WO2012105664A1 - Housing having layered textile/resin structure and manufacturing method therefor - Google Patents
Housing having layered textile/resin structure and manufacturing method therefor Download PDFInfo
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- WO2012105664A1 WO2012105664A1 PCT/JP2012/052433 JP2012052433W WO2012105664A1 WO 2012105664 A1 WO2012105664 A1 WO 2012105664A1 JP 2012052433 W JP2012052433 W JP 2012052433W WO 2012105664 A1 WO2012105664 A1 WO 2012105664A1
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- Prior art keywords
- textile
- resin
- layer
- housing
- adhesive
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
- B29C45/14786—Fibrous material or fibre containing material, e.g. fibre mats or fibre reinforced material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
- B29C45/14811—Multilayered articles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B1/00—Layered products having a non-planar shape
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/1418—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the inserts being deformed or preformed, e.g. by the injection pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/02—Composition of the impregnated, bonded or embedded layer
- B32B2260/021—Fibrous or filamentary layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
- B32B2260/04—Impregnation, embedding, or binder material
- B32B2260/046—Synthetic resin
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2270/00—Resin or rubber layer containing a blend of at least two different polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/584—Scratch resistance
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
- B32B2307/734—Dimensional stability
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
Definitions
- the present invention relates to a textile / resin laminated housing and a manufacturing apparatus thereof, and more particularly, to a textile / resin laminated housing in which a textile layer is laminated on a base resin layer and a manufacturing apparatus thereof.
- housings for electronic devices, home appliances, etc. and housings for automobile interior parts are often made by resin molding in which a decorative material is laminated on the outer surface.
- various types of housings are applied to resin molded housings.
- Decorative material is an indispensable element for differentiating from other products. In such a situation, some companies can freely select a decorative design of a product by applying various decorative materials to the resin molded housing even for the same product.
- Patent Document 1 As a method for decorating a resin molded housing, there is a technique for painting, transferring, and gravure printing on a resin sheet (see, for example, Patent Document 1), and a decorative material containing fibers (textiles) with excellent decorative properties is used.
- a resin molded body formed on the surface of a resin container by molding is proposed (for example, see Patent Document 2).
- a base material film and a decorative material made of a textile material bonded to each other are fused to the surface of the object to be decorated.
- the decorative material is made of a textile material covered with a base film
- the base film is made of polyester resin, polyamide resin such as nylon, polyolefin resin, polystyrene resin, or the like.
- the decoration by painting is not only a flat decoration part, but also the volatile organic compound (VOC) used in the painting process causes health damage,
- VOC volatile organic compound
- the paint is easily peeled off from the plastic molded casing, and the decoration by gravure printing is not suitable for individual small-scale production because of the need to prepare a mold roll for each pattern.
- the base material film covering the textile material is inferior in impact resistance and easily damaged, and the textile material for the object to be decorated is low in resistance at high temperatures during in-mold molding.
- Patent Document 3 In the technology of Patent Document 3, the adhesion of the textile material to the material to be decorated is not sufficient, and the low-volume productivity for diversification of products and the versatility of each product are not always taken into consideration. Further, in the technique of Patent Document 3, the textile material is liable to wrinkle or the pattern is distorted when the molten resin is injected under pressure, and the yield during mass production is poor.
- the object of the present invention is to provide a textile / resin laminated structure housing which is excellent in adhesion of the textile layer to the base resin layer, impact resistance and scratch resistance of the surface of the textile layer, and in addition, there is no generation of wrinkles in the textile layer or distortion of the pattern.
- Textile / resin that can improve the adhesion of the textile layer to the base resin layer and the impact resistance and scratch resistance of the surface of the textile layer, as well as eliminate the occurrence of wrinkles in the textile layer and distortion of the pattern
- An object of the present invention is to provide an apparatus for manufacturing a laminated structure housing.
- a textile / resin laminated structure housing comprising: a transparent acrylic sheet layer; a textile layer bonded to the transparent acrylic sheet layer with an adhesive; and the textile layer. And a base resin layer fixed to the textile layer while infiltrating the gaps between the fibers.
- An apparatus for manufacturing a textile / resin laminated structure housing wherein a fixed mold for receiving a laminate of a transparent acrylic sheet layer and a textile layer bonded to each other via an adhesive with the textile layer as a front surface.
- a movable mold that is moved toward the stationary mold so as to push the received laminated body into the stationary mold in order to form the laminated body; and
- Other fixed molds that are received with the layers facing up, an injection mold that is moved toward the laminated body that is received in the other fixed mold, and a laminated body that is received in the other fixed mold
- the textile / resin laminated housing manufacturing apparatus comprising: a stationary mold for receiving a laminate of a transparent acrylic sheet layer and a textile layer bonded to each other via an adhesive with the textile layer as a front surface; A movable mold moved toward the fixed mold so as to push the received laminated body into the fixed mold in order to form the laminate, and a laminate pushed into the fixed mold An injection mold that is moved toward the body, and an injection unit that injects the raw material of the base resin layer into a space defined by the laminate received by the fixed mold and the injection mold. It is characterized by.
- the textile / resin laminated housing according to claim 1 has improved adhesion of the textile layer to the base resin layer and excellent impact resistance and scratch resistance on the surface of the textile layer. There is no occurrence or distortion of the pattern.
