent during upgrading of steam cracked tar
WO2020086394A1 (en) 2018-10-25 2020-04-30 Exxonmobil Chemical Patents Inc. Solvent and temperature assisted dissolution of solids from steam cracked tar
CN113195688A (en) 2018-12-14 2021-07-30 埃克森美孚化学专利公司 Temperature control of tar for centrifugal steam cracking
CN113166656A (en) 2018-12-14 2021-07-23 埃克森美孚化学专利公司 Solvent control of tar for centrifugal steam cracking
US20220204866A1 (en) 2019-06-05 2022-06-30 Exxonmobil Chemical Patents Inc. Pyrolysis Tar Upgrading
CN115698232A (en) 2020-04-20 2023-02-03 埃克森美孚化学专利公司 Hydrocarbon pyrolysis of nitrogen-containing feedstocks
CN115667466B (en) 2020-05-22 2024-09-10 埃克森美孚化学专利公司 Fluid for tar hydrotreatment
US20230203386A1 (en) 2020-06-17 2023-06-29 Exxonmobil Chemical Patents Inc. Hydrocarbon Pyrolysis of Advantaged Feeds
CN118525073A (en) 2021-12-09 2024-08-20 埃克森美孚化学专利公司 Steam cracking feed containing arsenic hydrocarbon

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1159843A (en) * 1967-05-24 1969-07-30 Exxon Research Engineering Co Process for manufacture of Heavy Aromatic Solvent
US4173529A (en) * 1978-05-30 1979-11-06 The Lummus Company Hydrotreating of pyrolysis gasoline
US5158668A (en) * 1988-10-13 1992-10-27 Conoco Inc. Preparation of recarburizer coke
US5215649A (en) * 1990-05-02 1993-06-01 Exxon Chemical Patents Inc. Method for upgrading steam cracker tars
WO2010144512A2 (en) * 2009-06-11 2010-12-16 Shell Oil Company A process for the selective hydrogenation and hydrodesulferization of a pyrolysis gasoline feedstock

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6632351B1 (en) 2000-03-08 2003-10-14 Shell Oil Company Thermal cracking of crude oil and crude oil fractions containing pitch in an ethylene furnace
US7097758B2 (en) 2002-07-03 2006-08-29 Exxonmobil Chemical Patents Inc. Converting mist flow to annular flow in thermal cracking application
US7138047B2 (en) 2002-07-03 2006-11-21 Exxonmobil Chemical Patents Inc. Process for steam cracking heavy hydrocarbon feedstocks
US7090765B2 (en) 2002-07-03 2006-08-15 Exxonmobil Chemical Patents Inc. Process for cracking hydrocarbon feed with water substitution
US7820035B2 (en) 2004-03-22 2010-10-26 Exxonmobilchemical Patents Inc. Process for steam cracking heavy hydrocarbon feedstocks
US7235705B2 (en) 2004-05-21 2007-06-26 Exxonmobil Chemical Patents Inc. Process for reducing vapor condensation in flash/separation apparatus overhead during steam cracking of hydrocarbon feedstocks
US7311746B2 (en) 2004-05-21 2007-12-25 Exxonmobil Chemical Patents Inc. Vapor/liquid separation apparatus for use in cracking hydrocarbon feedstock containing resid
US7297833B2 (en) 2004-05-21 2007-11-20 Exxonmobil Chemical Patents Inc. Steam cracking of light hydrocarbon feedstocks containing non-volatile components and/or coke precursors
US7244871B2 (en) 2004-05-21 2007-07-17 Exxonmobil Chemical Patents, Inc. Process and apparatus for removing coke formed during steam cracking of hydrocarbon feedstocks containing resids
US7247765B2 (en) 2004-05-21 2007-07-24 Exxonmobil Chemical Patents Inc. Cracking hydrocarbon feedstock containing resid utilizing partial condensation of vapor phase from vapor/liquid separation to mitigate fouling in a flash/separation vessel
US7488459B2 (en) 2004-05-21 2009-02-10 Exxonmobil Chemical Patents Inc. Apparatus and process for controlling temperature of heated feed directed to a flash drum whose overhead provides feed for cracking
US7351872B2 (en) 2004-05-21 2008-04-01 Exxonmobil Chemical Patents Inc. Process and draft control system for use in cracking a heavy hydrocarbon feedstock in a pyrolysis furnace
US7312371B2 (en) 2004-05-21 2007-12-25 Exxonmobil Chemical Patents Inc. Steam cracking of hydrocarbon feedstocks containing non-volatile components and/or coke precursors
US7220887B2 (en) 2004-05-21 2007-05-22 Exxonmobil Chemical Patents Inc. Process and apparatus for cracking hydrocarbon feedstock containing resid
US8083931B2 (en) 2006-08-31 2011-12-27 Exxonmobil Chemical Patents Inc. Upgrading of tar using POX/coker
JP5339845B2 (en) * 2008-10-14 2013-11-13 Ｊｘ日鉱日石エネルギー株式会社 Fluid catalytic cracking method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1159843A (en) * 1967-05-24 1969-07-30 Exxon Research Engineering Co Process for manufacture of Heavy Aromatic Solvent
US4173529A (en) * 1978-05-30 1979-11-06 The Lummus Company Hydrotreating of pyrolysis gasoline
US5158668A (en) * 1988-10-13 1992-10-27 Conoco Inc. Preparation of recarburizer coke
US5215649A (en) * 1990-05-02 1993-06-01 Exxon Chemical Patents Inc. Method for upgrading steam cracker tars
WO2010144512A2 (en) * 2009-06-11 2010-12-16 Shell Oil Company A process for the selective hydrogenation and hydrodesulferization of a pyrolysis gasoline feedstock

