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WO2013015676A3 - Thermal de-polymerization process of plastic waste materials - Google Patents

Thermal de-polymerization process of plastic waste materials Download PDF

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Publication number
WO2013015676A3
WO2013015676A3 PCT/MY2012/000212 MY2012000212W WO2013015676A3 WO 2013015676 A3 WO2013015676 A3 WO 2013015676A3 MY 2012000212 W MY2012000212 W MY 2012000212W WO 2013015676 A3 WO2013015676 A3 WO 2013015676A3
Authority
WO
WIPO (PCT)
Prior art keywords
waste materials
plastic waste
thermal
polymerization process
gaseous
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/MY2012/000212
Other languages
French (fr)
Other versions
WO2013015676A2 (en
Inventor
Bahar Bin Mohd Nor Shamsul
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to AU2012287570A priority Critical patent/AU2012287570A1/en
Priority to EP12817287.1A priority patent/EP2734579A4/en
Priority to CN201280046012.7A priority patent/CN103842420A/en
Priority to US14/234,381 priority patent/US20140155662A1/en
Publication of WO2013015676A2 publication Critical patent/WO2013015676A2/en
Publication of WO2013015676A3 publication Critical patent/WO2013015676A3/en
Anticipated expiration legal-status Critical
Priority to ZA2014/01327A priority patent/ZA201401327B/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/12—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by dry-heat treatment only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J11/00—Recovery or working-up of waste materials
    • C08J11/04—Recovery or working-up of waste materials of polymers
    • C08J11/10—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation
    • C08J11/14—Recovery or working-up of waste materials of polymers by chemically breaking down the molecular chains of polymers or breaking of crosslinks, e.g. devulcanisation by treatment with steam or water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1003—Waste materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/307—Cetane number, cetane index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/62—Plastics recycling; Rubber recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Sustainable Development (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The present invention relates to a process for producing liquid transportation fuel (15) based on plastic waste materials (10), comprising the step of: providing (S101) plastic waste materials (10) in molten form; de-polymerizing (S103) molten plastic waste materials (10) into a reaction chamber using a limestone catalyst (20) at a temperature ranging 420°C to 450°C under normal atmospheric pressure condition of 1 Bar; and introducing (S106) gaseous de-polymerized products (25) to a distillation unit thereby allows the gaseous de-polymerized products (25) to be fractionally distilled and condensed into liquid transportation fuels (15).
PCT/MY2012/000212 2011-07-22 2012-07-23 Thermal de-polymerization process of plastic waste materials Ceased WO2013015676A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU2012287570A AU2012287570A1 (en) 2011-07-22 2012-07-23 Thermal de-polymerization process of plastic waste materials
EP12817287.1A EP2734579A4 (en) 2011-07-22 2012-07-23 Thermal de-polymerization process of plastic waste materials
CN201280046012.7A CN103842420A (en) 2011-07-22 2012-07-23 Thermal Depolymerization Method of Plastic Waste
US14/234,381 US20140155662A1 (en) 2011-07-22 2012-07-23 Thermal de-polymerization process of plastic waste materials
ZA2014/01327A ZA201401327B (en) 2011-07-22 2014-02-21 Thermal de-polymerization process of plastic waste materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
MYPI2011003443 2011-07-22
MYPI2011003443 MY150550A (en) 2011-07-22 2011-07-22 Thermal de-polymerization process of plastic waste materials

Publications (2)

Publication Number Publication Date
WO2013015676A2 WO2013015676A2 (en) 2013-01-31
WO2013015676A3 true WO2013015676A3 (en) 2013-04-25

Family

ID=47601694

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/MY2012/000212 Ceased WO2013015676A2 (en) 2011-07-22 2012-07-23 Thermal de-polymerization process of plastic waste materials

Country Status (7)