- the adhesiveness of the textile layer to the base resin layer is improved, and the impact resistance and abrasion of the surface of the textile layer are improved by the transparent acrylic layer.
- the generation of wrinkles in the textile layer and distortion of the pattern can be eliminated during the injection molding of the base resin layer.
- FIG. 1 is an external perspective view of a textile / resin laminated structure housing according to an embodiment of the present invention. It is sectional drawing of the textile / resin laminated structure housing which follows the line II-II of FIG. It is a figure used for demonstrating the manufacturing apparatus of the textile / resin laminated structure housing which concerns on embodiment of this invention. It is an external appearance perspective view of the textile / resin laminated structure housing which concerns on other embodiment of this invention.
- FIG. 5 is a cross-sectional view of the textile / resin laminate housing taken along line VV in FIG. 4.
- FIG. 5 is a cross-sectional view of the textile / resin laminate housing taken along line VI-VI in FIG. 4.
- FIG. 1 is an external perspective view of a textile / resin laminated structure housing according to an embodiment of the present invention.
- a textile / resin laminated structure housing 1 (hereinafter sometimes simply referred to as “housing 1”) is an upper casing for a remote control device having a reverse boat structure, and two openings 6 are formed at the bottom of the reverse boat structure.
- housing 1 is an upper casing for a remote control device having a reverse boat structure, and two openings 6 are formed at the bottom of the reverse boat structure.
- FIG. 2 is a cross-sectional view of the textile / resin laminate housing taken along line II-II in FIG.
- the housing 1 is fixed to the textile layer 4 while infiltrating the gap between the fibers of the transparent acrylic sheet layer 2, the textile layer 4 adhered to the transparent acrylic sheet layer 2 via the adhesive 3, and the textile layer 4. And a base resin layer 5.
- the transparent acrylic sheet layer 2 is made of a soft acrylic sheet having a thickness of 0.1 to 0.4 mm containing an elastomer, and has a function of coating the textile layer 4 and resistance to mechanical damage (impact resistance, scratch resistance). .
- the transparent acrylic sheet layer 2 is preferably, for example, a soft acrylic sheet (trade name: Clarity) manufactured and sold by Kuraray Co., Ltd. or a soft acrylic sheet (trade name: Technoloy) manufactured and sold by Sumitomo Chemical Co., Ltd. These soft acrylic sheets are excellent in impact resistance and scratch resistance.
- the above-mentioned elastomer has a kneading rate of 10 to 60 parts by weight with respect to 100 parts by weight of soft acrylic.
- the elastomer contained in the soft acrylic sheet (trade name: clarity) consists of a synthetic rubber containing one material selected from the group of acrylic rubber, nitrile rubber, and isoprene rubber.
- the soft acrylic sheet (trade name: Technoloy) ) Consists of PMMA (polymethacrylate) containing a rubber component in the molecule.
- the textile layer 4 is made of textile including fiber products such as woven fabric and knitted fabric.
- the textile include polyester fabric, knitted fabric, lace, and carbon fiber.
- This textile allows various designs to be easily obtained, and the three-dimensional feeling of the fiber fabric appears as it is. Further, the use of the textile has the effect of increasing the strength of the housing 1 in addition to increasing the degree of freedom of design of the housing 1.
- the adhesive 3 has a characteristic that it can easily adhere both the transparent acrylic sheet layer 2 and the textile layer 4 to each other, and has a low viscosity and a curing speed that is slow enough to allow bubbles to escape.
- the adhesive is made of one material selected from the group of polyurethane adhesives, acrylic adhesives, epoxy resin adhesives, and vinyl chloride adhesives.
- the base resin layer 5 is made of a thermoplastic synthetic resin, preferably a synthetic resin for injection molding.
- the base resin layer 5 is made of ABS (acrylbutyl styrene) resin, PC (polycarbonate) resin, ABS + PC resin, PMMA resin (acrylic resin). It consists of one raw material selected from the group, preferably ABS resin, and the thickness is arbitrarily set according to the product, and in this embodiment is about 2 mm.
- the raw material of the base resin layer 5 is heated and melted by an injection molding machine 20 shown in FIG. 3 to be described later, and a laminate of the transparent acrylic sheet layer 2 and the textile layer 4 bonded to each other by the adhesive 3 has the textile layer 4 as a table. It is injected into a die die 22 shown in FIG.
- the base resin layer 5 is more firmly fixed to the textile layer 4 due to shrinkage of the textile layer 4 and the base resin layer 5 during cooling and solidification.
- the textile layer 4 adheres to the base resin layer 5 by an anchor effect.
- the fibers of the textile layer 4 can improve the strength of the housing 1 and the transparent acrylic sheet layer 2 improves the impact resistance and scratch resistance of the upper casing for the remote control device. Generation of wrinkles in the textile layer 4 and distortion of the pattern can be eliminated during the injection molding of the base resin layer 5. Further, according to the housing of FIG. 1, the pattern on the surface of the housing 1 can be variously selected by changing the textile layer 4.
- a top coating having chemical resistance may be coated on the surface of the transparent acrylic sheet layer 2.
- the housing 1 in FIG. 1 has an inverted boat structure with the transparent acrylic sheet layer 2 as the front
- the housing 1 may have an inverted boat structure with the base resin layer 5 as the front.