Also Published As

Publication number Publication date
EP2751234A2 (en) 2014-07-09
CA2843517A1 (en) 2013-03-07
WO2013033590A2 (en) 2013-03-07
EP2751234B1 (en) 2016-11-16
CN103764799B (en) 2016-08-24
CN103764799A (en) 2014-04-30

Similar Documents

Publication Publication Date Title
WO2013033590A3 (en) Upgrading hydrocarbon pyrolysis products by hydroprocessing
WO2013033301A3 (en) Use of low boiling point aromatic solvent in hydroprocessing heavy hydrocarbons
IN2015DN03742A (en)
WO2015167774A3 (en) Upgrading hydrocarbon pyrolysis products
WO2013033288A3 (en) Hydroprocessing of heavy hydrocarbon feeds using solvent dilution
WO2014086780A3 (en) Improved fermentation method
WO2011150217A3 (en) Conversion of liquid heavy hydrocarbon feedstocks to gaseous products
WO2014031512A3 (en) Methane conversion apparatus and process using a supersonic flow reactor
WO2013015908A3 (en) Methods and apparatuses for producing aromatic hydrocarbon-rich effluent from lignocellulosic material
EP4223730A3 (en) Organo-catalytic biomass deconstruction
EP2627737A4 (en) Methods for upgrading of contaminated hydrocarbon streams
WO2013043287A3 (en) Hydrocarbon conversion process
PH12014501483A1 (en) Sulfide scavengers, methods for making and methods for using them
PT2553055E (en) Process for treating a stream of cracked gas coming from a hydrocarbon pyrolysis plant, and associated plant
EP2633249A4 (en) Process for separating and recovering ngls from hydrocarbon streams
WO2013033298A3 (en) Use of supercritical fluid in hydroprocessing heavy hydrocarbons
MX350512B (en) Flashline heater system and method.
WO2013012810A3 (en) Upgrading platform using alkali metals
WO2013111015A8 (en) Hydrogen generation
PT2463240E (en) Installation and process for recovering methane from a liquid effluent
WO2012030857A3 (en) Methods and systems for recovering phosphorus from wastewater including digestate recycle
EP2664380A4 (en) Catalyst recovery system, hydrocarbon synthesis reaction apparatus, hydrocarbon synthesis reaction system, and catalyst recovery method
WO2014180969A3 (en) Method and system for preparing a pipelineable hydrocarbon mixture
WO2010127290A3 (en) Improved isoprene hydrocarbon production using genetically engineered cyanobacteria
WO2012021316A3 (en) Selective hydrocracking process for either naphtha or distillate production

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12762465

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2843517

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

REEP Request for entry into the european phase

Ref document number: 2012762465

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2012762465

Country of ref document: EP