Country Link
US (1) US20140155662A1 (en)
EP (1) EP2734579A4 (en)
CN (1) CN103842420A (en)
AU (1) AU2012287570A1 (en)
MY (1) MY150550A (en)
WO (1) WO2013015676A2 (en)
ZA (1) ZA201401327B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2918871C (en) * 2013-07-25 2020-04-28 Newpek S.A. De C.V. Method and equipment for producing hydrocarbons by catalytic decomposition of plastic waste products in a single step
CN106349500B (en) * 2016-09-23 2019-09-27 苏州大学 A kind of dechlorination method of chlorine-containing plastic
CN107151561B (en) * 2017-07-19 2019-03-15 北京科技大学 A kind of polystyrene foam plastics pyrolysis oil preparation device
SK8601Y1 (en) 2018-04-21 2019-11-05 Daniska Vladimir Ing Method of thermal depolymerization of plastics material and apparatus for its implementation
CN116328854B (en) * 2023-02-21 2024-02-13 山东科技大学 Preparation method and application of a catalyst for pyrolysis of waste plastics into oil
MX2023005240A (en) * 2023-05-03 2024-12-06 Jaime Manuel SOBRADO ESCUDERO The invention relates to a catalytic system and method for obtaining gasoline and diesel from plastic waste.
US12214341B1 (en) 2024-05-28 2025-02-04 Shandong University Of Science And Technology Method for preparing a catalyst for pyrolysis of waste plastics to produce oil and use thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5849964A (en) * 1993-04-03 1998-12-15 Veba Oel Aktiengesellschaft Process for the processing of salvaged or waste plastic materials
KR20020023472A (en) * 2000-09-22 2002-03-29 손재익 Catalyst for recycle of monomer from disused plastic of polyethylene origin
US20030199717A1 (en) * 2002-04-18 2003-10-23 Miller Stephen J. Process for converting heavy fischer tropsch waxy feeds blended with a waste plastic feedstream into high VI lube oils
KR20090028173A (en) * 2007-09-14 2009-03-18 어스 리사이클 가부시키가이샤 Emulsification Method of Waste
US7626062B2 (en) * 2007-07-31 2009-12-01 Carner William E System and method for recycling plastics

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3969542A (en) * 1974-07-12 1976-07-13 Toyo Engineering Corporation Catalysts and methods of making
US4515659A (en) * 1982-09-30 1985-05-07 Ford Motor Company Pyrolytic conversion of plastic and rubber waste to hydrocarbons with basic salt catalysts
US6534689B1 (en) * 2001-08-24 2003-03-18 Pyrocat Ltd. Process for the conversion of waste plastics to produce hydrocarbon oils
US7932424B2 (en) * 2006-01-26 2011-04-26 Kitakyushu Foundation For The Advancement Of Industry, Science And Technology Method for catalytically cracking waste plastics and apparatus for catalytically cracking waste plastics
US8344195B2 (en) * 2009-10-16 2013-01-01 Jumluck Srinakruang Process for producing fuel from plastic waste material by using dolomite catalyst

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5849964A (en) * 1993-04-03 1998-12-15 Veba Oel Aktiengesellschaft Process for the processing of salvaged or waste plastic materials
KR20020023472A (en) * 2000-09-22 2002-03-29 손재익 Catalyst for recycle of monomer from disused plastic of polyethylene origin
US20030199717A1 (en) * 2002-04-18 2003-10-23 Miller Stephen J. Process for converting heavy fischer tropsch waxy feeds blended with a waste plastic feedstream into high VI lube oils
US7626062B2 (en) * 2007-07-31 2009-12-01 Carner William E System and method for recycling plastics
KR20090028173A (en) * 2007-09-14 2009-03-18 어스 리사이클 가부시키가이샤 Emulsification Method of Waste

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2734579A4 *

Also Published As

Publication number Publication date
WO2013015676A2 (en) 2013-01-31
US20140155662A1 (en) 2014-06-05
AU2012287570A1 (en) 2014-03-13
CN103842420A (en) 2014-06-04
ZA201401327B (en) 2014-12-23
MY150550A (en) 2014-01-30
EP2734579A4 (en) 2015-02-25
EP2734579A2 (en) 2014-05-28

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