- the use of the housing 1 is not limited to the upper casing of the remote control structure.
- FIG. 3 is a diagram used for explaining a textile / resin laminated housing manufacturing apparatus according to an embodiment of the present invention.
- steps I and II are performed by a press machine, and steps III and IV are performed by an injection molding machine.
- a laminate of the transparent acrylic sheet layer 2 and the textile layer 2 bonded to each other via the adhesive 3 is prepared.
- the laminate of the transparent acrylic sheet layer 2 and the textile layer 4 is a textile layer.
- Table 4 is placed on a female die 10 (fixed die) of the press machine. This laminated body may be cut into a predetermined shape in advance.
- the adhesive 3 is made of one material selected from the group of polyurethane adhesives, acrylic adhesives, epoxy resin adhesives, and vinyl chloride adhesives.
- step II the male die 11 (movable die) of the press machine is moved to the female die so that the laminate of the transparent acrylic sheet 2 and the textile layer 4 placed in step I is pushed into the female die 10.
- step II the male die 11 (movable die) of the press machine is moved to the female die so that the laminate of the transparent acrylic sheet 2 and the textile layer 4 placed in step I is pushed into the female die 10.
- step II the male die 11 (movable die) of the press machine is moved to the female die so that the laminate of the transparent acrylic sheet 2 and the textile layer 4 placed in step I is pushed into the female die 10.
- die 11 this molded laminated body is taken out from a press machine.
- the periphery of the formed laminated body may be deburred by cutting with a laser cutter or a cutting die (cutting unit).
- Step III of FIG. 3 the laminate of the transparent acrylic sheet layer 2 and the textile layer 4 formed by a press machine is mounted in the female mold 22 (other fixed mold) with the textile layer 4 as a table. Then, the injection molding male mold 12 (injection molding mold) is moved toward the laminated body received in the mold die 22, and the injection hole 20 a of the injection machine 20 is moved through the injection molding male mold 12. After pressing against the injection molding hole 12a, the injection screw 21 is rotated clockwise to feed the raw material 31 of the base resin layer 5 in the tank 30 into the space defined by the laminate and the injection molding male mold 12. Eject.
- the raw material 31 of the base resin layer 5 is infiltrated into the gaps between the fibers of the textile layer 4, and the textile layer 4 and the base resin layer 5 are more firmly fixed to each other due to the shrinkage of the textile layer 4 and the base resin layer 5 when the raw material 31 is cooled and solidified. become.
- step IV after the injection-molded base resin layer 5 is cooled and solidified, the injection machine 20 and the injection-molded male mold 12 are separated from the female mold 10 and the housing 1 is taken out.
- the female mold 10 and the male mold 11 constitute a press machine
- the female mold 22, the injection molding male mold 12 and the injection machine 20 constitute an injection molding machine.
- the press machine and the injection molding machine are the housing 1.
- the manufacturing apparatus is configured.
- the press machine and the injection molding machine may be integrated, and the female die 10 may be used as the female die 22.
- the injection molding male mold 12 is moved toward the laminated body of the transparent acrylic sheet layer 2 and the textile layer 4 molded in the female mold 10.
- step III the raw material 31 of the base resin layer 5 infiltrates into the gaps between the fibers of the textile layer 4, and the textile layer 4 when the raw material 31 is cooled. Further, the shrinkage of the base resin layer 5 makes the fixing to the textile layer 4 stronger, and in addition, the manufacturing process of the housing 1 can be simplified and the surface coating process can be omitted. Furthermore, polycarbonate that can be molded only at high temperatures can be used as the material of the base resin layer 5.
- the adhesiveness of the textile layer 4 to the base resin layer 5 is improved, and the impact resistance of the surface of the textile layer 4 is improved by the transparent acrylic layer 2. Scratch can be improved, and in addition, generation of wrinkles in the textile layer 4 and distortion of the pattern can be eliminated when the base resin layer 5 is injection molded.
- the housing 1 has an inverted boat structure with the transparent acrylic sheet layer 2 as the front.
- the housing 1 has an inverted boat structure with the base resin layer 5 as the surface. It is good.
- the use of these housings 1 is not limited to the remote control structure upper casing.
- FIG. 4 is an external perspective view of a textile / resin laminated structure housing according to another embodiment of the present invention.
- a textile / resin laminated structure housing 40 (hereinafter sometimes simply referred to as “housing 40”) is a casing having an inverted basin structure, and has one protrusion 41 and one opening at the bottom of the inverted basin structure. 42.
- the structure of the housing 40 in FIG. 4 and the manufacturing apparatus thereof are the same as the structure of the housing 1 in FIG. 1 and the manufacturing apparatus thereof, and the same components are denoted by the same reference numerals.
- the cross section of the protrusion 41 is shown in FIG. 5 as a cross-sectional view along line VV in FIG. 4, and the cross section of the opening 42 is shown in FIG. 6 as a cross sectional view along line VI-VI in FIG. .
- the textile / resin structure housings 1 and 40 are described as the upper casing for the remote control device.
- Is intended for decorative products by in-mold molding with a surface coating layer Is intended for decorative products by in-mold molding with a surface coating layer.
- miscellaneous goods including containers and stationery, housings for electronic devices and home appliances including mobile phones and laptop computers, buildings, Examples include housings for interior and exterior products of automobiles and interior housings for aircraft.
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- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Description
本発明は、テキスタイル/樹脂積層構造ハウジング及びその製造装置に関し、特に、基盤樹脂層の上にテキスタイル層が積層されたテキスタイル/樹脂積層構造ハウジング及びその製造装置に関する。 The present invention relates to a textile / resin laminated housing and a manufacturing apparatus thereof, and more particularly, to a textile / resin laminated housing in which a textile layer is laminated on a base resin layer and a manufacturing apparatus thereof.
電子機器や家電等のハウジング及び自動車内装品のハウジングの技術分野において、そのハウジングは、外面に加飾材が積層された樹脂成形によって作られる場合が多く、近年、樹脂成形ハウジングに施されるさまざまな加飾材が他の製品からの差別化に欠かせない要素となっている。このような状況において、一部の企業は、同一製品でも、樹脂成形ハウジングに多様な加飾材を施すことで顧客が自由に製品の加飾デザインを選択することができるようになっている。 In the technical field of housings for electronic devices, home appliances, etc. and housings for automobile interior parts, the housings are often made by resin molding in which a decorative material is laminated on the outer surface. Recently, various types of housings are applied to resin molded housings. Decorative material is an indispensable element for differentiating from other products. In such a situation, some companies can freely select a decorative design of a product by applying various decorative materials to the resin molded housing even for the same product.
樹脂成形ハウジングの加飾方法としては、樹脂シートに塗装、転写、グラビア印刷を施す技術があり(例えば、特許文献1参照)、また、装飾性に優れた繊維(テキスタイル)を含む装飾材をインモールド成形によって樹脂容器の表面に形成した樹脂成形体が提案されている(例えば、特許文献2参照)。この樹脂成形体は、互いに接合された基材フィルム及びテキスタイル素材からなる装飾材が被装飾体の表面に融着されている。装飾材は、一例として、基材フィルムが覆われたテキスタイル素材からなり、基材フィルムはポリエステル樹脂、ナイロン等のポリアミド樹脂、ポリオレフィン樹脂、ポリスチレン樹脂等からなる。 As a method for decorating a resin molded housing, there is a technique for painting, transferring, and gravure printing on a resin sheet (see, for example, Patent Document 1), and a decorative material containing fibers (textiles) with excellent decorative properties is used. A resin molded body formed on the surface of a resin container by molding is proposed (for example, see Patent Document 2). In this resin molded body, a base material film and a decorative material made of a textile material bonded to each other are fused to the surface of the object to be decorated. For example, the decorative material is made of a textile material covered with a base film, and the base film is made of polyester resin, polyamide resin such as nylon, polyolefin resin, polystyrene resin, or the like.
また、被装飾体に加飾材としてのテキスタイル素材を接着する技術として、テキスタイル素材を金型キャビティ面上に張設した後キャビティ内に溶融樹脂を加圧注入することにより、加飾材に溶融樹脂を浸透させて両者を投錨状態に積層圧着する技術がある(例えば、特許文献3参照)。 In addition, as a technique for bonding textile materials as decorating materials to the body to be decorated, the textile materials are stretched over the mold cavity surface, and then molten resin is injected into the cavities to melt into the decorating materials. There is a technique in which a resin is infiltrated and both are laminated and pressure-bonded in a throwing state (see, for example, Patent Document 3).
しかしながら、特許文献1の技術では、塗装による加飾は、加飾部が平面的でしかない上に塗装工程で使用される揮発性有機化合物(VOC)が健康被害を引き起こし、転写による加飾は、プラスチック成形筐体から塗料が剥離し易い場合が多く、グラビア印刷による加飾は、絵柄毎に金型ロールを準備する必要性から個別少量生産には適していない。 However, in the technology of Patent Document 1, the decoration by painting is not only a flat decoration part, but also the volatile organic compound (VOC) used in the painting process causes health damage, In many cases, the paint is easily peeled off from the plastic molded casing, and the decoration by gravure printing is not suitable for individual small-scale production because of the need to prepare a mold roll for each pattern.
また、特許文献2の技術では、テキスタイル素材を覆う基材フィルムが耐衝撃性に劣ると共に傷がつき易いのに加えて、インモールド成形時の高温下における耐性が低く且つ被装飾体に対するテキスタイル素材の接着性が劣り、製品のハウジングを形成するには装飾材が融着された被装飾体にさらなるハウジング加工工程を施す必要がある。
In addition, in the technique of
特許文献3の技術では、被装飾材に対するテキスタイル素材の密着性が十分でない上に、必ずしも製品の多様化のための多種少量生産性及び各製品への汎用性が考慮されていない。また、特許文献3の技術では、溶融樹脂の加圧注入時にテキスタイル素材に皺がよったり絵柄がゆがんだりし易く量産時の歩留まりが悪い。
In the technology of
本発明の目的は、テキスタイル層の基盤樹脂層に対する密着性及びテキスタイル層の表面の耐衝撃性及び擦過性が優れ、加えてテキスタイル層の皺の発生や絵柄のゆがみがないテキスタイル/樹脂積層構造ハウジングを提供すると共に、テキスタイル層の基盤樹脂層に対する密着性及びテキスタイル層の表面の耐衝撃性及び擦過性を向上させ、加えてテキスタイル層の皺の発生や絵柄のゆがみを無くすことができるテキスタイル/樹脂積層構造ハウジングの製造装置を提供することにある。 The object of the present invention is to provide a textile / resin laminated structure housing which is excellent in adhesion of the textile layer to the base resin layer, impact resistance and scratch resistance of the surface of the textile layer, and in addition, there is no generation of wrinkles in the textile layer or distortion of the pattern. Textile / resin that can improve the adhesion of the textile layer to the base resin layer and the impact resistance and scratch resistance of the surface of the textile layer, as well as eliminate the occurrence of wrinkles in the textile layer and distortion of the pattern An object of the present invention is to provide an apparatus for manufacturing a laminated structure housing.
上記目的を達成するために、請求項1に記載のテキスタイル/樹脂積層構造ハウジングは、透明アクリルシート層と、前記透明アクリルシート層に接着剤を介して接着されたテキスタイル層と、前記テキスタイル層の各繊維の隙間に浸潤しつつ前記テキスタイル層に固着された基盤樹脂層とを備えることを特徴とする。 In order to achieve the above object, a textile / resin laminated structure housing according to claim 1, comprising: a transparent acrylic sheet layer; a textile layer bonded to the transparent acrylic sheet layer with an adhesive; and the textile layer. And a base resin layer fixed to the textile layer while infiltrating the gaps between the fibers.
請求項10に記載のテキスタイル/樹脂積層構造ハウジングの製造装置は、接着剤を介して互いに接着された透明アクリルシート層及びテキスタイル層の積層体を前記テキスタイル層を表にして受容する固定金型と、前記積層体を成形するために当該受容された積層体を前記固定金型の中に押し込むように前記固定金型に向けて移動される可動金型と、前記成形された積層体を前記テキスタイル層を表にして受容する他の固定金型と、前記他の固定金型に受容された積層体に向けて移動される射出成形金型と、前記他の固定金型に受容された積層体と前記射出成形金型とで規定される空間に基盤樹脂層の原料を射出する射出手段とを備えることを特徴とする。
An apparatus for manufacturing a textile / resin laminated structure housing according to
請求項11に記載のテキスタイル/樹脂積層構造ハウジングの製造装置は、接着剤を介して互いに接着された透明アクリルシート層及びテキスタイル層の積層体を前記テキスタイル層を表にして受容する固定金型と、前記積層体を成形するために当該受容された積層体を前記固定金型の中に押し込むように前記固定金型に向けて移動される可動金型と、前記固定金型に押し込まれた積層体に向けて移動される射出成形金型と、前記固定金型に受容された積層体と前記射出成形金型とで規定される空間に基盤樹脂層の原料を射出する射出手段とを備えることを特徴とする。
The textile / resin laminated housing manufacturing apparatus according to
請求項1に記載のテキスタイル/樹脂積層構造ハウジングは、テキスタイル層の基盤樹脂層に対する密着性が向上していると共にテキスタイル層の表面の耐衝撃性及び擦過性が優れ、加えてテキスタイル層の皺の発生や絵柄のゆがみがない。 The textile / resin laminated housing according to claim 1 has improved adhesion of the textile layer to the base resin layer and excellent impact resistance and scratch resistance on the surface of the textile layer. There is no occurrence or distortion of the pattern.
請求項10又は11に記載のテキスタイル/樹脂積層構造ハウジングの製造装置によれば、テキスタイル層の基盤樹脂層に対する密着性を向上させると共に、透明アクリル層によって、テキスタイル層の表面の耐衝撃性及び擦過性を向上させ、加えて基盤樹脂層の射出成形時にテキスタイル層の皺の発生や絵柄のゆがみを無くすことができる
According to the apparatus for manufacturing a textile / resin laminated structure housing according to
以下、本発明を図面を参照しながら詳述する。 Hereinafter, the present invention will be described in detail with reference to the drawings.
図1は、本発明の実施の形態に係るテキスタイル/樹脂積層構造ハウジングの外観斜視図である。 FIG. 1 is an external perspective view of a textile / resin laminated structure housing according to an embodiment of the present invention.
図1において、テキスタイル/樹脂積層構造ハウジング1(以下、単に「ハウジング1」という場合もある)は、逆舟形構造のリモコン装置用上部ケーシングであり、逆舟形構造の底部に2つの開口部6を有する。
In FIG. 1, a textile / resin laminated structure housing 1 (hereinafter sometimes simply referred to as “housing 1”) is an upper casing for a remote control device having a reverse boat structure, and two
図2は、図1の線II−IIに沿うテキスタイル/樹脂積層構造ハウジングの断面図である。 FIG. 2 is a cross-sectional view of the textile / resin laminate housing taken along line II-II in FIG.
ハウジング1は、透明アクリルシート層2と、透明アクリルシート層2に接着剤3を介して接着されたテキスタイル層4と、テキスタイル層4の各繊維の隙間に浸潤しつつテキスタイル層4に固着された基盤樹脂層5とを備える。
The housing 1 is fixed to the
透明アクリルシート層2は、エラストマーを含有する厚さ0.1~0.4mmのソフトアクリルシートからなり、テキスタイル層4をコーティングする機能とメカニカルダメージに対する耐性(耐衝撃性、耐擦過性)を有する。透明アクリルシート層2は、例えば、株式会社クラレが製造販売するソフトアクリルシート(商品名:クラリティ)、又は住友化学工業株式会社が製造販売するソフトアクリルシート(商品名:テクノロイ)が好ましい。これらのソフトアクリルシートは耐衝撃性及び耐擦過性が優れている。上記エラストマーは、ソフトアクリル100重量部に対する混練率は、10~60重量部である。また、ソフトアクリルシート(商品名:クラリティ)に含有されるエラストマーは、アクリルゴム、ニトリルゴム、イソプレンゴムの群から選択された1つの素材を含む合成ゴムからなり、ソフトアクリルシート(商品名:テクノロイ)は、分子内にゴム成分を含有するPMMA(ポリメタクリルアクリレート)からなる。
The transparent
テキスタイル層4は、織物、編物等の繊維製品を含むテキスタイルからなる。このテキスタイルとしては、ポリエステル織物、編物、レース、カーボン繊維が挙げられる。
The
このテキスタイルは、さまざまなデザインが容易に得られると共に繊維生地の立体感がそのまま現出される。また、テキスタイルの使用は、ハウジング1のデザイン性の自由度を高めることができるのに加えて、ハウジング1の強度を高める効果を有する。 This textile allows various designs to be easily obtained, and the three-dimensional feeling of the fiber fabric appears as it is. Further, the use of the textile has the effect of increasing the strength of the housing 1 in addition to increasing the degree of freedom of design of the housing 1.
接着剤3は、透明アクリルシート層2とテキスタイル層4の双方を互いに接着し易くし得、しかも、粘度が低く、気泡を逃すことができるほどに硬化速度が遅い特性を有するのが好ましい。接着剤は、ポリウレタン系接着剤、アクリル系接着剤、エポキシ樹脂系接着剤、及び塩化ビニル系接着剤の群から選択された1つの素材からなる。
It is preferable that the
基盤樹脂層5は、熱可塑性合成樹脂、好ましくは射出成形用合成樹脂からなり、具体的には、ABS(アクリルブチルスチレン)樹脂、PC(ポリカーボネート)樹脂、ABS+PC樹脂、PMMA樹脂(アクリル樹脂)の群から選択された1つの素材、好ましくはABS樹脂からなり、厚さは、製品に応じて任意に設定され、本実施の形態では、約2mmである。基盤樹脂層5の原料は、後述する図3の射出成形機20で加熱溶融され、接着剤3により互いに接着された透明アクリルシート層2とテキスタイル層4の積層体がテキスタイル層4を表にして装着された後述する図3における金型ダイ22の中に射出されて、テキスタイル層4の各繊維の隙間に浸潤しながらテキスタイル層4に固着されている(図3)。基盤樹脂層5は、冷却固化時におけるテキスタイル層4及び基盤樹脂層5の収縮によりテキスタイル層4との固着がより強固になっている。
The
図1のハウジング1によれば、基盤樹脂層5がテキスタイル層4の各繊維の隙間に浸潤しつつテキスタイル層4に固着されているので、アンカー効果により、テキスタイル層4の基盤樹脂層5に対する密着性を向上させると共にテキスタイル層4の各繊維がハウジング1の強度を向上させることができ、加えて、透明アクリルシート層2により、リモコン装置用上部ケーシングの耐衝撃性及び耐擦過性を向上させると共に基盤樹脂層5の射出成形時にテキスタイル層4の皺の発生及び絵柄のゆがみを無くすことができる。また、図1のハウジングによれば、ハウジング1の表面の絵柄をテキスタイル層4の変更によりさまざまに選択することができる。
According to the housing 1 of FIG. 1, since the
図1のハウジング1において、透明アクリルシート層2の表面に対薬品性を有するトップコーティングが被覆されてもよい。
In the housing 1 of FIG. 1, a top coating having chemical resistance may be coated on the surface of the transparent
図1のハウジング1は、透明アクリルシート層2を表とする逆舟形構造としたが、このハウジング1は、基盤樹脂層5を表とする逆舟形構造としてもよい。これのハウジング1は、用途がリモコン構造上部ケーシングに限定されない。
Although the housing 1 in FIG. 1 has an inverted boat structure with the transparent
図3は、本発明の実施の形態に係るテキスタイル/樹脂積層構造ハウジングの製造装置を説明するのに用いられる図である。 FIG. 3 is a diagram used for explaining a textile / resin laminated housing manufacturing apparatus according to an embodiment of the present invention.
図3では、プレス機により工程I及びIIが実施されると共に、射出成形機により工程III及びIVが実施される。 In FIG. 3, steps I and II are performed by a press machine, and steps III and IV are performed by an injection molding machine.
まず、接着剤3を介して互いに接着された透明アクリルシート層2及びテキスタイル層2の積層体を準備し、図3の工程Iにおいて、透明アクリルシート層2及びテキスタイル層4の積層体をテキスタイル層4を表にしてプレス機のメス金型10(固定金型)の上に載置する。この積層体は、予め所定の形状に切断されていてもよい。また、接着剤3は、ポリウレタン系接着剤、アクリル系接着剤、エポキシ樹脂系接着剤、及び塩化ビニル系接着剤の群から選択された1つの素材からなる。
First, a laminate of the transparent
次いで、工程IIにおいて、工程Iで載置された透明アクリルシート2及びテキスタイル層4の積層体をメス金型10の中に押し込むようにプレス機のオス金型11(可動金型)をメス金型10に向かって移動する。これにより、透明アクリルシート層2及びテキスタイル層4の積層体をメス金型10及びオス金型11により規定される形状に成形した後、この成形された積層体はプレス機から取り出される。このとき、成形された積層体の周囲をレーザカッタや切断用金型(切断ユニット)で切断してバリ取りを行ってもよい。
Next, in step II, the male die 11 (movable die) of the press machine is moved to the female die so that the laminate of the
続いて、図3の工程IIIにおいて、プレス機で成形された透明アクリルシート層2及びテキスタイル層4の積層体をテキスタイル層4を表にしてメス金型22(他の固定金型)内に装着した上で、金型ダイ22内に受容された積層体に向けて射出成形オス金型12(射出成型金型)を移動すると共に、射出機20の射出孔20aを射出成形オス金型12の射出成形孔12aに押し当てた上で、射出スクリュー21を時計回りに回転させてタンク30内の基盤樹脂層5の原料31を当該積層体と射出成形オス金型12とで規定される空間に射出する。このとき、基盤樹脂層5の原料31はテキスタイル層4の各繊維の隙間に浸潤し、原料31の冷却固化時におけるテキスタイル層4及び基盤樹脂層5の収縮によりテキスタイル層4との固着がより強固になる。
Subsequently, in Step III of FIG. 3, the laminate of the transparent
最後に、工程IVにおいて、射出成形された基盤樹脂層5が冷却して固化した後、射出機20及び射出成形オス金型12がメス金型10から離間されて、ハウジング1が取り出される。
Finally, in step IV, after the injection-molded
メス金型10及びオス金型11はプレス機を構成すると共に、メス金型22、射出成形オス金型12、及び射出機20は射出成形機を構成し、プレス機及び射出成形機はハウジング1の製造装置を構成する。変形例として、プレス機と射出成形機とが一体となっていて、メス金型10がメス金型22として使用されてもよい。この場合は、メス金型10の中で成形された透明アクリルシート層2及びテキスタイル層4の積層体に向けて射出成形オス金型12が移動される。
The
図3のテキスタイル/樹脂積層構造ハウジングの製造装置によれば、工程IIIにおいて、基盤樹脂層5の原料31がテキスタイル層4の各繊維の隙間に浸潤し、原料31の冷却時時におけるテキスタイル層4及び基盤樹脂層5の収縮によりテキスタイル層4との固着がより強固になるのに加えて、ハウジング1の製造工程を簡略化させると共に、表面コーティング塗装工程を省くことができる。さらに、基盤樹脂層5の素材として、高温でしか成形できないポリカーボネートを用いることができる。
According to the textile / resin laminated housing manufacturing apparatus of FIG. 3, in step III, the
また、図3のテキスタイル/樹脂積層構造ハウジングの製造装置によれば、テキスタイル層4の基盤樹脂層5に対する密着性を向上させると共に、透明アクリル層2によって、テキスタイル層4の表面の耐衝撃性及び擦過性を向上させ、加えて基盤樹脂層5の射出成形時にテキスタイル層4の皺の発生や絵柄のゆがみを無くすことができる。
In addition, according to the textile / resin laminated housing manufacturing apparatus of FIG. 3, the adhesiveness of the
図3のテキスタイル/樹脂積層構造ハウジングの製造装置は、ハウジング1を、透明アクリルシート層2を表とする逆舟形構造としているが、このハウジング1は、基盤樹脂層5を表とする逆舟形構造としてもよい。これらのハウジング1は、用途がリモコン構造上部ケーシングに限定されない。
In the textile / resin laminated housing manufacturing apparatus of FIG. 3, the housing 1 has an inverted boat structure with the transparent
図4は、本発明の他の実施の形態に係るテキスタイル/樹脂積層構造ハウジングの外観斜視図である。 FIG. 4 is an external perspective view of a textile / resin laminated structure housing according to another embodiment of the present invention.
図4において、テキスタイル/樹脂積層構造ハウジング40(以下、単に「ハウジング40」という場合もある)は、逆盆構造のケーシングであり、逆盆構造の底部に1つの突出部41と1つの開口部42を有する。
In FIG. 4, a textile / resin laminated structure housing 40 (hereinafter sometimes simply referred to as “
図4のハウジング40の構造及びその製造装置は、上述した図1のハウジング1の構造及びその製造装置と同様であり、同じ構成要素には同一の参照番号が付されている。
The structure of the
突出部41の断面は、図4の線V−Vに沿う断面図として図5で示されると共に、開口部42の断面は、図4の線VI−VIに沿う断面図として図6で示される。
The cross section of the
本発明の実施の形態及び他の実施の形態においては、テキスタイル/樹脂構造ハウジング1及び40は、リモコン装置用上部ケーシングとして記載されているが、本発明の実施の形態の他の適用技術分野としては、表面コーティング層を有するインモールド成形による加飾品が対象であり、具体的には、容器やステーショナリを含む雑貨品、携帯電話やノートパソコンを含む電子機器や家電製品等のハウジング、建築物や自動車の内外装品のハウジング、航空機の内装ハウジングが挙げられる。
In the embodiment of the present invention and the other embodiments, the textile /
1 テキスタイル/樹脂積層構造ハウジング
2 透明アクリルシート層
3 接着剤
4 テキスタイル層
5 基盤樹脂層
6 開口部
10 メス金型
11 オス金型
12 射出成形オス金型
20 射出機
21 射出スクリュー
22 メス金型
30 タンク
31 原料
40 テキスタイル/樹脂積層構造ハウジング
41 突出部
42 開口部
DESCRIPTION OF SYMBOLS 1 Textile / resin laminated
Claims (20)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2011-31350 | 2011-01-31 | ||
| JP2011031350 | 2011-01-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2012105664A1 true WO2012105664A1 (en) | 2012-08-09 |
Family
ID=46602868
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2012/052434 Ceased WO2012105665A1 (en) | 2011-01-31 | 2012-01-27 | Housing having layered textile/resin structure and manufacturing method therefor |
| PCT/JP2012/052433 Ceased WO2012105664A1 (en) | 2011-01-31 | 2012-01-27 | Housing having layered textile/resin structure and manufacturing method therefor |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2012/052434 Ceased WO2012105665A1 (en) | 2011-01-31 | 2012-01-27 | Housing having layered textile/resin structure and manufacturing method therefor |
Country Status (1)
| Country | Link |
|---|---|
| WO (2) | WO2012105665A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2014156861A1 (en) | 2013-03-25 | 2014-10-02 | Art&Tech株式会社 | Nonwoven fabric, sheet, film, multilayer sheet, molded article, and method for producing nonwoven fabric |
| WO2015029453A1 (en) | 2013-08-30 | 2015-03-05 | Art&Tech株式会社 | Textile-like in-mold sheet, method for manufacturing same, preform molded article, textile-like resin molded article, and method for manufacturing same |
| CN115091821A (en) * | 2022-07-07 | 2022-09-23 | 广东东田转印新材料有限公司 | Composite membrane containing solid layer, preparation method thereof and application thereof in plastic molded product |
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| JPH08323934A (en) * | 1995-03-28 | 1996-12-10 | Mitsubishi Rayon Co Ltd | Acrylic film and acrylic laminated injection molded product using the same |
| JPH091586A (en) * | 1995-06-19 | 1997-01-07 | Dainippon Printing Co Ltd | Surface decoration resin molding and simultaneous molding decoration method |
| JP2001277294A (en) * | 2000-03-31 | 2001-10-09 | Yoshida Industry Co Ltd | Method for manufacturing protective panel of display window of electronic machinery |
| JP2005534531A (en) * | 2002-07-29 | 2005-11-17 | ダウ グローバル テクノロジーズ インコーポレーテッド | Molded part having discontinuous fabric surface area and method for producing the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5468743B2 (en) * | 2008-03-18 | 2014-04-09 | 株式会社ユポ・コーポレーション | In-mold molding label and injection-molded body with the label |
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2012
- 2012-01-27 WO PCT/JP2012/052434 patent/WO2012105665A1/en not_active Ceased
- 2012-01-27 WO PCT/JP2012/052433 patent/WO2012105664A1/en not_active Ceased
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| JPH08323934A (en) * | 1995-03-28 | 1996-12-10 | Mitsubishi Rayon Co Ltd | Acrylic film and acrylic laminated injection molded product using the same |
| JPH091586A (en) * | 1995-06-19 | 1997-01-07 | Dainippon Printing Co Ltd | Surface decoration resin molding and simultaneous molding decoration method |
| JP2001277294A (en) * | 2000-03-31 | 2001-10-09 | Yoshida Industry Co Ltd | Method for manufacturing protective panel of display window of electronic machinery |
| JP2005534531A (en) * | 2002-07-29 | 2005-11-17 | ダウ グローバル テクノロジーズ インコーポレーテッド | Molded part having discontinuous fabric surface area and method for producing the same |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014156861A1 (en) | 2013-03-25 | 2014-10-02 | Art&Tech株式会社 | Nonwoven fabric, sheet, film, multilayer sheet, molded article, and method for producing nonwoven fabric |
| WO2015029453A1 (en) | 2013-08-30 | 2015-03-05 | Art&Tech株式会社 | Textile-like in-mold sheet, method for manufacturing same, preform molded article, textile-like resin molded article, and method for manufacturing same |
| KR20160048096A (en) | 2013-08-30 | 2016-05-03 | 아트&테크 가부시키가이샤 | Textile-like in-mold sheet, method for manufacturing same, preform molded article, textile-like resin molded article, and method for manufacturing same |
| EP3718731A1 (en) | 2013-08-30 | 2020-10-07 | Art&Tech Co., Ltd. | Textile-like in-mold sheet, production method of the same, preform molded body, textile-like resin molded body, and production method of the same |
| US11000980B2 (en) | 2013-08-30 | 2021-05-11 | Art & Tech Co., Ltd. | Textile-like in-mold sheet, production method of the same, preform molded body, textile-like resin molded body, and production method of the same |
| CN115091821A (en) * | 2022-07-07 | 2022-09-23 | 广东东田转印新材料有限公司 | Composite membrane containing solid layer, preparation method thereof and application thereof in plastic molded product |
| CN115091821B (en) * | 2022-07-07 | 2023-02-03 | 广东东田转印新材料有限公司 | Composite membrane containing solid layer, preparation method thereof and application thereof in plastic molded product |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012105665A1 (en) | 2012-08-09 |
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